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#$Date: 2016-09-16 14:55:27 +0300 (Fri, 16 Sep 2016) $
#$Revision: 186592 $
#$URL: file:///home/coder/svn-repositories/cod/cif/1/53/32/1533272.cif $
#------------------------------------------------------------------------------
#
# This file is available in the Crystallography Open Database (COD),
# http://www.crystallography.net/
#
# All data on this site have been placed in the public domain by the
# contributors.
#
data_1533272
loop_
_publ_author_name
'Yusenko, K.V.'
'Gromilov, S.A.'
'Baidina, I.A.'
'Basova, T.V.'
'Shubin, Yu.V.'
'Korenev, S.V.'
'Drebushchak, T.N.'
'Korol'kov, I.V.'
_publ_section_title
;
 Synthesis, structure and thermal decomposition of
 chloropentaamminerhodium(III) hexabromoplatinate(IV)
;
_journal_name_full
'Zhurnal Strukturnoi Khimii (Issue-No. from 1981)'
_journal_page_first              699
_journal_page_last               705
_journal_volume                  43
_journal_year                    2002
_chemical_formula_sum            'Br6 Cl H15 N5 Pt Rh'
_chemical_name_systematic        '(Rh (N H3)5 Cl) (Pt Br6)'
_space_group_IT_number           11
_symmetry_space_group_name_Hall  '-P 2yb'
_symmetry_space_group_name_H-M   'P 1 21/m 1'
_cell_angle_alpha                90
_cell_angle_beta                 91.13
_cell_angle_gamma                90
_cell_formula_units_Z            4
_cell_length_a                   12.013
_cell_length_b                   8.401
_cell_length_c                   15.999
_cell_volume                     1614.324
_citation_journal_id_ASTM        ZSTKAI
_cod_data_source_file            Yusenko_ZSTKAI_2002_660.cif
_cod_data_source_block           H15Br6Cl1N5Pt1Rh1
_cod_original_formula_sum        'H15 Br6 Cl1 N5 Pt1 Rh1'
_cod_database_code               1533272
loop_
_symmetry_equiv_pos_as_xyz
x,y,z
-x,y+1/2,-z
-x,-y,-z
x,-y-1/2,z
loop_
_atom_site_label
_atom_site_type_symbol
_atom_site_fract_x
_atom_site_fract_y
_atom_site_fract_z
_atom_site_occupancy
_atom_site_U_iso_or_equiv
_atom_site_attached_hydrogens
Br2 Br-1 0.8748 0.25 0.0111 1 0.0 0
N7 N-3 0.205 0.25 0.269 1 0.0 3
Br1 Br-1 0.981 0.0386 0.8468 1 0.0 0
Br4 Br-1 0.803 0.25 0.7068 1 0.0 0
Br3 Br-1 0.6991 0.0403 0.875 1 0.0 0
N5 N-3 0.033 0.077 0.367 1 0.0 3
Pt2 Pt+4 0.6578 0.25 0.3606 1 0.0 0
Pt1 Pt+4 0.8396 0.25 0.8599 1 0.0 0
N1 N-3 0.227 0.25 0.787 1 0.0 3
Rh1 Rh+3 0.3315 0.25 0.8986 1 0.0 0
Br8 Br-1 0.532 0.25 0.4774 1 0.0 0
Br5 Br-1 0.8121 0.25 0.4647 1 0.0 0
N3 N-3 0.339 0.001 0.899 1 0.0 3
Br9 Br-1 0.7984 0.25 0.2469 1 0.0 0
Rh2 Rh+3 0.1537 0.25 0.3926 1 0.0 0
Br7 Br-1 0.6556 -0.0425 0.3613 1 0.0 0
N2 N-3 0.46 0.25 0.818 1 0.0 3
N4 N-3 0.205 0.25 0.981 1 0.0 3
N6 N-3 0.272 0.073 0.425 1 0.0 3
Cl2 Cl-1 0.0984 0.25 0.5298 1 0.0 0
Cl1 Cl-1 0.4565 0.25 0.0119 1 0.0 0
Br6 Br-1 0.5046 0.25 0.2555 1 0.0 0
