#------------------------------------------------------------------------------
#$Date: 2016-02-18 17:37:37 +0200 (Thu, 18 Feb 2016) $
#$Revision: 176729 $
#$URL: svn://www.crystallography.net/cod/cif/1/50/19/1501930.cif $
#------------------------------------------------------------------------------
#
# This file is available in the Crystallography Open Database (COD),
# http://www.crystallography.net/
#
# All data on this site have been placed in the public domain by the
# contributors.
#
data_1501930
loop_
_publ_author_name
'Mori, Fumiya'
'Fukawa, Naohiro'
'Noguchi, Keiichi'
'Tanaka, Ken'
_publ_section_title
;
 Asymmetric synthesis of axially chiral biaryl diphosphine ligands by
 rhodium-catalyzed enantioselective intramolecular double [2 + 2 + 2]
 cycloaddition.
;
_journal_issue                   3
_journal_name_full               'Organic letters'
_journal_page_first              362
_journal_page_last               365
_journal_paper_doi               10.1021/ol102927y
_journal_volume                  13
_journal_year                    2011
_chemical_absolute_configuration ad
_chemical_formula_moiety         'C44 H36 O4 P2'
_chemical_formula_sum            'C44 H36 O4 P2'
_chemical_formula_weight         690.67
_chemical_name_systematic
;
  (R)-5,5'-Bis(diphenylphosphanyl)-1,3,6,8,1',3',6',8'-octahydro-
  [4,4']bi[2,7-dioxaasindacenyl]
;
_space_group_IT_number           19
_symmetry_cell_setting           orthorhombic
_symmetry_Int_Tables_number      19
_symmetry_space_group_name_Hall  'P 2ac 2ab'
_symmetry_space_group_name_H-M   'P 21 21 21'
_atom_sites_solution_hydrogens   geom
_atom_sites_solution_primary     direct
_atom_sites_solution_secondary   difmap
_cell_angle_alpha                90.00
_cell_angle_beta                 90.00
_cell_angle_gamma                90.00
_cell_formula_units_Z            4
_cell_length_a                   8.98499(16)
_cell_length_b                   16.8485(3)
_cell_length_c                   23.4132(4)
_cell_measurement_reflns_used    63276
_cell_measurement_temperature    193(2)
_cell_measurement_theta_max      68.2
_cell_measurement_theta_min      3.2
_cell_volume                     3544.37(11)
_computing_cell_refinement       PROCESS-AUTO
_computing_data_collection       PROCESS-AUTO
_computing_data_reduction        CrystalStructure
_computing_publication_material  'SHELXL-97 (Sheldrick, 1997)'
_computing_structure_refinement  'SHELXL-97 (Sheldrick, 1997)'
_computing_structure_solution    SIR2004
_diffrn_ambient_temperature      193(2)
_diffrn_detector_area_resol_mean 10.00
_diffrn_measured_fraction_theta_full 0.993
_diffrn_measured_fraction_theta_max 0.993
_diffrn_measurement_device_type  'Rigaku RAXIS-RAPID'
_diffrn_measurement_method       ω
_diffrn_radiation_monochromator  graphite
_diffrn_radiation_source         'fine-focus sealed tube'
_diffrn_radiation_type           CuK\a
_diffrn_radiation_wavelength     1.54187
_diffrn_reflns_av_R_equivalents  0.0237
_diffrn_reflns_av_sigmaI/netI    0.0112
_diffrn_reflns_limit_h_max       10
_diffrn_reflns_limit_h_min       -10
_diffrn_reflns_limit_k_max       19
_diffrn_reflns_limit_k_min       -18
_diffrn_reflns_limit_l_max       28
_diffrn_reflns_limit_l_min       -28
_diffrn_reflns_number            66960
_diffrn_reflns_theta_full        68.23
_diffrn_reflns_theta_max         68.23
_diffrn_reflns_theta_min         3.23
_exptl_absorpt_coefficient_mu    1.464
_exptl_absorpt_correction_T_max  0.694
_exptl_absorpt_correction_T_min  0.365
_exptl_absorpt_correction_type   numerical
_exptl_absorpt_process_details
;
    Higashi, T. (1999). Program for Absorption Correction.
    Rigaku Corporation, Tokyo, Japan.
;
_exptl_crystal_colour            colorless
_exptl_crystal_density_diffrn    1.294
_exptl_crystal_density_method    'not measured'
_exptl_crystal_description       block
_exptl_crystal_F_000             1448
_exptl_crystal_size_max          0.50
_exptl_crystal_size_mid          0.40
_exptl_crystal_size_min          0.25
_refine_diff_density_max         0.242
_refine_diff_density_min         -0.336
_refine_diff_density_rms         0.070
_refine_ls_abs_structure_details
'Flack H D (1983), Acta Cryst. A39, 876-881.  2812 Friedel Pairs'
_refine_ls_abs_structure_Flack   0.014(12)
_refine_ls_extinction_method     none
_refine_ls_goodness_of_fit_ref   1.081
_refine_ls_hydrogen_treatment    constr
_refine_ls_matrix_type           full
_refine_ls_number_parameters     451
_refine_ls_number_reflns         6446
_refine_ls_number_restraints     0
_refine_ls_restrained_S_all      1.081
_refine_ls_R_factor_all          0.0322
_refine_ls_R_factor_gt           0.0319
_refine_ls_shift/su_max          0.000
_refine_ls_shift/su_mean         0.000
_refine_ls_structure_factor_coef Fsqd
_refine_ls_weighting_details
'calc w=1/[σ²(Fo²)+(0.0569P)²+0.4792P] where P=(Fo²+2Fc²)/3'
_refine_ls_weighting_scheme      calc
_refine_ls_wR_factor_gt          0.0822
_refine_ls_wR_factor_ref         0.0826
_reflns_number_gt                6352
_reflns_number_total             6446
_reflns_threshold_expression     >2sigma(I)
_cod_data_source_file            ol102927y_si_002.cif
_cod_data_source_block           I
_cod_original_cell_volume        3544.38(11)
_cod_database_code               1501930
loop_
_symmetry_equiv_pos_site_id
_symmetry_equiv_pos_as_xyz
1 +X,+Y,+Z
2 1/2+X,1/2-Y,-Z
3 -X,1/2+Y,1/2-Z
4 1/2-X,-Y,1/2+Z
loop_
_atom_site_label
_atom_site_type_symbol
_atom_site_fract_x
_atom_site_fract_y
_atom_site_fract_z
_atom_site_U_iso_or_equiv
_atom_site_adp_type
_atom_site_occupancy
_atom_site_symmetry_multiplicity
_atom_site_calc_flag
_atom_site_refinement_flags
P1 P 0.46255(4) 0.08931(2) 0.244772(15) 0.02942(10) Uani 1 1 d .
P2 P 0.46507(4) -0.03639(2) 0.108302(15) 0.02814(9) Uani 1 1 d .
O1 O 0.6345(2) -0.10186(12) 0.38573(6) 0.0813(6) Uani 1 1 d .
O2 O 0.92816(15) -0.17245(8) 0.16604(5) 0.0477(3) Uani 1 1 d .
O3 O 0.5459(2) 0.19717(11) -0.01112(8) 0.0874(6) Uani 1 1 d .
O4 O 0.98734(16) 0.20387(8) 0.17228(5) 0.0523(3) Uani 1 1 d .
C1 C 0.68799(15) -0.00330(9) 0.20079(6) 0.0257(3) Uani 1 1 d .
C2 C 0.59752(15) 0.00716(8) 0.24989(6) 0.0261(3) Uani 1 1 d .
C3 C 0.61730(16) -0.04535(9) 0.29538(6) 0.0296(3) Uani 1 1 d .
C4 C 0.5471(2) -0.04788(11) 0.35390(7) 0.0424(4) Uani 1 1 d .
H4A H 0.5484 0.0054 0.3718 0.051 Uiso 1 1 calc R
H4B H 0.4427 -0.0664 0.3515 0.051 Uiso 1 1 calc R
C5 C 0.7216(2) -0.15038(11) 0.34950(7) 0.0412(4) Uani 1 1 d .
H5A H 0.6780 -0.2041 0.3461 0.049 Uiso 1 1 calc R
H5B H 0.8247 -0.1551 0.3641 0.049 Uiso 1 1 calc R
C6 C 0.71898(16) -0.10803(9) 0.29279(6) 0.0291(3) Uani 1 1 d .
C7 C 0.79768(16) -0.12116(9) 0.24289(6) 0.0282(3) Uani 1 1 d .
C8 C 0.90649(19) -0.18491(10) 0.22580(7) 0.0366(4) Uani 1 1 d .
H8A H 1.0014 -0.1792 0.2469 0.044 Uiso 1 1 calc R
H8B H 0.8650 -0.2383 0.2332 0.044 Uiso 1 1 calc R
C9 C 0.88819(18) -0.09285(10) 0.15127(7) 0.0361(4) Uani 1 1 d .
H9A H 0.8379 -0.0911 0.1137 0.043 Uiso 1 1 calc R
H9B H 0.9771 -0.0582 0.1500 0.043 Uiso 1 1 calc R
C10 C 0.78370(16) -0.06746(9) 0.19829(6) 0.0277(3) Uani 1 1 d .
C11 C 0.68444(16) 0.05760(8) 0.15354(6) 0.0258(3) Uani 1 1 d .
C12 C 0.58337(16) 0.05239(8) 0.10745(6) 0.0278(3) Uani 1 1 d .
C13 C 0.58187(18) 0.11436(10) 0.06744(7) 0.0353(3) Uani 1 1 d .
C14 C 0.4915(2) 0.12618(13) 0.01366(8) 0.0540(5) Uani 1 1 d .
H14A H 0.5052 0.0809 -0.0128 0.065 Uiso 1 1 calc R
H14B H 0.3844 0.1312 0.0228 0.065 Uiso 1 1 calc R
C15 C 0.6491(3) 0.23631(14) 0.02466(10) 0.0660(6) Uani 1 1 d .
H15A H 0.6076 0.2871 0.0388 0.079 Uiso 1 1 calc R
H15B H 0.7429 0.2473 0.0039 0.079 Uiso 1 1 calc R
C16 C 0.6754(2) 0.17955(10) 0.07313(7) 0.0399(4) Uani 1 1 d .
C17 C 0.77586(18) 0.18330(9) 0.11704(7) 0.0344(3) Uani 1 1 d .
C18 C 0.8918(2) 0.24365(12) 0.13286(8) 0.0486(5) Uani 1 1 d .
H18A H 0.9481 0.2610 0.0987 0.058 Uiso 1 1 calc R
H18B H 0.8454 0.2907 0.1509 0.058 Uiso 1 1 calc R
C19 C 0.9105(2) 0.13683(12) 0.19649(7) 0.0411(4) Uani 1 1 d .
H19A H 0.8733 0.1494 0.2353 0.049 Uiso 1 1 calc R
H19B H 0.9771 0.0901 0.1988 0.049 Uiso 1 1 calc R
C20 C 0.78298(17) 0.12118(9) 0.15616(6) 0.0294(3) Uani 1 1 d .
C21 C 0.56694(17) 0.16995(9) 0.27827(6) 0.0307(3) Uani 1 1 d .
C22 C 0.6838(2) 0.16061(10) 0.31658(7) 0.0368(4) Uani 1 1 d .
H22 H 0.7092 0.1090 0.3296 0.044 Uiso 1 1 calc R
C23 C 0.76383(19) 0.22571(11) 0.33606(8) 0.0406(4) Uani 1 1 d .
H23 H 0.8453 0.2183 0.3614 0.049 Uiso 1 1 calc R
C24 C 0.7247(2) 0.30112(11) 0.31861(9) 0.0451(4) Uani 1 1 d .
H24 H 0.7788 0.3457 0.3322 0.054 Uiso 1 1 calc R
C25 C 0.6089(2) 0.31170(11) 0.28197(10) 0.0516(5) Uani 1 1 d .
H25 H 0.5812 0.3638 0.2707 0.062 Uiso 1 1 calc R
C26 C 0.5310(2) 0.24677(10) 0.26087(8) 0.0435(4) Uani 1 1 d .
H26 H 0.4524 0.2548 0.2343 0.052 Uiso 1 1 calc R
C27 C 0.31374(17) 0.06878(10) 0.29627(7) 0.0319(3) Uani 1 1 d .
C28 C 0.27190(19) 0.12278(11) 0.33829(7) 0.0393(4) Uani 1 1 d .
H28 H 0.3322 0.1680 0.3453 0.047 Uiso 1 1 calc R
C29 C 0.1426(2) 0.11139(13) 0.37024(8) 0.0516(5) Uani 1 1 d .
H29 H 0.1151 0.1491 0.3985 0.062 Uiso 1 1 calc R
C30 C 0.0551(2) 0.04589(14) 0.36094(9) 0.0545(5) Uani 1 1 d .
H30 H -0.0325 0.0380 0.3830 0.065 Uiso 1 1 calc R
C31 C 0.0948(2) -0.00867(14) 0.31932(10) 0.0563(5) Uani 1 1 d .
H31 H 0.0355 -0.0546 0.3133 0.068 Uiso 1 1 calc R
C32 C 0.2213(2) 0.00379(11) 0.28638(9) 0.0459(4) Uani 1 1 d .
H32 H 0.2451 -0.0325 0.2567 0.055 Uiso 1 1 calc R
C33 C 0.30259(17) -0.00730(10) 0.06597(7) 0.0324(3) Uani 1 1 d .
C34 C 0.21031(19) 0.05103(11) 0.08849(7) 0.0408(4) Uani 1 1 d .
H34 H 0.2342 0.0750 0.1241 0.049 Uiso 1 1 calc R
C35 C 0.0831(2) 0.07450(13) 0.05914(9) 0.0496(5) Uani 1 1 d .
H35 H 0.0214 0.1150 0.0745 0.060 Uiso 1 1 calc R
C36 C 0.0460(2) 0.03929(13) 0.00791(9) 0.0536(5) Uani 1 1 d .
H36 H -0.0405 0.0557 -0.0122 0.064 Uiso 1 1 calc R
C37 C 0.1348(3) -0.01959(14) -0.01373(10) 0.0612(6) Uani 1 1 d .
H37 H 0.1085 -0.0447 -0.0486 0.073 Uiso 1 1 calc R
C38 C 0.2633(2) -0.04286(12) 0.01492(8) 0.0486(5) Uani 1 1 d .
H38 H 0.3244 -0.0835 -0.0007 0.058 Uiso 1 1 calc R
C39 C 0.56655(17) -0.10286(9) 0.05959(6) 0.0327(3) Uani 1 1 d .
C40 C 0.6603(2) -0.07744(12) 0.01599(7) 0.0452(4) Uani 1 1 d .
H40 H 0.6741 -0.0223 0.0095 0.054 Uiso 1 1 calc R
C41 C 0.7337(3) -0.13218(15) -0.01808(9) 0.0598(5) Uani 1 1 d .
H41 H 0.7984 -0.1143 -0.0475 0.072 Uiso 1 1 calc R
C42 C 0.7132(3) -0.21241(14) -0.00950(10) 0.0618(6) Uani 1 1 d .
H42 H 0.7619 -0.2497 -0.0335 0.074 Uiso 1 1 calc R
C43 C 0.6222(3) -0.23834(13) 0.03384(10) 0.0606(6) Uani 1 1 d .
H43 H 0.6085 -0.2936 0.0399 0.073 Uiso 1 1 calc R
C44 C 0.5505(2) -0.18407(11) 0.06877(9) 0.0466(4) Uani 1 1 d .
H44 H 0.4898 -0.2024 0.0993 0.056 Uiso 1 1 calc R
loop_
_atom_type_symbol
_atom_type_description
_atom_type_scat_dispersion_real
_atom_type_scat_dispersion_imag
_atom_type_scat_source
C C 0.0181 0.0091 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
H H 0.0000 0.0000 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
O O 0.0492 0.0322 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
P P 0.2955 0.4335 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
loop_
_geom_angle_atom_site_label_1
_geom_angle_atom_site_label_2
_geom_angle_atom_site_label_3
_geom_angle
C21 P1 C27 103.43(7)
C21 P1 C2 101.11(7)
C27 P1 C2 107.17(7)
C33 P2 C12 103.75(7)
C33 P2 C39 102.85(7)
C12 P2 C39 101.67(7)
C4 O1 C5 111.29(13)
C8 O2 C9 109.90(12)
C15 O3 C14 112.19(15)
C18 O4 C19 109.55(13)
C10 C1 C2 119.19(13)
C10 C1 C11 120.91(12)
C2 C1 C11 119.83(12)
C3 C2 C1 117.81(13)
C3 C2 P1 127.51(11)
C1 C2 P1 114.66(10)
C2 C3 C6 121.93(13)
C2 C3 C4 131.11(14)
C6 C3 C4 106.94(13)
O1 C4 C3 105.34(14)
O1 C4 H4A 110.7
C3 C4 H4A 110.7
O1 C4 H4B 110.7
C3 C4 H4B 110.7
H4A C4 H4B 108.8
O1 C5 C6 104.23(13)
O1 C5 H5A 110.9
C6 C5 H5A 110.9
O1 C5 H5B 110.9
C6 C5 H5B 110.9
H5A C5 H5B 108.9
C7 C6 C3 119.45(13)
C7 C6 C5 131.30(14)
C3 C6 C5 109.25(13)
C6 C7 C10 119.01(13)
C6 C7 C8 132.07(14)
C10 C7 C8 108.90(13)
O2 C8 C7 104.12(12)
O2 C8 H8A 110.9
C7 C8 H8A 110.9
O2 C8 H8B 110.9
C7 C8 H8B 110.9
H8A C8 H8B 109.0
O2 C9 C10 104.21(12)
O2 C9 H9A 110.9
C10 C9 H9A 110.9
O2 C9 H9B 110.9
C10 C9 H9B 110.9
H9A C9 H9B 108.9
C1 C10 C7 122.31(13)
C1 C10 C9 129.76(13)
C7 C10 C9 107.94(13)
C20 C11 C12 119.38(13)
C20 C11 C1 118.53(12)
C12 C11 C1 122.09(12)
C13 C12 C11 118.03(13)
C13 C12 P2 127.48(11)
C11 C12 P2 114.49(10)
C16 C13 C12 121.23(14)
C16 C13 C14 107.50(15)
C12 C13 C14 131.27(15)
O3 C14 C13 105.51(16)
O3 C14 H14A 110.6
C13 C14 H14A 110.6
O3 C14 H14B 110.6
C13 C14 H14B 110.6
H14A C14 H14B 108.8
O3 C15 C16 104.71(16)
O3 C15 H15A 110.8
C16 C15 H15A 110.8
O3 C15 H15B 110.8
C16 C15 H15B 110.8
H15A C15 H15B 108.9
C17 C16 C13 120.48(15)
C17 C16 C15 129.88(17)
C13 C16 C15 109.60(16)
C16 C17 C20 119.30(14)
C16 C17 C18 132.33(15)
C20 C17 C18 108.35(15)
O4 C18 C17 104.98(14)
O4 C18 H18A 110.8
C17 C18 H18A 110.8
O4 C18 H18B 110.8
C17 C18 H18B 110.8
H18A C18 H18B 108.8
O4 C19 C20 104.77(14)
O4 C19 H19A 110.8
C20 C19 H19A 110.8
O4 C19 H19B 110.8
C20 C19 H19B 110.8
H19A C19 H19B 108.9
C11 C20 C17 121.37(14)
C11 C20 C19 130.23(14)
C17 C20 C19 108.39(14)
C22 C21 C26 117.95(15)
C22 C21 P1 125.47(12)
C26 C21 P1 116.46(12)
C23 C22 C21 120.92(16)
C23 C22 H22 119.5
C21 C22 H22 119.5
C24 C23 C22 119.87(17)
C24 C23 H23 120.1
C22 C23 H23 120.1
C25 C24 C23 120.13(17)
C25 C24 H24 119.9
C23 C24 H24 119.9
C24 C25 C26 120.45(17)
C24 C25 H25 119.8
C26 C25 H25 119.8
C25 C26 C21 120.64(17)
C25 C26 H26 119.7
C21 C26 H26 119.7
C28 C27 C32 118.03(15)
C28 C27 P1 122.59(13)
C32 C27 P1 118.27(13)
C27 C28 C29 120.94(17)
C27 C28 H28 119.5
C29 C28 H28 119.5
C30 C29 C28 120.19(18)
C30 C29 H29 119.9
C28 C29 H29 119.9
C29 C30 C31 119.82(18)
C29 C30 H30 120.1
C31 C30 H30 120.1
C30 C31 C32 120.02(19)
C30 C31 H31 120.0
C32 C31 H31 120.0
C31 C32 C27 120.94(18)
C31 C32 H32 119.5
C27 C32 H32 119.5
C38 C33 C34 118.81(16)
C38 C33 P2 123.75(13)
C34 C33 P2 117.35(12)
C33 C34 C35 120.25(17)
C33 C34 H34 119.9
C35 C34 H34 119.9
C36 C35 C34 120.39(18)
C36 C35 H35 119.8
C34 C35 H35 119.8
C37 C36 C35 119.49(17)
C37 C36 H36 120.3
C35 C36 H36 120.3
C36 C37 C38 120.6(2)
C36 C37 H37 119.7
C38 C37 H37 119.7
C33 C38 C37 120.44(19)
C33 C38 H38 119.8
C37 C38 H38 119.8
C40 C39 C44 118.58(16)
C40 C39 P2 124.58(13)
C44 C39 P2 116.81(13)
C41 C40 C39 120.36(19)
C41 C40 H40 119.8
C39 C40 H40 119.8
C42 C41 C40 120.3(2)
C42 C41 H41 119.8
C40 C41 H41 119.8
C43 C42 C41 119.9(2)
C43 C42 H42 120.0
C41 C42 H42 120.0
C42 C43 C44 120.2(2)
C42 C43 H43 119.9
C44 C43 H43 119.9
C43 C44 C39 120.61(18)
C43 C44 H44 119.7
C39 C44 H44 119.7
loop_
_geom_bond_atom_site_label_1
_geom_bond_atom_site_label_2
_geom_bond_distance
P1 C21 1.8278(16)
P1 C27 1.8334(16)
P1 C2 1.8441(14)
P2 C33 1.8314(16)
P2 C12 1.8351(14)
P2 C39 1.8401(16)
O1 C4 1.414(2)
O1 C5 1.415(2)
O2 C8 1.428(2)
O2 C9 1.431(2)
O3 C15 1.413(3)
O3 C14 1.416(2)
O4 C18 1.427(3)
O4 C19 1.440(2)
C1 C10 1.383(2)
C1 C2 1.419(2)
C1 C11 1.509(2)
C2 C3 1.396(2)
C3 C6 1.398(2)
C3 C4 1.509(2)
C4 H4A 0.9900
C4 H4B 0.9900
C5 C6 1.508(2)
C5 H5A 0.9900
C5 H5B 0.9900
C6 C7 1.383(2)
C7 C10 1.387(2)
C7 C8 1.506(2)
C8 H8A 0.9900
C8 H8B 0.9900
C9 C10 1.509(2)
C9 H9A 0.9900
C9 H9B 0.9900
C11 C20 1.391(2)
C11 C12 1.413(2)
C12 C13 1.403(2)
C13 C16 1.389(2)
C13 C14 1.511(2)
C14 H14A 0.9900
C14 H14B 0.9900
C15 C16 1.503(2)
C15 H15A 0.9900
C15 H15B 0.9900
C16 C17 1.370(2)
C17 C20 1.392(2)
C17 C18 1.502(2)
C18 H18A 0.9900
C18 H18B 0.9900
C19 C20 1.508(2)
C19 H19A 0.9900
C19 H19B 0.9900
C21 C22 1.390(2)
C21 C26 1.395(2)
C22 C23 1.389(2)
C22 H22 0.9500
C23 C24 1.380(3)
C23 H23 0.9500
C24 C25 1.360(3)
C24 H24 0.9500
C25 C26 1.390(3)
C25 H25 0.9500
C26 H26 0.9500
C27 C28 1.392(2)
C27 C32 1.394(2)
C28 C29 1.395(3)
C28 H28 0.9500
C29 C30 1.373(3)
C29 H29 0.9500
C30 C31 1.386(3)
C30 H30 0.9500
C31 C32 1.389(3)
C31 H31 0.9500
C32 H32 0.9500
C33 C38 1.383(2)
C33 C34 1.390(2)
C34 C35 1.391(3)
C34 H34 0.9500
C35 C36 1.379(3)
C35 H35 0.9500
C36 C37 1.371(3)
C36 H36 0.9500
C37 C38 1.391(3)
C37 H37 0.9500
C38 H38 0.9500
C39 C40 1.391(2)
C39 C44 1.392(2)
C40 C41 1.386(3)
C40 H40 0.9500
C41 C42 1.379(3)
C41 H41 0.9500
C42 C43 1.374(3)
C42 H42 0.9500
C43 C44 1.386(3)
C43 H43 0.9500
C44 H44 0.9500
loop_
_geom_torsion_atom_site_label_1
_geom_torsion_atom_site_label_2
_geom_torsion_atom_site_label_3
_geom_torsion_atom_site_label_4
_geom_torsion
C10 C1 C2 C3 4.4(2)
C11 C1 C2 C3 -172.52(13)
C10 C1 C2 P1 -174.42(11)
C11 C1 C2 P1 8.69(17)
C21 P1 C2 C3 87.13(14)
C27 P1 C2 C3 -20.83(15)
C21 P1 C2 C1 -94.21(11)
C27 P1 C2 C1 157.82(11)
C1 C2 C3 C6 -2.0(2)
P1 C2 C3 C6 176.64(11)
C1 C2 C3 C4 176.07(16)
P1 C2 C3 C4 -5.3(3)
C5 O1 C4 C3 -17.8(2)
C2 C3 C4 O1 -166.50(18)
C6 C3 C4 O1 11.8(2)
C4 O1 C5 C6 16.3(2)
C2 C3 C6 C7 -3.1(2)
C4 C3 C6 C7 178.40(15)
C2 C3 C6 C5 176.35(14)
C4 C3 C6 C5 -2.11(18)
O1 C5 C6 C7 171.14(18)
O1 C5 C6 C3 -8.3(2)
C3 C6 C7 C10 5.8(2)
C5 C6 C7 C10 -173.60(16)
C3 C6 C7 C8 -176.19(16)
C5 C6 C7 C8 4.4(3)
C9 O2 C8 C7 21.24(18)
C6 C7 C8 O2 170.53(16)
C10 C7 C8 O2 -11.27(18)
C8 O2 C9 C10 -22.59(18)
C2 C1 C10 C7 -1.8(2)
C11 C1 C10 C7 175.07(13)
C2 C1 C10 C9 178.67(15)
C11 C1 C10 C9 -4.5(2)
C6 C7 C10 C1 -3.4(2)
C8 C7 C10 C1 178.16(14)
C6 C7 C10 C9 176.27(14)
C8 C7 C10 C9 -2.21(17)
O2 C9 C10 C1 -165.58(15)
O2 C9 C10 C7 14.83(17)
C10 C1 C11 C20 -87.17(18)
C2 C1 C11 C20 89.67(16)
C10 C1 C11 C12 93.63(17)
C2 C1 C11 C12 -89.53(18)
C20 C11 C12 C13 -3.1(2)
C1 C11 C12 C13 176.05(14)
C20 C11 C12 P2 177.90(11)
C1 C11 C12 P2 -2.90(18)
C33 P2 C12 C13 -22.37(16)
C39 P2 C12 C13 84.15(15)
C33 P2 C12 C11 156.47(11)
C39 P2 C12 C11 -97.01(11)
C11 C12 C13 C16 -0.8(2)
P2 C12 C13 C16 178.00(13)
C11 C12 C13 C14 178.63(18)
P2 C12 C13 C14 -2.6(3)
C15 O3 C14 C13 -6.8(3)
C16 C13 C14 O3 3.5(2)
C12 C13 C14 O3 -176.00(19)
C14 O3 C15 C16 7.2(3)
C12 C13 C16 C17 2.5(3)
C14 C13 C16 C17 -177.01(17)
C12 C13 C16 C15 -179.64(18)
C14 C13 C16 C15 0.8(2)
O3 C15 C16 C17 172.8(2)
O3 C15 C16 C13 -4.8(3)
C13 C16 C17 C20 -0.3(3)
C15 C16 C17 C20 -177.6(2)
C13 C16 C17 C18 177.97(18)
C15 C16 C17 C18 0.7(3)
C19 O4 C18 C17 -20.45(19)
C16 C17 C18 O4 -163.81(18)
C20 C17 C18 O4 14.57(19)
C18 O4 C19 C20 18.36(19)
C12 C11 C20 C17 5.5(2)
C1 C11 C20 C17 -173.72(13)
C12 C11 C20 C19 -173.13(16)
C1 C11 C20 C19 7.6(2)
C16 C17 C20 C11 -3.8(2)
C18 C17 C20 C11 177.58(14)
C16 C17 C20 C19 175.11(15)
C18 C17 C20 C19 -3.51(18)
O4 C19 C20 C11 170.03(15)
O4 C19 C20 C17 -8.75(18)
C27 P1 C21 C22 87.85(15)
C2 P1 C21 C22 -23.02(15)
C27 P1 C21 C26 -96.24(14)
C2 P1 C21 C26 152.89(13)
C26 C21 C22 C23 -1.2(2)
P1 C21 C22 C23 174.70(13)
C21 C22 C23 C24 1.9(3)
C22 C23 C24 C25 -0.6(3)
C23 C24 C25 C26 -1.3(3)
C24 C25 C26 C21 2.1(3)
C22 C21 C26 C25 -0.8(3)
P1 C21 C26 C25 -177.03(16)
C21 P1 C27 C28 18.81(15)
C2 P1 C27 C28 125.14(13)
C21 P1 C27 C32 -173.48(13)
C2 P1 C27 C32 -67.16(14)
C32 C27 C28 C29 1.1(3)
P1 C27 C28 C29 168.86(14)
C27 C28 C29 C30 0.6(3)
C28 C29 C30 C31 -0.6(3)
C29 C30 C31 C32 -1.3(3)
C30 C31 C32 C27 3.1(3)
C28 C27 C32 C31 -3.0(3)
P1 C27 C32 C31 -171.23(16)
C12 P2 C33 C38 116.45(16)
C39 P2 C33 C38 10.82(17)
C12 P2 C33 C34 -67.09(14)
C39 P2 C33 C34 -172.72(13)
C38 C33 C34 C35 -1.8(3)
P2 C33 C34 C35 -178.46(14)
C33 C34 C35 C36 1.0(3)
C34 C35 C36 C37 0.5(3)
C35 C36 C37 C38 -1.3(3)
C34 C33 C38 C37 1.1(3)
P2 C33 C38 C37 177.47(16)
C36 C37 C38 C33 0.5(3)
C33 P2 C39 C40 81.17(15)
C12 P2 C39 C40 -26.05(15)
C33 P2 C39 C44 -100.84(14)
C12 P2 C39 C44 151.94(14)
C44 C39 C40 C41 1.2(3)
P2 C39 C40 C41 179.11(15)
C39 C40 C41 C42 0.7(3)
C40 C41 C42 C43 -1.5(4)
C41 C42 C43 C44 0.3(4)
C42 C43 C44 C39 1.6(3)
C40 C39 C44 C43 -2.3(3)
P2 C39 C44 C43 179.58(17)
