#------------------------------------------------------------------------------
#$Date: 2017-03-05 21:59:09 +0200 (Sun, 05 Mar 2017) $
#$Revision: 193981 $
#$URL: file:///home/coder/svn-repositories/cod/cif/1/50/60/1506039.cif $
#------------------------------------------------------------------------------
#
# This file is available in the Crystallography Open Database (COD),
# http://www.crystallography.net/
#
# All data on this site have been placed in the public domain by the
# contributors.
#
data_1506039
loop_
_publ_author_name
'Babu, Srinivasarao Arulananda'
'Yasuda, Makoto'
'Okabe, Yuji'
'Shibata, Ikuya'
'Baba, Akio'
_publ_section_title
;
 High chelation control of three contiguous stereogenic centers in the
 Reformatsky reactions of indium enolates with alpha-hydroxy ketones:
 unexpected stereochemistry of lactone formation.
;
_journal_issue                   14
_journal_name_full               'Organic letters'
_journal_page_first              3029
_journal_page_last               3032
_journal_paper_doi               10.1021/ol060943m
_journal_volume                  8
_journal_year                    2006
_chemical_formula_moiety         'C19 H20 O4 '
_chemical_formula_sum            'C19 H20 O4'
_chemical_formula_weight         312.36
_space_group_IT_number           14
_symmetry_cell_setting           monoclinic
_symmetry_Int_Tables_number      14
_symmetry_space_group_name_Hall  '-P 2yab'
_symmetry_space_group_name_H-M   'P 1 21/a 1'
_cell_angle_alpha                90
_cell_angle_beta                 93.79(1)
_cell_angle_gamma                90
_cell_formula_units_Z            4
_cell_length_a                   9.238(2)
_cell_length_b                   13.245(2)
_cell_length_c                   13.418(2)
_cell_measurement_reflns_used    25
_cell_measurement_temperature    296.2
_cell_measurement_theta_max      14.9
_cell_measurement_theta_min      13.8
_cell_volume                     1638.2(5)
_computing_cell_refinement       'MSC/AFC Diffractometer Control'
_computing_data_collection       'MSC/AFC Diffractometer Control'
_computing_data_reduction        'teXsan Ver. 1.11'
_computing_publication_material  'teXsan Ver. 1.11'
_computing_structure_refinement  'teXsan Ver. 1.10'
_computing_structure_solution    SIR92
_diffrn_measured_fraction_theta_full 0.9992
_diffrn_measured_fraction_theta_max 0.9992
_diffrn_measurement_device_type  'Rigaku AFC5R'
_diffrn_measurement_method       ω-2θ
_diffrn_radiation_type           'Mo K\a'
_diffrn_radiation_wavelength     0.7107
_diffrn_reflns_av_R_equivalents  0.018
_diffrn_reflns_limit_h_max       12
_diffrn_reflns_limit_h_min       0
_diffrn_reflns_limit_k_max       18
_diffrn_reflns_limit_k_min       0
_diffrn_reflns_limit_l_max       18
_diffrn_reflns_limit_l_min       -18
_diffrn_reflns_number            5241
_diffrn_reflns_theta_full        30.00
_diffrn_reflns_theta_max         30.00
_diffrn_standards_decay_%        0.70
_diffrn_standards_interval_count 150
_diffrn_standards_number         3
_exptl_absorpt_coefficient_mu    0.088
_exptl_absorpt_correction_T_max  1.000
_exptl_absorpt_correction_T_min  0.965
_exptl_absorpt_correction_type   psi-scan
_exptl_absorpt_process_details   '(North, Phillips & Mathews, 1968)'
_exptl_crystal_colour            colorless
_exptl_crystal_density_diffrn    1.266
_exptl_crystal_density_method    'not measured'
_exptl_crystal_description       prismatic
_exptl_crystal_size_max          0.500
_exptl_crystal_size_mid          0.400
_exptl_crystal_size_min          0.400
_refine_diff_density_max         0.22
_refine_diff_density_min         -0.32
_refine_ls_extinction_method     none
_refine_ls_goodness_of_fit_ref   1.198
_refine_ls_hydrogen_treatment    refall
_refine_ls_number_parameters     288
_refine_ls_number_reflns         2882
_refine_ls_R_factor_gt           0.0530
_refine_ls_shift/su_max          0.0034
_refine_ls_structure_factor_coef Fsqd
_refine_ls_weighting_details
'w = 1/[σ²(Fo²) + (0.06500(Max(Fo²,0) + 2Fc²)/3)²]'
_refine_ls_weighting_scheme      calc
_refine_ls_wR_factor_ref         0.1336
_reflns_number_gt                2068
_reflns_number_total             4771
_reflns_threshold_expression     F²>2.0σ(F²)
_cod_data_source_file            ol060943msi20060522_021902.cif
_cod_data_source_block           babu833B
_cod_depositor_comments
;
The following automatic conversions were performed:
data name '_geom_hbond_site_distance_dh' replaced with
'_geom_hbond_distance_DH' as specified in the replacement file
'/home/antanas/src/cod-tools/trunk/data/replacement-values/replacement_tags.lst'.

data
name '_geom_hbond_site_distance_ha' replaced with
'_geom_hbond_distance_HA' as specified in the replacement file
'/home/antanas/src/cod-tools/trunk/data/replacement-values/replacement_tags.lst'.

data
name '_geom_hbond_site_distance_da' replaced with
'_geom_hbond_distance_DA' as specified in the replacement file
'/home/antanas/src/cod-tools/trunk/data/replacement-values/replacement_tags.lst'.

Automatic conversion script
Id: cif_correct_tags 5005 2017-03-03 11:38:54Z antanas 
;
_cod_original_cell_volume        1638.3(4)
_cod_original_formula_sum        'C19 H20 O4 '
_cod_database_code               1506039
loop_
_symmetry_equiv_pos_as_xyz
x,y,z
1/2-x,1/2+y,-z
-x,-y,-z
1/2+x,1/2-y,z
loop_
_atom_site_label
_atom_site_type_symbol
_atom_site_fract_x
_atom_site_fract_y
_atom_site_fract_z
_atom_site_U_iso_or_equiv
_atom_site_adp_type
_atom_site_occupancy
_atom_site_calc_flag
O(1) O 0.4701(2) -0.0776(2) 0.1289(1) 0.0608(5) Uani 1.00 d
O(2) O 0.7361(2) -0.0665(2) -0.0160(1) 0.0869(7) Uani 1.00 d
O(3) O 0.6726(2) -0.2272(1) -0.0223(1) 0.0833(6) Uani 1.00 d
O(4) O 0.5648(2) 0.0927(1) 0.2251(1) 0.0587(5) Uani 1.00 d
C(1) C 0.6045(2) -0.0786(2) 0.1885(1) 0.0437(5) Uani 1.00 d
C(2) C 0.6966(2) -0.1589(2) 0.1391(2) 0.0476(6) Uani 1.00 d
C(3) C 0.7046(3) -0.1416(2) 0.0271(2) 0.0598(7) Uani 1.00 d
C(4) C 0.6460(5) -0.3101(3) 0.0456(2) 0.095(1) Uani 1.00 d
C(5) C 0.6358(4) -0.2657(2) 0.1454(2) 0.0695(9) Uani 1.00 d
C(6) C 0.5783(2) -0.1089(1) 0.2958(1) 0.0447(5) Uani 1.00 d
C(7) C 0.6860(3) -0.1539(2) 0.3587(2) 0.0550(6) Uani 1.00 d
C(8) C 0.6591(3) -0.1785(2) 0.4565(2) 0.0669(8) Uani 1.00 d
C(9) C 0.5271(4) -0.1569(2) 0.4931(2) 0.0759(9) Uani 1.00 d
C(10) C 0.4209(3) -0.1128(2) 0.4316(2) 0.0770(9) Uani 1.00 d
C(11) C 0.4452(3) -0.0891(2) 0.3340(2) 0.0589(7) Uani 1.00 d
C(12) C 0.6711(2) 0.0292(2) 0.1854(2) 0.0464(6) Uani 1.00 d
C(13) C 0.5851(4) 0.1974(2) 0.2052(3) 0.0766(10) Uani 1.00 d
C(14) C 0.8190(2) 0.0408(1) 0.2392(1) 0.0430(5) Uani 1.00 d
C(15) C 0.8351(3) 0.0658(2) 0.3401(2) 0.0541(7) Uani 1.00 d
C(16) C 0.9718(3) 0.0761(2) 0.3877(2) 0.0651(8) Uani 1.00 d
C(17) C 1.0939(3) 0.0618(2) 0.3357(2) 0.0667(8) Uani 1.00 d
C(18) C 1.0798(3) 0.0387(2) 0.2356(2) 0.0606(7) Uani 1.00 d
C(19) C 0.9440(2) 0.0287(2) 0.1878(2) 0.0497(6) Uani 1.00 d
H(1) H 0.444(3) -0.023(2) 0.126(2) 0.083(10) Uiso 1.00 calc
H(2) H 0.797(2) -0.156(1) 0.166(1) 0.043(5) Uiso 1.00 calc
H(3) H 0.737(5) -0.361(4) 0.036(3) 0.195(10) Uiso 1.00 calc
H(4) H 0.556(4) -0.332(3) 0.013(3) 0.14(1) Uiso 1.00 calc
H(5) H 0.686(4) -0.305(3) 0.192(3) 0.12(1) Uiso 1.00 calc
H(6) H 0.539(4) -0.261(3) 0.161(3) 0.12(1) Uiso 1.00 calc
H(7) H 0.777(2) -0.171(2) 0.334(2) 0.052(6) Uiso 1.00 calc
H(8) H 0.737(3) -0.208(2) 0.499(2) 0.078(8) Uiso 1.00 calc
H(9) H 0.513(3) -0.173(2) 0.559(2) 0.103(9) Uiso 1.00 calc
H(10) H 0.328(3) -0.096(2) 0.460(2) 0.084(8) Uiso 1.00 calc
H(11) H 0.369(3) -0.054(2) 0.292(2) 0.069(7) Uiso 1.00 calc
H(12) H 0.674(2) 0.046(2) 0.116(2) 0.050(6) Uiso 1.00 calc
H(13) H 0.497(4) 0.230(3) 0.226(2) 0.105(9) Uiso 1.00 calc
H(14) H 0.675(3) 0.225(2) 0.242(2) 0.097(9) Uiso 1.00 calc
H(15) H 0.596(4) 0.206(2) 0.133(3) 0.106(10) Uiso 1.00 calc
H(16) H 0.749(3) 0.080(2) 0.375(2) 0.059(6) Uiso 1.00 calc
H(17) H 0.979(3) 0.096(2) 0.455(2) 0.087(8) Uiso 1.00 calc
H(18) H 1.187(3) 0.070(2) 0.371(2) 0.094(9) Uiso 1.00 calc
H(19) H 1.167(3) 0.032(2) 0.199(2) 0.082(8) Uiso 1.00 calc
H(20) H 0.935(2) 0.011(2) 0.117(2) 0.060(6) Uiso 1.00 calc
loop_
_atom_type_symbol
_atom_type_description
_atom_type_scat_dispersion_real
_atom_type_scat_dispersion_imag
_atom_type_scat_source
C C 0.003 0.002
;International Tables for Crystallography
(1992, Vol. C, Tables 4.2.6.8 and 6.1.1.1)
;
H H 0.000 0.000
;International Tables for Crystallography
(1992, Vol. C, Table 6.1.1.2)
;
O O 0.011 0.006
;International Tables for Crystallography
(1992, Vol. C, Tables 4.2.6.8 and 6.1.1.1)
;
loop_
_geom_angle_atom_site_label_1
_geom_angle_atom_site_label_2
_geom_angle_atom_site_label_3
_geom_angle
_geom_angle_publ_flag
C(1) O(1) H(1) 106(2) no
C(3) O(3) C(4) 111.7(2) yes
C(12) O(4) C(13) 113.7(2) yes
O(1) C(1) C(2) 104.4(2) yes
O(1) C(1) C(6) 110.1(2) yes
O(1) C(1) C(12) 107.8(2) yes
C(2) C(1) C(6) 110.5(2) yes
C(2) C(1) C(12) 113.1(2) yes
C(6) C(1) C(12) 110.8(2) yes
C(1) C(2) C(3) 112.6(2) yes
C(1) C(2) C(5) 113.6(2) yes
C(1) C(2) H(2) 110(1) no
C(3) C(2) C(5) 103.6(2) yes
C(3) C(2) H(2) 104(1) no
C(5) C(2) H(2) 111(1) no
O(2) C(3) O(3) 121.3(2) yes
O(2) C(3) C(2) 129.0(2) yes
O(3) C(3) C(2) 109.7(2) yes
O(3) C(4) C(5) 106.9(2) yes
O(3) C(4) H(3) 103(2) no
O(3) C(4) H(4) 96(2) no
C(5) C(4) H(3) 116(2) no
C(5) C(4) H(4) 115(2) no
H(3) C(4) H(4) 114(3) no
C(2) C(5) C(4) 105.9(2) yes
C(2) C(5) H(5) 113(2) no
C(2) C(5) H(6) 108(2) no
C(4) C(5) H(5) 109(2) no
C(4) C(5) H(6) 110(2) no
H(5) C(5) H(6) 109(3) no
C(1) C(6) C(7) 122.1(2) yes
C(1) C(6) C(11) 119.8(2) yes
C(7) C(6) C(11) 118.1(2) yes
C(6) C(7) C(8) 120.4(2) yes
C(6) C(7) H(7) 120(1) no
C(8) C(7) H(7) 119(1) no
C(7) C(8) C(9) 120.5(3) yes
C(7) C(8) H(8) 118(1) no
C(9) C(8) H(8) 120(1) no
C(8) C(9) C(10) 119.3(2) yes
C(8) C(9) H(9) 118(1) no
C(10) C(9) H(9) 121(1) no
C(9) C(10) C(11) 120.9(3) yes
C(9) C(10) H(10) 117(1) no
C(11) C(10) H(10) 121(1) no
C(6) C(11) C(10) 120.7(3) yes
C(6) C(11) H(11) 119(1) no
C(10) C(11) H(11) 119(1) no
O(4) C(12) C(1) 104.4(2) yes
O(4) C(12) C(14) 112.7(2) yes
O(4) C(12) H(12) 106(1) no
C(1) C(12) C(14) 115.2(2) yes
C(1) C(12) H(12) 105(1) no
C(14) C(12) H(12) 111(1) no
O(4) C(13) H(13) 105(1) no
O(4) C(13) H(14) 111(1) no
O(4) C(13) H(15) 108(1) no
H(13) C(13) H(14) 112(2) no
H(13) C(13) H(15) 111(2) no
H(14) C(13) H(15) 107(2) no
C(12) C(14) C(15) 121.6(2) yes
C(12) C(14) C(19) 120.3(2) yes
C(15) C(14) C(19) 118.0(2) yes
C(14) C(15) C(16) 120.5(2) yes
C(14) C(15) H(16) 118(1) no
C(16) C(15) H(16) 120(1) no
C(15) C(16) C(17) 120.4(2) yes
C(15) C(16) H(17) 118(1) no
C(17) C(16) H(17) 121(1) no
C(16) C(17) C(18) 119.8(2) yes
C(16) C(17) H(18) 117(1) no
C(18) C(17) H(18) 122(1) no
C(17) C(18) C(19) 120.0(2) yes
C(17) C(18) H(19) 119(1) no
C(19) C(18) H(19) 120(1) no
C(14) C(19) C(18) 121.3(2) yes
C(14) C(19) H(20) 119(1) no
C(18) C(19) H(20) 119(1) no
loop_
_geom_bond_atom_site_label_1
_geom_bond_atom_site_label_2
_geom_bond_distance
_geom_bond_publ_flag
O(1) C(1) 1.433(2) yes
O(1) H(1) 0.77(3) no
O(2) C(3) 1.196(3) yes
O(3) C(3) 1.337(3) yes
O(3) C(4) 1.458(4) yes
O(4) C(12) 1.423(2) yes
O(4) C(13) 1.427(3) yes
C(1) C(2) 1.540(3) yes
C(1) C(6) 1.529(3) yes
C(1) C(12) 1.556(3) yes
C(2) C(3) 1.528(3) yes
C(2) C(5) 1.527(3) yes
C(2) H(2) 0.97(2) no
C(4) C(5) 1.471(4) yes
C(4) H(3) 1.09(5) no
C(4) H(4) 0.96(4) no
C(5) H(5) 0.91(4) no
C(5) H(6) 0.93(4) no
C(6) C(7) 1.395(3) yes
C(6) C(11) 1.388(3) yes
C(7) C(8) 1.390(3) yes
C(7) H(7) 0.95(2) no
C(8) C(9) 1.374(4) yes
C(8) H(8) 0.97(3) no
C(9) C(10) 1.371(4) yes
C(9) H(9) 0.93(3) no
C(10) C(11) 1.380(4) yes
C(10) H(10) 0.98(3) no
C(11) H(11) 0.99(3) no
C(12) C(14) 1.510(3) yes
C(12) H(12) 0.96(2) no
C(13) H(13) 0.98(3) no
C(13) H(14) 1.01(3) no
C(13) H(15) 0.99(3) no
C(14) C(15) 1.392(3) yes
C(14) C(19) 1.393(3) yes
C(15) C(16) 1.383(3) yes
C(15) H(16) 0.97(2) no
C(16) C(17) 1.378(4) yes
C(16) H(17) 0.94(3) no
C(17) C(18) 1.376(4) yes
C(17) H(18) 0.96(3) no
C(18) C(19) 1.377(3) yes
C(18) H(19) 0.97(3) no
C(19) H(20) 0.98(2) no
loop_
_geom_contact_atom_site_label_1
_geom_contact_atom_site_label_2
_geom_contact_distance
_geom_contact_site_symmetry_2
O(1) H(3) 2.55(5) 4_445
O(1) O(2) 3.030(3) 3_655
O(1) H(5) 3.22(4) 4_445
O(1) H(19) 3.34(3) 1_455
O(1) C(4) 3.461(5) 4_445
O(1) H(12) 3.49(2) 3_655
O(2) H(19) 2.71(3) 3_755
O(2) H(3) 2.75(5) 2_655
O(2) H(4) 3.25(4) 4_545
O(2) H(20) 3.49(2) 3_755
O(2) C(18) 3.517(3) 3_755
O(2) C(4) 3.596(4) 2_655
O(3) H(15) 2.82(3) 3_655
O(3) H(15) 2.82(3) 2_645
O(3) H(13) 3.06(3) 3_655
O(3) C(13) 3.327(4) 3_655
O(3) H(14) 3.41(3) 2_645
O(3) C(13) 3.572(4) 2_645
O(3) H(12) 3.59(2) 2_645
O(4) H(9) 3.21(3) 3_656
C(2) H(6) 3.33(4) 4_545
C(3) H(1) 3.24(3) 3_655
C(3) H(4) 3.29(4) 4_545
C(3) H(15) 3.50(3) 3_655
C(3) H(15) 3.55(3) 2_645
C(4) H(20) 3.27(2) 2_645
C(4) H(12) 3.41(2) 2_645
C(4) H(15) 3.45(3) 3_655
C(4) H(20) 3.47(2) 4_445
C(4) H(15) 3.49(3) 2_645
C(4) H(19) 3.58(3) 4_445
C(5) H(2) 3.33(2) 4_445
C(8) H(18) 3.00(3) 3_756
C(8) H(10) 3.36(3) 4_545
C(8) H(17) 3.49(3) 2_646
C(9) H(8) 3.23(3) 4_445
C(9) H(18) 3.32(3) 3_756
C(9) H(17) 3.34(3) 2_646
C(9) H(16) 3.35(2) 3_656
C(10) H(8) 3.09(3) 4_445
C(10) H(16) 3.15(2) 3_656
C(10) H(18) 3.31(3) 1_455
C(10) H(7) 3.39(2) 4_445
C(11) H(18) 3.25(3) 1_455
C(11) H(5) 3.28(4) 4_445
C(11) H(19) 3.44(3) 1_455
C(11) H(7) 3.54(2) 4_445
C(12) H(3) 3.46(5) 2_655
C(13) H(9) 3.36(3) 3_656
C(13) C(18) 3.519(4) 4_455
C(13) H(4) 3.59(4) 3_655
C(14) H(13) 3.46(4) 4_555
C(15) H(10) 3.19(3) 3_656
C(15) H(13) 3.49(4) 4_555
C(16) H(17) 3.12(3) 3_756
C(16) H(13) 3.38(3) 4_555
C(16) H(9) 3.40(3) 2_656
C(16) H(8) 3.48(3) 3_756
C(16) H(10) 3.56(3) 3_656
C(17) H(11) 3.06(3) 1_655
C(17) H(14) 3.20(3) 4_555
C(17) H(13) 3.22(3) 4_555
C(17) H(8) 3.26(3) 3_756
C(17) H(10) 3.37(3) 1_655
C(18) H(11) 2.99(3) 1_655
C(18) H(13) 3.15(3) 4_555
C(18) H(14) 3.25(3) 4_555
C(18) H(5) 3.32(4) 4_545
C(19) H(4) 3.26(4) 2_655
C(19) H(13) 3.26(3) 4_555
H(1) H(3) 2.69(6) 4_445
H(1) H(19) 2.89(4) 1_455
H(1) H(12) 3.37(4) 3_655
H(1) H(5) 3.46(5) 4_445
H(2) H(4) 3.27(4) 4_545
H(3) H(12) 2.57(5) 2_645
H(3) H(15) 2.95(6) 2_645
H(3) H(20) 3.02(5) 2_645
H(3) H(19) 3.24(6) 4_445
H(3) H(6) 3.55(6) 4_545
H(4) H(20) 2.71(5) 2_645
H(4) H(15) 2.86(5) 3_655
H(4) H(20) 3.01(5) 4_445
H(4) H(13) 3.47(5) 3_655
H(4) H(12) 3.52(4) 2_645
H(5) H(11) 2.82(4) 4_545
H(5) H(19) 3.02(5) 4_445
H(5) H(6) 3.43(5) 4_545
H(6) H(20) 3.48(4) 4_445
H(6) H(7) 3.58(4) 4_445
H(7) H(10) 3.53(3) 4_545
H(8) H(18) 2.59(4) 3_756
H(8) H(10) 2.78(4) 4_545
H(8) H(17) 3.04(4) 3_756
H(8) H(9) 3.06(4) 4_545
H(8) H(16) 3.27(4) 2_646
H(8) H(17) 3.35(4) 2_646
H(9) H(16) 2.90(4) 3_656
H(9) H(13) 2.99(4) 3_656
H(9) H(17) 3.07(4) 2_646
H(9) H(18) 3.18(4) 3_756
H(9) H(14) 3.35(4) 3_656
H(10) H(18) 2.79(4) 1_455
H(10) H(17) 3.13(4) 3_656
H(11) H(18) 2.62(4) 1_455
H(13) H(14) 3.06(4) 4_455
H(13) H(19) 3.55(4) 4_455
H(14) H(18) 3.23(4) 4_455
H(14) H(19) 3.27(4) 4_455
H(17) H(17) 2.84(5) 3_756
H(20) H(20) 3.44(5) 3_755
loop_
_geom_hbond_atom_site_label_D
_geom_hbond_atom_site_label_H
_geom_hbond_atom_site_label_A
_geom_hbond_distance_DH
_geom_hbond_distance_HA
_geom_hbond_distance_DA
_geom_hbond_angle_DHA
_geom_hbond_publ_flag
O(1) H(1) O(4) 0.77(3) 2.27(2) 2.715(2) 118(2) no
loop_
_geom_torsion_atom_site_label_1
_geom_torsion_atom_site_label_2
_geom_torsion_atom_site_label_3
_geom_torsion_atom_site_label_4
_geom_torsion
_geom_torsion_publ_flag
O(1) C(1) C(2) C(3) 52.0(2) yes
O(1) C(1) C(2) C(5) -65.4(2) yes
O(1) C(1) C(6) C(7) 154.3(2) yes
O(1) C(1) C(6) C(11) -27.6(3) yes
O(1) C(1) C(12) O(4) 59.6(2) yes
O(1) C(1) C(12) C(14) -176.2(2) yes
O(2) C(3) O(3) C(4) 176.6(3) yes
O(2) C(3) C(2) C(1) 51.2(4) yes
O(2) C(3) C(2) C(5) 174.4(3) yes
O(3) C(3) C(2) C(1) -130.1(2) yes
O(3) C(3) C(2) C(5) -6.9(3) yes
O(3) C(4) C(5) C(2) -14.6(4) yes
O(4) C(12) C(1) C(2) 174.5(2) yes
O(4) C(12) C(1) C(6) -60.9(2) yes
O(4) C(12) C(14) C(15) 30.8(3) yes
O(4) C(12) C(14) C(19) -147.8(2) yes
C(1) C(2) C(5) C(4) 135.5(3) yes
C(1) C(6) C(7) C(8) 178.6(2) yes
C(1) C(6) C(11) C(10) -177.8(2) yes
C(1) C(12) O(4) C(13) -164.3(2) yes
C(1) C(12) C(14) C(15) -88.9(2) yes
C(1) C(12) C(14) C(19) 92.6(2) yes
C(2) C(1) C(6) C(7) 39.5(3) yes
C(2) C(1) C(6) C(11) -142.4(2) yes
C(2) C(1) C(12) C(14) -61.4(2) yes
C(2) C(3) O(3) C(4) -2.2(3) yes
C(3) O(3) C(4) C(5) 10.9(4) yes
C(3) C(2) C(1) C(6) 170.3(2) yes
C(3) C(2) C(1) C(12) -64.9(2) yes
C(3) C(2) C(5) C(4) 13.0(3) yes
C(5) C(2) C(1) C(6) 52.9(2) yes
C(5) C(2) C(1) C(12) 177.7(2) yes
C(6) C(1) C(12) C(14) 63.3(2) yes
C(6) C(7) C(8) C(9) -1.4(4) yes
C(6) C(11) C(10) C(9) -0.4(4) yes
C(7) C(6) C(1) C(12) -86.6(2) yes
C(7) C(6) C(11) C(10) 0.4(3) yes
C(7) C(8) C(9) C(10) 1.4(4) yes
C(8) C(7) C(6) C(11) 0.5(3) yes
C(8) C(9) C(10) C(11) -0.5(4) yes
C(11) C(6) C(1) C(12) 91.5(2) yes
C(12) C(14) C(15) C(16) -179.9(2) yes
C(12) C(14) C(19) C(18) -179.9(2) yes
C(13) O(4) C(12) C(14) 69.9(3) yes
C(14) C(15) C(16) C(17) 0.1(3) yes
C(14) C(19) C(18) C(17) -0.5(3) yes
C(15) C(14) C(19) C(18) 1.5(3) yes
C(15) C(16) C(17) C(18) 1.0(4) yes
C(16) C(15) C(14) C(19) -1.3(3) yes
C(16) C(17) C(18) C(19) -0.8(4) yes
C(16) C(17) C(18) C(19) -0.8(4) yes
