#------------------------------------------------------------------------------
#$Date: 2015-12-06 10:55:50 +0200 (Sun, 06 Dec 2015) $
#$Revision: 170840 $
#$URL: svn://www.crystallography.net/cod/cif/1/54/06/1540636.cif $
#------------------------------------------------------------------------------
#
# This file is available in the Crystallography Open Database (COD),
# http://www.crystallography.net/
#
# All data on this site have been placed in the public domain by the
# contributors.
#
data_1540636
loop_
_publ_author_name
'Tai, Xi-Shi'
'You, Hai-Ying'
_publ_section_title
;
 A New 1D Chained Coordination Polymer: Synthesis, Crystal Structure,
 Antitumor Activity and Luminescent Property
;
_journal_issue                   4
_journal_name_full               Crystals
_journal_page_first              608
_journal_paper_doi               10.3390/cryst5040608
_journal_volume                  5
_journal_year                    2015
_chemical_absolute_configuration unk
_chemical_formula_sum            'C32 H34 Cu0 N4 O8 Zn'
_chemical_formula_weight         668.00
_chemical_name_systematic
; 
 ? 
;
_space_group_IT_number           4
_symmetry_cell_setting           monoclinic
_symmetry_space_group_name_Hall  'P 2yb'
_symmetry_space_group_name_H-M   'P 1 21 1'
_atom_sites_solution_hydrogens   geom
_atom_sites_solution_primary     direct
_atom_sites_solution_secondary   difmap
_audit_creation_method           SHELXL-97
_cell_angle_alpha                90.00
_cell_angle_beta                 106.112(3)
_cell_angle_gamma                90.00
_cell_formula_units_Z            2
_cell_length_a                   11.421(2)
_cell_length_b                   9.2213(17)
_cell_length_c                   15.188(3)
_cell_measurement_temperature    293(2)
_cell_volume                     1536.7(5)
_computing_structure_refinement  'SHELXL-97 (Sheldrick, 1997)'
_computing_structure_solution    'SHELXS-97 (Sheldrick, 1990)'
_diffrn_ambient_temperature      293(2)
_diffrn_measured_fraction_theta_full 0.962
_diffrn_measured_fraction_theta_max 0.962
_diffrn_measurement_device_type  'CCD area detector'
_diffrn_measurement_method       'phi and omega scans'
_diffrn_radiation_monochromator  graphite
_diffrn_radiation_source         'fine-focus sealed tube'
_diffrn_radiation_type           MoK\a
_diffrn_radiation_wavelength     0.71073
_diffrn_reflns_av_R_equivalents  0.0362
_diffrn_reflns_av_sigmaI/netI    0.0691
_diffrn_reflns_limit_h_max       13
_diffrn_reflns_limit_h_min       -15
_diffrn_reflns_limit_k_max       12
_diffrn_reflns_limit_k_min       -9
_diffrn_reflns_limit_l_max       20
_diffrn_reflns_limit_l_min       -18
_diffrn_reflns_number            8997
_diffrn_reflns_theta_full        28.26
_diffrn_reflns_theta_max         28.26
_diffrn_reflns_theta_min         1.86
_exptl_absorpt_coefficient_mu    0.857
_exptl_crystal_colour            colourless
_exptl_crystal_density_diffrn    1.444
_exptl_crystal_density_method    'not measured'
_exptl_crystal_description       block
_exptl_crystal_F_000             696
_exptl_crystal_size_max          0.32
_exptl_crystal_size_mid          0.28
_exptl_crystal_size_min          0.22
_refine_diff_density_max         0.870
_refine_diff_density_min         -0.880
_refine_diff_density_rms         0.082
_refine_ls_abs_structure_details 'Flack H D (1983), Acta Cryst. A39, 876-881'
_refine_ls_abs_structure_Flack   0.026(16)
_refine_ls_extinction_method     none
_refine_ls_goodness_of_fit_ref   1.005
_refine_ls_hydrogen_treatment    mixed
_refine_ls_matrix_type           full
_refine_ls_number_parameters     411
_refine_ls_number_reflns         5465
_refine_ls_number_restraints     1
_refine_ls_restrained_S_all      1.005
_refine_ls_R_factor_all          0.0711
_refine_ls_R_factor_gt           0.0439
_refine_ls_shift/su_max          0.000
_refine_ls_shift/su_mean         0.000
_refine_ls_structure_factor_coef Fsqd
_refine_ls_weighting_details
'calc w=1/[σ²(Fo²)+(0.0605P)²+0.0000P] where P=(Fo²+2Fc²)/3'
_refine_ls_weighting_scheme      calc
_refine_ls_wR_factor_gt          0.1013
_refine_ls_wR_factor_ref         0.1156
_reflns_number_gt                4217
_reflns_number_total             5465
_reflns_threshold_expression     >2sigma(I)
_cod_data_source_file            ww.cif
_cod_data_source_block           ww
_cod_original_sg_symbol_H-M      P21
_cod_database_code               1540636
loop_
_symmetry_equiv_pos_as_xyz
'x, y, z'
'-x, y+1/2, -z'
loop_
_atom_site_label
_atom_site_type_symbol
_atom_site_fract_x
_atom_site_fract_y
_atom_site_fract_z
_atom_site_U_iso_or_equiv
_atom_site_adp_type
_atom_site_occupancy
_atom_site_symmetry_multiplicity
_atom_site_calc_flag
_atom_site_refinement_flags
_atom_site_disorder_assembly
_atom_site_disorder_group
Zn1 Zn 0.01477(3) 0.91895(6) 0.09444(3) 0.03182(13) Uani 1 1 d . . .
O1 O 0.0628(2) 0.9467(3) 0.23966(18) 0.0333(8) Uani 1 1 d . B .
N1 N 0.0312(3) 0.7389(4) -0.2330(2) 0.0375(9) Uani 1 1 d . . .
C1 C 0.3936(5) 1.0611(7) 0.4145(4) 0.0603(16) Uani 1 1 d . . .
H1A H 0.3414 1.1354 0.4209 0.072 Uiso 1 1 calc R A 1
O2 O 0.1633(3) 0.9264(6) -0.2211(3) 0.0675(10) Uani 1 1 d . . .
N2 N 0.0373(3) 0.9034(5) 0.4455(2) 0.0355(8) Uani 1 1 d . B 1
C2 C 0.4975(5) 1.0947(9) 0.3876(4) 0.0761(18) Uani 1 1 d . B 1
H2A H 0.5122 1.1901 0.3739 0.091 Uiso 1 1 calc R B 1
O3 O 0.1182(3) 0.7311(4) 0.3031(2) 0.0516(9) Uani 1 1 d . B 1
N3 N 0.2017(2) 0.9208(6) 0.08757(19) 0.0332(7) Uani 1 1 d . . 1
C3 C 0.5769(6) 0.9893(11) 0.3811(5) 0.076(2) Uani 1 1 d . B 1
H3A H 0.6471 1.0127 0.3646 0.091 Uiso 1 1 calc R B 1
O4 O 0.0368(3) 1.1313(4) 0.5004(3) 0.0561(9) Uani 1 1 d . B 1
N4 N -0.1730(3) 0.9365(5) 0.0941(2) 0.0347(8) Uani 1 1 d . . 1
C4 C 0.5544(6) 0.8494(10) 0.3987(5) 0.072(2) Uani 1 1 d . B 1
H4A H 0.6096 0.7770 0.3951 0.087 Uiso 1 1 calc R B 1
O5 O -0.0416(2) 0.8963(4) -0.04682(17) 0.0327(7) Uani 1 1 d . . 1
C5 C 0.4478(5) 0.8146(8) 0.4222(4) 0.0604(15) Uani 1 1 d . B 1
H5A H 0.4309 0.7181 0.4316 0.072 Uiso 1 1 calc R B 1
O6 O 0.0162(3) 1.1592(3) 0.0674(2) 0.0348(6) Uani 1 1 d . . 1
C6 C 0.3669(3) 0.9217(8) 0.4319(2) 0.0446(10) Uani 1 1 d . B 1
O7 O 0.0212(3) 0.6962(4) 0.1241(3) 0.0463(8) Uani 1 1 d . . 1
H7C H 0.0499 0.6840 0.1794 0.070 Uiso 1 1 calc R . 1
H7L H 0.052(7) 0.655(9) 0.094(5) 0.09(3) Uiso 1 1 d . C 1
C7 C 0.2576(4) 0.8834(6) 0.4649(3) 0.0428(12) Uani 1 1 d . B 1
H7A H 0.2685 0.9252 0.5252 0.051 Uiso 1 1 calc R B 1
H7B H 0.2545 0.7789 0.4711 0.051 Uiso 1 1 calc R B 1
C8 C 0.1350(3) 0.9356(6) 0.4019(2) 0.0330(9) Uani 1 1 d . B 1
H8A H 0.1390 1.0407 0.3939 0.040 Uiso 1 1 calc R B 1
O8 O 0.2362(4) 0.1410(5) 0.6723(3) 0.0823(13) Uani 1 1 d . D 1
H80A H 0.2376 0.0914 0.6170 0.099 Uiso 1 1 d R D 1
H8B H 0.1944 0.0882 0.7032 0.099 Uiso 1 1 d R D 1
C9 C -0.0003(4) 1.0051(5) 0.4935(3) 0.0362(10) Uani 1 1 d . B 1
C10 C -0.0946(5) 0.9583(6) 0.5411(4) 0.0529(15) Uani 1 1 d . B 1
H10A H -0.1155 1.0392 0.5736 0.079 Uiso 1 1 calc R B 1
H10B H -0.0618 0.8816 0.5836 0.079 Uiso 1 1 calc R B 1
H10C H -0.1663 0.9243 0.4963 0.079 Uiso 1 1 calc R B 1
C11 C 0.1030(3) 0.8630(5) 0.3070(3) 0.0322(9) Uani 1 1 d . B 1
C12 C -0.2918(4) 0.8405(5) -0.2329(3) 0.0382(10) Uani 1 1 d . E 1
C13 C -0.3512(6) 0.9565(6) -0.2814(5) 0.0693(19) Uani 1 1 d . E 1
H13A H -0.3186 1.0025 -0.3238 0.083 Uiso 1 1 calc R E 1
C14 C -0.4594(6) 1.0060(8) -0.2682(5) 0.088(2) Uani 1 1 d . E 1
H14A H -0.4986 1.0849 -0.3019 0.106 Uiso 1 1 calc R E 1
C15 C -0.5096(5) 0.9412(8) -0.2064(4) 0.0638(16) Uani 1 1 d . E 1
H15A H -0.5835 0.9735 -0.1992 0.077 Uiso 1 1 calc R E 1
C16 C -0.4492(5) 0.8281(7) -0.1556(4) 0.0601(15) Uani 1 1 d . E 1
H16A H -0.4810 0.7837 -0.1122 0.072 Uiso 1 1 calc R E 1
C17 C -0.3410(4) 0.7801(6) -0.1687(3) 0.0519(12) Uani 1 1 d . E 1
H17A H -0.3000 0.7041 -0.1329 0.062 Uiso 1 1 calc R E 1
C18 C -0.1829(4) 0.7723(6) -0.2551(3) 0.0400(10) Uani 1 1 d . E 1
H18A H -0.1888 0.7929 -0.3188 0.048 Uiso 1 1 calc R E 1
H18B H -0.1891 0.6680 -0.2494 0.048 Uiso 1 1 calc R E 1
C19 C -0.0570(4) 0.8182(5) -0.1981(3) 0.0329(9) Uani 1 1 d . E 1
H19A H -0.0469 0.9224 -0.2063 0.039 Uiso 1 1 calc R E 1
C20 C 0.1346(4) 0.8013(6) -0.2425(3) 0.0439(11) Uani 1 1 d . E 1
C21 C 0.2093(4) 0.7039(7) -0.2845(4) 0.0595(15) Uani 1 1 d . E 1
H21A H 0.2804 0.7550 -0.2893 0.089 Uiso 1 1 calc R E 1
H21B H 0.1617 0.6746 -0.3444 0.089 Uiso 1 1 calc R E 1
H21C H 0.2335 0.6197 -0.2466 0.089 Uiso 1 1 calc R E 1
C22 C -0.0358(3) 0.7859(5) -0.0951(2) 0.0270(9) Uani 1 1 d . . 1
C23 C -0.2527(4) 1.0290(6) 0.0418(3) 0.0417(11) Uani 1 1 d . . 1
H23A H -0.2241 1.0955 0.0066 0.050 Uiso 1 1 calc R . 1
C24 C -0.3755(4) 1.0312(6) 0.0372(3) 0.0420(11) Uani 1 1 d . . 1
H24A H -0.4272 1.0991 0.0008 0.050 Uiso 1 1 calc R . 1
C25 C -0.4208(3) 0.9303(7) 0.0880(2) 0.0345(9) Uani 1 1 d . . 1
C26 C -0.3388(4) 0.8349(6) 0.1426(3) 0.0472(12) Uani 1 1 d . . 1
H26A H -0.3649 0.7671 0.1783 0.057 Uiso 1 1 calc R . 1
C27 C -0.2168(4) 0.8412(6) 0.1436(3) 0.0453(12) Uani 1 1 d . . 1
H27A H -0.1629 0.7759 0.1805 0.054 Uiso 1 1 calc R . 1
C28 C 0.2351(4) 0.9716(5) 0.0151(3) 0.0373(11) Uani 1 1 d . . 1
H28A H 0.1747 1.0054 -0.0352 0.045 Uiso 1 1 calc R . 1
C29 C 0.3550(4) 0.9763(5) 0.0117(3) 0.0383(10) Uani 1 1 d . . 1
H29A H 0.3735 1.0124 -0.0400 0.046 Uiso 1 1 calc R . 1
C30 C 0.4473(3) 0.9269(7) 0.0856(2) 0.0349(8) Uani 1 1 d . . 1
C31 C 0.4117(4) 0.8697(6) 0.1591(3) 0.0465(13) Uani 1 1 d . . 1
H31A H 0.4699 0.8322 0.2095 0.056 Uiso 1 1 calc R . 1
C32 C 0.2906(4) 0.8689(6) 0.1570(3) 0.0447(13) Uani 1 1 d . . 1
H32A H 0.2694 0.8298 0.2069 0.054 Uiso 1 1 calc R . 1
loop_
_atom_type_symbol
_atom_type_description
_atom_type_scat_dispersion_real
_atom_type_scat_dispersion_imag
_atom_type_scat_source
C C 0.0033 0.0016 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
Cu Cu 0.3201 1.2651 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
N N 0.0061 0.0033 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
O O 0.0106 0.0060 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
Zn Zn 0.2839 1.4301 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
H H 0.0000 0.0000 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
loop_
_geom_angle_atom_site_label_1
_geom_angle_atom_site_label_2
_geom_angle_atom_site_label_3
_geom_angle
_geom_angle_site_symmetry_1
_geom_angle_site_symmetry_3
O5 Zn1 O7 96.06(14) . .
O5 Zn1 O1 176.76(11) . .
O7 Zn1 O1 84.96(14) . .
O5 Zn1 N4 88.98(11) . .
O7 Zn1 N4 92.82(17) . .
O1 Zn1 N4 87.89(11) . .
O5 Zn1 N3 88.74(10) . .
O7 Zn1 N3 92.39(17) . .
O1 Zn1 N3 94.30(11) . .
N4 Zn1 N3 174.5(2) . .
O5 Zn1 O6 85.78(12) . .
O7 Zn1 O6 177.40(15) . .
O1 Zn1 O6 93.30(12) . .
N4 Zn1 O6 89.04(15) . .
N3 Zn1 O6 85.80(16) . .
C11 O1 Zn1 134.0(3) . .
C20 N1 C19 122.4(4) . .
C6 C1 C2 121.4(6) . .
C6 C1 H1A 119.3 . .
C2 C1 H1A 119.3 . .
C9 N2 C8 120.2(4) . .
C3 C2 C1 120.3(7) . .
C3 C2 H2A 119.8 . .
C1 C2 H2A 119.8 . .
C32 N3 C28 116.4(3) . .
C32 N3 Zn1 120.2(3) . .
C28 N3 Zn1 123.3(3) . .
C2 C3 C4 120.2(7) . .
C2 C3 H3A 119.9 . .
C4 C3 H3A 119.9 . .
C23 N4 C27 117.0(3) . .
C23 N4 Zn1 124.3(3) . .
C27 N4 Zn1 118.5(3) . .
C3 C4 C5 119.6(7) . .
C3 C4 H4A 120.2 . .
C5 C4 H4A 120.2 . .
C22 O5 Zn1 129.0(3) . .
C6 C5 C4 121.1(7) . .
C6 C5 H5A 119.5 . .
C4 C5 H5A 119.5 . .
C22 O6 Zn1 150.9(3) 2 .
C1 C6 C5 117.3(5) . .
C1 C6 C7 122.3(5) . .
C5 C6 C7 120.3(6) . .
Zn1 O7 H7C 109.5 . .
Zn1 O7 H7L 111(6) . .
H7C O7 H7L 115.7 . .
C6 C7 C8 114.4(4) . .
C6 C7 H7A 108.6 . .
C8 C7 H7A 108.6 . .
C6 C7 H7B 108.6 . .
C8 C7 H7B 108.6 . .
H7A C7 H7B 107.6 . .
N2 C8 C7 109.2(3) . .
N2 C8 C11 108.7(3) . .
C7 C8 C11 112.7(4) . .
N2 C8 H8A 108.7 . .
C7 C8 H8A 108.7 . .
C11 C8 H8A 108.7 . .
H80A O8 H8B 109.7 . .
O4 C9 N2 123.8(4) . .
O4 C9 C10 120.1(4) . .
N2 C9 C10 116.1(4) . .
C9 C10 H10A 109.5 . .
C9 C10 H10B 109.5 . .
H10A C10 H10B 109.5 . .
C9 C10 H10C 109.5 . .
H10A C10 H10C 109.5 . .
H10B C10 H10C 109.5 . .
O3 C11 O1 126.1(4) . .
O3 C11 C8 118.3(4) . .
O1 C11 C8 115.6(4) . .
C13 C12 C17 117.5(4) . .
C13 C12 C18 121.3(4) . .
C17 C12 C18 120.9(4) . .
C12 C13 C14 120.6(5) . .
C12 C13 H13A 119.7 . .
C14 C13 H13A 119.7 . .
C15 C14 C13 121.2(6) . .
C15 C14 H14A 119.4 . .
C13 C14 H14A 119.4 . .
C14 C15 C16 118.7(5) . .
C14 C15 H15A 120.7 . .
C16 C15 H15A 120.7 . .
C15 C16 C17 119.7(5) . .
C15 C16 H16A 120.1 . .
C17 C16 H16A 120.1 . .
C12 C17 C16 122.2(5) . .
C12 C17 H17A 118.9 . .
C16 C17 H17A 118.9 . .
C12 C18 C19 117.7(4) . .
C12 C18 H18A 107.9 . .
C19 C18 H18A 107.9 . .
C12 C18 H18B 107.9 . .
C19 C18 H18B 107.9 . .
H18A C18 H18B 107.2 . .
N1 C19 C18 107.1(3) . .
N1 C19 C22 110.0(3) . .
C18 C19 C22 112.4(3) . .
N1 C19 H19A 109.1 . .
C18 C19 H19A 109.1 . .
C22 C19 H19A 109.1 . .
O2 C20 N1 123.5(4) . .
O2 C20 C21 122.5(4) . .
N1 C20 C21 114.0(5) . .
C20 C21 H21A 109.5 . .
C20 C21 H21B 109.5 . .
H21A C21 H21B 109.5 . .
C20 C21 H21C 109.5 . .
H21A C21 H21C 109.5 . .
H21B C21 H21C 109.5 . .
O6 C22 O5 126.4(4) 2_545 .
O6 C22 C19 119.2(4) 2_545 .
O5 C22 C19 114.4(4) . .
N4 C23 C24 123.5(4) . .
N4 C23 H23A 118.3 . .
C24 C23 H23A 118.3 . .
C23 C24 C25 119.2(4) . .
C23 C24 H24A 120.4 . .
C25 C24 H24A 120.4 . .
C26 C25 C24 117.6(3) . .
C26 C25 C30 120.8(4) . 1_455
C24 C25 C30 121.6(4) . 1_455
C25 C26 C27 119.4(4) . .
C25 C26 H26A 120.3 . .
C27 C26 H26A 120.3 . .
N4 C27 C26 123.4(4) . .
N4 C27 H27A 118.3 . .
C26 C27 H27A 118.3 . .
N3 C28 C29 123.3(4) . .
N3 C28 H28A 118.3 . .
C29 C28 H28A 118.3 . .
C28 C29 C30 119.8(4) . .
C28 C29 H29A 120.1 . .
C30 C29 H29A 120.1 . .
C29 C30 C31 116.6(3) . .
C29 C30 C25 123.2(4) . 1_655
C31 C30 C25 120.2(3) . 1_655
C32 C31 C30 119.9(4) . .
C32 C31 H31A 120.0 . .
C30 C31 H31A 120.0 . .
N3 C32 C31 123.9(4) . .
N3 C32 H32A 118.1 . .
C31 C32 H32A 118.1 . .
loop_
_geom_bond_atom_site_label_1
_geom_bond_atom_site_label_2
_geom_bond_distance
_geom_bond_site_symmetry_2
Zn1 O5 2.072(3) .
Zn1 O7 2.100(4) .
Zn1 O1 2.135(3) .
Zn1 N4 2.150(3) .
Zn1 N3 2.166(3) .
Zn1 O6 2.254(3) .
O1 C11 1.262(5) .
N1 C20 1.356(6) .
N1 C19 1.458(5) .
C1 C6 1.364(9) .
C1 C2 1.393(8) .
C1 H1A 0.9300 .
O2 C20 1.219(7) .
N2 C9 1.330(6) .
N2 C8 1.477(5) .
C2 C3 1.351(11) .
C2 H2A 0.9300 .
O3 C11 1.232(5) .
N3 C32 1.333(5) .
N3 C28 1.345(5) .
C3 C4 1.356(10) .
C3 H3A 0.9300 .
O4 C9 1.233(6) .
N4 C23 1.336(6) .
N4 C27 1.340(6) .
C4 C5 1.398(8) .
C4 H4A 0.9300 .
O5 C22 1.267(5) .
C5 C6 1.388(8) .
C5 H5A 0.9300 .
O6 C22 1.241(5) 2
C6 C7 1.511(6) .
O7 H7C 0.8200 .
O7 H7L 0.75(8) .
C7 C8 1.537(6) .
C7 H7A 0.9700 .
C7 H7B 0.9700 .
C8 C11 1.538(6) .
C8 H8A 0.9800 .
O8 H80A 0.9600 .
O8 H8B 0.9000 .
C9 C10 1.517(6) .
C10 H10A 0.9600 .
C10 H10B 0.9600 .
C10 H10C 0.9600 .
C12 C13 1.368(7) .
C12 C17 1.371(6) .
C12 C18 1.514(6) .
C13 C14 1.383(8) .
C13 H13A 0.9300 .
C14 C15 1.365(9) .
C14 H14A 0.9300 .
C15 C16 1.365(8) .
C15 H15A 0.9300 .
C16 C17 1.379(7) .
C16 H16A 0.9300 .
C17 H17A 0.9300 .
C18 C19 1.518(6) .
C18 H18A 0.9700 .
C18 H18B 0.9700 .
C19 C22 1.544(6) .
C19 H19A 0.9800 .
C20 C21 1.497(7) .
C21 H21A 0.9600 .
C21 H21B 0.9600 .
C21 H21C 0.9600 .
C22 O6 1.241(5) 2_545
C23 C24 1.386(5) .
C23 H23A 0.9300 .
C24 C25 1.395(7) .
C24 H24A 0.9300 .
C25 C26 1.381(7) .
C25 C30 1.497(4) 1_455
C26 C27 1.389(6) .
C26 H26A 0.9300 .
C27 H27A 0.9300 .
C28 C29 1.385(6) .
C28 H28A 0.9300 .
C29 C30 1.386(6) .
C29 H29A 0.9300 .
C30 C31 1.394(6) .
C30 C25 1.497(4) 1_655
C31 C32 1.376(6) .
C31 H31A 0.9300 .
C32 H32A 0.9300 .
loop_
_geom_torsion_atom_site_label_1
_geom_torsion_atom_site_label_2
_geom_torsion_atom_site_label_3
_geom_torsion_atom_site_label_4
_geom_torsion
_geom_torsion_site_symmetry_1
_geom_torsion_site_symmetry_4
O5 Zn1 O1 C11 123(2) . .
O7 Zn1 O1 C11 14.2(3) . .
N4 Zn1 O1 C11 107.2(4) . .
N3 Zn1 O1 C11 -77.9(4) . .
O6 Zn1 O1 C11 -163.9(3) . .
C6 C1 C2 C3 -2.4(9) . .
O5 Zn1 N3 C32 -149.4(4) . .
O7 Zn1 N3 C32 -53.4(4) . .
O1 Zn1 N3 C32 31.8(4) . .
N4 Zn1 N3 C32 145.0(14) . .
O6 Zn1 N3 C32 124.8(4) . .
O5 Zn1 N3 C28 30.2(4) . .
O7 Zn1 N3 C28 126.2(4) . .
O1 Zn1 N3 C28 -148.7(4) . .
N4 Zn1 N3 C28 -35.4(19) . .
O6 Zn1 N3 C28 -55.7(4) . .
C1 C2 C3 C4 1.7(11) . .
O5 Zn1 N4 C23 -52.2(4) . .
O7 Zn1 N4 C23 -148.3(4) . .
O1 Zn1 N4 C23 126.9(4) . .
N3 Zn1 N4 C23 13.3(19) . .
O6 Zn1 N4 C23 33.6(4) . .
O5 Zn1 N4 C27 122.0(4) . .
O7 Zn1 N4 C27 26.0(4) . .
O1 Zn1 N4 C27 -58.9(4) . .
N3 Zn1 N4 C27 -172.4(15) . .
O6 Zn1 N4 C27 -152.2(4) . .
C2 C3 C4 C5 0.9(12) . .
O7 Zn1 O5 C22 -18.6(3) . .
O1 Zn1 O5 C22 -127(2) . .
N4 Zn1 O5 C22 -111.3(3) . .
N3 Zn1 O5 C22 73.7(3) . .
O6 Zn1 O5 C22 159.6(3) . .
C3 C4 C5 C6 -2.8(10) . .
O5 Zn1 O6 C22 -177.3(5) . 2
O7 Zn1 O6 C22 -42(4) . 2
O1 Zn1 O6 C22 5.8(5) . 2
N4 Zn1 O6 C22 93.6(5) . 2
N3 Zn1 O6 C22 -88.3(5) . 2
C2 C1 C6 C5 0.5(7) . .
C2 C1 C6 C7 177.5(5) . .
C4 C5 C6 C1 2.1(8) . .
C4 C5 C6 C7 -174.9(5) . .
C1 C6 C7 C8 56.7(6) . .
C5 C6 C7 C8 -126.4(5) . .
C9 N2 C8 C7 96.4(5) . .
C9 N2 C8 C11 -140.4(4) . .
C6 C7 C8 N2 -175.0(4) . .
C6 C7 C8 C11 64.2(6) . .
C8 N2 C9 O4 4.4(7) . .
C8 N2 C9 C10 -175.8(4) . .
Zn1 O1 C11 O3 -5.1(6) . .
Zn1 O1 C11 C8 175.0(2) . .
N2 C8 C11 O3 -76.5(5) . .
C7 C8 C11 O3 44.6(5) . .
N2 C8 C11 O1 103.4(4) . .
C7 C8 C11 O1 -135.5(4) . .
C17 C12 C13 C14 -2.5(9) . .
C18 C12 C13 C14 171.8(6) . .
C12 C13 C14 C15 0.1(12) . .
C13 C14 C15 C16 1.8(11) . .
C14 C15 C16 C17 -1.3(10) . .
C13 C12 C17 C16 3.0(8) . .
C18 C12 C17 C16 -171.3(5) . .
C15 C16 C17 C12 -1.1(9) . .
C13 C12 C18 C19 97.4(6) . .
C17 C12 C18 C19 -88.5(6) . .
C20 N1 C19 C18 139.7(4) . .
C20 N1 C19 C22 -97.9(5) . .
C12 C18 C19 N1 -179.6(4) . .
C12 C18 C19 C22 59.5(5) . .
C19 N1 C20 O2 1.5(7) . .
C19 N1 C20 C21 -176.7(4) . .
Zn1 O5 C22 O6 14.9(5) . 2_545
Zn1 O5 C22 C19 -165.7(2) . .
N1 C19 C22 O6 -43.7(5) . 2_545
C18 C19 C22 O6 75.5(4) . 2_545
N1 C19 C22 O5 136.8(3) . .
C18 C19 C22 O5 -103.9(4) . .
C27 N4 C23 C24 0.5(7) . .
Zn1 N4 C23 C24 174.8(4) . .
N4 C23 C24 C25 -1.4(8) . .
C23 C24 C25 C26 1.7(7) . .
C23 C24 C25 C30 -179.8(4) . 1_455
C24 C25 C26 C27 -1.1(7) . .
C30 C25 C26 C27 -179.7(4) 1_455 .
C23 N4 C27 C26 0.1(7) . .
Zn1 N4 C27 C26 -174.6(4) . .
C25 C26 C27 N4 0.3(8) . .
C32 N3 C28 C29 -2.2(7) . .
Zn1 N3 C28 C29 178.3(3) . .
N3 C28 C29 C30 -0.1(7) . .
C28 C29 C30 C31 2.2(8) . .
C28 C29 C30 C25 -179.0(4) . 1_655
C29 C30 C31 C32 -2.1(8) . .
C25 C30 C31 C32 179.1(5) 1_655 .
C28 N3 C32 C31 2.3(8) . .
Zn1 N3 C32 C31 -178.1(4) . .
C30 C31 C32 N3 -0.2(8) . .
