#------------------------------------------------------------------------------
#$Date: 2015-01-27 21:58:39 +0200 (Tue, 27 Jan 2015) $
#$Revision: 130149 $
#$URL: svn://www.crystallography.net/cod/cif/1/00/40/1004047.cif $
#------------------------------------------------------------------------------
#
# This file is available in the Crystallography Open Database (COD),
# http://www.crystallography.net/
#
# All data on this site have been placed in the public domain by the
# contributors.
#
data_1004047
loop_
_publ_author_name
'Abraham, F'
'Trehoux, J'
'Thomas, D'
_publ_section_title
;
 L A Os₂ O₁₀, a new compound containing isolated clusters Os₂
O₁₀ with metal-metal bonds
;
_journal_coden_ASTM              JSSCBI
_journal_name_full               'Journal of Solid State Chemistry'
_journal_page_first              73
_journal_page_last               79
_journal_paper_doi               10.1016/0022-4596(79)90210-X
_journal_volume                  29
_journal_year                    1979
_chemical_formula_structural     'La3 Os2 O10'
_chemical_formula_sum            'La3 O10 Os2'
_chemical_name_systematic        'Trilanthanum decaoxodiosmate(II)'
_space_group_IT_number           12
_symmetry_cell_setting           monoclinic
_symmetry_Int_Tables_number      12
_symmetry_space_group_name_Hall  '-C 2y'
_symmetry_space_group_name_H-M   'C 1 2/m 1'
_cell_angle_alpha                90
_cell_angle_beta                 115.76(2)
_cell_angle_gamma                90
_cell_formula_units_Z            2
_cell_length_a                   7.911(2)
_cell_length_b                   7.963(2)
_cell_length_c                   6.966(2)
_cell_volume                     395.2
_refine_ls_R_factor_all          0.025
_cod_database_code               1004047
loop_
_symmetry_equiv_pos_as_xyz
x,y,z
x,-y,z
-x,-y,-z
-x,y,-z
1/2+x,1/2+y,z
1/2+x,1/2-y,z
1/2-x,1/2-y,-z
1/2-x,1/2+y,-z
loop_
_atom_site_label
_atom_site_type_symbol
_atom_site_symmetry_multiplicity
_atom_site_Wyckoff_symbol
_atom_site_fract_x
_atom_site_fract_y
_atom_site_fract_z
_atom_site_occupancy
_atom_site_attached_hydrogens
_atom_site_calc_flag
La1 La3+ 2 b 0. 0.5 0. 1. 0 d
La2 La3+ 4 h 0. 0.24319(7) 0.5 1. 0 d
Os1 Os6+ 4 i 0.13397(5) 0. 0.17838(5) 1. 0 d
O1 O2- 4 i 0.86059(105) 0. 0.10590(108) 1. 0 d
O2 O2- 8 j 0.13993(80) 0.23735(75) 0.21221(88) 1. 0 d
O3 O2- 4 i 0.40242(97) 0. 0.28138(105) 1. 0 d
O4 O2- 4 i 0.17857(101) 0. 0.47689(112) 1. 0 d
loop_
_atom_type_symbol
_atom_type_oxidation_number
La3+ 3.000
Os6+ 5.500
O2- -2.000
