#------------------------------------------------------------------------------
#$Date: 2019-11-08 02:46:13 +0200 (Fri, 08 Nov 2019) $
#$Revision: 224857 $
#$URL: file:///home/coder/svn-repositories/cod/cif/1/55/12/1551242.cif $
#------------------------------------------------------------------------------
#
# This file is available in the Crystallography Open Database (COD),
# http://www.crystallography.net/
#
# All data on this site have been placed in the public domain by the
# contributors.
#
data_1551242
loop_
_publ_author_name
'Sánchez-Viveros, José Manuel'
'Bucio-Ortega, Job'
'Ortiz-Pastrana, Naytzé'
'Olguín, Juan'
_publ_section_title
;
 Mononuclear complexes of FeII, CoII and CoIII containing imine-based
 ligands of 8-aminoquinoline and 7-aminoindazole: spin state tuning of
 FeII complexes in solution
;
_journal_issue                   25
_journal_name_full               'New Journal of Chemistry'
_journal_page_first              9776
_journal_paper_doi               10.1039/C9NJ01622H
_journal_volume                  43
_journal_year                    2019
_chemical_formula_moiety         'C60 H66 B4 Co2 F16 N16 O5'
_chemical_formula_sum            'C60 H66 B4 Co2 F16 N16 O5'
_chemical_formula_weight         1556.38
_space_group_crystal_system      monoclinic
_space_group_IT_number           15
_space_group_name_Hall           '-C 2yc'
_space_group_name_H-M_alt        'C 1 2/c 1'
_symmetry_space_group_name_Hall  '-C 2yc'
_symmetry_space_group_name_H-M   'C 1 2/c 1'
_atom_sites_solution_hydrogens   mixed
_atom_sites_solution_primary     direct
_atom_sites_solution_secondary   difmap
_audit_creation_method           SHELXL-2017/1
_audit_update_record
;
2019-05-29 deposited with the CCDC.    2019-06-04 downloaded from the CCDC.
;
_cell_angle_alpha                90
_cell_angle_beta                 119.63(2)
_cell_angle_gamma                90
_cell_formula_units_Z            2
_cell_length_a                   21.699(9)
_cell_length_b                   12.540(4)
_cell_length_c                   15.873(8)
_cell_measurement_reflns_used    9789
_cell_measurement_temperature    166(2)
_cell_measurement_theta_max      26.44
_cell_measurement_theta_min      2.66
_cell_volume                     3754(3)
_computing_cell_refinement       'Bruker SAINT'
_computing_data_collection       'Bruker APEX2'
_computing_data_reduction        'Bruker SAINT'
_computing_molecular_graphics    'Bruker SHELXTL'
_computing_publication_material  'Bruker SHELXTL'
_computing_structure_refinement  'SHELXL-2017/1 (Sheldrick, 2017)'
_computing_structure_solution    'SHELXT 2014/5 (Sheldrick, 2014)'
_diffrn_ambient_temperature      166(2)
_diffrn_measured_fraction_theta_full 0.995
_diffrn_measured_fraction_theta_max 0.990
_diffrn_measurement_device_type  'Bruker D8 VENTURE diffractometer'
_diffrn_measurement_method       'φ and ω scans'
_diffrn_radiation_monochromator  'multilayer mirror'
_diffrn_radiation_type           MoK\a
_diffrn_radiation_wavelength     0.71073
_diffrn_reflns_av_R_equivalents  0.0784
_diffrn_reflns_av_unetI/netI     0.0237
_diffrn_reflns_Laue_measured_fraction_full 0.995
_diffrn_reflns_Laue_measured_fraction_max 0.990
_diffrn_reflns_limit_h_max       29
_diffrn_reflns_limit_h_min       -29
_diffrn_reflns_limit_k_max       17
_diffrn_reflns_limit_k_min       -17
_diffrn_reflns_limit_l_max       21
_diffrn_reflns_limit_l_min       -21
_diffrn_reflns_number            136569
_diffrn_reflns_point_group_measured_fraction_full 0.995
_diffrn_reflns_point_group_measured_fraction_max 0.990
_diffrn_reflns_theta_full        25.242
_diffrn_reflns_theta_max         28.907
_diffrn_reflns_theta_min         2.953
_diffrn_source                   'microfocus sealed tube'
_diffrn_source_type              'Incoatec I\mS HB'
_exptl_absorpt_coefficient_mu    0.537
_exptl_absorpt_correction_T_max  0.7458
_exptl_absorpt_correction_T_min  0.6754
_exptl_absorpt_correction_type   multi-scan
_exptl_absorpt_process_details   '(Sheldrick, 2012)'
_exptl_crystal_colour            red
_exptl_crystal_density_diffrn    1.377
_exptl_crystal_density_meas      ?
_exptl_crystal_density_method    'not measured'
_exptl_crystal_description       block
_exptl_crystal_F_000             1592
_exptl_crystal_recrystallization_method
'Re-crystallisation from solvent: methanol/diethyl ether'
_exptl_crystal_size_max          0.460
_exptl_crystal_size_mid          0.300
_exptl_crystal_size_min          0.200
_exptl_transmission_factor_max   0.7458
_exptl_transmission_factor_min   0.6754
_refine_diff_density_max         0.604
_refine_diff_density_min         -0.585
_refine_diff_density_rms         0.070
_refine_ls_extinction_method     none
_refine_ls_goodness_of_fit_ref   1.038
_refine_ls_hydrogen_treatment    mixed
_refine_ls_matrix_type           full
_refine_ls_number_parameters     279
_refine_ls_number_reflns         4894
_refine_ls_number_restraints     21
_refine_ls_restrained_S_all      1.058
_refine_ls_R_factor_all          0.0692
_refine_ls_R_factor_gt           0.0540
_refine_ls_shift/su_max          0.000
_refine_ls_shift/su_mean         0.000
_refine_ls_structure_factor_coef Fsqd
_refine_ls_weighting_details
'w=1/[σ²(Fo²)+(0.1076P)²+2.1227P] where P=(Fo²+2Fc²)/3'
_refine_ls_weighting_scheme      calc
_refine_ls_wR_factor_gt          0.1564
_refine_ls_wR_factor_ref         0.1683
_reflns_Friedel_coverage         0.000
_reflns_number_gt                3948
_reflns_number_total             4894
_reflns_threshold_expression     'I > 2σ(I)'
_cod_data_source_file            c9nj01622h2.cif
_cod_data_source_block           ICQ02
_cod_depositor_comments
;
The following automatic conversions were performed:

'_exptl_crystal_density_meas' value 'not measured' was changed to '?'
- the value is perceived as not measured.

Automatic conversion script
Id: cif_fix_values 4973 2017-02-22 13:04:09Z antanas 

 Adding full bibliography for 1551241--1551243.cif.
;
_cod_database_code               1551242
_shelx_shelxl_version_number     2017/1
_shelx_space_group_comment
;
The symmetry employed for this shelxl refinement is uniquely defined
by the following loop, which should always be used as a source of
symmetry information in preference to the above space-group names.
They are only intended as comments.
;
_shelx_estimated_absorpt_t_min   0.790
_shelx_estimated_absorpt_t_max   0.900
loop_
_space_group_symop_operation_xyz
'x, y, z'
'-x, y, -z+1/2'
'x+1/2, y+1/2, z'
'-x+1/2, y+1/2, -z+1/2'
'-x, -y, -z'
'x, -y, z-1/2'
'-x+1/2, -y+1/2, -z'
'x+1/2, -y+1/2, z-1/2'
loop_
_atom_site_label
_atom_site_type_symbol
_atom_site_fract_x
_atom_site_fract_y
_atom_site_fract_z
_atom_site_U_iso_or_equiv
_atom_site_adp_type
_atom_site_occupancy
_atom_site_site_symmetry_order
_atom_site_calc_flag
_atom_site_refinement_flags_posn
_atom_site_refinement_flags_adp
_atom_site_refinement_flags_occupancy
_atom_site_disorder_assembly
_atom_site_disorder_group
Co1 Co 0.500000 0.38494(3) 0.250000 0.03790(15) Uani 1 2 d S T P . .
F1 F 0.39986(12) 0.8865(2) 0.4378(2) 0.1180(10) Uani 1 1 d . . . . .
B1 B 0.33560(18) 0.8500(3) 0.4163(3) 0.0704(9) Uani 1 1 d . . . . .
N1 N 0.49112(9) 0.50085(14) 0.34273(13) 0.0456(4) Uani 1 1 d . . . . .
N2 N 0.44871(11) 0.56994(18) 0.35455(16) 0.0555(5) Uani 1 1 d . . . . .
H2 H 0.402740 0.574304 0.314672 0.067 Uiso 1 1 calc R U . . .
N3 N 0.60468(9) 0.39020(13) 0.36566(12) 0.0401(4) Uani 1 1 d . . . . .
C3 C 0.48324(17) 0.6310(2) 0.4326(2) 0.0630(7) Uani 1 1 d . . . . .
H3 H 0.463033 0.684481 0.453869 0.076 Uiso 1 1 calc R U . . .
C5 C 0.61935(17) 0.6307(2) 0.5602(2) 0.0665(7) Uani 1 1 d . . . . .
H5 H 0.621035 0.685266 0.602835 0.080 Uiso 1 1 calc R U . . .
N4 N 0.55253(9) 0.25864(14) 0.22004(12) 0.0421(4) Uani 1 1 d . . . . .
C4 C 0.55440(15) 0.60230(19) 0.47742(19) 0.0541(6) Uani 1 1 d . . . . .
C8 C 0.61794(11) 0.46771(17) 0.43590(14) 0.0436(4) Uani 1 1 d . . . . .
C7 C 0.68016(13) 0.4965(2) 0.51590(17) 0.0551(6) Uani 1 1 d . . . . .
H7 H 0.723278 0.462309 0.529927 0.066 Uiso 1 1 calc R U . . .
C6 C 0.67978(16) 0.5774(2) 0.57749(19) 0.0666(7) Uani 1 1 d . . . . .
H6 H 0.723266 0.595862 0.633339 0.080 Uiso 1 1 calc R U . . .
C9 C 0.55566(11) 0.52096(17) 0.41775(14) 0.0435(4) Uani 1 1 d . . . . .
C15 C 0.52304(13) 0.1890(2) 0.14841(18) 0.0533(5) Uani 1 1 d . . . . .
H15 H 0.474075 0.195802 0.102382 0.064 Uiso 1 1 calc R U . . .
C14 C 0.56116(18) 0.1063(2) 0.1382(2) 0.0686(8) Uani 1 1 d . . . . .
H14 H 0.538678 0.056607 0.086633 0.082 Uiso 1 1 calc R U . . .
C13 C 0.63203(18) 0.0977(2) 0.2042(2) 0.0705(8) Uani 1 1 d . . . . .
H13 H 0.659318 0.042037 0.198169 0.085 Uiso 1 1 calc R U . . .
C12 C 0.66358(14) 0.1698(2) 0.2791(2) 0.0594(6) Uani 1 1 d . . . . .
H12 H 0.712716 0.165376 0.324993 0.071 Uiso 1 1 calc R U . . .
C11 C 0.62194(12) 0.24863(17) 0.28559(15) 0.0433(4) Uani 1 1 d . . . . .
C10 C 0.64913(11) 0.32489(17) 0.36528(15) 0.0439(5) Uani 1 1 d . . . . .
H10 H 0.697589 0.325607 0.414333 0.053 Uiso 1 1 calc R U . . .
C20 C 0.2800(3) 0.6516(4) 0.1535(4) 0.1220(16) Uani 1 1 d . . . . .
H1A H 0.301286 0.658800 0.111909 0.183 Uiso 1 1 calc R U . . .
H1B H 0.289494 0.716107 0.192928 0.183 Uiso 1 1 calc R U . . .
H1C H 0.228629 0.641873 0.113121 0.183 Uiso 1 1 calc R U . . .
O1 O 0.30833(14) 0.5658(2) 0.2125(2) 0.1061(9) Uani 1 1 d D . . . .
H1 H 0.297(5) 0.493(2) 0.194(6) 0.28(5) Uiso 1 1 d D . . . .
F2A F 0.2815(3) 0.8891(4) 0.3348(5) 0.0807(16) Uani 0.626(12) 1 d . . P A 1
F3A F 0.3218(2) 0.8685(7) 0.4925(3) 0.122(3) Uani 0.626(12) 1 d . . P A 1
F4A F 0.3391(4) 0.7426(5) 0.4114(8) 0.147(3) Uani 0.626(12) 1 d . . P A 1
F2B F 0.3276(6) 0.7709(10) 0.4512(9) 0.137(6) Uani 0.374(12) 1 d . U P A 2
F3B F 0.3050(8) 0.9365(10) 0.4327(16) 0.182(7) Uani 0.374(12) 1 d . U P A 2
F4B F 0.2912(10) 0.8572(16) 0.3205(13) 0.193(8) Uani 0.374(12) 1 d . U P A 2
O30 O 0.500000 0.1039(11) 0.750000 0.145(4) Uani 0.5 2 d DS T P . .
C31 C 0.4483(7) 0.1767(12) 0.6936(12) 0.197(7) Uani 0.5 1 d D . P . .
H31A H 0.467429 0.231433 0.667763 0.236 Uiso 0.5 1 calc R U P . .
H31B H 0.429303 0.212475 0.731544 0.236 Uiso 0.5 1 calc R U P . .
C32 C 0.3931(9) 0.1133(10) 0.6148(11) 0.157(5) Uani 0.5 1 d D . P . .
H32A H 0.397673 0.038435 0.634810 0.236 Uiso 0.5 1 calc R U P . .
H32B H 0.398507 0.118928 0.557141 0.236 Uiso 0.5 1 calc R U P . .
H32C H 0.346331 0.140037 0.599610 0.236 Uiso 0.5 1 calc R U P . .
loop_
_atom_type_symbol
_atom_type_description
_atom_type_scat_dispersion_real
_atom_type_scat_dispersion_imag
_atom_type_scat_source
C C 0.0033 0.0016 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
H H 0.0000 0.0000 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
N N 0.0061 0.0033 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
Co Co 0.3494 0.9721 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
B B 0.0013 0.0007 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
F F 0.0171 0.0103 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
O O 0.0106 0.0060 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
loop_
_geom_angle_atom_site_label_1
_geom_angle_atom_site_label_2
_geom_angle_atom_site_label_3
_geom_angle
_geom_angle_site_symmetry_1
_geom_angle_site_symmetry_3
N3 Co1 N3 176.40(9) . 2_655
N3 Co1 N4 75.67(7) . .
N3 Co1 N4 107.10(7) 2_655 .
N3 Co1 N4 107.10(7) . 2_655
N3 Co1 N4 75.67(7) 2_655 2_655
N4 Co1 N4 84.39(10) . 2_655
N3 Co1 N1 78.70(7) . .
N3 Co1 N1 98.82(7) 2_655 .
N4 Co1 N1 153.35(7) . .
N4 Co1 N1 96.36(7) 2_655 .
N3 Co1 N1 98.82(7) . 2_655
N3 Co1 N1 78.70(7) 2_655 2_655
N4 Co1 N1 96.36(7) . 2_655
N4 Co1 N1 153.35(7) 2_655 2_655
N1 Co1 N1 94.63(11) . 2_655
F2B B1 F1 122.6(6) . .
F2A B1 F1 115.2(4) . .
F2B B1 F4B 113.3(10) . .
F1 B1 F4B 109.8(9) . .
F2A B1 F4A 110.9(6) . .
F1 B1 F4A 105.8(5) . .
F2B B1 F3B 112.2(9) . .
F1 B1 F3B 102.9(6) . .
F4B B1 F3B 91.0(10) . .
F2A B1 F3A 108.3(4) . .
F1 B1 F3A 111.3(4) . .
F4A B1 F3A 104.9(5) . .
C9 N1 N2 103.99(18) . .
C9 N1 Co1 109.19(14) . .
N2 N1 Co1 146.48(15) . .
C3 N2 N1 113.1(2) . .
C3 N2 H2 123.4 . .
N1 N2 H2 123.4 . .
C10 N3 C8 126.60(18) . .
C10 N3 Co1 118.18(14) . .
C8 N3 Co1 115.23(14) . .
N2 C3 C4 107.4(2) . .
N2 C3 H3 126.3 . .
C4 C3 H3 126.3 . .
C6 C5 C4 118.5(2) . .
C6 C5 H5 120.8 . .
C4 C5 H5 120.8 . .
C15 N4 C11 118.91(19) . .
C15 N4 Co1 126.63(16) . .
C11 N4 Co1 114.36(13) . .
C3 C4 C9 103.3(2) . .
C3 C4 C5 138.8(2) . .
C9 C4 C5 117.8(3) . .
C7 C8 N3 130.1(2) . .
C7 C8 C9 118.3(2) . .
N3 C8 C9 111.69(18) . .
C8 C7 C6 119.4(2) . .
C8 C7 H7 120.3 . .
C6 C7 H7 120.3 . .
C5 C6 C7 122.9(2) . .
C5 C6 H6 118.5 . .
C7 C6 H6 118.5 . .
N1 C9 C4 112.1(2) . .
N1 C9 C8 124.76(19) . .
C4 C9 C8 123.1(2) . .
N4 C15 C14 122.2(2) . .
N4 C15 H15 118.9 . .
C14 C15 H15 118.9 . .
C13 C14 C15 118.6(3) . .
C13 C14 H14 120.7 . .
C15 C14 H14 120.7 . .
C14 C13 C12 119.9(3) . .
C14 C13 H13 120.1 . .
C12 C13 H13 120.1 . .
C11 C12 C13 118.1(3) . .
C11 C12 H12 120.9 . .
C13 C12 H12 120.9 . .
N4 C11 C12 122.2(2) . .
N4 C11 C10 115.28(18) . .
C12 C11 C10 122.5(2) . .
N3 C10 C11 116.46(18) . .
N3 C10 H10 121.8 . .
C11 C10 H10 121.8 . .
O1 C20 H1A 109.5 . .
O1 C20 H1B 109.5 . .
H1A C20 H1B 109.5 . .
O1 C20 H1C 109.5 . .
H1A C20 H1C 109.5 . .
H1B C20 H1C 109.5 . .
C20 O1 H1 126(6) . .
C31 O30 C31 97.1(16) 2_656 .
O30 C31 C32 104.7(12) . .
O30 C31 H31A 110.8 . .
C32 C31 H31A 110.8 . .
O30 C31 H31B 110.8 . .
C32 C31 H31B 110.8 . .
H31A C31 H31B 108.9 . .
C31 C32 H32A 109.5 . .
C31 C32 H32B 109.5 . .
H32A C32 H32B 109.5 . .
C31 C32 H32C 109.5 . .
H32A C32 H32C 109.5 . .
H32B C32 H32C 109.5 . .
loop_
_geom_bond_atom_site_label_1
_geom_bond_atom_site_label_2
_geom_bond_distance
_geom_bond_site_symmetry_2
Co1 N3 2.100(2) .
Co1 N3 2.100(2) 2_655
Co1 N4 2.1377(18) .
Co1 N4 2.1377(18) 2_655
Co1 N1 2.1439(19) .
Co1 N1 2.1439(19) 2_655
F1 B1 1.341(4) .
B1 F2B 1.190(8) .
B1 F2A 1.338(6) .
B1 F4B 1.342(17) .
B1 F4A 1.353(7) .
B1 F3B 1.362(11) .
B1 F3A 1.403(6) .
N1 C9 1.339(3) .
N1 N2 1.343(3) .
N2 C3 1.328(4) .
N2 H2 0.8800 .
N3 C10 1.267(3) .
N3 C8 1.398(3) .
C3 C4 1.391(4) .
C3 H3 0.9500 .
C5 C6 1.373(5) .
C5 C4 1.417(4) .
C5 H5 0.9500 .
N4 C15 1.322(3) .
N4 C11 1.348(3) .
C4 C9 1.401(3) .
C8 C7 1.368(3) .
C8 C9 1.404(3) .
C7 C6 1.412(4) .
C7 H7 0.9500 .
C6 H6 0.9500 .
C15 C14 1.384(4) .
C15 H15 0.9500 .
C14 C13 1.371(5) .
C14 H14 0.9500 .
C13 C12 1.377(4) .
C13 H13 0.9500 .
C12 C11 1.377(3) .
C12 H12 0.9500 .
C11 C10 1.458(3) .
C10 H10 0.9500 .
C20 O1 1.358(6) .
C20 H1A 0.9800 .
C20 H1B 0.9800 .
C20 H1C 0.9800 .
O1 H1 0.956(10) .
O30 C31 1.378(9) 2_656
O30 C31 1.378(9) .
C31 C32 1.466(9) .
C31 H31A 0.9900 .
C31 H31B 0.9900 .
C32 H32A 0.9800 .
C32 H32B 0.9800 .
C32 H32C 0.9800 .
loop_
_geom_hbond_atom_site_label_D
_geom_hbond_atom_site_label_H
_geom_hbond_atom_site_label_A
_geom_hbond_distance_DH
_geom_hbond_distance_HA
_geom_hbond_distance_DA
_geom_hbond_angle_DHA
_geom_hbond_site_symmetry_A
_geom_hbond_publ_flag
N2 H2 O1 0.88 1.88 2.752(4) 168.1 . yes
C3 H3 F4A^a 0.95 2.53 3.288(8) 136.4 . yes
C15 H15 F1 0.95 2.51 3.222(4) 131.3 6_565 yes
C12 H12 F4A^a 0.95 2.57 3.441(9) 152.0 3_545 yes
C10 H10 F3A^a 0.95 2.40 3.306(5) 158.3 3_545 yes
C20 H1B F4B^b 0.98 2.68 3.62(2) 161.5 . yes
C20 H1C F3B^b 0.98 2.68 3.171(17) 111.5 4_545 yes
O1 H1 F2A^a 0.956(10) 2.00(6) 2.798(5) 139(7) 4_545 yes
O1 H1 F3B^b 0.956(10) 2.24(8) 2.896(19) 125(7) 4_545 yes
O1 H1 F4B^b 0.956(10) 2.48(6) 3.26(2) 140(7) 4_545 yes
loop_
_geom_torsion_atom_site_label_1
_geom_torsion_atom_site_label_2
_geom_torsion_atom_site_label_3
_geom_torsion_atom_site_label_4
_geom_torsion
_geom_torsion_site_symmetry_1
C9 N1 N2 C3 -0.3(3) .
Co1 N1 N2 C3 -172.0(2) .
N1 N2 C3 C4 0.2(3) .
N2 C3 C4 C9 -0.1(3) .
N2 C3 C4 C5 -179.3(3) .
C6 C5 C4 C3 179.3(3) .
C6 C5 C4 C9 0.1(4) .
C10 N3 C8 C7 4.1(4) .
Co1 N3 C8 C7 -175.5(2) .
C10 N3 C8 C9 -175.5(2) .
Co1 N3 C8 C9 5.0(2) .
N3 C8 C7 C6 -179.1(2) .
C9 C8 C7 C6 0.4(4) .
C4 C5 C6 C7 0.6(5) .
C8 C7 C6 C5 -0.9(4) .
N2 N1 C9 C4 0.2(3) .
Co1 N1 C9 C4 175.39(16) .
N2 N1 C9 C8 -179.8(2) .
Co1 N1 C9 C8 -4.7(3) .
C3 C4 C9 N1 -0.1(3) .
C5 C4 C9 N1 179.4(2) .
C3 C4 C9 C8 180.0(2) .
C5 C4 C9 C8 -0.6(4) .
C7 C8 C9 N1 -179.6(2) .
N3 C8 C9 N1 0.0(3) .
C7 C8 C9 C4 0.3(3) .
N3 C8 C9 C4 180.0(2) .
C11 N4 C15 C14 -0.3(4) .
Co1 N4 C15 C14 -176.5(2) .
N4 C15 C14 C13 -0.8(5) .
C15 C14 C13 C12 0.7(5) .
C14 C13 C12 C11 0.6(5) .
C15 N4 C11 C12 1.7(3) .
Co1 N4 C11 C12 178.30(19) .
C15 N4 C11 C10 -176.5(2) .
Co1 N4 C11 C10 0.1(2) .
C13 C12 C11 N4 -1.8(4) .
C13 C12 C11 C10 176.2(2) .
C8 N3 C10 C11 177.82(19) .
Co1 N3 C10 C11 -2.6(3) .
N4 C11 C10 N3 1.6(3) .
C12 C11 C10 N3 -176.6(2) .
C31 O30 C31 C32 168.6(17) 2_656
