#------------------------------------------------------------------------------
#$Date: 2020-05-30 08:15:24 +0300 (Sat, 30 May 2020) $
#$Revision: 252489 $
#$URL: file:///home/coder/svn-repositories/cod/cif/1/55/81/1558159.cif $
#------------------------------------------------------------------------------
#
# This file is available in the Crystallography Open Database (COD),
# http://www.crystallography.net/. The original data for this entry
# were provided by IUCr Journals, http://journals.iucr.org/.
#
# The file may be used within the scientific community so long as
# proper attribution is given to the journal article from which the
# data were obtained.
#
data_1558159
loop_
_publ_author_name
'Alanazi, Saud A.'
'Abdel-Wahab, Bakr F.'
'Hegazy, Amany S.'
'Kariuki, Benson M.'
'El-Hiti, Gamal A.'
_publ_section_title
;
 2-[3-(4-Chlorophenyl)-5-(4-fluorophenyl)-4,5-dihydro-1H-pyrazol-1-yl]-5-[(4-fluorophenyl)diazenyl]-4-methylthiazole
;
_journal_coeditor_code           ZL4041
_journal_issue                   5
_journal_name_full               IUCrData
_journal_page_first              x200700
_journal_paper_doi               10.1107/S2414314620007002
_journal_volume                  5
_journal_year                    2020
_chemical_formula_iupac          'C25 H18 Cl F2 N5 S'
_chemical_formula_moiety         'C25 H18 Cl F2 N5 S'
_chemical_formula_sum            'C25 H18 Cl F2 N5 S'
_chemical_formula_weight         493.95
_chemical_name_systematic
2-[3-(4-Chlorophenyl)-5-(4-fluorophenyl)-4,5-dihydro-1H-pyrazol-1-yl]-5-[(4-fluorophenyl)diazenyl]-4-methylthiazole
_space_group_crystal_system      monoclinic
_space_group_IT_number           14
_space_group_name_Hall           '-P 2ybc'
_space_group_name_H-M_alt        'P 1 21/c 1'
_atom_sites_solution_hydrogens   geom
_atom_sites_solution_primary     direct
_atom_sites_solution_secondary   difmap
_audit_creation_method           SHELXL-2018/1
_cell_angle_alpha                90
_cell_angle_beta                 92.891(4)
_cell_angle_gamma                90
_cell_formula_units_Z            4
_cell_length_a                   16.9376(6)
_cell_length_b                   13.1440(4)
_cell_length_c                   10.6399(4)
_cell_measurement_reflns_used    6505
_cell_measurement_temperature    293(2)
_cell_measurement_theta_max      26.8130
_cell_measurement_theta_min      3.5210
_cell_volume                     2365.72(14)
_computing_cell_refinement
;
CrysAlis PRO (Rigaku OD, 2015)
;
_computing_data_collection
;
CrysAlis PRO (Rigaku OD, 2015)
;
_computing_data_reduction
;
CrysAlis PRO (Rigaku OD, 2015)
;
_computing_molecular_graphics
;
CHEMDRAW Ultra (Cambridge Soft, 2001), WinGx (Farrugia,
2012)
;
_computing_publication_material
;
CHEMDRAW Ultra (Cambridge Soft, 2001), WinGx (Farrugia,
2012)
;
_computing_structure_refinement
;
SHELXL (Sheldrick, 2015)
;
_computing_structure_solution
;
SHELXS (Sheldrick, 2008)
;
_diffrn_ambient_temperature      293(2)
_diffrn_measured_fraction_theta_full 0.998
_diffrn_measured_fraction_theta_max 0.872
_diffrn_measurement_device_type
'Rigaku Oxford Diffraction SuperNova, Dual, Cu at zero, Atlas'
_diffrn_measurement_method       'ω scans'
_diffrn_radiation_type           MoK\a
_diffrn_radiation_wavelength     0.71073
_diffrn_reflns_av_R_equivalents  0.0273
_diffrn_reflns_av_unetI/netI     0.0289
_diffrn_reflns_limit_h_max       23
_diffrn_reflns_limit_h_min       -17
_diffrn_reflns_limit_k_max       17
_diffrn_reflns_limit_k_min       -18
_diffrn_reflns_limit_l_max       14
_diffrn_reflns_limit_l_min       -14
_diffrn_reflns_number            21848
_diffrn_reflns_theta_full        25.242
_diffrn_reflns_theta_max         29.847
_diffrn_reflns_theta_min         3.100
_diffrn_standards_decay_%        0
_diffrn_standards_interval_count 0
_diffrn_standards_interval_time  0
_diffrn_standards_number         0
_exptl_absorpt_coefficient_mu    0.289
_exptl_absorpt_correction_T_max  1.000
_exptl_absorpt_correction_T_min  0.727
_exptl_absorpt_correction_type   gaussian
_exptl_absorpt_process_details
;
(CrysAlisPro; Rigaku OD, 2015)
;
_exptl_crystal_colour            colourless
_exptl_crystal_density_diffrn    1.387
_exptl_crystal_description       plate
_exptl_crystal_F_000             1016
_exptl_crystal_size_max          0.318
_exptl_crystal_size_mid          0.185
_exptl_crystal_size_min          0.041
_refine_diff_density_max         0.140
_refine_diff_density_min         -0.206
_refine_ls_extinction_method     none
_refine_ls_goodness_of_fit_ref   1.016
_refine_ls_hydrogen_treatment    constr
_refine_ls_matrix_type           full
_refine_ls_number_parameters     364
_refine_ls_number_reflns         5930
_refine_ls_number_restraints     255
_refine_ls_restrained_S_all      1.009
_refine_ls_R_factor_all          0.0955
_refine_ls_R_factor_gt           0.0484
_refine_ls_shift/su_max          0.001
_refine_ls_shift/su_mean         0.000
_refine_ls_structure_factor_coef Fsqd
_refine_ls_weighting_details
'w=1/[σ²(Fo²)+(0.0445P)²+0.6409P] where P=(Fo²+2Fc²)/3'
_refine_ls_weighting_scheme      calc
_refine_ls_wR_factor_gt          0.1036
_refine_ls_wR_factor_ref         0.1252
_reflns_number_gt                3549
_reflns_number_total             5930
_reflns_threshold_expression     'I > 2σ(I)'
_cod_data_source_file            zl4041sup1.cif
_cod_data_source_block           I
_cod_original_sg_symbol_H-M      'P 21/c'
_cod_database_code               1558159
_shelx_space_group_comment
;
The symmetry employed for this shelxl refinement is uniquely defined
by the following loop, which should always be used as a source of
symmetry information in preference to the above space-group names.
They are only intended as comments.
;
_shelx_estimated_absorpt_t_min   0.914
_shelx_estimated_absorpt_t_max   0.988
loop_
_space_group_symop_operation_xyz
'x, y, z'
'-x, y+1/2, -z+1/2'
'-x, -y, -z'
'x, -y-1/2, z-1/2'
loop_
_atom_site_type_symbol
_atom_site_label
_atom_site_fract_x
_atom_site_fract_y
_atom_site_fract_z
_atom_site_U_iso_or_equiv
_atom_site_adp_type
_atom_site_calc_flag
_atom_site_occupancy
_atom_site_disorder_assembly
_atom_site_disorder_group
C C1 0.91410(14) -0.11438(18) 0.8797(2) 0.0725(6) Uani d 1 . .
C C2 0.87189(13) -0.18539(17) 0.8117(2) 0.0713(6) Uani d 1 . .
H H2 0.855169 -0.245141 0.848925 0.086 Uiso calc 1 . .
C C3 0.85468(13) -0.16585(16) 0.6857(2) 0.0671(6) Uani d 1 . .
H H3 0.826052 -0.213282 0.637229 0.081 Uiso calc 1 . .
C C4 0.87930(12) -0.07710(16) 0.6308(2) 0.0621(5) Uani d 1 . .
C C5 0.92300(13) -0.00652(17) 0.7036(2) 0.0704(6) Uani d 1 . .
H H5 0.940622 0.053154 0.667359 0.085 Uiso calc 1 . .
C C6 0.93986(14) -0.02567(18) 0.8292(2) 0.0774(6) Uani d 1 . .
H H6 0.968353 0.021092 0.878928 0.093 Uiso calc 1 . .
C C7 0.85842(12) 0.03407(15) 0.3320(2) 0.0626(5) Uani d 1 . .
C C8 0.87394(12) 0.11841(15) 0.2618(2) 0.0656(6) Uani d 1 . .
C C9 0.80263(12) 0.03318(14) 0.1218(2) 0.0601(5) Uani d 1 . .
C C10 0.92100(14) 0.20868(18) 0.3087(3) 0.0885(8) Uani d 1 . .
H H10A 0.932863 0.201734 0.397511 0.133 Uiso calc 0.57(3) . .
H H10B 0.890877 0.269636 0.293062 0.133 Uiso calc 0.57(3) . .
H H10C 0.969369 0.212399 0.265659 0.133 Uiso calc 0.57(3) . .
H H10D 0.929210 0.254112 0.239977 0.133 Uiso calc 0.43(3) . .
H H10E 0.971196 0.186210 0.344426 0.133 Uiso calc 0.43(3) . .
H H10F 0.892703 0.243447 0.371829 0.133 Uiso calc 0.43(3) . .
C C11 0.74684(12) 0.08582(15) -0.09277(19) 0.0619(5) Uani d 1 . .
H H11 0.796880 0.108379 -0.125855 0.074 Uiso calc 1 A 1
C C12 0.70269(14) 0.01744(15) -0.1895(2) 0.0663(6) Uani d 1 . .
H H12A 0.652423 0.047161 -0.217543 0.080 Uiso calc 1 . .
H H12B 0.733981 0.005413 -0.261916 0.080 Uiso calc 1 . .
C C13 0.69096(12) -0.07930(14) -0.11686(19) 0.0575(5) Uani d 1 . .
C C14 0.69975(11) 0.17716(14) -0.05306(19) 0.0558(5) Uani d 0.767(10) B 1
C C15 0.6495(3) 0.1762(4) 0.0439(5) 0.0655(13) Uani d 0.767(10) B 1
H H15 0.643982 0.116965 0.090367 0.079 Uiso calc 0.767(10) B 1
C C16 0.6071(3) 0.2618(4) 0.0739(6) 0.0750(14) Uani d 0.767(10) B 1
H H16 0.573373 0.260671 0.140280 0.090 Uiso calc 0.767(10) B 1
C C17 0.6154(4) 0.3473(4) 0.0048(6) 0.0683(12) Uani d 0.767(10) B 1
C C18 0.6614(2) 0.3505(3) -0.0949(5) 0.0728(11) Uani d 0.767(10) B 1
H H18 0.664560 0.409543 -0.142531 0.087 Uiso calc 0.767(10) B 1
C C19 0.7038(2) 0.2650(3) -0.1254(5) 0.0640(10) Uani d 0.767(10) B 1
H H19 0.735132 0.266155 -0.194617 0.077 Uiso calc 0.767(10) B 1
F F2 0.5728(5) 0.4315(5) 0.0333(6) 0.1030(16) Uani d 0.767(10) B 1
C C14B 0.69975(11) 0.17716(14) -0.05306(19) 0.0558(5) Uani d 0.233(10) B 2
C C15B 0.6368(10) 0.1597(14) 0.0220(18) 0.062(2) Uani d 0.233(10) B 2
H H15B 0.624555 0.093644 0.045623 0.074 Uiso calc 0.233(10) B 2
C C16B 0.5927(11) 0.2392(12) 0.061(2) 0.066(2) Uani d 0.233(10) B 2
H H16B 0.549429 0.227761 0.109998 0.079 Uiso calc 0.233(10) B 2
C C17B 0.6127(14) 0.3346(14) 0.029(3) 0.072(2) Uani d 0.233(10) B 2
C C18B 0.6792(8) 0.3578(9) -0.0333(16) 0.070(2) Uani d 0.233(10) B 2
H H18B 0.693605 0.424663 -0.049414 0.084 Uiso calc 0.233(10) B 2
C C19B 0.7238(8) 0.2759(8) -0.0711(16) 0.068(2) Uani d 0.233(10) B 2
H H19B 0.771021 0.287906 -0.109519 0.081 Uiso calc 0.233(10) B 2
F F2B 0.5692(13) 0.4152(14) 0.0696(19) 0.089(4) Uani d 0.233(10) B 2
C C20 0.64915(12) -0.16914(15) -0.16629(18) 0.0575(5) Uani d 1 . .
C C21 0.60277(15) -0.16523(18) -0.2771(2) 0.0760(6) Uani d 1 . .
H H21 0.596607 -0.103776 -0.319834 0.091 Uiso calc 1 . .
C C22 0.56563(16) -0.2511(2) -0.3250(2) 0.0843(7) Uani d 1 . .
H H22 0.535116 -0.247636 -0.400041 0.101 Uiso calc 1 . .
C C23 0.57369(13) -0.34122(17) -0.2621(2) 0.0705(6) Uani d 1 . .
C C24 0.61747(14) -0.34719(17) -0.1505(2) 0.0766(6) Uani d 1 . .
H H24 0.621560 -0.408430 -0.106855 0.092 Uiso calc 1 . .
C C25 0.65523(13) -0.26174(16) -0.1037(2) 0.0688(6) Uani d 1 . .
H H25 0.685526 -0.265981 -0.028541 0.083 Uiso calc 1 . .
N N1 0.85765(10) -0.06409(13) 0.50112(17) 0.0643(4) Uani d 1 . .
N N2 0.88125(10) 0.01956(14) 0.45499(17) 0.0657(5) Uani d 1 . .
N N3 0.84226(10) 0.11839(12) 0.14170(18) 0.0656(5) Uani d 1 . .
N N4 0.76260(10) 0.01344(12) 0.01117(17) 0.0649(5) Uani d 1 . .
N N5 0.72506(10) -0.07906(12) -0.00653(16) 0.0606(4) Uani d 1 . .
S S1 0.80048(3) -0.05346(4) 0.24354(5) 0.06286(17) Uani d 1 . .
F F1 0.93157(10) -0.13275(12) 1.00396(13) 0.1024(5) Uani d 1 . .
Cl Cl1 0.52834(4) -0.44993(5) -0.32473(8) 0.1043(3) Uani d 1 . .
loop_
_atom_type_symbol
_atom_type_description
_atom_type_scat_dispersion_real
_atom_type_scat_dispersion_imag
_atom_type_scat_source
C C 0.0033 0.0016 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
H H 0.0000 0.0000 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
N N 0.0061 0.0033 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
Cl Cl 0.1484 0.1585 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
S S 0.1246 0.1234 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
F F 0.0171 0.0103 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
loop_
_geom_angle_atom_site_label_1
_geom_angle_atom_site_label_2
_geom_angle_atom_site_label_3
_geom_angle_site_symmetry_1
_geom_angle_site_symmetry_3
_geom_angle
_geom_angle_publ_flag
C2 C1 F1 . . 118.5(2) ?
C2 C1 C6 . . 123.2(2) ?
F1 C1 C6 . . 118.4(2) ?
C1 C2 C3 . . 117.9(2) ?
C1 C2 H2 . . 121.1 ?
C3 C2 H2 . . 121.1 ?
C4 C3 C2 . . 121.0(2) ?
C4 C3 H3 . . 119.5 ?
C2 C3 H3 . . 119.5 ?
C3 C4 C5 . . 119.3(2) ?
C3 C4 N1 . . 116.42(18) ?
C5 C4 N1 . . 124.2(2) ?
C6 C5 C4 . . 119.7(2) ?
C6 C5 H5 . . 120.1 ?
C4 C5 H5 . . 120.1 ?
C1 C6 C5 . . 118.9(2) ?
C1 C6 H6 . . 120.5 ?
C5 C6 H6 . . 120.5 ?
N2 C7 C8 . . 125.8(2) ?
N2 C7 S1 . . 123.29(16) ?
C8 C7 S1 . . 110.82(17) ?
N3 C8 C7 . . 115.76(19) ?
N3 C8 C10 . . 119.3(2) ?
C7 C8 C10 . . 124.9(2) ?
N3 C9 N4 . . 122.10(19) ?
N3 C9 S1 . . 118.06(17) ?
N4 C9 S1 . . 119.83(15) ?
C8 C10 H10A . . 109.5 ?
C8 C10 H10B . . 109.5 ?
H10A C10 H10B . . 109.5 ?
C8 C10 H10C . . 109.5 ?
H10A C10 H10C . . 109.5 ?
H10B C10 H10C . . 109.5 ?
C8 C10 H10D . . 109.5 ?
H10A C10 H10D . . 141.1 ?
H10B C10 H10D . . 56.3 ?
H10C C10 H10D . . 56.3 ?
C8 C10 H10E . . 109.5 ?
H10A C10 H10E . . 56.3 ?
H10B C10 H10E . . 141.1 ?
H10C C10 H10E . . 56.3 ?
H10D C10 H10E . . 109.5 ?
C8 C10 H10F . . 109.5 ?
H10A C10 H10F . . 56.3 ?
H10B C10 H10F . . 56.3 ?
H10C C10 H10F . . 141.1 ?
H10D C10 H10F . . 109.5 ?
H10E C10 H10F . . 109.5 ?
N4 C11 C14B . . 112.39(17) ?
N4 C11 C14 . . 112.39(17) ?
N4 C11 C12 . . 100.91(15) ?
C14B C11 C12 . . 113.99(17) ?
C14 C11 C12 . . 113.99(17) ?
N4 C11 H11 . . 109.7 ?
C14 C11 H11 . . 109.7 ?
C12 C11 H11 . . 109.7 ?
C13 C12 C11 . . 102.89(16) ?
C13 C12 H12A . . 111.2 ?
C11 C12 H12A . . 111.2 ?
C13 C12 H12B . . 111.2 ?
C11 C12 H12B . . 111.2 ?
H12A C12 H12B . . 109.1 ?
N5 C13 C20 . . 121.30(18) ?
N5 C13 C12 . . 113.75(18) ?
C20 C13 C12 . . 124.86(18) ?
C15 C14 C19 . . 118.3(3) ?
C15 C14 C11 . . 124.0(3) ?
C19 C14 C11 . . 117.6(2) ?
C14 C15 C16 . . 121.2(4) ?
C14 C15 H15 . . 119.4 ?
C16 C15 H15 . . 119.4 ?
C17 C16 C15 . . 118.7(5) ?
C17 C16 H16 . . 120.7 ?
C15 C16 H16 . . 120.7 ?
C18 C17 C16 . . 122.2(4) ?
C18 C17 F2 . . 118.8(4) ?
C16 C17 F2 . . 118.8(4) ?
C17 C18 C19 . . 119.1(3) ?
C17 C18 H18 . . 120.4 ?
C19 C18 H18 . . 120.4 ?
C18 C19 C14 . . 120.3(3) ?
C18 C19 H19 . . 119.8 ?
C14 C19 H19 . . 119.8 ?
C19B C14B C15B . . 118.6(9) ?
C19B C14B C11 . . 123.0(5) ?
C15B C14B C11 . . 117.5(8) ?
C16B C15B C14B . . 120.1(13) ?
C16B C15B H15B . . 120.0 ?
C14B C15B H15B . . 120.0 ?
C17B C16B C15B . . 119.1(15) ?
C17B C16B H16B . . 120.4 ?
C15B C16B H16B . . 120.4 ?
C16B C17B C18B . . 123.6(13) ?
C16B C17B F2B . . 119.5(14) ?
C18B C17B F2B . . 116.6(15) ?
C17B C18B C19B . . 116.2(11) ?
C17B C18B H18B . . 121.9 ?
C19B C18B H18B . . 121.9 ?
C14B C19B C18B . . 121.5(9) ?
C14B C19B H19B . . 119.2 ?
C18B C19B H19B . . 119.2 ?
C21 C20 C25 . . 117.8(2) ?
C21 C20 C13 . . 121.36(18) ?
C25 C20 C13 . . 120.86(19) ?
C22 C21 C20 . . 120.9(2) ?
C22 C21 H21 . . 119.6 ?
C20 C21 H21 . . 119.6 ?
C23 C22 C21 . . 119.8(2) ?
C23 C22 H22 . . 120.1 ?
C21 C22 H22 . . 120.1 ?
C22 C23 C24 . . 120.8(2) ?
C22 C23 Cl1 . . 119.6(2) ?
C24 C23 Cl1 . . 119.62(19) ?
C23 C24 C25 . . 119.3(2) ?
C23 C24 H24 . . 120.4 ?
C25 C24 H24 . . 120.4 ?
C24 C25 C20 . . 121.4(2) ?
C24 C25 H25 . . 119.3 ?
C20 C25 H25 . . 119.3 ?
N2 N1 C4 . . 114.00(17) ?
N1 N2 C7 . . 114.31(18) ?
C9 N3 C8 . . 108.94(17) ?
C9 N4 N5 . . 119.63(16) ?
C9 N4 C11 . . 126.37(17) ?
N5 N4 C11 . . 113.68(16) ?
C13 N5 N4 . . 108.07(16) ?
C9 S1 C7 . . 86.43(10) ?
loop_
_geom_bond_atom_site_label_1
_geom_bond_atom_site_label_2
_geom_bond_site_symmetry_2
_geom_bond_distance
_geom_bond_publ_flag
C1 C2 . 1.361(3) ?
C1 F1 . 1.362(3) ?
C1 C6 . 1.364(3) ?
C2 C3 . 1.381(3) ?
C2 H2 . 0.9300 ?
C3 C4 . 1.379(3) ?
C3 H3 . 0.9300 ?
C4 C5 . 1.397(3) ?
C4 N1 . 1.420(3) ?
C5 C6 . 1.375(3) ?
C5 H5 . 0.9300 ?
C6 H6 . 0.9300 ?
C7 N2 . 1.359(3) ?
C7 C8 . 1.370(3) ?
C7 S1 . 1.755(2) ?
C8 N3 . 1.361(3) ?
C8 C10 . 1.501(3) ?
C9 N3 . 1.317(2) ?
C9 N4 . 1.354(3) ?
C9 S1 . 1.726(2) ?
C10 H10A . 0.9600 ?
C10 H10B . 0.9600 ?
C10 H10C . 0.9600 ?
C10 H10D . 0.9600 ?
C10 H10E . 0.9600 ?
C10 H10F . 0.9600 ?
C11 N4 . 1.473(2) ?
C11 C14B . 1.513(3) ?
C11 C14 . 1.513(3) ?
C11 C12 . 1.532(3) ?
C11 H11 . 0.9800 ?
C12 C13 . 1.506(3) ?
C12 H12A . 0.9700 ?
C12 H12B . 0.9700 ?
C13 N5 . 1.282(2) ?
C13 C20 . 1.461(3) ?
C14 C15 . 1.370(5) ?
C14 C19 . 1.391(4) ?
C15 C16 . 1.381(5) ?
C15 H15 . 0.9300 ?
C16 C17 . 1.354(6) ?
C16 H16 . 0.9300 ?
C17 C18 . 1.348(5) ?
C17 F2 . 1.364(5) ?
C18 C19 . 1.380(4) ?
C18 H18 . 0.9300 ?
C19 H19 . 0.9300 ?
C14B C19B . 1.376(10) ?
C14B C15B . 1.383(13) ?
C15B C16B . 1.363(13) ?
C15B H15B . 0.9300 ?
C16B C17B . 1.348(13) ?
C16B H16B . 0.9300 ?
C17B C18B . 1.371(14) ?
C17B F2B . 1.371(13) ?
C18B C19B . 1.386(11) ?
C18B H18B . 0.9300 ?
C19B H19B . 0.9300 ?
C20 C21 . 1.385(3) ?
C20 C25 . 1.389(3) ?
C21 C22 . 1.377(3) ?
C21 H21 . 0.9300 ?
C22 C23 . 1.364(3) ?
C22 H22 . 0.9300 ?
C23 C24 . 1.370(3) ?
C23 Cl1 . 1.739(2) ?
C24 C25 . 1.373(3) ?
C24 H24 . 0.9300 ?
C25 H25 . 0.9300 ?
N1 N2 . 1.276(2) ?
N4 N5 . 1.380(2) ?
loop_
_geom_hbond_atom_site_label_D
_geom_hbond_atom_site_label_H
_geom_hbond_atom_site_label_A
_geom_hbond_site_symmetry_A
_geom_hbond_distance_DH
_geom_hbond_distance_HA
_geom_hbond_distance_DA
_geom_hbond_angle_DHA
_geom_hbond_publ_flag
C2 H2 S1 4_556 0.93 3.00 3.699(2) 132.9 yes
C6 H6 F1 3_757 0.93 2.52 3.441(3) 169.1 yes

_cod_database_fobs_code 1558159
