#------------------------------------------------------------------------------
#$Date: 2017-05-06 01:16:50 +0300 (Sat, 06 May 2017) $
#$Revision: 196475 $
#$URL: file:///home/coder/svn-repositories/cod/cif/1/54/56/1545609.cif $
#------------------------------------------------------------------------------
#
# This file is available in the Crystallography Open Database (COD),
# http://www.crystallography.net/
#
# All data on this site have been placed in the public domain by the
# contributors.
#
data_1545609
loop_
_publ_author_name
'Li, Xiao-Yu'
'Su, Hai-Feng'
'Kurmoo, Mohamedally'
'Tung, Chen-Ho'
'Sun, Di'
'Zheng, Lan-Sun'
_publ_section_title
;
 Structure, solution assembly, and electroconductivity of nanosized
 argento-organic-cluster/framework templated by chromate.
;
_journal_issue                   16
_journal_name_full               Nanoscale
_journal_page_first              5305
_journal_page_last               5314
_journal_paper_doi               10.1039/c7nr00732a
_journal_volume                  9
_journal_year                    2017
_chemical_formula_sum            'C50 H98 Ag20 Cr5 F12 N4 O30 S10'
_chemical_formula_weight         4201.32
_chemical_name_systematic
; 
 ? 
;
_space_group_crystal_system      hexagonal
_space_group_IT_number           171
_space_group_name_Hall           'P 62'
_space_group_name_H-M_alt        'P 62'
_symmetry_space_group_name_Hall  'P 62'
_symmetry_space_group_name_H-M   'P 62'
_atom_sites_solution_hydrogens   geom
_atom_sites_solution_primary     direct
_atom_sites_solution_secondary   difmap
_audit_creation_method           SHELXL-97
_audit_update_record
;
2017-03-04 deposited with the CCDC.
2017-03-20 downloaded from the CCDC.
;
_cell_angle_alpha                90.00
_cell_angle_beta                 90.00
_cell_angle_gamma                120.00
_cell_formula_units_Z            3
_cell_length_a                   17.5994(5)
_cell_length_b                   17.5994(5)
_cell_length_c                   29.2422(9)
_cell_measurement_reflns_used    9952
_cell_measurement_temperature    173(2)
_cell_measurement_theta_max      54.921
_cell_measurement_theta_min      4.961
_cell_volume                     7844.0(4)
_computing_structure_refinement  'SHELXL-97 (Sheldrick, 1997)'
_computing_structure_solution    'SHELXS-97 (Sheldrick, 1990)'
_diffrn_ambient_temperature      173(2)
_diffrn_measured_fraction_theta_full 0.993
_diffrn_measured_fraction_theta_max 0.993
_diffrn_measurement_device_type  'Bruker APEX-II CCD'
_diffrn_measurement_method       'φ and ω scans'
_diffrn_radiation_monochromator  graphite
_diffrn_radiation_source         'fine-focus sealed tube'
_diffrn_radiation_type           MoK\a
_diffrn_radiation_wavelength     0.71073
_diffrn_reflns_av_R_equivalents  0.0444
_diffrn_reflns_av_sigmaI/netI    0.0678
_diffrn_reflns_limit_h_max       21
_diffrn_reflns_limit_h_min       -17
_diffrn_reflns_limit_k_max       18
_diffrn_reflns_limit_k_min       -22
_diffrn_reflns_limit_l_max       37
_diffrn_reflns_limit_l_min       -28
_diffrn_reflns_number            29051
_diffrn_reflns_theta_full        27.51
_diffrn_reflns_theta_max         27.51
_diffrn_reflns_theta_min         2.48
_exptl_absorpt_coefficient_mu    4.426
_exptl_absorpt_correction_T_max  0.8090
_exptl_absorpt_correction_T_min  0.7184
_exptl_absorpt_correction_type   multi-scan
_exptl_absorpt_process_details   sadabs
_exptl_crystal_colour            red
_exptl_crystal_density_diffrn    2.668
_exptl_crystal_density_method    'not measured'
_exptl_crystal_description       block
_exptl_crystal_F_000             5982
_exptl_crystal_size_max          0.08
_exptl_crystal_size_mid          0.05
_exptl_crystal_size_min          0.05
_refine_diff_density_max         1.317
_refine_diff_density_min         -1.313
_refine_diff_density_rms         0.236
_refine_ls_abs_structure_details 'Flack H D (1983), Acta Cryst. A39, 876-881'
_refine_ls_abs_structure_Flack   0.01(3)
_refine_ls_extinction_method     none
_refine_ls_goodness_of_fit_ref   1.102
_refine_ls_hydrogen_treatment    mixed
_refine_ls_matrix_type           full
_refine_ls_number_parameters     606
_refine_ls_number_reflns         10170
_refine_ls_number_restraints     19
_refine_ls_restrained_S_all      1.102
_refine_ls_R_factor_all          0.0635
_refine_ls_R_factor_gt           0.0430
_refine_ls_shift/su_max          0.001
_refine_ls_shift/su_mean         0.000
_refine_ls_structure_factor_coef Fsqd
_refine_ls_weighting_details
'calc w=1/[σ²(Fo²)+(0.0000P)²+36.2377P] where P=(Fo²+2Fc²)/3'
_refine_ls_weighting_scheme      calc
_refine_ls_wR_factor_gt          0.0621
_refine_ls_wR_factor_ref         0.0689
_reflns_number_gt                8545
_reflns_number_total             10170
_reflns_threshold_expression     >2sigma(I)
_cod_data_source_file            c7nr00732a2.cif
_cod_data_source_block           p62
_cod_depositor_comments
'Adding full bibliography for 1545608--1545612.cif.'
_cod_database_code               1545609
loop_
_symmetry_equiv_pos_as_xyz
'x, y, z'
'-y, x-y, z+2/3'
'-x+y, -x, z+1/3'
'-x, -y, z'
'y, -x+y, z+2/3'
'x-y, x, z+1/3'
loop_
_atom_site_label
_atom_site_type_symbol
_atom_site_fract_x
_atom_site_fract_y
_atom_site_fract_z
_atom_site_U_iso_or_equiv
_atom_site_adp_type
_atom_site_occupancy
_atom_site_symmetry_multiplicity
_atom_site_calc_flag
_atom_site_refinement_flags
Ag1 Ag 0.97077(5) 0.65058(5) 0.35777(2) 0.01804(16) Uani 1 1 d .
Ag2 Ag 0.78696(5) 0.55388(5) 0.32862(2) 0.01871(17) Uani 1 1 d .
Ag3 Ag 0.76149(5) 0.42854(5) 0.24879(3) 0.02248(18) Uani 1 1 d .
Ag4 Ag 1.20126(5) 0.71539(5) 0.20743(2) 0.01888(17) Uani 1 1 d .
Ag5 Ag 1.07495(5) 0.77691(5) 0.22265(2) 0.01843(16) Uani 1 1 d .
Ag6 Ag 0.90304(5) 0.71012(5) 0.27586(3) 0.02044(17) Uani 1 1 d .
Ag7 Ag 1.17053(5) 0.74866(5) 0.30377(2) 0.01964(17) Uani 1 1 d .
Ag8 Ag 0.75111(5) 0.36837(5) 0.35141(2) 0.02184(17) Uani 1 1 d .
Ag9 Ag 1.0000 0.5000 0.38913(4) 0.0216(2) Uani 1 2 d S
Ag10 Ag 1.0000 0.5000 0.16135(4) 0.0216(2) Uani 1 2 d S
Ag11 Ag 0.91212(5) 0.62050(5) 0.18893(2) 0.01929(16) Uani 1 1 d .
S1 S 0.86269(15) 0.50464(15) 0.38904(8) 0.0154(5) Uani 1 1 d .
S2 S 0.78656(15) 0.57543(15) 0.24086(8) 0.0150(5) Uani 1 1 d .
S3 S 1.28104(15) 0.71389(15) 0.28005(8) 0.0157(5) Uani 1 1 d .
S4 S 0.93898(15) 0.33881(15) 0.16553(8) 0.0159(5) Uani 1 1 d .
S5 S 1.05161(16) 0.77988(15) 0.30854(8) 0.0156(5) Uani 1 1 d .
Cr1 Cr 1.0000 0.5000 0.27598(8) 0.0136(4) Uani 1 2 d S
Cr2 Cr 1.17149(10) 0.75782(10) 0.43165(5) 0.0206(4) Uani 1 1 d .
Cr3 Cr 1.33857(11) 0.74780(11) 0.45618(5) 0.0237(4) Uani 1 1 d .
C1 C 0.9398(6) 0.8675(6) 0.1867(4) 0.024(2) Uani 1 1 d .
H1 H 0.9466 0.8550 0.1566 0.029 Uiso 1 1 calc R
C2 C 0.8599(8) 0.9341(8) 0.1557(4) 0.036(3) Uani 1 1 d .
H2A H 0.8790 0.9220 0.1273 0.055 Uiso 1 1 calc R
H2B H 0.8803 0.9958 0.1579 0.055 Uiso 1 1 calc R
H2C H 0.7970 0.9019 0.1571 0.055 Uiso 1 1 calc R
C3 C 0.8772(7) 0.9267(7) 0.2392(3) 0.028(3) Uani 1 1 d .
H3A H 0.8993 0.9025 0.2615 0.042 Uiso 1 1 calc R
H3B H 0.8150 0.9012 0.2431 0.042 Uiso 1 1 calc R
H3C H 0.9052 0.9891 0.2434 0.042 Uiso 1 1 calc R
C4 C 0.4994(13) 0.3885(14) 0.4421(6) 0.127(9) Uani 1 1 d .
H4A H 0.4691 0.3261 0.4466 0.191 Uiso 1 1 calc R
H4B H 0.4599 0.4102 0.4478 0.191 Uiso 1 1 calc R
H4C H 0.5481 0.4159 0.4628 0.191 Uiso 1 1 calc R
C5 C 0.4588(11) 0.3720(15) 0.3587(7) 0.116(8) Uani 1 1 d .
H5A H 0.4858 0.3952 0.3297 0.173 Uiso 1 1 calc R
H5B H 0.4162 0.3894 0.3651 0.173 Uiso 1 1 calc R
H5C H 0.4304 0.3091 0.3580 0.173 Uiso 1 1 calc R
C6 C 0.6120(9) 0.4396(8) 0.3866(5) 0.043(3) Uani 1 1 d .
H6 H 0.6520 0.4588 0.4106 0.051 Uiso 1 1 calc R
C7 C 1.2700(6) 0.9240(6) 0.2035(4) 0.023(2) Uani 1 1 d .
C8 C 1.3447(8) 1.0175(8) 0.2069(5) 0.041(3) Uani 1 1 d .
C9 C 0.7949(7) 0.7383(7) 0.3506(4) 0.027(2) Uani 1 1 d .
C10 C 0.7702(8) 0.7976(8) 0.3799(4) 0.034(3) Uani 1 1 d .
C11 C 0.9179(7) 0.2889(7) 0.1080(3) 0.026(2) Uani 1 1 d .
H11 H 0.8548 0.2600 0.1018 0.032 Uiso 1 1 calc R
C12 C 0.9656(8) 0.3594(8) 0.0725(3) 0.036(3) Uani 1 1 d .
H12A H 0.9463 0.4016 0.0742 0.054 Uiso 1 1 calc R
H12B H 0.9532 0.3334 0.0426 0.054 Uiso 1 1 calc R
H12C H 1.0276 0.3880 0.0781 0.054 Uiso 1 1 calc R
C13 C 0.9456(8) 0.2208(8) 0.1074(4) 0.047(3) Uani 1 1 d .
H13A H 1.0068 0.2479 0.1149 0.071 Uiso 1 1 calc R
H13B H 0.9360 0.1952 0.0774 0.071 Uiso 1 1 calc R
H13C H 0.9118 0.1760 0.1294 0.071 Uiso 1 1 calc R
C14 C 1.3965(6) 0.8022(6) 0.2765(4) 0.023(2) Uani 1 1 d U
H14 H 1.4058 0.8329 0.2473 0.028 Uiso 1 1 calc R
C15 C 1.4542(9) 0.7623(10) 0.2783(8) 0.106(8) Uani 1 1 d U
H15A H 1.4360 0.7210 0.3030 0.159 Uiso 1 1 calc R
H15B H 1.5139 0.8077 0.2830 0.159 Uiso 1 1 calc R
H15C H 1.4497 0.7328 0.2500 0.159 Uiso 1 1 calc R
C16 C 1.4147(8) 0.8662(8) 0.3148(4) 0.054(4) Uani 1 1 d U
H16A H 1.3741 0.8874 0.3132 0.082 Uiso 1 1 calc R
H16B H 1.4735 0.9146 0.3121 0.082 Uiso 1 1 calc R
H16C H 1.4082 0.8374 0.3436 0.082 Uiso 1 1 calc R
C17 C 0.8901(7) 0.5023(7) 0.4820(3) 0.023(2) Uani 1 1 d .
H17A H 0.8877 0.4479 0.4748 0.034 Uiso 1 1 calc R
H17B H 0.8681 0.4994 0.5124 0.034 Uiso 1 1 calc R
H17C H 0.9497 0.5495 0.4802 0.034 Uiso 1 1 calc R
C18 C 0.8403(7) 0.6061(6) 0.4544(3) 0.026(2) Uani 1 1 d .
H18A H 0.9007 0.6516 0.4526 0.038 Uiso 1 1 calc R
H18B H 0.8171 0.6080 0.4838 0.038 Uiso 1 1 calc R
H18C H 0.8074 0.6148 0.4309 0.038 Uiso 1 1 calc R
C19 C 0.8339(6) 0.5184(6) 0.4479(3) 0.018(2) Uani 1 1 d .
H19 H 0.7727 0.4732 0.4531 0.022 Uiso 1 1 calc R
C20 C 0.6953(6) 0.5941(7) 0.2226(3) 0.023(2) Uani 1 1 d .
H20 H 0.6731 0.5639 0.1934 0.028 Uiso 1 1 calc R
C21 C 0.6216(7) 0.5508(7) 0.2570(4) 0.035(3) Uani 1 1 d .
H21A H 0.6043 0.4899 0.2599 0.052 Uiso 1 1 calc R
H21B H 0.5724 0.5558 0.2468 0.052 Uiso 1 1 calc R
H21C H 0.6411 0.5792 0.2861 0.052 Uiso 1 1 calc R
C22 C 0.7280(7) 0.6877(7) 0.2149(4) 0.033(3) Uani 1 1 d .
H22A H 0.7568 0.7201 0.2420 0.049 Uiso 1 1 calc R
H22B H 0.6797 0.6965 0.2077 0.049 Uiso 1 1 calc R
H22C H 0.7688 0.7079 0.1899 0.049 Uiso 1 1 calc R
C23 C 1.0806(7) 0.8894(6) 0.3294(3) 0.023(2) Uani 1 1 d .
H23 H 1.0500 0.9111 0.3101 0.028 Uiso 1 1 calc R
C24 C 1.0484(7) 0.8844(7) 0.3781(4) 0.030(3) Uani 1 1 d .
H24A H 0.9857 0.8474 0.3790 0.045 Uiso 1 1 calc R
H24B H 1.0639 0.9422 0.3884 0.045 Uiso 1 1 calc R
H24C H 1.0751 0.8606 0.3977 0.045 Uiso 1 1 calc R
C25 C 1.1771(7) 0.9506(6) 0.3235(4) 0.027(3) Uani 1 1 d .
H25A H 1.2089 0.9327 0.3432 0.041 Uiso 1 1 calc R
H25B H 1.1909 1.0091 0.3313 0.041 Uiso 1 1 calc R
H25C H 1.1932 0.9492 0.2923 0.041 Uiso 1 1 calc R
O1 O 0.9547(4) 0.4119(4) 0.3090(2) 0.0214(16) Uani 1 1 d .
O2 O 0.9238(4) 0.4999(5) 0.2433(2) 0.0264(17) Uani 1 1 d .
O3 O 1.0693(4) 0.6845(4) 0.4253(2) 0.0235(16) Uani 1 1 d .
O4 O 1.1813(5) 0.8392(4) 0.4613(2) 0.0325(19) Uani 1 1 d .
O5 O 1.2184(4) 0.7916(5) 0.3825(2) 0.0322(19) Uani 1 1 d .
O6 O 1.2242(4) 0.7085(4) 0.4618(2) 0.0251(17) Uani 1 1 d .
O7 O 1.3895(5) 0.8530(5) 0.4546(3) 0.043(2) Uani 1 1 d .
O8 O 1.3702(5) 0.7137(5) 0.4997(2) 0.0322(18) Uani 1 1 d .
O9 O 1.3543(5) 0.7078(5) 0.4095(2) 0.040(2) Uani 1 1 d .
O10 O 0.8457(5) 0.7796(5) 0.3205(3) 0.0331(19) Uani 1 1 d .
O11 O 0.7561(5) 0.6590(5) 0.3611(3) 0.0355(19) Uani 1 1 d .
O12 O 0.6410(5) 0.4465(6) 0.3480(3) 0.048(2) Uani 1 1 d .
O13 O 1.2944(5) 0.8693(5) 0.1979(3) 0.0350(19) Uani 1 1 d .
O14 O 1.1956(5) 0.9147(4) 0.2059(2) 0.0270(17) Uani 1 1 d .
O15 O 0.9737(4) 0.8444(4) 0.2169(2) 0.0247(16) Uani 1 1 d .
F1 F 1.4057(8) 1.0247(6) 0.2339(5) 0.166(7) Uani 1 1 d .
F2 F 1.3868(8) 1.0485(6) 0.1687(5) 0.144(6) Uani 1 1 d .
F3 F 1.3248(5) 1.0767(4) 0.2192(3) 0.068(3) Uani 1 1 d .
F4 F 0.7305(5) 0.7606(5) 0.4189(2) 0.058(2) Uani 1 1 d .
F5 F 0.7172(4) 0.8173(5) 0.3562(3) 0.0502(19) Uani 1 1 d .
F6 F 0.8430(5) 0.8733(5) 0.3919(2) 0.0499(19) Uani 1 1 d .
N1 N 0.5302(7) 0.4079(8) 0.3968(4) 0.058(3) Uani 1 1 d .
N2 N 0.8955(5) 0.9077(5) 0.1936(3) 0.023(2) Uani 1 1 d .
loop_
_atom_type_symbol
_atom_type_description
_atom_type_scat_dispersion_real
_atom_type_scat_dispersion_imag
_atom_type_scat_source
C C 0.0033 0.0016 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
H H 0.0000 0.0000 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
Ag Ag -0.8971 1.1015 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
Cr Cr 0.3209 0.6236 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
F F 0.0171 0.0103 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
N N 0.0061 0.0033 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
O O 0.0106 0.0060 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
S S 0.1246 0.1234 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
loop_
_geom_angle_atom_site_label_1
_geom_angle_atom_site_label_2
_geom_angle_atom_site_label_3
_geom_angle
_geom_angle_site_symmetry_1
_geom_angle_site_symmetry_3
S5 Ag1 S1 164.39(8) . .
S5 Ag1 O3 103.32(16) . .
S1 Ag1 O3 92.16(15) . .
S5 Ag1 O1 83.47(16) . 4_765
S1 Ag1 O1 93.07(15) . 4_765
O3 Ag1 O1 95.8(2) . 4_765
S5 Ag1 Ag2 109.12(6) . .
S1 Ag1 Ag2 56.90(6) . .
O3 Ag1 Ag2 143.41(15) . .
O1 Ag1 Ag2 104.18(15) 4_765 .
S5 Ag1 Ag9 134.64(6) . .
S1 Ag1 Ag9 51.07(6) . .
O3 Ag1 Ag9 64.87(16) . .
O1 Ag1 Ag9 56.53(15) 4_765 .
Ag2 Ag1 Ag9 101.40(3) . .
S5 Ag1 Ag6 51.19(6) . .
S1 Ag1 Ag6 114.28(6) . .
O3 Ag1 Ag6 150.92(15) . .
O1 Ag1 Ag6 94.70(16) 4_765 .
Ag2 Ag1 Ag6 57.94(2) . .
Ag9 Ag1 Ag6 141.52(3) . .
O11 Ag2 O12 87.0(3) . .
O11 Ag2 S2 105.30(19) . .
O12 Ag2 S2 105.8(2) . .
O11 Ag2 S1 110.00(19) . .
O12 Ag2 S1 95.9(2) . .
S2 Ag2 S1 139.26(8) . .
O11 Ag2 Ag6 78.59(19) . .
O12 Ag2 Ag6 147.8(2) . .
S2 Ag2 Ag6 52.45(6) . .
S1 Ag2 Ag6 116.00(6) . .
O11 Ag2 Ag1 92.7(2) . .
O12 Ag2 Ag1 146.5(2) . .
S2 Ag2 Ag1 106.61(6) . .
S1 Ag2 Ag1 52.90(6) . .
Ag6 Ag2 Ag1 63.67(2) . .
O11 Ag2 Ag8 137.42(19) . .
O12 Ag2 Ag8 62.4(2) . .
S2 Ag2 Ag8 110.84(6) . .
S1 Ag2 Ag8 50.78(5) . .
Ag6 Ag2 Ag8 142.36(3) . .
Ag1 Ag2 Ag8 97.74(3) . .
O11 Ag2 Ag3 148.47(19) . .
O12 Ag2 Ag3 84.2(2) . .
S2 Ag2 Ag3 49.19(5) . .
S1 Ag2 Ag3 100.99(6) . .
Ag6 Ag2 Ag3 93.25(3) . .
Ag1 Ag2 Ag3 111.03(3) . .
Ag8 Ag2 Ag3 61.67(2) . .
S2 Ag3 S3 161.64(9) . 4_765
S2 Ag3 O2 84.48(17) . .
S3 Ag3 O2 103.35(17) 4_765 .
S2 Ag3 Ag2 54.70(6) . .
S3 Ag3 Ag2 108.37(7) 4_765 .
O2 Ag3 Ag2 88.16(16) . .
S2 Ag3 Ag8 113.62(6) . .
S3 Ag3 Ag8 49.80(6) 4_765 .
O2 Ag3 Ag8 95.15(15) . .
Ag2 Ag3 Ag8 58.95(2) . .
S2 Ag3 Ag4 145.57(7) . 4_765
S3 Ag3 Ag4 52.53(6) 4_765 4_765
O2 Ag3 Ag4 74.55(17) . 4_765
Ag2 Ag3 Ag4 148.08(3) . 4_765
Ag8 Ag3 Ag4 95.47(3) . 4_765
O13 Ag4 S4 111.5(2) . 4_765
O13 Ag4 O8 101.5(2) . 2_754
S4 Ag4 O8 106.82(18) 4_765 2_754
O13 Ag4 S3 92.3(2) . .
S4 Ag4 S3 148.62(8) 4_765 .
O8 Ag4 S3 87.06(18) 2_754 .
O13 Ag4 Ag5 79.45(19) . .
S4 Ag4 Ag5 55.14(6) 4_765 .
O8 Ag4 Ag5 159.52(17) 2_754 .
S3 Ag4 Ag5 113.40(6) . .
O13 Ag4 Ag7 88.66(19) . .
S4 Ag4 Ag7 107.40(6) 4_765 .
O8 Ag4 Ag7 137.45(17) 2_754 .
S3 Ag4 Ag7 51.01(6) . .
Ag5 Ag4 Ag7 62.73(2) . .
O13 Ag4 Ag3 131.06(19) . 4_765
S4 Ag4 Ag3 116.53(6) 4_765 4_765
O8 Ag4 Ag3 56.37(17) 2_754 4_765
S3 Ag4 Ag3 48.49(6) . 4_765
Ag5 Ag4 Ag3 137.12(3) . 4_765
Ag7 Ag4 Ag3 85.78(3) . 4_765
O14 Ag5 S4 111.45(19) . 4_765
O14 Ag5 S5 104.87(19) . .
S4 Ag5 S5 135.21(8) 4_765 .
O14 Ag5 O15 89.3(2) . .
S4 Ag5 O15 120.63(16) 4_765 .
S5 Ag5 O15 84.27(16) . .
O14 Ag5 Ag4 83.61(17) . .
S4 Ag5 Ag4 52.96(6) 4_765 .
S5 Ag5 Ag4 108.33(6) . .
O15 Ag5 Ag4 166.75(16) . .
O14 Ag5 Ag11 147.51(17) . .
S4 Ag5 Ag11 51.76(6) 4_765 .
S5 Ag5 Ag11 104.75(6) . .
O15 Ag5 Ag11 80.68(15) . .
Ag4 Ag5 Ag11 99.44(3) . .
O14 Ag5 Ag6 135.52(18) . .
S4 Ag5 Ag6 110.12(6) 4_765 .
S5 Ag5 Ag6 50.93(6) . .
O15 Ag5 Ag6 55.71(15) . .
Ag4 Ag5 Ag6 135.68(3) . .
Ag11 Ag5 Ag6 60.31(2) . .
O14 Ag5 Ag7 92.41(17) . .
S4 Ag5 Ag7 102.54(6) 4_765 .
S5 Ag5 Ag7 49.69(6) . .
O15 Ag5 Ag7 132.66(15) . .
Ag4 Ag5 Ag7 59.09(2) . .
Ag11 Ag5 Ag7 117.08(3) . .
Ag6 Ag5 Ag7 93.50(3) . .
O10 Ag6 S2 111.6(2) . .
O10 Ag6 S5 98.7(2) . .
S2 Ag6 S5 144.23(8) . .
O10 Ag6 Ag2 85.17(19) . .
S2 Ag6 Ag2 57.05(6) . .
S5 Ag6 Ag2 109.51(6) . .
O10 Ag6 Ag11 152.67(19) . .
S2 Ag6 Ag11 51.99(6) . .
S5 Ag6 Ag11 105.41(6) . .
Ag2 Ag6 Ag11 98.46(3) . .
O10 Ag6 Ag5 133.23(19) . .
S2 Ag6 Ag5 110.28(6) . .
S5 Ag6 Ag5 53.61(6) . .
Ag2 Ag6 Ag5 136.22(3) . .
Ag11 Ag6 Ag5 58.42(2) . .
O10 Ag6 Ag1 94.92(18) . .
S2 Ag6 Ag1 105.92(6) . .
S5 Ag6 Ag1 51.13(6) . .
Ag2 Ag6 Ag1 58.39(2) . .
Ag11 Ag6 Ag1 110.12(3) . .
Ag5 Ag6 Ag1 92.84(3) . .
S3 Ag7 S5 166.48(9) . .
S3 Ag7 O5 98.78(18) . .
S5 Ag7 O5 94.54(18) . .
S3 Ag7 O1 95.44(16) . 4_765
S5 Ag7 O1 83.27(16) . 4_765
O5 Ag7 O1 104.9(2) . 4_765
S3 Ag7 Ag4 55.28(6) . .
S5 Ag7 Ag4 111.20(6) . .
O5 Ag7 Ag4 152.21(17) . .
O1 Ag7 Ag4 88.86(14) 4_765 .
S3 Ag7 Ag5 113.12(7) . .
S5 Ag7 Ag5 53.49(6) . .
O5 Ag7 Ag5 143.79(18) . .
O1 Ag7 Ag5 89.18(15) 4_765 .
Ag4 Ag7 Ag5 58.18(2) . .
S3 Ag7 Ag8 47.40(6) . 4_765
S5 Ag7 Ag8 142.67(6) . 4_765
O5 Ag7 Ag8 66.92(18) . 4_765
O1 Ag7 Ag8 71.73(16) 4_765 4_765
Ag4 Ag7 Ag8 95.89(3) . 4_765
Ag5 Ag7 Ag8 148.70(3) . 4_765
O9 Ag8 S3 113.1(2) 4_765 4_765
O9 Ag8 S1 104.3(2) 4_765 .
S3 Ag8 S1 142.43(8) 4_765 .
O9 Ag8 Ag2 116.3(2) 4_765 .
S3 Ag8 Ag2 107.97(6) 4_765 .
S1 Ag8 Ag2 54.84(6) . .
O9 Ag8 Ag3 140.10(18) 4_765 .
S3 Ag8 Ag3 48.96(6) 4_765 .
S1 Ag8 Ag3 102.30(6) . .
Ag2 Ag8 Ag3 59.38(2) . .
O9 Ag8 Ag7 113.7(2) 4_765 4_765
S3 Ag8 Ag7 46.75(6) 4_765 4_765
S1 Ag8 Ag7 114.56(6) . 4_765
Ag2 Ag8 Ag7 129.99(3) . 4_765
Ag3 Ag8 Ag7 80.57(3) . 4_765
S1 Ag9 S1 179.88(12) . 4_765
S1 Ag9 Ag1 51.79(6) . .
S1 Ag9 Ag1 128.16(6) 4_765 .
S1 Ag9 Ag1 128.16(6) . 4_765
S1 Ag9 Ag1 51.79(6) 4_765 4_765
Ag1 Ag9 Ag1 145.37(5) . 4_765
S4 Ag10 S4 174.35(12) 4_765 .
S4 Ag10 Ag11 47.60(6) 4_765 .
S4 Ag10 Ag11 130.55(6) . .
S4 Ag10 Ag11 130.55(6) 4_765 4_765
S4 Ag10 Ag11 47.60(6) . 4_765
Ag11 Ag10 Ag11 151.61(4) . 4_765
S4 Ag11 S2 157.68(8) 4_765 .
S4 Ag11 O4 110.13(17) 4_765 5_564
S2 Ag11 O4 91.62(18) . 5_564
S4 Ag11 Ag5 55.02(6) 4_765 .
S2 Ag11 Ag5 112.78(6) . .
O4 Ag11 Ag5 112.36(17) 5_564 .
S4 Ag11 Ag6 114.15(6) 4_765 .
S2 Ag11 Ag6 51.65(6) . .
O4 Ag11 Ag6 107.20(18) 5_564 .
Ag5 Ag11 Ag6 61.26(2) . .
S4 Ag11 Ag10 48.64(6) 4_765 .
S2 Ag11 Ag10 125.38(6) . .
O4 Ag11 Ag10 118.01(18) 5_564 .
Ag5 Ag11 Ag10 97.57(2) . .
Ag6 Ag11 Ag10 134.73(3) . .
C19 S1 Ag9 110.0(3) . .
C19 S1 Ag8 114.0(3) . .
Ag9 S1 Ag8 106.59(9) . .
C19 S1 Ag1 109.1(3) . .
Ag9 S1 Ag1 77.14(7) . .
Ag8 S1 Ag1 131.75(10) . .
C19 S1 Ag2 111.7(3) . .
Ag9 S1 Ag2 133.29(10) . .
Ag8 S1 Ag2 74.38(7) . .
Ag1 S1 Ag2 70.20(6) . .
C20 S2 Ag3 120.2(4) . .
C20 S2 Ag6 109.0(4) . .
Ag3 S2 Ag6 127.88(10) . .
C20 S2 Ag11 118.6(3) . .
Ag3 S2 Ag11 93.35(8) . .
Ag6 S2 Ag11 76.36(7) . .
C20 S2 Ag2 111.9(3) . .
Ag3 S2 Ag2 76.12(7) . .
Ag6 S2 Ag2 70.51(6) . .
Ag11 S2 Ag2 126.11(10) . .
C14 S3 Ag3 119.6(3) . 4_765
C14 S3 Ag7 119.4(3) . .
Ag3 S3 Ag7 120.15(10) 4_765 .
C14 S3 Ag8 112.3(4) . 4_765
Ag3 S3 Ag8 81.25(8) 4_765 4_765
Ag7 S3 Ag8 85.84(8) . 4_765
C14 S3 Ag4 108.9(4) . .
Ag3 S3 Ag4 78.98(8) 4_765 .
Ag7 S3 Ag4 73.71(7) . .
Ag8 S3 Ag4 138.77(10) 4_765 .
C11 S4 Ag11 109.0(4) . 4_765
C11 S4 Ag4 110.0(4) . 4_765
Ag11 S4 Ag4 133.61(10) 4_765 4_765
C11 S4 Ag10 111.6(3) . .
Ag11 S4 Ag10 83.75(7) 4_765 .
Ag4 S4 Ag10 104.04(9) 4_765 .
C11 S4 Ag5 107.5(3) . 4_765
Ag11 S4 Ag5 73.22(7) 4_765 4_765
Ag4 S4 Ag5 71.90(7) 4_765 4_765
Ag10 S4 Ag5 139.35(10) . 4_765
C23 S5 Ag7 116.1(3) . .
C23 S5 Ag1 120.5(3) . .
Ag7 S5 Ag1 89.40(8) . .
C23 S5 Ag6 108.7(3) . .
Ag7 S5 Ag6 133.54(10) . .
Ag1 S5 Ag6 77.68(7) . .
C23 S5 Ag5 112.7(3) . .
Ag7 S5 Ag5 76.82(7) . .
Ag1 S5 Ag5 125.64(10) . .
Ag6 S5 Ag5 75.46(7) . .
O2 Cr1 O2 109.1(5) . 4_765
O2 Cr1 O1 110.5(3) . 4_765
O2 Cr1 O1 109.1(3) 4_765 4_765
O2 Cr1 O1 109.1(3) . .
O2 Cr1 O1 110.5(3) 4_765 .
O1 Cr1 O1 108.6(5) 4_765 .
O4 Cr2 O5 110.2(4) . .
O4 Cr2 O3 110.7(4) . .
O5 Cr2 O3 110.5(3) . .
O4 Cr2 O6 108.4(3) . .
O5 Cr2 O6 108.9(3) . .
O3 Cr2 O6 108.0(3) . .
O7 Cr3 O8 110.7(4) . .
O7 Cr3 O9 111.0(4) . .
O8 Cr3 O9 109.6(4) . .
O7 Cr3 O6 108.8(4) . .
O8 Cr3 O6 108.4(3) . .
O9 Cr3 O6 108.3(3) . .
O15 C1 N2 125.7(10) . .
O12 C6 N1 125.2(13) . .
O14 C7 O13 131.0(9) . .
O14 C7 C8 115.3(10) . .
O13 C7 C8 113.7(10) . .
F1 C8 F2 102.3(13) . .
F1 C8 F3 107.2(12) . .
F2 C8 F3 103.0(11) . .
F1 C8 C7 112.1(11) . .
F2 C8 C7 113.8(11) . .
F3 C8 C7 116.9(11) . .
O10 C9 O11 133.0(10) . .
O10 C9 C10 111.5(9) . .
O11 C9 C10 115.4(10) . .
F4 C10 F5 107.9(9) . .
F4 C10 F6 105.6(9) . .
F5 C10 F6 108.5(9) . .
F4 C10 C9 113.3(9) . .
F5 C10 C9 110.5(9) . .
F6 C10 C9 110.8(9) . .
C13 C11 C12 112.2(9) . .
C13 C11 S4 108.7(7) . .
C12 C11 S4 109.7(8) . .
C15 C14 C16 112.6(12) . .
C15 C14 S3 108.8(8) . .
C16 C14 S3 108.8(7) . .
C18 C19 C17 112.7(8) . .
C18 C19 S1 111.5(7) . .
C17 C19 S1 109.8(6) . .
C22 C20 C21 115.1(9) . .
C22 C20 S2 110.6(7) . .
C21 C20 S2 108.6(7) . .
C25 C23 C24 113.8(9) . .
C25 C23 S5 109.7(7) . .
C24 C23 S5 110.6(7) . .
Cr1 O1 Ag1 128.7(3) . 4_765
Cr1 O1 Ag7 137.8(3) . 4_765
Ag1 O1 Ag7 84.36(19) 4_765 4_765
Cr1 O2 Ag3 133.9(4) . .
Cr2 O3 Ag1 130.2(3) . .
Cr2 O4 Ag11 123.9(4) . 6_655
Cr2 O5 Ag7 133.8(4) . .
Cr3 O6 Cr2 121.8(4) . .
Cr3 O8 Ag4 125.8(4) . 3_775
Cr3 O9 Ag8 126.3(4) . 4_765
C9 O10 Ag6 118.4(7) . .
C9 O11 Ag2 124.2(7) . .
C6 O12 Ag2 122.2(9) . .
C7 O13 Ag4 123.8(6) . .
C7 O14 Ag5 120.1(6) . .
C1 O15 Ag5 138.5(7) . .
C6 N1 C4 122.2(14) . .
C6 N1 C5 120.6(12) . .
C4 N1 C5 116.1(14) . .
C1 N2 C3 121.9(9) . .
C1 N2 C2 121.6(9) . .
C3 N2 C2 116.4(8) . .
loop_
_geom_bond_atom_site_label_1
_geom_bond_atom_site_label_2
_geom_bond_distance
_geom_bond_site_symmetry_2
Ag1 S5 2.457(2) .
Ag1 S1 2.483(2) .
Ag1 O3 2.495(6) .
Ag1 O1 2.531(6) 4_765
Ag1 Ag2 2.9295(10) .
Ag1 Ag9 3.0810(8) .
Ag1 Ag6 3.0830(10) .
Ag2 O11 2.373(7) .
Ag2 O12 2.374(8) .
Ag2 S2 2.595(2) .
Ag2 S1 2.608(2) .
Ag2 Ag6 2.9151(10) .
Ag2 Ag8 3.0726(10) .
Ag2 Ag3 3.0866(11) .
Ag3 S2 2.406(2) .
Ag3 S3 2.409(3) 4_765
Ag3 O2 2.484(7) .
Ag3 Ag8 3.1570(11) .
Ag3 Ag4 3.1575(10) 4_765
Ag4 O13 2.379(7) .
Ag4 S4 2.480(2) 4_765
Ag4 O8 2.511(7) 2_754
Ag4 S3 2.553(3) .
Ag4 Ag5 2.9528(10) .
Ag4 Ag7 2.9814(10) .
Ag4 Ag3 3.1575(10) 4_765
Ag5 O14 2.341(7) .
Ag5 S4 2.549(2) 4_765
Ag5 S5 2.550(2) .
Ag5 O15 2.595(7) .
Ag5 Ag11 2.9789(10) .
Ag5 Ag6 3.0660(11) .
Ag5 Ag7 3.0888(10) .
Ag6 O10 2.334(7) .
Ag6 S2 2.452(2) .
Ag6 S5 2.459(2) .
Ag6 Ag11 3.0376(11) .
Ag7 S3 2.414(3) .
Ag7 S5 2.419(2) .
Ag7 O5 2.438(7) .
Ag7 O1 2.577(6) 4_765
Ag7 Ag8 3.3053(11) 4_765
Ag8 O9 2.374(7) 4_765
Ag8 S3 2.440(3) 4_765
Ag8 S1 2.472(2) .
Ag8 Ag7 3.3053(11) 4_765
Ag9 S1 2.458(2) .
Ag9 S1 2.458(2) 4_765
Ag9 Ag1 3.0810(8) 4_765
Ag10 S4 2.484(2) 4_765
Ag10 S4 2.484(2) .
Ag10 Ag11 3.2894(8) .
Ag10 Ag11 3.2894(8) 4_765
Ag11 S4 2.444(2) 4_765
Ag11 S2 2.463(2) .
Ag11 O4 2.470(7) 5_564
S1 C19 1.845(9) .
S2 C20 1.870(9) .
S3 C14 1.843(9) .
S3 Ag3 2.409(3) 4_765
S3 Ag8 2.440(3) 4_765
S4 C11 1.849(10) .
S4 Ag11 2.444(2) 4_765
S4 Ag4 2.480(2) 4_765
S4 Ag5 2.549(2) 4_765
S5 C23 1.834(10) .
Cr1 O2 1.646(6) .
Cr1 O2 1.646(6) 4_765
Cr1 O1 1.653(6) 4_765
Cr1 O1 1.653(6) .
Cr2 O4 1.609(7) .
Cr2 O5 1.615(7) .
Cr2 O3 1.616(6) .
Cr2 O6 1.787(7) .
Cr3 O7 1.604(8) .
Cr3 O8 1.621(7) .
Cr3 O9 1.623(7) .
Cr3 O6 1.780(7) .
C1 O15 1.241(11) .
C1 N2 1.305(12) .
C2 N2 1.458(13) .
C3 N2 1.451(12) .
C4 N1 1.408(19) .
C5 N1 1.56(2) .
C6 O12 1.220(14) .
C6 N1 1.292(15) .
C7 O14 1.237(12) .
C7 O13 1.246(12) .
C7 C8 1.510(15) .
C8 F1 1.286(15) .
C8 F2 1.300(15) .
C8 F3 1.305(14) .
C9 O10 1.206(12) .
C9 O11 1.247(12) .
C9 C10 1.571(14) .
C10 F4 1.324(12) .
C10 F5 1.339(12) .
C10 F6 1.354(13) .
C11 C13 1.502(15) .
C11 C12 1.509(14) .
C14 C15 1.497(16) .
C14 C16 1.504(15) .
C17 C19 1.525(12) .
C18 C19 1.502(12) .
C20 C22 1.467(14) .
C20 C21 1.512(14) .
C23 C25 1.498(14) .
C23 C24 1.521(14) .
O1 Ag1 2.531(6) 4_765
O1 Ag7 2.577(6) 4_765
O4 Ag11 2.470(7) 6_655
O8 Ag4 2.511(7) 3_775
O9 Ag8 2.374(7) 4_765
