#------------------------------------------------------------------------------
#$Date: 2021-02-26 11:54:15 +0200 (Fri, 26 Feb 2021) $
#$Revision: 262257 $
#$URL: file:///home/coder/svn-repositories/cod/cif/1/56/06/1560669.cif $
#------------------------------------------------------------------------------
#
# This file is available in the Crystallography Open Database (COD),
# http://www.crystallography.net/
#
# All data on this site have been placed in the public domain by the
# contributors.
#
data_1560669
loop_
_publ_author_name
'Zhao, Hui'
'Sun, Xiao-Xia'
'Hu, Huai-Ming'
'An, Ran'
'Yang, Meng-Lin'
'Xue, Ganglin'
_publ_section_title
;
 Syntheses, structures and luminescent properties of lanthanide
 coordination polymers assembled from imidazophenanthroline derivative and
 oxalate ligands
;
_journal_name_full               'Journal of Solid State Chemistry'
_journal_page_first              67
_journal_page_last               73
_journal_paper_doi               10.1016/j.jssc.2016.09.033
_journal_volume                  245
_journal_year                    2017
_chemical_formula_moiety         'C40 H20 N8 O18 S4 Eu2, 4(O)'
_chemical_formula_sum            'C40 H24 Eu2 N8 O22 S4'
_chemical_formula_weight         1400.83
_space_group_IT_number           2
_space_group_name_Hall           '-P 1'
_space_group_name_H-M_alt        'P -1'
_symmetry_cell_setting           triclinic
_symmetry_space_group_name_Hall  '-P 1'
_symmetry_space_group_name_H-M   'P -1'
_atom_sites_solution_hydrogens   geom
_atom_sites_solution_primary     direct
_atom_sites_solution_secondary   difmap
_cell_angle_alpha                98.488(3)
_cell_angle_beta                 91.272(3)
_cell_angle_gamma                115.376(3)
_cell_formula_units_Z            1
_cell_length_a                   9.9470(18)
_cell_length_b                   10.8985(19)
_cell_length_c                   12.115(2)
_cell_measurement_reflns_used    1485
_cell_measurement_temperature    296(2)
_cell_measurement_theta_max      21.02
_cell_measurement_theta_min      2.13
_cell_volume                     1168.3(4)
_computing_cell_refinement       'Bruker SAINT'
_computing_data_collection       'Bruker APEX2'
_computing_data_reduction        'Bruker SAINT'
_computing_molecular_graphics    'Bruker SHELXTL'
_computing_publication_material  'Bruker SHELXTL'
_computing_structure_refinement  'SHELXL-97 (Sheldrick, 1997)'
_computing_structure_solution    'SHELXS-97 (Sheldrick, 1990)'
_diffrn_ambient_temperature      296(2)
_diffrn_measured_fraction_theta_full 0.980
_diffrn_measured_fraction_theta_max 0.980
_diffrn_measurement_device_type  'Bruker APEX-II CCD'
_diffrn_measurement_method       'φ and ω scans'
_diffrn_radiation_monochromator  graphite
_diffrn_radiation_source         'fine-focus sealed tube'
_diffrn_radiation_type           MoK\a
_diffrn_radiation_wavelength     0.71073
_diffrn_reflns_av_R_equivalents  0.0323
_diffrn_reflns_av_sigmaI/netI    0.0724
_diffrn_reflns_limit_h_max       11
_diffrn_reflns_limit_h_min       -10
_diffrn_reflns_limit_k_max       6
_diffrn_reflns_limit_k_min       -12
_diffrn_reflns_limit_l_max       14
_diffrn_reflns_limit_l_min       -14
_diffrn_reflns_number            5815
_diffrn_reflns_theta_full        25.05
_diffrn_reflns_theta_max         25.05
_diffrn_reflns_theta_min         2.28
_exptl_absorpt_coefficient_mu    2.934
_exptl_absorpt_correction_T_max  0.675
_exptl_absorpt_correction_T_min  0.601
_exptl_absorpt_correction_type   multi-scan
_exptl_absorpt_process_details   sadabs
_exptl_crystal_colour            yellow
_exptl_crystal_density_diffrn    1.991
_exptl_crystal_density_method    'not measured'
_exptl_crystal_description       block
_exptl_crystal_F_000             686
_exptl_crystal_size_max          0.17
_exptl_crystal_size_mid          0.15
_exptl_crystal_size_min          0.13
_refine_diff_density_max         1.367
_refine_diff_density_min         -0.661
_refine_diff_density_rms         0.142
_refine_ls_extinction_method     none
_refine_ls_goodness_of_fit_ref   1.022
_refine_ls_hydrogen_treatment    mixed
_refine_ls_matrix_type           full
_refine_ls_number_parameters     349
_refine_ls_number_reflns         4048
_refine_ls_number_restraints     2
_refine_ls_restrained_S_all      1.021
_refine_ls_R_factor_all          0.0548
_refine_ls_R_factor_gt           0.0418
_refine_ls_shift/su_max          0.001
_refine_ls_shift/su_mean         0.000
_refine_ls_structure_factor_coef Fsqd
_refine_ls_weighting_details
'calc w=1/[σ²(Fo²)+(0.0349P)²+0.0000P] where P=(Fo²+2Fc²)/3'
_refine_ls_weighting_scheme      calc
_refine_ls_wR_factor_gt          0.0817
_refine_ls_wR_factor_ref         0.0876
_reflns_number_gt                3365
_reflns_number_total             4048
_reflns_threshold_expression     >2sigma(I)
_cod_data_source_file            JSSC-2017-245-67.cif
_cod_data_source_block           nw1979
_cod_depositor_comments
;
The following automatic conversions were performed:

data item '_symmetry_cell_setting' value 'Triclinic' was changed to
'triclinic' in accordance with the built-in table derived from the
CIF Core dictionary named 'cif_core.dic' version 2.4.5 last updated
on 2014-11-21.

Automatic conversion script
Id: cif_fix_values 8369 2020-08-20 11:38:08Z andrius 
;
_cod_original_cell_volume        1168.2(4)
_cod_original_sg_symbol_H-M      P-1
_cod_database_code               1560669
loop_
_symmetry_equiv_pos_as_xyz
'x, y, z'
'-x, -y, -z'
loop_
_atom_site_label
_atom_site_type_symbol
_atom_site_fract_x
_atom_site_fract_y
_atom_site_fract_z
_atom_site_U_iso_or_equiv
_atom_site_adp_type
_atom_site_occupancy
_atom_site_symmetry_multiplicity
_atom_site_calc_flag
_atom_site_refinement_flags
_atom_site_disorder_assembly
_atom_site_disorder_group
Eu1 Eu 0.54526(4) 0.74546(3) 0.39683(3) 0.01989(11) Uani 1 1 d . . .
S1 S 0.77881(18) 0.23085(15) -0.26925(13) 0.0231(4) Uani 1 1 d . . .
S2 S 1.24878(17) 0.43490(15) -0.50702(12) 0.0201(3) Uani 1 1 d . . .
N1 N 0.5240(6) 0.5644(5) 0.2264(4) 0.0242(12) Uani 1 1 d . . .
N2 N 0.7447(6) 0.8277(5) 0.2592(4) 0.0258(13) Uani 1 1 d . . .
N3 N 0.9647(6) 0.6785(5) -0.0673(4) 0.0254(12) Uani 1 1 d . . .
N4 N 0.8077(6) 0.4586(5) -0.0711(4) 0.0290(13) Uani 1 1 d . . .
H4 H 0.7651 0.3705 -0.0914 0.035 Uiso 1 1 calc R . .
O1 O 0.6550(4) 0.2687(4) -0.2793(3) 0.0255(10) Uani 1 1 d . . .
O2 O 0.7976(5) 0.2057(4) -0.1573(4) 0.0322(11) Uani 1 1 d . . .
O3 O 0.7685(5) 0.1228(4) -0.3576(4) 0.0326(11) Uani 1 1 d . . .
O4 O 1.3564(5) 0.4016(4) -0.4497(4) 0.0302(11) Uani 1 1 d . . .
O5 O 1.3245(5) 0.5602(4) -0.5544(3) 0.0284(11) Uani 1 1 d . . .
O6 O 1.1454(5) 0.3198(4) -0.5874(3) 0.0291(11) Uani 1 1 d . . .
O7 O 0.4509(5) 0.8440(4) 0.5462(3) 0.0279(11) Uani 1 1 d . . .
O8 O 0.4031(5) 1.0209(4) 0.6135(3) 0.0261(10) Uani 1 1 d . . .
C1 C 0.4187(8) 0.4355(7) 0.2132(5) 0.0338(17) Uani 1 1 d . . .
H1 H 0.3373 0.4166 0.2553 0.041 Uiso 1 1 calc R . .
C2 C 0.4239(8) 0.3265(7) 0.1392(6) 0.0383(19) Uani 1 1 d . . .
H2 H 0.3493 0.2372 0.1347 0.046 Uiso 1 1 calc R . .
C3 C 0.5384(8) 0.3523(7) 0.0743(5) 0.0342(17) Uani 1 1 d . . .
H3 H 0.5427 0.2810 0.0242 0.041 Uiso 1 1 calc R . .
C4 C 0.6513(7) 0.4882(6) 0.0831(5) 0.0248(15) Uani 1 1 d . . .
C5 C 0.7713(7) 0.5313(6) 0.0143(5) 0.0243(15) Uani 1 1 d . . .
C6 C 0.8702(7) 0.6661(6) 0.0166(5) 0.0225(14) Uani 1 1 d . . .
C7 C 0.8667(7) 0.7752(6) 0.1004(5) 0.0216(14) Uani 1 1 d . . .
C8 C 0.9698(7) 0.9131(7) 0.1150(5) 0.0319(17) Uani 1 1 d . . .
H8 H 1.0457 0.9423 0.0678 0.038 Uiso 1 1 calc R . .
C9 C 0.9583(7) 1.0058(6) 0.1999(6) 0.0326(17) Uani 1 1 d . . .
H9 H 1.0243 1.0989 0.2100 0.039 Uiso 1 1 calc R . .
C10 C 0.8463(7) 0.9573(6) 0.2700(6) 0.0329(17) Uani 1 1 d . . .
H10 H 0.8422 1.0203 0.3289 0.040 Uiso 1 1 calc R . .
C11 C 0.7539(7) 0.7347(6) 0.1737(5) 0.0208(14) Uani 1 1 d . . .
C12 C 0.6403(6) 0.5909(6) 0.1610(5) 0.0190(13) Uani 1 1 d . . .
C13 C 0.9219(7) 0.5483(6) -0.1188(5) 0.0245(15) Uani 1 1 d . . .
C14 C 0.9918(7) 0.5113(6) -0.2174(5) 0.0216(14) Uani 1 1 d . . .
C15 C 1.1192(7) 0.6193(6) -0.2446(5) 0.0308(17) Uani 1 1 d . . .
H15 H 1.1529 0.7065 -0.2011 0.037 Uiso 1 1 calc R . .
C16 C 1.1974(8) 0.6009(6) -0.3344(5) 0.0316(17) Uani 1 1 d . . .
H16 H 1.2819 0.6744 -0.3507 0.038 Uiso 1 1 calc R . .
C17 C 1.1469(7) 0.4708(6) -0.3990(5) 0.0212(14) Uani 1 1 d . . .
C18 C 1.0201(7) 0.3622(6) -0.3764(5) 0.0230(14) Uani 1 1 d . . .
H18 H 0.9865 0.2758 -0.4213 0.028 Uiso 1 1 calc R . .
C19 C 0.9419(7) 0.3815(6) -0.2860(5) 0.0218(14) Uani 1 1 d . . .
C20 C 0.4588(7) 0.9611(6) 0.5456(5) 0.0202(14) Uani 1 1 d . . .
O9 O 0.7663(6) 0.8829(5) 0.5296(4) 0.0435(13) Uani 1 1 d D . .
H9A H 0.800(8) 0.840(7) 0.566(5) 0.052 Uiso 1 1 d D . .
H9B H 0.769(8) 0.956(5) 0.568(5) 0.052 Uiso 1 1 d D . .
O10 O 0.5752(9) 0.0614(8) 0.1671(6) 0.110(3) Uani 1 1 d . . .
O11 O 0.3170(8) 0.0040(7) 0.0254(7) 0.103(3) Uani 1 1 d . . .
loop_
_atom_type_symbol
_atom_type_description
_atom_type_scat_dispersion_real
_atom_type_scat_dispersion_imag
_atom_type_scat_source
C C 0.0033 0.0016 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
H H 0.0000 0.0000 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
N N 0.0061 0.0033 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
O O 0.0106 0.0060 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
Eu Eu -0.1578 3.6682 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
S S 0.1246 0.1234 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
loop_
_geom_angle_atom_site_label_1
_geom_angle_atom_site_label_2
_geom_angle_atom_site_label_3
_geom_angle
_geom_angle_site_symmetry_1
_geom_angle_site_symmetry_3
O4 Eu1 O1 138.75(14) 2_765 2_665
O4 Eu1 O7 113.89(15) 2_765 .
O1 Eu1 O7 86.94(15) 2_665 .
O4 Eu1 O8 145.41(15) 2_765 2_676
O1 Eu1 O8 74.47(14) 2_665 2_676
O7 Eu1 O8 68.08(13) . 2_676
O4 Eu1 O5 78.33(15) 2_765 1_456
O1 Eu1 O5 74.53(14) 2_665 1_456
O7 Eu1 O5 72.80(14) . 1_456
O8 Eu1 O5 130.62(14) 2_676 1_456
O4 Eu1 O9 71.41(15) 2_765 .
O1 Eu1 O9 149.84(15) 2_665 .
O7 Eu1 O9 76.71(17) . .
O8 Eu1 O9 75.93(16) 2_676 .
O5 Eu1 O9 122.65(17) 1_456 .
O4 Eu1 N2 90.46(16) 2_765 .
O1 Eu1 N2 96.47(15) 2_665 .
O7 Eu1 N2 138.22(15) . .
O8 Eu1 N2 72.82(15) 2_676 .
O5 Eu1 N2 148.13(15) 1_456 .
O9 Eu1 N2 80.17(18) . .
O4 Eu1 N1 70.14(16) 2_765 .
O1 Eu1 N1 76.60(16) 2_665 .
O7 Eu1 N1 154.53(15) . .
O8 Eu1 N1 123.99(15) 2_676 .
O5 Eu1 N1 84.03(15) 1_456 .
O9 Eu1 N1 126.19(17) . .
N2 Eu1 N1 64.10(15) . .
O4 Eu1 C20 146.09(15) 2_765 2_676
O1 Eu1 C20 74.28(15) 2_665 2_676
O7 Eu1 C20 47.92(14) . 2_676
O8 Eu1 C20 20.32(13) 2_676 2_676
O5 Eu1 C20 113.03(14) 1_456 2_676
O9 Eu1 C20 75.96(16) . 2_676
N2 Eu1 C20 92.92(15) . 2_676
N1 Eu1 C20 140.23(15) . 2_676
O3 S1 O2 114.6(3) . .
O3 S1 O1 112.9(3) . .
O2 S1 O1 110.3(3) . .
O3 S1 C19 106.5(3) . .
O2 S1 C19 106.8(3) . .
O1 S1 C19 104.9(3) . .
O6 S2 O5 113.2(3) . .
O6 S2 O4 112.1(3) . .
O5 S2 O4 111.1(3) . .
O6 S2 C17 108.0(3) . .
O5 S2 C17 107.5(3) . .
O4 S2 C17 104.3(3) . .
C1 N1 C12 117.5(5) . .
C1 N1 Eu1 121.5(4) . .
C12 N1 Eu1 119.5(4) . .
C10 N2 C11 117.3(5) . .
C10 N2 Eu1 122.6(4) . .
C11 N2 Eu1 120.1(4) . .
C13 N3 C6 103.8(5) . .
C13 N4 C5 108.5(5) . .
C13 N4 H4 125.8 . .
C5 N4 H4 125.8 . .
S1 O1 Eu1 146.3(3) . 2_665
S2 O4 Eu1 155.4(3) . 2_765
S2 O5 Eu1 152.8(3) . 1_654
C20 O7 Eu1 118.6(4) . .
C20 O8 Eu1 118.2(4) . 2_676
N1 C1 C2 123.4(6) . .
N1 C1 H1 118.3 . .
C2 C1 H1 118.3 . .
C3 C2 C1 119.4(6) . .
C3 C2 H2 120.3 . .
C1 C2 H2 120.3 . .
C2 C3 C4 119.5(6) . .
C2 C3 H3 120.3 . .
C4 C3 H3 120.3 . .
C12 C4 C3 117.8(6) . .
C12 C4 C5 116.9(5) . .
C3 C4 C5 125.2(6) . .
N4 C5 C6 105.0(5) . .
N4 C5 C4 130.9(6) . .
C6 C5 C4 123.9(5) . .
C5 C6 N3 111.2(5) . .
C5 C6 C7 120.6(5) . .
N3 C6 C7 128.2(5) . .
C8 C7 C11 118.8(5) . .
C8 C7 C6 124.6(5) . .
C11 C7 C6 116.6(5) . .
C9 C8 C7 119.3(6) . .
C9 C8 H8 120.4 . .
C7 C8 H8 120.4 . .
C8 C9 C10 118.4(6) . .
C8 C9 H9 120.8 . .
C10 C9 H9 120.8 . .
N2 C10 C9 124.7(6) . .
N2 C10 H10 117.6 . .
C9 C10 H10 117.6 . .
N2 C11 C7 121.5(5) . .
N2 C11 C12 117.4(5) . .
C7 C11 C12 121.1(5) . .
N1 C12 C4 122.5(5) . .
N1 C12 C11 117.1(5) . .
C4 C12 C11 120.4(5) . .
N3 C13 N4 111.5(5) . .
N3 C13 C14 122.9(5) . .
N4 C13 C14 125.6(5) . .
C15 C14 C19 117.5(5) . .
C15 C14 C13 115.6(5) . .
C19 C14 C13 127.0(5) . .
C16 C15 C14 122.3(6) . .
C16 C15 H15 118.8 . .
C14 C15 H15 118.8 . .
C17 C16 C15 118.7(6) . .
C17 C16 H16 120.7 . .
C15 C16 H16 120.7 . .
C18 C17 C16 120.8(6) . .
C18 C17 S2 117.5(5) . .
C16 C17 S2 121.6(5) . .
C17 C18 C19 120.2(5) . .
C17 C18 H18 119.9 . .
C19 C18 H18 119.9 . .
C18 C19 C14 120.5(5) . .
C18 C19 S1 114.6(4) . .
C14 C19 S1 125.0(4) . .
O7 C20 O8 125.4(5) . .
O7 C20 C20 117.8(7) . 2_676
O8 C20 C20 116.8(6) . 2_676
O7 C20 Eu1 166.2(4) . 2_676
O8 C20 Eu1 41.4(3) . 2_676
C20 C20 Eu1 75.5(4) 2_676 2_676
Eu1 O9 H9A 118(5) . .
Eu1 O9 H9B 116(5) . .
H9A O9 H9B 114(7) . .
loop_
_geom_bond_atom_site_label_1
_geom_bond_atom_site_label_2
_geom_bond_distance
_geom_bond_site_symmetry_2
Eu1 O4 2.357(4) 2_765
Eu1 O1 2.359(4) 2_665
Eu1 O7 2.382(4) .
Eu1 O8 2.396(4) 2_676
Eu1 O5 2.420(4) 1_456
Eu1 O9 2.445(5) .
Eu1 N2 2.565(5) .
Eu1 N1 2.574(5) .
Eu1 C20 3.189(6) 2_676
S1 O3 1.437(4) .
S1 O2 1.446(4) .
S1 O1 1.464(4) .
S1 C19 1.789(6) .
S2 O6 1.438(4) .
S2 O5 1.460(4) .
S2 O4 1.461(4) .
S2 C17 1.772(6) .
N1 C1 1.327(7) .
N1 C12 1.367(7) .
N2 C10 1.323(7) .
N2 C11 1.372(7) .
N3 C13 1.339(7) .
N3 C6 1.383(7) .
N4 C13 1.350(7) .
N4 C5 1.360(7) .
N4 H4 0.8600 .
O1 Eu1 2.359(4) 2_665
O4 Eu1 2.357(4) 2_765
O5 Eu1 2.420(4) 1_654
O7 C20 1.246(7) .
O8 C20 1.257(7) .
O8 Eu1 2.396(4) 2_676
C1 C2 1.399(9) .
C1 H1 0.9300 .
C2 C3 1.351(9) .
C2 H2 0.9300 .
C3 C4 1.411(8) .
C3 H3 0.9300 .
C4 C12 1.398(8) .
C4 C5 1.421(8) .
C5 C6 1.370(8) .
C6 C7 1.458(8) .
C7 C8 1.391(8) .
C7 C11 1.407(8) .
C8 C9 1.375(9) .
C8 H8 0.9300 .
C9 C10 1.382(9) .
C9 H9 0.9300 .
C10 H10 0.9300 .
C11 C12 1.470(8) .
C13 C14 1.486(8) .
C14 C15 1.398(8) .
C14 C19 1.404(8) .
C15 C16 1.391(8) .
C15 H15 0.9300 .
C16 C17 1.385(8) .
C16 H16 0.9300 .
C17 C18 1.378(8) .
C18 C19 1.399(8) .
C18 H18 0.9300 .
C20 C20 1.527(11) 2_676
C20 Eu1 3.189(6) 2_676
O9 H9A 0.84(2) .
O9 H9B 0.85(2) .
loop_
_geom_torsion_atom_site_label_1
_geom_torsion_atom_site_label_2
_geom_torsion_atom_site_label_3
_geom_torsion_atom_site_label_4
_geom_torsion
_geom_torsion_site_symmetry_1
_geom_torsion_site_symmetry_2
_geom_torsion_site_symmetry_3
_geom_torsion_site_symmetry_4
O4 Eu1 N1 C1 77.3(5) 2_765 . . .
O1 Eu1 N1 C1 -77.9(5) 2_665 . . .
O7 Eu1 N1 C1 -26.8(7) . . . .
O8 Eu1 N1 C1 -138.4(5) 2_676 . . .
O5 Eu1 N1 C1 -2.4(5) 1_456 . . .
O9 Eu1 N1 C1 124.1(5) . . . .
N2 Eu1 N1 C1 177.9(6) . . . .
C20 Eu1 N1 C1 -121.7(5) 2_676 . . .
O4 Eu1 N1 C12 -88.2(5) 2_765 . . .
O1 Eu1 N1 C12 116.6(5) 2_665 . . .
O7 Eu1 N1 C12 167.7(4) . . . .
O8 Eu1 N1 C12 56.1(5) 2_676 . . .
O5 Eu1 N1 C12 -167.9(5) 1_456 . . .
O9 Eu1 N1 C12 -41.4(5) . . . .
N2 Eu1 N1 C12 12.4(4) . . . .
C20 Eu1 N1 C12 72.8(5) 2_676 . . .
O4 Eu1 N2 C10 -117.0(5) 2_765 . . .
O1 Eu1 N2 C10 103.7(5) 2_665 . . .
O7 Eu1 N2 C10 11.0(7) . . . .
O8 Eu1 N2 C10 32.2(5) 2_676 . . .
O5 Eu1 N2 C10 174.7(5) 1_456 . . .
O9 Eu1 N2 C10 -46.0(5) . . . .
N1 Eu1 N2 C10 175.4(6) . . . .
C20 Eu1 N2 C10 29.2(5) 2_676 . . .
O4 Eu1 N2 C11 59.5(5) 2_765 . . .
O1 Eu1 N2 C11 -79.8(5) 2_665 . . .
O7 Eu1 N2 C11 -172.5(4) . . . .
O8 Eu1 N2 C11 -151.3(5) 2_676 . . .
O5 Eu1 N2 C11 -8.8(6) 1_456 . . .
O9 Eu1 N2 C11 130.5(5) . . . .
N1 Eu1 N2 C11 -8.1(4) . . . .
C20 Eu1 N2 C11 -154.3(5) 2_676 . . .
O3 S1 O1 Eu1 -15.4(5) . . . 2_665
O2 S1 O1 Eu1 -145.1(4) . . . 2_665
C19 S1 O1 Eu1 100.2(5) . . . 2_665
O6 S2 O4 Eu1 -11.5(7) . . . 2_765
O5 S2 O4 Eu1 -139.2(6) . . . 2_765
C17 S2 O4 Eu1 105.2(6) . . . 2_765
O6 S2 O5 Eu1 -119.0(6) . . . 1_654
O4 S2 O5 Eu1 8.2(7) . . . 1_654
C17 S2 O5 Eu1 121.7(6) . . . 1_654
O4 Eu1 O7 C20 148.5(4) 2_765 . . .
O1 Eu1 O7 C20 -68.4(4) 2_665 . . .
O8 Eu1 O7 C20 6.1(4) 2_676 . . .
O5 Eu1 O7 C20 -143.2(5) 1_456 . . .
O9 Eu1 O7 C20 86.0(5) . . . .
N2 Eu1 O7 C20 27.9(6) . . . .
N1 Eu1 O7 C20 -117.7(5) . . . .
C20 Eu1 O7 C20 3.1(5) 2_676 . . .
C12 N1 C1 C2 2.1(10) . . . .
Eu1 N1 C1 C2 -163.7(6) . . . .
N1 C1 C2 C3 -2.3(12) . . . .
C1 C2 C3 C4 0.6(11) . . . .
C2 C3 C4 C12 1.0(10) . . . .
C2 C3 C4 C5 -175.0(7) . . . .
C13 N4 C5 C6 -1.3(7) . . . .
C13 N4 C5 C4 173.1(7) . . . .
C12 C4 C5 N4 -176.7(7) . . . .
C3 C4 C5 N4 -0.6(12) . . . .
C12 C4 C5 C6 -3.3(10) . . . .
C3 C4 C5 C6 172.7(7) . . . .
N4 C5 C6 N3 1.4(7) . . . .
C4 C5 C6 N3 -173.5(6) . . . .
N4 C5 C6 C7 -178.8(6) . . . .
C4 C5 C6 C7 6.4(10) . . . .
C13 N3 C6 C5 -0.9(7) . . . .
C13 N3 C6 C7 179.3(6) . . . .
C5 C6 C7 C8 174.5(6) . . . .
N3 C6 C7 C8 -5.6(11) . . . .
C5 C6 C7 C11 -2.6(9) . . . .
N3 C6 C7 C11 177.3(6) . . . .
C11 C7 C8 C9 -0.3(10) . . . .
C6 C7 C8 C9 -177.4(6) . . . .
C7 C8 C9 C10 1.8(11) . . . .
C11 N2 C10 C9 1.6(10) . . . .
Eu1 N2 C10 C9 178.2(5) . . . .
C8 C9 C10 N2 -2.5(11) . . . .
C10 N2 C11 C7 0.0(9) . . . .
Eu1 N2 C11 C7 -176.7(4) . . . .
C10 N2 C11 C12 -179.5(6) . . . .
Eu1 N2 C11 C12 3.8(7) . . . .
C8 C7 C11 N2 -0.6(9) . . . .
C6 C7 C11 N2 176.7(6) . . . .
C8 C7 C11 C12 178.9(6) . . . .
C6 C7 C11 C12 -3.8(9) . . . .
C1 N1 C12 C4 -0.4(9) . . . .
Eu1 N1 C12 C4 165.7(5) . . . .
C1 N1 C12 C11 178.2(6) . . . .
Eu1 N1 C12 C11 -15.8(7) . . . .
C3 C4 C12 N1 -1.2(10) . . . .
C5 C4 C12 N1 175.2(6) . . . .
C3 C4 C12 C11 -179.6(6) . . . .
C5 C4 C12 C11 -3.3(9) . . . .
N2 C11 C12 N1 7.9(8) . . . .
C7 C11 C12 N1 -171.7(6) . . . .
N2 C11 C12 C4 -173.6(6) . . . .
C7 C11 C12 C4 6.9(9) . . . .
C6 N3 C13 N4 0.0(7) . . . .
C6 N3 C13 C14 178.8(6) . . . .
C5 N4 C13 N3 0.8(8) . . . .
C5 N4 C13 C14 -177.9(6) . . . .
N3 C13 C14 C15 8.3(9) . . . .
N4 C13 C14 C15 -173.2(6) . . . .
N3 C13 C14 C19 -170.6(6) . . . .
N4 C13 C14 C19 8.0(11) . . . .
C19 C14 C15 C16 -1.3(10) . . . .
C13 C14 C15 C16 179.8(6) . . . .
C14 C15 C16 C17 0.0(11) . . . .
C15 C16 C17 C18 1.2(10) . . . .
C15 C16 C17 S2 -174.4(5) . . . .
O6 S2 C17 C18 29.3(6) . . . .
O5 S2 C17 C18 151.9(5) . . . .
O4 S2 C17 C18 -90.1(5) . . . .
O6 S2 C17 C16 -154.9(5) . . . .
O5 S2 C17 C16 -32.4(6) . . . .
O4 S2 C17 C16 85.6(6) . . . .
C16 C17 C18 C19 -1.2(10) . . . .
S2 C17 C18 C19 174.6(5) . . . .
C17 C18 C19 C14 -0.2(9) . . . .
C17 C18 C19 S1 179.3(5) . . . .
C15 C14 C19 C18 1.3(9) . . . .
C13 C14 C19 C18 -179.9(6) . . . .
C15 C14 C19 S1 -178.0(5) . . . .
C13 C14 C19 S1 0.8(10) . . . .
O3 S1 C19 C18 -0.2(6) . . . .
O2 S1 C19 C18 122.7(5) . . . .
O1 S1 C19 C18 -120.2(5) . . . .
O3 S1 C19 C14 179.1(5) . . . .
O2 S1 C19 C14 -57.9(6) . . . .
O1 S1 C19 C14 59.2(6) . . . .
Eu1 O7 C20 O8 174.0(5) . . . .
Eu1 O7 C20 C20 -5.4(9) . . . 2_676
Eu1 O7 C20 Eu1 -170.3(16) . . . 2_676
Eu1 O8 C20 O7 174.4(5) 2_676 . . .
Eu1 O8 C20 C20 -6.2(9) 2_676 . . 2_676
