#------------------------------------------------------------------------------
#$Date: 2021-02-25 12:01:52 +0200 (Thu, 25 Feb 2021) $
#$Revision: 262227 $
#$URL: file:///home/coder/svn-repositories/cod/cif/1/56/06/1560647.cif $
#------------------------------------------------------------------------------
#
# This file is available in the Crystallography Open Database (COD),
# http://www.crystallography.net/
#
# All data on this site have been placed in the public domain by the
# contributors.
#
data_1560647
loop_
_publ_author_name
'Zheng, Ran'
'Zhang, Huixia'
'Liu, Yunping'
'Wang, Xiaoxiao'
'Han, Zhangang'
_publ_section_title
;
 Ag-ligand modified tungstovandates and their efficient catalysis
 degradation properties for methylene blue
;
_journal_name_full               'Journal of Solid State Chemistry'
_journal_page_first              258
_journal_page_last               263
_journal_paper_doi               10.1016/j.jssc.2016.11.037
_journal_volume                  246
_journal_year                    2017
_chemical_formula_sum            'C120 H120 Ag6 N20 O40 V W12'
_chemical_formula_weight         5386.72
_space_group_IT_number           4
_space_group_name_Hall           'P 2yb'
_space_group_name_H-M_alt        'P 1 21 1'
_symmetry_cell_setting           monoclinic
_symmetry_space_group_name_H-M   'P 1 21 1'
_atom_sites_solution_hydrogens   geom
_atom_sites_solution_primary     direct
_atom_sites_solution_secondary   difmap
_cell_angle_alpha                90.00
_cell_angle_beta                 108.5230(10)
_cell_angle_gamma                90.00
_cell_formula_units_Z            2
_cell_length_a                   15.7092(12)
_cell_length_b                   28.162(2)
_cell_length_c                   16.6588(12)
_cell_measurement_reflns_used    8836
_cell_measurement_temperature    296(2)
_cell_measurement_theta_max      25.71
_cell_measurement_theta_min      2.27
_cell_volume                     6988.1(9)
_computing_cell_refinement       'Bruker SMART'
_computing_data_collection       'Bruker SMART'
_computing_data_reduction        'Bruker SAINT'
_computing_molecular_graphics    'Bruker SHELXTL'
_computing_publication_material  'Bruker SHELXTL'
_computing_structure_refinement  'Bruker SHELXTL'
_computing_structure_solution    'Bruker SHELXTL'
_diffrn_ambient_temperature      296(2)
_diffrn_measured_fraction_theta_full 0.999
_diffrn_measured_fraction_theta_max 0.999
_diffrn_measurement_device_type  'CCD area detector'
_diffrn_measurement_method       'phi and omega scans'
_diffrn_radiation_monochromator  graphite
_diffrn_radiation_source         'fine-focus sealed tube'
_diffrn_radiation_type           MoK\a
_diffrn_radiation_wavelength     0.71073
_diffrn_reflns_av_R_equivalents  0.0292
_diffrn_reflns_av_sigmaI/netI    0.0570
_diffrn_reflns_limit_h_max       18
_diffrn_reflns_limit_h_min       -18
_diffrn_reflns_limit_k_max       33
_diffrn_reflns_limit_k_min       -29
_diffrn_reflns_limit_l_max       19
_diffrn_reflns_limit_l_min       -17
_diffrn_reflns_number            34925
_diffrn_reflns_theta_full        25.01
_diffrn_reflns_theta_max         25.01
_diffrn_reflns_theta_min         1.71
_exptl_absorpt_coefficient_mu    10.793
_exptl_absorpt_correction_T_max  0.305
_exptl_absorpt_correction_T_min  0.216
_exptl_absorpt_correction_type   empirical
_exptl_absorpt_process_details   sadabs
_exptl_crystal_colour            red
_exptl_crystal_density_diffrn    2.560
_exptl_crystal_density_method    'not measured'
_exptl_crystal_description       block
_exptl_crystal_F_000             4986
_exptl_crystal_size_max          0.15
_exptl_crystal_size_mid          0.13
_exptl_crystal_size_min          0.11
_refine_diff_density_max         1.854
_refine_diff_density_min         -3.287
_refine_diff_density_rms         0.219
_refine_ls_abs_structure_details 'Flack H D (1983), Acta Cryst. A39, 876-881'
_refine_ls_abs_structure_Flack   0.526(10)
_refine_ls_extinction_method     none
_refine_ls_goodness_of_fit_ref   1.060
_refine_ls_hydrogen_treatment    mixed
_refine_ls_matrix_type           full
_refine_ls_number_parameters     1741
_refine_ls_number_reflns         23104
_refine_ls_number_restraints     3185
_refine_ls_restrained_S_all      1.002
_refine_ls_R_factor_all          0.0717
_refine_ls_R_factor_gt           0.0529
_refine_ls_shift/su_max          0.000
_refine_ls_shift/su_mean         0.000
_refine_ls_structure_factor_coef Fsqd
_refine_ls_weighting_details
'calc w=1/[σ²(Fo²)+(0.0550P)²+65.4723P] where P=(Fo²+2Fc²)/3'
_refine_ls_weighting_scheme      calc
_refine_ls_wR_factor_gt          0.1215
_refine_ls_wR_factor_ref         0.1336
_reflns_number_gt                18723
_reflns_number_total             23104
_reflns_threshold_expression     >2sigma(I)
_cod_data_source_file            JSSC-2017-246-258.cif
_cod_data_source_block           20140728_hzg_lyp_23_0m
_cod_depositor_comments
;
The following automatic conversions were performed:

data item '_symmetry_cell_setting' value 'Monoclinic' was changed to
'monoclinic' in accordance with the built-in table derived from the
CIF Core dictionary named 'cif_core.dic' version 2.4.5 last updated
on 2014-11-21.

data item '_exptl_crystal_density_meas' value 'none' was changed to
'?' -- the value is perceived as not measured.

Automatic conversion script
Id: cif_fix_values 8369 2020-08-20 11:38:08Z andrius 
;
_cod_original_sg_symbol_H-M      'P2(1)   '
_cod_database_code               1560647
loop_
_symmetry_equiv_pos_as_xyz
'x, y, z'
'-x, y+1/2, -z'
loop_
_atom_site_label
_atom_site_type_symbol
_atom_site_fract_x
_atom_site_fract_y
_atom_site_fract_z
_atom_site_U_iso_or_equiv
_atom_site_adp_type
_atom_site_occupancy
_atom_site_symmetry_multiplicity
_atom_site_calc_flag
_atom_site_refinement_flags
_atom_site_disorder_assembly
_atom_site_disorder_group
W1 W 0.75495(6) 0.13577(3) 0.51698(5) 0.0404(2) Uani 1 1 d . . .
W2 W 0.73631(6) -0.11405(3) 0.48399(5) 0.0413(2) Uani 1 1 d . . .
W3 W 0.65612(6) 0.06710(3) 0.64766(5) 0.0416(2) Uani 1 1 d . . .
W4 W 0.54372(6) 0.07663(3) 0.42117(5) 0.0412(2) Uani 1 1 d . . .
W5 W 0.64506(6) -0.05420(3) 0.63008(5) 0.0445(2) Uani 1 1 d . . .
W6 W 0.94514(6) 0.07029(3) 0.59172(5) 0.0431(2) Uani 1 1 d . . .
W7 W 0.82924(6) -0.04933(3) 0.36070(5) 0.0407(2) Uani 1 1 d . . .
W8 W 0.62802(5) 0.02100(3) 0.28243(5) 0.0410(2) Uani 1 1 d . . .
W9 W 0.84558(5) 0.00095(3) 0.72074(5) 0.0409(2) Uani 1 1 d . . .
W10 W 0.84139(6) 0.07968(3) 0.37948(5) 0.0438(2) Uani 1 1 d . . .
W11 W 0.93497(5) -0.05831(3) 0.57350(5) 0.0405(2) Uani 1 1 d . . .
W12 W 0.53511(6) -0.04402(3) 0.40429(5) 0.0451(2) Uani 1 1 d . . .
Ag1 Ag 0.44677(11) 0.00515(9) 0.55835(13) 0.0761(6) Uani 1 1 d . . .
Ag2 Ag 1.03383(12) 0.01504(10) 0.44061(15) 0.0829(7) Uani 1 1 d . . .
Ag3 Ag 0.61165(18) 0.24687(7) 0.95232(14) 0.0835(7) Uani 1 1 d . . .
V1 V 0.7410(3) 0.0106(2) 0.5010(3) 0.0562(8) Uani 1 1 d . . .
Ag4 Ag 0.84590(17) 0.23373(8) 0.06222(15) 0.0887(7) Uani 1 1 d . . .
Ag5 Ag 0.65176(19) 0.78355(10) 0.94555(17) 0.1032(9) Uani 1 1 d . . .
Ag6 Ag 0.88534(17) 0.76863(7) 0.03690(13) 0.0815(7) Uani 1 1 d . . .
O1 O 0.5897(9) 0.0269(5) 0.1777(8) 0.054(4) Uani 1 1 d . . .
O2 O 0.9083(8) -0.0040(4) 0.8239(6) 0.041(3) Uani 1 1 d . . .
O3 O 0.8863(9) 0.1068(4) 0.3103(8) 0.040(3) Uani 1 1 d . . .
O4 O 0.6245(10) -0.0898(5) 0.4172(8) 0.052(4) Uani 1 1 d . . .
O5 O 0.9033(11) 0.0467(4) 0.6792(8) 0.056(4) Uani 1 1 d . . .
O6 O 0.5929(10) -0.0905(5) 0.6809(9) 0.054(4) Uani 1 1 d . . .
O7 O 0.6441(10) 0.1197(4) 0.4471(8) 0.046(4) Uani 1 1 d . . .
O8 O 1.0328(8) -0.0858(5) 0.6206(8) 0.039(3) Uani 1 1 d . . .
O9 O 0.9702(9) 0.0052(5) 0.5737(9) 0.056(4) Uani 1 1 d . . .
O10 O 0.8695(7) 0.0155(5) 0.3693(8) 0.052(3) Uani 1 1 d . . .
O11 O 0.4413(9) -0.0766(5) 0.3655(8) 0.042(3) Uani 1 1 d . . .
O12 O 0.8032(8) 0.0591(4) 0.4995(7) 0.035(3) Uani 1 1 d . . .
O13 O 0.6411(7) 0.0168(4) 0.4254(7) 0.037(3) Uani 1 1 d . . .
O14 O 0.8950(9) -0.0448(4) 0.6650(8) 0.047(3) Uani 1 1 d . . .
O15 O 0.5427(10) -0.0262(4) 0.2968(9) 0.050(4) Uani 1 1 d . . .
O16 O 1.0472(10) 0.0901(5) 0.6468(9) 0.056(4) Uani 1 1 d . . .
O17 O 0.7940(8) -0.0366(4) 0.4838(7) 0.036(3) Uani 1 1 d . . .
O18 O 0.5520(10) 0.0692(5) 0.3070(8) 0.056(4) Uani 1 1 d . . .
O19 O 0.7249(11) 0.1140(5) 0.6125(8) 0.055(4) Uani 1 1 d . . .
O20 O 0.4537(9) 0.1129(5) 0.3950(9) 0.049(4) Uani 1 1 d . . .
O21 O 0.6056(8) 0.0072(5) 0.6636(10) 0.061(4) Uani 1 1 d . . .
O22 O 0.8557(10) -0.1137(5) 0.5553(7) 0.055(4) Uani 1 1 d . . .
O23 O 0.6116(9) 0.1018(5) 0.7061(9) 0.048(4) Uani 1 1 d . . .
O24 O 0.5688(9) 0.0696(5) 0.5412(8) 0.045(3) Uani 1 1 d . . .
O25 O 0.7023(9) -0.0960(5) 0.5779(8) 0.045(3) Uani 1 1 d . . .
O26 O 0.7263(7) 0.0077(4) 0.5942(6) 0.041(3) Uani 1 1 d . . .
O27 O 0.7538(9) -0.0446(4) 0.7229(8) 0.047(3) Uani 1 1 d . . .
O28 O 0.4800(9) 0.0177(5) 0.4053(9) 0.063(4) Uani 1 1 d . . .
O29 O 0.5550(9) -0.0461(6) 0.5239(8) 0.062(5) Uani 1 1 d . . .
O30 O 0.7183(11) -0.1738(5) 0.4773(9) 0.056(4) Uani 1 1 d . . .
O31 O 0.7733(10) -0.1038(6) 0.3884(8) 0.061(5) Uani 1 1 d . . .
O32 O 0.7136(9) -0.0263(4) 0.2991(9) 0.049(4) Uani 1 1 d . . .
O33 O 0.8648(10) -0.0714(5) 0.2847(9) 0.052(4) Uani 1 1 d . . .
O34 O 0.9348(9) -0.0636(5) 0.4586(8) 0.047(3) Uani 1 1 d . . .
O35 O 0.7250(9) 0.0649(4) 0.3147(8) 0.051(4) Uani 1 1 d . . .
O36 O 0.9472(10) 0.0804(6) 0.4787(8) 0.065(5) Uani 1 1 d . . .
O37 O 0.7997(11) 0.1369(5) 0.4195(8) 0.061(4) Uani 1 1 d . . .
O38 O 0.8796(10) 0.1273(6) 0.5859(9) 0.062(4) Uani 1 1 d . . .
O39 O 0.7477(10) 0.1936(4) 0.5277(9) 0.053(4) Uani 1 1 d . . .
O40 O 0.7647(10) 0.0493(4) 0.7356(9) 0.054(4) Uani 1 1 d . . .
N1 N 0.3558(10) -0.0234(6) 0.6344(10) 0.084(3) Uani 1 1 d GU . .
C1 C 0.3660(10) -0.0671(6) 0.6752(11) 0.094(4) Uani 1 1 d GU . .
H1 H 0.4148 -0.0863 0.6773 0.112 Uiso 1 1 calc R . .
C2 C 0.3032(13) -0.0820(5) 0.7128(11) 0.095(4) Uani 1 1 d GDU . .
C3 C 0.2303(11) -0.0532(6) 0.7096(10) 0.094(4) Uani 1 1 d GU . .
H3 H 0.1884 -0.0632 0.7348 0.113 Uiso 1 1 calc R . .
C4 C 0.2202(9) -0.0096(6) 0.6688(11) 0.091(4) Uani 1 1 d GU . .
H4 H 0.1714 0.0097 0.6667 0.110 Uiso 1 1 calc R . .
C5 C 0.2829(11) 0.0054(4) 0.6312(10) 0.082(3) Uani 1 1 d GDU . .
C11 C 0.3215(19) -0.1286(6) 0.7588(16) 0.099(4) Uani 1 1 d DU . .
H11A H 0.3713 -0.1439 0.7479 0.148 Uiso 1 1 calc R . .
H11B H 0.2693 -0.1485 0.7393 0.148 Uiso 1 1 calc R . .
H11C H 0.3356 -0.1231 0.8185 0.148 Uiso 1 1 calc R . .
N2 N 0.3438(10) 0.0633(5) 0.5565(10) 0.084(3) Uani 1 1 d GU . .
C6 C 0.2757(12) 0.0520(4) 0.5898(10) 0.084(3) Uani 1 1 d GDU . .
C7 C 0.2111(10) 0.0857(6) 0.5899(10) 0.089(4) Uani 1 1 d GU . .
H7 H 0.1655 0.0782 0.6122 0.106 Uiso 1 1 calc R . .
C8 C 0.2145(11) 0.1307(5) 0.5566(12) 0.097(4) Uani 1 1 d GU . .
H8 H 0.1713 0.1532 0.5567 0.117 Uiso 1 1 calc R . .
C9 C 0.2827(14) 0.1419(5) 0.5233(12) 0.095(4) Uani 1 1 d GDU . .
C10 C 0.3473(11) 0.1083(6) 0.5232(10) 0.091(4) Uani 1 1 d GU . .
H10 H 0.3929 0.1158 0.5009 0.109 Uiso 1 1 calc R . .
C12 C 0.2867(19) 0.1868(7) 0.4764(15) 0.098(4) Uani 1 1 d DU . .
H12A H 0.2422 0.1858 0.4214 0.147 Uiso 1 1 calc R . .
H12B H 0.3452 0.1900 0.4704 0.147 Uiso 1 1 calc R . .
H12C H 0.2752 0.2135 0.5073 0.147 Uiso 1 1 calc R . .
N3 N 1.1387(9) -0.0380(6) 0.4409(10) 0.095(4) Uani 1 1 d GU . .
C13 C 1.1409(11) -0.0833(6) 0.4746(10) 0.096(4) Uani 1 1 d GU . .
H13 H 1.0975 -0.0925 0.4986 0.115 Uiso 1 1 calc R . .
C14 C 1.2080(14) -0.1150(5) 0.4723(12) 0.100(5) Uani 1 1 d GU . .
C15 C 1.2729(11) -0.1013(6) 0.4364(12) 0.101(4) Uani 1 1 d GU . .
H15 H 1.3178 -0.1225 0.4348 0.121 Uiso 1 1 calc R . .
C16 C 1.2706(10) -0.0560(7) 0.4027(10) 0.095(4) Uani 1 1 d GU . .
H16 H 1.3140 -0.0468 0.3787 0.114 Uiso 1 1 calc R . .
C17 C 1.2036(12) -0.0243(5) 0.4050(10) 0.089(4) Uani 1 1 d GDU . .
C23 C 1.1960(19) -0.1645(11) 0.4940(17) 0.104(4) Uani 1 1 d U . .
H23A H 1.1944 -0.1660 0.5511 0.156 Uiso 1 1 calc R . .
H23B H 1.2451 -0.1833 0.4892 0.156 Uiso 1 1 calc R . .
H23C H 1.1407 -0.1765 0.4561 0.156 Uiso 1 1 calc R . .
N4 N 1.1196(10) 0.0470(6) 0.3595(10) 0.094(4) Uani 1 1 d GU . .
C18 C 1.2001(12) 0.0242(5) 0.3667(10) 0.092(4) Uani 1 1 d GDU . .
C19 C 1.2624(9) 0.0454(6) 0.3346(11) 0.096(4) Uani 1 1 d GU . .
H19 H 1.3163 0.0301 0.3395 0.116 Uiso 1 1 calc R . .
C20 C 1.2442(10) 0.0894(6) 0.2953(11) 0.101(5) Uani 1 1 d GU . .
H20 H 1.2858 0.1036 0.2738 0.122 Uiso 1 1 calc R . .
C21 C 1.1636(11) 0.1123(5) 0.2880(11) 0.100(4) Uani 1 1 d GDU . .
C22 C 1.1013(9) 0.0911(6) 0.3201(11) 0.100(4) Uani 1 1 d GDU . .
H22 H 1.0475 0.1064 0.3152 0.120 Uiso 1 1 calc R . .
C24 C 1.1414(17) 0.1586(7) 0.2416(16) 0.101(4) Uani 1 1 d DU . .
H24A H 1.1586 0.1573 0.1913 0.152 Uiso 1 1 calc R . .
H24B H 1.1733 0.1838 0.2774 0.152 Uiso 1 1 calc R . .
H24C H 1.0780 0.1643 0.2265 0.152 Uiso 1 1 calc R . .
C25 C 0.6936(16) 0.2371(9) 1.1590(14) 0.061(4) Uani 1 1 d U . .
H25 H 0.7185 0.2667 1.1561 0.073 Uiso 1 1 calc R . .
C26 C 0.6999(17) 0.2185(8) 1.2368(15) 0.060(4) Uani 1 1 d U . .
C27 C 0.6686(16) 0.1729(8) 1.2433(15) 0.061(4) Uani 1 1 d U . .
H27 H 0.6731 0.1594 1.2954 0.074 Uiso 1 1 calc R . .
C28 C 0.6302(15) 0.1484(8) 1.1674(13) 0.056(4) Uani 1 1 d U . .
H28 H 0.6094 0.1175 1.1680 0.067 Uiso 1 1 calc R . .
C29 C 0.6232(15) 0.1702(8) 1.0920(14) 0.054(3) Uani 1 1 d U . .
C30 C 0.5765(15) 0.1439(8) 1.0112(13) 0.054(3) Uani 1 1 d U . .
C31 C 0.5556(15) 0.0962(8) 1.0079(14) 0.057(3) Uani 1 1 d U . .
H31 H 0.5707 0.0788 1.0579 0.068 Uiso 1 1 calc R . .
C32 C 0.5136(15) 0.0738(9) 0.9332(13) 0.066(4) Uani 1 1 d U . .
H32 H 0.5004 0.0416 0.9330 0.079 Uiso 1 1 calc R . .
C33 C 0.4901(16) 0.0992(9) 0.8566(15) 0.065(4) Uani 1 1 d U . .
C34 C 0.5125(17) 0.1468(10) 0.8663(16) 0.073(3) Uani 1 1 d U . .
H34 H 0.4982 0.1653 0.8175 0.088 Uiso 1 1 calc R . .
C35 C 0.4448(17) 0.0756(10) 0.7746(15) 0.077(3) Uani 1 1 d U . .
H35A H 0.4124 0.0988 0.7342 0.116 Uiso 1 1 calc R . .
H35B H 0.4038 0.0521 0.7823 0.116 Uiso 1 1 calc R . .
H35C H 0.4889 0.0606 0.7543 0.116 Uiso 1 1 calc R . .
C36 C 0.7490(17) 0.2460(9) 1.3220(15) 0.072(4) Uani 1 1 d U . .
H36A H 0.8031 0.2294 1.3524 0.108 Uiso 1 1 calc R . .
H36B H 0.7101 0.2476 1.3561 0.108 Uiso 1 1 calc R . .
H36C H 0.7637 0.2775 1.3089 0.108 Uiso 1 1 calc R . .
C37 C 0.5851(17) 0.3577(9) 0.9908(18) 0.076(4) Uani 1 1 d U . .
H37 H 0.6057 0.3472 1.0466 0.091 Uiso 1 1 calc R . .
C38 C 0.5677(18) 0.4050(10) 0.9764(19) 0.079(4) Uani 1 1 d U . .
C39 C 0.5514(18) 0.4194(10) 0.8923(18) 0.080(4) Uani 1 1 d U . .
H39 H 0.5434 0.4514 0.8786 0.096 Uiso 1 1 calc R . .
C40 C 0.5478(18) 0.3914(10) 0.8387(19) 0.077(4) Uani 1 1 d U . .
H40 H 0.5374 0.4032 0.7842 0.092 Uiso 1 1 calc R . .
C41 C 0.5576(17) 0.3428(9) 0.8491(17) 0.068(4) Uani 1 1 d U . .
C42 C 0.5545(19) 0.3084(10) 0.7829(18) 0.070(4) Uani 1 1 d U . .
C43 C 0.5042(19) 0.3159(9) 0.6928(17) 0.074(4) Uani 1 1 d U . .
H43 H 0.4698 0.3431 0.6758 0.089 Uiso 1 1 calc R . .
C44 C 0.5077(19) 0.2849(10) 0.6379(18) 0.081(4) Uani 1 1 d U . .
H44 H 0.4831 0.2930 0.5811 0.097 Uiso 1 1 calc R . .
C45 C 0.5463(19) 0.2394(10) 0.6572(17) 0.079(4) Uani 1 1 d U . .
C46 C 0.5908(18) 0.2339(10) 0.7445(17) 0.077(4) Uani 1 1 d U . .
H46 H 0.6233 0.2060 0.7616 0.092 Uiso 1 1 calc R . .
C47 C 0.5392(18) 0.2020(9) 0.5931(16) 0.085(3) Uani 1 1 d U . .
H47A H 0.4874 0.2079 0.5447 0.127 Uiso 1 1 calc R . .
H47B H 0.5333 0.1716 0.6168 0.127 Uiso 1 1 calc R . .
H47C H 0.5922 0.2023 0.5761 0.127 Uiso 1 1 calc R . .
C48 C 0.5820(17) 0.4356(9) 1.0514(16) 0.080(3) Uani 1 1 d U . .
H48A H 0.5464 0.4242 1.0847 0.120 Uiso 1 1 calc R . .
H48B H 0.5647 0.4676 1.0335 0.120 Uiso 1 1 calc R . .
H48C H 0.6443 0.4350 1.0848 0.120 Uiso 1 1 calc R . .
C49 C 0.8157(19) 0.3542(10) 0.0135(19) 0.089(4) Uani 1 1 d U . .
H49 H 0.7754 0.3442 -0.0377 0.107 Uiso 1 1 calc R . .
C50 C 0.8395(19) 0.4008(10) 0.022(2) 0.088(4) Uani 1 1 d U . .
C51 C 0.8944(19) 0.4115(10) 0.0963(19) 0.086(4) Uani 1 1 d U . .
H51 H 0.9124 0.4431 0.1049 0.103 Uiso 1 1 calc R . .
C52 C 0.9277(18) 0.3820(9) 0.1616(19) 0.084(4) Uani 1 1 d U . .
H52 H 0.9650 0.3926 0.2138 0.101 Uiso 1 1 calc R . .
C53 C 0.9036(19) 0.3352(10) 0.1472(19) 0.081(4) Uani 1 1 d U . .
C54 C 0.936(2) 0.3022(10) 0.2165(19) 0.078(4) Uani 1 1 d U . .
C55 C 0.993(2) 0.3139(10) 0.3014(19) 0.085(4) Uani 1 1 d U . .
H55 H 1.0146 0.3446 0.3143 0.102 Uiso 1 1 calc R . .
C56 C 1.013(2) 0.2797(11) 0.362(2) 0.091(4) Uani 1 1 d U . .
H56 H 1.0432 0.2891 0.4175 0.109 Uiso 1 1 calc R . .
C57 C 0.996(2) 0.2364(11) 0.3495(19) 0.086(4) Uani 1 1 d U . .
C58 C 0.9430(19) 0.2250(12) 0.265(2) 0.091(4) Uani 1 1 d U . .
H58 H 0.9188 0.1946 0.2540 0.109 Uiso 1 1 calc R . .
C59 C 1.0083(19) 0.2012(10) 0.4145(18) 0.090(4) Uani 1 1 d U . .
H59A H 1.0588 0.2098 0.4624 0.135 Uiso 1 1 calc R . .
H59B H 1.0190 0.1709 0.3932 0.135 Uiso 1 1 calc R . .
H59C H 0.9553 0.1995 0.4314 0.135 Uiso 1 1 calc R . .
C60 C 0.7927(18) 0.4361(10) -0.0490(18) 0.094(4) Uani 1 1 d U . .
H60A H 0.7349 0.4444 -0.0449 0.141 Uiso 1 1 calc R . .
H60B H 0.7853 0.4217 -0.1030 0.141 Uiso 1 1 calc R . .
H60C H 0.8287 0.4642 -0.0433 0.141 Uiso 1 1 calc R . .
C61 C 0.8278(17) 0.1217(9) 0.0901(15) 0.068(4) Uani 1 1 d U . .
H61 H 0.8332 0.1328 0.1440 0.081 Uiso 1 1 calc R . .
C62 C 0.8227(17) 0.0706(8) 0.0797(14) 0.067(4) Uani 1 1 d U . .
C63 C 0.8087(17) 0.0568(9) -0.0050(14) 0.074(4) Uani 1 1 d U . .
H63 H 0.7996 0.0249 -0.0200 0.089 Uiso 1 1 calc R . .
C64 C 0.8084(17) 0.0921(9) -0.0694(15) 0.072(4) Uani 1 1 d U . .
H64 H 0.8009 0.0834 -0.1251 0.086 Uiso 1 1 calc R . .
C65 C 0.8200(17) 0.1391(9) -0.0441(13) 0.066(4) Uani 1 1 d U . .
C66 C 0.8182(17) 0.1767(8) -0.1064(14) 0.066(4) Uani 1 1 d U . .
C67 C 0.8054(18) 0.1667(9) -0.1889(15) 0.077(4) Uani 1 1 d U . .
H67 H 0.7954 0.1353 -0.2070 0.093 Uiso 1 1 calc R . .
C68 C 0.8066(19) 0.2006(9) -0.2459(16) 0.079(4) Uani 1 1 d U . .
H68 H 0.7994 0.1928 -0.3019 0.095 Uiso 1 1 calc R . .
C69 C 0.819(2) 0.2469(10) -0.2192(16) 0.085(4) Uani 1 1 d U . .
C70 C 0.8384(18) 0.2515(9) -0.1327(15) 0.077(4) Uani 1 1 d U . .
H70 H 0.8536 0.2817 -0.1102 0.092 Uiso 1 1 calc R . .
C71 C 0.812(2) 0.2865(9) -0.2772(16) 0.085(4) Uani 1 1 d U . .
H71A H 0.7533 0.2864 -0.3191 0.128 Uiso 1 1 calc R . .
H71B H 0.8567 0.2835 -0.3046 0.128 Uiso 1 1 calc R . .
H71C H 0.8203 0.3158 -0.2462 0.128 Uiso 1 1 calc R . .
C72 C 0.8290(17) 0.0380(9) 0.1479(14) 0.073(4) Uani 1 1 d U . .
H72A H 0.7873 0.0472 0.1765 0.110 Uiso 1 1 calc R . .
H72B H 0.8888 0.0386 0.1872 0.110 Uiso 1 1 calc R . .
H72C H 0.8150 0.0065 0.1256 0.110 Uiso 1 1 calc R . .
C73 C 0.6611(18) 0.9016(11) 0.9195(18) 0.083(4) Uani 1 1 d U . .
H73 H 0.6621 0.8928 0.8660 0.099 Uiso 1 1 calc R . .
C74 C 0.6563(17) 0.9451(9) 0.9328(14) 0.076(4) Uani 1 1 d DU . .
C75 C 0.6575(17) 0.9592(10) 1.0110(15) 0.082(4) Uani 1 1 d U . .
H75 H 0.6517 0.9910 1.0231 0.098 Uiso 1 1 calc R . .
C76 C 0.6680(17) 0.9238(10) 1.0737(17) 0.080(4) Uani 1 1 d U . .
H76 H 0.6711 0.9330 1.1283 0.095 Uiso 1 1 calc R . .
C77 C 0.6734(18) 0.8782(11) 1.0572(16) 0.079(4) Uani 1 1 d U . .
N14 N 0.6545(12) 0.7944(6) 1.0840(8) 0.091(4) Uani 1 1 d GU . .
C78 C 0.6719(13) 0.8401(5) 1.1168(10) 0.080(4) Uani 1 1 d GU . .
C79 C 0.6900(13) 0.8477(5) 1.2030(10) 0.086(4) Uani 1 1 d GU . .
H79 H 0.7016 0.8783 1.2250 0.103 Uiso 1 1 calc R . .
C80 C 0.6907(13) 0.8097(7) 1.2565(8) 0.092(4) Uani 1 1 d GU . .
H80 H 0.7028 0.8148 1.3142 0.110 Uiso 1 1 calc R . .
C81 C 0.6733(13) 0.7641(6) 1.2236(10) 0.093(4) Uani 1 1 d GDU . .
C82 C 0.6552(12) 0.7564(5) 1.1374(11) 0.092(4) Uani 1 1 d GU . .
H82 H 0.6436 0.7259 1.1154 0.111 Uiso 1 1 calc R . .
C83 C 0.677(2) 0.7222(7) 1.2806(15) 0.096(4) Uani 1 1 d DU . .
H83A H 0.7270 0.7025 1.2821 0.144 Uiso 1 1 calc R . .
H83B H 0.6222 0.7042 1.2593 0.144 Uiso 1 1 calc R . .
H83C H 0.6828 0.7332 1.3367 0.144 Uiso 1 1 calc R . .
C84 C 0.6475(18) 0.9820(9) 0.8660(14) 0.084(4) Uani 1 1 d DU . .
H84A H 0.7041 0.9860 0.8563 0.126 Uiso 1 1 calc R . .
H84B H 0.6298 1.0116 0.8845 0.126 Uiso 1 1 calc R . .
H84C H 0.6030 0.9722 0.8145 0.126 Uiso 1 1 calc R . .
N15 N 0.6609(12) 0.6987(5) 0.9352(13) 0.105(4) Uani 1 1 d GU . .
C85 C 0.7019(12) 0.6699(7) 1.0044(10) 0.106(4) Uani 1 1 d GU . .
H85 H 0.7381 0.6833 1.0547 0.128 Uiso 1 1 calc R . .
C86 C 0.6888(13) 0.6210(7) 0.9984(11) 0.111(5) Uani 1 1 d GDU . .
C87 C 0.6347(13) 0.6010(5) 0.9232(14) 0.110(5) Uani 1 1 d GU . .
H87 H 0.6259 0.5683 0.9192 0.132 Uiso 1 1 calc R . .
C88 C 0.5936(12) 0.6299(7) 0.8540(11) 0.102(5) Uani 1 1 d GU . .
H88 H 0.5574 0.6165 0.8037 0.123 Uiso 1 1 calc R . .
C89 C 0.6067(12) 0.6787(7) 0.8600(11) 0.102(4) Uani 1 1 d GU . .
C90 C 0.564(2) 0.7130(13) 0.793(2) 0.099(4) Uani 1 1 d U . .
C91 C 0.523(2) 0.6973(12) 0.718(2) 0.101(5) Uani 1 1 d U . .
H91 H 0.5180 0.6648 0.7077 0.121 Uiso 1 1 calc R . .
C92 C 0.486(2) 0.7290(12) 0.651(2) 0.105(5) Uani 1 1 d U . .
H92 H 0.4530 0.7177 0.5983 0.126 Uiso 1 1 calc R . .
C93 C 0.501(2) 0.7792(11) 0.6653(19) 0.107(5) Uani 1 1 d DU . .
C94 C 0.542(2) 0.7915(13) 0.741(2) 0.106(5) Uani 1 1 d U . .
H94 H 0.5452 0.8239 0.7525 0.127 Uiso 1 1 calc R . .
C95 C 0.4623(19) 0.8159(11) 0.5982(18) 0.110(5) Uani 1 1 d DU . .
H95A H 0.3987 0.8182 0.5874 0.165 Uiso 1 1 calc R . .
H95B H 0.4740 0.8068 0.5471 0.165 Uiso 1 1 calc R . .
H95C H 0.4898 0.8460 0.6171 0.165 Uiso 1 1 calc R . .
C96 C 0.7244(19) 0.5951(10) 1.0809(13) 0.113(4) Uani 1 1 d DU . .
H96A H 0.7728 0.6129 1.1187 0.169 Uiso 1 1 calc R . .
H96B H 0.7459 0.5644 1.0713 0.169 Uiso 1 1 calc R . .
H96C H 0.6773 0.5913 1.1057 0.169 Uiso 1 1 calc R . .
C97 C 0.9346(18) 0.6596(9) -0.0004(17) 0.074(4) Uani 1 1 d U . .
H97 H 0.9301 0.6713 -0.0538 0.089 Uiso 1 1 calc R . .
C98 C 0.9456(19) 0.6112(9) 0.0158(18) 0.075(4) Uani 1 1 d U . .
C99 C 0.9684(19) 0.5959(9) 0.0953(17) 0.078(4) Uani 1 1 d U . .
H99 H 0.9815 0.5640 0.1074 0.094 Uiso 1 1 calc R . .
C100 C 0.9732(18) 0.6299(9) 0.1652(16) 0.071(4) Uani 1 1 d U . .
H100 H 0.9914 0.6204 0.2215 0.086 Uiso 1 1 calc R . .
C101 C 0.9493(18) 0.6758(9) 0.1421(16) 0.069(4) Uani 1 1 d U . .
C102 C 0.947(2) 0.7119(9) 0.2086(18) 0.072(4) Uani 1 1 d U . .
C103 C 0.987(2) 0.7012(9) 0.2909(16) 0.077(4) Uani 1 1 d U . .
H103 H 1.0147 0.6721 0.3087 0.092 Uiso 1 1 calc R . .
C104 C 0.983(2) 0.7369(9) 0.3466(17) 0.082(4) Uani 1 1 d U . .
H104 H 1.0111 0.7318 0.4041 0.098 Uiso 1 1 calc R . .
C105 C 0.9424(19) 0.7785(9) 0.3220(16) 0.077(4) Uani 1 1 d U . .
C106 C 0.9014(18) 0.7858(9) 0.2355(15) 0.073(4) Uani 1 1 d U . .
H106 H 0.8726 0.8144 0.2163 0.088 Uiso 1 1 calc R . .
C107 C 0.9261(19) 0.8133(9) 0.3820(16) 0.083(3) Uani 1 1 d U . .
H10A H 0.9680 0.8391 0.3898 0.124 Uiso 1 1 calc R . .
H10B H 0.9337 0.7981 0.4354 0.124 Uiso 1 1 calc R . .
H10C H 0.8660 0.8254 0.3597 0.124 Uiso 1 1 calc R . .
C108 C 0.9430(18) 0.5723(8) -0.0499(16) 0.082(4) Uani 1 1 d U . .
H10D H 0.9470 0.5417 -0.0238 0.124 Uiso 1 1 calc R . .
H10E H 0.9927 0.5765 -0.0711 0.124 Uiso 1 1 calc R . .
H10F H 0.8878 0.5746 -0.0959 0.124 Uiso 1 1 calc R . .
C109 C 0.9867(18) 0.8709(9) 0.1267(16) 0.071(4) Uani 1 1 d U . .
H109 H 1.0123 0.8517 0.1735 0.085 Uiso 1 1 calc R . .
C110 C 0.9955(16) 0.9181(8) 0.1414(14) 0.062(4) Uani 1 1 d U . .
C111 C 0.9637(16) 0.9439(8) 0.0711(14) 0.063(4) Uani 1 1 d U . .
H111 H 0.9712 0.9766 0.0744 0.076 Uiso 1 1 calc R . .
C112 C 0.9206(16) 0.9238(8) -0.0051(14) 0.061(3) Uani 1 1 d U . .
H112 H 0.8961 0.9428 -0.0525 0.073 Uiso 1 1 calc R . .
C113 C 0.9135(16) 0.8747(8) -0.0117(14) 0.054(3) Uani 1 1 d U . .
C114 C 0.8678(16) 0.8511(8) -0.0945(14) 0.054(3) Uani 1 1 d U . .
C115 C 0.8567(16) 0.8703(8) -0.1729(14) 0.061(3) Uani 1 1 d U . .
H115 H 0.8813 0.9000 -0.1757 0.073 Uiso 1 1 calc R . .
C116 C 0.8147(17) 0.8496(8) -0.2420(15) 0.059(4) Uani 1 1 d U . .
H116 H 0.8038 0.8658 -0.2929 0.071 Uiso 1 1 calc R . .
C117 C 0.7849(17) 0.8032(8) -0.2424(15) 0.064(4) Uani 1 1 d U . .
C118 C 0.8012(16) 0.7825(8) -0.1609(14) 0.060(4) Uani 1 1 d U . .
H118 H 0.7839 0.7511 -0.1582 0.072 Uiso 1 1 calc R . .
C119 C 0.7444(17) 0.7752(9) -0.3178(15) 0.068(3) Uani 1 1 d U . .
H11D H 0.6839 0.7673 -0.3213 0.101 Uiso 1 1 calc R . .
H11E H 0.7784 0.7466 -0.3152 0.101 Uiso 1 1 calc R . .
H11F H 0.7441 0.7932 -0.3669 0.101 Uiso 1 1 calc R . .
C120 C 1.0466(17) 0.9368(8) 0.2254(14) 0.070(3) Uani 1 1 d U . .
H12D H 1.1086 0.9279 0.2387 0.105 Uiso 1 1 calc R . .
H12E H 1.0229 0.9239 0.2672 0.105 Uiso 1 1 calc R . .
H12F H 1.0418 0.9708 0.2250 0.105 Uiso 1 1 calc R . .
N5 N 0.6523(13) 0.2136(6) 1.0866(11) 0.052(3) Uani 1 1 d U . .
N6 N 0.5529(14) 0.1684(8) 0.9395(12) 0.069(3) Uani 1 1 d U . .
N7 N 0.5745(14) 0.3268(7) 0.9316(15) 0.073(3) Uani 1 1 d U . .
N8 N 0.5907(15) 0.2644(8) 0.8043(14) 0.073(3) Uani 1 1 d U . .
N9 N 0.8483(15) 0.3207(8) 0.0773(16) 0.082(4) Uani 1 1 d U . .
N10 N 0.9267(16) 0.2543(9) 0.2021(16) 0.081(4) Uani 1 1 d U . .
N11 N 0.8261(14) 0.1520(7) 0.0371(11) 0.066(3) Uani 1 1 d U . .
N12 N 0.8379(16) 0.2187(7) -0.0808(12) 0.075(4) Uani 1 1 d U . .
N13 N 0.6652(14) 0.8645(8) 0.9777(13) 0.078(4) Uani 1 1 d U . .
N16 N 0.5802(18) 0.7628(10) 0.8064(18) 0.103(4) Uani 1 1 d U . .
N17 N 0.9305(15) 0.6895(7) 0.0613(14) 0.073(4) Uani 1 1 d U . .
N18 N 0.9035(15) 0.7514(7) 0.1794(13) 0.069(3) Uani 1 1 d U . .
N19 N 0.9461(14) 0.8481(7) 0.0542(12) 0.067(3) Uani 1 1 d U . .
N20 N 0.8382(15) 0.8044(7) -0.0909(12) 0.060(3) Uani 1 1 d U . .
loop_
_atom_type_symbol
_atom_type_description
_atom_type_scat_dispersion_real
_atom_type_scat_dispersion_imag
_atom_type_scat_source
C C 0.0033 0.0016 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
H H 0.0000 0.0000 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
N N 0.0061 0.0033 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
O O 0.0106 0.0060 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
W W -0.8490 6.8722 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
V V 0.3005 0.5294 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
Ag Ag -0.8971 1.1015 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
loop_
_geom_angle_atom_site_label_1
_geom_angle_atom_site_label_2
_geom_angle_atom_site_label_3
_geom_angle
_geom_angle_site_symmetry_1
_geom_angle_site_symmetry_3
O39 W1 O7 103.3(7) . .
O39 W1 O19 100.6(7) . .
O7 W1 O19 90.8(6) . .
O39 W1 O38 98.5(7) . .
O7 W1 O38 158.1(7) . .
O19 W1 O38 86.5(7) . .
O39 W1 O37 97.4(7) . .
O7 W1 O37 89.8(6) . .
O19 W1 O37 161.4(6) . .
O38 W1 O37 86.1(6) . .
O39 W1 O12 164.5(6) . .
O7 W1 O12 88.5(5) . .
O19 W1 O12 89.1(5) . .
O38 W1 O12 69.8(6) . .
O37 W1 O12 72.3(5) . .
O30 W2 O22 99.2(7) . .
O30 W2 O25 103.7(6) . .
O22 W2 O25 87.9(6) . .
O30 W2 O31 100.7(7) . .
O22 W2 O31 91.1(6) . .
O25 W2 O31 155.4(7) . .
O30 W2 O4 102.4(7) . .
O22 W2 O4 158.4(6) . .
O25 W2 O4 86.3(5) . .
O31 W2 O4 85.7(7) . .
O30 W2 O17 165.3(6) . .
O22 W2 O17 71.8(5) . .
O25 W2 O17 87.8(5) . .
O31 W2 O17 68.6(6) . .
O4 W2 O17 87.2(6) . .
O23 W3 O24 102.3(6) . .
O23 W3 O19 98.9(7) . .
O24 W3 O19 89.9(6) . .
O23 W3 O21 99.5(6) . .
O24 W3 O21 87.3(6) . .
O19 W3 O21 161.6(6) . .
O23 W3 O40 98.1(6) . .
O24 W3 O40 159.6(6) . .
O19 W3 O40 87.9(6) . .
O21 W3 O40 88.4(6) . .
O23 W3 O26 166.7(6) . .
O24 W3 O26 87.6(5) . .
O19 W3 O26 89.9(5) . .
O21 W3 O26 71.9(5) . .
O40 W3 O26 72.1(5) . .
O20 W4 O28 97.5(7) . .
O20 W4 O24 102.1(6) . .
O28 W4 O24 88.8(6) . .
O20 W4 O7 103.7(7) . .
O28 W4 O7 158.8(6) . .
O24 W4 O7 87.1(5) . .
O20 W4 O18 97.1(6) . .
O28 W4 O18 88.1(5) . .
O24 W4 O18 160.9(6) . .
O7 W4 O18 89.0(6) . .
O20 W4 O13 164.3(6) . .
O28 W4 O13 71.1(5) . .
O24 W4 O13 88.7(5) . .
O7 W4 O13 88.0(5) . .
O18 W4 O13 72.4(5) . .
O6 W5 O25 103.5(7) . .
O6 W5 O29 101.7(7) . .
O25 W5 O29 88.2(6) . .
O6 W5 O27 97.4(6) . .
O25 W5 O27 91.6(6) . .
O29 W5 O27 160.4(7) . .
O6 W5 O21 98.2(7) . .
O25 W5 O21 158.3(6) . .
O29 W5 O21 87.1(6) . .
O27 W5 O21 85.9(5) . .
O6 W5 O26 164.4(6) . .
O25 W5 O26 88.2(5) . .
O29 W5 O26 88.8(6) . .
O27 W5 O26 71.6(4) . .
O21 W5 O26 70.5(5) . .
O16 W6 O38 98.9(7) . .
O16 W6 O5 101.7(7) . .
O38 W6 O5 91.3(6) . .
O16 W6 O36 100.2(7) . .
O38 W6 O36 90.2(6) . .
O5 W6 O36 157.6(7) . .
O16 W6 O9 101.3(7) . .
O38 W6 O9 159.7(7) . .
O5 W6 O9 85.6(5) . .
O36 W6 O9 85.3(6) . .
O16 W6 O12 166.8(6) . .
O38 W6 O12 71.6(5) . .
O5 W6 O12 88.1(6) . .
O36 W6 O12 71.2(6) . .
O9 W6 O12 88.2(5) . .
O33 W7 O32 102.3(7) . .
O33 W7 O31 100.2(7) . .
O32 W7 O31 88.3(6) . .
O33 W7 O10 103.3(6) . .
O32 W7 O10 87.2(5) . .
O31 W7 O10 156.5(6) . .
O33 W7 O34 99.0(7) . .
O32 W7 O34 158.7(6) . .
O31 W7 O34 88.1(6) . .
O10 W7 O34 87.8(5) . .
O33 W7 O17 165.3(6) . .
O32 W7 O17 88.2(5) . .
O31 W7 O17 69.5(6) . .
O10 W7 O17 87.3(5) . .
O34 W7 O17 70.9(5) . .
O1 W8 O32 103.5(7) . .
O1 W8 O35 102.8(6) . .
O32 W8 O35 86.9(5) . .
O1 W8 O18 96.3(6) . .
O32 W8 O18 160.2(6) . .
O35 W8 O18 88.7(6) . .
O1 W8 O15 99.4(6) . .
O32 W8 O15 89.2(6) . .
O35 W8 O15 157.8(6) . .
O18 W8 O15 87.6(5) . .
O1 W8 O13 164.4(5) . .
O32 W8 O13 89.2(5) . .
O35 W8 O13 86.7(5) . .
O18 W8 O13 71.3(5) . .
O15 W8 O13 71.4(5) . .
O2 W9 O5 104.0(6) . .
O2 W9 O14 104.2(6) . .
O5 W9 O14 87.9(5) . .
O2 W9 O40 97.0(6) . .
O5 W9 O40 88.7(6) . .
O14 W9 O40 158.7(6) . .
O2 W9 O27 97.1(6) . .
O5 W9 O27 158.8(6) . .
O14 W9 O27 88.9(5) . .
O40 W9 O27 86.6(5) . .
O2 W9 O26 164.1(5) . .
O5 W9 O26 87.3(6) . .
O14 W9 O26 87.1(5) . .
O40 W9 O26 71.8(5) . .
O27 W9 O26 71.5(5) . .
O3 W10 O35 104.5(6) . .
O3 W10 O10 102.1(6) . .
O35 W10 O10 87.0(5) . .
O3 W10 O36 98.3(7) . .
O35 W10 O36 157.0(7) . .
O10 W10 O36 85.6(6) . .
O3 W10 O37 96.8(6) . .
O35 W10 O37 90.5(6) . .
O10 W10 O37 161.0(6) . .
O36 W10 O37 89.5(6) . .
O3 W10 O12 163.9(5) . .
O35 W10 O12 88.2(5) . .
O10 W10 O12 88.3(5) . .
O36 W10 O12 69.9(6) . .
O37 W10 O12 72.8(5) . .
O8 W11 O14 102.0(6) . .
O8 W11 O9 102.4(6) . .
O14 W11 O9 88.9(5) . .
O8 W11 O34 98.2(6) . .
O14 W11 O34 159.7(6) . .
O9 W11 O34 89.0(5) . .
O8 W11 O22 98.5(6) . .
O14 W11 O22 85.7(6) . .
O9 W11 O22 159.1(6) . .
O34 W11 O22 89.2(5) . .
O8 W11 O17 165.1(5) . .
O14 W11 O17 88.4(5) . .
O9 W11 O17 88.3(5) . .
O34 W11 O17 71.3(5) . .
O22 W11 O17 71.4(5) . .
O11 W12 O4 101.7(7) . .
O11 W12 O15 95.2(6) . .
O4 W12 O15 91.2(6) . .
O11 W12 O29 102.5(7) . .
O4 W12 O29 89.5(6) . .
O15 W12 O29 161.7(7) . .
O11 W12 O28 98.8(6) . .
O4 W12 O28 159.5(6) . .
O15 W12 O28 86.2(6) . .
O29 W12 O28 86.8(6) . .
O11 W12 O13 162.5(5) . .
O4 W12 O13 90.9(6) . .
O15 W12 O13 72.1(5) . .
O29 W12 O13 89.6(6) . .
O28 W12 O13 69.0(5) . .
N2 Ag1 N1 72.7(5) . .
N2 Ag1 O29 164.2(5) . .
N1 Ag1 O29 121.2(6) . .
N2 Ag1 O21 121.6(5) . .
N1 Ag1 O21 105.6(5) . .
O29 Ag1 O21 64.7(5) . .
N3 Ag2 N4 72.6(5) . .
N3 Ag2 O10 131.6(6) . .
N4 Ag2 O10 114.8(5) . .
N3 Ag2 O36 164.1(5) . .
N4 Ag2 O36 108.7(6) . .
O10 Ag2 O36 63.0(5) . .
N5 Ag3 N7 120.9(7) . .
N5 Ag3 N6 72.0(7) . .
N7 Ag3 N6 144.6(7) . .
N5 Ag3 N8 165.1(7) . .
N7 Ag3 N8 72.9(8) . .
N6 Ag3 N8 100.0(7) . .
O17 V1 O26 110.9(6) . .
O17 V1 O13 111.0(6) . .
O26 V1 O13 109.6(6) . .
O17 V1 O12 109.0(5) . .
O26 V1 O12 108.1(6) . .
O13 V1 O12 108.2(6) . .
N11 Ag4 N10 114.8(8) . .
N11 Ag4 N12 71.6(7) . .
N10 Ag4 N12 151.3(8) . .
N11 Ag4 N9 173.2(8) . .
N10 Ag4 N9 70.5(8) . .
N12 Ag4 N9 105.8(8) . .
N16 Ag5 N14 152.1(8) . .
N16 Ag5 N13 117.2(10) . .
N14 Ag5 N13 70.8(7) . .
N16 Ag5 N15 72.4(9) . .
N14 Ag5 N15 102.7(7) . .
N13 Ag5 N15 169.6(8) . .
N20 Ag6 N17 125.5(7) . .
N20 Ag6 N18 160.6(7) . .
N17 Ag6 N18 72.2(7) . .
N20 Ag6 N19 72.4(7) . .
N17 Ag6 N19 141.0(7) . .
N18 Ag6 N19 98.9(7) . .
W12 O4 W2 147.6(8) . .
W9 O5 W6 150.4(8) . .
W1 O7 W4 148.2(7) . .
W11 O9 W6 146.9(7) . .
W10 O10 W7 147.0(7) . .
W10 O10 Ag2 101.6(5) . .
W7 O10 Ag2 107.4(6) . .
V1 O12 W6 123.1(6) . .
V1 O12 W10 121.4(6) . .
W6 O12 W10 94.6(4) . .
V1 O12 W1 122.3(6) . .
W6 O12 W1 94.3(4) . .
W10 O12 W1 93.4(4) . .
V1 O13 W4 124.2(6) . .
V1 O13 W8 122.0(6) . .
W4 O13 W8 95.2(4) . .
V1 O13 W12 119.2(6) . .
W4 O13 W12 95.7(4) . .
W8 O13 W12 93.3(4) . .
W11 O14 W9 146.8(7) . .
W12 O15 W8 123.1(7) . .
V1 O17 W7 123.9(6) . .
V1 O17 W11 122.2(6) . .
W7 O17 W11 94.7(5) . .
V1 O17 W2 122.1(7) . .
W7 O17 W2 93.3(4) . .
W11 O17 W2 92.5(4) . .
W8 O18 W4 121.0(7) . .
W1 O19 W3 142.6(8) . .
W3 O21 W5 123.3(7) . .
W3 O21 Ag1 106.4(6) . .
W5 O21 Ag1 96.4(6) . .
W2 O22 W11 124.2(7) . .
W3 O24 W4 147.0(8) . .
W5 O25 W2 150.5(7) . .
V1 O26 W3 123.4(6) . .
V1 O26 W9 122.8(6) . .
W3 O26 W9 93.1(4) . .
V1 O26 W5 121.9(6) . .
W3 O26 W5 94.3(4) . .
W9 O26 W5 93.2(4) . .
W5 O27 W9 123.6(6) . .
W4 O28 W12 124.2(7) . .
W5 O29 W12 143.2(7) . .
W5 O29 Ag1 102.8(6) . .
W12 O29 Ag1 109.4(6) . .
W2 O31 W7 128.4(9) . .
W8 O32 W7 148.7(7) . .
W11 O34 W7 123.1(7) . .
W10 O35 W8 149.9(7) . .
W6 O36 W10 124.1(9) . .
W6 O36 Ag2 108.8(7) . .
W10 O36 Ag2 99.5(6) . .
W10 O37 W1 121.3(8) . .
W6 O38 W1 124.3(9) . .
W3 O40 W9 123.0(7) . .
C1 N1 C5 120.0 . .
C1 N1 Ag1 125.1(9) . .
C5 N1 Ag1 114.7(9) . .
N1 C1 C2 120.0 . .
N1 C1 H1 120.0 . .
C2 C1 H1 120.0 . .
C1 C2 C3 120.0 . .
C1 C2 C11 116.5(17) . .
C3 C2 C11 123.4(17) . .
C4 C3 C2 120.0 . .
C4 C3 H3 120.0 . .
C2 C3 H3 120.0 . .
C3 C4 C5 120.0 . .
C3 C4 H4 120.0 . .
C5 C4 H4 120.0 . .
C4 C5 N1 120.0 . .
C4 C5 C6 121.4(13) . .
N1 C5 C6 118.5(13) . .
C2 C11 H11A 109.5 . .
C2 C11 H11B 109.5 . .
H11A C11 H11B 109.5 . .
C2 C11 H11C 109.5 . .
H11A C11 H11C 109.5 . .
H11B C11 H11C 109.5 . .
C6 N2 C10 120.0 . .
C6 N2 Ag1 117.4(9) . .
C10 N2 Ag1 122.6(9) . .
N2 C6 C7 120.0 . .
N2 C6 C5 115.9(13) . .
C7 C6 C5 123.8(13) . .
C8 C7 C6 120.0 . .
C8 C7 H7 120.0 . .
C6 C7 H7 120.0 . .
C7 C8 C9 120.0 . .
C7 C8 H8 120.0 . .
C9 C8 H8 120.0 . .
C10 C9 C8 120.0 . .
C10 C9 C12 115.1(17) . .
C8 C9 C12 124.5(17) . .
C9 C10 N2 120.0 . .
C9 C10 H10 120.0 . .
N2 C10 H10 120.0 . .
C9 C12 H12A 109.5 . .
C9 C12 H12B 109.5 . .
H12A C12 H12B 109.5 . .
C9 C12 H12C 109.5 . .
H12A C12 H12C 109.5 . .
H12B C12 H12C 109.5 . .
C13 N3 C17 120.0 . .
C13 N3 Ag2 122.8(10) . .
C17 N3 Ag2 117.2(10) . .
N3 C13 C14 120.0 . .
N3 C13 H13 120.0 . .
C14 C13 H13 120.0 . .
C13 C14 C15 120.0 . .
C13 C14 C23 116.4(17) . .
C15 C14 C23 122.6(17) . .
C16 C15 C14 120.0 . .
C16 C15 H15 120.0 . .
C14 C15 H15 120.0 . .
C15 C16 C17 120.0 . .
C15 C16 H16 120.0 . .
C17 C16 H16 120.0 . .
C16 C17 N3 120.0 . .
C16 C17 C18 119.8(13) . .
N3 C17 C18 120.2(13) . .
C14 C23 H23A 109.5 . .
C14 C23 H23B 109.5 . .
H23A C23 H23B 109.5 . .
C14 C23 H23C 109.5 . .
H23A C23 H23C 109.5 . .
H23B C23 H23C 109.5 . .
C18 N4 C22 120.0 . .
C18 N4 Ag2 116.1(8) . .
C22 N4 Ag2 122.7(8) . .
C19 C18 N4 120.0 . .
C19 C18 C17 128.2(12) . .
N4 C18 C17 111.6(12) . .
C20 C19 C18 120.0 . .
C20 C19 H19 120.0 . .
C18 C19 H19 120.0 . .
C21 C20 C19 120.0 . .
C21 C20 H20 120.0 . .
C19 C20 H20 120.0 . .
C22 C21 C20 120.0 . .
C22 C21 C24 119.6(9) . .
C20 C21 C24 120.3(9) . .
C21 C22 N4 120.0 . .
C21 C22 H22 120.0 . .
N4 C22 H22 120.0 . .
C21 C24 H24A 109.5 . .
C21 C24 H24B 109.5 . .
H24A C24 H24B 109.5 . .
C21 C24 H24C 109.5 . .
H24A C24 H24C 109.5 . .
H24B C24 H24C 109.5 . .
N5 C25 C26 122(2) . .
N5 C25 H25 119.0 . .
C26 C25 H25 119.0 . .
C25 C26 C27 120(2) . .
C25 C26 C36 122(2) . .
C27 C26 C36 118(2) . .
C26 C27 C28 117(2) . .
C26 C27 H27 121.7 . .
C28 C27 H27 121.7 . .
C29 C28 C27 120(2) . .
C29 C28 H28 120.2 . .
C27 C28 H28 120.2 . .
N5 C29 C28 123(2) . .
N5 C29 C30 118.5(19) . .
C28 C29 C30 118(2) . .
N6 C30 C31 118(2) . .
N6 C30 C29 118(2) . .
C31 C30 C29 123.9(19) . .
C32 C31 C30 122(2) . .
C32 C31 H31 119.1 . .
C30 C31 H31 119.1 . .
C31 C32 C33 120(2) . .
C31 C32 H32 119.8 . .
C33 C32 H32 119.8 . .
C34 C33 C32 114(2) . .
C34 C33 C35 125(2) . .
C32 C33 C35 121(2) . .
N6 C34 C33 125(2) . .
N6 C34 H34 117.3 . .
C33 C34 H34 117.3 . .
C33 C35 H35A 109.5 . .
C33 C35 H35B 109.5 . .
H35A C35 H35B 109.5 . .
C33 C35 H35C 109.5 . .
H35A C35 H35C 109.5 . .
H35B C35 H35C 109.5 . .
C26 C36 H36A 109.5 . .
C26 C36 H36B 109.5 . .
H36A C36 H36B 109.5 . .
C26 C36 H36C 109.5 . .
H36A C36 H36C 109.5 . .
H36B C36 H36C 109.5 . .
N7 C37 C38 124(3) . .
N7 C37 H37 118.1 . .
C38 C37 H37 118.1 . .
C37 C38 C39 115(3) . .
C37 C38 C48 117(3) . .
C39 C38 C48 127(3) . .
C40 C39 C38 121(3) . .
C40 C39 H39 119.5 . .
C38 C39 H39 119.5 . .
C39 C40 C41 126(3) . .
C39 C40 H40 116.9 . .
C41 C40 H40 116.9 . .
C40 C41 N7 115(3) . .
C40 C41 C42 126(2) . .
N7 C41 C42 119(2) . .
N8 C42 C41 120(2) . .
N8 C42 C43 116(3) . .
C41 C42 C43 124(2) . .
C44 C43 C42 120(2) . .
C44 C43 H43 120.0 . .
C42 C43 H43 120.0 . .
C43 C44 C45 125(3) . .
C43 C44 H44 117.6 . .
C45 C44 H44 117.6 . .
C46 C45 C44 112(3) . .
C46 C45 C47 125(2) . .
C44 C45 C47 124(2) . .
N8 C46 C45 126(2) . .
N8 C46 H46 116.9 . .
C45 C46 H46 116.9 . .
C45 C47 H47A 109.5 . .
C45 C47 H47B 109.5 . .
H47A C47 H47B 109.5 . .
C45 C47 H47C 109.5 . .
H47A C47 H47C 109.5 . .
H47B C47 H47C 109.5 . .
C38 C48 H48A 109.5 . .
C38 C48 H48B 109.5 . .
H48A C48 H48B 109.5 . .
C38 C48 H48C 109.5 . .
H48A C48 H48C 109.5 . .
H48B C48 H48C 109.5 . .
C50 C49 N9 124(3) . .
C50 C49 H49 118.2 . .
N9 C49 H49 118.2 . .
C51 C50 C49 114(3) . .
C51 C50 C60 126(3) . .
C49 C50 C60 120(3) . .
C50 C51 C52 127(3) . .
C50 C51 H51 116.5 . .
C52 C51 H51 116.5 . .
C51 C52 C53 116(3) . .
C51 C52 H52 122.0 . .
C53 C52 H52 122.0 . .
N9 C53 C52 122(3) . .
N9 C53 C54 119(3) . .
C52 C53 C54 118(3) . .
N10 C54 C53 120(3) . .
N10 C54 C55 113(3) . .
C53 C54 C55 126(3) . .
C56 C55 C54 120(3) . .
C56 C55 H55 120.2 . .
C54 C55 H55 120.2 . .
C57 C56 C55 125(3) . .
C57 C56 H56 117.5 . .
C55 C56 H56 117.5 . .
C56 C57 C58 115(3) . .
C56 C57 C59 125(3) . .
C58 C57 C59 119(3) . .
N10 C58 C57 124(3) . .
N10 C58 H58 118.0 . .
C57 C58 H58 118.0 . .
C57 C59 H59A 109.5 . .
C57 C59 H59B 109.5 . .
H59A C59 H59B 109.5 . .
C57 C59 H59C 109.5 . .
H59A C59 H59C 109.5 . .
H59B C59 H59C 109.5 . .
C50 C60 H60A 109.5 . .
C50 C60 H60B 109.5 . .
H60A C60 H60B 109.5 . .
C50 C60 H60C 109.5 . .
H60A C60 H60C 109.5 . .
H60B C60 H60C 109.5 . .
N11 C61 C62 128(2) . .
N11 C61 H61 115.8 . .
C62 C61 H61 115.8 . .
C63 C62 C72 124(2) . .
C63 C62 C61 112(2) . .
C72 C62 C61 123.5(19) . .
C62 C63 C64 121(2) . .
C62 C63 H63 119.7 . .
C64 C63 H63 119.7 . .
C65 C64 C63 117(2) . .
C65 C64 H64 121.4 . .
C63 C64 H64 121.4 . .
N11 C65 C64 121(2) . .
N11 C65 C66 119(2) . .
C64 C65 C66 119.9(19) . .
N12 C66 C67 119(2) . .
N12 C66 C65 119.0(19) . .
C67 C66 C65 122(2) . .
C68 C67 C66 122(2) . .
C68 C67 H67 118.8 . .
C66 C67 H67 118.8 . .
C67 C68 C69 118(2) . .
C67 C68 H68 120.8 . .
C69 C68 H68 120.8 . .
C68 C69 C70 113(2) . .
C68 C69 C71 123(2) . .
C70 C69 C71 125(2) . .
N12 C70 C69 127(2) . .
N12 C70 H70 116.6 . .
C69 C70 H70 116.6 . .
C69 C71 H71A 109.5 . .
C69 C71 H71B 109.5 . .
H71A C71 H71B 109.5 . .
C69 C71 H71C 109.5 . .
H71A C71 H71C 109.5 . .
H71B C71 H71C 109.5 . .
C62 C72 H72A 109.5 . .
C62 C72 H72B 109.5 . .
H72A C72 H72B 109.5 . .
C62 C72 H72C 109.5 . .
H72A C72 H72C 109.5 . .
H72B C72 H72C 109.5 . .
C74 C73 N13 127(2) . .
C74 C73 H73 116.7 . .
N13 C73 H73 116.7 . .
C73 C74 C75 118(3) . .
C73 C74 C84 123(2) . .
C75 C74 C84 119(2) . .
C74 C75 C76 118(2) . .
C74 C75 H75 121.1 . .
C76 C75 H75 121.1 . .
C77 C76 C75 122(2) . .
C77 C76 H76 119.0 . .
C75 C76 H76 119.0 . .
C76 C77 N13 119(3) . .
C76 C77 C78 124(2) . .
N13 C77 C78 116(2) . .
C78 N14 C82 120.0 . .
C78 N14 Ag5 117.0(9) . .
C82 N14 Ag5 122.0(9) . .
C79 C78 N14 120.0 . .
C79 C78 C77 122.9(14) . .
N14 C78 C77 117.0(14) . .
C78 C79 C80 120.0 . .
C78 C79 H79 120.0 . .
C80 C79 H79 120.0 . .
C79 C80 C81 120.0 . .
C79 C80 H80 120.0 . .
C81 C80 H80 120.0 . .
C82 C81 C80 120.0 . .
C82 C81 C83 119.0(15) . .
C80 C81 C83 120.9(15) . .
C81 C82 N14 120.0 . .
C81 C82 H82 120.0 . .
N14 C82 H82 120.0 . .
C81 C83 H83A 109.5 . .
C81 C83 H83B 109.5 . .
H83A C83 H83B 109.5 . .
C81 C83 H83C 109.5 . .
H83A C83 H83C 109.5 . .
H83B C83 H83C 109.5 . .
C74 C84 H84A 109.5 . .
C74 C84 H84B 109.5 . .
H84A C84 H84B 109.5 . .
C74 C84 H84C 109.5 . .
H84A C84 H84C 109.5 . .
H84B C84 H84C 109.5 . .
C85 N15 C89 120.0 . .
C85 N15 Ag5 123.0(11) . .
C89 N15 Ag5 115.7(10) . .
N15 C85 C86 120.0 . .
N15 C85 H85 120.0 . .
C86 C85 H85 120.0 . .
C87 C86 C85 120.0 . .
C87 C86 C96 124.9(18) . .
C85 C86 C96 114.4(18) . .
C86 C87 C88 120.0 . .
C86 C87 H87 120.0 . .
C88 C87 H87 120.0 . .
C87 C88 C89 120.0 . .
C87 C88 H88 120.0 . .
C89 C88 H88 120.0 . .
C88 C89 N15 120.0 . .
C88 C89 C90 125.0(17) . .
N15 C89 C90 115.0(17) . .
C91 C90 N16 120(4) . .
C91 C90 C89 119(3) . .
N16 C90 C89 121(3) . .
C90 C91 C92 120(3) . .
C90 C91 H91 119.9 . .
C92 C91 H91 119.9 . .
C91 C92 C93 120(3) . .
C91 C92 H92 120.1 . .
C93 C92 H92 120.1 . .
C94 C93 C92 116(3) . .
C94 C93 C95 121(3) . .
C92 C93 C95 123(3) . .
C93 C94 N16 127(3) . .
C93 C94 H94 116.6 . .
N16 C94 H94 116.6 . .
C93 C95 H95A 109.5 . .
C93 C95 H95B 109.5 . .
H95A C95 H95B 109.5 . .
C93 C95 H95C 109.5 . .
H95A C95 H95C 109.5 . .
H95B C95 H95C 109.5 . .
C86 C96 H96A 109.5 . .
C86 C96 H96B 109.5 . .
H96A C96 H96B 109.5 . .
C86 C96 H96C 109.5 . .
H96A C96 H96C 109.5 . .
H96B C96 H96C 109.5 . .
N17 C97 C98 120(2) . .
N17 C97 H97 120.0 . .
C98 C97 H97 120.0 . .
C99 C98 C97 119(3) . .
C99 C98 C108 115(2) . .
C97 C98 C108 126(2) . .
C98 C99 C100 120(2) . .
C98 C99 H99 120.0 . .
C100 C99 H99 120.0 . .
C101 C100 C99 117(2) . .
C101 C100 H100 121.7 . .
C99 C100 H100 121.7 . .
N17 C101 C100 121(2) . .
N17 C101 C102 120(2) . .
C100 C101 C102 120(2) . .
N18 C102 C103 126(3) . .
N18 C102 C101 115(2) . .
C103 C102 C101 119(2) . .
C102 C103 C104 114(2) . .
C102 C103 H103 122.8 . .
C104 C103 H103 122.8 . .
C105 C104 C103 123(2) . .
C105 C104 H104 118.3 . .
C103 C104 H104 118.3 . .
C104 C105 C106 118(2) . .
C104 C105 C107 123(2) . .
C106 C105 C107 119(2) . .
N18 C106 C105 120(2) . .
N18 C106 H106 119.9 . .
C105 C106 H106 119.9 . .
C105 C107 H10A 109.5 . .
C105 C107 H10B 109.5 . .
H10A C107 H10B 109.5 . .
C105 C107 H10C 109.5 . .
H10A C107 H10C 109.5 . .
H10B C107 H10C 109.5 . .
C98 C108 H10D 109.5 . .
C98 C108 H10E 109.5 . .
H10D C108 H10E 109.5 . .
C98 C108 H10F 109.5 . .
H10D C108 H10F 109.5 . .
H10E C108 H10F 109.5 . .
N19 C109 C110 129(2) . .
N19 C109 H109 115.5 . .
C110 C109 H109 115.5 . .
C111 C110 C109 113(2) . .
C111 C110 C120 125(2) . .
C109 C110 C120 121(2) . .
C110 C111 C112 122(2) . .
C110 C111 H111 119.0 . .
C112 C111 H111 119.0 . .
C111 C112 C113 119(2) . .
C111 C112 H112 120.3 . .
C113 C112 H112 120.3 . .
N19 C113 C112 121(2) . .
N19 C113 C114 118(2) . .
C112 C113 C114 121(2) . .
C115 C114 N20 118(2) . .
C115 C114 C113 125(2) . .
N20 C114 C113 116.6(18) . .
C116 C115 C114 124(2) . .
C116 C115 H115 118.2 . .
C114 C115 H115 118.2 . .
C115 C116 C117 121(2) . .
C115 C116 H116 119.5 . .
C117 C116 H116 119.5 . .
C116 C117 C118 115(2) . .
C116 C117 C119 125(2) . .
C118 C117 C119 120(2) . .
N20 C118 C117 124(2) . .
N20 C118 H118 118.0 . .
C117 C118 H118 118.0 . .
C117 C119 H11D 109.5 . .
C117 C119 H11E 109.5 . .
H11D C119 H11E 109.5 . .
C117 C119 H11F 109.5 . .
H11D C119 H11F 109.5 . .
H11E C119 H11F 109.5 . .
C110 C120 H12D 109.5 . .
C110 C120 H12E 109.5 . .
H12D C120 H12E 109.5 . .
C110 C120 H12F 109.5 . .
H12D C120 H12F 109.5 . .
H12E C120 H12F 109.5 . .
C29 N5 C25 118.2(19) . .
C29 N5 Ag3 116.4(15) . .
C25 N5 Ag3 124.8(15) . .
C30 N6 C34 120(2) . .
C30 N6 Ag3 114.4(16) . .
C34 N6 Ag3 124.5(17) . .
C37 N7 C41 118(2) . .
C37 N7 Ag3 125.2(18) . .
C41 N7 Ag3 114.9(17) . .
C46 N8 C42 120(2) . .
C46 N8 Ag3 127.0(16) . .
C42 N8 Ag3 111.1(18) . .
C53 N9 C49 117(2) . .
C53 N9 Ag4 113.2(19) . .
C49 N9 Ag4 127.4(18) . .
C58 N10 C54 120(3) . .
C58 N10 Ag4 123(2) . .
C54 N10 Ag4 114(2) . .
C61 N11 C65 120(2) . .
C61 N11 Ag4 125.9(15) . .
C65 N11 Ag4 113.6(16) . .
C66 N12 C70 120(2) . .
C66 N12 Ag4 115.7(16) . .
C70 N12 Ag4 123.0(16) . .
C77 N13 C73 116(2) . .
C77 N13 Ag5 119(2) . .
C73 N13 Ag5 125.7(14) . .
C94 N16 C90 117(3) . .
C94 N16 Ag5 128(2) . .
C90 N16 Ag5 114(2) . .
C101 N17 C97 123(2) . .
C101 N17 Ag6 114.1(16) . .
C97 N17 Ag6 123.3(17) . .
C102 N18 C106 118(2) . .
C102 N18 Ag6 115.6(17) . .
C106 N18 Ag6 121.8(15) . .
C113 N19 C109 116(2) . .
C113 N19 Ag6 113.7(16) . .
C109 N19 Ag6 127.6(16) . .
C118 N20 C114 118(2) . .
C118 N20 Ag6 124.0(16) . .
C114 N20 Ag6 116.4(15) . .
loop_
_geom_bond_atom_site_label_1
_geom_bond_atom_site_label_2
_geom_bond_distance
_geom_bond_site_symmetry_2
W1 O39 1.645(13) .
W1 O7 1.818(15) .
W1 O19 1.899(13) .
W1 O38 1.945(14) .
W1 O37 1.964(14) .
W1 O12 2.336(11) .
W2 O30 1.705(13) .
W2 O22 1.874(14) .
W2 O25 1.876(12) .
W2 O31 1.883(14) .
W2 O4 1.883(14) .
W2 O17 2.363(11) .
W3 O23 1.681(13) .
W3 O24 1.867(13) .
W3 O19 1.913(14) .
W3 O21 1.918(14) .
W3 O40 1.928(14) .
W3 O26 2.330(12) .
W4 O20 1.685(13) .
W4 O28 1.913(14) .
W4 O24 1.921(13) .
W4 O7 1.927(13) .
W4 O18 1.959(13) .
W4 O13 2.262(11) .
W5 O6 1.696(14) .
W5 O25 1.857(12) .
W5 O29 1.895(13) .
W5 O27 1.924(14) .
W5 O21 1.977(14) .
W5 O26 2.347(11) .
W6 O16 1.671(14) .
W6 O38 1.894(15) .
W6 O5 1.899(12) .
W6 O36 1.914(14) .
W6 O9 1.919(13) .
W6 O12 2.292(12) .
W7 O33 1.658(13) .
W7 O32 1.895(13) .
W7 O31 1.896(14) .
W7 O10 1.923(13) .
W7 O34 1.963(13) .
W7 O17 2.315(11) .
W8 O1 1.663(14) .
W8 O32 1.849(13) .
W8 O35 1.901(12) .
W8 O18 1.936(14) .
W8 O15 1.956(12) .
W8 O13 2.327(10) .
W9 O2 1.693(10) .
W9 O5 1.832(13) .
W9 O14 1.893(11) .
W9 O40 1.933(14) .
W9 O27 1.939(13) .
W9 O26 2.341(10) .
W10 O3 1.711(11) .
W10 O35 1.852(13) .
W10 O10 1.881(13) .
W10 O36 1.936(14) .
W10 O37 1.936(14) .
W10 O12 2.335(11) .
W11 O8 1.677(12) .
W11 O14 1.863(11) .
W11 O9 1.872(12) .
W11 O34 1.920(13) .
W11 O22 1.958(13) .
W11 O17 2.325(11) .
W12 O11 1.681(13) .
W12 O4 1.868(13) .
W12 O15 1.899(13) .
W12 O29 1.918(13) .
W12 O28 1.944(15) .
W12 O13 2.336(11) .
Ag1 N2 2.295(11) .
Ag1 N1 2.334(11) .
Ag1 O29 2.434(13) .
Ag1 O21 2.554(13) .
Ag2 N3 2.223(11) .
Ag2 N4 2.369(12) .
Ag2 O10 2.476(11) .
Ag2 O36 2.488(15) .
Ag3 N5 2.320(17) .
Ag3 N7 2.32(2) .
Ag3 N6 2.38(2) .
Ag3 N8 2.43(2) .
V1 O17 1.641(13) .
V1 O26 1.643(11) .
V1 O13 1.681(11) .
V1 O12 1.686(13) .
Ag4 N11 2.34(2) .
Ag4 N10 2.34(2) .
Ag4 N12 2.383(19) .
Ag4 N9 2.46(2) .
Ag5 N16 2.31(2) .
Ag5 N14 2.313(12) .
Ag5 N13 2.34(2) .
Ag5 N15 2.402(15) .
Ag6 N20 2.258(17) .
Ag6 N17 2.34(2) .
Ag6 N18 2.350(19) .
Ag6 N19 2.41(2) .
N1 C1 1.3900 .
N1 C5 1.3900 .
C1 C2 1.3900 .
C1 H1 0.9300 .
C2 C3 1.3900 .
C2 C11 1.500(9) .
C3 C4 1.3900 .
C3 H3 0.9300 .
C4 C5 1.3900 .
C4 H4 0.9300 .
C5 C6 1.472(9) .
C11 H11A 0.9600 .
C11 H11B 0.9600 .
C11 H11C 0.9600 .
N2 C6 1.3900 .
N2 C10 1.3900 .
C6 C7 1.3900 .
C7 C8 1.3900 .
C7 H7 0.9300 .
C8 C9 1.3900 .
C8 H8 0.9300 .
C9 C10 1.3900 .
C9 C12 1.498(9) .
C10 H10 0.9300 .
C12 H12A 0.9600 .
C12 H12B 0.9600 .
C12 H12C 0.9600 .
N3 C13 1.3900 .
N3 C17 1.3900 .
C13 C14 1.3900 .
C13 H13 0.9300 .
C14 C15 1.3900 .
C14 C23 1.47(3) .
C15 C16 1.3900 .
C15 H15 0.9300 .
C16 C17 1.3900 .
C16 H16 0.9300 .
C17 C18 1.501(9) .
C23 H23A 0.9600 .
C23 H23B 0.9600 .
C23 H23C 0.9600 .
N4 C18 1.3900 .
N4 C22 1.3900 .
C18 C19 1.3900 .
C19 C20 1.3900 .
C19 H19 0.9300 .
C20 C21 1.3900 .
C20 H20 0.9300 .
C21 C22 1.3900 .
C21 C24 1.499(9) .
C22 H22 0.9300 .
C24 H24A 0.9600 .
C24 H24B 0.9600 .
C24 H24C 0.9600 .
C25 N5 1.35(3) .
C25 C26 1.37(3) .
C25 H25 0.9300 .
C26 C27 1.39(3) .
C26 C36 1.58(3) .
C27 C28 1.40(3) .
C27 H27 0.9300 .
C28 C29 1.37(3) .
C28 H28 0.9300 .
C29 N5 1.32(3) .
C29 C30 1.51(3) .
C30 N6 1.33(3) .
C30 C31 1.38(3) .
C31 C32 1.36(3) .
C31 H31 0.9300 .
C32 C33 1.41(3) .
C32 H32 0.9300 .
C33 C34 1.38(3) .
C33 C35 1.48(3) .
C34 N6 1.33(3) .
C34 H34 0.9300 .
C35 H35A 0.9600 .
C35 H35B 0.9600 .
C35 H35C 0.9600 .
C36 H36A 0.9600 .
C36 H36B 0.9600 .
C36 H36C 0.9600 .
C37 N7 1.28(3) .
C37 C38 1.37(3) .
C37 H37 0.9300 .
C38 C39 1.40(4) .
C38 C48 1.47(4) .
C39 C40 1.18(3) .
C39 H39 0.9300 .
C40 C41 1.38(3) .
C40 H40 0.9300 .
C41 N7 1.39(3) .
C41 C42 1.46(4) .
C42 N8 1.36(3) .
C42 C43 1.47(4) .
C43 C44 1.28(4) .
C43 H43 0.9300 .
C44 C45 1.41(3) .
C44 H44 0.9300 .
C45 C46 1.41(3) .
C45 C47 1.48(3) .
C46 N8 1.32(3) .
C46 H46 0.9300 .
C47 H47A 0.9600 .
C47 H47B 0.9600 .
C47 H47C 0.9600 .
C48 H48A 0.9600 .
C48 H48B 0.9600 .
C48 H48C 0.9600 .
C49 C50 1.36(3) .
C49 N9 1.39(3) .
C49 H49 0.9300 .
C50 C51 1.30(4) .
C50 C60 1.54(4) .
C51 C52 1.34(4) .
C51 H51 0.9300 .
C52 C53 1.37(3) .
C52 H52 0.9300 .
C53 N9 1.28(3) .
C53 C54 1.44(4) .
C54 N10 1.37(3) .
C54 C55 1.45(4) .
C55 C56 1.36(4) .
C55 H55 0.9300 .
C56 C57 1.25(4) .
C56 H56 0.9300 .
C57 C58 1.43(4) .
C57 C59 1.44(3) .
C58 N10 1.29(4) .
C58 H58 0.9300 .
C59 H59A 0.9600 .
C59 H59B 0.9600 .
C59 H59C 0.9600 .
C60 H60A 0.9600 .
C60 H60B 0.9600 .
C60 H60C 0.9600 .
C61 N11 1.22(3) .
C61 C62 1.45(3) .
C61 H61 0.9300 .
C62 C63 1.41(3) .
C62 C72 1.44(3) .
C63 C64 1.46(3) .
C63 H63 0.9300 .
C64 C65 1.38(3) .
C64 H64 0.9300 .
C65 N11 1.37(2) .
C65 C66 1.48(3) .
C66 N12 1.26(3) .
C66 C67 1.35(3) .
C67 C68 1.35(3) .
C67 H67 0.9300 .
C68 C69 1.37(3) .
C68 H68 0.9300 .
C69 C70 1.38(3) .
C69 C71 1.46(3) .
C70 N12 1.27(3) .
C70 H70 0.9300 .
C71 H71A 0.9600 .
C71 H71B 0.9600 .
C71 H71C 0.9600 .
C72 H72A 0.9600 .
C72 H72B 0.9600 .
C72 H72C 0.9600 .
C73 C74 1.25(3) .
C73 N13 1.41(4) .
C73 H73 0.9300 .
C74 C75 1.36(3) .
C74 C84 1.497(10) .
C75 C76 1.41(4) .
C75 H75 0.9300 .
C76 C77 1.32(4) .
C76 H76 0.9300 .
C77 N13 1.35(3) .
C77 C78 1.47(3) .
N14 C78 1.3900 .
N14 C82 1.3900 .
C78 C79 1.3900 .
C79 C80 1.3900 .
C79 H79 0.9300 .
C80 C81 1.3900 .
C80 H80 0.9300 .
C81 C82 1.3900 .
C81 C83 1.504(9) .
C82 H82 0.9300 .
C83 H83A 0.9600 .
C83 H83B 0.9600 .
C83 H83C 0.9600 .
C84 H84A 0.9600 .
C84 H84B 0.9600 .
C84 H84C 0.9600 .
N15 C85 1.3900 .
N15 C89 1.3900 .
C85 C86 1.3900 .
C85 H85 0.9300 .
C86 C87 1.3900 .
C86 C96 1.499(9) .
C87 C88 1.3900 .
C87 H87 0.9300 .
C88 C89 1.3900 .
C88 H88 0.9300 .
C89 C90 1.47(4) .
C90 C91 1.29(4) .
C90 N16 1.43(4) .
C91 C92 1.39(4) .
C91 H91 0.9300 .
C92 C93 1.44(4) .
C92 H92 0.9300 .
C93 C94 1.27(4) .
C93 C95 1.500(10) .
C94 N16 1.34(4) .
C94 H94 0.9300 .
C95 H95A 0.9600 .
C95 H95B 0.9600 .
C95 H95C 0.9600 .
C96 H96A 0.9600 .
C96 H96B 0.9600 .
C96 H96C 0.9600 .
C97 N17 1.35(3) .
C97 C98 1.39(3) .
C97 H97 0.9300 .
C98 C99 1.33(3) .
C98 C108 1.54(3) .
C99 C100 1.49(3) .
C99 H99 0.9300 .
C100 C101 1.37(3) .
C100 H100 0.9300 .
C101 N17 1.34(3) .
C101 C102 1.51(4) .
C102 N18 1.31(3) .
C102 C103 1.35(3) .
C103 C104 1.38(3) .
C103 H103 0.9300 .
C104 C105 1.34(3) .
C104 H104 0.9300 .
C105 C106 1.39(3) .
C105 C107 1.48(3) .
C106 N18 1.35(3) .
C106 H106 0.9300 .
C107 H10A 0.9600 .
C107 H10B 0.9600 .
C107 H10C 0.9600 .
C108 H10D 0.9600 .
C108 H10E 0.9600 .
C108 H10F 0.9600 .
C109 N19 1.34(3) .
C109 C110 1.35(3) .
C109 H109 0.9300 .
C110 C111 1.33(3) .
C110 C120 1.47(3) .
C111 C112 1.36(3) .
C111 H111 0.9300 .
C112 C113 1.39(3) .
C112 H112 0.9300 .
C113 N19 1.29(3) .
C113 C114 1.49(3) .
C114 C115 1.37(3) .
C114 N20 1.40(3) .
C115 C116 1.27(3) .
C115 H115 0.9300 .
C116 C117 1.39(3) .
C116 H116 0.9300 .
C117 C118 1.42(3) .
C117 C119 1.45(3) .
C118 N20 1.28(3) .
C118 H118 0.9300 .
C119 H11D 0.9600 .
C119 H11E 0.9600 .
C119 H11F 0.9600 .
C120 H12D 0.9600 .
C120 H12E 0.9600 .
C120 H12F 0.9600 .
