#------------------------------------------------------------------------------
#$Date: 2015-07-11 00:07:12 +0300 (Sat, 11 Jul 2015) $
#$Revision: 143468 $
#$URL: svn://www.crystallography.net/cod/cif/1/52/01/1520124.cif $
#------------------------------------------------------------------------------
#
# This file is available in the Crystallography Open Database (COD),
# http://www.crystallography.net/
#
# All data on this site have been placed in the public domain by the
# contributors.
#
data_1520124
loop_
_publ_author_name
'Wu, Jianfeng'
'Zhao, Lang'
'Zhang, Peng'
'Zhang, Li'
'Guo, Mei'
'Tang, Jinkui'
_publ_section_title
;
 Linear 3d-4f compounds: synthesis, structure, and determination of the
 d-f magnetic interaction.
;
_journal_issue                   26
_journal_name_full
'Dalton transactions (Cambridge, England : 2003)'
_journal_page_first              11935
_journal_page_last               11942
_journal_paper_doi               10.1039/c5dt01382h
_journal_volume                  44
_journal_year                    2015
_chemical_formula_moiety         'C76 H70 Cu2 Dy2 N4 O26'
_chemical_formula_sum            'C76 H70 Cu2 Dy2 N4 O26'
_chemical_formula_weight         1915.44
_space_group_crystal_system      monoclinic
_space_group_IT_number           15
_space_group_name_Hall           '-C 2yc'
_space_group_name_H-M_alt        'C 1 2/c 1'
_symmetry_space_group_name_Hall  '-C 2yc'
_symmetry_space_group_name_H-M   'C 1 2/c 1'
_atom_sites_solution_hydrogens   geom
_audit_creation_method           SHELXL-2014/7
_audit_update_record
;
2015-05-06 deposited with the CCDC.
2015-05-29 downloaded from the CCDC.
;
_cell_angle_alpha                90
_cell_angle_beta                 119.867(4)
_cell_angle_gamma                90
_cell_formula_units_Z            4
_cell_length_a                   23.592(6)
_cell_length_b                   16.697(4)
_cell_length_c                   23.137(8)
_cell_measurement_reflns_used    5551
_cell_measurement_temperature    296(2)
_cell_measurement_theta_max      23.97
_cell_measurement_theta_min      2.44
_cell_volume                     7904(4)
_computing_cell_refinement       'Bruker SMART'
_computing_data_collection       'Bruker SMART'
_computing_data_reduction        'Bruker SAINT'
_computing_molecular_graphics    'SHELXL-2014/7 (Sheldrick, 2014)'
_computing_structure_refinement  'SHELXL-2014/7 (Sheldrick, 2014)'
_computing_structure_solution    'Bruker SHELXTL'
_diffrn_ambient_temperature      296(2)
_diffrn_measured_fraction_theta_full 0.992
_diffrn_measured_fraction_theta_max 0.992
_diffrn_measurement_device_type  'CCD area detector'
_diffrn_measurement_method       'phi and omega scans'
_diffrn_radiation_type           MoK\a
_diffrn_radiation_wavelength     0.71073
_diffrn_reflns_av_R_equivalents  0.0565
_diffrn_reflns_av_unetI/netI     0.0624
_diffrn_reflns_laue_measured_fraction_full 0.992
_diffrn_reflns_laue_measured_fraction_max 0.992
_diffrn_reflns_limit_h_max       27
_diffrn_reflns_limit_h_min       -28
_diffrn_reflns_limit_k_max       19
_diffrn_reflns_limit_k_min       -19
_diffrn_reflns_limit_l_max       24
_diffrn_reflns_limit_l_min       -27
_diffrn_reflns_number            21852
_diffrn_reflns_point_group_measured_fraction_full 0.992
_diffrn_reflns_point_group_measured_fraction_max 0.992
_diffrn_reflns_theta_full        25.045
_diffrn_reflns_theta_max         25.045
_diffrn_reflns_theta_min         1.574
_exptl_absorpt_coefficient_mu    2.482
_exptl_absorpt_correction_T_max  0.594
_exptl_absorpt_correction_T_min  0.571
_exptl_absorpt_correction_type   multi-scan
_exptl_crystal_colour            blue
_exptl_crystal_density_diffrn    1.616
_exptl_crystal_description       block
_exptl_crystal_F_000             3840
_exptl_crystal_size_max          0.23
_exptl_crystal_size_mid          0.22
_exptl_crystal_size_min          0.21
_refine_diff_density_max         2.292
_refine_diff_density_min         -2.569
_refine_diff_density_rms         0.169
_refine_ls_extinction_method     none
_refine_ls_goodness_of_fit_ref   1.031
_refine_ls_hydrogen_treatment    constr
_refine_ls_matrix_type           full
_refine_ls_number_parameters     443
_refine_ls_number_reflns         6930
_refine_ls_number_restraints     304
_refine_ls_restrained_S_all      1.073
_refine_ls_R_factor_all          0.1279
_refine_ls_R_factor_gt           0.0777
_refine_ls_shift/su_max          0.001
_refine_ls_shift/su_mean         0.000
_refine_ls_structure_factor_coef Fsqd
_refine_ls_weighting_details
'w=1/[σ²(Fo²)+(0.1280P)²+112.7976P] where P=(Fo²+2Fc²)/3'
_refine_ls_weighting_scheme      calc
_refine_ls_wR_factor_gt          0.2114
_refine_ls_wR_factor_ref         0.2580
_reflns_Friedel_coverage         0.000
_reflns_number_gt                4240
_reflns_number_total             6930
_reflns_threshold_expression     'I > 2σ(I)'
_cod_data_source_file            c5dt01382h2.cif
_cod_data_source_block           Dy2Cu2
_cod_depositor_comments
'Adding full bibliography for 1520123--1520137.cif.'
_cod_database_code               1520124
_audit_block_doi                 10.5517/cc14ht6n
_shelx_shelxl_version_number     2014/7
_shelx_space_group_comment
;
The symmetry employed for this shelxl refinement is uniquely defined
by the following loop, which should always be used as a source of
symmetry information in preference to the above space-group names.
They are only intended as comments.
;
loop_
_space_group_symop_operation_xyz
'x, y, z'
'-x, y, -z+1/2'
'x+1/2, y+1/2, z'
'-x+1/2, y+1/2, -z+1/2'
'-x, -y, -z'
'x, -y, z-1/2'
'-x+1/2, -y+1/2, -z'
'x+1/2, -y+1/2, z-1/2'
loop_
_atom_site_label
_atom_site_type_symbol
_atom_site_fract_x
_atom_site_fract_y
_atom_site_fract_z
_atom_site_U_iso_or_equiv
_atom_site_adp_type
_atom_site_occupancy
_atom_site_site_symmetry_order
_atom_site_calc_flag
_atom_site_refinement_flags_posn
_atom_site_refinement_flags_adp
C1 C 0.2834(4) 0.4757(9) 0.7119(5) 0.117(4) Uani 1 1 d . U
H1A H 0.2900 0.4190 0.7184 0.176 Uiso 1 1 calc R U
H1B H 0.3236 0.5030 0.7406 0.176 Uiso 1 1 calc R U
H1C H 0.2694 0.4886 0.6663 0.176 Uiso 1 1 calc R U
C2 C 0.1733(2) 0.4692(3) 0.6907(2) 0.081(3) Uani 1 1 d G U
C3 C 0.1552(3) 0.4177(4) 0.6371(3) 0.123(4) Uani 1 1 d G U
H3 H 0.1851 0.4045 0.6235 0.147 Uiso 1 1 calc R U
C4 C 0.0924(3) 0.3861(5) 0.6037(4) 0.152(4) Uani 1 1 d G U
H4 H 0.0803 0.3517 0.5678 0.182 Uiso 1 1 calc R U
C5 C 0.0477(3) 0.4058(5) 0.6239(4) 0.116(4) Uani 1 1 d G U
H5 H 0.0057 0.3846 0.6016 0.140 Uiso 1 1 calc R U
C6 C 0.0658(2) 0.4572(4) 0.6776(3) 0.076(3) Uani 1 1 d G U
C7 C 0.1286(3) 0.4889(3) 0.7110(3) 0.061(2) Uani 1 1 d G U
C8 C 0.0198(4) 0.4696(5) 0.6997(4) 0.067(2) Uani 1 1 d . U
H8 H -0.0161 0.4356 0.6831 0.080 Uiso 1 1 calc R U
C9 C 0.0571(4) 0.7603(5) 0.8087(4) 0.070(2) Uani 1 1 d . U
H9 H 0.0270 0.7987 0.8052 0.084 Uiso 1 1 calc R U
C10 C 0.1261(2) 0.7781(3) 0.85521(19) 0.074(3) Uani 1 1 d G U
C11 C 0.1390(3) 0.8453(3) 0.8954(3) 0.108(4) Uani 1 1 d G U
H11 H 0.1047 0.8761 0.8922 0.130 Uiso 1 1 calc R U
C12 C 0.2033(3) 0.8663(4) 0.9405(3) 0.111(4) Uani 1 1 d G U
H12 H 0.2119 0.9112 0.9674 0.133 Uiso 1 1 calc R U
C13 C 0.2545(2) 0.8202(4) 0.9454(3) 0.106(3) Uani 1 1 d G U
H13 H 0.2975 0.8342 0.9755 0.128 Uiso 1 1 calc DR U
C14 C 0.2415(2) 0.7530(4) 0.9052(3) 0.081(3) Uani 1 1 d G U
C15 C 0.1773(2) 0.7320(3) 0.8601(2) 0.069(2) Uani 1 1 d G U
C16 C 0.3536(5) 0.7255(6) 0.9538(6) 0.137(5) Uani 1 1 d . U
H16A H 0.3607 0.7796 0.9449 0.206 Uiso 1 1 calc R U
H16B H 0.3829 0.6904 0.9485 0.206 Uiso 1 1 calc R U
H16C H 0.3615 0.7217 0.9987 0.206 Uiso 1 1 calc DR U
C17 C 0.1693(3) 0.5227(5) 0.9151(4) 0.058(2) Uani 1 1 d . U
C18 C 0.1772(4) 0.4692(5) 0.9709(4) 0.067(2) Uani 1 1 d . U
C19 C 0.1300(5) 0.4666(7) 0.9888(5) 0.097(3) Uani 1 1 d . U
H19 H 0.0931 0.4986 0.9661 0.116 Uiso 1 1 calc R U
C20 C 0.1356(7) 0.4176(8) 1.0396(7) 0.130(4) Uani 1 1 d . U
H20 H 0.1036 0.4165 1.0517 0.156 Uiso 1 1 calc R U
C21 C 0.1919(6) 0.3695(8) 1.0721(6) 0.124(4) Uani 1 1 d . U
H21 H 0.1966 0.3351 1.1058 0.148 Uiso 1 1 calc R U
C22 C 0.2396(5) 0.3721(7) 1.0553(5) 0.103(4) Uani 1 1 d . U
H22 H 0.2769 0.3406 1.0776 0.124 Uiso 1 1 calc R U
C23 C 0.2311(4) 0.4236(5) 1.0036(4) 0.068(2) Uani 1 1 d . U
H23 H 0.2633 0.4261 0.9916 0.082 Uiso 1 1 calc R U
C24 C 0.3475(5) 0.4768(8) 0.9248(5) 0.097(3) Uani 1 1 d . U
C25 C 0.3939(3) 0.4158(5) 0.9757(3) 0.091(3) Uani 1 1 d G U
C26 C 0.3800(4) 0.3345(5) 0.9731(4) 0.139(4) Uani 1 1 d G U
H26 H 0.3407 0.3146 0.9389 0.167 Uiso 1 1 calc R U
C27 C 0.4247(5) 0.2831(5) 1.0217(5) 0.174(5) Uani 1 1 d G U
H27 H 0.4153 0.2288 1.0200 0.208 Uiso 1 1 calc R U
C28 C 0.4833(5) 0.3129(7) 1.0728(4) 0.150(5) Uani 1 1 d G U
H28 H 0.5132 0.2785 1.1053 0.180 Uiso 1 1 calc R U
C29 C 0.4973(3) 0.3941(7) 1.0754(3) 0.139(5) Uani 1 1 d G U
H29 H 0.5365 0.4141 1.1096 0.167 Uiso 1 1 calc R U
C30 C 0.4526(3) 0.4456(5) 1.0268(3) 0.142(4) Uani 1 1 d G U
H30 H 0.4619 0.4999 1.0286 0.171 Uiso 1 1 calc R U
C31 C 0.3055(5) 0.6729(6) 0.7724(4) 0.085(3) Uani 1 1 d . U
C32 C 0.3327(2) 0.7188(3) 0.7355(2) 0.081(3) Uani 1 1 d G U
C33 C 0.3025(3) 0.7884(4) 0.7009(3) 0.093(3) Uani 1 1 d G U
H33 H 0.2667 0.8089 0.7025 0.112 Uiso 1 1 calc R U
C34 C 0.3259(4) 0.8274(4) 0.6639(4) 0.114(4) Uani 1 1 d G U
H34 H 0.3058 0.8740 0.6408 0.137 Uiso 1 1 calc R U
C35 C 0.3795(4) 0.7968(5) 0.6616(4) 0.117(4) Uani 1 1 d G U
H35 H 0.3952 0.8229 0.6368 0.141 Uiso 1 1 calc R U
C36 C 0.4097(3) 0.7271(5) 0.6962(4) 0.117(4) Uani 1 1 d G U
H36 H 0.4456 0.7066 0.6946 0.141 Uiso 1 1 calc R U
C37 C 0.3863(3) 0.6881(4) 0.7332(3) 0.110(4) Uani 1 1 d G U
H37 H 0.4065 0.6416 0.7563 0.132 Uiso 1 1 calc R U
C38 C 0.9485(7) 0.3362(11) 0.3487(6) 0.164(6) Uani 1 1 d D U
H38A H 0.9232 0.2915 0.3493 0.246 Uiso 1 1 calc R U
H38B H 0.9592 0.3286 0.3141 0.246 Uiso 1 1 calc R U
H38C H 0.9237 0.3846 0.3405 0.246 Uiso 1 1 calc R U
Cu1 Cu 0.09181(4) 0.60495(6) 0.78098(4) 0.0550(3) Uani 1 1 d . .
Dy1 Dy 0.25410(2) 0.58123(3) 0.83693(2) 0.07504(15) Uani 1 1 d . .
N1 N 0.0334(3) 0.6966(4) 0.7717(3) 0.0533(17) Uani 1 1 d . .
N2 N 0.0246(2) 0.5237(4) 0.7405(3) 0.0505(16) Uani 1 1 d . .
O1 O 0.2879(3) 0.7029(4) 0.9085(3) 0.094(2) Uani 1 1 d . U
O2 O 0.1688(2) 0.6699(4) 0.8214(2) 0.0675(16) Uani 1 1 d . U
O3 O 0.2339(2) 0.5007(4) 0.7277(3) 0.0793(18) Uani 1 1 d . U
O4 O 0.1491(2) 0.5372(3) 0.7620(2) 0.0594(14) Uani 1 1 d . U
O5 O 0.2486(3) 0.6858(4) 0.7604(3) 0.088(2) Uani 1 1 d D U
O6 O 0.3399(3) 0.6194(5) 0.8145(3) 0.094(2) Uani 1 1 d . U
O7 O 0.3503(3) 0.5470(5) 0.9375(3) 0.102(2) Uani 1 1 d . U
O8 O 0.3045(3) 0.4490(5) 0.8674(3) 0.098(2) Uani 1 1 d . U
O9 O 0.2183(2) 0.5313(4) 0.9078(2) 0.0715(17) Uani 1 1 d . U
O10 O 0.1161(2) 0.5561(4) 0.8806(2) 0.0683(16) Uani 1 1 d . U
O11 O 1.0095(7) 0.3420(10) 0.4139(5) 0.245(7) Uani 1 1 d D U
H11A H 1.0408 0.3467 0.4079 0.368 Uiso 1 1 calc DR U
O12 O 0.1416(6) 0.7916(8) 0.6832(6) 0.228(6) Uani 1 1 d D U
loop_
_atom_type_symbol
_atom_type_description
_atom_type_scat_dispersion_real
_atom_type_scat_dispersion_imag
_atom_type_scat_source
C C 0.0033 0.0016 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
H H 0.0000 0.0000 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
N N 0.0061 0.0033 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
O O 0.0106 0.0060 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
Cu Cu 0.3201 1.2651 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
Dy Dy -0.1892 4.4098 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
loop_
_geom_angle_atom_site_label_1
_geom_angle_atom_site_label_2
_geom_angle_atom_site_label_3
_geom_angle
_geom_angle_site_symmetry_1
_geom_angle_site_symmetry_3
O3 C2 C3 124.3(4) . .
O3 C2 C7 115.7(4) . .
C3 C2 C7 120.0 . .
C4 C3 C2 120.0 . .
C3 C4 C5 120.0 . .
C4 C5 C6 120.0 . .
C7 C6 C5 120.0 . .
C7 C6 C8 122.5(5) . .
C5 C6 C8 117.3(5) . .
O4 C7 C6 123.3(4) . .
O4 C7 C2 116.7(4) . .
C6 C7 C2 120.0 . .
N2 C8 C6 124.6(7) . .
N1 C9 C10 127.2(8) . .
C11 C10 C15 120.0 . .
C11 C10 C9 116.7(5) . .
C15 C10 C9 123.3(5) . .
C10 C11 C12 120.0 . .
C13 C12 C11 120.0 . .
C12 C13 C14 120.0 . .
O1 C14 C15 115.9(5) . .
O1 C14 C13 124.0(5) . .
C15 C14 C13 120.0 . .
O2 C15 C14 116.7(4) . .
O2 C15 C10 123.2(4) . .
C14 C15 C10 120.0 . .
O10 C17 O9 124.7(8) . .
O10 C17 C18 118.4(7) . .
O9 C17 C18 117.0(7) . .
C23 C18 C19 119.8(9) . .
C23 C18 C17 119.8(8) . .
C19 C18 C17 120.5(8) . .
C18 C19 C20 121.8(11) . .
C19 C20 C21 117.3(14) . .
C22 C21 C20 121.5(13) . .
C21 C22 C23 118.4(11) . .
C18 C23 C22 121.2(10) . .
O7 C24 O8 121.4(10) . .
O7 C24 C25 122.0(8) . .
O8 C24 C25 116.6(10) . .
O7 C24 Dy1 59.2(5) . .
O8 C24 Dy1 62.5(6) . .
C25 C24 Dy1 173.8(7) . .
C26 C25 C30 120.0 . .
C26 C25 C24 123.6(6) . .
C30 C25 C24 116.4(6) . .
C25 C26 C27 120.0 . .
C28 C27 C26 120.0 . .
C29 C28 C27 120.0 . .
C28 C29 C30 120.0 . .
C29 C30 C25 120.0 . .
O5 C31 O6 119.9(9) . .
O5 C31 C32 120.0(8) . .
O6 C31 C32 120.1(9) . .
O5 C31 Dy1 60.7(5) . .
O6 C31 Dy1 59.2(5) . .
C32 C31 Dy1 177.2(7) . .
C33 C32 C37 120.0 . .
C33 C32 C31 120.7(5) . .
C37 C32 C31 119.2(5) . .
C34 C33 C32 120.0 . .
C33 C34 C35 120.0 . .
C36 C35 C34 120.0 . .
C37 C36 C35 120.0 . .
C36 C37 C32 120.0 . .
O2 Cu1 N2 169.4(3) . .
O2 Cu1 O4 81.1(2) . .
N2 Cu1 O4 88.7(2) . .
O2 Cu1 N1 93.1(2) . .
N2 Cu1 N1 97.4(2) . .
O4 Cu1 N1 158.1(2) . .
O2 Cu1 O10 90.5(2) . .
N2 Cu1 O10 88.3(2) . .
O4 Cu1 O10 99.7(2) . .
N1 Cu1 O10 101.5(2) . .
O2 Cu1 Dy1 42.66(18) . .
N2 Cu1 Dy1 126.72(17) . .
O4 Cu1 Dy1 41.51(13) . .
N1 Cu1 Dy1 135.74(17) . .
O10 Cu1 Dy1 84.43(14) . .
O4 Dy1 O9 77.73(18) . .
O4 Dy1 O7 143.0(2) . .
O9 Dy1 O7 74.4(2) . .
O4 Dy1 O2 64.97(18) . .
O9 Dy1 O2 75.7(2) . .
O7 Dy1 O2 128.5(2) . .
O4 Dy1 O6 128.3(2) . .
O9 Dy1 O6 151.54(18) . .
O7 Dy1 O6 77.2(2) . .
O2 Dy1 O6 122.8(2) . .
O4 Dy1 O8 96.6(2) . .
O9 Dy1 O8 76.6(2) . .
O7 Dy1 O8 53.7(3) . .
O2 Dy1 O8 149.5(2) . .
O6 Dy1 O8 87.8(3) . .
O4 Dy1 O5 91.91(19) . .
O9 Dy1 O5 148.8(2) . .
O7 Dy1 O5 124.2(2) . .
O2 Dy1 O5 73.2(2) . .
O6 Dy1 O5 53.3(2) . .
O8 Dy1 O5 134.3(2) . .
O4 Dy1 O1 128.6(2) . .
O9 Dy1 O1 86.1(2) . .
O7 Dy1 O1 73.2(3) . .
O2 Dy1 O1 63.83(19) . .
O6 Dy1 O1 84.4(3) . .
O8 Dy1 O1 126.7(2) . .
O5 Dy1 O1 77.5(2) . .
O4 Dy1 O3 61.08(18) . .
O9 Dy1 O3 121.6(2) . .
O7 Dy1 O3 115.9(2) . .
O2 Dy1 O3 115.43(17) . .
O6 Dy1 O3 72.8(2) . .
O8 Dy1 O3 69.6(2) . .
O5 Dy1 O3 75.8(2) . .
O1 Dy1 O3 151.9(2) . .
O4 Dy1 C24 121.0(3) . .
O9 Dy1 C24 72.1(3) . .
O7 Dy1 C24 25.8(3) . .
O2 Dy1 C24 144.4(3) . .
O6 Dy1 C24 82.9(3) . .
O8 Dy1 C24 28.0(3) . .
O5 Dy1 C24 136.2(3) . .
O1 Dy1 C24 98.8(3) . .
O3 Dy1 C24 94.5(3) . .
O4 Dy1 C31 111.0(2) . .
O9 Dy1 C31 166.2(3) . .
O7 Dy1 C31 101.4(3) . .
O2 Dy1 C31 97.9(3) . .
O6 Dy1 C31 26.9(2) . .
O8 Dy1 C31 111.8(3) . .
O5 Dy1 C31 26.4(2) . .
O1 Dy1 C31 80.1(3) . .
O3 Dy1 C31 72.1(3) . .
C24 Dy1 C31 109.9(3) . .
O4 Dy1 Cu1 34.23(14) . .
O9 Dy1 Cu1 64.98(13) . .
O7 Dy1 Cu1 138.4(2) . .
O2 Dy1 Cu1 33.03(13) . .
O6 Dy1 Cu1 142.56(15) . .
O8 Dy1 Cu1 120.66(17) . .
O5 Dy1 Cu1 89.88(14) . .
O1 Dy1 Cu1 94.90(15) . .
O3 Dy1 Cu1 93.54(11) . .
C24 Dy1 Cu1 133.7(2) . .
C31 Dy1 Cu1 116.0(2) . .
C9 N1 N1 116.0(6) . 2_556
C9 N1 Cu1 120.4(5) . .
N1 N1 Cu1 123.6(3) 2_556 .
C8 N2 N2 116.3(5) . 2_556
C8 N2 Cu1 127.3(6) . .
N2 N2 Cu1 116.5(4) 2_556 .
C14 O1 C16 115.6(8) . .
C14 O1 Dy1 119.1(4) . .
C16 O1 Dy1 125.3(7) . .
C15 O2 Cu1 124.4(5) . .
C15 O2 Dy1 123.8(4) . .
Cu1 O2 Dy1 104.3(3) . .
C2 O3 C1 117.3(7) . .
C2 O3 Dy1 115.2(4) . .
C1 O3 Dy1 126.5(5) . .
C7 O4 Cu1 124.6(4) . .
C7 O4 Dy1 130.2(4) . .
Cu1 O4 Dy1 104.3(2) . .
C31 O5 Dy1 93.0(6) . .
C31 O6 Dy1 93.8(6) . .
C24 O7 Dy1 94.9(6) . .
C24 O8 Dy1 89.6(7) . .
C17 O9 Dy1 144.3(5) . .
C17 O10 Cu1 119.2(6) . .
loop_
_geom_bond_atom_site_label_1
_geom_bond_atom_site_label_2
_geom_bond_distance
_geom_bond_site_symmetry_2
C1 O3 1.447(12) .
C2 O3 1.355(7) .
C2 C3 1.3900 .
C2 C7 1.3900 .
C3 C4 1.3900 .
C4 C5 1.3900 .
C5 C6 1.3900 .
C6 C7 1.3900 .
C6 C8 1.426(10) .
C7 O4 1.307(7) .
C8 N2 1.271(10) .
C9 N1 1.304(10) .
C9 C10 1.467(9) .
C10 C11 1.3900 .
C10 C15 1.3900 .
C11 C12 1.3900 .
C12 C13 1.3900 .
C13 C14 1.3900 .
C14 O1 1.349(9) .
C14 C15 1.3900 .
C15 O2 1.318(7) .
C16 O1 1.422(11) .
C17 O10 1.234(9) .
C17 O9 1.256(10) .
C17 C18 1.503(12) .
C18 C23 1.347(11) .
C18 C19 1.367(14) .
C19 C20 1.383(17) .
C20 C21 1.406(18) .
C21 C22 1.361(19) .
C22 C23 1.405(15) .
C24 O7 1.203(14) .
C24 O8 1.290(12) .
C24 C25 1.529(12) .
C24 Dy1 2.751(11) .
C25 C26 1.3900 .
C25 C30 1.3900 .
C26 C27 1.3900 .
C27 C28 1.3900 .
C28 C29 1.3900 .
C29 C30 1.3900 .
C31 O5 1.246(12) .
C31 O6 1.272(11) .
C31 C32 1.508(12) .
C31 Dy1 2.800(10) .
C32 C33 1.3900 .
C32 C37 1.3900 .
C33 C34 1.3900 .
C34 C35 1.3900 .
C35 C36 1.3900 .
C36 C37 1.3900 .
C38 O11 1.480(13) .
Cu1 O2 1.912(5) .
Cu1 N2 1.937(6) .
Cu1 O4 1.973(6) .
Cu1 N1 1.998(6) .
Cu1 O10 2.235(5) .
Cu1 Dy1 3.3995(13) .
Dy1 O4 2.325(4) .
Dy1 O9 2.342(6) .
Dy1 O7 2.373(6) .
Dy1 O2 2.378(6) .
Dy1 O6 2.411(7) .
Dy1 O8 2.440(8) .
Dy1 O5 2.445(6) .
Dy1 O1 2.489(7) .
Dy1 O3 2.688(6) .
N1 N1 1.383(11) 2_556
N2 N2 1.431(12) 2_556
