#------------------------------------------------------------------------------
#$Date: 2019-11-17 07:26:40 +0200 (Sun, 17 Nov 2019) $
#$Revision: 228664 $
#$URL: file:///home/coder/svn-repositories/cod/cif/1/54/95/1549567.cif $
#------------------------------------------------------------------------------
#
# This file is available in the Crystallography Open Database (COD),
# http://www.crystallography.net/
#
# All data on this site have been placed in the public domain by the
# contributors.
#
data_1549567
loop_
_publ_author_name
'Ruan, Wenqing'
'Leung, Tsz-Fai'
'Shi, Chuan'
'Lee, Ka Ho'
'Sung, Herman H. Y.'
'Williams, Ian D.'
'Lin, Zhenyang'
'Jia, Guochen'
_publ_section_title
;
 Facile synthesis of polycyclic metallaarynes.
;
_journal_issue                   27
_journal_name_full               'Chemical science'
_journal_page_first              5994
_journal_page_last               5998
_journal_paper_doi               10.1039/c8sc02086h
_journal_volume                  9
_journal_year                    2018
_chemical_formula_moiety         'C52 H46 Cl2 Os P2 Si, 3(C H2 Cl2)'
_chemical_formula_sum            'C55 H52 Cl8 Os P2 Si'
_chemical_formula_weight         1276.79
_space_group_crystal_system      monoclinic
_space_group_IT_number           11
_space_group_name_Hall           '-P 2yb'
_space_group_name_H-M_alt        'P 1 21/m 1'
_symmetry_space_group_name_Hall  '-P 2yb'
_symmetry_space_group_name_H-M   'P 1 21/m 1'
_atom_sites_solution_hydrogens   geom
_atom_sites_solution_primary     heavy
_audit_creation_date             2018-02-06
_audit_creation_method
;
Olex2 1.2
(compiled 2017.08.10 svn.r3458 for OlexSys, GUI svn.r5381)
;
_audit_update_record
;
2018-03-20 deposited with the CCDC.
2018-06-19 downloaded from the CCDC.
;
_cell_angle_alpha                90
_cell_angle_beta                 102.8377(19)
_cell_angle_gamma                90
_cell_formula_units_Z            2
_cell_length_a                   11.4227(2)
_cell_length_b                   17.2735(3)
_cell_length_c                   13.9125(3)
_cell_measurement_reflns_used    8846
_cell_measurement_temperature    100.01(10)
_cell_measurement_theta_max      75.3830
_cell_measurement_theta_min      4.1460
_cell_volume                     2676.46(9)
_computing_cell_refinement       'CrysAlisPro 1.171.38.46 (Rigaku OD, 2015)'
_computing_data_collection       'CrysAlisPro 1.171.38.46 (Rigaku OD, 2015)'
_computing_data_reduction        'CrysAlisPro 1.171.38.46 (Rigaku OD, 2015)'
_computing_molecular_graphics    'Olex2 (Dolomanov et al., 2009)'
_computing_publication_material  'Olex2 (Dolomanov et al., 2009)'
_computing_structure_refinement  'ShelXL (Sheldrick, 2015)'
_computing_structure_solution    'ShelXS-1997 (Sheldrick, 2008)'
_diffrn_ambient_temperature      100.15
_diffrn_detector_area_resol_mean 10.3577
_diffrn_detector_type            Atlas
_diffrn_measured_fraction_theta_full 0.997
_diffrn_measured_fraction_theta_max 0.997
_diffrn_measurement_details
;
List of Runs (angles in degrees, time in seconds):

  # Type    Start    End  Width  tₑₓₚ   ω     θ     κ     φ   Frames
#--------------------------------------------------------------------------
  1  ω     34.00 137.00   1.00   20.00    --  110.57 -77.00 150.00  103
  2  ω    -69.00  33.00   1.00    5.00    --  -40.20  77.00   0.00  102
  3  ω      1.00  50.00   1.00    5.00    --   40.20 -99.00 120.00   49
  4  ω   -115.00 -14.00   1.00    5.00    --  -40.20 -37.00-120.00  101
  5  ω   -112.00 -11.00   1.00    5.00    --  -40.20 -57.00 150.00  101
  6  ω     56.00  82.00   1.00    5.00    --   40.20 -99.00 120.00   26
  7  ω     49.00 142.00   1.00   20.00    --  110.57 -77.00 -30.00   93
  8  ω     83.00 176.00   1.00   20.00    --  110.57  45.00  90.00   93
  9  ω     57.00 151.00   1.00   20.00    --  110.57 178.00-120.00   94
 10  ω     37.00 140.00   1.00   20.00    --  110.57 -30.00 120.00  103
 11  ω     35.00 115.00   1.00   20.00    --  110.57-111.00 -30.00   80
 12  ω     40.00 141.00   1.00   20.00    --  110.57 -30.00 -90.00  101
;
_diffrn_measurement_device       'kappa diffractometer'
_diffrn_measurement_device_type  'SuperNova, Dual, Cu at zero, Atlas'
_diffrn_measurement_method       'ω scans'
_diffrn_radiation_type           CuK\a
_diffrn_radiation_wavelength     1.54184
_diffrn_reflns_av_R_equivalents  0.0386
_diffrn_reflns_av_unetI/netI     0.0363
_diffrn_reflns_Laue_measured_fraction_full 0.997
_diffrn_reflns_Laue_measured_fraction_max 0.997
_diffrn_reflns_limit_h_max       10
_diffrn_reflns_limit_h_min       -13
_diffrn_reflns_limit_k_max       20
_diffrn_reflns_limit_k_min       -20
_diffrn_reflns_limit_l_max       16
_diffrn_reflns_limit_l_min       -16
_diffrn_reflns_number            15170
_diffrn_reflns_point_group_measured_fraction_full 0.997
_diffrn_reflns_point_group_measured_fraction_max 0.997
_diffrn_reflns_theta_full        66.500
_diffrn_reflns_theta_max         67.498
_diffrn_reflns_theta_min         3.969
_exptl_absorpt_coefficient_mu    9.238
_exptl_absorpt_correction_T_max  1.00000
_exptl_absorpt_correction_T_min  0.65007
_exptl_absorpt_correction_type   multi-scan
_exptl_absorpt_process_details
;
CrysAlisPro 1.171.38.46 (Rigaku Oxford Diffraction, 2015)
Empirical absorption correction using spherical harmonics,
 implemented in SCALE3 ABSPACK scaling algorithm.
;
_exptl_crystal_colour            green
_exptl_crystal_colour_primary    green
_exptl_crystal_density_diffrn    1.584
_exptl_crystal_description       plate
_exptl_crystal_F_000             1276
_exptl_crystal_size_max          0.12
_exptl_crystal_size_mid          0.06
_exptl_crystal_size_min          0.02
_refine_diff_density_max         1.823
_refine_diff_density_min         -1.299
_refine_diff_density_rms         0.107
_refine_ls_extinction_method     none
_refine_ls_goodness_of_fit_ref   1.077
_refine_ls_hydrogen_treatment    constr
_refine_ls_matrix_type           full
_refine_ls_number_parameters     415
_refine_ls_number_reflns         4986
_refine_ls_number_restraints     42
_refine_ls_restrained_S_all      1.096
_refine_ls_R_factor_all          0.0466
_refine_ls_R_factor_gt           0.0424
_refine_ls_shift/su_max          0.018
_refine_ls_shift/su_mean         0.001
_refine_ls_structure_factor_coef Fsqd
_refine_ls_weighting_details
'w=1/[σ²(Fo²)+(0.0405P)²+10.4102P] where P=(Fo²+2Fc²)/3'
_refine_ls_weighting_scheme      calc
_refine_ls_wR_factor_gt          0.1003
_refine_ls_wR_factor_ref         0.1023
_reflns_Friedel_coverage         0.000
_reflns_number_gt                4638
_reflns_number_total             4986
_reflns_threshold_expression     'I > 2σ(I)'
_cod_data_source_file            c8sc02086h2.cif
_cod_data_source_block           ruan35a
_cod_depositor_comments
'Adding full bibliography for 1549565--1549567.cif.'
_cod_database_code               1549567
_shelx_shelxl_version_number     2014/7
_shelx_space_group_comment
;
The symmetry employed for this shelxl refinement is uniquely defined
by the following loop, which should always be used as a source of
symmetry information in preference to the above space-group names.
They are only intended as comments.
;
_shelx_estimated_absorpt_t_max   0.837
_shelx_estimated_absorpt_t_min   0.404
_olex2_refinement_description
;
1. Fixed Uiso
 At 1.2 times of:
  All C(H) groups, All C(H,H) groups
 At 1.5 times of:
  All C(H,H,H) groups
2. Restrained distances
 Cl3S-C2S = Cl4S-C2S
 1.72 with sigma of 0.02
 C32A-C31A \\sim C33A-C32A \\sim C34A-C33A \\sim C34A-C35A \\sim C36A-C35A
\\sim C36A-C31A
 with sigma of 0.02
 C32-C31 \\sim C33-C32 \\sim C34-C33 \\sim C34-C35 \\sim C36-C35 \\sim C36-C31
 with sigma of 0.02
 Si1-C15 \\sim Si1-C14 \\sim Si1-C16
 with sigma of 0.02
 Cl3S-C2S \\sim Cl4S-C2S
 with sigma of 0.02
3. Uiso/Uaniso restraints and constraints
Uanis(Cl3S) \\sim Ueq: with sigma of 0.005 and sigma for terminal atoms of 0.002
4. Others
 Fixed Sof: Si1(0.5) C14(0.5) H14A(0.5) H14B(0.5) H14C(0.5) C15(0.5) H15A(0.5)
 H15B(0.5) H15C(0.5) C16(0.5) H16A(0.5) H16B(0.5) H16C(0.5) C31(0.5) C31A(0.5)
 C32(0.5) H32(0.5) C32A(0.5) H32A(0.5) C33(0.5) H33(0.5) C33A(0.5) H33A(0.5)
 C34(0.5) H34(0.5) C34A(0.5) H34A(0.5) C35(0.5) H35(0.5) C35A(0.5) H35A(0.5)
 C36(0.5) H36(0.5) C36A(0.5) H36A(0.5) Cl3S(0.5) Cl4S(0.5) C2S(0.5) H2SA(0.5)
 H2SB(0.5)
5.a Secondary CH2 refined with riding coordinates:
 C1S(H1SA,H1SB), C2S(H2SA,H2SB)
5.b Aromatic/amide H refined with riding coordinates:
 C5(H5), C6(H6), C7(H7), C10(H10), C11(H11), C12(H12), C13(H13), C22(H22),
 C23(H23), C24(H24), C25(H25), C26(H26), C32(H32), C32A(H32A), C33(H33),
 C33A(H33A), C34(H34), C34A(H34A), C35(H35), C35A(H35A), C36(H36), C36A(H36A),
 C42(H42), C43(H43), C44(H44), C45(H45), C46(H46)
5.c Idealised Me refined as rotating group:
 C14(H14A,H14B,H14C), C15(H15A,H15B,H15C), C16(H16A,H16B,H16C)
;
_olex2_submission_special_instructions 'No special instructions were received'
_oxdiff_exptl_absorpt_empirical_details
;
Empirical correction (ABSPACK) includes:
- Absorption correction using spherical harmonics
- Frame scaling
;
loop_
_space_group_symop_operation_xyz
'x, y, z'
'-x, y+1/2, -z'
'-x, -y, -z'
'x, -y-1/2, z'
loop_
_atom_site_label
_atom_site_type_symbol
_atom_site_fract_x
_atom_site_fract_y
_atom_site_fract_z
_atom_site_U_iso_or_equiv
_atom_site_adp_type
_atom_site_occupancy
_atom_site_site_symmetry_order
_atom_site_calc_flag
_atom_site_refinement_flags_posn
_atom_site_refinement_flags_adp
_atom_site_refinement_flags_occupancy
_atom_site_disorder_assembly
_atom_site_disorder_group
Os1 Os 0.71026(2) 0.2500 0.30718(2) 0.02547(11) Uani 1 2 d S T P A .
Cl1 Cl 0.76187(13) 0.2500 0.14429(10) 0.0280(3) Uani 1 2 d S T P . .
Cl2 Cl 0.92732(14) 0.2500 0.38122(12) 0.0431(5) Uani 1 2 d S T P . .
P1 P 0.71465(11) 0.11052(8) 0.30890(10) 0.0348(3) Uani 1 1 d . . . . .
Si1 Si 0.5193(2) 0.2368(5) 0.56896(19) 0.0366(19) Uani 0.5 1 d D . . . .
C1 C 0.6255(6) 0.2500 0.4012(5) 0.0317(16) Uani 1 2 d S T P . .
C2 C 0.5232(6) 0.2500 0.4335(5) 0.0357(17) Uani 1 2 d S T P A .
C3 C 0.4192(6) 0.2500 0.3525(5) 0.0272(14) Uani 1 2 d S T P . .
C4 C 0.4296(6) 0.2500 0.2507(5) 0.0254(13) Uani 1 2 d S T P A .
C5 C 0.5418(5) 0.2500 0.2261(5) 0.0216(12) Uani 1 2 d S T P . .
H5 H 0.5372 0.2500 0.1571 0.026 Uiso 1 2 calc RS T P A .
C6 C 0.3019(6) 0.2500 0.3718(6) 0.0344(16) Uani 1 2 d S T P A .
H6 H 0.2936 0.2500 0.4382 0.041 Uiso 1 2 calc RS T P . .
C7 C 0.2029(6) 0.2500 0.2991(6) 0.0382(17) Uani 1 2 d S T P . .
H7 H 0.1267 0.2500 0.3158 0.046 Uiso 1 2 calc RS T P A .
C8 C 0.2078(6) 0.2500 0.1982(6) 0.0330(16) Uani 1 2 d S T P A .
C9 C 0.3211(6) 0.2500 0.1731(5) 0.0278(14) Uani 1 2 d S T P . .
C10 C 0.1004(6) 0.2500 0.1235(7) 0.049(2) Uani 1 2 d S T P . .
H10 H 0.0250 0.2500 0.1415 0.059 Uiso 1 2 calc RS T P A .
C11 C 0.1042(6) 0.2500 0.0262(7) 0.045(2) Uani 1 2 d S T P A .
H11 H 0.0319 0.2500 -0.0232 0.054 Uiso 1 2 calc RS T P . .
C12 C 0.2146(7) 0.2500 -0.0003(6) 0.0396(18) Uani 1 2 d S T P . .
H12 H 0.2175 0.2500 -0.0680 0.047 Uiso 1 2 calc RS T P A .
C13 C 0.3204(6) 0.2500 0.0716(5) 0.0308(15) Uani 1 2 d S T P A .
H13 H 0.3949 0.2500 0.0518 0.037 Uiso 1 2 calc RS T P . .
C14 C 0.6730(10) 0.2160(9) 0.6424(7) 0.057(4) Uani 0.5 1 d D . . A -1
H14A H 0.7307 0.2505 0.6214 0.085 Uiso 0.5 1 calc GR . . A -1
H14B H 0.6938 0.1620 0.6320 0.085 Uiso 0.5 1 calc GR . . A -1
H14C H 0.6755 0.2244 0.7125 0.085 Uiso 0.5 1 calc GR . . A -1
C15 C 0.4214(15) 0.1565(11) 0.5938(18) 0.050(5) Uani 0.5 1 d D . . A -1
H15A H 0.4223 0.1550 0.6644 0.075 Uiso 0.5 1 calc GR . . A -1
H15B H 0.4512 0.1072 0.5738 0.075 Uiso 0.5 1 calc GR . . A -1
H15C H 0.3391 0.1651 0.5562 0.075 Uiso 0.5 1 calc GR . . A -1
C16 C 0.4708(14) 0.3323(10) 0.6079(16) 0.047(5) Uani 0.5 1 d D . . A -1
H16A H 0.5289 0.3720 0.5995 0.071 Uiso 0.5 1 calc GR . . A -1
H16B H 0.4664 0.3298 0.6774 0.071 Uiso 0.5 1 calc GR . . A -1
H16C H 0.3916 0.3453 0.5675 0.071 Uiso 0.5 1 calc GR . . A -1
C21 C 0.7834(5) 0.0594(4) 0.2203(4) 0.0432(14) Uani 1 1 d . . . . .
C22 C 0.8908(5) 0.0880(4) 0.2021(4) 0.0460(15) Uani 1 1 d . . . . .
H22 H 0.9236 0.1354 0.2308 0.055 Uiso 1 1 calc R . . . .
C23 C 0.9495(6) 0.0457(5) 0.1408(5) 0.065(2) Uani 1 1 d . . . . .
H23 H 1.0222 0.0648 0.1273 0.079 Uiso 1 1 calc R . . . .
C24 C 0.9024(8) -0.0234(5) 0.1000(5) 0.076(3) Uani 1 1 d . . . . .
H24 H 0.9434 -0.0522 0.0594 0.092 Uiso 1 1 calc R . . . .
C25 C 0.7967(8) -0.0508(5) 0.1179(6) 0.076(2) Uani 1 1 d . . . . .
H25 H 0.7645 -0.0983 0.0892 0.091 Uiso 1 1 calc R . . . .
C26 C 0.7370(7) -0.0101(4) 0.1769(6) 0.0609(18) Uani 1 1 d . . . . .
H26 H 0.6634 -0.0294 0.1883 0.073 Uiso 1 1 calc R . . . .
C31 C 0.787(2) 0.0527(10) 0.4122(16) 0.029(4) Uani 0.5 1 d D . . B 1
C31A C 0.7896(19) 0.0766(10) 0.4366(15) 0.027(4) Uani 0.5 1 d D . . B 2
C32 C 0.8276(15) 0.0900(10) 0.5010(12) 0.035(3) Uani 0.5 1 d D . . B 1
H32 H 0.8197 0.1447 0.5039 0.041 Uiso 0.5 1 calc R . . B 1
C32A C 0.8208(17) 0.1224(10) 0.5186(11) 0.039(4) Uani 0.5 1 d D . . B 2
H32A H 0.8024 0.1761 0.5133 0.047 Uiso 0.5 1 calc R . . B 2
C33 C 0.8798(13) 0.0495(9) 0.5867(11) 0.043(3) Uani 0.5 1 d D . . B 1
H33 H 0.9055 0.0762 0.6475 0.051 Uiso 0.5 1 calc R . . B 1
C33A C 0.8787(14) 0.0924(10) 0.6095(11) 0.053(4) Uani 0.5 1 d D . . B 2
H33A H 0.9012 0.1249 0.6657 0.064 Uiso 0.5 1 calc R . . B 2
C34 C 0.8937(13) -0.0299(9) 0.5820(11) 0.033(3) Uani 0.5 1 d D . . B 1
H34 H 0.9322 -0.0579 0.6391 0.040 Uiso 0.5 1 calc R . . B 1
C34A C 0.9025(13) 0.0145(10) 0.6160(11) 0.047(4) Uani 0.5 1 d D . . B 2
H34A H 0.9399 -0.0072 0.6779 0.056 Uiso 0.5 1 calc R . . B 2
C35 C 0.8514(12) -0.0685(9) 0.4942(9) 0.041(3) Uani 0.5 1 d D . . B 1
H35 H 0.8599 -0.1231 0.4910 0.049 Uiso 0.5 1 calc R . . B 1
C35A C 0.8734(13) -0.0329(11) 0.5346(11) 0.041(4) Uani 0.5 1 d D . . B 2
H35A H 0.8918 -0.0866 0.5399 0.049 Uiso 0.5 1 calc R . . B 2
C36 C 0.7968(12) -0.0276(8) 0.4112(9) 0.029(3) Uani 0.5 1 d D . . B 1
H36 H 0.7648 -0.0549 0.3519 0.035 Uiso 0.5 1 calc R . . B 1
C36A C 0.8172(11) -0.0012(8) 0.4452(10) 0.031(3) Uani 0.5 1 d D . . B 2
H36A H 0.7971 -0.0335 0.3887 0.037 Uiso 0.5 1 calc R . . B 2
C41 C 0.5609(5) 0.0740(3) 0.2865(5) 0.0407(13) Uani 1 1 d . . . . .
C42 C 0.4897(5) 0.0762(3) 0.1919(5) 0.0445(14) Uani 1 1 d . . . . .
H42 H 0.5232 0.0902 0.1377 0.053 Uiso 1 1 calc R . . . .
C43 C 0.3676(5) 0.0576(3) 0.1773(5) 0.0496(16) Uani 1 1 d . . . . .
H43 H 0.3184 0.0584 0.1125 0.060 Uiso 1 1 calc R . . . .
C44 C 0.3183(5) 0.0382(4) 0.2554(6) 0.0562(18) Uani 1 1 d . . . . .
H44 H 0.2352 0.0262 0.2446 0.067 Uiso 1 1 calc R . . . .
C45 C 0.3882(5) 0.0361(4) 0.3483(6) 0.0578(18) Uani 1 1 d . . . . .
H45 H 0.3536 0.0224 0.4021 0.069 Uiso 1 1 calc R . . . .
C46 C 0.5097(5) 0.0538(4) 0.3652(5) 0.0495(15) Uani 1 1 d . . . . .
H46 H 0.5579 0.0521 0.4303 0.059 Uiso 1 1 calc R . . . .
Cl1S Cl 0.5398(2) 0.14218(17) 0.9042(2) 0.1158(10) Uani 1 1 d . . . . .
Cl2S Cl 0.7874(3) 0.13535(19) 0.88008(18) 0.1120(10) Uani 1 1 d . . . . .
C1S C 0.6861(7) 0.1187(5) 0.9540(5) 0.067(2) Uani 1 1 d . . . . .
H1SA H 0.6897 0.0632 0.9718 0.081 Uiso 1 1 calc R . . . .
H1SB H 0.7127 0.1485 1.0159 0.081 Uiso 1 1 calc R . . . .
Cl3S Cl 0.2106(4) 0.2273(3) 0.7000(4) 0.0953(15) Uani 0.5 1 d D U . C -1
Cl4S Cl -0.0076(3) 0.2248(2) 0.7551(2) 0.0610(10) Uani 0.5 1 d D . . C -1
C2S C 0.0650(10) 0.2182(11) 0.6614(11) 0.085(6) Uani 0.5 1 d D . . C -1
H2SA H 0.0470 0.1674 0.6285 0.102 Uiso 0.5 1 calc R . . C -1
H2SB H 0.0349 0.2590 0.6122 0.102 Uiso 0.5 1 calc R . . C -1
loop_
_atom_type_symbol
_atom_type_description
_atom_type_scat_dispersion_real
_atom_type_scat_dispersion_imag
_atom_type_scat_source
C C 0.0181 0.0091 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
H H 0.0000 0.0000 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
Cl Cl 0.3639 0.7018 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
Os Os -4.9801 6.2216 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
P P 0.2955 0.4335 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
Si Si 0.2541 0.3302 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
loop_
_geom_angle_atom_site_label_1
_geom_angle_atom_site_label_2
_geom_angle_atom_site_label_3
_geom_angle
_geom_angle_site_symmetry_1
_geom_angle_site_symmetry_3
Cl2 Os1 Cl1 87.73(5) . .
P1 Os1 Cl1 90.02(3) 4_565 .
P1 Os1 Cl1 90.02(3) . .
P1 Os1 Cl2 88.80(3) . .
P1 Os1 Cl2 88.80(3) 4_565 .
P1 Os1 P1 177.59(6) . 4_565
C1 Os1 Cl1 161.7(2) . .
C1 Os1 Cl2 110.6(2) . .
C1 Os1 P1 90.35(3) . 4_565
C1 Os1 P1 90.35(3) . .
C1 Os1 C5 78.7(3) . .
C5 Os1 Cl1 83.02(18) . .
C5 Os1 Cl2 170.75(18) . .
C5 Os1 P1 91.20(3) . .
C5 Os1 P1 91.20(3) . 4_565
C21 P1 Os1 119.2(2) . .
C21 P1 C31A 108.2(5) . .
C31 P1 Os1 124.7(5) . .
C31 P1 C21 94.6(5) . .
C31 P1 C41 101.6(7) . .
C31A P1 Os1 108.9(5) . .
C41 P1 Os1 109.07(17) . .
C41 P1 C21 105.0(3) . .
C41 P1 C31A 105.7(7) . .
Si1 Si1 C2 83.2(2) 4_565 .
Si1 Si1 C14 101.2(5) 4_565 .
Si1 Si1 C15 138.2(7) 4_565 .
Si1 Si1 C16 27.5(7) 4_565 .
C14 Si1 C2 109.8(4) . .
C14 Si1 C15 106.6(8) . .
C15 Si1 C2 114.8(9) . .
C16 Si1 C2 104.9(8) . .
C16 Si1 C14 108.5(8) . .
C16 Si1 C15 112.1(6) . .
C2 C1 Os1 153.7(5) . .
Si1 C2 Si1 13.7(5) 4_565 .
C1 C2 Si1 122.9(5) . .
C1 C2 Si1 122.9(5) . 4_565
C1 C2 C3 111.5(6) . .
C3 C2 Si1 125.0(5) . 4_565
C3 C2 Si1 125.0(5) . .
C2 C3 C4 122.0(6) . .
C6 C3 C2 119.9(6) . .
C6 C3 C4 118.1(6) . .
C3 C4 C9 119.0(6) . .
C5 C4 C3 121.2(6) . .
C5 C4 C9 119.8(6) . .
C4 C5 Os1 132.9(5) . .
C7 C6 C3 122.0(7) . .
C6 C7 C8 122.4(6) . .
C7 C8 C10 120.5(7) . .
C9 C8 C7 118.9(7) . .
C9 C8 C10 120.5(8) . .
C8 C9 C4 119.6(7) . .
C13 C9 C4 123.9(6) . .
C13 C9 C8 116.4(6) . .
C11 C10 C8 120.9(7) . .
C10 C11 C12 119.6(7) . .
C13 C12 C11 120.3(8) . .
C12 C13 C9 122.1(7) . .
C22 C21 P1 118.5(5) . .
C26 C21 P1 121.9(5) . .
C26 C21 C22 119.4(6) . .
C21 C22 C23 118.9(7) . .
C24 C23 C22 120.4(7) . .
C25 C24 C23 120.2(7) . .
C24 C25 C26 120.4(8) . .
C25 C26 C21 120.6(8) . .
C32 C31 P1 117.4(11) . .
C32 C31 C36 117.6(17) . .
C36 C31 P1 124.8(13) . .
C32A C31A P1 125.9(11) . .
C32A C31A C36A 118.6(14) . .
C36A C31A P1 115.6(11) . .
C31 C32 C33 121.7(16) . .
C31A C32A C33A 121.7(15) . .
C34 C33 C32 119.1(13) . .
C34A C33A C32A 118.2(14) . .
C35 C34 C33 120.0(11) . .
C33A C34A C35A 121.4(13) . .
C36 C35 C34 119.8(12) . .
C34A C35A C36A 119.0(13) . .
C35 C36 C31 121.7(15) . .
C31A C36A C35A 121.1(14) . .
C42 C41 P1 119.4(5) . .
C42 C41 C46 119.5(5) . .
C46 C41 P1 120.5(5) . .
C41 C42 C43 119.1(6) . .
C44 C43 C42 120.8(6) . .
C45 C44 C43 120.1(6) . .
C44 C45 C46 120.6(7) . .
C45 C46 C41 119.9(6) . .
Cl1S C1S Cl2S 116.2(4) . .
Cl3S C2S Cl4S 112.1(9) . .
loop_
_geom_bond_atom_site_label_1
_geom_bond_atom_site_label_2
_geom_bond_distance
_geom_bond_site_symmetry_2
Os1 Cl1 2.4651(14) .
Os1 Cl2 2.4646(16) .
Os1 P1 2.4098(14) .
Os1 P1 2.4099(14) 4_565
Os1 C1 1.792(7) .
Os1 C5 2.003(6) .
P1 C21 1.829(6) .
P1 C31 1.79(3) .
P1 C31A 1.89(2) .
P1 C41 1.827(6) .
Si1 Si1 0.455(16) 4_565
Si1 C2 1.909(7) .
Si1 C14 1.861(10) .
Si1 C15 1.862(13) .
Si1 C16 1.858(14) .
C1 C2 1.342(10) .
C2 Si1 1.909(7) 4_565
C2 C3 1.444(10) .
C3 C4 1.448(10) .
C3 C6 1.424(9) .
C4 C5 1.397(9) .
C4 C9 1.451(9) .
C6 C7 1.339(11) .
C7 C8 1.417(11) .
C8 C9 1.414(10) .
C8 C10 1.420(11) .
C9 C13 1.411(10) .
C10 C11 1.364(13) .
C11 C12 1.390(11) .
C12 C13 1.388(10) .
C21 C22 1.398(9) .
C21 C26 1.393(10) .
C22 C23 1.401(9) .
C23 C24 1.380(12) .
C24 C25 1.370(13) .
C25 C26 1.372(10) .
C31 C32 1.378(14) .
C31 C36 1.392(14) .
C31A C32A 1.369(13) .
C31A C36A 1.380(14) .
C32 C33 1.397(14) .
C32A C33A 1.391(14) .
C33 C34 1.385(15) .
C33A C34A 1.372(14) .
C34 C35 1.381(13) .
C34A C35A 1.376(15) .
C35 C36 1.379(14) .
C35A C36A 1.380(13) .
C41 C42 1.385(8) .
C41 C46 1.396(8) .
C42 C43 1.402(8) .
C43 C44 1.372(10) .
C44 C45 1.361(10) .
C45 C46 1.389(8) .
Cl1S C1S 1.710(8) .
Cl2S C1S 1.734(9) .
Cl3S C2S 1.638(11) .
Cl4S C2S 1.698(11) .
