#------------------------------------------------------------------------------
#$Date: 2016-02-18 17:37:37 +0200 (Thu, 18 Feb 2016) $
#$Revision: 176729 $
#$URL: svn://www.crystallography.net/cod/cif/1/10/07/1100753.cif $
#------------------------------------------------------------------------------
#
# This file is available in the Crystallography Open Database (COD),
# http://www.crystallography.net/
#
# All data on this site have been placed in the public domain by the
# contributors.
#
data_1100753
loop_
_publ_author_name
'James D. Crowley'
'Ian M. Steele'
'B. Bosnich'
_publ_section_title
;

Supramolecular Recognition Forces: An Examination of Weak Metal-Metal

Interactions in Host-Guest Formation

;
_journal_name_full               'Inorganic Chemistry'
_journal_page_first              2989
_journal_page_last               2991
_journal_paper_doi               10.1021/ic0481531
_journal_volume                  44
_journal_year                    2005
_chemical_formula_sum            'C92 H118 Cl2 F12 N16 O9 Pt2 Sb2'
_chemical_formula_weight         2524.60
_chemical_name_systematic
; 

 ? 

;
_space_group_IT_number           2
_symmetry_space_group_name_Hall  '-P 1'
_symmetry_space_group_name_H-M   'P -1'
_atom_sites_solution_hydrogens   geom
_atom_sites_solution_primary     direct
_atom_sites_solution_secondary   difmap
_audit_creation_method           SHELXL-97
_cell_angle_alpha                91.11(5)
_cell_angle_beta                 93.27(5)
_cell_angle_gamma                90.39(5)
_cell_formula_units_Z            2
_cell_length_a                   13.90(4)
_cell_length_b                   18.83(5)
_cell_length_c                   19.15(5)
_cell_measurement_temperature    108(2)
_cell_volume                     5003(2)
_computing_structure_refinement  'SHELXL-97 (Sheldrick, 1997)'
_computing_structure_solution    'SHELXS-97 (Sheldrick, 1990)'
_diffrn_ambient_temperature      108(2)
_diffrn_measured_fraction_theta_full 0.996
_diffrn_measured_fraction_theta_max 0.996
_diffrn_radiation_monochromator  graphite
_diffrn_radiation_source         'fine-focus sealed tube'
_diffrn_radiation_type           MoK\a
_diffrn_radiation_wavelength     0.71073
_diffrn_reflns_av_R_equivalents  0.0327
_diffrn_reflns_av_sigmaI/netI    0.0417
_diffrn_reflns_limit_h_max       16
_diffrn_reflns_limit_h_min       -16
_diffrn_reflns_limit_k_max       22
_diffrn_reflns_limit_k_min       -22
_diffrn_reflns_limit_l_max       22
_diffrn_reflns_limit_l_min       -22
_diffrn_reflns_number            47859
_diffrn_reflns_theta_full        25.03
_diffrn_reflns_theta_max         25.03
_diffrn_reflns_theta_min         1.47
_exptl_absorpt_coefficient_mu    3.459
_exptl_absorpt_correction_T_max  0.354
_exptl_absorpt_correction_T_min  0.266
_exptl_absorpt_correction_type   multi-scan
_exptl_absorpt_process_details
;

absorption corrections were made based on correspondance of

equivalent intensities usingprogram SADABS (G. Sheldrick, Bruker 

Analytical X-ray Systems, Madison, WI)

;
_exptl_crystal_colour            orange
_exptl_crystal_density_diffrn    1.675
_exptl_crystal_density_method    'not measured'
_exptl_crystal_description       fragment
_exptl_crystal_F_000             2508
_exptl_crystal_size_max          0.40
_exptl_crystal_size_mid          0.30
_exptl_crystal_size_min          0.30
_refine_diff_density_max         7.527
_refine_diff_density_min         -2.665
_refine_diff_density_rms         0.206
_refine_ls_extinction_method     none
_refine_ls_goodness_of_fit_ref   1.075
_refine_ls_hydrogen_treatment    constr
_refine_ls_matrix_type           full
_refine_ls_number_parameters     1240
_refine_ls_number_reflns         17626
_refine_ls_number_restraints     0
_refine_ls_restrained_S_all      1.075
_refine_ls_R_factor_all          0.0793
_refine_ls_R_factor_gt           0.0678
_refine_ls_shift/su_max          2.489
_refine_ls_shift/su_mean         0.015
_refine_ls_structure_factor_coef Fsqd
_refine_ls_weighting_details
'calc w=1/[σ²(Fo²)+(0.0917P)²+46.6967P] where P=(Fo²+2Fc²)/3'
_refine_ls_weighting_scheme      calc
_refine_ls_wR_factor_gt          0.1767
_refine_ls_wR_factor_ref         0.1830
_reflns_number_gt                14417
_reflns_number_total             17626
_reflns_threshold_expression     >2sigma(I)
_cod_data_source_file            ic0481531si20041231_115410_1.cif
_cod_data_source_block           1-Ptreceptor
_cod_original_cell_volume        5005.0(24)
_cod_database_code               1100753
loop_
_symmetry_equiv_pos_as_xyz
'x, y, z'
'-x, -y, -z'
loop_
_atom_site_label
_atom_site_type_symbol
_atom_site_fract_x
_atom_site_fract_y
_atom_site_fract_z
_atom_site_U_iso_or_equiv
_atom_site_adp_type
_atom_site_occupancy
_atom_site_symmetry_multiplicity
_atom_site_calc_flag
_atom_site_refinement_flags
_atom_site_disorder_assembly
_atom_site_disorder_group
C1 C 0.6844(7) 0.0402(6) 0.6488(5) 0.037(2) Uani 1 1 d . . .
H1 H 0.6909 0.0018 0.6801 0.044 Uiso 1 1 calc R . .
C2 C 0.7036(7) 0.1088(6) 0.6735(5) 0.042(3) Uani 1 1 d . . .
H2 H 0.7217 0.1170 0.7216 0.051 Uiso 1 1 calc R . .
C3 C 0.6967(7) 0.1641(6) 0.6294(5) 0.039(2) Uani 1 1 d . . .
H3 H 0.7102 0.2112 0.6462 0.046 Uiso 1 1 calc R . .
C4 C 0.6696(6) 0.1511(5) 0.5590(5) 0.033(2) Uani 1 1 d . . .
H4 H 0.6645 0.1891 0.5271 0.039 Uiso 1 1 calc R . .
C5 C 0.6510(6) 0.0840(5) 0.5368(5) 0.030(2) Uani 1 1 d . . .
C6 C 0.6208(6) 0.0627(5) 0.4629(5) 0.033(2) Uani 1 1 d . . .
C7 C 0.5782(7) -0.2127(5) 0.4683(6) 0.041(2) Uani 1 1 d . . .
H7 H 0.5905 -0.2316 0.5135 0.049 Uiso 1 1 calc R . .
C8 C 0.5525(8) -0.2577(6) 0.4130(7) 0.054(3) Uani 1 1 d . . .
H8 H 0.5477 -0.3073 0.4204 0.064 Uiso 1 1 calc R . .
C9 C 0.5338(8) -0.2318(6) 0.3474(7) 0.051(3) Uani 1 1 d . . .
H9 H 0.5161 -0.2631 0.3093 0.062 Uiso 1 1 calc R . .
C10 C 0.5410(7) -0.1597(6) 0.3376(6) 0.040(2) Uani 1 1 d . . .
H10 H 0.5288 -0.1406 0.2924 0.048 Uiso 1 1 calc R . .
C11 C 0.5665(6) -0.1150(5) 0.3946(5) 0.034(2) Uani 1 1 d . . .
C12 C 0.5779(6) -0.0369(5) 0.3912(5) 0.031(2) Uani 1 1 d . . .
C13 C 0.6112(6) 0.1092(6) 0.4080(5) 0.034(2) Uani 1 1 d . . .
H13 H 0.6211 0.1589 0.4146 0.041 Uiso 1 1 calc R . .
C14 C 0.5853(6) 0.0778(5) 0.3401(5) 0.030(2) Uani 1 1 d . . .
C15 C 0.5671(6) 0.0057(5) 0.3325(5) 0.032(2) Uani 1 1 d . . .
H15 H 0.5475 -0.0145 0.2881 0.038 Uiso 1 1 calc R . .
C16 C 0.5803(6) 0.1246(5) 0.2792(5) 0.030(2) Uani 1 1 d . . .
C17 C 0.6488(7) 0.1789(5) 0.2740(5) 0.030(2) Uani 1 1 d . . .
H17 H 0.6981 0.1858 0.3099 0.036 Uiso 1 1 calc R . .
C18 C 0.6446(7) 0.2227(5) 0.2164(5) 0.033(2) Uani 1 1 d . . .
C19 C 0.5720(7) 0.2135(6) 0.1640(5) 0.039(2) Uani 1 1 d . . .
C20 C 0.5054(7) 0.1606(6) 0.1701(5) 0.039(2) Uani 1 1 d . . .
H20 H 0.4553 0.1549 0.1345 0.047 Uiso 1 1 calc R . .
C21 C 0.5081(7) 0.1154(5) 0.2257(5) 0.035(2) Uani 1 1 d . . .
H21 H 0.4616 0.0784 0.2279 0.042 Uiso 1 1 calc R . .
C22 C 0.5718(8) 0.2615(7) 0.1018(6) 0.053(3) Uani 1 1 d . . .
H22A H 0.6153 0.2418 0.0673 0.063 Uiso 1 1 calc R . .
H22B H 0.5060 0.2629 0.0793 0.063 Uiso 1 1 calc R . .
C23 C 0.6034(8) 0.3346(6) 0.1221(6) 0.050(3) Uani 1 1 d . . .
H23A H 0.5535 0.3574 0.1496 0.060 Uiso 1 1 calc R . .
H23B H 0.6101 0.3625 0.0793 0.060 Uiso 1 1 calc R . .
C24 C 0.6980(7) 0.3355(5) 0.1647(5) 0.037(2) Uani 1 1 d . . .
C25 C 0.7182(7) 0.2788(5) 0.2102(5) 0.033(2) Uani 1 1 d . . .
C26 C 0.7674(7) 0.3880(6) 0.1601(5) 0.039(2) Uani 1 1 d . . .
C27 C 0.8549(7) 0.3848(6) 0.2007(5) 0.039(2) Uani 1 1 d . . .
C28 C 0.8676(7) 0.3262(5) 0.2441(5) 0.034(2) Uani 1 1 d . . .
C29 C 0.9335(8) 0.4378(6) 0.1961(6) 0.048(3) Uani 1 1 d . . .
H29A H 0.9058 0.4835 0.1806 0.058 Uiso 1 1 calc R . .
H29B H 0.9780 0.4214 0.1606 0.058 Uiso 1 1 calc R . .
C30 C 0.9899(8) 0.4491(6) 0.2662(6) 0.048(3) Uani 1 1 d . . .
H30A H 1.0479 0.4784 0.2596 0.058 Uiso 1 1 calc R . .
H30B H 0.9494 0.4749 0.2991 0.058 Uiso 1 1 calc R . .
C31 C 1.0196(7) 0.3783(6) 0.2965(6) 0.042(2) Uani 1 1 d . . .
C32 C 0.9602(7) 0.3198(5) 0.2871(5) 0.036(2) Uani 1 1 d . . .
C33 C 1.1066(8) 0.3722(6) 0.3381(6) 0.047(3) Uani 1 1 d . . .
H33 H 1.1494 0.4117 0.3434 0.056 Uiso 1 1 calc R . .
C34 C 1.1295(8) 0.3103(6) 0.3704(6) 0.046(3) Uani 1 1 d . . .
H34 H 1.1872 0.3077 0.3993 0.055 Uiso 1 1 calc R . .
C35 C 1.0693(6) 0.2505(5) 0.3618(5) 0.035(2) Uani 1 1 d . . .
C36 C 0.9838(6) 0.2567(5) 0.3185(5) 0.034(2) Uani 1 1 d . . .
H36 H 0.9422 0.2167 0.3110 0.041 Uiso 1 1 calc R . .
C37 C 1.0910(6) 0.1835(5) 0.3970(5) 0.031(2) Uani 1 1 d . . .
C38 C 1.1252(6) 0.1857(6) 0.4665(5) 0.039(2) Uani 1 1 d . . .
H38 H 1.1399 0.2294 0.4905 0.047 Uiso 1 1 calc R . .
C39 C 1.0747(6) 0.1186(6) 0.3614(5) 0.038(2) Uani 1 1 d . . .
H39 H 1.0550 0.1182 0.3130 0.045 Uiso 1 1 calc R . .
C40 C 1.1374(6) 0.1197(6) 0.5001(5) 0.036(2) Uani 1 1 d . . .
C41 C 1.1694(6) 0.1071(6) 0.5743(5) 0.042(3) Uani 1 1 d . . .
C42 C 1.1983(7) 0.1623(7) 0.6209(5) 0.044(3) Uani 1 1 d . . .
H42 H 1.1989 0.2104 0.6068 0.053 Uiso 1 1 calc R . .
C43 C 1.2273(7) 0.1427(8) 0.6914(6) 0.052(3) Uani 1 1 d . . .
H43 H 1.2488 0.1780 0.7249 0.062 Uiso 1 1 calc R . .
C44 C 1.2237(7) 0.0746(7) 0.7092(6) 0.049(3) Uani 1 1 d . . .
H44 H 1.2412 0.0616 0.7559 0.058 Uiso 1 1 calc R . .
C45 C 1.1948(7) 0.0229(7) 0.6602(6) 0.050(3) Uani 1 1 d . . .
H45 H 1.1930 -0.0252 0.6742 0.060 Uiso 1 1 calc R . .
C46 C 1.0870(6) 0.0543(6) 0.3959(5) 0.038(2) Uani 1 1 d . . .
C47 C 1.0722(7) -0.0177(6) 0.3691(5) 0.038(2) Uani 1 1 d . . .
C48 C 1.0426(7) -0.0348(6) 0.3017(5) 0.039(2) Uani 1 1 d . . .
H48 H 1.0318 0.0015 0.2684 0.047 Uiso 1 1 calc R . .
C49 C 1.0285(7) -0.1054(6) 0.2821(6) 0.046(3) Uani 1 1 d . . .
H49 H 1.0078 -0.1181 0.2354 0.056 Uiso 1 1 calc R . .
C50 C 1.0447(7) -0.1568(6) 0.3311(6) 0.047(3) Uani 1 1 d . . .
H50 H 1.0349 -0.2056 0.3189 0.056 Uiso 1 1 calc R . .
C51 C 1.0754(7) -0.1366(6) 0.3983(6) 0.045(3) Uani 1 1 d . . .
H51 H 1.0881 -0.1725 0.4316 0.053 Uiso 1 1 calc R . .
C52 C 0.7458(7) 0.4507(5) 0.1131(5) 0.038(2) Uani 1 1 d . . .
C53 C 0.6823(7) 0.5010(6) 0.1343(5) 0.040(2) Uani 1 1 d . . .
H53 H 0.6572 0.4982 0.1793 0.048 Uiso 1 1 calc R . .
C54 C 0.6539(7) 0.5568(6) 0.0902(6) 0.042(2) Uani 1 1 d . . .
C55 C 0.6928(7) 0.5581(6) 0.0251(5) 0.042(2) Uani 1 1 d . . .
H55 H 0.6742 0.5950 -0.0058 0.051 Uiso 1 1 calc R . .
C56 C 0.7573(8) 0.5080(6) 0.0033(6) 0.042(2) Uani 1 1 d . . .
C57 C 0.7821(8) 0.4528(5) 0.0481(6) 0.042(2) Uani 1 1 d . . .
H57 H 0.8243 0.4166 0.0336 0.051 Uiso 1 1 calc R . .
C58 C 0.5813(8) 0.6128(6) 0.1116(6) 0.047(3) Uani 1 1 d . . .
C59 C 0.5358(9) 0.5955(7) 0.1806(6) 0.057(3) Uani 1 1 d . . .
H59A H 0.5036 0.5491 0.1761 0.086 Uiso 1 1 calc R . .
H59B H 0.4885 0.6320 0.1912 0.086 Uiso 1 1 calc R . .
H59C H 0.5861 0.5945 0.2185 0.086 Uiso 1 1 calc R . .
C60 C 0.6339(10) 0.6846(7) 0.1222(8) 0.065(4) Uani 1 1 d . . .
H60A H 0.6822 0.6815 0.1613 0.097 Uiso 1 1 calc R . .
H60B H 0.5873 0.7216 0.1325 0.097 Uiso 1 1 calc R . .
H60C H 0.6658 0.6963 0.0795 0.097 Uiso 1 1 calc R . .
C61 C 0.5016(9) 0.6178(8) 0.0532(7) 0.067(4) Uani 1 1 d . . .
H61A H 0.5297 0.6326 0.0100 0.100 Uiso 1 1 calc R . .
H61B H 0.4538 0.6528 0.0668 0.100 Uiso 1 1 calc R . .
H61C H 0.4703 0.5713 0.0456 0.100 Uiso 1 1 calc R . .
C62 C 0.7941(10) 0.5106(7) -0.0723(6) 0.055(3) Uani 1 1 d . . .
C63 C 0.8345(12) 0.5833(7) -0.0858(9) 0.078(5) Uani 1 1 d . . .
H63A H 0.8972 0.5892 -0.0602 0.117 Uiso 1 1 calc R . .
H63B H 0.7902 0.6196 -0.0700 0.117 Uiso 1 1 calc R . .
H63C H 0.8425 0.5881 -0.1360 0.117 Uiso 1 1 calc R . .
C64 C 0.7044(15) 0.5040(14) -0.1258(9) 0.132(9) Uani 1 1 d . . .
H64A H 0.7256 0.5075 -0.1735 0.198 Uiso 1 1 calc R . .
H64B H 0.6592 0.5424 -0.1167 0.198 Uiso 1 1 calc R . .
H64C H 0.6725 0.4580 -0.1205 0.198 Uiso 1 1 calc R . .
C65 C 0.863(2) 0.4586(12) -0.0859(10) 0.169(14) Uani 1 1 d . . .
H65A H 0.9172 0.4628 -0.0507 0.253 Uiso 1 1 calc R . .
H65B H 0.8870 0.4655 -0.1325 0.253 Uiso 1 1 calc R . .
H65C H 0.8339 0.4113 -0.0839 0.253 Uiso 1 1 calc R . .
C66 C 0.2740(15) 0.6958(14) 0.2407(13) 0.120(8) Uani 1 1 d . . .
H66 H 0.2270 0.6741 0.2676 0.144 Uiso 1 1 calc R . .
C67 C 0.1412(12) 0.7400(11) 0.1641(14) 0.134(10) Uani 1 1 d . . .
H67A H 0.1026 0.7160 0.1979 0.201 Uiso 1 1 calc R . .
H67B H 0.1259 0.7198 0.1172 0.201 Uiso 1 1 calc R . .
H67C H 0.1266 0.7908 0.1646 0.201 Uiso 1 1 calc R . .
C68 C 0.3116(18) 0.7609(11) 0.1380(16) 0.161(13) Uani 1 1 d . . .
H68A H 0.2943 0.8103 0.1289 0.242 Uiso 1 1 calc R . .
H68B H 0.3105 0.7338 0.0937 0.242 Uiso 1 1 calc R . .
H68C H 0.3764 0.7593 0.1609 0.242 Uiso 1 1 calc R . .
C69 C 0.1291(8) 0.9003(6) 0.8089(5) 0.044(3) Uani 1 1 d . . .
H69 H 0.1680 0.8616 0.7954 0.053 Uiso 1 1 calc R . .
C70 C 0.2704(9) 0.9433(7) 0.8787(7) 0.061(3) Uani 1 1 d . . .
H70A H 0.2742 0.9426 0.9299 0.091 Uiso 1 1 calc R . .
H70B H 0.3069 0.9842 0.8630 0.091 Uiso 1 1 calc R . .
H70C H 0.2978 0.8994 0.8603 0.091 Uiso 1 1 calc R . .
C71 C 0.1159(8) 1.0088(6) 0.8780(6) 0.049(3) Uani 1 1 d . . .
H71A H 0.0484 1.0045 0.8604 0.073 Uiso 1 1 calc R . .
H71B H 0.1436 1.0529 0.8611 0.073 Uiso 1 1 calc R . .
H71C H 0.1193 1.0098 0.9292 0.073 Uiso 1 1 calc R . .
C72 C 0.135(2) 0.7916(15) 0.9810(15) 0.152(11) Uani 1 1 d . . .
H72 H 0.1608 0.8308 1.0081 0.182 Uiso 1 1 calc R . .
C73 C 0.0150(16) 0.7495(10) 0.8989(10) 0.111(7) Uani 1 1 d . . .
H73A H 0.0581 0.7085 0.8973 0.166 Uiso 1 1 calc R . .
H73B H 0.0097 0.7714 0.8528 0.166 Uiso 1 1 calc R . .
H73C H -0.0489 0.7337 0.9116 0.166 Uiso 1 1 calc R . .
C74 C 0.0000(16) 0.8631(9) 0.9613(12) 0.117(8) Uani 1 1 d . . .
H74A H 0.0377 0.8955 0.9930 0.176 Uiso 1 1 calc R . .
H74B H -0.0606 0.8509 0.9821 0.176 Uiso 1 1 calc R . .
H74C H -0.0140 0.8862 0.9165 0.176 Uiso 1 1 calc R . .
C75 C 0.1139(10) 0.2499(8) 0.8179(9) 0.075(4) Uani 1 1 d . . .
H75 H 0.1151 0.2636 0.7704 0.090 Uiso 1 1 calc R . .
C76 C 0.1021(15) 0.2855(12) 0.9355(10) 0.113(7) Uani 1 1 d . . .
H76A H 0.1534 0.2520 0.9485 0.170 Uiso 1 1 calc R . .
H76B H 0.0395 0.2648 0.9451 0.170 Uiso 1 1 calc R . .
H76C H 0.1122 0.3298 0.9628 0.170 Uiso 1 1 calc R . .
C77 C 0.0993(13) 0.3738(8) 0.8467(13) 0.112(7) Uani 1 1 d . . .
H77A H 0.0948 0.3809 0.7961 0.168 Uiso 1 1 calc R . .
H77B H 0.1574 0.3975 0.8673 0.168 Uiso 1 1 calc R . .
H77C H 0.0424 0.3939 0.8675 0.168 Uiso 1 1 calc R . .
C78 C 0.4565(10) 0.0885(9) 0.8630(7) 0.074(4) Uani 1 1 d . . .
H78 H 0.5216 0.0737 0.8614 0.088 Uiso 1 1 calc R . .
C79 C 0.4898(16) 0.101(2) 0.9888(9) 0.198(17) Uani 1 1 d . . .
H79A H 0.4511 0.1054 1.0298 0.297 Uiso 1 1 calc R . .
H79B H 0.5379 0.1397 0.9903 0.297 Uiso 1 1 calc R . .
H79C H 0.5226 0.0554 0.9889 0.297 Uiso 1 1 calc R . .
C80 C 0.3328(12) 0.1326(8) 0.9351(7) 0.077(5) Uani 1 1 d . . .
H80A H 0.3002 0.1403 0.8892 0.116 Uiso 1 1 calc R . .
H80B H 0.3369 0.1775 0.9618 0.116 Uiso 1 1 calc R . .
H80C H 0.2963 0.0977 0.9605 0.116 Uiso 1 1 calc R . .
C81 C 0.4307(13) 0.6856(8) 0.6035(8) 0.075(4) Uani 1 1 d . . .
H81 H 0.4968 0.6916 0.6180 0.090 Uiso 1 1 calc R . .
C82 C 0.4314(16) 0.5898(8) 0.6829(8) 0.098(6) Uani 1 1 d . . .
H82A H 0.5014 0.5970 0.6865 0.147 Uiso 1 1 calc R . .
H82B H 0.4166 0.5409 0.6672 0.147 Uiso 1 1 calc R . .
H82C H 0.4054 0.5984 0.7288 0.147 Uiso 1 1 calc R . .
C83 C 0.2860(13) 0.6295(14) 0.6121(12) 0.127(8) Uani 1 1 d . . .
H83A H 0.2541 0.6758 0.6110 0.191 Uiso 1 1 calc R . .
H83B H 0.2561 0.5993 0.6460 0.191 Uiso 1 1 calc R . .
H83C H 0.2792 0.6069 0.5655 0.191 Uiso 1 1 calc R . .
C84 C 0.6461(14) 0.5507(16) 0.5769(16) 0.147(10) Uani 1 1 d . . .
H84 H 0.6458 0.5673 0.5303 0.176 Uiso 1 1 calc R . .
C85 C 0.613(3) 0.4269(17) 0.550(3) 0.30(3) Uani 1 1 d . . .
H85A H 0.6732 0.4095 0.5325 0.456 Uiso 1 1 calc R . .
H85B H 0.5714 0.4442 0.5107 0.456 Uiso 1 1 calc R . .
H85C H 0.5795 0.3882 0.5725 0.456 Uiso 1 1 calc R . .
C86 C 0.637(3) 0.465(2) 0.6676(14) 0.25(2) Uani 1 1 d . . .
H86A H 0.5725 0.4633 0.6849 0.381 Uiso 1 1 calc R . .
H86B H 0.6760 0.5011 0.6941 0.381 Uiso 1 1 calc R . .
H86C H 0.6677 0.4184 0.6733 0.381 Uiso 1 1 calc R . .
C87 C 0.2772(10) 0.2423(7) 0.1024(7) 0.058(3) Uani 1 1 d . . .
H87 H 0.2362 0.2070 0.0802 0.070 Uiso 1 1 calc R . .
C88 C 0.2024(16) 0.2114(9) 0.2105(9) 0.103(6) Uani 1 1 d . . .
H88A H 0.1480 0.1955 0.1792 0.154 Uiso 1 1 calc R . .
H88B H 0.1789 0.2414 0.2481 0.154 Uiso 1 1 calc R . .
H88C H 0.2351 0.1699 0.2306 0.154 Uiso 1 1 calc R . .
C89 C 0.3333(13) 0.3022(9) 0.2103(9) 0.091(5) Uani 1 1 d . . .
H89A H 0.3889 0.2770 0.2311 0.137 Uiso 1 1 calc R . .
H89B H 0.2980 0.3251 0.2473 0.137 Uiso 1 1 calc R . .
H89C H 0.3556 0.3384 0.1787 0.137 Uiso 1 1 calc R . .
C90 C 0.8617(19) 0.3181(10) 0.5496(12) 0.123(8) Uani 1 1 d . . .
H90 H 0.8574 0.2828 0.5134 0.148 Uiso 1 1 calc R . .
C91 C 0.8974(11) 0.4399(7) 0.5837(9) 0.075(4) Uani 1 1 d . . .
H91A H 0.8552 0.4296 0.6216 0.112 Uiso 1 1 calc R . .
H91B H 0.8735 0.4815 0.5584 0.112 Uiso 1 1 calc R . .
H91C H 0.9629 0.4495 0.6034 0.112 Uiso 1 1 calc R . .
C92 C 0.9472(13) 0.3888(10) 0.4734(9) 0.091(5) Uani 1 1 d . . .
H92A H 0.9387 0.3461 0.4435 0.137 Uiso 1 1 calc R . .
H92B H 1.0160 0.3969 0.4850 0.137 Uiso 1 1 calc R . .
H92C H 0.9203 0.4298 0.4485 0.137 Uiso 1 1 calc R . .
Cl1 Cl 0.65267(18) -0.13980(15) 0.62730(14) 0.0458(6) Uani 1 1 d . . .
Cl2 Cl 1.14575(17) -0.13494(16) 0.57155(14) 0.0488(7) Uani 1 1 d . . .
F1 F 0.1728(8) 0.9110(5) 0.1584(5) 0.108(4) Uani 1 1 d . . .
F2 F 0.2878(8) 0.9392(5) 0.0582(5) 0.101(3) Uani 1 1 d . . .
F3 F 0.1326(7) 1.0100(10) 0.0669(6) 0.169(7) Uani 1 1 d . . .
F4 F 0.2974(9) 1.0710(5) 0.1016(5) 0.115(4) Uani 1 1 d . . .
F5 F 0.1812(8) 1.0429(5) 0.2005(5) 0.107(4) Uani 1 1 d . . .
F6 F 0.3372(7) 0.9730(7) 0.1903(5) 0.107(4) Uani 1 1 d . . .
F7 F 0.0982(7) 0.3566(7) 0.6416(8) 0.136(5) Uani 1 1 d . . .
F8 F 0.2298(8) 0.3252(5) 0.5508(5) 0.103(3) Uani 1 1 d . . .
F9 F 0.2721(6) 0.3196(5) 0.6854(4) 0.078(2) Uani 1 1 d . . .
F10 F 0.3316(12) 0.4195(4) 0.6018(7) 0.170(7) Uani 1 1 d . . .
F11 F 0.1713(8) 0.4566(5) 0.5655(6) 0.116(4) Uani 1 1 d . . .
F12 F 0.2216(8) 0.4551(6) 0.7004(6) 0.106(3) Uani 1 1 d . . .
N1 N 0.6569(5) 0.0273(4) 0.5815(4) 0.0307(17) Uani 1 1 d . . .
N2 N 0.6043(5) -0.0072(4) 0.4534(4) 0.0276(16) Uani 1 1 d . . .
N3 N 0.5861(5) -0.1426(4) 0.4595(4) 0.0324(17) Uani 1 1 d . . .
N4 N 0.8010(6) 0.2746(4) 0.2491(4) 0.0363(19) Uani 1 1 d . . .
N5 N 1.0879(5) -0.0696(5) 0.4183(4) 0.037(2) Uani 1 1 d . . .
N6 N 1.1196(5) 0.0588(5) 0.4650(4) 0.0359(19) Uani 1 1 d . . .
N7 N 1.1688(5) 0.0383(5) 0.5928(4) 0.037(2) Uani 1 1 d . . .
N8 N 0.2434(11) 0.7301(8) 0.1830(10) 0.099(5) Uani 1 1 d . . .
N9 N 0.1696(6) 0.9488(5) 0.8530(5) 0.044(2) Uani 1 1 d . . .
N10 N 0.0534(12) 0.8005(7) 0.9501(8) 0.084(4) Uani 1 1 d . . .
N11 N 0.1039(7) 0.3007(5) 0.8601(6) 0.055(3) Uani 1 1 d . . .
N12 N 0.4280(8) 0.1064(8) 0.9260(5) 0.078(4) Uani 1 1 d . . .
N13 N 0.3875(9) 0.6394(6) 0.6324(6) 0.065(3) Uani 1 1 d . . .
N14 N 0.6317(11) 0.4817(10) 0.5979(9) 0.103(5) Uani 1 1 d . . .
N15 N 0.2699(9) 0.2519(5) 0.1710(6) 0.062(3) Uani 1 1 d . . .
N16 N 0.8985(8) 0.3793(5) 0.5361(6) 0.056(3) Uani 1 1 d . . .
O1 O 0.3581(10) 0.6907(10) 0.2605(8) 0.139(6) Uani 1 1 d . . .
O2 O 0.0460(6) 0.9014(5) 0.7845(4) 0.057(2) Uani 1 1 d . . .
O3 O 0.1867(19) 0.7353(12) 0.9798(12) 0.217(11) Uani 1 1 d . . .
O4 O 0.1222(7) 0.1864(5) 0.8263(5) 0.066(2) Uani 1 1 d . . .
O5 O 0.4118(6) 0.0886(5) 0.8090(4) 0.057(2) Uani 1 1 d . . .
O6 O 0.3991(9) 0.7260(5) 0.5571(5) 0.077(3) Uani 1 1 d . . .
O7 O 0.6612(15) 0.5909(17) 0.639(2) 0.34(3) Uani 1 1 d . . .
O8 O 0.3297(7) 0.2730(5) 0.0654(5) 0.069(3) Uani 1 1 d . . .
O9 O 0.8308(15) 0.3025(8) 0.6090(8) 0.151(7) Uani 1 1 d . . .
Pt1 Pt 0.62565(2) -0.06758(2) 0.533218(19) 0.03159(12) Uani 1 1 d . . .
Pt2 Pt 1.12998(2) -0.02938(2) 0.51401(2) 0.03835(13) Uani 1 1 d . . .
Sb1 Sb 0.23262(5) 0.99192(4) 0.12774(4) 0.0469(2) Uani 1 1 d . . .
Sb2 Sb 0.22306(7) 0.38940(5) 0.62609(6) 0.0698(3) Uani 1 1 d . . .
loop_
_atom_type_symbol
_atom_type_description
_atom_type_scat_dispersion_real
_atom_type_scat_dispersion_imag
_atom_type_scat_source
C C 0.0033 0.0016 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
H H 0.0000 0.0000 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
N N 0.0061 0.0033 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
Cl Cl 0.1484 0.1585 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
Pt Pt -1.7033 8.3905 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
F F 0.0171 0.0103 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
O O 0.0106 0.0060 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
Sb Sb -0.5866 1.5461 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
loop_
_geom_angle_atom_site_label_1
_geom_angle_atom_site_label_2
_geom_angle_atom_site_label_3
_geom_angle
_geom_angle_site_symmetry_1
_geom_angle_site_symmetry_3
_geom_angle_publ_flag
N1 C1 C2 121.1(9) . . ?
C3 C2 C1 120.3(10) . . ?
C2 C3 C4 119.0(10) . . ?
C5 C4 C3 119.1(9) . . ?
C4 C5 N1 122.2(9) . . ?
C4 C5 C6 124.6(9) . . ?
N1 C5 C6 113.1(8) . . ?
N2 C6 C13 121.5(9) . . ?
N2 C6 C5 114.0(8) . . ?
C13 C6 C5 124.5(9) . . ?
N3 C7 C8 121.1(11) . . ?
C9 C8 C7 120.7(11) . . ?
C8 C9 C10 119.0(11) . . ?
C9 C10 C11 119.3(11) . . ?
N3 C11 C10 120.3(9) . . ?
N3 C11 C12 114.8(9) . . ?
C10 C11 C12 124.8(9) . . ?
N2 C12 C15 119.5(9) . . ?
N2 C12 C11 112.4(8) . . ?
C15 C12 C11 128.0(9) . . ?
C6 C13 C14 116.1(9) . . ?
C15 C14 C13 120.7(9) . . ?
C15 C14 C16 121.2(9) . . ?
C13 C14 C16 118.1(9) . . ?
C14 C15 C12 118.9(9) . . ?
C17 C16 C21 119.0(8) . . ?
C17 C16 C14 120.1(8) . . ?
C21 C16 C14 120.9(8) . . ?
C18 C17 C16 120.1(8) . . ?
C19 C18 C17 120.3(9) . . ?
C19 C18 C25 119.7(9) . . ?
C17 C18 C25 120.0(8) . . ?
C20 C19 C18 118.9(9) . . ?
C20 C19 C22 122.8(9) . . ?
C18 C19 C22 118.2(9) . . ?
C19 C20 C21 122.4(9) . . ?
C20 C21 C16 119.2(9) . . ?
C23 C22 C19 111.9(10) . . ?
C22 C23 C24 111.9(9) . . ?
C26 C24 C25 118.2(9) . . ?
C26 C24 C23 123.4(9) . . ?
C25 C24 C23 118.4(9) . . ?
N4 C25 C24 122.5(9) . . ?
N4 C25 C18 118.6(8) . . ?
C24 C25 C18 118.9(8) . . ?
C24 C26 C27 120.3(9) . . ?
C24 C26 C52 118.9(9) . . ?
C27 C26 C52 120.7(9) . . ?
C28 C27 C26 116.8(9) . . ?
C28 C27 C29 120.2(9) . . ?
C26 C27 C29 122.9(9) . . ?
N4 C28 C27 123.6(9) . . ?
N4 C28 C32 117.7(8) . . ?
C27 C28 C32 118.6(9) . . ?
C27 C29 C30 111.7(9) . . ?
C31 C30 C29 110.2(9) . . ?
C32 C31 C33 118.9(10) . . ?
C32 C31 C30 120.5(9) . . ?
C33 C31 C30 120.5(9) . . ?
C36 C32 C31 120.7(9) . . ?
C36 C32 C28 120.2(9) . . ?
C31 C32 C28 119.1(9) . . ?
C34 C33 C31 120.7(10) . . ?
C33 C34 C35 121.0(10) . . ?
C34 C35 C36 117.7(9) . . ?
C34 C35 C37 122.3(9) . . ?
C36 C35 C37 120.0(9) . . ?
C32 C36 C35 121.0(9) . . ?
C38 C37 C39 120.8(9) . . ?
C38 C37 C35 119.0(9) . . ?
C39 C37 C35 120.2(9) . . ?
C37 C38 C40 116.9(10) . . ?
C46 C39 C37 120.9(9) . . ?
N6 C40 C38 120.7(9) . . ?
N6 C40 C41 111.5(9) . . ?
C38 C40 C41 127.8(10) . . ?
N7 C41 C42 122.8(10) . . ?
N7 C41 C40 114.7(10) . . ?
C42 C41 C40 122.5(11) . . ?
C41 C42 C43 116.8(12) . . ?
C44 C43 C42 119.5(12) . . ?
C43 C44 C45 120.4(11) . . ?
N7 C45 C44 122.5(12) . . ?
N6 C46 C39 116.3(10) . . ?
N6 C46 C47 114.3(9) . . ?
C39 C46 C47 129.3(9) . . ?
C48 C47 N5 121.2(10) . . ?
C48 C47 C46 124.3(10) . . ?
N5 C47 C46 114.4(9) . . ?
C47 C48 C49 119.5(10) . . ?
C50 C49 C48 119.1(11) . . ?
C49 C50 C51 119.0(11) . . ?
N5 C51 C50 122.9(10) . . ?
C57 C52 C53 121.0(9) . . ?
C57 C52 C26 120.1(10) . . ?
C53 C52 C26 118.6(9) . . ?
C52 C53 C54 120.6(10) . . ?
C55 C54 C53 117.1(10) . . ?
C55 C54 C58 121.0(9) . . ?
C53 C54 C58 121.9(10) . . ?
C56 C55 C54 122.8(10) . . ?
C55 C56 C57 118.3(10) . . ?
C55 C56 C62 119.9(10) . . ?
C57 C56 C62 121.6(10) . . ?
C52 C57 C56 120.1(10) . . ?
C54 C58 C61 108.7(10) . . ?
C54 C58 C60 108.7(9) . . ?
C61 C58 C60 110.2(11) . . ?
C54 C58 C59 112.6(9) . . ?
C61 C58 C59 109.2(10) . . ?
C60 C58 C59 107.5(11) . . ?
C65 C62 C63 109.6(15) . . ?
C65 C62 C56 113.6(11) . . ?
C63 C62 C56 110.3(11) . . ?
C65 C62 C64 111.2(18) . . ?
C63 C62 C64 103.5(14) . . ?
C56 C62 C64 108.2(11) . . ?
O1 C66 N8 124(2) . . ?
O2 C69 N9 125.3(10) . . ?
N10 C72 O3 127(3) . . ?
O4 C75 N11 132.0(17) . . ?
O5 C78 N12 128.5(14) . . ?
N13 C81 O6 128.0(18) . . ?
N14 C84 O7 105(3) . . ?
O8 C87 N15 127.5(14) . . ?
O9 C90 N16 124(2) . . ?
C1 N1 C5 118.1(9) . . ?
C1 N1 Pt1 128.4(7) . . ?
C5 N1 Pt1 113.4(6) . . ?
C12 N2 C6 123.1(8) . . ?
C12 N2 Pt1 119.0(7) . . ?
C6 N2 Pt1 117.8(6) . . ?
C7 N3 C11 119.6(9) . . ?
C7 N3 Pt1 127.3(7) . . ?
C11 N3 Pt1 113.1(7) . . ?
C25 N4 C28 118.6(8) . . ?
C51 N5 C47 118.3(9) . . ?
C51 N5 Pt2 128.8(7) . . ?
C47 N5 Pt2 112.9(7) . . ?
C40 N6 C46 124.2(9) . . ?
C40 N6 Pt2 119.3(7) . . ?
C46 N6 Pt2 116.3(7) . . ?
C41 N7 C45 118.0(10) . . ?
C41 N7 Pt2 113.9(7) . . ?
C45 N7 Pt2 128.1(9) . . ?
C66 N8 C68 121(2) . . ?
C66 N8 C67 122(2) . . ?
C68 N8 C67 117(2) . . ?
C69 N9 C71 121.6(9) . . ?
C69 N9 C70 121.2(10) . . ?
C71 N9 C70 117.1(10) . . ?
C72 N10 C74 121(2) . . ?
C72 N10 C73 120.8(19) . . ?
C74 N10 C73 118.0(18) . . ?
C75 N11 C77 128.8(16) . . ?
C75 N11 C76 118.6(15) . . ?
C77 N11 C76 112.5(15) . . ?
C78 N12 C80 121.2(12) . . ?
C78 N12 C79 122.8(15) . . ?
C80 N12 C79 116.0(14) . . ?
C81 N13 C83 117.3(17) . . ?
C81 N13 C82 125.0(15) . . ?
C83 N13 C82 117.5(16) . . ?
C86 N14 C84 121(3) . . ?
C86 N14 C85 117(3) . . ?
C84 N14 C85 122(3) . . ?
C87 N15 C89 120.3(13) . . ?
C87 N15 C88 122.4(13) . . ?
C89 N15 C88 117.2(13) . . ?
C90 N16 C92 120.3(16) . . ?
C90 N16 C91 123.2(15) . . ?
C92 N16 C91 116.5(12) . . ?
N2 Pt1 N3 80.7(4) . . ?
N2 Pt1 N1 81.6(4) . . ?
N3 Pt1 N1 162.3(3) . . ?
N2 Pt1 Cl1 179.3(2) . . ?
N3 Pt1 Cl1 99.0(3) . . ?
N1 Pt1 Cl1 98.7(3) . . ?
N6 Pt2 N7 80.6(4) . . ?
N6 Pt2 N5 81.9(4) . . ?
N7 Pt2 N5 162.4(3) . . ?
N6 Pt2 Cl2 178.7(2) . . ?
N7 Pt2 Cl2 99.6(3) . . ?
N5 Pt2 Cl2 98.0(3) . . ?
F3 Sb1 F4 91.6(7) . . ?
F3 Sb1 F2 88.8(6) . . ?
F4 Sb1 F2 90.1(5) . . ?
F3 Sb1 F1 91.8(7) . . ?
F4 Sb1 F1 176.5(6) . . ?
F2 Sb1 F1 90.4(5) . . ?
F3 Sb1 F5 93.7(7) . . ?
F4 Sb1 F5 90.5(5) . . ?
F2 Sb1 F5 177.4(5) . . ?
F1 Sb1 F5 88.9(4) . . ?
F3 Sb1 F6 179.5(5) . . ?
F4 Sb1 F6 88.2(6) . . ?
F2 Sb1 F6 90.7(5) . . ?
F1 Sb1 F6 88.4(5) . . ?
F5 Sb1 F6 86.7(6) . . ?
F10 Sb2 F11 85.1(7) . . ?
F10 Sb2 F9 96.1(6) . . ?
F11 Sb2 F9 178.1(5) . . ?
F10 Sb2 F12 92.4(5) . . ?
F11 Sb2 F12 90.2(5) . . ?
F9 Sb2 F12 91.2(5) . . ?
F10 Sb2 F8 85.1(5) . . ?
F11 Sb2 F8 89.6(5) . . ?
F9 Sb2 F8 89.0(4) . . ?
F12 Sb2 F8 177.5(5) . . ?
F10 Sb2 F7 173.2(7) . . ?
F11 Sb2 F7 89.9(5) . . ?
F9 Sb2 F7 88.8(5) . . ?
F12 Sb2 F7 92.3(6) . . ?
F8 Sb2 F7 90.2(6) . . ?
loop_
_geom_bond_atom_site_label_1
_geom_bond_atom_site_label_2
_geom_bond_distance
_geom_bond_site_symmetry_2
_geom_bond_publ_flag
C1 N1 1.341(13) . ?
C1 C2 1.385(16) . ?
C2 C3 1.355(15) . ?
C3 C4 1.396(14) . ?
C4 C5 1.343(14) . ?
C5 N1 1.382(12) . ?
C5 C6 1.499(14) . ?
C6 N2 1.341(13) . ?
C6 C13 1.383(13) . ?
C7 N3 1.338(13) . ?
C7 C8 1.373(17) . ?
C8 C9 1.367(18) . ?
C9 C10 1.380(16) . ?
C10 C11 1.394(15) . ?
C11 N3 1.371(13) . ?
C11 C12 1.481(14) . ?
C12 N2 1.338(12) . ?
C12 C15 1.394(13) . ?
C13 C14 1.443(14) . ?
C14 C15 1.383(14) . ?
C14 C16 1.474(13) . ?
C16 C17 1.401(13) . ?
C16 C21 1.400(13) . ?
C17 C18 1.389(13) . ?
C18 C19 1.389(13) . ?
C18 C25 1.478(13) . ?
C19 C20 1.367(14) . ?
C19 C22 1.508(14) . ?
C20 C21 1.377(14) . ?
C22 C23 1.479(17) . ?
C23 C24 1.508(14) . ?
C24 C26 1.385(14) . ?
C24 C25 1.409(13) . ?
C25 N4 1.339(12) . ?
C26 C27 1.408(14) . ?
C26 C52 1.520(13) . ?
C27 C28 1.401(14) . ?
C27 C29 1.482(14) . ?
C28 N4 1.346(13) . ?
C28 C32 1.495(13) . ?
C29 C30 1.526(16) . ?
C30 C31 1.515(15) . ?
C31 C32 1.377(14) . ?
C31 C33 1.417(15) . ?
C32 C36 1.374(14) . ?
C33 C34 1.363(16) . ?
C34 C35 1.401(15) . ?
C35 C36 1.417(13) . ?
C35 C37 1.466(14) . ?
C37 C38 1.388(14) . ?
C37 C39 1.400(15) . ?
C38 C40 1.418(15) . ?
C39 C46 1.398(15) . ?
C40 N6 1.331(14) . ?
C40 C41 1.489(14) . ?
C41 N7 1.351(15) . ?
C41 C42 1.398(16) . ?
C42 C43 1.442(15) . ?
C43 C44 1.336(18) . ?
C44 C45 1.380(18) . ?
C45 N7 1.357(13) . ?
C46 N6 1.376(13) . ?
C46 C47 1.450(16) . ?
C47 C48 1.364(15) . ?
C47 N5 1.380(13) . ?
C48 C49 1.384(16) . ?
C49 C50 1.372(16) . ?
C50 C51 1.377(16) . ?
C51 N5 1.320(15) . ?
C52 C57 1.370(15) . ?
C52 C53 1.372(15) . ?
C53 C54 1.405(14) . ?
C54 C55 1.386(15) . ?
C54 C58 1.532(16) . ?
C55 C56 1.381(15) . ?
C56 C57 1.392(14) . ?
C56 C62 1.565(16) . ?
C58 C61 1.533(16) . ?
C58 C60 1.536(18) . ?
C58 C59 1.537(16) . ?
C62 C65 1.41(2) . ?
C62 C63 1.508(18) . ?
C62 C64 1.57(2) . ?
C66 O1 1.21(2) . ?
C66 N8 1.34(3) . ?
C67 N8 1.46(2) . ?
C68 N8 1.44(3) . ?
C69 O2 1.222(13) . ?
C69 N9 1.331(14) . ?
C70 N9 1.465(15) . ?
C71 N9 1.448(14) . ?
C72 N10 1.26(3) . ?
C72 O3 1.29(3) . ?
C73 N10 1.44(2) . ?
C74 N10 1.42(2) . ?
C75 O4 1.215(17) . ?
C75 N11 1.255(18) . ?
C76 N11 1.48(2) . ?
C77 N11 1.405(19) . ?
C78 O5 1.176(15) . ?
C78 N12 1.329(16) . ?
C79 N12 1.44(2) . ?
C80 N12 1.43(2) . ?
C81 N13 1.215(18) . ?
C81 O6 1.244(17) . ?
C82 N13 1.467(19) . ?
C83 N13 1.45(2) . ?
C84 N14 1.38(3) . ?
C84 O7 1.40(3) . ?
C85 N14 1.38(3) . ?
C86 N14 1.38(3) . ?
C87 O8 1.199(15) . ?
C87 N15 1.334(16) . ?
C88 N15 1.46(2) . ?
C89 N15 1.457(19) . ?
C90 O9 1.28(2) . ?
C90 N16 1.30(2) . ?
C91 N16 1.447(18) . ?
C92 N16 1.425(19) . ?
Cl1 Pt1 2.294(5) . ?
Cl2 Pt2 2.297(6) . ?
F1 Sb1 1.852(9) . ?
F2 Sb1 1.850(9) . ?
F3 Sb1 1.801(10) . ?
F4 Sb1 1.828(9) . ?
F5 Sb1 1.857(9) . ?
F6 Sb1 1.872(10) . ?
F7 Sb2 1.881(12) . ?
F8 Sb2 1.871(10) . ?
F9 Sb2 1.862(9) . ?
F10 Sb2 1.702(14) . ?
F11 Sb2 1.855(9) . ?
F12 Sb2 1.869(10) . ?
N1 Pt1 2.028(9) . ?
N2 Pt1 1.933(8) . ?
N3 Pt1 2.028(9) . ?
N5 Pt2 2.023(10) . ?
N6 Pt2 1.926(10) . ?
N7 Pt2 2.004(10) . ?
loop_
_geom_torsion_atom_site_label_1
_geom_torsion_atom_site_label_2
_geom_torsion_atom_site_label_3
_geom_torsion_atom_site_label_4
_geom_torsion
_geom_torsion_site_symmetry_1
_geom_torsion_site_symmetry_2
_geom_torsion_site_symmetry_3
_geom_torsion_site_symmetry_4
_geom_torsion_publ_flag
N1 C1 C2 C3 -1.4(14) . . . . ?
C1 C2 C3 C4 0.3(14) . . . . ?
C2 C3 C4 C5 0.1(14) . . . . ?
C3 C4 C5 N1 0.6(13) . . . . ?
C3 C4 C5 C6 179.7(8) . . . . ?
C4 C5 C6 N2 -178.8(8) . . . . ?
N1 C5 C6 N2 0.4(11) . . . . ?
C4 C5 C6 C13 2.0(14) . . . . ?
N1 C5 C6 C13 -178.8(8) . . . . ?
N3 C7 C8 C9 -0.4(16) . . . . ?
C7 C8 C9 C10 -0.1(17) . . . . ?
C8 C9 C10 C11 -0.5(15) . . . . ?
C9 C10 C11 N3 1.4(14) . . . . ?
C9 C10 C11 C12 179.3(9) . . . . ?
N3 C11 C12 N2 -0.9(11) . . . . ?
C10 C11 C12 N2 -178.9(8) . . . . ?
N3 C11 C12 C15 177.1(8) . . . . ?
C10 C11 C12 C15 -0.9(15) . . . . ?
N2 C6 C13 C14 -1.7(13) . . . . ?
C5 C6 C13 C14 177.4(8) . . . . ?
C6 C13 C14 C15 3.0(12) . . . . ?
C6 C13 C14 C16 -176.2(8) . . . . ?
C13 C14 C15 C12 -2.6(13) . . . . ?
C16 C14 C15 C12 176.6(8) . . . . ?
N2 C12 C15 C14 0.8(13) . . . . ?
C11 C12 C15 C14 -177.1(8) . . . . ?
C15 C14 C16 C17 -139.8(9) . . . . ?
C13 C14 C16 C17 39.4(12) . . . . ?
C15 C14 C16 C21 39.7(13) . . . . ?
C13 C14 C16 C21 -141.1(9) . . . . ?
C21 C16 C17 C18 -0.1(14) . . . . ?
C14 C16 C17 C18 179.4(9) . . . . ?
C16 C17 C18 C19 0.8(15) . . . . ?
C16 C17 C18 C25 -178.6(9) . . . . ?
C17 C18 C19 C20 -0.4(16) . . . . ?
C25 C18 C19 C20 179.0(10) . . . . ?
C17 C18 C19 C22 -178.8(10) . . . . ?
C25 C18 C19 C22 0.6(15) . . . . ?
C18 C19 C20 C21 -0.8(17) . . . . ?
C22 C19 C20 C21 177.6(11) . . . . ?
C19 C20 C21 C16 1.6(16) . . . . ?
C17 C16 C21 C20 -1.1(15) . . . . ?
C14 C16 C21 C20 179.4(9) . . . . ?
C20 C19 C22 C23 144.9(11) . . . . ?
C18 C19 C22 C23 -36.7(15) . . . . ?
C19 C22 C23 C24 51.8(14) . . . . ?
C22 C23 C24 C26 144.6(11) . . . . ?
C22 C23 C24 C25 -33.5(15) . . . . ?
C26 C24 C25 N4 0.7(16) . . . . ?
C23 C24 C25 N4 178.8(10) . . . . ?
C26 C24 C25 C18 179.4(10) . . . . ?
C23 C24 C25 C18 -2.5(15) . . . . ?
C19 C18 C25 N4 -161.4(10) . . . . ?
C17 C18 C25 N4 18.0(14) . . . . ?
C19 C18 C25 C24 19.9(15) . . . . ?
C17 C18 C25 C24 -160.7(10) . . . . ?
C25 C24 C26 C27 -0.9(16) . . . . ?
C23 C24 C26 C27 -179.0(11) . . . . ?
C25 C24 C26 C52 -178.1(10) . . . . ?
C23 C24 C26 C52 3.8(17) . . . . ?
C24 C26 C27 C28 1.0(16) . . . . ?
C52 C26 C27 C28 178.2(10) . . . . ?
C24 C26 C27 C29 177.5(11) . . . . ?
C52 C26 C27 C29 -5.4(17) . . . . ?
C26 C27 C28 N4 -0.9(16) . . . . ?
C29 C27 C28 N4 -177.5(10) . . . . ?
C26 C27 C28 C32 178.7(9) . . . . ?
C29 C27 C28 C32 2.2(15) . . . . ?
C28 C27 C29 C30 -35.6(15) . . . . ?
C26 C27 C29 C30 148.0(11) . . . . ?
C27 C29 C30 C31 50.0(13) . . . . ?
C29 C30 C31 C32 -35.2(15) . . . . ?
C29 C30 C31 C33 148.1(11) . . . . ?
C33 C31 C32 C36 1.2(16) . . . . ?
C30 C31 C32 C36 -175.6(10) . . . . ?
C33 C31 C32 C28 179.2(10) . . . . ?
C30 C31 C32 C28 2.4(15) . . . . ?
N4 C28 C32 C36 13.5(14) . . . . ?
C27 C28 C32 C36 -166.2(10) . . . . ?
N4 C28 C32 C31 -164.5(10) . . . . ?
C27 C28 C32 C31 15.8(15) . . . . ?
C32 C31 C33 C34 -2.5(17) . . . . ?
C30 C31 C33 C34 174.3(11) . . . . ?
C31 C33 C34 C35 2.0(18) . . . . ?
C33 C34 C35 C36 -0.3(16) . . . . ?
C33 C34 C35 C37 -178.7(10) . . . . ?
C31 C32 C36 C35 0.5(15) . . . . ?
C28 C32 C36 C35 -177.4(9) . . . . ?
C34 C35 C36 C32 -1.0(15) . . . . ?
C37 C35 C36 C32 177.4(9) . . . . ?
C34 C35 C37 C38 42.1(14) . . . . ?
C36 C35 C37 C38 -136.4(10) . . . . ?
C34 C35 C37 C39 -139.7(10) . . . . ?
C36 C35 C37 C39 41.9(13) . . . . ?
C39 C37 C38 C40 -3.5(13) . . . . ?
C35 C37 C38 C40 174.8(8) . . . . ?
C38 C37 C39 C46 3.8(13) . . . . ?
C35 C37 C39 C46 -174.4(8) . . . . ?
C37 C38 C40 N6 2.3(13) . . . . ?
C37 C38 C40 C41 -177.7(9) . . . . ?
N6 C40 C41 N7 -3.8(11) . . . . ?
C38 C40 C41 N7 176.2(9) . . . . ?
N6 C40 C41 C42 175.9(8) . . . . ?
C38 C40 C41 C42 -4.2(15) . . . . ?
N7 C41 C42 C43 -0.6(14) . . . . ?
C40 C41 C42 C43 179.8(8) . . . . ?
C41 C42 C43 C44 -1.2(14) . . . . ?
C42 C43 C44 C45 1.6(15) . . . . ?
C43 C44 C45 N7 -0.1(16) . . . . ?
C37 C39 C46 N6 -2.7(13) . . . . ?
C37 C39 C46 C47 178.7(9) . . . . ?
N6 C46 C47 C48 -178.2(8) . . . . ?
C39 C46 C47 C48 0.3(16) . . . . ?
N6 C46 C47 N5 3.6(11) . . . . ?
C39 C46 C47 N5 -177.8(9) . . . . ?
N5 C47 C48 C49 -0.3(14) . . . . ?
C46 C47 C48 C49 -178.3(9) . . . . ?
C47 C48 C49 C50 -0.1(15) . . . . ?
C48 C49 C50 C51 -0.5(15) . . . . ?
C49 C50 C51 N5 1.7(16) . . . . ?
C24 C26 C52 C57 -100.8(12) . . . . ?
C27 C26 C52 C57 82.0(14) . . . . ?
C24 C26 C52 C53 73.2(14) . . . . ?
C27 C26 C52 C53 -104.0(12) . . . . ?
C57 C52 C53 C54 -0.9(16) . . . . ?
C26 C52 C53 C54 -174.8(9) . . . . ?
C52 C53 C54 C55 0.1(15) . . . . ?
C52 C53 C54 C58 178.5(10) . . . . ?
C53 C54 C55 C56 -0.6(16) . . . . ?
C58 C54 C55 C56 -179.1(10) . . . . ?
C54 C55 C56 C57 1.9(16) . . . . ?
C54 C55 C56 C62 176.9(10) . . . . ?
C53 C52 C57 C56 2.2(16) . . . . ?
C26 C52 C57 C56 176.0(9) . . . . ?
C55 C56 C57 C52 -2.6(16) . . . . ?
C62 C56 C57 C52 -177.5(10) . . . . ?
C55 C54 C58 C61 50.2(14) . . . . ?
C53 C54 C58 C61 -128.1(11) . . . . ?
C55 C54 C58 C60 -69.7(13) . . . . ?
C53 C54 C58 C60 111.9(12) . . . . ?
C55 C54 C58 C59 171.3(10) . . . . ?
C53 C54 C58 C59 -7.0(15) . . . . ?
C55 C56 C62 C65 176.9(18) . . . . ?
C57 C56 C62 C65 -8(2) . . . . ?
C55 C56 C62 C63 53.4(15) . . . . ?
C57 C56 C62 C63 -131.8(12) . . . . ?
C55 C56 C62 C64 -59.1(17) . . . . ?
C57 C56 C62 C64 115.7(15) . . . . ?
C2 C1 N1 C5 2.0(13) . . . . ?
C2 C1 N1 Pt1 179.6(7) . . . . ?
C4 C5 N1 C1 -1.6(12) . . . . ?
C6 C5 N1 C1 179.2(8) . . . . ?
C4 C5 N1 Pt1 -179.6(7) . . . . ?
C6 C5 N1 Pt1 1.2(9) . . . . ?
C15 C12 N2 C6 0.5(13) . . . . ?
C11 C12 N2 C6 178.7(8) . . . . ?
C15 C12 N2 Pt1 -176.7(6) . . . . ?
C11 C12 N2 Pt1 1.5(10) . . . . ?
C13 C6 N2 C12 0.0(13) . . . . ?
C5 C6 N2 C12 -179.2(7) . . . . ?
C13 C6 N2 Pt1 177.3(7) . . . . ?
C5 C6 N2 Pt1 -2.0(10) . . . . ?
C8 C7 N3 C11 1.3(14) . . . . ?
C8 C7 N3 Pt1 -178.6(8) . . . . ?
C10 C11 N3 C7 -1.8(13) . . . . ?
C12 C11 N3 C7 -179.9(8) . . . . ?
C10 C11 N3 Pt1 178.1(7) . . . . ?
C12 C11 N3 Pt1 0.0(9) . . . . ?
C24 C25 N4 C28 -0.6(15) . . . . ?
C18 C25 N4 C28 -179.3(9) . . . . ?
C27 C28 N4 C25 0.7(15) . . . . ?
C32 C28 N4 C25 -179.0(9) . . . . ?
C50 C51 N5 C47 -2.1(14) . . . . ?
C50 C51 N5 Pt2 178.9(7) . . . . ?
C48 C47 N5 C51 1.4(13) . . . . ?
C46 C47 N5 C51 179.6(8) . . . . ?
C48 C47 N5 Pt2 -179.4(7) . . . . ?
C46 C47 N5 Pt2 -1.2(10) . . . . ?
C38 C40 N6 C46 -1.4(13) . . . . ?
C41 C40 N6 C46 178.6(8) . . . . ?
C38 C40 N6 Pt2 -176.5(7) . . . . ?
C41 C40 N6 Pt2 3.5(10) . . . . ?
C39 C46 N6 C40 1.6(13) . . . . ?
C47 C46 N6 C40 -179.7(8) . . . . ?
C39 C46 N6 Pt2 176.8(6) . . . . ?
C47 C46 N6 Pt2 -4.4(10) . . . . ?
C42 C41 N7 C45 2.0(14) . . . . ?
C40 C41 N7 C45 -178.4(8) . . . . ?
C42 C41 N7 Pt2 -177.2(7) . . . . ?
C40 C41 N7 Pt2 2.4(10) . . . . ?
C44 C45 N7 C41 -1.6(14) . . . . ?
C44 C45 N7 Pt2 177.4(7) . . . . ?
O1 C66 N8 C68 3(3) . . . . ?
O1 C66 N8 C67 -174.9(19) . . . . ?
O2 C69 N9 C71 1.3(17) . . . . ?
O2 C69 N9 C70 -179.1(11) . . . . ?
O3 C72 N10 C74 174(3) . . . . ?
O3 C72 N10 C73 -10(5) . . . . ?
O4 C75 N11 C77 176.7(16) . . . . ?
O4 C75 N11 C76 1(3) . . . . ?
O5 C78 N12 C80 -3(3) . . . . ?
O5 C78 N12 C79 178(2) . . . . ?
O6 C81 N13 C83 -1(2) . . . . ?
O6 C81 N13 C82 174.9(14) . . . . ?
O7 C84 N14 C86 -2(3) . . . . ?
O7 C84 N14 C85 179(2) . . . . ?
O8 C87 N15 C89 -3(2) . . . . ?
O8 C87 N15 C88 179.5(14) . . . . ?
O9 C90 N16 C92 169(2) . . . . ?
O9 C90 N16 C91 -8(3) . . . . ?
C12 N2 Pt1 N3 -1.2(6) . . . . ?
C6 N2 Pt1 N3 -178.6(7) . . . . ?
C12 N2 Pt1 N1 179.4(7) . . . . ?
C6 N2 Pt1 N1 2.1(6) . . . . ?
C7 N3 Pt1 N2 -179.5(8) . . . . ?
C11 N3 Pt1 N2 0.6(6) . . . . ?
C7 N3 Pt1 N1 -177.5(8) . . . . ?
C11 N3 Pt1 N1 2.7(13) . . . . ?
C7 N3 Pt1 Cl1 1.2(8) . . . . ?
C11 N3 Pt1 Cl1 -178.7(6) . . . . ?
C1 N1 Pt1 N2 -179.5(8) . . . . ?
C5 N1 Pt1 N2 -1.7(6) . . . . ?
C1 N1 Pt1 N3 178.5(8) . . . . ?
C5 N1 Pt1 N3 -3.8(13) . . . . ?
C1 N1 Pt1 Cl1 -0.2(8) . . . . ?
C5 N1 Pt1 Cl1 177.6(5) . . . . ?
C40 N6 Pt2 N7 -1.8(7) . . . . ?
C46 N6 Pt2 N7 -177.3(7) . . . . ?
C40 N6 Pt2 N5 178.4(7) . . . . ?
C46 N6 Pt2 N5 3.0(6) . . . . ?
C41 N7 Pt2 N6 -0.5(6) . . . . ?
C45 N7 Pt2 N6 -179.6(8) . . . . ?
C41 N7 Pt2 N5 0.2(14) . . . . ?
C45 N7 Pt2 N5 -178.9(9) . . . . ?
C41 N7 Pt2 Cl2 178.2(6) . . . . ?
C45 N7 Pt2 Cl2 -0.9(8) . . . . ?
C51 N5 Pt2 N6 178.2(9) . . . . ?
C47 N5 Pt2 N6 -0.9(6) . . . . ?
C51 N5 Pt2 N7 177.5(9) . . . . ?
C47 N5 Pt2 N7 -1.6(13) . . . . ?
C51 N5 Pt2 Cl2 -0.5(8) . . . . ?
C47 N5 Pt2 Cl2 -179.6(6) . . . . ?
