#------------------------------------------------------------------------------
#$Date: 2019-06-18 03:19:07 +0300 (Tue, 18 Jun 2019) $
#$Revision: 216033 $
#$URL: file:///home/coder/svn-repositories/cod/cif/1/55/14/1551462.cif $
#------------------------------------------------------------------------------
#
# This file is available in the Crystallography Open Database (COD),
# http://www.crystallography.net/
#
# All data on this site have been placed in the public domain by the
# contributors.
#
data_1551462
loop_
_publ_author_name
'Hartmann, Deborah'
'Schädler, Marcel'
'Greb, Lutz'
_publ_section_title
;
 Bis(catecholato)silanes: assessment, rationale and increase of
 silicon’s Lewis superacidity
;
_journal_name_full               'Chemical Science'
_journal_paper_doi               10.1039/C9SC02167A
_journal_year                    2019
_chemical_formula_moiety         'C24 H24 F9 K O10 Si'
_chemical_formula_sum            'C24 H24 F9 K O10 Si'
_chemical_formula_weight         710.62
_space_group_crystal_system      triclinic
_space_group_IT_number           2
_space_group_name_Hall           '-P 1'
_space_group_name_H-M_alt        'P -1'
_symmetry_space_group_name_Hall  '-P 1'
_symmetry_space_group_name_H-M   'P -1'
_atom_sites_solution_hydrogens   geom
_atom_sites_solution_primary     dual
_audit_creation_date             2019-01-23
_audit_creation_method
;
Olex2 1.2
(compiled 2018.05.29 svn.r3508 for OlexSys, GUI svn.r5506)
;
_audit_update_record
;
2019-03-26 deposited with the CCDC.    2019-06-17 downloaded from the CCDC.
;
_cell_angle_alpha                77.14(3)
_cell_angle_beta                 77.77(3)
_cell_angle_gamma                69.26(3)
_cell_formula_units_Z            2
_cell_length_a                   9.3030(19)
_cell_length_b                   10.781(2)
_cell_length_c                   15.544(3)
_cell_measurement_reflns_used    864
_cell_measurement_temperature    120
_cell_measurement_theta_max      26
_cell_measurement_theta_min      1
_cell_volume                     1406.2(6)
_computing_cell_refinement       'DENZO/SCALEPACK (Bruker AXS, 1997-2009)'
_computing_data_collection       'COLLECT (Bruker AXS, 1997-2009)'
_computing_data_reduction        'DENZO/SCALEPACK (Bruker AXS, 1997-2009)'
_computing_molecular_graphics    'Olex2 (Dolomanov et al., 2009)'
_computing_publication_material  'Olex2 (Dolomanov et al., 2009)'
_computing_structure_refinement  'ShelXL (Sheldrick, 2015)'
_computing_structure_solution    'ShelXT (Sheldrick, 2015)'
_diffrn_ambient_temperature      120
_diffrn_measured_fraction_theta_full 0.998
_diffrn_measured_fraction_theta_max 0.988
_diffrn_measurement_device_type  'NONIUS Kappa CCD'
_diffrn_measurement_method       O-Scan
_diffrn_radiation_type           MoK\a
_diffrn_radiation_wavelength     0.71073
_diffrn_reflns_av_R_equivalents  0.0254
_diffrn_reflns_av_unetI/netI     0.0464
_diffrn_reflns_Laue_measured_fraction_full 0.998
_diffrn_reflns_Laue_measured_fraction_max 0.988
_diffrn_reflns_limit_h_max       13
_diffrn_reflns_limit_h_min       -13
_diffrn_reflns_limit_k_max       15
_diffrn_reflns_limit_k_min       -14
_diffrn_reflns_limit_l_max       21
_diffrn_reflns_limit_l_min       -21
_diffrn_reflns_number            14651
_diffrn_reflns_point_group_measured_fraction_full 0.998
_diffrn_reflns_point_group_measured_fraction_max 0.988
_diffrn_reflns_theta_full        25.242
_diffrn_reflns_theta_max         30.123
_diffrn_reflns_theta_min         2.047
_diffrn_source                   'fine-focus sealed tube'
_exptl_absorpt_coefficient_mu    0.347
_exptl_absorpt_correction_type   none
_exptl_crystal_colour            colourless
_exptl_crystal_colour_primary    colourless
_exptl_crystal_density_diffrn    1.678
_exptl_crystal_description       block
_exptl_crystal_F_000             724
_exptl_crystal_size_max          0.6
_exptl_crystal_size_mid          0.55
_exptl_crystal_size_min          0.4
_refine_diff_density_max         0.387
_refine_diff_density_min         -0.372
_refine_diff_density_rms         0.060
_refine_ls_extinction_method     none
_refine_ls_goodness_of_fit_ref   1.024
_refine_ls_hydrogen_treatment    constr
_refine_ls_matrix_type           full
_refine_ls_number_parameters     409
_refine_ls_number_reflns         8189
_refine_ls_number_restraints     0
_refine_ls_restrained_S_all      1.024
_refine_ls_R_factor_all          0.0680
_refine_ls_R_factor_gt           0.0385
_refine_ls_shift/su_max          0.001
_refine_ls_shift/su_mean         0.000
_refine_ls_structure_factor_coef Fsqd
_refine_ls_weighting_details
'w=1/[σ²(Fo²)+(0.0451P)²+0.2378P] where P=(Fo²+2Fc²)/3'
_refine_ls_weighting_scheme      calc
_refine_ls_wR_factor_gt          0.0868
_refine_ls_wR_factor_ref         0.0994
_reflns_Friedel_coverage         0.000
_reflns_number_gt                5810
_reflns_number_total             8189
_reflns_threshold_expression     'I > 2σ(I)'
_cod_data_source_file            c9sc02167a2.cif
_cod_data_source_block           ms83_p1
_cod_database_code               1551462
_shelx_shelxl_version_number     2018/3
_shelx_space_group_comment
;
The symmetry employed for this shelxl refinement is uniquely defined
by the following loop, which should always be used as a source of
symmetry information in preference to the above space-group names.
They are only intended as comments.
;
_shelx_estimated_absorpt_t_max   0.874
_shelx_estimated_absorpt_t_min   0.819
_olex2_refinement_description
;
1. Fixed Uiso
 At 1.2 times of:
  All C(H,H) groups
2.a Secondary CH2 refined with riding coordinates:
 C13(H13A,H13B), C14(H14A,H14B), C15(H15A,H15B), C16(H16A,H16B), C17(H17A,
 H17B), C18(H18A,H18B), C19(H19A,H19B), C20(H20A,H20B), C21(H21A,H21B),
 C22(H22A,H22B), C23(H23A,H23B), C24(H24A,H24B)
;
_olex2_submission_special_instructions 'No special instructions were received'
loop_
_space_group_symop_operation_xyz
'x, y, z'
'-x, -y, -z'
loop_
_atom_site_label
_atom_site_type_symbol
_atom_site_fract_x
_atom_site_fract_y
_atom_site_fract_z
_atom_site_U_iso_or_equiv
_atom_site_adp_type
_atom_site_occupancy
_atom_site_site_symmetry_order
_atom_site_calc_flag
_atom_site_refinement_flags_posn
_atom_site_refinement_flags_adp
_atom_site_refinement_flags_occupancy
K1 K 0.500000 0.000000 1.000000 0.02571(11) Uani 1 2 d S T P
K2 K 0.500000 0.500000 0.500000 0.02874(12) Uani 1 2 d S T P
Si1 Si 0.85191(5) 0.22087(4) 0.69661(3) 0.02305(10) Uani 1 1 d . . .
F1 F 1.00330(10) 0.09397(9) 0.71383(6) 0.0306(2) Uani 1 1 d . . .
F2 F 0.97626(12) 0.51757(10) 0.81638(7) 0.0379(2) Uani 1 1 d . . .
F3 F 0.82809(12) 0.54208(10) 0.98612(7) 0.0376(2) Uani 1 1 d . . .
F4 F 0.62195(11) 0.40987(10) 1.06347(6) 0.0335(2) Uani 1 1 d . . .
F5 F 0.55920(11) 0.25037(10) 0.97349(6) 0.0301(2) Uani 1 1 d . . .
F6 F 0.63822(12) -0.00253(10) 0.56775(6) 0.0344(2) Uani 1 1 d . . .
F7 F 0.69673(12) 0.04297(10) 0.38663(6) 0.0348(2) Uani 1 1 d . . .
F8 F 0.86468(12) 0.20740(10) 0.30050(6) 0.0352(2) Uani 1 1 d . . .
F9 F 0.96770(11) 0.33625(10) 0.39385(6) 0.0354(2) Uani 1 1 d . . .
O1 O 0.72704(12) 0.21952(10) 0.79648(7) 0.0236(2) Uani 1 1 d . . .
O2 O 0.90830(12) 0.34281(11) 0.72504(7) 0.0263(2) Uani 1 1 d . . .
O3 O 0.89073(12) 0.29297(11) 0.58701(7) 0.0257(2) Uani 1 1 d . . .
O4 O 0.74308(13) 0.14268(11) 0.66307(7) 0.0262(2) Uani 1 1 d . . .
O5 O 0.73182(12) -0.15358(11) 0.88683(7) 0.0245(2) Uani 1 1 d . . .
O6 O 0.81400(12) -0.05980(11) 1.02009(7) 0.0245(2) Uani 1 1 d . . .
O7 O 0.57475(12) 0.03578(11) 1.15599(7) 0.0257(2) Uani 1 1 d . . .
O8 O 0.66692(12) 0.62657(11) 0.36180(7) 0.0273(2) Uani 1 1 d . . .
O9 O 0.63868(12) 0.66670(11) 0.53757(7) 0.0264(2) Uani 1 1 d . . .
O10 O 0.53156(13) 0.48685(11) 0.67980(7) 0.0261(2) Uani 1 1 d . . .
C1 C 0.74288(17) 0.29600(15) 0.84951(10) 0.0228(3) Uani 1 1 d . . .
C2 C 0.84743(17) 0.36584(15) 0.80866(10) 0.0241(3) Uani 1 1 d . . .
C3 C 0.87496(18) 0.44996(16) 0.85387(11) 0.0268(3) Uani 1 1 d . . .
C4 C 0.79802(19) 0.46428(16) 0.93959(11) 0.0277(3) Uani 1 1 d . . .
C5 C 0.69497(18) 0.39629(16) 0.97945(11) 0.0259(3) Uani 1 1 d . . .
C6 C 0.66530(17) 0.31221(15) 0.93379(11) 0.0244(3) Uani 1 1 d . . .
C7 C 0.85109(17) 0.23626(16) 0.52983(10) 0.0240(3) Uani 1 1 d . . .
C8 C 0.76681(17) 0.14968(15) 0.57396(10) 0.0235(3) Uani 1 1 d . . .
C9 C 0.71763(18) 0.08294(16) 0.52606(11) 0.0261(3) Uani 1 1 d . . .
C10 C 0.74985(19) 0.10387(16) 0.43398(11) 0.0273(3) Uani 1 1 d . . .
C11 C 0.83325(18) 0.18846(17) 0.39045(10) 0.0276(3) Uani 1 1 d . . .
C12 C 0.88492(18) 0.25561(16) 0.43830(11) 0.0270(3) Uani 1 1 d . . .
C13 C 0.69774(19) -0.13137(17) 0.79839(10) 0.0281(3) Uani 1 1 d . . .
H13A H 0.776833 -0.199003 0.764330 0.034 Uiso 1 1 calc R . .
H13B H 0.699812 -0.041023 0.767602 0.034 Uiso 1 1 calc R . .
C14 C 0.88627(18) -0.15470(17) 0.88617(11) 0.0279(3) Uani 1 1 d . . .
H14A H 0.899565 -0.068940 0.852741 0.034 Uiso 1 1 calc R . .
H14B H 0.962383 -0.228932 0.856440 0.034 Uiso 1 1 calc R . .
C15 C 0.91346(17) -0.17316(16) 0.98017(11) 0.0269(3) Uani 1 1 d . . .
H15A H 0.892561 -0.255596 1.014549 0.032 Uiso 1 1 calc R . .
H15B H 1.023254 -0.183591 0.981049 0.032 Uiso 1 1 calc R . .
C16 C 0.84235(18) -0.07181(17) 1.10854(11) 0.0279(3) Uani 1 1 d . . .
H16A H 0.948883 -0.071041 1.107256 0.034 Uiso 1 1 calc R . .
H16B H 0.833212 -0.157869 1.143991 0.034 Uiso 1 1 calc R . .
C17 C 0.72618(18) 0.04339(17) 1.15041(11) 0.0283(3) Uani 1 1 d . . .
H17A H 0.748187 0.039076 1.210793 0.034 Uiso 1 1 calc R . .
H17B H 0.732924 0.129570 1.113956 0.034 Uiso 1 1 calc R . .
C18 C 0.45980(19) 0.14214(17) 1.19722(11) 0.0279(3) Uani 1 1 d . . .
H18A H 0.464121 0.229920 1.162372 0.033 Uiso 1 1 calc R . .
H18B H 0.480332 0.136516 1.258148 0.033 Uiso 1 1 calc R . .
C19 C 0.62668(19) 0.65601(17) 0.27436(10) 0.0270(3) Uani 1 1 d . . .
H19A H 0.712739 0.675061 0.229860 0.032 Uiso 1 1 calc R . .
H19B H 0.532852 0.736248 0.269493 0.032 Uiso 1 1 calc R . .
C20 C 0.70456(19) 0.73386(17) 0.38141(11) 0.0285(3) Uani 1 1 d . . .
H20A H 0.611536 0.815063 0.382979 0.034 Uiso 1 1 calc R . .
H20B H 0.786275 0.755825 0.334579 0.034 Uiso 1 1 calc R . .
C21 C 0.76086(19) 0.69101(17) 0.46982(11) 0.0296(4) Uani 1 1 d . . .
H21A H 0.851817 0.608127 0.468694 0.035 Uiso 1 1 calc R . .
H21B H 0.793337 0.762127 0.482915 0.035 Uiso 1 1 calc R . .
C22 C 0.68771(19) 0.63051(16) 0.62337(11) 0.0274(3) Uani 1 1 d . . .
H22A H 0.715485 0.704357 0.636321 0.033 Uiso 1 1 calc R . .
H22B H 0.780659 0.549142 0.624347 0.033 Uiso 1 1 calc R . .
C23 C 0.55866(19) 0.60386(16) 0.69244(11) 0.0265(3) Uani 1 1 d . . .
H23A H 0.586554 0.589865 0.752709 0.032 Uiso 1 1 calc R . .
H23B H 0.462928 0.682238 0.687583 0.032 Uiso 1 1 calc R . .
C24 C 0.40387(19) 0.46277(17) 0.74307(11) 0.0285(3) Uani 1 1 d . . .
H24A H 0.310078 0.542952 0.737778 0.034 Uiso 1 1 calc R . .
H24B H 0.428752 0.445428 0.804378 0.034 Uiso 1 1 calc R . .
loop_
_atom_type_symbol
_atom_type_description
_atom_type_scat_dispersion_real
_atom_type_scat_dispersion_imag
_atom_type_scat_source
C C 0.0033 0.0016 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
H H 0.0000 0.0000 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
F F 0.0171 0.0103 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
K K 0.2009 0.2494 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
O O 0.0106 0.0060 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
Si Si 0.0817 0.0704 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
loop_
_geom_angle_atom_site_label_1
_geom_angle_atom_site_label_2
_geom_angle_atom_site_label_3
_geom_angle
_geom_angle_site_symmetry_1
_geom_angle_site_symmetry_3
F5 K1 F5 180.0 2_657 .
O5 K1 F5 105.49(4) . .
O5 K1 F5 105.49(4) 2_657 2_657
O5 K1 F5 74.51(4) . 2_657
O5 K1 F5 74.51(4) 2_657 .
O5 K1 O5 180.0 . 2_657
O5 K1 O6 119.08(4) 2_657 .
O5 K1 O6 60.92(4) 2_657 2_657
O5 K1 O6 60.92(4) . .
O5 K1 O6 119.08(4) . 2_657
O5 K1 O7 61.33(4) 2_657 .
O5 K1 O7 61.33(4) . 2_657
O5 K1 O7 118.67(4) 2_657 2_657
O5 K1 O7 118.67(4) . .
O6 K1 F5 72.55(4) 2_657 2_657
O6 K1 F5 72.55(4) . .
O6 K1 F5 107.45(4) . 2_657
O6 K1 F5 107.45(4) 2_657 .
O6 K1 O6 180.00(5) . 2_657
O7 K1 F5 110.49(4) 2_657 .
O7 K1 F5 69.51(4) . .
O7 K1 F5 69.51(4) 2_657 2_657
O7 K1 F5 110.49(4) . 2_657
O7 K1 O6 120.38(4) . 2_657
O7 K1 O6 120.38(4) 2_657 .
O7 K1 O6 59.62(4) . .
O7 K1 O6 59.62(4) 2_657 2_657
O7 K1 O7 180.00(4) . 2_657
O8 K2 O8 180.0 . 2_666
O8 K2 O10 59.63(3) 2_666 .
O8 K2 O10 120.37(4) 2_666 2_666
O8 K2 O10 120.37(3) . .
O8 K2 O10 59.63(3) . 2_666
O8 K2 C7 92.21(5) 2_666 .
O8 K2 C7 87.79(5) 2_666 2_666
O8 K2 C7 87.79(5) . .
O8 K2 C7 92.21(5) . 2_666
O9 K2 O8 119.16(4) 2_666 .
O9 K2 O8 119.16(4) . 2_666
O9 K2 O8 60.84(4) . .
O9 K2 O8 60.84(4) 2_666 2_666
O9 K2 O9 180.0 2_666 .
O9 K2 O10 61.27(4) 2_666 2_666
O9 K2 O10 61.27(4) . .
O9 K2 O10 118.73(4) 2_666 .
O9 K2 O10 118.73(4) . 2_666
O9 K2 C7 87.06(4) 2_666 2_666
O9 K2 C7 92.94(4) 2_666 .
O9 K2 C7 87.06(4) . .
O9 K2 C7 92.94(4) . 2_666
O10 K2 O10 180.00(4) . 2_666
O10 K2 C7 103.74(5) 2_666 .
O10 K2 C7 103.74(5) . 2_666
O10 K2 C7 76.26(5) 2_666 2_666
O10 K2 C7 76.26(5) . .
C7 K2 C7 180.0 . 2_666
F1 Si1 O1 105.10(6) . .
F1 Si1 O2 98.96(6) . .
F1 Si1 O3 105.12(7) . .
F1 Si1 O4 99.23(6) . .
O1 Si1 O2 89.42(6) . .
O1 Si1 O4 85.50(5) . .
O3 Si1 O1 149.78(6) . .
O3 Si1 O2 86.32(6) . .
O3 Si1 O4 89.31(6) . .
O4 Si1 O2 161.81(6) . .
C6 F5 K1 142.71(9) . .
C1 O1 Si1 112.24(9) . .
C2 O2 Si1 112.12(9) . .
C7 O3 Si1 111.77(9) . .
C8 O4 Si1 111.70(9) . .
C13 O5 K1 114.10(9) . .
C13 O5 C14 111.16(12) . .
C14 O5 K1 116.31(9) . .
C15 O6 K1 111.89(8) . .
C16 O6 K1 115.76(9) . .
C16 O6 C15 111.06(12) . .
C17 O7 K1 116.25(9) . .
C17 O7 C18 110.96(12) . .
C18 O7 K1 113.73(9) . .
C19 O8 K2 119.20(8) . .
C19 O8 C20 111.49(12) . .
C20 O8 K2 116.29(9) . .
C21 O9 K2 114.29(9) . .
C22 O9 K2 115.18(9) . .
C22 O9 C21 110.45(12) . .
C23 O10 K2 111.70(9) . .
C23 O10 C24 110.52(12) . .
C24 O10 K2 113.68(9) . .
O1 C1 C2 112.92(14) . .
O1 C1 C6 126.61(14) . .
C6 C1 C2 120.44(14) . .
O2 C2 C1 112.77(13) . .
O2 C2 C3 127.22(14) . .
C3 C2 C1 119.99(15) . .
F2 C3 C2 121.22(15) . .
F2 C3 C4 119.49(14) . .
C2 C3 C4 119.29(14) . .
F3 C4 C3 120.07(14) . .
F3 C4 C5 119.19(15) . .
C5 C4 C3 120.70(14) . .
F4 C5 C4 120.16(14) . .
F4 C5 C6 119.51(14) . .
C4 C5 C6 120.33(15) . .
F5 C6 C1 121.77(14) . .
F5 C6 C5 119.00(14) . .
C1 C6 C5 119.23(14) . .
O3 C7 K2 94.39(9) . .
O3 C7 C8 112.50(13) . .
O3 C7 C12 127.27(14) . .
C8 C7 K2 89.87(10) . .
C12 C7 K2 86.07(10) . .
C12 C7 C8 120.23(14) . .
O4 C8 C7 112.68(13) . .
O4 C8 C9 127.05(13) . .
C9 C8 C7 120.27(14) . .
F6 C9 C8 120.98(14) . .
F6 C9 C10 119.57(14) . .
C8 C9 C10 119.46(14) . .
F7 C10 C9 119.70(14) . .
F7 C10 C11 119.91(14) . .
C11 C10 C9 120.38(14) . .
F8 C11 C10 119.77(14) . .
F8 C11 C12 119.57(14) . .
C10 C11 C12 120.66(14) . .
F9 C12 C7 121.82(14) . .
F9 C12 C11 119.18(14) . .
C7 C12 C11 118.99(14) . .
O5 C13 H13A 109.9 . .
O5 C13 H13B 109.9 . .
O5 C13 C18 108.96(13) . 2_657
H13A C13 H13B 108.3 . .
C18 C13 H13A 109.9 2_657 .
C18 C13 H13B 109.9 2_657 .
O5 C14 H14A 109.9 . .
O5 C14 H14B 109.9 . .
O5 C14 C15 108.83(13) . .
H14A C14 H14B 108.3 . .
C15 C14 H14A 109.9 . .
C15 C14 H14B 109.9 . .
O6 C15 C14 109.81(13) . .
O6 C15 H15A 109.7 . .
O6 C15 H15B 109.7 . .
C14 C15 H15A 109.7 . .
C14 C15 H15B 109.7 . .
H15A C15 H15B 108.2 . .
O6 C16 H16A 109.9 . .
O6 C16 H16B 109.9 . .
O6 C16 C17 109.08(13) . .
H16A C16 H16B 108.3 . .
C17 C16 H16A 109.9 . .
C17 C16 H16B 109.9 . .
O7 C17 C16 108.79(13) . .
O7 C17 H17A 109.9 . .
O7 C17 H17B 109.9 . .
C16 C17 H17A 109.9 . .
C16 C17 H17B 109.9 . .
H17A C17 H17B 108.3 . .
O7 C18 C13 109.50(13) . 2_657
O7 C18 H18A 109.8 . .
O7 C18 H18B 109.8 . .
C13 C18 H18A 109.8 2_657 .
C13 C18 H18B 109.8 2_657 .
H18A C18 H18B 108.2 . .
O8 C19 H19A 110.0 . .
O8 C19 H19B 110.0 . .
O8 C19 C24 108.54(13) . 2_666
H19A C19 H19B 108.4 . .
C24 C19 H19A 110.0 2_666 .
C24 C19 H19B 110.0 2_666 .
O8 C20 H20A 110.0 . .
O8 C20 H20B 110.0 . .
O8 C20 C21 108.69(13) . .
H20A C20 H20B 108.3 . .
C21 C20 H20A 110.0 . .
C21 C20 H20B 110.0 . .
O9 C21 C20 109.34(12) . .
O9 C21 H21A 109.8 . .
O9 C21 H21B 109.8 . .
C20 C21 H21A 109.8 . .
C20 C21 H21B 109.8 . .
H21A C21 H21B 108.3 . .
O9 C22 H22A 109.8 . .
O9 C22 H22B 109.8 . .
O9 C22 C23 109.19(12) . .
H22A C22 H22B 108.3 . .
C23 C22 H22A 109.8 . .
C23 C22 H22B 109.8 . .
O10 C23 C22 109.64(13) . .
O10 C23 H23A 109.7 . .
O10 C23 H23B 109.7 . .
C22 C23 H23A 109.7 . .
C22 C23 H23B 109.7 . .
H23A C23 H23B 108.2 . .
O10 C24 C19 109.40(13) . 2_666
O10 C24 H24A 109.8 . .
O10 C24 H24B 109.8 . .
C19 C24 H24A 109.8 2_666 .
C19 C24 H24B 109.8 2_666 .
H24A C24 H24B 108.2 . .
loop_
_geom_bond_atom_site_label_1
_geom_bond_atom_site_label_2
_geom_bond_distance
_geom_bond_site_symmetry_2
K1 F5 2.8671(11) .
K1 F5 2.8670(11) 2_657
K1 O5 2.7655(16) 2_657
K1 O5 2.7654(16) .
K1 O6 2.8302(12) 2_657
K1 O6 2.8302(12) .
K1 O7 2.7987(12) 2_657
K1 O7 2.7987(12) .
K2 O8 2.7695(14) .
K2 O8 2.7695(14) 2_666
K2 O9 2.7684(12) .
K2 O9 2.7684(12) 2_666
K2 O10 2.8388(12) .
K2 O10 2.8388(12) 2_666
K2 C7 3.528(2) .
K2 C7 3.528(2) 2_666
Si1 F1 1.5997(12) .
Si1 O1 1.7313(13) .
Si1 O2 1.7445(12) .
Si1 O3 1.7280(12) .
Si1 O4 1.7410(12) .
F2 C3 1.3504(18) .
F3 C4 1.3516(18) .
F4 C5 1.3518(19) .
F5 C6 1.3507(18) .
F6 C9 1.3521(18) .
F7 C10 1.3475(18) .
F8 C11 1.3507(18) .
F9 C12 1.3445(18) .
O1 C1 1.3494(18) .
O2 C2 1.3432(19) .
O3 C7 1.3565(18) .
O4 C8 1.3449(18) .
O5 C13 1.4255(19) .
O5 C14 1.4304(18) .
O6 C15 1.424(2) .
O6 C16 1.4236(18) .
O7 C17 1.4233(19) .
O7 C18 1.427(2) .
O8 C19 1.4239(19) .
O8 C20 1.4291(18) .
O9 C21 1.4319(19) .
O9 C22 1.4280(19) .
O10 C23 1.4319(18) .
O10 C24 1.4337(19) .
C1 C2 1.400(2) .
C1 C6 1.371(2) .
C2 C3 1.381(2) .
C3 C4 1.386(2) .
C4 C5 1.373(2) .
C5 C6 1.396(2) .
C7 C8 1.401(2) .
C7 C12 1.375(2) .
C8 C9 1.377(2) .
C9 C10 1.383(2) .
C10 C11 1.377(2) .
C11 C12 1.395(2) .
C13 H13A 0.9900 .
C13 H13B 0.9900 .
C13 C18 1.497(2) 2_657
C14 H14A 0.9900 .
C14 H14B 0.9900 .
C14 C15 1.493(2) .
C15 H15A 0.9900 .
C15 H15B 0.9900 .
C16 H16A 0.9900 .
C16 H16B 0.9900 .
C16 C17 1.499(2) .
C17 H17A 0.9900 .
C17 H17B 0.9900 .
C18 H18A 0.9900 .
C18 H18B 0.9900 .
C19 H19A 0.9900 .
C19 H19B 0.9900 .
C19 C24 1.496(2) 2_666
C20 H20A 0.9900 .
C20 H20B 0.9900 .
C20 C21 1.492(2) .
C21 H21A 0.9900 .
C21 H21B 0.9900 .
C22 H22A 0.9900 .
C22 H22B 0.9900 .
C22 C23 1.496(2) .
C23 H23A 0.9900 .
C23 H23B 0.9900 .
C24 H24A 0.9900 .
C24 H24B 0.9900 .
