#------------------------------------------------------------------------------
#$Date: 2021-02-25 11:40:25 +0200 (Thu, 25 Feb 2021) $
#$Revision: 262223 $
#$URL: file:///home/coder/svn-repositories/cod/cif/1/56/06/1560639.cif $
#------------------------------------------------------------------------------
#
# This file is available in the Crystallography Open Database (COD),
# http://www.crystallography.net/
#
# All data on this site have been placed in the public domain by the
# contributors.
#
data_1560639
loop_
_publ_author_name
'Ding, Ling'
'Zhong, Jie-Cen'
'Qiu, Xing-Tai'
'Sun, Yan-Qiong'
'Chen, Yi-Ping'
_publ_section_title
;
 Syntheses, structures, photoluminescence and photocatalysis of 2D layered
 lanthanide-carboxylates with 2, 2′-dithiodibenzoic acid
;
_journal_name_full               'Journal of Solid State Chemistry'
_journal_page_first              138
_journal_page_last               144
_journal_paper_doi               10.1016/j.jssc.2016.11.002
_journal_volume                  246
_journal_year                    2017
_chemical_formula_sum            'C30 H23 Eu O9 S4'
_chemical_formula_weight         807.68
_space_group_IT_number           2
_space_group_name_Hall           '-P 1'
_space_group_name_H-M_alt        'P -1'
_symmetry_cell_setting           triclinic
_symmetry_space_group_name_H-M   'P -1'
_atom_sites_solution_hydrogens   geom
_atom_sites_solution_primary     direct
_atom_sites_solution_secondary   difmap
_cell_angle_alpha                90.241(5)
_cell_angle_beta                 100.443(5)
_cell_angle_gamma                109.126(4)
_cell_formula_units_Z            2
_cell_length_a                   9.191(4)
_cell_length_b                   11.581(5)
_cell_length_c                   15.798(6)
_cell_measurement_reflns_used    2552
_cell_measurement_temperature    293(2)
_cell_measurement_theta_max      25.66
_cell_measurement_theta_min      2.39
_cell_volume                     1558.8(11)
_computing_cell_refinement       'Bruker SMART'
_computing_data_collection       'Bruker SMART'
_computing_data_reduction        'Bruker SAINT'
_computing_molecular_graphics    'Bruker SHELXTL'
_computing_publication_material  'Bruker SHELXTL'
_computing_structure_refinement  'SHELXL-97 (Sheldrick, 1997)'
_computing_structure_solution    'SHELXS-97 (Sheldrick, 1990)'
_diffrn_ambient_temperature      293(2)
_diffrn_measured_fraction_theta_full 0.971
_diffrn_measured_fraction_theta_max 0.971
_diffrn_measurement_device_type  'CCD area detector'
_diffrn_measurement_method       'phi and omega scans'
_diffrn_radiation_monochromator  graphite
_diffrn_radiation_source         'fine-focus sealed tube'
_diffrn_radiation_type           MoK\a
_diffrn_radiation_wavelength     0.71073
_diffrn_reflns_av_R_equivalents  0.0432
_diffrn_reflns_av_sigmaI/netI    0.0856
_diffrn_reflns_limit_h_max       10
_diffrn_reflns_limit_h_min       -11
_diffrn_reflns_limit_k_max       14
_diffrn_reflns_limit_k_min       -14
_diffrn_reflns_limit_l_max       19
_diffrn_reflns_limit_l_min       -19
_diffrn_reflns_number            9405
_diffrn_reflns_theta_full        26.00
_diffrn_reflns_theta_max         26.00
_diffrn_reflns_theta_min         1.31
_exptl_absorpt_coefficient_mu    2.333
_exptl_absorpt_correction_T_max  0.9
_exptl_absorpt_correction_T_min  0.881
_exptl_absorpt_correction_type   multi-scan
_exptl_crystal_colour            colorless
_exptl_crystal_density_diffrn    1.721
_exptl_crystal_density_method    'not measured'
_exptl_crystal_description       block
_exptl_crystal_F_000             804
_exptl_crystal_size_max          0.3
_exptl_crystal_size_mid          0.25
_exptl_crystal_size_min          0.2
_refine_diff_density_max         1.430
_refine_diff_density_min         -1.247
_refine_diff_density_rms         0.134
_refine_ls_extinction_method     none
_refine_ls_goodness_of_fit_ref   0.958
_refine_ls_hydrogen_treatment    mixed
_refine_ls_matrix_type           full
_refine_ls_number_parameters     402
_refine_ls_number_reflns         5954
_refine_ls_number_restraints     3
_refine_ls_restrained_S_all      0.958
_refine_ls_R_factor_all          0.0629
_refine_ls_R_factor_gt           0.0395
_refine_ls_shift/su_max          0.000
_refine_ls_shift/su_mean         0.000
_refine_ls_structure_factor_coef Fsqd
_refine_ls_weighting_details
'calc w=1/[σ²(Fo²)+(0.0280P)²+0.0000P] where P=(Fo²+2Fc²)/3'
_refine_ls_weighting_scheme      calc
_refine_ls_wR_factor_gt          0.0709
_refine_ls_wR_factor_ref         0.0772
_reflns_number_gt                4566
_reflns_number_total             5954
_reflns_threshold_expression     >2sigma(I)
_cod_data_source_file            JSSC-2017-246-138.cif
_cod_data_source_block           1
_cod_depositor_comments
;
The following automatic conversions were performed:

data item '_exptl_absorpt_correction_type' value 'Multi-scan' was
changed to 'multi-scan' in accordance with the built-in table derived
from the CIF Core dictionary named 'cif_core.dic' version 2.4.5 last
updated on 2014-11-21.

data item '_symmetry_cell_setting' value 'Triclinic' was changed to
'triclinic' in accordance with the built-in table derived from the
CIF Core dictionary named 'cif_core.dic' version 2.4.5 last updated
on 2014-11-21.

Automatic conversion script
Id: cif_fix_values 8369 2020-08-20 11:38:08Z andrius 
;
_cod_original_sg_symbol_H-M      P-1
_cod_database_code               1560639
loop_
_symmetry_equiv_pos_as_xyz
'x, y, z'
'-x, -y, -z'
loop_
_atom_site_label
_atom_site_type_symbol
_atom_site_fract_x
_atom_site_fract_y
_atom_site_fract_z
_atom_site_U_iso_or_equiv
_atom_site_adp_type
_atom_site_occupancy
_atom_site_symmetry_multiplicity
_atom_site_calc_flag
_atom_site_refinement_flags
_atom_site_disorder_assembly
_atom_site_disorder_group
Eu Eu 0.79685(3) 0.01849(2) 0.494214(18) 0.01767(8) Uani 1 1 d D . .
S1 S 0.66745(18) 0.14498(14) 0.25396(9) 0.0336(4) Uani 1 1 d . . .
S2 S 0.74260(17) 0.22579(13) 0.14798(9) 0.0321(4) Uani 1 1 d . . .
S3 S 0.93343(17) 0.43081(13) 0.38485(10) 0.0318(4) Uani 1 1 d . . .
S4 S 0.98391(19) 0.61664(13) 0.37947(10) 0.0362(4) Uani 1 1 d . . .
O1 O 0.5750(4) -0.1684(3) 0.5010(3) 0.0338(10) Uani 1 1 d D . .
H1 H 0.503(3) -0.158(2) 0.524(3) 0.051 Uiso 1 1 d D . .
O2 O 0.3299(4) -0.0586(3) 0.4007(2) 0.0329(10) Uani 1 1 d . . .
O3 O 0.5781(4) 0.0518(3) 0.4003(2) 0.0221(8) Uani 1 1 d . . .
O4 O 0.8933(5) 0.3838(4) 0.0426(3) 0.0467(12) Uani 1 1 d . . .
O5 O 1.1330(6) 0.4081(5) 0.0189(4) 0.0711(16) Uani 1 1 d . . .
H5 H 1.1320 0.4770 0.0078 0.107 Uiso 1 1 calc R . .
O6 O 1.0739(4) 0.1094(3) 0.4388(2) 0.0268(9) Uani 1 1 d . . .
O7 O 0.9013(4) 0.2051(3) 0.4284(2) 0.0260(9) Uani 1 1 d . . .
O8 O 0.7793(4) 0.8964(3) 0.3710(2) 0.0271(9) Uani 1 1 d . . .
O9 O 1.0036(4) 0.8542(3) 0.3932(2) 0.0253(9) Uani 1 1 d . . .
C1 C 0.3945(8) -0.3774(6) 0.5017(5) 0.068(2) Uani 1 1 d . . .
H1A H 0.3591 -0.4575 0.4726 0.103 Uiso 1 1 calc R . .
H1B H 0.3074 -0.3481 0.4986 0.103 Uiso 1 1 calc R . .
H1C H 0.4388 -0.3815 0.5610 0.103 Uiso 1 1 calc R . .
C2 C 0.5169(8) -0.2914(5) 0.4592(4) 0.0502(18) Uani 1 1 d D . .
H2A H 0.6037 -0.3221 0.4613 0.060 Uiso 1 1 calc R . .
H2B H 0.4723 -0.2884 0.3990 0.060 Uiso 1 1 calc R . .
C3 C 0.4445(6) -0.0194(5) 0.3628(3) 0.0221(12) Uani 1 1 d . . .
C4 C 0.4196(6) -0.0590(5) 0.2700(3) 0.0228(12) Uani 1 1 d . . .
C5 C 0.2941(6) -0.1670(5) 0.2387(4) 0.0326(14) Uani 1 1 d . . .
H5A H 0.2278 -0.2075 0.2752 0.039 Uiso 1 1 calc R . .
C6 C 0.2680(7) -0.2135(6) 0.1546(4) 0.0430(16) Uani 1 1 d . . .
H6 H 0.1874 -0.2866 0.1351 0.052 Uiso 1 1 calc R . .
C7 C 0.3631(7) -0.1503(6) 0.1001(4) 0.0363(15) Uani 1 1 d . . .
H7 H 0.3459 -0.1811 0.0433 0.044 Uiso 1 1 calc R . .
C8 C 0.4825(7) -0.0427(5) 0.1282(3) 0.0303(14) Uani 1 1 d . . .
H8 H 0.5440 -0.0006 0.0901 0.036 Uiso 1 1 calc R . .
C9 C 0.5131(6) 0.0050(5) 0.2145(3) 0.0232(12) Uani 1 1 d . . .
C10 C 0.8956(7) 0.1685(5) 0.1325(4) 0.0347(14) Uani 1 1 d . . .
C11 C 0.9055(8) 0.0607(6) 0.1676(4) 0.0473(17) Uani 1 1 d . . .
H11 H 0.8327 0.0186 0.2002 0.057 Uiso 1 1 calc R . .
C12 C 1.0207(9) 0.0155(7) 0.1549(5) 0.066(2) Uani 1 1 d . . .
H12 H 1.0260 -0.0560 0.1798 0.079 Uiso 1 1 calc R . .
C13 C 1.1293(9) 0.0745(7) 0.1056(6) 0.071(2) Uani 1 1 d . . .
H13 H 1.2057 0.0424 0.0960 0.086 Uiso 1 1 calc R . .
C14 C 1.1220(8) 0.1818(7) 0.0710(5) 0.057(2) Uani 1 1 d . . .
H14 H 1.1956 0.2229 0.0385 0.069 Uiso 1 1 calc R . .
C15 C 1.0071(7) 0.2299(6) 0.0836(4) 0.0391(15) Uani 1 1 d . . .
C16 C 1.0038(8) 0.3470(6) 0.0469(4) 0.0397(16) Uani 1 1 d . . .
C17 C 1.0265(6) 0.1971(5) 0.4120(3) 0.0239(12) Uani 1 1 d . . .
C18 C 1.1152(6) 0.2887(5) 0.3580(3) 0.0253(13) Uani 1 1 d . . .
C19 C 1.2341(7) 0.2660(6) 0.3238(4) 0.0373(15) Uani 1 1 d . . .
H19 H 1.2568 0.1946 0.3360 0.045 Uiso 1 1 calc R . .
C20 C 1.3179(8) 0.3467(7) 0.2725(4) 0.0530(19) Uani 1 1 d . . .
H20 H 1.3966 0.3301 0.2504 0.064 Uiso 1 1 calc R . .
C21 C 1.2844(8) 0.4525(6) 0.2542(4) 0.0511(19) Uani 1 1 d . . .
H21 H 1.3420 0.5080 0.2201 0.061 Uiso 1 1 calc R . .
C22 C 1.1661(7) 0.4769(5) 0.2858(4) 0.0421(16) Uani 1 1 d . . .
H22 H 1.1427 0.5474 0.2713 0.051 Uiso 1 1 calc R . .
C23 C 1.0811(6) 0.3970(5) 0.3394(3) 0.0253(13) Uani 1 1 d . . .
C24 C 0.8475(6) 0.6318(5) 0.2874(4) 0.0280(13) Uani 1 1 d . . .
C25 C 0.7869(7) 0.5434(5) 0.2187(4) 0.0394(16) Uani 1 1 d . . .
H25 H 0.8218 0.4766 0.2187 0.047 Uiso 1 1 calc R . .
C26 C 0.6750(7) 0.5536(6) 0.1500(4) 0.0450(17) Uani 1 1 d . . .
H26 H 0.6367 0.4942 0.1043 0.054 Uiso 1 1 calc R . .
C27 C 0.6202(7) 0.6509(6) 0.1490(4) 0.0431(17) Uani 1 1 d . . .
H27 H 0.5441 0.6569 0.1033 0.052 Uiso 1 1 calc R . .
C28 C 0.6801(6) 0.7397(5) 0.2170(4) 0.0314(14) Uani 1 1 d . . .
H28 H 0.6416 0.8047 0.2169 0.038 Uiso 1 1 calc R . .
C29 C 0.7958(6) 0.7343(5) 0.2853(3) 0.0214(12) Uani 1 1 d . . .
C30 C 0.8652(6) 0.8366(5) 0.3557(3) 0.0215(12) Uani 1 1 d . . .
loop_
_atom_type_symbol
_atom_type_description
_atom_type_scat_dispersion_real
_atom_type_scat_dispersion_imag
_atom_type_scat_source
C C 0.0033 0.0016 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
H H 0.0000 0.0000 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
Eu Eu -0.1578 3.6682 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
O O 0.0106 0.0060 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
S S 0.1246 0.1234 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
loop_
_geom_angle_atom_site_label_1
_geom_angle_atom_site_label_2
_geom_angle_atom_site_label_3
_geom_angle
_geom_angle_site_symmetry_1
_geom_angle_site_symmetry_3
O2 Eu O6 102.68(13) 2_656 2_756
O2 Eu O8 146.82(13) 2_656 1_545
O6 Eu O8 82.05(12) 2_756 1_545
O2 Eu O7 107.70(13) 2_656 .
O6 Eu O7 129.15(12) 2_756 .
O8 Eu O7 93.15(13) 1_545 .
O2 Eu O9 73.33(13) 2_656 2_766
O6 Eu O9 74.78(12) 2_756 2_766
O8 Eu O9 138.18(12) 1_545 2_766
O7 Eu O9 76.19(12) . 2_766
O2 Eu O3 81.73(12) 2_656 .
O6 Eu O3 151.88(12) 2_756 .
O8 Eu O3 79.88(12) 1_545 .
O7 Eu O3 73.43(12) . .
O9 Eu O3 132.10(12) 2_766 .
O2 Eu O1 72.82(13) 2_656 .
O6 Eu O1 78.64(13) 2_756 .
O8 Eu O1 76.10(13) 1_545 .
O7 Eu O1 149.15(13) . .
O9 Eu O1 130.47(13) 2_766 .
O3 Eu O1 76.22(12) . .
O2 Eu O6 140.51(12) 2_656 .
O6 Eu O6 80.43(12) 2_756 .
O8 Eu O6 72.58(11) 1_545 .
O7 Eu O6 50.43(10) . .
O9 Eu O6 69.60(12) 2_766 .
O3 Eu O6 113.96(11) . .
O1 Eu O6 144.29(11) . .
O2 Eu Eu 132.51(9) 2_656 2_756
O6 Eu Eu 43.98(9) 2_756 2_756
O8 Eu Eu 72.90(8) 1_545 2_756
O7 Eu Eu 86.09(8) . 2_756
O9 Eu Eu 66.19(8) 2_766 2_756
O3 Eu Eu 144.82(8) . 2_756
O1 Eu Eu 116.95(8) . 2_756
O6 Eu Eu 36.45(7) . 2_756
C9 S1 S2 106.14(19) . .
C10 S2 S1 104.8(2) . .
C23 S3 S4 105.16(19) . .
C24 S4 S3 104.08(19) . .
C2 O1 Eu 135.0(3) . .
C2 O1 H1 108.2(14) . .
Eu O1 H1 115.1(14) . .
C3 O2 Eu 146.6(4) . 2_656
C3 O3 Eu 133.1(3) . .
C16 O5 H5 109.5 . .
C17 O6 Eu 168.0(3) . 2_756
C17 O6 Eu 86.1(3) . .
Eu O6 Eu 99.57(12) 2_756 .
C17 O7 Eu 102.6(3) . .
C30 O8 Eu 130.3(3) . 1_565
C30 O9 Eu 141.4(3) . 2_766
C2 C1 H1A 109.5 . .
C2 C1 H1B 109.5 . .
H1A C1 H1B 109.5 . .
C2 C1 H1C 109.5 . .
H1A C1 H1C 109.5 . .
H1B C1 H1C 109.5 . .
O1 C2 C1 111.7(5) . .
O1 C2 H2A 109.3 . .
C1 C2 H2A 109.3 . .
O1 C2 H2B 109.3 . .
C1 C2 H2B 109.3 . .
H2A C2 H2B 107.9 . .
O2 C3 O3 122.9(5) . .
O2 C3 C4 117.8(5) . .
O3 C3 C4 119.3(5) . .
C9 C4 C5 119.6(5) . .
C9 C4 C3 123.2(5) . .
C5 C4 C3 117.2(5) . .
C6 C5 C4 120.9(5) . .
C6 C5 H5A 119.6 . .
C4 C5 H5A 119.6 . .
C7 C6 C5 119.2(6) . .
C7 C6 H6 120.4 . .
C5 C6 H6 120.4 . .
C8 C7 C6 120.9(6) . .
C8 C7 H7 119.5 . .
C6 C7 H7 119.5 . .
C7 C8 C9 120.7(5) . .
C7 C8 H8 119.7 . .
C9 C8 H8 119.7 . .
C4 C9 C8 118.6(5) . .
C4 C9 S1 119.2(4) . .
C8 C9 S1 122.2(4) . .
C11 C10 C15 118.2(6) . .
C11 C10 S2 120.8(5) . .
C15 C10 S2 121.0(4) . .
C12 C11 C10 121.1(6) . .
C12 C11 H11 119.5 . .
C10 C11 H11 119.5 . .
C11 C12 C13 121.0(7) . .
C11 C12 H12 119.5 . .
C13 C12 H12 119.5 . .
C14 C13 C12 118.7(7) . .
C14 C13 H13 120.7 . .
C12 C13 H13 120.7 . .
C13 C14 C15 121.4(7) . .
C13 C14 H14 119.3 . .
C15 C14 H14 119.3 . .
C14 C15 C10 119.7(6) . .
C14 C15 C16 120.2(6) . .
C10 C15 C16 120.0(6) . .
O4 C16 O5 122.8(6) . .
O4 C16 C15 123.6(6) . .
O5 C16 C15 113.6(6) . .
O7 C17 O6 120.5(5) . .
O7 C17 C18 119.0(4) . .
O6 C17 C18 120.5(5) . .
C19 C18 C23 119.1(5) . .
C19 C18 C17 119.2(5) . .
C23 C18 C17 121.7(5) . .
C20 C19 C18 121.5(6) . .
C20 C19 H19 119.3 . .
C18 C19 H19 119.3 . .
C19 C20 C21 119.4(6) . .
C19 C20 H20 120.3 . .
C21 C20 H20 120.3 . .
C20 C21 C22 120.6(6) . .
C20 C21 H21 119.7 . .
C22 C21 H21 119.7 . .
C21 C22 C23 120.9(6) . .
C21 C22 H22 119.6 . .
C23 C22 H22 119.6 . .
C22 C23 C18 118.5(5) . .
C22 C23 S3 121.4(4) . .
C18 C23 S3 120.1(4) . .
C25 C24 C29 118.8(5) . .
C25 C24 S4 121.7(4) . .
C29 C24 S4 119.4(4) . .
C26 C25 C24 120.9(5) . .
C26 C25 H25 119.6 . .
C24 C25 H25 119.6 . .
C27 C26 C25 120.6(6) . .
C27 C26 H26 119.7 . .
C25 C26 H26 119.7 . .
C26 C27 C28 119.1(5) . .
C26 C27 H27 120.5 . .
C28 C27 H27 120.5 . .
C27 C28 C29 121.8(5) . .
C27 C28 H28 119.1 . .
C29 C28 H28 119.1 . .
C28 C29 C24 118.8(5) . .
C28 C29 C30 120.4(4) . .
C24 C29 C30 120.8(5) . .
O9 C30 O8 126.0(5) . .
O9 C30 C29 116.7(4) . .
O8 C30 C29 117.3(4) . .
loop_
_geom_bond_atom_site_label_1
_geom_bond_atom_site_label_2
_geom_bond_distance
_geom_bond_site_symmetry_2
Eu O2 2.319(4) 2_656
Eu O6 2.331(3) 2_756
Eu O8 2.350(4) 1_545
Eu O7 2.386(3) .
Eu O9 2.392(3) 2_766
Eu O3 2.414(3) .
Eu O1 2.458(4) .
Eu O6 2.724(4) .
Eu Eu 3.8682(17) 2_756
S1 C9 1.787(5) .
S1 S2 2.041(2) .
S2 C10 1.792(6) .
S3 C23 1.793(5) .
S3 S4 2.053(2) .
S4 C24 1.790(6) .
O1 C2 1.455(7) .
O1 H1 0.853(9) .
O2 C3 1.261(6) .
O2 Eu 2.319(4) 2_656
O3 C3 1.267(6) .
O4 C16 1.215(7) .
O5 C16 1.322(7) .
O5 H5 0.8200 .
O6 C17 1.277(6) .
O6 Eu 2.331(3) 2_756
O7 C17 1.255(6) .
O8 C30 1.261(6) .
O8 Eu 2.350(4) 1_565
O9 C30 1.251(6) .
O9 Eu 2.392(3) 2_766
C1 C2 1.501(8) .
C1 H1A 0.9600 .
C1 H1B 0.9600 .
C1 H1C 0.9600 .
C2 H2A 0.9700 .
C2 H2B 0.9700 .
C3 C4 1.489(7) .
C4 C9 1.385(7) .
C4 C5 1.407(7) .
C5 C6 1.381(8) .
C5 H5A 0.9300 .
C6 C7 1.379(8) .
C6 H6 0.9300 .
C7 C8 1.370(7) .
C7 H7 0.9300 .
C8 C9 1.413(7) .
C8 H8 0.9300 .
C10 C11 1.392(8) .
C10 C15 1.402(8) .
C11 C12 1.370(9) .
C11 H11 0.9300 .
C12 C13 1.381(10) .
C12 H12 0.9300 .
C13 C14 1.376(9) .
C13 H13 0.9300 .
C14 C15 1.388(8) .
C14 H14 0.9300 .
C15 C16 1.485(8) .
C17 C18 1.486(7) .
C18 C19 1.399(7) .
C18 C23 1.408(7) .
C19 C20 1.373(8) .
C19 H19 0.9300 .
C20 C21 1.378(9) .
C20 H20 0.9300 .
C21 C22 1.382(8) .
C21 H21 0.9300 .
C22 C23 1.398(7) .
C22 H22 0.9300 .
C24 C25 1.391(7) .
C24 C29 1.414(7) .
C25 C26 1.387(8) .
C25 H25 0.9300 .
C26 C27 1.375(8) .
C26 H26 0.9300 .
C27 C28 1.386(8) .
C27 H27 0.9300 .
C28 C29 1.388(7) .
C28 H28 0.9300 .
C29 C30 1.511(7) .
loop_
_geom_torsion_atom_site_label_1
_geom_torsion_atom_site_label_2
_geom_torsion_atom_site_label_3
_geom_torsion_atom_site_label_4
_geom_torsion
_geom_torsion_site_symmetry_1
_geom_torsion_site_symmetry_2
_geom_torsion_site_symmetry_3
_geom_torsion_site_symmetry_4
C9 S1 S2 C10 -90.2(3) . . . .
C23 S3 S4 C24 100.9(3) . . . .
O2 Eu O1 C2 -176.2(5) 2_656 . . .
O6 Eu O1 C2 -68.9(5) 2_756 . . .
O8 Eu O1 C2 15.6(5) 1_545 . . .
O7 Eu O1 C2 87.9(5) . . . .
O9 Eu O1 C2 -127.4(5) 2_766 . . .
O3 Eu O1 C2 98.3(5) . . . .
O6 Eu O1 C2 -13.7(6) . . . .
Eu Eu O1 C2 -46.7(5) 2_756 . . .
O2 Eu O3 C3 -92.7(4) 2_656 . . .
O6 Eu O3 C3 8.8(6) 2_756 . . .
O8 Eu O3 C3 59.6(4) 1_545 . . .
O7 Eu O3 C3 156.0(4) . . . .
O9 Eu O3 C3 -151.2(4) 2_766 . . .
O1 Eu O3 C3 -18.5(4) . . . .
O6 Eu O3 C3 125.2(4) . . . .
Eu Eu O3 C3 99.1(4) 2_756 . . .
O2 Eu O6 C17 -71.0(3) 2_656 . . .
O6 Eu O6 C17 -169.3(3) 2_756 . . .
O8 Eu O6 C17 106.1(3) 1_545 . . .
O7 Eu O6 C17 -3.5(3) . . . .
O9 Eu O6 C17 -92.1(3) 2_766 . . .
O3 Eu O6 C17 36.0(3) . . . .
O1 Eu O6 C17 135.9(3) . . . .
Eu Eu O6 C17 -169.3(3) 2_756 . . .
O2 Eu O6 Eu 98.37(19) 2_656 . . 2_756
O6 Eu O6 Eu 0.0 2_756 . . 2_756
O8 Eu O6 Eu -84.60(14) 1_545 . . 2_756
O7 Eu O6 Eu 165.9(2) . . . 2_756
O9 Eu O6 Eu 77.21(13) 2_766 . . 2_756
O3 Eu O6 Eu -154.66(12) . . . 2_756
O1 Eu O6 Eu -54.8(2) . . . 2_756
O2 Eu O7 C17 145.5(3) 2_656 . . .
O6 Eu O7 C17 21.7(4) 2_756 . . .
O8 Eu O7 C17 -60.7(3) 1_545 . . .
O9 Eu O7 C17 78.4(3) 2_766 . . .
O3 Eu O7 C17 -139.1(3) . . . .
O1 Eu O7 C17 -128.5(3) . . . .
O6 Eu O7 C17 3.6(3) . . . .
Eu Eu O7 C17 11.9(3) 2_756 . . .
Eu O1 C2 C1 168.0(4) . . . .
Eu O2 C3 O3 32.8(9) 2_656 . . .
Eu O2 C3 C4 -146.9(5) 2_656 . . .
Eu O3 C3 O2 80.5(6) . . . .
Eu O3 C3 C4 -99.8(5) . . . .
O2 C3 C4 C9 158.2(5) . . . .
O3 C3 C4 C9 -21.5(7) . . . .
O2 C3 C4 C5 -21.7(7) . . . .
O3 C3 C4 C5 158.5(5) . . . .
C9 C4 C5 C6 3.5(8) . . . .
C3 C4 C5 C6 -176.5(5) . . . .
C4 C5 C6 C7 -2.5(9) . . . .
C5 C6 C7 C8 0.2(9) . . . .
C6 C7 C8 C9 1.2(9) . . . .
C5 C4 C9 C8 -2.1(7) . . . .
C3 C4 C9 C8 178.0(5) . . . .
C5 C4 C9 S1 177.6(4) . . . .
C3 C4 C9 S1 -2.3(7) . . . .
C7 C8 C9 C4 -0.3(8) . . . .
C7 C8 C9 S1 -179.9(4) . . . .
S2 S1 C9 C4 -168.2(4) . . . .
S2 S1 C9 C8 11.5(5) . . . .
S1 S2 C10 C11 20.8(6) . . . .
S1 S2 C10 C15 -160.1(5) . . . .
C15 C10 C11 C12 0.0(10) . . . .
S2 C10 C11 C12 179.0(6) . . . .
C10 C11 C12 C13 -1.1(12) . . . .
C11 C12 C13 C14 1.6(13) . . . .
C12 C13 C14 C15 -1.0(12) . . . .
C13 C14 C15 C10 0.0(11) . . . .
C13 C14 C15 C16 178.9(7) . . . .
C11 C10 C15 C14 0.6(10) . . . .
S2 C10 C15 C14 -178.5(5) . . . .
C11 C10 C15 C16 -178.3(6) . . . .
S2 C10 C15 C16 2.6(8) . . . .
C14 C15 C16 O4 167.1(7) . . . .
C10 C15 C16 O4 -14.0(10) . . . .
C14 C15 C16 O5 -12.8(9) . . . .
C10 C15 C16 O5 166.1(6) . . . .
Eu O7 C17 O6 -6.9(6) . . . .
Eu O7 C17 C18 170.8(4) . . . .
Eu O6 C17 O7 -112.8(16) 2_756 . . .
Eu O6 C17 O7 5.9(5) . . . .
Eu O6 C17 C18 69.5(18) 2_756 . . .
Eu O6 C17 C18 -171.8(5) . . . .
O7 C17 C18 C19 -166.1(5) . . . .
O6 C17 C18 C19 11.5(8) . . . .
O7 C17 C18 C23 12.9(8) . . . .
O6 C17 C18 C23 -169.4(5) . . . .
C23 C18 C19 C20 -0.1(9) . . . .
C17 C18 C19 C20 179.0(6) . . . .
C18 C19 C20 C21 -0.1(10) . . . .
C19 C20 C21 C22 -0.9(11) . . . .
C20 C21 C22 C23 2.1(11) . . . .
C21 C22 C23 C18 -2.1(9) . . . .
C21 C22 C23 S3 177.1(5) . . . .
C19 C18 C23 C22 1.1(8) . . . .
C17 C18 C23 C22 -177.9(5) . . . .
C19 C18 C23 S3 -178.2(4) . . . .
C17 C18 C23 S3 2.8(7) . . . .
S4 S3 C23 C22 -20.4(5) . . . .
S4 S3 C23 C18 158.9(4) . . . .
S3 S4 C24 C25 -27.3(5) . . . .
S3 S4 C24 C29 150.8(4) . . . .
C29 C24 C25 C26 -1.5(9) . . . .
S4 C24 C25 C26 176.5(5) . . . .
C24 C25 C26 C27 -0.8(10) . . . .
C25 C26 C27 C28 1.0(10) . . . .
C26 C27 C28 C29 1.2(10) . . . .
C27 C28 C29 C24 -3.5(9) . . . .
C27 C28 C29 C30 176.4(5) . . . .
C25 C24 C29 C28 3.6(8) . . . .
S4 C24 C29 C28 -174.5(4) . . . .
C25 C24 C29 C30 -176.3(5) . . . .
S4 C24 C29 C30 5.6(7) . . . .
Eu O9 C30 O8 1.2(9) 2_766 . . .
Eu O9 C30 C29 -179.0(3) 2_766 . . .
Eu O8 C30 O9 -20.7(8) 1_565 . . .
Eu O8 C30 C29 159.6(3) 1_565 . . .
C28 C29 C30 O9 -151.5(5) . . . .
C24 C29 C30 O9 28.3(7) . . . .
C28 C29 C30 O8 28.2(7) . . . .
C24 C29 C30 O8 -151.9(5) . . . .
