#------------------------------------------------------------------------------
#$Date: 2021-02-15 15:09:18 +0200 (Mon, 15 Feb 2021) $
#$Revision: 261974 $
#$URL: file:///home/coder/svn-repositories/cod/cif/1/56/03/1560397.cif $
#------------------------------------------------------------------------------
#
# This file is available in the Crystallography Open Database (COD),
# http://www.crystallography.net/
#
# All data on this site have been placed in the public domain by the
# contributors.
#
data_1560397
loop_
_publ_author_name
'Lahoud, Marcelo G.'
'Frem, Regina C.G.'
'Marques, Lippy F.'
'Arroyos, Guilherme'
'Brandão, Paula'
'Ferreira, Rute A.S.'
'Carlos, Luís D.'
_publ_section_title
;
 A novel near monochromatic red emissive europium(III) metal-organic
 framework based on 1,2,4,5-benzenetetracarboxylate: From synthesis to
 photoluminescence studies
;
_journal_name_full               'Journal of Solid State Chemistry'
_journal_page_first              176
_journal_page_last               183
_journal_paper_doi               10.1016/j.jssc.2017.05.041
_journal_volume                  253
_journal_year                    2017
_chemical_formula_moiety         'C15 H5 Eu2 O13'
_chemical_formula_sum            'C15 H5 Eu2 O13'
_chemical_formula_weight         697.11
_space_group_crystal_system      triclinic
_space_group_IT_number           2
_space_group_name_Hall           '-P 1'
_space_group_name_H-M_alt        'P -1'
_atom_sites_solution_hydrogens   mixed
_cell_angle_alpha                111.167(2)
_cell_angle_beta                 92.775(2)
_cell_angle_gamma                111.021(2)
_cell_formula_units_Z            2
_cell_length_a                   7.5213(4)
_cell_length_b                   10.3018(6)
_cell_length_c                   11.4847(6)
_cell_measurement_reflns_used    490
_cell_measurement_temperature    150(2)
_cell_measurement_theta_max      26.30
_cell_measurement_theta_min      2.86
_cell_volume                     758.25(7)
_computing_cell_refinement       'Bruker Smart'
_computing_data_collection       'Bruker Smart'
_computing_data_reduction        'Bruker Saint'
_computing_molecular_graphics
;
O. V. Dolomanov, L. J. Bourhis, R. J. Gildea, J. A. K. Howard and H. Puschmann,
OLEX2: a complete structure solution, refinement and analysis program.
J. Appl. Cryst. (2009). 42, 339-341.
;
_computing_publication_material
;
O. V. Dolomanov, L. J. Bourhis, R. J. Gildea, J. A. K. Howard and H. Puschmann,
OLEX2: a complete structure solution, refinement and analysis program.
J. Appl. Cryst. (2009). 42, 339-341.
;
_computing_structure_refinement  'SHELXL-2013 (Sheldrick, 2013)'
_computing_structure_solution    'SHELXS-2013 (Sheldrick, 2013)'
_diffrn_ambient_temperature      150(2)
_diffrn_measured_fraction_theta_full 1.000
_diffrn_measured_fraction_theta_max 0.999
_diffrn_measurement_device_type  CCD
_diffrn_measurement_method       'omega and phi scans'
_diffrn_radiation_type           MoK\a
_diffrn_radiation_wavelength     0.71073
_diffrn_reflns_av_R_equivalents  0.0456
_diffrn_reflns_av_unetI/netI     0.0205
_diffrn_reflns_Laue_measured_fraction_full 1.000
_diffrn_reflns_Laue_measured_fraction_max 0.999
_diffrn_reflns_limit_h_max       10
_diffrn_reflns_limit_h_min       -10
_diffrn_reflns_limit_k_max       14
_diffrn_reflns_limit_k_min       -14
_diffrn_reflns_limit_l_max       16
_diffrn_reflns_limit_l_min       -16
_diffrn_reflns_number            59925
_diffrn_reflns_point_group_measured_fraction_full 1.000
_diffrn_reflns_point_group_measured_fraction_max 0.999
_diffrn_reflns_theta_full        25.242
_diffrn_reflns_theta_max         30.580
_diffrn_reflns_theta_min         2.317
_diffrn_source                   'fine-focus sealed tube'
_exptl_absorpt_coefficient_mu    8.282
_exptl_absorpt_correction_T_max  0.7461
_exptl_absorpt_correction_T_min  0.5855
_exptl_absorpt_correction_type   multi-scan
_exptl_crystal_colour            colourless
_exptl_crystal_density_diffrn    3.053
_exptl_crystal_description       plate
_exptl_crystal_F_000             650
_exptl_crystal_size_max          0.06
_exptl_crystal_size_mid          0.04
_exptl_crystal_size_min          0.01
_refine_diff_density_max         1.174
_refine_diff_density_min         -1.077
_refine_diff_density_rms         0.156
_refine_ls_extinction_coef       .
_refine_ls_extinction_method     none
_refine_ls_goodness_of_fit_ref   1.085
_refine_ls_hydrogen_treatment    mixed
_refine_ls_matrix_type           full
_refine_ls_number_parameters     279
_refine_ls_number_reflns         4665
_refine_ls_number_restraints     0
_refine_ls_restrained_S_all      1.085
_refine_ls_R_factor_all          0.0249
_refine_ls_R_factor_gt           0.0188
_refine_ls_shift/su_max          0.004
_refine_ls_shift/su_mean         0.000
_refine_ls_structure_factor_coef Fsqd
_refine_ls_weighting_details
'w=1/[σ²(Fo²)+(0.0069P)²+3.1570P] where P=(Fo²+2Fc²)/3'
_refine_ls_weighting_scheme      calc
_refine_ls_wR_factor_gt          0.0376
_refine_ls_wR_factor_ref         0.0392
_reflns_Friedel_coverage         0.000
_reflns_Friedel_fraction_full    .
_reflns_Friedel_fraction_max     .
_reflns_number_gt                4096
_reflns_number_total             4665
_reflns_threshold_expression     'I > 2σ(I)'
_cod_data_source_file            Eu_MOF.cif
_cod_data_source_block           Eu_MOF
_cod_database_code               1560397
_olex2_refinement_description
;
1. Others
 Fixed Uiso: H6(0.009) H9(0.01) H24(0.008)
 Fixed X: H6(0.8409) H9(0.6538) H24(0.8072)
 Fixed Y: H6(0.6602) H9(0.308) H24(0.006)
 Fixed Z: H6(0.7321) H9(0.3084) H24(0.0507)
;
_shelx_estimated_absorpt_t_max   0.922
_shelx_estimated_absorpt_t_min   0.636
loop_
_space_group_symop_operation_xyz
'x, y, z'
'-x, -y, -z'
loop_
_atom_site_label
_atom_site_type_symbol
_atom_site_fract_x
_atom_site_fract_y
_atom_site_fract_z
_atom_site_U_iso_or_equiv
_atom_site_adp_type
_atom_site_occupancy
_atom_site_site_symmetry_order
_atom_site_calc_flag
_atom_site_refinement_flags_posn
_atom_site_refinement_flags_adp
_atom_site_refinement_flags_occupancy
_atom_site_disorder_assembly
_atom_site_disorder_group
Eu1 Eu 0.80426(2) 0.58566(2) 1.05908(2) 0.00395(3) Uani 1 1 d . . . . .
Eu2 Eu 0.75470(2) -0.10124(2) 0.36360(2) 0.00563(4) Uani 1 1 d . . . . .
O1 O 1.0452(3) 0.8365(3) 1.2513(2) 0.0105(4) Uani 1 1 d . . . . .
H1A H 1.077(8) 0.909(6) 1.239(5) 0.039(15) Uiso 1 1 d . . . . .
H1B H 1.129(7) 0.833(5) 1.278(5) 0.022(13) Uiso 1 1 d . . . . .
O2 O 0.7267(3) 0.4862(2) 0.83821(19) 0.0075(4) Uani 1 1 d . . . . .
O3 O 0.5942(3) 0.2429(2) 0.7007(2) 0.0086(4) Uani 1 1 d . . . . .
C4 C 0.6731(4) 0.3846(3) 0.7278(3) 0.0059(5) Uani 1 1 d . . . . .
C5 C 0.7037(4) 0.4337(3) 0.6185(3) 0.0059(5) Uani 1 1 d . . . . .
C6 C 0.7986(4) 0.5887(3) 0.6457(3) 0.0078(5) Uani 1 1 d . . . . .
H6 H 0.8409 0.6602 0.7321 0.009 Uiso 1 1 calc R U . . .
C7 C 0.8325(4) 0.6408(3) 0.5490(3) 0.0064(5) Uani 1 1 d . . . . .
C8 C 0.7755(4) 0.5344(3) 0.4216(3) 0.0063(5) Uani 1 1 d . . . . .
C9 C 0.6874(4) 0.3800(3) 0.3944(3) 0.0079(5) Uani 1 1 d . . . . .
H9 H 0.6538 0.3080 0.3084 0.010 Uiso 1 1 calc R U . . .
C10 C 0.6476(4) 0.3288(3) 0.4907(3) 0.0065(5) Uani 1 1 d . . . . .
C11 C 0.9410(4) 0.8068(3) 0.5847(3) 0.0071(5) Uani 1 1 d . . . . .
O12 O 1.0053(3) 0.8975(2) 0.6986(2) 0.0107(4) Uani 1 1 d . . . . .
O13 O 0.9766(3) 0.8556(2) 0.4956(2) 0.0079(4) Uani 1 1 d . . . . .
C14 C 0.7990(4) 0.5727(3) 0.3079(3) 0.0063(5) Uani 1 1 d . . . . .
O15 O 0.6967(3) 0.6369(2) 0.27893(19) 0.0066(4) Uani 1 1 d . . . . .
O16 O 0.9039(3) 0.5290(2) 0.2361(2) 0.0101(4) Uani 1 1 d . . . . .
C17 C 0.5410(4) 0.1577(3) 0.4446(3) 0.0064(5) Uani 1 1 d . . . . .
O18 O 0.3667(3) 0.1036(2) 0.4546(2) 0.0095(4) Uani 1 1 d . . . . .
O19 O 0.6297(3) 0.0809(2) 0.3865(2) 0.0124(4) Uani 1 1 d . . . . .
O20 O 0.6998(3) -0.1968(2) 0.13678(19) 0.0072(4) Uani 1 1 d . . . . .
O21 O 0.4881(3) -0.3772(2) -0.0338(2) 0.0075(4) Uani 1 1 d . . . . .
C22 C 0.5631(4) -0.2397(3) 0.0448(3) 0.0050(5) Uani 1 1 d . . . . .
C23 C 0.5173(4) -0.1196(3) 0.0236(3) 0.0056(5) Uani 1 1 d . . . . .
C24 C 0.6821(4) 0.0038(3) 0.0298(3) 0.0070(5) Uani 1 1 d . . . . .
H24 H 0.8072 0.0060 0.0507 0.008 Uiso 1 1 calc R U . . .
C25 C 0.3319(4) -0.1238(3) -0.0061(3) 0.0064(5) Uani 1 1 d . . . . .
C26 C 0.1433(4) -0.2394(3) -0.0021(3) 0.0058(5) Uani 1 1 d . . . . .
O27 O 0.1387(3) -0.3543(2) 0.01969(19) 0.0063(4) Uani 1 1 d . . . . .
O28 O -0.0061(3) -0.2137(2) -0.0096(2) 0.0078(4) Uani 1 1 d . . . . .
loop_
_atom_type_symbol
_atom_type_description
_atom_type_scat_dispersion_real
_atom_type_scat_dispersion_imag
_atom_type_scat_source
C C 0.0033 0.0016 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
H H 0.0000 0.0000 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
O O 0.0106 0.0060 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
Eu Eu -0.1578 3.6682 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
loop_
_geom_angle_atom_site_label_1
_geom_angle_atom_site_label_2
_geom_angle_atom_site_label_3
_geom_angle
_geom_angle_site_symmetry_1
_geom_angle_site_symmetry_3
O1 Eu1 C14 65.31(8) . 1_556
O1 Eu1 O21 111.56(7) . 1_566
O1 Eu1 C26 64.68(7) . 1_666
O2 Eu1 O1 139.16(7) . .
O2 Eu1 C14 155.10(8) . 1_556
O2 Eu1 O15 150.29(7) . 1_556
O2 Eu1 O16 141.65(7) . 1_556
O2 Eu1 O20 106.03(7) . 1_566
O2 Eu1 O21 83.62(7) . 2_656
O2 Eu1 O21 66.65(7) . 1_566
O2 Eu1 C26 77.30(8) . 1_666
O2 Eu1 O27 72.90(7) . 2_656
O2 Eu1 O27 82.03(7) . 1_666
O2 Eu1 O28 72.09(7) . 1_666
O15 Eu1 O1 64.57(7) 1_556 .
O15 Eu1 C14 26.11(7) 1_556 1_556
O15 Eu1 O21 89.23(6) 1_556 1_566
O15 Eu1 C26 129.25(7) 1_556 1_666
O16 Eu1 O1 68.96(8) 1_556 .
O16 Eu1 C14 25.09(7) 1_556 1_556
O16 Eu1 O15 51.15(7) 1_556 1_556
O16 Eu1 O20 111.43(7) 1_556 1_566
O16 Eu1 O21 137.39(7) 1_556 1_566
O16 Eu1 C26 108.52(8) 1_556 1_666
O16 Eu1 O27 88.26(7) 1_556 1_666
O16 Eu1 O28 128.61(7) 1_556 1_666
O20 Eu1 O1 63.17(7) 1_566 .
O20 Eu1 C14 89.10(7) 1_566 1_556
O20 Eu1 O15 64.94(6) 1_566 1_556
O20 Eu1 O21 48.61(6) 1_566 1_566
O20 Eu1 C26 92.27(7) 1_566 1_666
O21 Eu1 O1 135.89(7) 2_656 .
O21 Eu1 C14 113.71(7) 1_566 1_556
O21 Eu1 C14 73.91(7) 2_656 1_556
O21 Eu1 O15 71.45(7) 2_656 1_556
O21 Eu1 O16 81.39(7) 2_656 1_556
O21 Eu1 O20 101.32(7) 2_656 1_566
O21 Eu1 O21 69.91(8) 2_656 1_566
O21 Eu1 C26 159.06(7) 2_656 1_666
O21 Eu1 C26 109.34(7) 1_566 1_666
O21 Eu1 O27 71.32(7) 2_656 2_656
O21 Eu1 O27 141.66(7) 2_656 1_666
O21 Eu1 O28 149.99(7) 2_656 1_666
C26 Eu1 C14 122.64(8) 1_666 1_556
O27 Eu1 O1 122.55(8) 2_656 .
O27 Eu1 O1 71.01(7) 1_666 .
O27 Eu1 C14 109.09(7) 1_666 1_556
O27 Eu1 C14 89.52(7) 2_656 1_556
O27 Eu1 O15 112.23(6) 2_656 1_556
O27 Eu1 O15 127.64(7) 1_666 1_556
O27 Eu1 O16 68.89(7) 2_656 1_556
O27 Eu1 O20 172.59(7) 2_656 1_566
O27 Eu1 O20 116.79(7) 1_666 1_566
O27 Eu1 O21 125.89(6) 2_656 1_566
O27 Eu1 O21 133.48(6) 1_666 1_566
O27 Eu1 C26 94.60(7) 2_656 1_666
O27 Eu1 C26 26.93(7) 1_666 1_666
O27 Eu1 O27 70.51(7) 2_656 1_666
O27 Eu1 O28 115.94(7) 2_656 1_666
O28 Eu1 O1 67.23(7) 1_666 .
O28 Eu1 C14 132.54(7) 1_666 1_556
O28 Eu1 O15 124.54(7) 1_666 1_556
O28 Eu1 O20 70.00(7) 1_666 1_566
O28 Eu1 O21 84.15(6) 1_666 1_566
O28 Eu1 C26 26.10(7) 1_666 1_666
O28 Eu1 O27 52.91(7) 1_666 1_666
O1 Eu2 Eu1 41.76(5) 1_544 1_544
O1 Eu2 C11 74.90(7) 1_544 2_766
O1 Eu2 C17 147.23(7) 1_544 2_656
O3 Eu2 Eu1 87.98(5) 2_656 1_544
O3 Eu2 O1 129.73(7) 2_656 1_544
O3 Eu2 C11 142.31(7) 2_656 2_766
O3 Eu2 O12 132.21(7) 2_656 2_766
O3 Eu2 O13 145.47(7) 2_656 2_766
O3 Eu2 O13 125.58(7) 2_656 1_545
O3 Eu2 C17 54.69(7) 2_656 2_656
C11 Eu2 Eu1 109.75(6) 2_766 1_544
C11 Eu2 C17 122.87(8) 2_766 2_656
O12 Eu2 Eu1 88.05(5) 2_766 1_544
O12 Eu2 O1 62.33(7) 2_766 1_544
O12 Eu2 C11 25.48(7) 2_766 2_766
O12 Eu2 C17 144.53(7) 2_766 2_656
O13 Eu2 Eu1 88.79(5) 1_545 1_544
O13 Eu2 Eu1 125.34(5) 2_766 1_544
O13 Eu2 O1 65.53(7) 1_545 1_544
O13 Eu2 O1 84.14(7) 2_766 1_544
O13 Eu2 C11 26.44(7) 2_766 2_766
O13 Eu2 C11 88.87(7) 1_545 2_766
O13 Eu2 O12 101.92(7) 1_545 2_766
O13 Eu2 O12 51.39(7) 2_766 2_766
O13 Eu2 O13 69.88(8) 1_545 2_766
O13 Eu2 C17 101.98(7) 2_766 2_656
O13 Eu2 C17 86.16(7) 1_545 2_656
O15 Eu2 Eu1 39.86(5) 1_545 1_544
O15 Eu2 O1 66.10(7) 1_545 1_544
O15 Eu2 O3 73.17(7) 1_545 2_656
O15 Eu2 C11 140.55(7) 1_545 2_766
O15 Eu2 O12 125.63(7) 1_545 2_766
O15 Eu2 O13 70.24(7) 1_545 1_545
O15 Eu2 O13 137.39(7) 1_545 2_766
O15 Eu2 C17 89.71(7) 1_545 2_656
O15 Eu2 O20 70.83(7) 1_545 .
C17 Eu2 Eu1 126.95(5) 2_656 1_544
O18 Eu2 Eu1 134.27(5) 2_656 1_544
O18 Eu2 O1 137.09(8) 2_656 1_544
O18 Eu2 O3 72.22(7) 2_656 2_656
O18 Eu2 C11 110.87(8) 2_656 2_766
O18 Eu2 O12 135.67(7) 2_656 2_766
O18 Eu2 O13 72.00(7) 2_656 1_545
O18 Eu2 O13 87.11(7) 2_656 2_766
O18 Eu2 O15 94.45(7) 2_656 1_545
O18 Eu2 C17 17.58(7) 2_656 2_656
O18 Eu2 O19 82.96(8) 2_656 .
O18 Eu2 O20 148.45(7) 2_656 .
O19 Eu2 Eu1 132.00(6) . 1_544
O19 Eu2 O1 134.03(8) . 1_544
O19 Eu2 O3 75.09(7) . 2_656
O19 Eu2 C11 68.33(8) . 2_766
O19 Eu2 O12 72.78(7) . 2_766
O19 Eu2 O13 75.15(7) . 2_766
O19 Eu2 O13 137.46(8) . 1_545
O19 Eu2 O15 147.35(7) . 1_545
O19 Eu2 C17 78.05(7) . 2_656
O19 Eu2 O20 94.67(8) . .
O20 Eu2 Eu1 37.35(5) . 1_544
O20 Eu2 O1 63.15(7) . 1_544
O20 Eu2 O3 76.75(7) . 2_656
O20 Eu2 C11 97.13(8) . 2_766
O20 Eu2 O12 71.69(7) . 2_766
O20 Eu2 O13 124.43(7) . 1_545
O20 Eu2 O13 122.84(7) . 2_766
O20 Eu2 C17 131.27(7) . 2_656
Eu1 O1 Eu2 94.43(7) . 1_566
Eu1 O1 H1A 115(4) . .
Eu1 O1 H1B 116(4) . .
Eu2 O1 H1A 91(4) 1_566 .
Eu2 O1 H1B 130(4) 1_566 .
H1A O1 H1B 108(6) . .
C4 O2 Eu1 156.16(19) . .
C4 O3 Eu2 121.82(18) . 2_656
O2 C4 O3 124.5(3) . .
O2 C4 C5 117.7(2) . .
O3 C4 C5 117.8(2) . .
C6 C5 C4 119.0(2) . .
C6 C5 C10 118.6(3) . .
C10 C5 C4 122.3(2) . .
C5 C6 H6 119.2 . .
C7 C6 C5 121.6(3) . .
C7 C6 H6 119.2 . .
C6 C7 C8 119.0(3) . .
C6 C7 C11 118.9(2) . .
C8 C7 C11 122.0(3) . .
C7 C8 C14 125.2(2) . .
C9 C8 C7 119.5(3) . .
C9 C8 C14 115.3(2) . .
C8 C9 H9 119.4 . .
C10 C9 C8 121.3(3) . .
C10 C9 H9 119.4 . .
C5 C10 C17 125.5(3) . .
C9 C10 C5 119.9(3) . .
C9 C10 C17 114.7(2) . .
C7 C11 Eu2 162.9(2) . 2_766
O12 C11 Eu2 63.09(15) . 2_766
O12 C11 C7 120.8(3) . .
O12 C11 O13 119.9(3) . .
O13 C11 Eu2 58.73(14) . 2_766
O13 C11 C7 119.2(2) . .
C11 O12 Eu2 91.43(17) . 2_766
Eu2 O13 Eu2 110.12(8) 1_565 2_766
C11 O13 Eu2 94.84(16) . 2_766
C11 O13 Eu2 128.04(18) . 1_565
C8 C14 Eu1 169.18(19) . 1_554
O15 C14 Eu1 64.07(15) . 1_554
O15 C14 C8 119.4(3) . .
O16 C14 Eu1 56.84(15) . 1_554
O16 C14 C8 119.6(3) . .
O16 C14 O15 120.7(3) . .
Eu2 O15 Eu1 104.59(7) 1_565 1_554
C14 O15 Eu1 89.82(17) . 1_554
C14 O15 Eu2 128.72(17) . 1_565
C14 O16 Eu1 98.07(17) . 1_554
C10 C17 Eu2 106.30(17) . 2_656
O18 C17 Eu2 33.95(13) . 2_656
O18 C17 C10 118.9(3) . .
O19 C17 Eu2 130.48(19) . 2_656
O19 C17 C10 115.8(2) . .
O19 C17 O18 124.8(3) . .
C17 O18 Eu2 128.47(19) . 2_656
C17 O19 Eu2 150.1(2) . .
Eu2 O20 Eu1 107.55(8) . 1_544
C22 O20 Eu1 100.45(17) . 1_544
C22 O20 Eu2 138.03(18) . .
Eu1 O21 Eu1 110.09(7) 2_656 1_544
C22 O21 Eu1 88.73(16) . 1_544
C22 O21 Eu1 132.91(18) . 2_656
O20 C22 Eu1 55.17(14) . 1_544
O20 C22 C23 117.4(2) . .
O21 C22 Eu1 66.52(15) . 1_544
O21 C22 O20 119.7(3) . .
O21 C22 C23 122.3(2) . .
C23 C22 Eu1 156.62(18) . 1_544
C24 C23 C22 113.5(2) . .
C24 C23 C25 119.7(2) . .
C25 C23 C22 126.7(2) . .
C23 C24 H24 119.1 . .
C25 C24 C23 121.9(3) 2_655 .
C25 C24 H24 119.1 2_655 .
C23 C25 C26 125.7(2) . .
C24 C25 C23 118.4(2) 2_655 .
C24 C25 C26 115.6(2) 2_655 .
C25 C26 Eu1 168.09(19) . 1_444
O27 C26 Eu1 60.60(14) . 1_444
O27 C26 C25 121.0(2) . .
O28 C26 Eu1 60.42(14) . 1_444
O28 C26 C25 118.1(2) . .
O28 C26 O27 120.6(2) . .
Eu1 O27 Eu1 109.49(7) 2_656 1_444
C26 O27 Eu1 92.47(16) . 1_444
C26 O27 Eu1 144.97(18) . 2_656
C26 O28 Eu1 93.48(16) . 1_444
loop_
_geom_bond_atom_site_label_1
_geom_bond_atom_site_label_2
_geom_bond_distance
_geom_bond_site_symmetry_2
Eu1 O1 2.640(2) .
Eu1 O2 2.318(2) .
Eu1 C14 2.910(3) 1_556
Eu1 O15 2.617(2) 1_556
Eu1 O16 2.461(2) 1_556
Eu1 O20 2.515(2) 1_566
Eu1 O21 2.764(2) 1_566
Eu1 O21 2.373(2) 2_656
Eu1 C26 2.835(3) 1_666
Eu1 O27 2.428(2) 2_656
Eu1 O27 2.472(2) 1_666
Eu1 O28 2.470(2) 1_666
Eu2 Eu1 3.9517(3) 1_544
Eu2 O1 2.744(2) 1_544
Eu2 O3 2.418(2) 2_656
Eu2 C11 2.894(3) 2_766
Eu2 O12 2.582(2) 2_766
Eu2 O13 2.483(2) 2_766
Eu2 O13 2.461(2) 1_545
Eu2 O15 2.374(2) 1_545
Eu2 C17 3.258(3) 2_656
Eu2 O18 2.324(2) 2_656
Eu2 O19 2.325(2) .
Eu2 O20 2.383(2) .
O1 Eu2 2.744(2) 1_566
O1 H1A 0.76(6) .
O1 H1B 0.70(5) .
O2 C4 1.247(3) .
O3 Eu2 2.418(2) 2_656
O3 C4 1.270(3) .
C4 C5 1.512(4) .
C5 C6 1.399(4) .
C5 C10 1.403(4) .
C6 H6 0.9500 .
C6 C7 1.395(4) .
C7 C8 1.404(4) .
C7 C11 1.490(4) .
C8 C9 1.390(4) .
C8 C14 1.495(4) .
C9 H9 0.9500 .
C9 C10 1.389(4) .
C10 C17 1.517(4) .
C11 Eu2 2.894(3) 2_766
C11 O12 1.246(3) .
C11 O13 1.293(3) .
O12 Eu2 2.582(2) 2_766
O13 Eu2 2.483(2) 2_766
O13 Eu2 2.461(2) 1_565
C14 Eu1 2.910(3) 1_554
C14 O15 1.281(3) .
C14 O16 1.246(4) .
O15 Eu1 2.617(2) 1_554
O15 Eu2 2.374(2) 1_565
O16 Eu1 2.461(2) 1_554
C17 Eu2 3.258(3) 2_656
C17 O18 1.257(3) .
C17 O19 1.248(4) .
O18 Eu2 2.324(2) 2_656
O20 Eu1 2.515(2) 1_544
O20 C22 1.265(3) .
O21 Eu1 2.764(2) 1_544
O21 Eu1 2.373(2) 2_656
O21 C22 1.262(3) .
C22 Eu1 3.013(3) 1_544
C22 C23 1.492(4) .
C23 C24 1.397(4) .
C23 C25 1.401(4) .
C24 H24 0.9500 .
C24 C25 1.396(4) 2_655
C25 C24 1.396(4) 2_655
C25 C26 1.505(4) .
C26 Eu1 2.835(3) 1_444
C26 O27 1.285(3) .
C26 O28 1.249(3) .
O27 Eu1 2.472(2) 1_444
O27 Eu1 2.428(2) 2_656
O28 Eu1 2.470(2) 1_444
