#------------------------------------------------------------------------------
#$Date: 2021-03-10 11:44:48 +0200 (Wed, 10 Mar 2021) $
#$Revision: 262966 $
#$URL: file:///home/coder/svn-repositories/cod/cif/1/56/09/1560989.cif $
#------------------------------------------------------------------------------
#
# This file is available in the Crystallography Open Database (COD),
# http://www.crystallography.net/
#
# All data on this site have been placed in the public domain by the
# contributors.
#
data_1560989
loop_
_publ_author_name
'Tarasenko, Maria S.'
'Berezin, Alexey S.'
'Kiryakov, Alexander S.'
'Piryazev, Dmitry A.'
'Filatova, Irina Yu.'
'Naumov, Nikolay G.'
_publ_section_title
;
 Synthesis, crystal structure and photoluminescence of Eu3+ or Tb3+ doped
 solid solutions (Y1-xREx)4S3(Si2O7)
;
_journal_name_full               'Journal of Solid State Chemistry'
_journal_page_first              36
_journal_page_last               41
_journal_paper_doi               10.1016/j.jssc.2018.05.016
_journal_volume                  265
_journal_year                    2018
_chemical_formula_sum            'Eu0.15 O7 S3 Si2 Y3.85'
_chemical_formula_weight         629.46
_chemical_melting_point          1818
_space_group_IT_number           141
_space_group_name_Hall           '-I 4bd 2'
_space_group_name_H-M_alt        'I 41/a m d :2'
_symmetry_cell_setting           tetragonal
_symmetry_Int_Tables_number      141
_symmetry_space_group_name_Hall  '-I 4bd 2'
_symmetry_space_group_name_H-M   'I 41/a m d :2'
_atom_sites_solution_hydrogens   notdet
_atom_sites_solution_primary     direct
_atom_sites_solution_secondary   difmap
_cell_angle_alpha                90.00
_cell_angle_beta                 90.00
_cell_angle_gamma                90.00
_cell_formula_units_Z            8
_cell_length_a                   11.6506(8)
_cell_length_b                   11.6506(8)
_cell_length_c                   13.6054(16)
_cell_measurement_reflns_used    1043
_cell_measurement_temperature    296(2)
_cell_measurement_theta_max      28.41
_cell_measurement_theta_min      4.61
_cell_volume                     1846.7(3)
_computing_cell_refinement       'Apex2 V.1.27 (Bruker, 2005)'
_computing_data_collection       'Apex2 V.1.27 (Bruker, 2005)'
_computing_data_reduction        'Apex2 V.1.27 (Bruker, 2005)'
_computing_molecular_graphics    'SHELXTL V6.22 (Bruker, 2000-2005)'
_computing_publication_material  'local programs'
_computing_structure_refinement  'SHELXL-97 (Sheldrick, 1997)'
_computing_structure_solution    'SHELXS-97 (Sheldrick, 1990)'
_diffrn_ambient_temperature      296(2)
_diffrn_detector_area_resol_mean 25
_diffrn_measured_fraction_theta_full 0.992
_diffrn_measured_fraction_theta_max 0.834
_diffrn_measurement_device_type  'Bruker Nonius X8Apex CCD area-detector'
_diffrn_measurement_method       'combined omega- and phi-scans'
_diffrn_radiation_monochromator  graphite
_diffrn_radiation_type           MoK\a
_diffrn_radiation_wavelength     0.71073
_diffrn_reflns_av_R_equivalents  0.0418
_diffrn_reflns_av_sigmaI/netI    0.0363
_diffrn_reflns_limit_h_max       14
_diffrn_reflns_limit_h_min       -10
_diffrn_reflns_limit_k_max       12
_diffrn_reflns_limit_k_min       -14
_diffrn_reflns_limit_l_max       15
_diffrn_reflns_limit_l_min       -17
_diffrn_reflns_number            3094
_diffrn_reflns_theta_full        25.50
_diffrn_reflns_theta_max         30.18
_diffrn_reflns_theta_min         3.88
_diffrn_source                   'fine-focus sealed tube'
_diffrn_standards_decay_%        0
_diffrn_standards_number         0
_exptl_absorpt_coefficient_mu    25.909
_exptl_absorpt_correction_T_max  0.3574
_exptl_absorpt_correction_T_min  0.1815
_exptl_absorpt_correction_type   multi-scan
_exptl_absorpt_process_details   'Bruker SADABS'
_exptl_crystal_colour            orange
_exptl_crystal_density_diffrn    4.528
_exptl_crystal_density_method    'not measured'
_exptl_crystal_description       block
_exptl_crystal_F_000             2333
_exptl_crystal_size_max          0.10
_exptl_crystal_size_mid          0.08
_exptl_crystal_size_min          0.05
_refine_diff_density_max         0.904
_refine_diff_density_min         -0.911
_refine_diff_density_rms         0.199
_refine_ls_extinction_coef       0.00027(5)
_refine_ls_extinction_expression Fc^*^=kFc[1+0.001xFc²λ³/sin(2θ)]^-1/4^
_refine_ls_extinction_method     SHELXL
_refine_ls_goodness_of_fit_ref   1.014
_refine_ls_hydrogen_treatment    noref
_refine_ls_matrix_type           full
_refine_ls_number_parameters     48
_refine_ls_number_reflns         626
_refine_ls_number_restraints     0
_refine_ls_restrained_S_all      1.014
_refine_ls_R_factor_all          0.0351
_refine_ls_R_factor_gt           0.0265
_refine_ls_shift/su_max          0.000
_refine_ls_shift/su_mean         0.000
_refine_ls_structure_factor_coef Fsqd
_refine_ls_weighting_details
'calc w=1/[σ²(Fo²)+(0.0187P)²+3.0471P] where P=(Fo²+2Fc²)/3'
_refine_ls_weighting_scheme      calc
_refine_ls_wR_factor_gt          0.0434
_refine_ls_wR_factor_ref         0.0455
_reflns_number_gt                541
_reflns_number_total             626
_reflns_threshold_expression     >2sigma(I)
_cod_data_source_file            JSSC-2018-265-36.cif
_cod_data_source_block           tm99t
_cod_original_sg_symbol_H-M      'I 41/a m d'
_cod_database_code               1560989
loop_
_symmetry_equiv_pos_as_xyz
'x, y, z'
'-y+1/4, x+3/4, z+1/4'
'-x, -y+1/2, z'
'y+1/4, -x+1/4, z+3/4'
'x, -y, -z'
'-x, y+1/2, -z'
'y+1/4, x+3/4, -z+1/4'
'-y+1/4, -x+1/4, -z+3/4'
'x+1/2, y+1/2, z+1/2'
'-y+3/4, x+5/4, z+3/4'
'-x+1/2, -y+1, z+1/2'
'y+3/4, -x+3/4, z+5/4'
'x+1/2, -y+1/2, -z+1/2'
'-x+1/2, y+1, -z+1/2'
'y+3/4, x+5/4, -z+3/4'
'-y+3/4, -x+3/4, -z+5/4'
'-x, -y, -z'
'y-1/4, -x-3/4, -z-1/4'
'x, y-1/2, -z'
'-y-1/4, x-1/4, -z-3/4'
'-x, y, z'
'x, -y-1/2, z'
'-y-1/4, -x-3/4, z-1/4'
'y-1/4, x-1/4, z-3/4'
'-x+1/2, -y+1/2, -z+1/2'
'y+1/4, -x-1/4, -z+1/4'
'x+1/2, y, -z+1/2'
'-y+1/4, x+1/4, -z-1/4'
'-x+1/2, y+1/2, z+1/2'
'x+1/2, -y, z+1/2'
'-y+1/4, -x-1/4, z+1/4'
'y+1/4, x+1/4, z-1/4'
loop_
_atom_site_label
_atom_site_type_symbol
_atom_site_fract_x
_atom_site_fract_y
_atom_site_fract_z
_atom_site_U_iso_or_equiv
_atom_site_adp_type
_atom_site_occupancy
_atom_site_symmetry_multiplicity
_atom_site_calc_flag
_atom_site_refinement_flags
_atom_site_disorder_assembly
_atom_site_disorder_group
Y1 Y 0.0000 0.01462(4) 0.34033(3) 0.00518(15) Uani 0.925 2 d SP . .
Eu1 Eu 0.0000 0.01462(4) 0.34033(3) 0.00518(15) Uani 0.075 2 d SP . .
Y2 Y 0.17308(3) 0.42308(3) 0.8750 0.00445(15) Uani 1 2 d S . .
S1 S 0.35270(12) 0.0000 0.0000 0.0101(3) Uani 1 2 d S . .
S2 S 0.0000 0.2500 0.3750 0.0108(6) Uani 1 8 d S . .
S3 S 0.0000 0.7500 0.1250 0.0063(5) Uani 1 8 d S . .
Si1 Si 0.0000 0.12495(12) 0.09513(10) 0.0042(3) Uani 1 2 d S . .
O1 O 0.1224(2) 0.1097(2) 0.04034(18) 0.0085(6) Uani 1 1 d . . .
O2 O 0.0000 0.0175(3) 0.1723(3) 0.0053(8) Uani 1 2 d S . .
O3 O 0.0000 0.2500 0.1476(4) 0.0107(12) Uani 1 4 d S . .
loop_
_atom_type_symbol
_atom_type_description
_atom_type_scat_dispersion_real
_atom_type_scat_dispersion_imag
_atom_type_scat_source
Y Y -2.7962 3.5667 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
S S 0.1246 0.1234 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
Si Si 0.0817 0.0704 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
O O 0.0106 0.0060 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
Eu Eu -0.1578 3.6682 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
loop_
_geom_angle_atom_site_label_1
_geom_angle_atom_site_label_2
_geom_angle_atom_site_label_3
_geom_angle
_geom_angle_site_symmetry_1
_geom_angle_site_symmetry_3
O2 Y1 O1 74.31(8) . 24_556
O2 Y1 O1 74.31(8) . 2_545
O1 Y1 O1 84.79(13) 24_556 2_545
O2 Y1 S1 141.63(2) . 11_545
O1 Y1 S1 126.50(6) 24_556 11_545
O1 Y1 S1 76.14(6) 2_545 11_545
O2 Y1 S1 141.63(2) . 27_455
O1 Y1 S1 76.14(6) 24_556 27_455
O1 Y1 S1 126.50(6) 2_545 27_455
S1 Y1 S1 76.45(5) 11_545 27_455
O2 Y1 S2 98.93(9) . .
O1 Y1 S2 136.12(7) 24_556 .
O1 Y1 S2 136.12(7) 2_545 .
S1 Y1 S2 85.858(12) 11_545 .
S1 Y1 S2 85.858(12) 27_455 .
O2 Y1 Si1 91.85(8) . 12_444
O1 Y1 Si1 25.81(7) 24_556 12_444
O1 Y1 Si1 71.08(7) 2_545 12_444
S1 Y1 Si1 101.17(3) 11_545 12_444
S1 Y1 Si1 70.44(3) 27_455 12_444
S2 Y1 Si1 152.58(2) . 12_444
O2 Y1 Si1 91.85(8) . 2_545
O1 Y1 Si1 71.08(7) 24_556 2_545
O1 Y1 Si1 25.81(7) 2_545 2_545
S1 Y1 Si1 70.44(3) 11_545 2_545
S1 Y1 Si1 101.17(3) 27_455 2_545
S2 Y1 Si1 152.58(2) . 2_545
Si1 Y1 Si1 50.58(4) 12_444 2_545
O2 Y1 Y2 38.30(4) . 2_544
O1 Y1 Y2 38.40(6) 24_556 2_544
O1 Y1 Y2 87.06(6) 2_545 2_544
S1 Y1 Y2 159.444(19) 11_545 2_544
S1 Y1 Y2 105.33(2) 27_455 2_544
S2 Y1 Y2 114.636(14) . 2_544
Si1 Y1 Y2 61.54(2) 12_444 2_544
Si1 Y1 Y2 89.28(3) 2_545 2_544
O2 Y1 Y2 38.30(4) . 19_556
O1 Y1 Y2 87.06(6) 24_556 19_556
O1 Y1 Y2 38.40(6) 2_545 19_556
S1 Y1 Y2 105.33(2) 11_545 19_556
S1 Y1 Y2 159.444(19) 27_455 19_556
S2 Y1 Y2 114.636(14) . 19_556
Si1 Y1 Y2 89.28(3) 12_444 19_556
Si1 Y1 Y2 61.54(2) 2_545 19_556
Y2 Y1 Y2 65.786(15) 2_544 19_556
O2 Y1 Y2 97.02(2) . 9_444
O1 Y1 Y2 37.40(6) 24_556 9_444
O1 Y1 Y2 119.67(7) 2_545 9_444
S1 Y1 Y2 118.84(3) 11_545 9_444
S1 Y1 Y2 45.51(2) 27_455 9_444
S2 Y1 Y2 104.112(8) . 9_444
Si1 Y1 Y2 49.25(2) 12_444 9_444
Si1 Y1 Y2 99.45(2) 2_545 9_444
Y2 Y1 Y2 59.817(6) 2_544 9_444
Y2 Y1 Y2 122.397(15) 19_556 9_444
O2 Y1 Y2 97.02(2) . 20_657
O1 Y1 Y2 119.67(7) 24_556 20_657
O1 Y1 Y2 37.40(6) 2_545 20_657
S1 Y1 Y2 45.51(2) 11_545 20_657
S1 Y1 Y2 118.84(3) 27_455 20_657
S2 Y1 Y2 104.112(8) . 20_657
Si1 Y1 Y2 99.45(2) 12_444 20_657
Si1 Y1 Y2 49.25(2) 2_545 20_657
Y2 Y1 Y2 122.397(15) 2_544 20_657
Y2 Y1 Y2 59.817(6) 19_556 20_657
Y2 Y1 Y2 145.952(15) 9_444 20_657
O1 Y2 O1 146.10(14) 28_556 22_566
O1 Y2 O2 73.80(10) 28_556 19_566
O1 Y2 O2 96.93(10) 22_566 19_566
O1 Y2 O2 96.93(10) 28_556 4
O1 Y2 O2 73.80(10) 22_566 4
O2 Y2 O2 148.47(15) 19_566 4
O1 Y2 O1 127.73(8) 28_556 19_566
O1 Y2 O1 69.27(11) 22_566 19_566
O2 Y2 O1 61.94(10) 19_566 19_566
O2 Y2 O1 135.31(10) 4 19_566
O1 Y2 O1 69.27(11) 28_556 32_556
O1 Y2 O1 127.73(8) 22_566 32_556
O2 Y2 O1 135.31(10) 19_566 32_556
O2 Y2 O1 61.94(10) 4 32_556
O1 Y2 O1 127.46(12) 19_566 32_556
O1 Y2 S1 140.30(7) 28_556 19_566
O1 Y2 S1 70.38(7) 22_566 19_566
O2 Y2 S1 129.70(8) 19_566 19_566
O2 Y2 S1 76.44(7) 4 19_566
O1 Y2 S1 68.18(6) 19_566 19_566
O1 Y2 S1 73.34(6) 32_556 19_566
O1 Y2 S1 70.38(7) 28_556 28_556
O1 Y2 S1 140.30(7) 22_566 28_556
O2 Y2 S1 76.44(7) 19_566 28_556
O2 Y2 S1 129.70(8) 4 28_556
O1 Y2 S1 73.34(6) 19_566 28_556
O1 Y2 S1 68.18(6) 32_556 28_556
S1 Y2 S1 83.90(2) 19_566 28_556
O1 Y2 S3 73.05(7) 28_556 17_566
O1 Y2 S3 73.05(7) 22_566 17_566
O2 Y2 S3 74.23(7) 19_566 17_566
O2 Y2 S3 74.23(7) 4 17_566
O1 Y2 S3 116.27(6) 19_566 17_566
O1 Y2 S3 116.27(6) 32_556 17_566
S1 Y2 S3 138.052(10) 19_566 17_566
S1 Y2 S3 138.052(10) 28_556 17_566
O1 Y2 Si1 102.02(7) 28_556 19_566
O1 Y2 Si1 80.56(7) 22_566 19_566
O2 Y2 Si1 30.97(9) 19_566 19_566
O2 Y2 Si1 153.99(9) 4 19_566
O1 Y2 Si1 31.07(6) 19_566 19_566
O1 Y2 Si1 142.12(6) 32_556 19_566
S1 Y2 Si1 99.21(3) 19_566 19_566
S1 Y2 Si1 74.16(3) 28_556 19_566
S3 Y2 Si1 94.355(19) 17_566 19_566
O1 Y2 Si1 80.56(7) 28_556 4
O1 Y2 Si1 102.02(7) 22_566 4
O2 Y2 Si1 153.99(9) 19_566 4
O2 Y2 Si1 30.97(9) 4 4
O1 Y2 Si1 142.12(7) 19_566 4
O1 Y2 Si1 31.07(6) 32_556 4
S1 Y2 Si1 74.16(3) 19_566 4
S1 Y2 Si1 99.21(3) 28_556 4
S3 Y2 Si1 94.355(19) 17_566 4
Si1 Y2 Si1 171.29(4) 19_566 4
O1 Y2 Y1 39.73(6) 28_556 19_566
O1 Y2 Y1 131.58(7) 22_566 19_566
O2 Y2 Y1 36.43(8) 19_566 19_566
O2 Y2 Y1 134.93(8) 4 19_566
O1 Y2 Y1 89.18(6) 19_566 19_566
O1 Y2 Y1 100.05(6) 32_556 19_566
S1 Y2 Y1 141.404(16) 19_566 19_566
S1 Y2 Y1 59.170(8) 28_556 19_566
S3 Y2 Y1 79.579(10) 17_566 19_566
Si1 Y2 Y1 62.35(3) 19_566 19_566
Si1 Y2 Y1 119.44(3) 4 19_566
Eu1 S1 Y1 0.000(12) 27 27
Eu1 S1 Y1 103.55(5) 27 11_544
Y1 S1 Y1 103.55(5) 27 11_544
Eu1 S1 Eu1 103.55(5) 27 11_544
Y1 S1 Eu1 103.55(5) 27 11_544
Y1 S1 Eu1 0.000(12) 11_544 11_544
Eu1 S1 Y2 154.825(19) 27 18_566
Y1 S1 Y2 154.825(19) 27 18_566
Y1 S1 Y2 90.361(12) 11_544 18_566
Eu1 S1 Y2 90.361(12) 11_544 18_566
Eu1 S1 Y2 90.361(12) 27 19_556
Y1 S1 Y2 90.361(12) 27 19_556
Y1 S1 Y2 154.825(19) 11_544 19_556
Eu1 S1 Y2 154.825(19) 11_544 19_556
Y2 S1 Y2 85.14(4) 18_566 19_556
Eu1 S1 Eu1 122.307(16) 27 26
Y1 S1 Eu1 122.307(16) 27 26
Y1 S1 Eu1 81.233(16) 11_544 26
Eu1 S1 Eu1 81.233(16) 11_544 26
Y2 S1 Eu1 80.08(2) 18_566 26
Y2 S1 Eu1 73.59(2) 19_556 26
Eu1 S1 Eu1 81.233(16) 27 4_554
Y1 S1 Eu1 81.233(16) 27 4_554
Y1 S1 Eu1 122.307(16) 11_544 4_554
Eu1 S1 Eu1 122.307(16) 11_544 4_554
Y2 S1 Eu1 73.59(2) 18_566 4_554
Y2 S1 Eu1 80.08(2) 19_556 4_554
Eu1 S1 Eu1 144.04(5) 26 4_554
Eu1 S2 Y1 0.000(3) 18_566 18_566
Eu1 S2 Y1 91.647(3) 18_566 .
Y1 S2 Y1 91.647(3) 18_566 .
Eu1 S2 Eu1 160.480(19) 18_566 28_556
Y1 S2 Eu1 160.480(19) 18_566 28_556
Y1 S2 Eu1 91.647(3) . 28_556
Eu1 S2 Y1 160.480(19) 18_566 28_556
Y1 S2 Y1 160.480(19) 18_566 28_556
Y1 S2 Y1 91.647(3) . 28_556
Eu1 S2 Y1 0.000(19) 28_556 28_556
Eu1 S2 Y1 91.647(3) 18_566 3
Y1 S2 Y1 91.647(3) 18_566 3
Y1 S2 Y1 160.480(19) . 3
Eu1 S2 Y1 91.647(3) 28_556 3
Y1 S2 Y1 91.647(3) 28_556 3
Eu1 S2 Eu1 91.647(3) 18_566 3
Y1 S2 Eu1 91.647(3) 18_566 3
Y1 S2 Eu1 160.480(19) . 3
Eu1 S2 Eu1 91.647(3) 28_556 3
Y1 S2 Eu1 91.647(3) 28_556 3
Y1 S2 Eu1 0.000(19) 3 3
Y2 S3 Y2 180.0 19_566 17_566
Y2 S3 Y2 90.0 19_566 12_453
Y2 S3 Y2 90.0 17_566 12_453
Y2 S3 Y2 90.0 19_566 2_554
Y2 S3 Y2 90.0 17_566 2_554
Y2 S3 Y2 180.0 12_453 2_554
O1 Si1 O1 123.5(2) 21 .
O1 Si1 O3 107.55(12) 21 .
O1 Si1 O3 107.55(12) . .
O1 Si1 O2 102.21(12) 21 .
O1 Si1 O2 102.21(12) . .
O3 Si1 O2 113.9(2) . .
O1 Si1 Y2 53.74(10) 21 2_544
O1 Si1 Y2 123.06(12) . 2_544
O3 Si1 Y2 128.21(10) . 2_544
O2 Si1 Y2 48.68(7) . 2_544
O1 Si1 Y2 123.06(12) 21 19_556
O1 Si1 Y2 53.74(10) . 19_556
O3 Si1 Y2 128.21(10) . 19_556
O2 Si1 Y2 48.68(7) . 19_556
Y2 Si1 Y2 80.38(4) 2_544 19_556
O1 Si1 Y1 146.56(12) 21 4_554
O1 Si1 Y1 40.70(10) . 4_554
O3 Si1 Y1 67.97(4) . 4_554
O2 Si1 Y1 109.85(4) . 4_554
Y2 Si1 Y1 155.15(4) 2_544 4_554
Y2 Si1 Y1 74.969(11) 19_556 4_554
O1 Si1 Eu1 146.56(12) 21 4_554
O1 Si1 Eu1 40.70(10) . 4_554
O3 Si1 Eu1 67.97(4) . 4_554
O2 Si1 Eu1 109.85(4) . 4_554
Y2 Si1 Eu1 155.15(4) 2_544 4_554
Y2 Si1 Eu1 74.969(11) 19_556 4_554
Y1 Si1 Eu1 0.000(17) 4_554 4_554
O1 Si1 Eu1 40.70(10) 21 10_444
O1 Si1 Eu1 146.56(12) . 10_444
O3 Si1 Eu1 67.97(4) . 10_444
O2 Si1 Eu1 109.85(4) . 10_444
Y2 Si1 Eu1 74.969(11) 2_544 10_444
Y2 Si1 Eu1 155.15(4) 19_556 10_444
Y1 Si1 Eu1 129.37(4) 4_554 10_444
Eu1 Si1 Eu1 129.37(4) 4_554 10_444
O1 Si1 Y1 40.70(10) 21 10_444
O1 Si1 Y1 146.56(12) . 10_444
O3 Si1 Y1 67.97(4) . 10_444
O2 Si1 Y1 109.85(4) . 10_444
Y2 Si1 Y1 74.969(11) 2_544 10_444
Y2 Si1 Y1 155.15(4) 19_556 10_444
Y1 Si1 Y1 129.37(4) 4_554 10_444
Eu1 Si1 Y1 129.37(4) 4_554 10_444
Eu1 Si1 Y1 0.000(17) 10_444 10_444
Si1 O1 Y2 132.67(15) . 18_566
Si1 O1 Y1 113.49(14) . 4_554
Y2 O1 Y1 101.87(10) 18_566 4_554
Si1 O1 Eu1 113.49(14) . 4_554
Y2 O1 Eu1 101.87(10) 18_566 4_554
Y1 O1 Eu1 0.00(2) 4_554 4_554
Si1 O1 Y2 95.19(12) . 19_556
Y2 O1 Y2 103.72(10) 18_566 19_556
Y1 O1 Y2 106.99(10) 4_554 19_556
Eu1 O1 Y2 106.99(10) 4_554 19_556
Si1 O2 Y1 130.8(2) . .
Si1 O2 Y2 100.35(11) . 2_544
Y1 O2 Y2 105.27(10) . 2_544
Si1 O2 Y2 100.35(11) . 19_556
Y1 O2 Y2 105.27(10) . 19_556
Y2 O2 Y2 115.41(14) 2_544 19_556
Si1 O3 Si1 127.8(3) . 3
loop_
_geom_bond_atom_site_label_1
_geom_bond_atom_site_label_2
_geom_bond_distance
_geom_bond_site_symmetry_2
Y1 O2 2.286(4) .
Y1 O1 2.425(3) 24_556
Y1 O1 2.425(3) 2_545
Y1 S1 2.7737(10) 11_545
Y1 S1 2.7737(10) 27_455
Y1 S2 2.7825(5) .
Y1 Si1 3.4106(8) 12_444
Y1 Si1 3.4106(8) 2_545
Y1 Y2 3.7130(5) 2_544
Y1 Y2 3.7130(5) 19_556
Y1 Y2 3.9834(5) 9_444
Y1 Y2 3.9834(5) 20_657
Y2 O1 2.357(2) 28_556
Y2 O1 2.357(2) 22_566
Y2 O2 2.3855(19) 19_566
Y2 O2 2.3855(19) 4
Y2 O1 2.530(3) 19_566
Y2 O1 2.530(3) 32_556
Y2 S1 2.8416(11) 19_566
Y2 S1 2.8416(11) 28_556
Y2 S3 2.8517(5) 17_566
Y2 Si1 3.1246(11) 19_566
Y2 Si1 3.1246(11) 4
Y2 Y1 3.7130(5) 19_566
S1 Eu1 2.7737(10) 27
S1 Y1 2.7737(10) 27
S1 Y1 2.7737(10) 11_544
S1 Eu1 2.7737(10) 11_544
S1 Y2 2.8416(11) 18_566
S1 Y2 2.8416(11) 19_556
S1 Eu1 3.3237(5) 26
S1 Eu1 3.3237(5) 4_554
S2 Eu1 2.7825(5) 18_566
S2 Y1 2.7825(5) 18_566
S2 Eu1 2.7825(5) 28_556
S2 Y1 2.7825(5) 28_556
S2 Y1 2.7825(5) 3
S2 Eu1 2.7825(5) 3
S3 Y2 2.8517(5) 19_566
S3 Y2 2.8517(5) 17_566
S3 Y2 2.8517(5) 12_453
S3 Y2 2.8517(5) 2_554
Si1 O1 1.619(3) 21
Si1 O1 1.619(3) .
Si1 O3 1.623(3) .
Si1 O2 1.634(4) .
Si1 Y2 3.1246(11) 2_544
Si1 Y2 3.1246(11) 19_556
Si1 Y1 3.4106(8) 4_554
Si1 Eu1 3.4106(8) 4_554
Si1 Eu1 3.4106(8) 10_444
Si1 Y1 3.4106(8) 10_444
O1 Y2 2.357(2) 18_566
O1 Y1 2.425(3) 4_554
O1 Eu1 2.425(3) 4_554
O1 Y2 2.530(3) 19_556
O2 Y2 2.3855(19) 2_544
O2 Y2 2.3855(19) 19_556
O3 Si1 1.623(3) 3
