#------------------------------------------------------------------------------
#$Date: 2019-10-28 22:47:32 +0200 (Mon, 28 Oct 2019) $
#$Revision: 220307 $
#$URL: file:///home/coder/svn-repositories/cod/cif/1/55/24/1552493.cif $
#------------------------------------------------------------------------------
#
# This file is available in the Crystallography Open Database (COD),
# http://www.crystallography.net/
#
# All data on this site have been placed in the public domain by the
# contributors.
#
data_1552493
loop_
_publ_author_name
'Hou, Sheng-Li'
'Dong, Jie'
'Tang, Meng-Hua'
'Jiang, Xiao-Lei'
'Jiao, Zhuo-Hao'
'Zhao, Bin'
_publ_section_title
;
 Triple-Interpenetrated Lanthanide-Organic Framework as Dual Wave Bands
 Self-Calibrated pH Luminescent Probe.
;
_journal_issue                   8
_journal_name_full               'Analytical chemistry'
_journal_page_first              5455
_journal_page_last               5460
_journal_paper_doi               10.1021/acs.analchem.9b00848
_journal_volume                  91
_journal_year                    2019
_chemical_formula_moiety         'C28 H26 Eu N4 O9, H2 O'
_chemical_formula_sum            'C28 H28 Eu N4 O10'
_chemical_formula_weight         732.50
_space_group_crystal_system      monoclinic
_space_group_IT_number           14
_space_group_name_Hall           '-P 2ybc'
_space_group_name_H-M_alt        'P 1 21/c 1'
_symmetry_space_group_name_Hall  '-P 2ybc'
_symmetry_space_group_name_H-M   'P 1 21/c 1'
_atom_sites_solution_hydrogens   mixed
_atom_sites_solution_primary     direct
_audit_creation_date             2018-03-26
_audit_creation_method
;
Olex2 1.2
(compiled 2017.08.10 svn.r3458 for OlexSys, GUI svn.r5381)
;
_cell_angle_alpha                90
_cell_angle_beta                 94.581(2)
_cell_angle_gamma                90
_cell_formula_units_Z            4
_cell_length_a                   12.2038(2)
_cell_length_b                   22.0069(5)
_cell_length_c                   10.8009(2)
_cell_measurement_reflns_used    7560
_cell_measurement_temperature    120.00(10)
_cell_measurement_theta_max      28.9550
_cell_measurement_theta_min      3.4660
_cell_volume                     2891.51(10)
_computing_cell_refinement       'CrysAlisPro 1.171.39.29c (Rigaku OD, 2017)'
_computing_data_collection       'CrysAlisPro 1.171.39.29c (Rigaku OD, 2017)'
_computing_data_reduction        'CrysAlisPro 1.171.39.29c (Rigaku OD, 2017)'
_computing_molecular_graphics    'Olex2 (Dolomanov et al., 2009)'
_computing_publication_material  'Olex2 (Dolomanov et al., 2009)'
_computing_structure_refinement  'XL (Sheldrick, 2008)'
_computing_structure_solution    'XS (Sheldrick, 2008)'
_diffrn_ambient_environment      N~2~
_diffrn_ambient_temperature      120.00(10)
_diffrn_detector                 'CCD plate'
_diffrn_detector_area_resol_mean 16.2116
_diffrn_detector_type            Eos
_diffrn_measured_fraction_theta_full 0.998
_diffrn_measured_fraction_theta_max 0.998
_diffrn_measurement_details
;
List of Runs (angles in degrees, time in seconds):

  # Type    Start    End  Width  tₑₓₚ   ω     θ     κ     φ   Frames
--------------------------------------------------------------------------
  1  ω      1.00  89.00   1.00    6.78    --   18.63  37.00  90.00   88
  2  ω    -28.00  73.00   1.00    6.78    --   18.63   0.00-120.00  101
  3  ω    -94.00 -62.00   1.00    6.78    --  -19.56-178.00-150.00   32
;
_diffrn_measurement_device       'four-circle diffractometer'
_diffrn_measurement_device_type  'SuperNova, Single source at offset/far, Eos'
_diffrn_measurement_method       'ω scans'
_diffrn_orient_matrix_type
'CrysAlisPro convention (1999,Acta A55,543-557)'
_diffrn_orient_matrix_UB_11      0.0560938000
_diffrn_orient_matrix_UB_12      0.0081474000
_diffrn_orient_matrix_UB_13      0.0119334000
_diffrn_orient_matrix_UB_21      0.0108693000
_diffrn_orient_matrix_UB_22      -0.0106534000
_diffrn_orient_matrix_UB_23      -0.0597645000
_diffrn_orient_matrix_UB_31      -0.0116062000
_diffrn_orient_matrix_UB_32      0.0292836000
_diffrn_orient_matrix_UB_33      -0.0251688000
_diffrn_radiation_monochromator  mirror
_diffrn_radiation_probe          x-ray
_diffrn_radiation_type           MoK\a
_diffrn_radiation_wavelength     0.71073
_diffrn_reflns_av_R_equivalents  0.0200
_diffrn_reflns_av_unetI/netI     0.0293
_diffrn_reflns_Laue_measured_fraction_full 0.998
_diffrn_reflns_Laue_measured_fraction_max 0.998
_diffrn_reflns_limit_h_max       14
_diffrn_reflns_limit_h_min       -14
_diffrn_reflns_limit_k_max       26
_diffrn_reflns_limit_k_min       -25
_diffrn_reflns_limit_l_max       12
_diffrn_reflns_limit_l_min       -6
_diffrn_reflns_number            10802
_diffrn_reflns_point_group_measured_fraction_full 0.998
_diffrn_reflns_point_group_measured_fraction_max 0.998
_diffrn_reflns_theta_full        25.009
_diffrn_reflns_theta_max         25.009
_diffrn_reflns_theta_min         3.050
_diffrn_source                   'micro-focus sealed X-ray tube'
_diffrn_source_type              'SuperNova (Mo) X-ray Source'
_exptl_absorpt_coefficient_mu    2.233
_exptl_absorpt_correction_T_max  1.00000
_exptl_absorpt_correction_T_min  0.70995
_exptl_absorpt_correction_type   multi-scan
_exptl_absorpt_process_details
;
CrysAlisPro 1.171.39.29c (Rigaku Oxford Diffraction, 2017)
Empirical absorption correction using spherical harmonics,
 implemented in SCALE3 ABSPACK scaling algorithm.
;
_exptl_crystal_density_diffrn    1.683
_exptl_crystal_description       block
_exptl_crystal_F_000             1468
_refine_diff_density_max         1.301
_refine_diff_density_min         -1.219
_refine_diff_density_rms         0.114
_refine_ls_extinction_method     none
_refine_ls_goodness_of_fit_ref   1.054
_refine_ls_hydrogen_treatment    constr
_refine_ls_matrix_type           full
_refine_ls_number_parameters     392
_refine_ls_number_reflns         5092
_refine_ls_number_restraints     46
_refine_ls_restrained_S_all      1.198
_refine_ls_R_factor_all          0.0427
_refine_ls_R_factor_gt           0.0386
_refine_ls_shift/su_max          0.004
_refine_ls_shift/su_mean         0.000
_refine_ls_structure_factor_coef Fsqd
_refine_ls_weighting_details
'w=1/[σ²(Fo²)+(0.0510P)²+10.6330P] where P=(Fo²+2Fc²)/3'
_refine_ls_weighting_scheme      calc
_refine_ls_wR_factor_gt          0.1008
_refine_ls_wR_factor_ref         0.1042
_reflns_Friedel_coverage         0.000
_reflns_number_gt                4614
_reflns_number_total             5092
_reflns_threshold_expression     'I > 2σ(I)'
_cod_data_source_file            ac9b00848_si_002.cif
_cod_data_source_block           p171006f1
_cod_original_cell_volume        2891.51(11)
_cod_database_code               1552493
_shelx_shelxl_version_number     2014/7
_chemical_oxdiff_formula         'C N O Eu'
_chemical_oxdiff_usercomment     HSL-Eu
_shelx_space_group_comment
;
The symmetry employed for this shelxl refinement is uniquely defined
by the following loop, which should always be used as a source of
symmetry information in preference to the above space-group names.
They are only intended as comments.
;
_reflns_odcompleteness_completeness 99.79
_reflns_odcompleteness_iscentric 1
_reflns_odcompleteness_theta     26.32
_olex2_refinement_description
;
1. Fixed Uiso
 At 1.2 times of:
  All C(H) groups
 At 1.5 times of:
  All C(H,H,H) groups, All O(H,H) groups
2. Restrained distances
 HA-O0AA
 0.85 with sigma of 0.02
3. Rigid bond restraints
 N2BA, O1
 with sigma for 1-2 distances of 0.0001 and sigma for 1-3 distances of 0.0001
 O3, N2BA
 with sigma for 1-2 distances of 0.0001 and sigma for 1-3 distances of 0.0001
 Eu1
 with sigma for 1-2 distances of 0.002 and sigma for 1-3 distances of 0.001
 Eu1, O6
 with sigma for 1-2 distances of 0.002 and sigma for 1-3 distances of 0.001
4. Uiso/Uaniso restraints and constraints
Uanis(N0AA) \\sim Ueq, Uanis(C5BA) \\sim Ueq: with sigma of 0.005 and sigma for
terminal atoms of 0.005
Uanis(Eu1) \\sim Ueq: with sigma of 0.000005 and sigma for terminal atoms of
0.000005
5. Rigid body (RIGU) restrains
 O6, C4BA, N0AA, C5, C5BA
 with sigma for 1-2 distances of 0.0001 and sigma for 1-3 distances of 0.0001
6.a Riding coordinates:
 O0AA(H,HA)
6.b Aromatic/amide H refined with riding coordinates:
 C19(H19), C7(H7), C15(H15), C0AA(H0AA), C4(H4), C12(H12), C3AA(H3AA),
 C2AA(H2AA), C5AA(H5AA), C6AA(H6AA), C4AA(H4AA), C10(H10), C7AA(H7AA),
 C4BA(H4BA)
6.c Idealised Me refined as rotating group:
 C8AA(H8AC,H8AB,H8AA), C9AA(H9AC,H9AB,H9AA), C5BA(H5BB,H5BC,H5BA), C5(H5A,H5B,
 H5C)
;
_olex2_submission_special_instructions 'No special instructions were received'
_oxdiff_exptl_absorpt_empirical_details
;
Empirical correction (ABSPACK) includes:
- Absorption correction using spherical harmonics
- Frame scaling
;
_oxdiff_exptl_absorpt_empirical_full_max 1.384
_oxdiff_exptl_absorpt_empirical_full_min 0.651
loop_
_space_group_symop_operation_xyz
'x, y, z'
'-x, y+1/2, -z+1/2'
'-x, -y, -z'
'x, -y-1/2, z-1/2'
loop_
_atom_site_label
_atom_site_type_symbol
_atom_site_fract_x
_atom_site_fract_y
_atom_site_fract_z
_atom_site_U_iso_or_equiv
_atom_site_adp_type
_atom_site_occupancy
_atom_site_site_symmetry_order
_atom_site_calc_flag
_atom_site_refinement_flags_posn
_atom_site_refinement_flags_adp
Eu1 Eu 0.45349(2) 0.42492(2) 0.90576(2) 0.02560(11) Uani 1 1 d . U
O1 O 0.4137(3) 0.53893(15) 0.9399(3) 0.0296(7) Uani 1 1 d . U
O2 O 0.3577(3) 0.43720(16) 1.0929(3) 0.0334(8) Uani 1 1 d . .
O3 O 0.3225(3) 0.49305(16) 0.7840(3) 0.0340(8) Uani 1 1 d . U
O4 O 0.6194(3) 0.36020(16) 0.8821(3) 0.0365(8) Uani 1 1 d . .
O5 O 0.5006(3) 0.32662(16) 1.0093(4) 0.0387(9) Uani 1 1 d . .
O6 O 0.2803(4) 0.3680(2) 0.8897(5) 0.0563(9) Uani 1 1 d . U
O7 O 0.5730(3) 0.48490(15) 0.7902(3) 0.0313(8) Uani 1 1 d . .
O9 O 0.4254(3) 0.37800(18) 0.7010(4) 0.0440(9) Uani 1 1 d . .
C13 C 0.6665(4) 0.2699(2) 0.9970(5) 0.0300(10) Uani 1 1 d . .
C17 C 0.5905(4) 0.3218(2) 0.9594(5) 0.0308(11) Uani 1 1 d . .
C19 C 0.6453(4) 0.2313(2) 1.0924(5) 0.0343(11) Uani 1 1 d . .
H19 H 0.5824 0.2368 1.1343 0.041 Uiso 1 1 calc R .
N1 N 0.9698(3) 0.11542(18) 1.0239(4) 0.0276(9) Uani 1 1 d . .
C7 C 0.7177(4) 0.1840(2) 1.1266(5) 0.0334(11) Uani 1 1 d . .
H7 H 0.7026 0.1583 1.1915 0.040 Uiso 1 1 calc R .
C9 C 0.8118(4) 0.1749(2) 1.0651(5) 0.0284(10) Uani 1 1 d . .
C11 C 0.8949(4) 0.1273(2) 1.1056(4) 0.0278(10) Uani 1 1 d . .
C15 C 0.7600(5) 0.2604(3) 0.9340(5) 0.0387(13) Uani 1 1 d . .
H15 H 0.7750 0.2860 0.8690 0.046 Uiso 1 1 calc R .
C0AA C 0.8307(4) 0.2130(3) 0.9674(5) 0.0384(13) Uani 1 1 d . .
H0AA H 0.8922 0.2067 0.9234 0.046 Uiso 1 1 calc R .
C1AA C 1.1311(4) 0.0636(2) 0.9626(5) 0.0272(10) Uani 1 1 d . .
C2 C 1.0501(4) 0.0753(2) 1.0572(5) 0.0274(10) Uani 1 1 d . .
C3 C 0.9819(4) 0.0589(2) 1.2589(5) 0.0295(10) Uani 1 1 d . .
C4 C 0.8975(4) 0.0999(2) 1.2223(4) 0.0271(10) Uani 1 1 d . .
H4 H 0.8435 0.1088 1.2755 0.033 Uiso 1 1 calc R .
C6 C 0.9908(4) 0.0297(2) 1.3829(5) 0.0298(11) Uani 1 1 d . .
C12 C 1.0579(4) 0.0469(2) 1.1729(5) 0.0309(11) Uani 1 1 d . .
H12 H 1.1147 0.0195 1.1928 0.037 Uiso 1 1 calc R .
C3AA C 1.1878(5) 0.0763(2) 0.7553(5) 0.0374(13) Uani 1 1 d . .
H3AA H 1.1755 0.0931 0.6764 0.045 Uiso 1 1 calc R .
C2AA C 1.1120(5) 0.0862(3) 0.8428(5) 0.0379(12) Uani 1 1 d . .
H2AA H 1.0482 0.1081 0.8210 0.045 Uiso 1 1 calc R .
C5AA C 1.0909(4) 0.0079(2) 1.4349(5) 0.0334(11) Uani 1 1 d . .
H5AA H 1.1534 0.0134 1.3922 0.040 Uiso 1 1 calc R .
C6AA C 0.8995(4) 0.0217(3) 1.4520(5) 0.0343(12) Uani 1 1 d . .
H6AA H 0.8313 0.0366 1.4212 0.041 Uiso 1 1 calc R .
C4AA C 1.2256(4) 0.0304(3) 0.9918(5) 0.0364(12) Uani 1 1 d . .
H4AA H 1.2398 0.0153 1.0718 0.044 Uiso 1 1 calc R .
C10 C 1.2996(4) 0.0193(3) 0.9038(5) 0.0382(12) Uani 1 1 d . .
H10 H 1.3623 -0.0036 0.9254 0.046 Uiso 1 1 calc R .
N4 N 0.4518(5) 0.3604(2) 0.4987(5) 0.0506(13) Uani 1 1 d . .
C7AA C 0.4741(5) 0.3867(3) 0.6084(6) 0.0474(14) Uani 1 1 d . .
H7AA H 0.5321 0.4142 0.6152 0.057 Uiso 1 1 calc R .
C8AA C 0.3635(6) 0.3174(3) 0.4790(7) 0.065(2) Uani 1 1 d . .
H8AC H 0.3932 0.2773 0.4714 0.098 Uiso 1 1 calc GR .
H8AB H 0.3194 0.3276 0.4043 0.098 Uiso 1 1 calc GR .
H8AA H 0.3188 0.3185 0.5482 0.098 Uiso 1 1 calc GR .
C9AA C 0.5208(7) 0.3725(4) 0.3970(7) 0.0652(19) Uani 1 1 d . .
H9AC H 0.5698 0.4055 0.4195 0.098 Uiso 1 1 calc GR .
H9AB H 0.4751 0.3832 0.3237 0.098 Uiso 1 1 calc GR .
H9AA H 0.5627 0.3369 0.3810 0.098 Uiso 1 1 calc GR .
C0BA C 1.2819(4) 0.0418(2) 0.7843(5) 0.0294(11) Uani 1 1 d . .
C1BA C 0.6375(4) 0.5286(2) 0.8117(5) 0.0297(11) Uani 1 1 d . .
N2BA N 0.3433(4) 0.5405(2) 0.8461(4) 0.0388(9) Uani 1 1 d . U
O3BA O 0.2846(5) 0.5996(3) 0.8122(6) 0.0882(18) Uani 1 1 d . .
N0AA N 0.1436(5) 0.3012(3) 0.8529(6) 0.0657(12) Uani 1 1 d . U
C4BA C 0.2334(6) 0.3314(4) 0.8299(8) 0.0739(15) Uani 1 1 d . U
H4BA H 0.2628 0.3219 0.7555 0.089 Uiso 1 1 calc R .
C5BA C 0.0901(7) 0.3146(4) 0.9546(9) 0.0862(18) Uani 1 1 d . U
H5BB H 0.0978 0.2815 1.0124 0.129 Uiso 1 1 calc GR .
H5BC H 0.0137 0.3212 0.9304 0.129 Uiso 1 1 calc GR .
H5BA H 0.1211 0.3507 0.9930 0.129 Uiso 1 1 calc GR .
C5 C 0.0986(9) 0.2562(6) 0.7732(11) 0.136(3) Uani 1 1 d . U
H5A H 0.1388 0.2543 0.7004 0.204 Uiso 1 1 calc GR .
H5B H 0.0230 0.2656 0.7495 0.204 Uiso 1 1 calc GR .
H5C H 0.1030 0.2176 0.8149 0.204 Uiso 1 1 calc GR .
O0AA O 0.3308(8) 0.3048(4) 1.1625(9) 0.150(3) Uani 1 1 d D .
H H 0.3978 0.3102 1.1489 0.224 Uiso 1 1 d R .
HA H 0.2899 0.3171 1.0794 0.224 Uiso 1 1 d DR .
loop_
_atom_type_symbol
_atom_type_description
_atom_type_scat_dispersion_real
_atom_type_scat_dispersion_imag
_atom_type_scat_source
C C 0.0033 0.0016 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
H H 0.0000 0.0000 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
Eu Eu -0.1578 3.6682 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
N N 0.0061 0.0033 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
O O 0.0106 0.0060 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
loop_
_geom_angle_atom_site_label_1
_geom_angle_atom_site_label_2
_geom_angle_atom_site_label_3
_geom_angle
_geom_angle_site_symmetry_1
_geom_angle_site_symmetry_3
O1 Eu1 Eu1 34.40(7) . 3_667
O1 Eu1 Eu1 38.12(8) 3_667 3_667
O1 Eu1 O1 72.52(12) 3_667 .
O1 Eu1 O2 74.01(12) 3_667 .
O1 Eu1 O3 122.97(11) 3_667 .
O1 Eu1 O4 75.50(12) 3_667 .
O1 Eu1 O5 81.63(12) 3_667 .
O1 Eu1 O6 139.41(14) 3_667 .
O1 Eu1 O7 76.73(12) 3_667 .
O1 Eu1 O9 144.99(12) 3_667 .
O1 Eu1 C17 76.54(13) 3_667 .
O1 Eu1 C17 148.95(13) . .
O1 Eu1 N2BA 25.84(11) . .
O1 Eu1 N2BA 98.04(12) 3_667 .
O2 Eu1 Eu1 67.69(8) . 3_667
O2 Eu1 O1 70.46(11) . .
O2 Eu1 O3 92.37(12) . .
O2 Eu1 O4 126.49(12) . .
O2 Eu1 O5 80.30(12) . .
O2 Eu1 O6 69.30(15) . .
O2 Eu1 O9 139.39(13) . .
O2 Eu1 C17 103.46(13) . .
O2 Eu1 N2BA 80.99(12) . .
O3 Eu1 Eu1 85.15(8) . 3_667
O3 Eu1 O1 51.05(11) . .
O3 Eu1 O4 141.13(12) . .
O3 Eu1 C17 158.16(13) . .
O3 Eu1 N2BA 25.22(12) . .
O4 Eu1 Eu1 108.84(9) . 3_667
O4 Eu1 O1 136.73(12) . .
O4 Eu1 C17 26.17(13) . .
O4 Eu1 N2BA 146.41(12) . .
O5 Eu1 Eu1 116.41(10) . 3_667
O5 Eu1 O1 145.13(12) . .
O5 Eu1 O3 151.53(12) . .
O5 Eu1 O4 52.44(11) . .
O5 Eu1 C17 26.29(13) . .
O5 Eu1 N2BA 160.60(12) . .
O6 Eu1 Eu1 131.82(12) . 3_667
O6 Eu1 O1 109.59(13) . .
O6 Eu1 O3 75.92(13) . .
O6 Eu1 O4 113.67(15) . .
O6 Eu1 O5 75.75(14) . .
O6 Eu1 C17 95.50(15) . .
O6 Eu1 N2BA 92.87(14) . .
O7 Eu1 Eu1 69.48(8) . 3_667
O7 Eu1 O1 70.64(11) . .
O7 Eu1 O2 136.64(12) . .
O7 Eu1 O3 77.56(12) . .
O7 Eu1 O4 74.26(12) . .
O7 Eu1 O5 125.96(12) . .
O7 Eu1 O6 143.47(14) . .
O7 Eu1 O9 78.92(13) . .
O7 Eu1 C17 99.97(13) . .
O7 Eu1 N2BA 72.19(12) . .
O9 Eu1 Eu1 145.58(10) . 3_667
O9 Eu1 O1 121.67(12) . .
O9 Eu1 O3 74.82(13) . .
O9 Eu1 O4 73.92(13) . .
O9 Eu1 O5 92.89(14) . .
O9 Eu1 O6 70.22(15) . .
O9 Eu1 C17 83.39(14) . .
O9 Eu1 N2BA 98.02(13) . .
C17 Eu1 Eu1 114.62(10) . 3_667
C17 Eu1 N2BA 171.48(14) . .
N2BA Eu1 Eu1 60.02(9) . 3_667
Eu1 O1 Eu1 107.48(12) 3_667 .
N2BA O1 Eu1 158.4(3) . 3_667
N2BA O1 Eu1 92.0(3) . .
C1BA O2 Eu1 138.1(3) 3_667 .
N2BA O3 Eu1 97.2(3) . .
C17 O4 Eu1 92.5(3) . .
C17 O5 Eu1 93.4(3) . .
C4BA O6 Eu1 141.4(6) . .
C1BA O7 Eu1 136.6(3) . .
C7AA O9 Eu1 129.4(4) . .
C19 C13 C17 121.5(5) . .
C19 C13 C15 119.0(5) . .
C15 C13 C17 119.5(5) . .
O4 C17 Eu1 61.4(3) . .
O4 C17 O5 121.6(5) . .
O4 C17 C13 119.3(4) . .
O5 C17 Eu1 60.3(3) . .
O5 C17 C13 119.0(5) . .
C13 C17 Eu1 175.4(4) . .
C13 C19 C7 120.4(5) . .
C11 N1 C2 118.1(4) . .
C9 C7 C19 120.8(5) . .
C7 C9 C11 121.9(4) . .
C0AA C9 C7 118.2(5) . .
C0AA C9 C11 119.8(4) . .
N1 C11 C9 115.1(4) . .
N1 C11 C4 122.7(4) . .
C4 C11 C9 122.1(4) . .
C0AA C15 C13 120.3(5) . .
C9 C0AA C15 121.2(5) . .
C2AA C1AA C2 120.2(5) . .
C4AA C1AA C2 121.3(4) . .
C4AA C1AA C2AA 118.5(5) . .
N1 C2 C1AA 115.9(4) . .
N1 C2 C12 122.0(5) . .
C12 C2 C1AA 122.1(4) . .
C4 C3 C6 122.3(4) . .
C12 C3 C4 116.6(5) . .
C12 C3 C6 121.1(5) . .
C11 C4 C3 119.7(4) . .
C5AA C6 C3 120.9(4) . .
C5AA C6 C6AA 116.9(5) . .
C6AA C6 C3 122.2(5) . .
C3 C12 C2 120.8(5) . .
C2AA C3AA C0BA 120.9(5) . .
C1AA C2AA C3AA 120.4(5) . .
C6AA C5AA C6 122.0(5) 3_758 .
C5AA C6AA C6 121.0(5) 3_758 .
C1AA C4AA C10 121.1(5) . .
C0BA C10 C4AA 121.0(5) . .
C7AA N4 C8AA 121.1(6) . .
C7AA N4 C9AA 120.2(6) . .
C8AA N4 C9AA 118.7(6) . .
O9 C7AA N4 125.9(6) . .
C3AA C0BA C1BA 121.4(5) . 2_746
C10 C0BA C3AA 118.0(5) . .
C10 C0BA C1BA 120.6(5) . 2_746
O2 C1BA C0BA 116.8(4) 3_667 2_756
O7 C1BA O2 126.3(4) . 3_667
O7 C1BA C0BA 116.9(4) . 2_756
O1 N2BA Eu1 62.1(2) . .
O1 N2BA O3BA 119.4(4) . .
O3 N2BA Eu1 57.6(2) . .
O3 N2BA O1 119.7(4) . .
O3 N2BA O3BA 120.9(4) . .
O3BA N2BA Eu1 178.5(4) . .
C4BA N0AA C5BA 120.2(7) . .
C4BA N0AA C5 122.2(8) . .
C5BA N0AA C5 117.6(7) . .
O6 C4BA N0AA 128.8(9) . .
loop_
_geom_bond_atom_site_label_1
_geom_bond_atom_site_label_2
_geom_bond_distance
_geom_bond_site_symmetry_2
Eu1 Eu1 3.9980(5) 3_667
Eu1 O1 2.587(3) .
Eu1 O1 2.368(3) 3_667
Eu1 O2 2.429(3) .
Eu1 O3 2.490(3) .
Eu1 O4 2.505(3) .
Eu1 O5 2.482(4) .
Eu1 O6 2.452(4) .
Eu1 O7 2.392(3) .
Eu1 O9 2.440(4) .
Eu1 C17 2.851(5) .
Eu1 N2BA 2.925(5) .
O1 Eu1 2.368(3) 3_667
O1 N2BA 1.276(6) .
O2 C1BA 1.274(6) 3_667
O3 N2BA 1.256(6) .
O4 C17 1.259(6) .
O5 C17 1.265(6) .
O6 C4BA 1.155(8) .
O7 C1BA 1.252(6) .
O9 C7AA 1.219(7) .
C13 C17 1.507(7) .
C13 C19 1.374(7) .
C13 C15 1.391(7) .
C19 C7 1.396(7) .
N1 C11 1.345(6) .
N1 C2 1.346(6) .
C7 C9 1.387(7) .
C9 C11 1.499(7) .
C9 C0AA 1.382(7) .
C11 C4 1.395(7) .
C15 C0AA 1.384(7) .
C1AA C2 1.499(7) .
C1AA C2AA 1.388(7) .
C1AA C4AA 1.380(7) .
C2 C12 1.395(7) .
C3 C4 1.402(7) .
C3 C6 1.482(7) .
C3 C12 1.390(7) .
C6 C5AA 1.389(7) .
C6 C6AA 1.401(7) .
C3AA C2AA 1.391(8) .
C3AA C0BA 1.392(8) .
C5AA C6AA 1.381(7) 3_758
C6AA C5AA 1.381(7) 3_758
C4AA C10 1.384(7) .
C10 C0BA 1.383(7) .
N4 C7AA 1.327(8) .
N4 C8AA 1.438(9) .
N4 C9AA 1.460(9) .
C0BA C1BA 1.513(7) 2_746
C1BA O2 1.274(6) 3_667
C1BA C0BA 1.513(7) 2_756
N2BA O3BA 1.515(7) .
N0AA C4BA 1.322(9) .
N0AA C5BA 1.354(10) .
N0AA C5 1.395(11) .
