#------------------------------------------------------------------------------
#$Date: 2016-05-05 04:29:29 +0300 (Thu, 05 May 2016) $
#$Revision: 182572 $
#$URL: svn://www.crystallography.net/cod/cif/1/54/32/1543255.cif $
#------------------------------------------------------------------------------
#
# This file is available in the Crystallography Open Database (COD),
# http://www.crystallography.net/. The original data for this entry
# were provided by IUCr Journals, http://journals.iucr.org/.
#
# The file may be used within the scientific community so long as
# proper attribution is given to the journal article from which the
# data were obtained.
#
data_1543255
loop_
_publ_author_name
'Bernès, Sylvain'
'Torrens, Hugo'
_publ_section_title
;
 Bis(pentafluorobenzenethiolato-κS){(pentafluorophenyl)phenyl[3,4,5,6-tetrafluoro-2-(pentafluorophenylsulfanyl)phenyl]phosphane-κ²P,S}platinum(II)
 dichloromethane hemisolvate
;
_journal_coeditor_code           FF4006
_journal_issue                   5
_journal_name_full               IUCrData
_journal_page_first              x160696
_journal_paper_doi               10.1107/S2414314616006969
_journal_volume                  1
_journal_year                    2016
_chemical_formula_iupac
'[Pt (C6 F5 S)2 (C24 H5 F14 P S)], 0.5C H2 Cl2'
_chemical_formula_moiety         'C36 H5 F24 P Pt S3, 0.5(C1 H2 Cl2)'
_chemical_formula_sum            'C36.5 H6 Cl F24 P Pt S3'
_chemical_formula_weight         1258.10
_chemical_name_systematic
'Bis(pentafluorobenzenethiolato-κS){(pentafluorophenyl)phenyl[3,4,5,6-tetrafluoro-2-(pentafluorophenylsulfanyl)phenyl]phosphane-κ²P,S}platinum(II) dichloromethane hemisolvate'
_space_group_crystal_system      triclinic
_space_group_IT_number           2
_space_group_name_Hall           '-P 1'
_space_group_name_H-M_alt        'P -1'
_symmetry_space_group_name_Hall  '-P 1'
_symmetry_space_group_name_H-M   'P -1'
_atom_sites_solution_hydrogens   geom
_atom_sites_solution_primary     direct
_atom_sites_solution_secondary   difmap
_audit_creation_method           SHELXL-2014/7
_cell_angle_alpha                104.477(8)
_cell_angle_beta                 96.359(8)
_cell_angle_gamma                111.675(7)
_cell_formula_units_Z            2
_cell_length_a                   11.2908(10)
_cell_length_b                   13.8516(14)
_cell_length_c                   14.6956(17)
_cell_measurement_reflns_used    75
_cell_measurement_temperature    296.0(10)
_cell_measurement_theta_max      12.51
_cell_measurement_theta_min      3.63
_cell_volume                     2014.6(4)
_computing_cell_refinement
;
XSCANS (Bruker, 1997)
;
_computing_data_collection
;
XSCANS (Bruker, 1997)
;
_computing_data_reduction
;
XSCANS (Bruker, 1997)
;
_computing_molecular_graphics
;
SHELXTL (Sheldrick, 2008)
;
_computing_publication_material
;
SHELXL2014 (Sheldrick, 2015)
;
_computing_structure_refinement
;
SHELXL2014 (Sheldrick, 2015)
;
_computing_structure_solution
;
SHELXS2013 (Sheldrick, 2008)
;
_diffrn_ambient_temperature      296.0(10)
_diffrn_measured_fraction_theta_full 1.000
_diffrn_measured_fraction_theta_max 0.980
_diffrn_measurement_device_type  'Bruker P4'
_diffrn_measurement_method       '2θ/ω scans'
_diffrn_radiation_monochromator  graphite
_diffrn_radiation_type           MoK\a
_diffrn_radiation_wavelength     0.71073
_diffrn_reflns_av_R_equivalents  0.0355
_diffrn_reflns_limit_h_max       8
_diffrn_reflns_limit_h_min       -14
_diffrn_reflns_limit_k_max       16
_diffrn_reflns_limit_k_min       -16
_diffrn_reflns_limit_l_max       19
_diffrn_reflns_limit_l_min       -19
_diffrn_reflns_number            15487
_diffrn_reflns_theta_full        25.242
_diffrn_reflns_theta_max         27.499
_diffrn_reflns_theta_min         1.842
_diffrn_standards_decay_%        1.5
_diffrn_standards_interval_count 97
_diffrn_standards_number         3
_exptl_absorpt_coefficient_mu    3.886
_exptl_absorpt_correction_T_max  0.897
_exptl_absorpt_correction_T_min  0.521
_exptl_absorpt_correction_type   psi-scan
_exptl_absorpt_process_details
;
(XSCANS; Bruker, 1997)
;
_exptl_crystal_colour            yellow
_exptl_crystal_density_diffrn    2.074
_exptl_crystal_description       plate
_exptl_crystal_F_000             1198
_exptl_crystal_size_max          0.65
_exptl_crystal_size_mid          0.40
_exptl_crystal_size_min          0.24
_refine_diff_density_max         0.986
_refine_diff_density_min         -0.736
_refine_ls_extinction_method     none
_refine_ls_goodness_of_fit_ref   1.023
_refine_ls_hydrogen_treatment    constr
_refine_ls_matrix_type           full
_refine_ls_number_constraints    0
_refine_ls_number_parameters     614
_refine_ls_number_reflns         9078
_refine_ls_number_restraints     0
_refine_ls_restrained_S_all      1.023
_refine_ls_R_factor_all          0.0521
_refine_ls_R_factor_gt           0.0368
_refine_ls_shift/su_max          0.002
_refine_ls_shift/su_mean         0.000
_refine_ls_structure_factor_coef Fsqd
_refine_ls_weighting_details
'w=1/[σ²(Fo²)+(0.0456P)²+0.2045P] where P=(Fo²+2Fc²)/3'
_refine_ls_weighting_scheme      calc
_refine_ls_wR_factor_gt          0.0824
_refine_ls_wR_factor_ref         0.0890
_reflns_number_gt                7392
_reflns_number_total             9078
_reflns_threshold_expression     'I > 2σ(I)'
_cod_data_source_file            ff4006sup1.cif
_cod_data_source_block           I
_cod_original_formula_sum        'C36.50 H6 Cl F24 P Pt S3'
_cod_database_code               1543255
loop_
_space_group_symop_operation_xyz
'x, y, z'
'-x, -y, -z'
loop_
_atom_site_type_symbol
_atom_site_label
_atom_site_fract_x
_atom_site_fract_y
_atom_site_fract_z
_atom_site_U_iso_or_equiv
_atom_site_adp_type
_atom_site_calc_flag
_atom_site_occupancy
Pt Pt1 0.65934(2) 0.65231(2) 0.20934(2) 0.04309(7) Uani d 1
P P1 0.66292(11) 0.81991(9) 0.24844(8) 0.0446(2) Uani d 1
S S1 0.67412(16) 0.65984(11) 0.36926(9) 0.0672(4) Uani d 1
S S2 0.64217(13) 0.47144(9) 0.15065(9) 0.0547(3) Uani d 1
S S3 0.64754(11) 0.64869(9) 0.05284(8) 0.0475(2) Uani d 1
C C1 0.5663(6) 0.5315(4) 0.3703(3) 0.0612(13) Uani d 1
C C2 0.6101(8) 0.4739(5) 0.4213(4) 0.0757(17) Uani d 1
F F2 0.7365(5) 0.5210(4) 0.4704(3) 0.1082(13) Uani d 1
C C3 0.5288(14) 0.3739(7) 0.4240(7) 0.127(4) Uani d 1
F F3 0.5813(10) 0.3252(5) 0.4758(6) 0.210(4) Uani d 1
C C4 0.4052(16) 0.3291(8) 0.3786(9) 0.157(7) Uani d 1
F F4 0.3278(10) 0.2290(5) 0.3779(6) 0.282(6) Uani d 1
C C5 0.3544(11) 0.3813(12) 0.3270(7) 0.165(7) Uani d 1
F F5 0.2305(6) 0.3384(8) 0.2828(4) 0.268(6) Uani d 1
C C6 0.4387(8) 0.4863(7) 0.3266(5) 0.101(2) Uani d 1
F F6 0.3857(4) 0.5362(7) 0.2785(4) 0.164(3) Uani d 1
C C7 0.7545(4) 0.4551(4) 0.2305(3) 0.0497(10) Uani d 1
C C8 0.8822(5) 0.5310(4) 0.2722(4) 0.0620(13) Uani d 1
F F8 0.9267(3) 0.6259(3) 0.2523(3) 0.0864(10) Uani d 1
C C9 0.9678(6) 0.5139(5) 0.3327(5) 0.0808(17) Uani d 1
F F9 1.0905(4) 0.5897(4) 0.3704(4) 0.1235(16) Uani d 1
C C10 0.9278(6) 0.4175(5) 0.3555(5) 0.0793(17) Uani d 1
F F10 1.0090(5) 0.3995(4) 0.4144(4) 0.1265(17) Uani d 1
C C11 0.8028(6) 0.3391(4) 0.3152(5) 0.0739(15) Uani d 1
F F11 0.7620(4) 0.2454(3) 0.3374(3) 0.1091(13) Uani d 1
C C12 0.7197(5) 0.3587(4) 0.2537(4) 0.0582(12) Uani d 1
F F12 0.5975(3) 0.2795(2) 0.2166(3) 0.0790(9) Uani d 1
C C13 0.7970(5) 0.6531(4) 0.0211(3) 0.0537(11) Uani d 1
C C14 0.7924(6) 0.5610(5) -0.0456(4) 0.0671(14) Uani d 1
F F14 0.6794(4) 0.4732(3) -0.0847(3) 0.0896(11) Uani d 1
C C15 0.9053(8) 0.5589(6) -0.0719(5) 0.092(2) Uani d 1
F F15 0.8988(6) 0.4678(4) -0.1353(4) 0.142(2) Uani d 1
C C16 1.0213(8) 0.6482(7) -0.0332(6) 0.096(2) Uani d 1
F F16 1.1287(5) 0.6446(5) -0.0603(4) 0.153(2) Uani d 1
C C17 1.0287(6) 0.7398(6) 0.0309(5) 0.0805(17) Uani d 1
F F17 1.1407(4) 0.8280(4) 0.0671(4) 0.1148(14) Uani d 1
C C18 0.9160(5) 0.7421(4) 0.0597(4) 0.0607(12) Uani d 1
F F18 0.9254(3) 0.8324(3) 0.1254(2) 0.0766(9) Uani d 1
C C19 0.6525(4) 0.7785(4) 0.0507(3) 0.0508(11) Uani d 1
C C20 0.6550(5) 0.8036(4) -0.0341(4) 0.0579(12) Uani d 1
F F20 0.6669(3) 0.7372(3) -0.1115(2) 0.0757(9) Uani d 1
C C21 0.6500(5) 0.8998(5) -0.0397(4) 0.0694(15) Uani d 1
F F21 0.6537(4) 0.9256(3) -0.1213(3) 0.0968(12) Uani d 1
C C22 0.6388(5) 0.9701(4) 0.0404(5) 0.0675(15) Uani d 1
F F22 0.6332(4) 1.0638(3) 0.0362(3) 0.0926(11) Uani d 1
C C23 0.6337(5) 0.9442(4) 0.1259(4) 0.0591(12) Uani d 1
F F23 0.6178(3) 1.0127(3) 0.1998(3) 0.0800(9) Uani d 1
C C24 0.6438(4) 0.8506(4) 0.1336(4) 0.0515(11) Uani d 1
C C25 0.5295(4) 0.8324(3) 0.3027(4) 0.0511(11) Uani d 1
C C26 0.4054(5) 0.7983(4) 0.2474(4) 0.0616(13) Uani d 1
F F26 0.3832(3) 0.7639(3) 0.1508(3) 0.0839(10) Uani d 1
C C27 0.3012(5) 0.7975(5) 0.2881(5) 0.0782(17) Uani d 1
F F27 0.1825(3) 0.7649(4) 0.2310(4) 0.1137(15) Uani d 1
C C28 0.3180(6) 0.8296(5) 0.3867(5) 0.0766(18) Uani d 1
F F28 0.2158(4) 0.8293(3) 0.4255(4) 0.1141(15) Uani d 1
C C29 0.4365(6) 0.8610(4) 0.4428(5) 0.0700(16) Uani d 1
F F29 0.4538(4) 0.8940(3) 0.5394(3) 0.0961(12) Uani d 1
C C30 0.5405(5) 0.8624(4) 0.4017(4) 0.0580(12) Uani d 1
F F30 0.6563(3) 0.8964(3) 0.4627(2) 0.0738(8) Uani d 1
C C31 0.8149(4) 0.9318(4) 0.3230(3) 0.0478(10) Uani d 1
C C32 0.8251(5) 1.0370(4) 0.3632(4) 0.0572(12) Uani d 1
H H32A 0.7514 1.0521 0.3567 0.069 Uiso calc 1
C C33 0.9454(5) 1.1192(4) 0.4130(4) 0.0663(14) Uani d 1
H H33A 0.9529 1.1900 0.4403 0.080 Uiso calc 1
C C34 1.0556(5) 1.0972(5) 0.4227(4) 0.0708(15) Uani d 1
H H34A 1.1370 1.1533 0.4551 0.085 Uiso calc 1
C C35 1.0437(5) 0.9921(5) 0.3841(4) 0.0688(14) Uani d 1
H H35A 1.1169 0.9766 0.3920 0.083 Uiso calc 1
C C36 0.9245(4) 0.9097(4) 0.3341(3) 0.0545(11) Uani d 1
H H36A 0.9174 0.8388 0.3077 0.065 Uiso calc 1
C C37 1.0152(16) 1.0944(13) 0.1602(11) 0.102(5) Uani d 0.5
H H37A 0.9769 1.0370 0.1884 0.123 Uiso calc 0.5
H H37B 1.1064 1.1356 0.1937 0.123 Uiso calc 0.5
Cl Cl1 0.9371(4) 1.1786(4) 0.1773(3) 0.1127(13) Uani d 0.5
Cl Cl2 1.0064(5) 1.0342(4) 0.0376(3) 0.1166(14) Uani d 0.5
loop_
_atom_type_symbol
_atom_type_description
_atom_type_scat_dispersion_real
_atom_type_scat_dispersion_imag
_atom_type_scat_source
C C 0.0033 0.0016 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
H H 0.0000 0.0000 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
F F 0.0171 0.0103 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
P P 0.1023 0.0942 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
S S 0.1246 0.1234 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
Cl Cl 0.1484 0.1585 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
Pt Pt -1.7033 8.3905 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
loop_
_diffrn_standard_refln_index_h
_diffrn_standard_refln_index_k
_diffrn_standard_refln_index_l
-2 1 1
1 1 -4
1 0 -3
loop_
_geom_angle_atom_site_label_1
_geom_angle_atom_site_label_2
_geom_angle_atom_site_label_3
_geom_angle_site_symmetry_1
_geom_angle
P1 Pt1 S3 . 89.63(4)
P1 Pt1 S1 . 89.40(5)
S3 Pt1 S1 . 178.81(4)
P1 Pt1 S2 . 173.59(4)
S3 Pt1 S2 . 84.72(4)
S1 Pt1 S2 . 96.28(5)
C31 P1 C25 . 107.8(2)
C31 P1 C24 . 104.1(2)
C25 P1 C24 . 106.7(2)
C31 P1 Pt1 . 116.75(15)
C25 P1 Pt1 . 114.57(15)
C24 P1 Pt1 . 105.86(15)
C1 S1 Pt1 . 106.76(17)
C7 S2 Pt1 . 108.35(15)
C13 S3 C19 . 102.4(2)
C13 S3 Pt1 . 109.13(17)
C19 S3 Pt1 . 105.85(16)
C6 C1 C2 . 117.3(7)
C6 C1 S1 . 122.4(6)
C2 C1 S1 . 120.2(5)
F2 C2 C3 . 120.0(8)
F2 C2 C1 . 118.2(5)
C3 C2 C1 . 121.8(9)
C4 C3 F3 . 122.7(11)
C4 C3 C2 . 120.3(11)
F3 C3 C2 . 117.0(12)
C3 C4 F4 . 119.8(17)
C3 C4 C5 . 121.3(10)
F4 C4 C5 . 118.8(16)
F5 C5 C4 . 121.9(14)
F5 C5 C6 . 120.0(16)
C4 C5 C6 . 118.1(11)
F6 C6 C1 . 122.2(8)
F6 C6 C5 . 116.7(10)
C1 C6 C5 . 121.1(10)
C12 C7 C8 . 114.9(5)
C12 C7 S2 . 120.0(4)
C8 C7 S2 . 125.0(4)
F8 C8 C9 . 117.2(5)
F8 C8 C7 . 119.6(5)
C9 C8 C7 . 123.2(5)
F9 C9 C8 . 120.7(6)
F9 C9 C10 . 119.4(6)
C8 C9 C10 . 119.9(5)
F10 C10 C11 . 119.8(6)
F10 C10 C9 . 120.9(6)
C11 C10 C9 . 119.3(5)
F11 C11 C10 . 120.0(5)
F11 C11 C12 . 120.7(6)
C10 C11 C12 . 119.2(5)
F12 C12 C11 . 117.0(5)
F12 C12 C7 . 119.5(5)
C11 C12 C7 . 123.5(5)
C18 C13 C14 . 118.5(5)
C18 C13 S3 . 124.0(4)
C14 C13 S3 . 117.4(4)
F14 C14 C13 . 120.5(5)
F14 C14 C15 . 119.4(5)
C13 C14 C15 . 120.1(6)
F15 C15 C16 . 120.9(6)
F15 C15 C14 . 119.0(7)
C16 C15 C14 . 120.1(6)
F16 C16 C17 . 119.7(8)
F16 C16 C15 . 119.1(7)
C17 C16 C15 . 121.2(6)
F17 C17 C16 . 121.5(6)
F17 C17 C18 . 119.3(6)
C16 C17 C18 . 119.2(6)
F18 C18 C13 . 120.6(4)
F18 C18 C17 . 118.6(5)
C13 C18 C17 . 120.8(5)
C20 C19 C24 . 120.5(5)
C20 C19 S3 . 119.5(4)
C24 C19 S3 . 119.8(4)
F20 C20 C19 . 120.6(5)
F20 C20 C21 . 118.5(5)
C19 C20 C21 . 120.9(5)
F21 C21 C20 . 121.5(6)
F21 C21 C22 . 119.4(5)
C20 C21 C22 . 119.1(5)
F22 C22 C21 . 120.0(5)
F22 C22 C23 . 119.8(6)
C21 C22 C23 . 120.2(5)
F23 C23 C24 . 121.0(5)
F23 C23 C22 . 117.8(5)
C24 C23 C22 . 121.2(5)
C23 C24 C19 . 117.9(5)
C23 C24 P1 . 124.1(4)
C19 C24 P1 . 117.7(3)
C26 C25 C30 . 115.4(4)
C26 C25 P1 . 121.6(4)
C30 C25 P1 . 122.4(4)
F26 C26 C27 . 117.7(5)
F26 C26 C25 . 120.2(4)
C27 C26 C25 . 122.1(5)
F27 C27 C26 . 119.8(6)
F27 C27 C28 . 120.1(5)
C26 C27 C28 . 120.1(6)
F28 C28 C29 . 121.0(7)
F28 C28 C27 . 119.5(6)
C29 C28 C27 . 119.5(5)
C28 C29 F29 . 119.7(5)
C28 C29 C30 . 120.1(6)
F29 C29 C30 . 120.1(6)
F30 C30 C29 . 116.6(5)
F30 C30 C25 . 120.7(4)
C29 C30 C25 . 122.7(5)
C36 C31 C32 . 120.0(4)
C36 C31 P1 . 117.3(3)
C32 C31 P1 . 122.6(4)
C33 C32 C31 . 119.3(5)
C33 C32 H32A . 120.3
C31 C32 H32A . 120.3
C32 C33 C34 . 120.6(5)
C32 C33 H33A . 119.7
C34 C33 H33A . 119.7
C35 C34 C33 . 119.5(5)
C35 C34 H34A . 120.2
C33 C34 H34A . 120.2
C36 C35 C34 . 120.4(5)
C36 C35 H35A . 119.8
C34 C35 H35A . 119.8
C35 C36 C31 . 120.1(5)
C35 C36 H36A . 119.9
C31 C36 H36A . 119.9
Cl1 C37 Cl2 . 112.9(9)
Cl1 C37 H37A . 109.0
Cl2 C37 H37A . 109.0
Cl1 C37 H37B . 109.0
Cl2 C37 H37B . 109.0
H37A C37 H37B . 107.8
Cl2 Cl2 C37 2_775 160.4(8)
loop_
_geom_bond_atom_site_label_1
_geom_bond_atom_site_label_2
_geom_bond_site_symmetry_2
_geom_bond_distance
Pt1 P1 . 2.2315(11)
Pt1 S3 . 2.2757(12)
Pt1 S1 . 2.3107(13)
Pt1 S2 . 2.3627(12)
P1 C31 . 1.821(5)
P1 C25 . 1.823(5)
P1 C24 . 1.851(5)
S1 C1 . 1.750(6)
S2 C7 . 1.747(5)
S3 C13 . 1.784(5)
S3 C19 . 1.787(5)
C1 C6 . 1.344(9)
C1 C2 . 1.396(8)
C2 F2 . 1.353(8)
C2 C3 . 1.364(10)
C3 C4 . 1.314(18)
C3 F3 . 1.356(13)
C4 F4 . 1.335(11)
C4 C5 . 1.38(2)
C5 F5 . 1.313(13)
C5 C6 . 1.416(15)
C6 F6 . 1.338(11)
C7 C12 . 1.387(7)
C7 C8 . 1.386(7)
C8 F8 . 1.343(6)
C8 C9 . 1.366(8)
C9 F9 . 1.339(7)
C9 C10 . 1.383(9)
C10 F10 . 1.324(7)
C10 C11 . 1.372(8)
C11 F11 . 1.344(6)
C11 C12 . 1.377(8)
C12 F12 . 1.349(6)
C13 C18 . 1.380(7)
C13 C14 . 1.380(7)
C14 F14 . 1.334(7)
C14 C15 . 1.381(9)
C15 F15 . 1.339(8)
C15 C16 . 1.362(11)
C16 F16 . 1.332(7)
C16 C17 . 1.346(10)
C17 F17 . 1.327(8)
C17 C18 . 1.392(7)
C18 F18 . 1.336(6)
C19 C20 . 1.375(7)
C19 C24 . 1.407(7)
C20 F20 . 1.327(6)
C20 C21 . 1.376(8)
C21 F21 . 1.335(6)
C21 C22 . 1.379(8)
C22 F22 . 1.339(6)
C22 C23 . 1.391(8)
C23 F23 . 1.330(6)
C23 C24 . 1.373(7)
C25 C26 . 1.384(7)
C25 C30 . 1.387(7)
C26 F26 . 1.341(6)
C26 C27 . 1.376(7)
C27 F27 . 1.348(7)
C27 C28 . 1.374(10)
C28 F28 . 1.341(6)
C28 C29 . 1.343(9)
C29 F29 . 1.345(7)
C29 C30 . 1.376(7)
C30 F30 . 1.344(6)
C31 C36 . 1.383(6)
C31 C32 . 1.385(6)
C32 C33 . 1.377(7)
C32 H32A . 0.9300
C33 C34 . 1.386(8)
C33 H33A . 0.9300
C34 C35 . 1.374(8)
C34 H34A . 0.9300
C35 C36 . 1.371(7)
C35 H35A . 0.9300
C36 H36A . 0.9300
C37 Cl1 . 1.692(17)
C37 Cl2 . 1.760(15)
C37 H37A . 0.9700
C37 H37B . 0.9700
Cl2 Cl2 2_775 1.217(9)
loop_
_geom_torsion_atom_site_label_1
_geom_torsion_atom_site_label_2
_geom_torsion_atom_site_label_3
_geom_torsion_atom_site_label_4
_geom_torsion_site_symmetry_4
_geom_torsion
Pt1 S1 C1 C6 . -55.3(5)
Pt1 S1 C1 C2 . 127.6(4)
C6 C1 C2 F2 . -176.2(5)
S1 C1 C2 F2 . 1.1(7)
C6 C1 C2 C3 . 2.5(8)
S1 C1 C2 C3 . 179.8(5)
F2 C2 C3 C4 . 178.2(7)
C1 C2 C3 C4 . -0.5(11)
F2 C2 C3 F3 . -1.2(9)
C1 C2 C3 F3 . -179.9(5)
F3 C3 C4 F4 . -3.8(14)
C2 C3 C4 F4 . 176.9(7)
F3 C3 C4 C5 . 179.5(8)
C2 C3 C4 C5 . 0.1(15)
C3 C4 C5 F5 . -178.6(8)
F4 C4 C5 F5 . 4.6(16)
C3 C4 C5 C6 . -1.8(16)
F4 C4 C5 C6 . -178.5(7)
C2 C1 C6 F6 . 177.9(6)
S1 C1 C6 F6 . 0.6(9)
C2 C1 C6 C5 . -4.1(9)
S1 C1 C6 C5 . 178.6(6)
F5 C5 C6 F6 . -1.1(12)
C4 C5 C6 F6 . -178.0(8)
F5 C5 C6 C1 . -179.2(7)
C4 C5 C6 C1 . 3.9(13)
Pt1 S2 C7 C12 . 139.5(4)
Pt1 S2 C7 C8 . -42.9(4)
C12 C7 C8 F8 . 178.2(4)
S2 C7 C8 F8 . 0.5(7)
C12 C7 C8 C9 . -0.8(8)
S2 C7 C8 C9 . -178.5(5)
F8 C8 C9 F9 . 0.4(9)
C7 C8 C9 F9 . 179.4(6)
F8 C8 C9 C10 . -179.7(6)
C7 C8 C9 C10 . -0.7(10)
F9 C9 C10 F10 . 0.3(11)
C8 C9 C10 F10 . -179.6(6)
F9 C9 C10 C11 . -178.7(6)
C8 C9 C10 C11 . 1.4(10)
F10 C10 C11 F11 . 1.7(10)
C9 C10 C11 F11 . -179.4(6)
F10 C10 C11 C12 . -179.6(6)
C9 C10 C11 C12 . -0.7(10)
F11 C11 C12 F12 . -0.7(8)
C10 C11 C12 F12 . -179.4(5)
F11 C11 C12 C7 . 177.8(5)
C10 C11 C12 C7 . -0.9(9)
C8 C7 C12 F12 . -179.9(4)
S2 C7 C12 F12 . -2.1(6)
C8 C7 C12 C11 . 1.5(8)
S2 C7 C12 C11 . 179.4(4)
C19 S3 C13 C18 . 45.1(5)
Pt1 S3 C13 C18 . -66.8(5)
C19 S3 C13 C14 . -135.4(4)
Pt1 S3 C13 C14 . 112.7(4)
C18 C13 C14 F14 . 180.0(5)
S3 C13 C14 F14 . 0.5(7)
C18 C13 C14 C15 . 0.6(8)
S3 C13 C14 C15 . -178.9(5)
F14 C14 C15 F15 . -0.8(10)
C13 C14 C15 F15 . 178.6(6)
F14 C14 C15 C16 . 179.5(6)
C13 C14 C15 C16 . -1.1(11)
F15 C15 C16 F16 . 0.9(12)
C14 C15 C16 F16 . -179.4(7)
F15 C15 C16 C17 . -179.7(7)
C14 C15 C16 C17 . 0.0(12)
F16 C16 C17 F17 . 1.1(12)
C15 C16 C17 F17 . -178.3(7)
F16 C16 C17 C18 . -179.1(6)
C15 C16 C17 C18 . 1.5(12)
C14 C13 C18 F18 . -179.2(5)
S3 C13 C18 F18 . 0.3(8)
C14 C13 C18 C17 . 1.0(8)
S3 C13 C18 C17 . -179.5(5)
F17 C17 C18 F18 . -2.0(9)
C16 C17 C18 F18 . 178.1(6)
F17 C17 C18 C13 . 177.8(5)
C16 C17 C18 C13 . -2.0(10)
C13 S3 C19 C20 . 61.7(4)
Pt1 S3 C19 C20 . 176.0(4)
C13 S3 C19 C24 . -123.0(4)
Pt1 S3 C19 C24 . -8.7(4)
C24 C19 C20 F20 . 178.1(4)
S3 C19 C20 F20 . -6.7(7)
C24 C19 C20 C21 . 0.4(8)
S3 C19 C20 C21 . 175.6(4)
F20 C20 C21 F21 . 1.6(8)
C19 C20 C21 F21 . 179.4(5)
F20 C20 C21 C22 . -179.5(5)
C19 C20 C21 C22 . -1.8(8)
F21 C21 C22 F22 . -0.8(8)
C20 C21 C22 F22 . -179.7(5)
F21 C21 C22 C23 . 179.5(5)
C20 C21 C22 C23 . 0.6(8)
F22 C22 C23 F23 . 2.8(7)
C21 C22 C23 F23 . -177.5(5)
F22 C22 C23 C24 . -177.7(4)
C21 C22 C23 C24 . 2.0(8)
F23 C23 C24 C19 . 176.2(4)
C22 C23 C24 C19 . -3.3(7)
F23 C23 C24 P1 . -10.0(7)
C22 C23 C24 P1 . 170.5(4)
C20 C19 C24 C23 . 2.1(7)
S3 C19 C24 C23 . -173.1(4)
C20 C19 C24 P1 . -172.1(4)
S3 C19 C24 P1 . 12.7(5)
C31 P1 C24 C23 . -60.2(4)
C25 P1 C24 C23 . 53.7(5)
Pt1 P1 C24 C23 . 176.2(4)
C31 P1 C24 C19 . 113.6(4)
C25 P1 C24 C19 . -132.5(4)
Pt1 P1 C24 C19 . -10.0(4)
C31 P1 C25 C26 . 149.1(4)
C24 P1 C25 C26 . 37.7(5)
Pt1 P1 C25 C26 . -79.1(4)
C31 P1 C25 C30 . -39.8(5)
C24 P1 C25 C30 . -151.1(4)
Pt1 P1 C25 C30 . 92.0(4)
C30 C25 C26 F26 . -177.6(5)
P1 C25 C26 F26 . -6.0(7)
C30 C25 C26 C27 . 1.9(8)
P1 C25 C26 C27 . 173.6(4)
F26 C26 C27 F27 . -1.3(8)
C25 C26 C27 F27 . 179.1(5)
F26 C26 C27 C28 . 178.5(5)
C25 C26 C27 C28 . -1.0(9)
F27 C27 C28 F28 . -0.7(9)
C26 C27 C28 F28 . 179.4(5)
F27 C27 C28 C29 . 179.4(6)
C26 C27 C28 C29 . -0.4(9)
F28 C28 C29 F29 . -0.8(8)
C27 C28 C29 F29 . 179.0(5)
F28 C28 C29 C30 . -179.0(5)
C27 C28 C29 C30 . 0.8(9)
C28 C29 C30 F30 . 179.0(5)
F29 C29 C30 F30 . 0.8(7)
C28 C29 C30 C25 . 0.2(8)
F29 C29 C30 C25 . -178.1(4)
C26 C25 C30 F30 . 179.7(4)
P1 C25 C30 F30 . 8.1(7)
C26 C25 C30 C29 . -1.5(7)
P1 C25 C30 C29 . -173.1(4)
C25 P1 C31 C36 . 143.3(4)
C24 P1 C31 C36 . -103.6(4)
Pt1 P1 C31 C36 . 12.6(4)
C25 P1 C31 C32 . -40.3(5)
C24 P1 C31 C32 . 72.8(4)
Pt1 P1 C31 C32 . -171.0(3)
C36 C31 C32 C33 . 1.0(7)
P1 C31 C32 C33 . -175.3(4)
C31 C32 C33 C34 . 0.1(8)
C32 C33 C34 C35 . -1.4(9)
C33 C34 C35 C36 . 1.7(9)
C34 C35 C36 C31 . -0.6(8)
C32 C31 C36 C35 . -0.7(7)
P1 C31 C36 C35 . 175.8(4)
Cl1 C37 Cl2 Cl2 2_775 -137(2)

_cod_database_fobs_code 1543255
