#------------------------------------------------------------------------------
#$Date: 2020-12-09 04:09:50 +0200 (Wed, 09 Dec 2020) $
#$Revision: 259673 $
#$URL: file:///home/coder/svn-repositories/cod/cif/1/55/97/1559721.cif $
#------------------------------------------------------------------------------
#
# This file is available in the Crystallography Open Database (COD),
# http://www.crystallography.net/
#
# All data on this site have been placed in the public domain by the
# contributors.
#
data_1559721
loop_
_publ_author_name
'Kaufmann, Sebastian'
'Krätschmer, Frederic'
'Köppe, Ralf'
'Schon, Thorben'
'Schoo, Christoph'
'Roesky, Peter W.'
_publ_section_title
;
 A cyclopentadienyl functionalized silylene -- a flexible ligand for Si-
 and C-coordination
;
_journal_issue                   46
_journal_name_full               'Chemical Science'
_journal_page_first              12446
_journal_page_last               12452
_journal_paper_doi               10.1039/D0SC04174B
_journal_volume                  11
_journal_year                    2020
_chemical_formula_moiety         'C32 H48 Cl N2 Rh Si'
_chemical_formula_sum            'C32 H48 Cl N2 Rh Si'
_chemical_formula_weight         627.17
_space_group_crystal_system      monoclinic
_space_group_IT_number           14
_space_group_name_Hall           '-P 2yn'
_space_group_name_H-M_alt        'P 1 21/n 1'
_atom_sites_solution_hydrogens   geom
_audit_creation_date             2020-03-24
_audit_creation_method
;
Olex2 1.2
(compiled 2018.05.29 svn.r3508 for OlexSys, GUI svn.r5506)
;
_audit_update_record
;
2020-07-29 deposited with the CCDC.	2020-10-13 downloaded from the CCDC.
;
_cell_angle_alpha                90
_cell_angle_beta                 101.761(5)
_cell_angle_gamma                90
_cell_formula_units_Z            4
_cell_length_a                   11.4019(6)
_cell_length_b                   20.6248(10)
_cell_length_c                   13.6772(9)
_cell_measurement_reflns_used    23361
_cell_measurement_temperature    150
_cell_measurement_theta_max      29.66
_cell_measurement_theta_min      1.81
_cell_volume                     3148.8(3)
_computing_molecular_graphics    'Olex2 (Dolomanov et al., 2009)'
_computing_publication_material  'Olex2 (Dolomanov et al., 2009)'
_computing_structure_refinement  'ShelXL (Sheldrick, 2015)'
_computing_structure_solution    'ShelXT (Sheldrick, 2015)'
_diffrn_ambient_temperature      150
_diffrn_detector                 'image plate (34cm diameter)'
_diffrn_detector_area_resol_mean 6.67
_diffrn_detector_type            'STOE image plate'
_diffrn_measured_fraction_theta_full 0.988
_diffrn_measured_fraction_theta_max 0.986
_diffrn_measurement_device       'two-circle goniometer'
_diffrn_measurement_device_type  'IPDS 150K'
_diffrn_measurement_method       'ω scans'
_diffrn_radiation_collimation    '0.5mm monocapillary'
_diffrn_radiation_monochromator  'plane graphite'
_diffrn_radiation_type           MoK\a
_diffrn_radiation_wavelength     0.71073
_diffrn_reflns_av_R_equivalents  0.0179
_diffrn_reflns_av_unetI/netI     0.0249
_diffrn_reflns_Laue_measured_fraction_full 0.988
_diffrn_reflns_Laue_measured_fraction_max 0.986
_diffrn_reflns_limit_h_max       15
_diffrn_reflns_limit_h_min       -15
_diffrn_reflns_limit_k_max       28
_diffrn_reflns_limit_k_min       -26
_diffrn_reflns_limit_l_max       18
_diffrn_reflns_limit_l_min       -18
_diffrn_reflns_number            20489
_diffrn_reflns_point_group_measured_fraction_full 0.988
_diffrn_reflns_point_group_measured_fraction_max 0.986
_diffrn_reflns_theta_full        25.242
_diffrn_reflns_theta_max         29.506
_diffrn_reflns_theta_min         1.813
_diffrn_source                   'sealed tube, 12x0.4mm long-fine focus'
_exptl_absorpt_coefficient_mu    0.688
_exptl_absorpt_correction_T_max  0.9146
_exptl_absorpt_correction_T_min  0.8196
_exptl_absorpt_correction_type   multi-scan
_exptl_absorpt_process_details
;
STOE X-Red32, absorption correction by Gaussian integration, analogous to
P. Coppens, "The Evaluation of Absorption and Extinction in Single-Crystal
Structure Analysis", published in
F. R. Ahmed (Editor), "Crystallographic Computing",
Munksgaard, Copenhagen (1970), 255 - 270
;
_exptl_crystal_colour            yellow
_exptl_crystal_colour_primary    yellow
_exptl_crystal_density_diffrn    1.323
_exptl_crystal_description       prism
_exptl_crystal_F_000             1320
_exptl_crystal_size_max          0.314
_exptl_crystal_size_mid          0.302
_exptl_crystal_size_min          0.28
_refine_diff_density_max         0.493
_refine_diff_density_min         -0.410
_refine_diff_density_rms         0.065
_refine_ls_extinction_method     none
_refine_ls_goodness_of_fit_ref   1.054
_refine_ls_hydrogen_treatment    constr
_refine_ls_matrix_type           full
_refine_ls_number_parameters     354
_refine_ls_number_reflns         8650
_refine_ls_number_restraints     0
_refine_ls_restrained_S_all      1.054
_refine_ls_R_factor_all          0.0385
_refine_ls_R_factor_gt           0.0267
_refine_ls_shift/su_max          0.005
_refine_ls_shift/su_mean         0.000
_refine_ls_structure_factor_coef Fsqd
_refine_ls_weighting_details
'w=1/[σ²(Fo²)+(0.0379P)²+1.0620P] where P=(Fo²+2Fc²)/3'
_refine_ls_weighting_scheme      calc
_refine_ls_wR_factor_gt          0.0675
_refine_ls_wR_factor_ref         0.0713
_reflns_Friedel_coverage         0.000
_reflns_number_gt                7018
_reflns_number_total             8650
_reflns_threshold_expression     'I > 2σ(I)'
_cod_data_source_file            d0sc04174b2.cif
_cod_data_source_block           skp205
_cod_database_code               1559721
_shelx_shelxl_version_number     2018/3
_shelx_space_group_comment
;
The symmetry employed for this shelxl refinement is uniquely defined
by the following loop, which should always be used as a source of
symmetry information in preference to the above space-group names.
They are only intended as comments.
;
_shelx_estimated_absorpt_t_max   0.831
_shelx_estimated_absorpt_t_min   0.813
_olex2_refinement_description
;
1. Fixed Uiso
 At 1.2 times of:
  All C(H) groups, All C(H,H) groups, All C(H,H,H,H) groups
 At 1.5 times of:
  All C(H,H,H) groups
2. Others
 Sof(H31C)=Sof(H31D)=Sof(C32B)=Sof(H32C)=Sof(H32D)=1-FVAR(1)
 Sof(H31A)=Sof(H31B)=Sof(C32A)=Sof(H32A)=Sof(H32B)=FVAR(1)
3.a Ternary CH refined with riding coordinates:
 C1(H1), C25(H25), C26(H26), C29(H29), C30(H30)
3.b Secondary CH2 refined with riding coordinates:
 C27(H27A,H27B), C28(H28A,H28B), C31(H31C,H31D), C31(H31A,H31B), C32A(H32A,
 H32B), C32B(H32C,H32D)
3.c Aromatic/amide H refined with riding coordinates:
 C12(H12), C13(H13), C14(H14), C15(H15), C16(H16)
3.d Idealised Me refined as rotating group:
 C6(H6A,H6B,H6C), C7(H7A,H7B,H7C), C8(H8A,H8B,H8C), C9(H9A,H9B,H9C), C18(H18A,
 H18B,H18C), C19(H19A,H19B,H19C), C20(H20A,H20B,H20C), C22(H22A,H22B,H22C),
 C23(H23A,H23B,H23C), C24(H24A,H24B,H24C)
;
_olex2_submission_special_instructions 'No special instructions were received'
loop_
_space_group_symop_operation_xyz
'x, y, z'
'-x+1/2, y+1/2, -z+1/2'
'-x, -y, -z'
'x-1/2, -y-1/2, z-1/2'
loop_
_atom_site_label
_atom_site_type_symbol
_atom_site_fract_x
_atom_site_fract_y
_atom_site_fract_z
_atom_site_U_iso_or_equiv
_atom_site_adp_type
_atom_site_occupancy
_atom_site_site_symmetry_order
_atom_site_calc_flag
_atom_site_refinement_flags_posn
_atom_site_refinement_flags_adp
_atom_site_refinement_flags_occupancy
_atom_site_disorder_assembly
_atom_site_disorder_group
Rh1 Rh 0.54204(2) 0.66810(2) 0.66331(2) 0.01768(4) Uani 1 1 d . . . . .
Cl1 Cl 0.53865(4) 0.74515(2) 0.79210(4) 0.03025(10) Uani 1 1 d . . . . .
Si1 Si 0.74635(4) 0.68004(2) 0.69337(3) 0.01593(9) Uani 1 1 d . . . . .
N1 N 0.82472(12) 0.62184(7) 0.78781(11) 0.0198(3) Uani 1 1 d . . . . .
N2 N 0.84507(11) 0.62829(6) 0.63531(10) 0.0168(3) Uani 1 1 d . . . . .
C1 C 0.82090(15) 0.76310(8) 0.71781(14) 0.0226(3) Uani 1 1 d . . . . .
H1 H 0.796142 0.782044 0.777803 0.027 Uiso 1 1 calc R . . . .
C2 C 0.78094(17) 0.80931(8) 0.63145(15) 0.0268(4) Uani 1 1 d . . . . .
C3 C 0.8786(2) 0.83293(10) 0.6030(2) 0.0419(5) Uani 1 1 d . . . . .
C4 C 0.9865(2) 0.80603(11) 0.6673(2) 0.0482(6) Uani 1 1 d . . . . .
C5 C 0.95506(17) 0.76626(9) 0.73499(18) 0.0348(5) Uani 1 1 d . . . . .
C6 C 0.65310(19) 0.82265(10) 0.58546(16) 0.0336(4) Uani 1 1 d . . . . .
H6A H 0.614528 0.782546 0.556858 0.050 Uiso 1 1 calc GR . . . .
H6B H 0.648971 0.855179 0.532646 0.050 Uiso 1 1 calc GR . . . .
H6C H 0.611763 0.838986 0.636651 0.050 Uiso 1 1 calc GR . . . .
C7 C 0.8827(3) 0.87745(14) 0.5164(3) 0.0701(9) Uani 1 1 d . . . . .
H7A H 0.916124 0.854121 0.465940 0.105 Uiso 1 1 calc GR . . . .
H7B H 0.933244 0.915018 0.540002 0.105 Uiso 1 1 calc GR . . . .
H7C H 0.801472 0.892171 0.486986 0.105 Uiso 1 1 calc GR . . . .
C8 C 1.1115(3) 0.82278(16) 0.6550(4) 0.0924(14) Uani 1 1 d . . . . .
H8A H 1.119779 0.812488 0.586816 0.139 Uiso 1 1 calc GR . . . .
H8B H 1.169851 0.797586 0.702635 0.139 Uiso 1 1 calc GR . . . .
H8C H 1.125988 0.869162 0.667628 0.139 Uiso 1 1 calc GR . . . .
C9 C 1.0382(2) 0.73117(11) 0.8165(2) 0.0553(8) Uani 1 1 d . . . . .
H9A H 1.012494 0.737855 0.879926 0.083 Uiso 1 1 calc GR . . . .
H9B H 1.119714 0.747911 0.821965 0.083 Uiso 1 1 calc GR . . . .
H9C H 1.036898 0.684731 0.801147 0.083 Uiso 1 1 calc GR . . . .
C10 C 0.87392(14) 0.59274(8) 0.71872(12) 0.0172(3) Uani 1 1 d . . . . .
C11 C 0.94195(15) 0.53081(8) 0.73094(13) 0.0204(3) Uani 1 1 d . . . . .
C12 C 0.88157(17) 0.47280(9) 0.70502(14) 0.0271(4) Uani 1 1 d . . . . .
H12 H 0.798304 0.473281 0.676535 0.033 Uiso 1 1 calc R . . . .
C13 C 0.9422(2) 0.41427(9) 0.72052(15) 0.0320(4) Uani 1 1 d . . . . .
H13 H 0.900685 0.374759 0.702131 0.038 Uiso 1 1 calc R . . . .
C14 C 1.0630(2) 0.41348(10) 0.76272(15) 0.0336(4) Uani 1 1 d . . . . .
H14 H 1.104116 0.373291 0.774611 0.040 Uiso 1 1 calc R . . . .
C15 C 1.12402(17) 0.47067(10) 0.78765(15) 0.0306(4) Uani 1 1 d . . . . .
H15 H 1.207374 0.469720 0.815774 0.037 Uiso 1 1 calc R . . . .
C16 C 1.06456(16) 0.52987(9) 0.77195(14) 0.0252(4) Uani 1 1 d . . . . .
H16 H 1.106994 0.569265 0.788982 0.030 Uiso 1 1 calc R . . . .
C17 C 0.88938(14) 0.62351(8) 0.54079(12) 0.0193(3) Uani 1 1 d . . . . .
C18 C 0.84908(19) 0.56009(9) 0.48685(15) 0.0303(4) Uani 1 1 d . . . . .
H18A H 0.887643 0.523564 0.526707 0.045 Uiso 1 1 calc GR . . . .
H18B H 0.871832 0.559982 0.421510 0.045 Uiso 1 1 calc GR . . . .
H18C H 0.761888 0.555999 0.477683 0.045 Uiso 1 1 calc GR . . . .
C19 C 1.02585(16) 0.62933(11) 0.56084(16) 0.0332(4) Uani 1 1 d . . . . .
H19A H 1.050604 0.669026 0.598848 0.050 Uiso 1 1 calc GR . . . .
H19B H 1.052612 0.631017 0.497195 0.050 Uiso 1 1 calc GR . . . .
H19C H 1.061810 0.591677 0.599332 0.050 Uiso 1 1 calc GR . . . .
C20 C 0.83581(17) 0.68073(9) 0.47571(14) 0.0281(4) Uani 1 1 d . . . . .
H20A H 0.748205 0.678775 0.464448 0.042 Uiso 1 1 calc GR . . . .
H20B H 0.861043 0.678665 0.411442 0.042 Uiso 1 1 calc GR . . . .
H20C H 0.863845 0.721428 0.509526 0.042 Uiso 1 1 calc GR . . . .
C21 C 0.80408(18) 0.59823(11) 0.88551(14) 0.0327(4) Uani 1 1 d . . . . .
C22 C 0.6873(2) 0.56036(14) 0.8695(2) 0.0534(7) Uani 1 1 d . . . . .
H22A H 0.622012 0.587377 0.833268 0.080 Uiso 1 1 calc GR . . . .
H22B H 0.670114 0.548110 0.934411 0.080 Uiso 1 1 calc GR . . . .
H22C H 0.694554 0.521187 0.830654 0.080 Uiso 1 1 calc GR . . . .
C23 C 0.9066(2) 0.55599(12) 0.94074(15) 0.0395(5) Uani 1 1 d . . . . .
H23A H 0.906994 0.514622 0.905549 0.059 Uiso 1 1 calc GR . . . .
H23B H 0.895518 0.547900 1.008883 0.059 Uiso 1 1 calc GR . . . .
H23C H 0.982965 0.578348 0.943189 0.059 Uiso 1 1 calc GR . . . .
C24 C 0.7965(3) 0.65871(13) 0.94844(17) 0.0549(7) Uani 1 1 d . . . . .
H24A H 0.873839 0.681196 0.961060 0.082 Uiso 1 1 calc GR . . . .
H24B H 0.776540 0.646041 1.012161 0.082 Uiso 1 1 calc GR . . . .
H24C H 0.734262 0.687683 0.912474 0.082 Uiso 1 1 calc GR . . . .
C25 C 0.34051(16) 0.67624(11) 0.60499(17) 0.0360(5) Uani 1 1 d . . . . .
H25 H 0.309484 0.718127 0.626445 0.043 Uiso 1 1 calc R . . A .
C26 C 0.35877(16) 0.63286(10) 0.68115(17) 0.0320(4) Uani 1 1 d . . . . .
H26 H 0.333978 0.648463 0.743138 0.038 Uiso 1 1 calc R . . . .
C27 C 0.3559(3) 0.56072(12) 0.6687(3) 0.0683(10) Uani 1 1 d . . . . .
H27A H 0.354984 0.541066 0.734534 0.082 Uiso 1 1 calc R . . . .
H27B H 0.279321 0.549115 0.623625 0.082 Uiso 1 1 calc R . . . .
C28 C 0.4531(2) 0.53046(10) 0.6296(2) 0.0469(6) Uani 1 1 d . . . . .
H28A H 0.417031 0.506297 0.568261 0.056 Uiso 1 1 calc R . . . .
H28B H 0.492764 0.498298 0.679200 0.056 Uiso 1 1 calc R . . . .
C29 C 0.54865(15) 0.57467(8) 0.60486(15) 0.0250(4) Uani 1 1 d . . . . .
H29 H 0.630650 0.555141 0.618814 0.030 Uiso 1 1 calc R . . . .
C30 C 0.52978(15) 0.61937(9) 0.52610(14) 0.0257(4) Uani 1 1 d . . . . .
H30 H 0.600832 0.625794 0.494700 0.031 Uiso 1 1 calc R . . . .
C31 C 0.41038(19) 0.63024(15) 0.45535(18) 0.0490(6) Uani 1 1 d . . . . .
H31C H 0.419972 0.666721 0.410585 0.059 Uiso 0.564(15) 1 calc R . P B 2
H31D H 0.391809 0.591105 0.413132 0.059 Uiso 0.564(15) 1 calc R . P B 2
H31A H 0.425829 0.648098 0.391980 0.059 Uiso 0.436(15) 1 calc R . P B 1
H31B H 0.370584 0.587721 0.440081 0.059 Uiso 0.436(15) 1 calc R . P B 1
C32A C 0.3269(6) 0.6742(5) 0.4928(4) 0.0277(15) Uani 0.436(15) 1 d . . P B 1
H32A H 0.243895 0.660890 0.463038 0.033 Uiso 0.436(15) 1 calc R . P B 1
H32B H 0.338316 0.718639 0.468895 0.033 Uiso 0.436(15) 1 calc R . P B 1
C32B C 0.3072(4) 0.6441(5) 0.4998(4) 0.0346(15) Uani 0.564(15) 1 d . . P B 2
H32C H 0.263907 0.603157 0.505483 0.042 Uiso 0.564(15) 1 calc R . P B 2
H32D H 0.252100 0.673289 0.454661 0.042 Uiso 0.564(15) 1 calc R . P B 2
loop_
_atom_type_symbol
_atom_type_description
_atom_type_scat_dispersion_real
_atom_type_scat_dispersion_imag
_atom_type_scat_source
C C 0.0033 0.0016 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
H H 0.0000 0.0000 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
Cl Cl 0.1484 0.1585 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
N N 0.0061 0.0033 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
Rh Rh -1.1178 0.9187 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
Si Si 0.0817 0.0704 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
loop_
_geom_angle_atom_site_label_1
_geom_angle_atom_site_label_2
_geom_angle_atom_site_label_3
_geom_angle
_geom_angle_site_symmetry_1
_geom_angle_site_symmetry_3
_geom_angle_publ_flag
Si1 Rh1 Cl1 87.982(17) . . ?
C25 Rh1 Cl1 92.44(6) . . ?
C25 Rh1 Si1 165.65(6) . . ?
C26 Rh1 Cl1 88.86(5) . . ?
C26 Rh1 Si1 159.61(6) . . ?
C26 Rh1 C25 34.68(8) . . ?
C29 Rh1 Cl1 154.83(6) . . ?
C29 Rh1 Si1 93.03(5) . . ?
C29 Rh1 C25 92.65(7) . . ?
C29 Rh1 C26 81.49(7) . . ?
C29 Rh1 C30 38.95(7) . . ?
C30 Rh1 Cl1 165.84(5) . . ?
C30 Rh1 Si1 95.24(5) . . ?
C30 Rh1 C25 81.05(7) . . ?
C30 Rh1 C26 92.72(7) . . ?
N1 Si1 Rh1 112.51(5) . . ?
N1 Si1 C1 108.93(7) . . ?
N2 Si1 Rh1 123.17(5) . . ?
N2 Si1 N1 71.07(6) . . ?
N2 Si1 C1 107.78(7) . . ?
C1 Si1 Rh1 121.77(6) . . ?
C10 N1 Si1 90.59(10) . . ?
C10 N1 C21 130.97(15) . . ?
C21 N1 Si1 134.17(12) . . ?
C10 N2 Si1 90.89(10) . . ?
C10 N2 C17 129.61(14) . . ?
C17 N2 Si1 139.42(11) . . ?
C2 C1 Si1 112.05(12) . . ?
C5 C1 Si1 117.97(12) . . ?
C5 C1 C2 103.29(16) . . ?
C3 C2 C1 108.58(18) . . ?
C3 C2 C6 127.43(19) . . ?
C6 C2 C1 123.94(17) . . ?
C2 C3 C4 109.4(2) . . ?
C2 C3 C7 127.5(2) . . ?
C4 C3 C7 123.0(2) . . ?
C3 C4 C8 122.8(3) . . ?
C5 C4 C3 109.61(19) . . ?
C5 C4 C8 127.6(3) . . ?
C4 C5 C1 109.06(19) . . ?
C4 C5 C9 126.4(2) . . ?
C9 C5 C1 124.5(2) . . ?
N1 C10 N2 106.92(14) . . ?
N1 C10 C11 126.26(15) . . ?
N2 C10 C11 126.74(15) . . ?
C12 C11 C10 119.42(15) . . ?
C12 C11 C16 119.59(16) . . ?
C16 C11 C10 120.93(15) . . ?
C13 C12 C11 120.36(18) . . ?
C14 C13 C12 119.87(18) . . ?
C15 C14 C13 120.29(17) . . ?
C14 C15 C16 120.50(18) . . ?
C15 C16 C11 119.37(18) . . ?
N2 C17 C18 110.83(14) . . ?
N2 C17 C19 110.69(14) . . ?
N2 C17 C20 106.83(13) . . ?
C18 C17 C19 110.44(15) . . ?
C18 C17 C20 109.58(15) . . ?
C20 C17 C19 108.37(15) . . ?
N1 C21 C22 109.50(17) . . ?
N1 C21 C23 112.71(16) . . ?
N1 C21 C24 106.06(18) . . ?
C22 C21 C23 109.70(19) . . ?
C22 C21 C24 110.6(2) . . ?
C24 C21 C23 108.20(18) . . ?
C26 C25 Rh1 72.35(11) . . ?
C26 C25 C32A 136.8(4) . . ?
C26 C25 C32B 113.5(4) . . ?
C32A C25 Rh1 103.9(3) . . ?
C32B C25 Rh1 109.27(18) . . ?
C25 C26 Rh1 72.97(11) . . ?
C25 C26 C27 124.8(2) . . ?
C27 C26 Rh1 107.74(13) . . ?
C28 C27 C26 117.68(19) . . ?
C27 C28 C29 117.27(18) . . ?
C28 C29 Rh1 112.74(13) . . ?
C30 C29 Rh1 71.09(10) . . ?
C30 C29 C28 124.37(18) . . ?
C29 C30 Rh1 69.96(10) . . ?
C29 C30 C31 124.39(19) . . ?
C31 C30 Rh1 112.66(13) . . ?
C32A C31 C30 115.3(3) . . ?
C32B C31 C30 117.3(2) . . ?
C31 C32A C25 115.3(4) . . ?
C31 C32B C25 113.8(3) . . ?
loop_
_geom_bond_atom_site_label_1
_geom_bond_atom_site_label_2
_geom_bond_distance
_geom_bond_site_symmetry_2
_geom_bond_publ_flag
Rh1 Cl1 2.3785(5) . ?
Rh1 Si1 2.2947(5) . ?
Rh1 C25 2.2797(18) . ?
Rh1 C26 2.2721(18) . ?
Rh1 C29 2.0935(17) . ?
Rh1 C30 2.1083(18) . ?
Si1 N1 1.8540(14) . ?
Si1 N2 1.8443(14) . ?
Si1 C1 1.9113(17) . ?
N1 C10 1.336(2) . ?
N1 C21 1.485(2) . ?
N2 C10 1.339(2) . ?
N2 C17 1.484(2) . ?
C1 C2 1.514(3) . ?
C1 C5 1.501(3) . ?
C2 C3 1.343(3) . ?
C2 C6 1.491(3) . ?
C3 C4 1.468(4) . ?
C3 C7 1.507(4) . ?
C4 C5 1.339(4) . ?
C4 C8 1.508(4) . ?
C5 C9 1.495(3) . ?
C10 C11 1.486(2) . ?
C11 C12 1.390(2) . ?
C11 C16 1.396(2) . ?
C12 C13 1.386(3) . ?
C13 C14 1.381(3) . ?
C14 C15 1.377(3) . ?
C15 C16 1.392(3) . ?
C17 C18 1.526(2) . ?
C17 C19 1.529(2) . ?
C17 C20 1.528(2) . ?
C21 C22 1.520(3) . ?
C21 C23 1.528(3) . ?
C21 C24 1.528(3) . ?
C25 C26 1.357(3) . ?
C25 C32A 1.512(6) . ?
C25 C32B 1.558(5) . ?
C26 C27 1.497(3) . ?
C27 C28 1.465(3) . ?
C28 C29 1.511(3) . ?
C29 C30 1.401(3) . ?
C30 C31 1.518(3) . ?
C31 C32A 1.479(6) . ?
C31 C32B 1.459(5) . ?
