Crystallography Open Database

Information card for entry 7038365

Preview

Coordinates	7038365.cif
Original paper (by DOI)	HTML

Structure parameters

Formula	C36 H62 Ge P3 Rh
Calculated formula	C36 H62 Ge P3 Rh
SMILES	[RhH2]([Ge](c1ccccc1)(c1ccccc1)c1ccccc1)([P](CC)(CC)CC)([P](CC)(CC)CC)[P](CC)(CC)CC
Title of publication	Synthesis of a rhodium(i) germyl complex: a useful tool for C-H and C-F bond activation reactions.
Authors of publication	Ahrens, Theresia; Ahrens, Mike; Braun, Thomas; Braun, Beatrice; Herrmann, Roy
Journal of publication	Dalton transactions (Cambridge, England : 2003)
Year of publication	2016
Journal volume	45
Journal issue	11
Pages of publication	4716 - 4728
a	28.273 ± 0.005 Å
b	17.334 ± 0.003 Å
c	23.14 ± 0.004 Å
α	90°
β	97.339 ± 0.006°
γ	90°
Cell volume	11248 ± 3 Å³
Cell temperature	100 ± 2 K
Ambient diffraction temperature	100 ± 2 K
Number of distinct elements	5
Space group number	14
Hermann-Mauguin space group symbol	P 1 21/c 1
Hall space group symbol	-P 2ybc
Residual factor for all reflections	0.114
Residual factor for significantly intense reflections	0.0526
Weighted residual factors for significantly intense reflections	0.0814
Weighted residual factors for all reflections included in the refinement	0.096
Goodness-of-fit parameter for all reflections included in the refinement	0.996
Diffraction radiation wavelength	0.71073 Å
Diffraction radiation type	MoKα
Has coordinates	Yes
Has disorder	No
Has F_obs	No

Version history

Revision	Date	Message	Files
181685 (current)	2016-04-05	cif/ Updating files of 7038365, 7038366, 7038367, 7038368, 7038369 Original log message: Adding full bibliography for 7038365--7038369.cif.	7038365.cif
176369	2016-02-11	cif/ Adding structures of 7038365, 7038366, 7038367, 7038368, 7038369 via cif-deposit CGI script.	7038365.cif