#------------------------------------------------------------------------------
#$Date: 2016-09-15 17:27:05 +0300 (Thu, 15 Sep 2016) $
#$Revision: 186580 $
#$URL: file:///home/coder/svn-repositories/cod/cif/1/54/21/1542163.cif $
#------------------------------------------------------------------------------
#
# This file is available in the Crystallography Open Database (COD),
# http://www.crystallography.net/
#
# All data on this site have been placed in the public domain by the
# contributors.
#
data_1542163
loop_
_publ_author_name
'Prout, C.K.'
_publ_section_title
;
 The crystal structure of Di-mue-hydroxo-bis(tetramminedicobalt(III))
 chloride tetrahydrate
;
_journal_name_full               'Journal of the Chemical Society'
_journal_page_first              4429
_journal_page_last               4437
_journal_volume                  1962
_journal_year                    1962
_chemical_formula_sum            'Cl4 Co2 H34 N8 O6'
_chemical_name_systematic        '(N H3)4 Co (O H)2 Co (N H3)4 Cl4 (H2 O)4'
_space_group_IT_number           2
_symmetry_space_group_name_Hall  '-P 1'
_symmetry_space_group_name_H-M   'P -1'
_cell_angle_alpha                92.8
_cell_angle_beta                 106.3
_cell_angle_gamma                106.5
_cell_formula_units_Z            1
_cell_length_a                   6.72
_cell_length_b                   7.76
_cell_length_c                   10.06
_cell_volume                     478.046
_citation_journal_id_ASTM        JCSOA9
_cod_data_source_file            Prout_JCSOA9_1962_1665.cif
_cod_data_source_block           H34Cl4Co2N8O6
_cod_original_cell_volume        478.0456
_cod_original_formula_sum        'H34 Cl4 Co2 N8 O6'
_cod_database_code               1542163
loop_
_symmetry_equiv_pos_as_xyz
x,y,z
-x,-y,-z
loop_
_atom_site_label
_atom_site_type_symbol
_atom_site_fract_x
_atom_site_fract_y
_atom_site_fract_z
_atom_site_occupancy
_atom_site_U_iso_or_equiv
_atom_site_attached_hydrogens
O2 O-2 0.5954 0.3153 0.2495 1 0.0 2
N4 N-3 0.797 0.0029 0.2431 1 0.0 3
Cl1 Cl-1 0.35 0.6615 0.0568 1 0.0 0
N1 N-3 0.0942 0.2757 0.1723 1 0.0 3
O1 O-2 0.1978 0.0223 0.0314 1 0.0 2
Co1 Co+3 0.0139 0.0099 0.1484 1 0.0 0
O3 O-2 0.3336 0.6932 0.4024 1 0.0 2
N2 N-3 0.9273 0.7473 0.1433 1 0.0 3
Cl2 Cl-1 0.843 0.6918 0.4627 1 0.0 0
N3 N-3 0.2608 0.0339 0.3225 1 0.0 3
