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#$Date: 2016-03-04 22:53:31 +0200 (Fri, 04 Mar 2016) $
#$Revision: 177576 $
#$URL: svn://www.crystallography.net/cod/cif/1/10/04/1100492.cif $
#------------------------------------------------------------------------------
#
# This file is available in the Crystallography Open Database (COD),
# http://www.crystallography.net/
#
# All data on this site have been placed in the public domain by the
# contributors.
#
data_1100492
loop_
_publ_author_name
'Garbe, Ralf'
'Wocadlo, Sigrid'
'Kang, Hak-Chul'
'Massa, Werner'
'Harms, Klaus'
'Dehnicke, Kurt'
_publ_section_title
;
 Phosphaniminato-Komplexe des Arsens. Kristallstrukturen von
 [AsCl(NPMe₃)]₂Cl₂, [AsCl(NPMe₃)₂SbCl₄]SbCl₆ und
 [AsCl(NPMe₃)₂SnCl₄] · CH₃CN
;
_journal_coden_ASTM              CHBEAM
_journal_issue                   1
_journal_name_full               'Chemische Berichte'
_journal_page_first              109
_journal_page_last               113
_journal_paper_doi               10.1002/cber.19961290120
_journal_volume                  129
_journal_year                    1996
_chemical_formula_sum            'C6 H18 As Cl11 N2 P2 Sb2'
_space_group_IT_number           15
_symmetry_cell_setting           monoclinic
_symmetry_space_group_name_Hall  '-C 2yc'
_symmetry_space_group_name_H-M   'C 1 2/c 1'
_cell_angle_alpha                90
_cell_angle_beta                 95.84(1)
_cell_angle_gamma                90
_cell_formula_units_Z            8
_cell_length_a                   26.667(6)
_cell_length_b                   7.921(3)
_cell_length_c                   25.604(2)
_cod_original_sg_symbol_H-M      'C 2/c'
_cod_original_formula_sum        'C6 H18 As1 Cl11 N2 P2 Sb2'
_cod_database_code               1100492
loop_
_symmetry_equiv_pos_site_id
_symmetry_equiv_pos_as_xyz
1 x,y,z
2 -x,y,1/2-z
3 1/2+x,1/2+y,z
4 1/2-x,1/2+y,1/2-z
5 -x,-y,-z
6 x,-y,-1/2+z
7 -1/2-x,-1/2-y,-z
8 -1/2+x,-1/2-y,-1/2+z
loop_
_atom_site_label
_atom_site_type_symbol
_atom_site_fract_x
_atom_site_fract_y
_atom_site_fract_z
Sb1 Sb 0.19914(4) 1.02828(14) 0.13198(4)
As1 As 0.08414(6) 1.0294(2) 0.12073(6)
Cl1 Cl 0.0633(2) 0.7807(7) 0.0842(2)
Cl2 Cl 0.2579(2) 1.1309(6) 0.0772(2)
Cl3 Cl 0.2010(2) 0.7616(6) 0.0909(2)
Cl4 Cl 0.2573(2) 0.9291(7) 0.1990(2)
Cl5 Cl 0.2002(2) 1.2973(6) 0.1726(2)
P1 P 0.1277(2) 1.1814(6) 0.0235(2)
P2 P 0.1281(2) 0.8585(6) 0.2234(2)
N1 N 0.1351(5) 1.0996(17) 0.0822(5)
N2 N 0.1352(5) 0.9648(18) 0.1702(5)
C1 C 0.1548(7) 1.0544(23) -0.0222(6)
C2 C 0.0602(6) 1.1941(27) 0.0039(6)
C3 C 0.1534(5) 1.3878(16) 0.0240(5)
C4 C 0.1597(5) 0.9547(16) 0.2793(5)
C5 C 0.1482(4) 0.6487(18) 0.2179(5)
C6 C 0.0622(4) 0.8514(18) 0.2306(5)
Sb2 Sb 0.43526(4) 0.84437(15) 0.13278(4)
Cl6 Cl 0.4311(2) 0.8384(6) 0.2246(2)
Cl7 Cl 0.4420(2) 0.8481(6) 0.0409(2)
Cl8 Cl 0.4533(2) 0.5502(5) 0.1345(2)
Cl9 Cl 0.4173(2) 1.1389(6) 0.1314(2)
Cl10 Cl 0.5228(2) 0.9095(6) 0.1472(2)
Cl11 Cl 0.3492(2) 0.7857(7) 0.1162(2)
loop_
_atom_type_symbol
_atom_type_radius_bond
C 0.68
As 1.21
Cl 0.99
N 0.68
P 1.05
Sb 1.44
