#------------------------------------------------------------------------------
#$Date: 2021-04-09 10:57:44 +0300 (Fri, 09 Apr 2021) $
#$Revision: 264007 $
#$URL: file:///home/coder/svn-repositories/cod/cif/1/56/15/1561597.cif $
#------------------------------------------------------------------------------
#
# This file is available in the Crystallography Open Database (COD),
# http://www.crystallography.net/
#
# All data on this site have been placed in the public domain by the
# contributors.
#
data_1561597
loop_
_publ_author_name
'Latshaw, Allison M.'
'Yeon, Jeongho'
'Smith, Mark D.'
'zur Loye, Hans-Conrad'
_publ_section_title
;
 Synthesis, structure, and polymorphism of A3LnSi2O7 (A=Na, K; Ln=Sm, Ho,
 Yb)
;
_journal_name_full               'Journal of Solid State Chemistry'
_journal_page_first              100
_journal_page_last               106
_journal_paper_doi               10.1016/j.jssc.2015.12.013
_journal_volume                  235
_journal_year                    2016
_chemical_formula_moiety         'Na3 O7 Si2 Yb'
_chemical_formula_sum            'Na3 O7 Si2 Yb'
_chemical_formula_weight         410.19
_space_group_crystal_system      trigonal
_space_group_IT_number           159
_space_group_name_Hall           'P 3 -2c'
_space_group_name_H-M_alt        'P 3 1 c'
_atom_sites_solution_hydrogens   .
_cell_angle_alpha                90
_cell_angle_beta                 90
_cell_angle_gamma                120
_cell_formula_units_Z            18
_cell_length_a                   16.2081(2)
_cell_length_b                   16.2081(2)
_cell_length_c                   13.7077(4)
_cell_measurement_reflns_used    8934
_cell_measurement_temperature    296(2)
_cell_measurement_theta_max      35.270
_cell_measurement_theta_min      2.972
_cell_volume                     3118.60(11)
_computing_cell_refinement       'SAINT-Plus Version 6.45 (Bruker, 2001)'
_computing_data_collection       'SMART Version 5.631 (Bruker, 2001)'
_computing_data_reduction        'SAINT-Plus Version 6.45 (Bruker, 2001)'
_computing_molecular_graphics    various
_computing_publication_material  various
_computing_structure_refinement  'SHELXL-2014 (Sheldrick, 2014)'
_computing_structure_solution    'SHELXS97 (Sheldrick, 2008)'
_diffrn_ambient_temperature      296(2)
_diffrn_measured_fraction_theta_full 1.000
_diffrn_measured_fraction_theta_max 1.000
_diffrn_measurement_device_type  'Bruker SMART APEX CCD diffractometer'
_diffrn_measurement_method       'omega and phi scans'
_diffrn_radiation_type           MoK\a
_diffrn_radiation_wavelength     0.71073
_diffrn_reflns_av_R_equivalents  0.0476
_diffrn_reflns_av_unetI/netI     0.0276
_diffrn_reflns_Laue_measured_fraction_full 1.000
_diffrn_reflns_Laue_measured_fraction_max 1.000
_diffrn_reflns_limit_h_max       26
_diffrn_reflns_limit_h_min       -26
_diffrn_reflns_limit_k_max       25
_diffrn_reflns_limit_k_min       -26
_diffrn_reflns_limit_l_max       22
_diffrn_reflns_limit_l_min       -22
_diffrn_reflns_number            86609
_diffrn_reflns_point_group_measured_fraction_full 1.000
_diffrn_reflns_point_group_measured_fraction_max 1.000
_diffrn_reflns_theta_full        25.242
_diffrn_reflns_theta_max         35.270
_diffrn_reflns_theta_min         1.451
_diffrn_source                   'sealed tube'
_exptl_absorpt_coefficient_mu    14.023
_exptl_absorpt_correction_T_max  1.0000
_exptl_absorpt_correction_T_min  0.4973
_exptl_absorpt_correction_type   multi-scan
_exptl_absorpt_process_details   'SADABS Version 2.05 (Bruker, 2001)'
_exptl_crystal_colour            colorless
_exptl_crystal_density_diffrn    3.931
_exptl_crystal_description       'hexagonal plate'
_exptl_crystal_F_000             3366
_exptl_crystal_size_max          0.200
_exptl_crystal_size_mid          0.160
_exptl_crystal_size_min          0.050
_refine_diff_density_max         1.537
_refine_diff_density_min         -2.156
_refine_diff_density_rms         0.222
_refine_ls_abs_structure_details
; 
 Refined as an inversion twin. 
;
_refine_ls_extinction_coef       0.000307(17)
_refine_ls_extinction_expression Fc^*^=kFc[1+0.001xFc²λ³/sin(2θ)]^-1/4^
_refine_ls_extinction_method     SHELXL
_refine_ls_goodness_of_fit_ref   1.069
_refine_ls_hydrogen_treatment    undef
_refine_ls_matrix_type           full
_refine_ls_number_parameters     356
_refine_ls_number_reflns         9324
_refine_ls_number_restraints     1
_refine_ls_restrained_S_all      1.068
_refine_ls_R_factor_all          0.0256
_refine_ls_R_factor_gt           0.0241
_refine_ls_shift/su_max          0.001
_refine_ls_shift/su_mean         0.000
_refine_ls_structure_factor_coef Fsqd
_refine_ls_weighting_details
'w=1/[σ²(Fo²)+(0.0216P)²+3.6719P] where P=(Fo²+2Fc²)/3'
_refine_ls_weighting_scheme      calc
_refine_ls_wR_factor_gt          0.0530
_refine_ls_wR_factor_ref         0.0536
_reflns_Friedel_coverage         0.995
_reflns_Friedel_fraction_full    1.000
_reflns_Friedel_fraction_max     1.000
_reflns_number_gt                9067
_reflns_number_total             9324
_reflns_threshold_expression     'I > 2σ(I)'
_cod_data_source_file            mmc4.cif
_cod_data_source_block           Na3YbSi2O7
_cod_original_cell_volume        3118.60(12)
_cod_database_code               1561597
_shelx_space_group_comment
; 
The symmetry employed for this shelxl refinement is uniquely defined 
by the following loop, which should always be used as a source of 
symmetry information in preference to the above space-group names. 
They are only intended as comments. 
;
_shelx_estimated_absorpt_t_min   0.166
_shelx_estimated_absorpt_t_max   0.541
loop_
_space_group_symop_operation_xyz
'x, y, z'
'-y, x-y, z'
'-x+y, -x, z'
'y, x, z+1/2'
'x-y, -y, z+1/2'
'-x, -x+y, z+1/2'
loop_
_atom_site_label
_atom_site_type_symbol
_atom_site_fract_x
_atom_site_fract_y
_atom_site_fract_z
_atom_site_U_iso_or_equiv
_atom_site_adp_type
_atom_site_occupancy
_atom_site_site_symmetry_order
_atom_site_calc_flag
_atom_site_refinement_flags_posn
_atom_site_refinement_flags_adp
_atom_site_refinement_flags_occupancy
_atom_site_disorder_assembly
_atom_site_disorder_group
Yb1 Yb 0.00732(2) 0.32807(2) 0.00031(5) 0.00708(9) Uani 1 1 d . . . . .
Yb2 Yb 0.33967(2) 0.34504(3) 0.48557(4) 0.00655(9) Uani 1 1 d . . . . .
Yb3 Yb 0.3333 0.6667 0.25151(6) 0.00681(15) Uani 1 3 d S T P . .
Yb4 Yb 0.6667 0.3333 0.24541(6) 0.00617(13) Uani 1 3 d S T P . .
Yb5 Yb 0.0000 0.0000 0.25204(7) 0.00738(15) Uani 1 3 d S T P . .
Si1 Si 0.11962(16) 0.23132(16) 0.35149(19) 0.0068(4) Uani 1 1 d . . . . .
Si2 Si 0.12742(17) 0.22025(16) 0.13316(19) 0.0087(4) Uani 1 1 d . . . . .
Si3 Si 0.10399(15) 0.54374(15) 0.35358(18) 0.0063(4) Uani 1 1 d . . . . .
Si4 Si 0.10895(14) 0.54332(15) 0.13784(18) 0.0073(4) Uani 1 1 d . . . . .
Si5 Si 0.44319(15) 0.22219(15) 0.35383(19) 0.0062(4) Uani 1 1 d . . . . .
Si6 Si 0.44328(14) 0.21460(15) 0.13628(18) 0.0069(4) Uani 1 1 d . . . . .
Na1 Na 0.3418(4) 0.3388(3) 0.2320(10) 0.027(2) Uani 1 1 d . . . . .
Na2 Na 0.2306(3) 0.4539(3) 0.4026(3) 0.0191(8) Uani 1 1 d . . . . .
Na3 Na 0.5454(3) 0.1093(2) 0.4143(3) 0.0196(8) Uani 1 1 d . . . . .
Na4 Na 0.0032(3) 0.3264(3) 0.2496(10) 0.0130(12) Uani 1 1 d . . . . .
Na5 Na 0.2325(3) 0.1127(3) 0.0835(3) 0.0228(9) Uani 1 1 d . . . . .
Na6 Na 0.2157(3) 0.1043(3) 0.3987(3) 0.0172(8) Uani 1 1 d . . . . .
Na7 Na 0.5538(3) 0.1116(2) 0.0882(3) 0.0166(8) Uani 1 1 d . . . . .
Na8 Na 0.2415(3) 0.4414(2) 0.0890(3) 0.0179(7) Uani 1 1 d . . . . .
Na9 Na 0.3333 0.6667 0.4954(11) 0.0114(14) Uani 1 3 d S T P . .
Na10 Na 0.3333 0.6667 -0.0089(12) 0.035(2) Uani 1 3 d S T P . .
Na11 Na 0.0000 0.0000 0.0001(15) 0.025(2) Uani 1 3 d S T P . .
O1 O 0.1208(4) 0.2675(4) 0.2387(4) 0.0181(11) Uani 1 1 d . . . . .
O2 O 0.0404(4) 0.1190(3) 0.3584(4) 0.0107(9) Uani 1 1 d . . . . .
O3 O 0.2239(4) 0.2497(4) 0.3830(4) 0.0171(11) Uani 1 1 d . . . . .
O4 O 0.0920(4) 0.2971(4) 0.4141(4) 0.0151(10) Uani 1 1 d . . . . .
O5 O 0.0998(4) 0.1107(4) 0.1493(4) 0.0107(9) Uani 1 1 d . . . . .
O6 O 0.2362(4) 0.2815(4) 0.0987(4) 0.0185(11) Uani 1 1 d . . . . .
O7 O 0.0574(4) 0.2325(4) 0.0602(4) 0.0167(10) Uani 1 1 d . . . . .
O8 O 0.0660(3) 0.4925(3) 0.2462(3) 0.0112(9) Uani 1 1 d . . . . .
O9 O 0.0506(3) 0.4610(3) 0.4336(4) 0.0127(9) Uani 1 1 d . . . . .
O10 O 0.2176(3) 0.5868(4) 0.3607(4) 0.0121(9) Uani 1 1 d . . . . .
O11 O 0.0739(4) 0.6238(4) 0.3658(4) 0.0144(10) Uani 1 1 d . . . . .
O12 O 0.1114(4) 0.4613(4) 0.0733(4) 0.0139(10) Uani 1 1 d . . . . .
O13 O 0.2142(4) 0.6361(4) 0.1519(4) 0.0121(10) Uani 1 1 d . . . . .
O14 O 0.0367(4) 0.5757(4) 0.0934(4) 0.0121(9) Uani 1 1 d . . . . .
O15 O 0.4175(4) 0.2467(3) 0.2431(3) 0.0107(9) Uani 1 1 d . . . . .
O16 O 0.3671(4) 0.1124(3) 0.3785(4) 0.0135(10) Uani 1 1 d . . . . .
O17 O 0.5512(3) 0.2430(3) 0.3530(4) 0.0079(8) Uani 1 1 d . . . . .
O18 O 0.4339(4) 0.2960(4) 0.4276(4) 0.0134(9) Uani 1 1 d . . . . .
O19 O 0.3750(4) 0.1007(3) 0.1222(4) 0.0116(9) Uani 1 1 d . . . . .
O20 O 0.5541(3) 0.2449(3) 0.1347(4) 0.0107(9) Uani 1 1 d . . . . .
O21 O 0.4214(4) 0.2745(4) 0.0551(4) 0.0141(9) Uani 1 1 d . . . . .
loop_
_atom_type_symbol
_atom_type_description
_atom_type_scat_dispersion_real
_atom_type_scat_dispersion_imag
_atom_type_scat_source
Na Na 0.0362 0.0249 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
O O 0.0106 0.0060 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
Si Si 0.0817 0.0704 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
Yb Yb -0.3850 5.5486 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
loop_
_geom_angle_atom_site_label_1
_geom_angle_atom_site_label_2
_geom_angle_atom_site_label_3
_geom_angle
_geom_angle_site_symmetry_1
_geom_angle_site_symmetry_3
O4 Yb1 O9 89.13(19) 6_554 6_554
O4 Yb1 O12 174.0(2) 6_554 .
O9 Yb1 O12 86.8(2) 6_554 .
O4 Yb1 O7 85.6(2) 6_554 .
O9 Yb1 O7 174.74(19) 6_554 .
O12 Yb1 O7 98.5(2) . .
O4 Yb1 O16 87.93(19) 6_554 4_554
O9 Yb1 O16 90.79(19) 6_554 4_554
O12 Yb1 O16 87.72(19) . 4_554
O7 Yb1 O16 88.91(19) . 4_554
O4 Yb1 O19 88.42(19) 6_554 2
O9 Yb1 O19 93.35(18) 6_554 2
O12 Yb1 O19 96.21(19) . 2
O7 Yb1 O19 86.63(18) . 2
O16 Yb1 O19 174.44(19) 4_554 2
O4 Yb1 Na5 55.81(17) 6_554 2
O9 Yb1 Na5 125.73(15) 6_554 2
O12 Yb1 Na5 130.20(17) . 2
O7 Yb1 Na5 50.75(15) . 2
O16 Yb1 Na5 123.22(16) 4_554 2
O19 Yb1 Na5 51.23(16) 2 2
O4 Yb1 Na6 66.36(15) 6_554 4_554
O9 Yb1 Na6 129.74(16) 6_554 4_554
O12 Yb1 Na6 113.26(15) . 4_554
O7 Yb1 Na6 47.50(15) . 4_554
O16 Yb1 Na6 47.67(16) 4_554 4_554
O19 Yb1 Na6 126.85(15) 2 4_554
Na5 Yb1 Na6 76.54(10) 2 4_554
O4 Yb1 Na3 122.26(17) 6_554 4_554
O9 Yb1 Na3 47.96(15) 6_554 4_554
O12 Yb1 Na3 51.83(16) . 4_554
O7 Yb1 Na3 135.70(14) . 4_554
O16 Yb1 Na3 61.56(16) 4_554 4_554
O19 Yb1 Na3 124.00(15) 2 4_554
Na5 Yb1 Na3 173.43(9) 2 4_554
Na6 Yb1 Na3 108.83(10) 4_554 4_554
O4 Yb1 Na4 122.15(16) 6_554 .
O9 Yb1 Na4 114.32(15) 6_554 .
O12 Yb1 Na4 63.69(16) . .
O7 Yb1 Na4 68.88(16) . .
O16 Yb1 Na4 139.20(15) 4_554 .
O19 Yb1 Na4 41.27(15) 2 .
Na5 Yb1 Na4 68.30(12) 2 .
Na6 Yb1 Na4 115.88(11) 4_554 .
Na3 Yb1 Na4 111.47(10) 4_554 .
O4 Yb1 Na4 55.39(16) 6_554 6_554
O9 Yb1 Na4 64.09(15) 6_554 6_554
O12 Yb1 Na4 118.70(17) . 6_554
O7 Yb1 Na4 112.47(15) . 6_554
O16 Yb1 Na4 44.22(15) 4_554 6_554
O19 Yb1 Na4 135.31(15) 2 6_554
Na5 Yb1 Na4 109.90(11) 2 6_554
Na6 Yb1 Na4 65.92(10) 4_554 6_554
Na3 Yb1 Na4 69.96(12) 4_554 6_554
Na4 Yb1 Na4 176.565(16) . 6_554
O4 Yb1 Na7 108.71(15) 6_554 2
O9 Yb1 Na7 45.46(15) 6_554 2
O12 Yb1 Na7 71.29(14) . 2
O7 Yb1 Na7 136.89(16) . 2
O16 Yb1 Na7 130.72(16) 4_554 2
O19 Yb1 Na7 54.59(14) 2 2
Na5 Yb1 Na7 103.57(9) 2 2
Na6 Yb1 Na7 174.12(12) 4_554 2
Na3 Yb1 Na7 70.68(9) 4_554 2
Na4 Yb1 Na7 69.20(10) . 2
Na4 Yb1 Na7 108.85(11) 6_554 2
O6 Yb2 O18 93.6(2) 4 .
O6 Yb2 O21 90.7(2) 4 4
O18 Yb2 O21 167.4(2) . 4
O6 Yb2 O11 171.3(2) 4 2_665
O18 Yb2 O11 92.5(2) . 2_665
O21 Yb2 O11 84.71(19) 4 2_665
O6 Yb2 O3 90.8(2) 4 .
O18 Yb2 O3 91.01(19) . .
O21 Yb2 O3 100.82(19) 4 .
O11 Yb2 O3 82.8(2) 2_665 .
O6 Yb2 O14 84.0(2) 4 5_665
O18 Yb2 O14 83.00(18) . 5_665
O21 Yb2 O14 85.63(19) 4 5_665
O11 Yb2 O14 102.91(19) 2_665 5_665
O3 Yb2 O14 171.82(18) . 5_665
O6 Yb2 Na8 52.38(17) 4 4
O18 Yb2 Na8 48.53(16) . 4
O21 Yb2 Na8 128.16(15) 4 4
O11 Yb2 Na8 135.81(16) 2_665 4
O3 Yb2 Na8 112.92(15) . 4
O14 Yb2 Na8 58.90(14) 5_665 4
O6 Yb2 Na2 123.64(17) 4 .
O18 Yb2 Na2 137.19(16) . .
O21 Yb2 Na2 46.06(15) 4 .
O11 Yb2 Na2 48.47(16) 2_665 .
O3 Yb2 Na2 70.12(15) . .
O14 Yb2 Na2 118.04(15) 5_665 .
Na8 Yb2 Na2 174.19(11) 4 .
O6 Yb2 Na3 124.16(17) 4 3_665
O18 Yb2 Na3 46.21(15) . 3_665
O21 Yb2 Na3 122.29(16) 4 3_665
O11 Yb2 Na3 64.44(16) 2_665 3_665
O3 Yb2 Na3 120.35(17) . 3_665
O14 Yb2 Na3 58.62(15) 5_665 3_665
Na8 Yb2 Na3 72.33(8) 4 3_665
Na2 Yb2 Na3 110.79(10) . 3_665
O6 Yb2 Na7 109.33(17) 4 6_665
O18 Yb2 Na7 115.97(15) . 6_665
O21 Yb2 Na7 51.44(15) 4 6_665
O11 Yb2 Na7 73.39(15) 2_665 6_665
O3 Yb2 Na7 144.18(15) . 6_665
O14 Yb2 Na7 43.99(15) 5_665 6_665
Na8 Yb2 Na7 102.77(9) 4 6_665
Na2 Yb2 Na7 74.06(9) . 6_665
Na3 Yb2 Na7 72.75(9) 3_665 6_665
O6 Yb2 Na1 43.82(18) 4 4
O18 Yb2 Na1 110.78(16) . 4
O21 Yb2 Na1 64.98(15) 4 4
O11 Yb2 Na1 138.41(16) 2_665 4
O3 Yb2 Na1 128.54(17) . 4
O14 Yb2 Na1 49.82(15) 5_665 4
Na8 Yb2 Na1 63.25(11) 4 4
Na2 Yb2 Na1 110.94(11) . 4
Na3 Yb2 Na1 107.44(11) 3_665 4
Na7 Yb2 Na1 65.55(11) 6_665 4
O6 Yb2 Na5 51.73(17) 4 4
O18 Yb2 Na5 134.36(15) . 4
O21 Yb2 Na5 56.39(16) 4 4
O11 Yb2 Na5 119.79(16) 2_665 4
O3 Yb2 Na5 64.84(17) . 4
O14 Yb2 Na5 115.90(15) 5_665 4
Na8 Yb2 Na5 103.98(10) 4 4
Na2 Yb2 Na5 72.52(10) . 4
Na3 Yb2 Na5 174.37(12) 3_665 4
Na7 Yb2 Na5 104.39(9) 6_665 4
Na1 Yb2 Na5 66.94(11) 4 4
O13 Yb3 O13 85.8(2) . 3_565
O13 Yb3 O13 85.8(2) . 2_665
O13 Yb3 O13 85.8(2) 3_565 2_665
O13 Yb3 O10 84.10(19) . .
O13 Yb3 O10 155.40(19) 3_565 .
O13 Yb3 O10 115.66(19) 2_665 .
O13 Yb3 O10 115.66(19) . 3_565
O13 Yb3 O10 84.10(19) 3_565 3_565
O13 Yb3 O10 155.40(19) 2_665 3_565
O10 Yb3 O10 80.2(2) . 3_565
O13 Yb3 O10 155.40(19) . 2_665
O13 Yb3 O10 115.66(19) 3_565 2_665
O13 Yb3 O10 84.10(19) 2_665 2_665
O10 Yb3 O10 80.2(2) . 2_665
O10 Yb3 O10 80.2(2) 3_565 2_665
O13 Yb3 Na9 128.15(14) . .
O13 Yb3 Na9 128.15(14) 3_565 .
O13 Yb3 Na9 128.15(14) 2_665 .
O10 Yb3 Na9 48.02(13) . .
O10 Yb3 Na9 48.02(13) 3_565 .
O10 Yb3 Na9 48.02(13) 2_665 .
O13 Yb3 Si3 63.92(14) . .
O13 Yb3 Si3 141.51(14) 3_565 .
O13 Yb3 Si3 113.27(14) 2_665 .
O10 Yb3 Si3 20.28(14) . .
O10 Yb3 Si3 88.12(15) 3_565 .
O10 Yb3 Si3 99.88(15) 2_665 .
Na9 Yb3 Si3 66.53(4) . .
O13 Yb3 Si3 113.27(14) . 3_565
O13 Yb3 Si3 63.92(14) 3_565 3_565
O13 Yb3 Si3 141.51(14) 2_665 3_565
O10 Yb3 Si3 99.89(15) . 3_565
O10 Yb3 Si3 20.28(14) 3_565 3_565
O10 Yb3 Si3 88.12(15) 2_665 3_565
Na9 Yb3 Si3 66.53(4) . 3_565
Si3 Yb3 Si3 105.19(5) . 3_565
O13 Yb3 Si3 141.51(14) . 2_665
O13 Yb3 Si3 113.27(14) 3_565 2_665
O13 Yb3 Si3 63.92(14) 2_665 2_665
O10 Yb3 Si3 88.12(15) . 2_665
O10 Yb3 Si3 99.88(15) 3_565 2_665
O10 Yb3 Si3 20.28(14) 2_665 2_665
Na9 Yb3 Si3 66.53(4) . 2_665
Si3 Yb3 Si3 105.19(5) . 2_665
Si3 Yb3 Si3 105.19(5) 3_565 2_665
O13 Yb3 Si4 82.02(15) . 3_565
O13 Yb3 Si4 19.90(14) 3_565 3_565
O13 Yb3 Si4 104.98(15) 2_665 3_565
O10 Yb3 Si4 135.75(15) . 3_565
O10 Yb3 Si4 68.77(13) 3_565 3_565
O10 Yb3 Si4 122.30(15) 2_665 3_565
Na9 Yb3 Si4 116.29(4) . 3_565
Si3 Yb3 Si4 125.19(5) . 3_565
Si3 Yb3 Si4 49.77(5) 3_565 3_565
Si3 Yb3 Si4 126.78(5) 2_665 3_565
O13 Yb3 Si4 104.98(15) . 2_665
O13 Yb3 Si4 82.02(15) 3_565 2_665
O13 Yb3 Si4 19.90(14) 2_665 2_665
O10 Yb3 Si4 122.30(14) . 2_665
O10 Yb3 Si4 135.74(15) 3_565 2_665
O10 Yb3 Si4 68.77(13) 2_665 2_665
Na9 Yb3 Si4 116.29(4) . 2_665
Si3 Yb3 Si4 126.78(5) . 2_665
Si3 Yb3 Si4 125.19(5) 3_565 2_665
Si3 Yb3 Si4 49.77(5) 2_665 2_665
Si4 Yb3 Si4 101.88(5) 3_565 2_665
O20 Yb4 O20 79.5(2) 2_655 3_665
O20 Yb4 O20 79.5(2) 2_655 .
O20 Yb4 O20 79.5(2) 3_665 .
O20 Yb4 O17 83.24(18) 2_655 2_655
O20 Yb4 O17 136.23(18) 3_665 2_655
O20 Yb4 O17 135.93(18) . 2_655
O20 Yb4 O17 135.93(18) 2_655 3_665
O20 Yb4 O17 83.24(18) 3_665 3_665
O20 Yb4 O17 136.23(18) . 3_665
O17 Yb4 O17 81.8(2) 2_655 3_665
O20 Yb4 O17 136.23(18) 2_655 .
O20 Yb4 O17 135.93(18) 3_665 .
O20 Yb4 O17 83.24(18) . .
O17 Yb4 O17 81.8(2) 2_655 .
O17 Yb4 O17 81.8(2) 3_665 .
O20 Yb4 Na10 132.39(13) 2_655 4
O20 Yb4 Na10 132.38(13) 3_665 4
O20 Yb4 Na10 132.38(13) . 4
O17 Yb4 Na10 49.14(13) 2_655 4
O17 Yb4 Na10 49.14(13) 3_665 4
O17 Yb4 Na10 49.14(13) . 4
O20 Yb4 Na9 47.62(13) 2_655 4_554
O20 Yb4 Na9 47.61(13) 3_665 4_554
O20 Yb4 Na9 47.62(13) . 4_554
O17 Yb4 Na9 130.86(13) 2_655 4_554
O17 Yb4 Na9 130.86(13) 3_665 4_554
O17 Yb4 Na9 130.86(13) . 4_554
Na10 Yb4 Na9 180.0 4 4_554
O20 Yb4 Si5 142.00(14) 2_655 .
O20 Yb4 Si5 115.00(13) 3_665 .
O20 Yb4 Si5 69.84(13) . .
O17 Yb4 Si5 103.27(14) 2_655 .
O17 Yb4 Si5 81.93(13) 3_665 .
O17 Yb4 Si5 21.66(13) . .
Na10 Yb4 Si5 64.65(5) 4 .
Na9 Yb4 Si5 115.35(5) 4_554 .
O20 Yb4 Si5 69.84(13) 2_655 2_655
O20 Yb4 Si5 142.00(14) 3_665 2_655
O20 Yb4 Si5 115.00(13) . 2_655
O17 Yb4 Si5 21.66(13) 2_655 2_655
O17 Yb4 Si5 103.27(14) 3_665 2_655
O17 Yb4 Si5 81.93(13) . 2_655
Na10 Yb4 Si5 64.65(5) 4 2_655
Na9 Yb4 Si5 115.35(5) 4_554 2_655
Si5 Yb4 Si5 103.00(5) . 2_655
O20 Yb4 Si5 115.00(13) 2_655 3_665
O20 Yb4 Si5 69.84(13) 3_665 3_665
O20 Yb4 Si5 142.00(13) . 3_665
O17 Yb4 Si5 81.93(13) 2_655 3_665
O17 Yb4 Si5 21.66(13) 3_665 3_665
O17 Yb4 Si5 103.27(14) . 3_665
Na10 Yb4 Si5 64.65(5) 4 3_665
Na9 Yb4 Si5 115.35(5) 4_554 3_665
Si5 Yb4 Si5 103.00(5) . 3_665
Si5 Yb4 Si5 103.00(5) 2_655 3_665
O20 Yb4 Si6 21.49(13) 2_655 2_655
O20 Yb4 Si6 101.00(14) 3_665 2_655
O20 Yb4 Si6 82.49(14) . 2_655
O17 Yb4 Si6 67.98(14) 2_655 2_655
O17 Yb4 Si6 140.55(13) 3_665 2_655
O17 Yb4 Si6 116.57(13) . 2_655
Na10 Yb4 Si6 115.49(5) 4 2_655
Na9 Yb4 Si6 64.51(5) 4_554 2_655
Si5 Yb4 Si6 128.29(5) . 2_655
Si5 Yb4 Si6 50.89(5) 2_655 2_655
Si5 Yb4 Si6 124.33(5) 3_665 2_655
O5 Yb5 O5 84.0(2) 2 3
O5 Yb5 O5 84.0(2) 2 .
O5 Yb5 O5 84.0(2) 3 .
O5 Yb5 O2 111.1(2) 2 .
O5 Yb5 O2 161.13(19) 3 .
O5 Yb5 O2 86.30(19) . .
O5 Yb5 O2 161.13(19) 2 3
O5 Yb5 O2 86.30(19) 3 3
O5 Yb5 O2 111.1(2) . 3
O2 Yb5 O2 82.2(2) . 3
O5 Yb5 O2 86.30(19) 2 2
O5 Yb5 O2 111.1(2) 3 2
O5 Yb5 O2 161.13(19) . 2
O2 Yb5 O2 82.2(2) . 2
O2 Yb5 O2 82.2(2) 3 2
O5 Yb5 Na11 129.43(15) 2 4
O5 Yb5 Na11 129.43(15) 3 4
O5 Yb5 Na11 129.43(15) . 4
O2 Yb5 Na11 49.36(13) . 4
O2 Yb5 Na11 49.36(13) 3 4
O2 Yb5 Na11 49.36(13) 2 4
O5 Yb5 Na11 50.57(15) 2 .
O5 Yb5 Na11 50.57(15) 3 .
O5 Yb5 Na11 50.57(15) . .
O2 Yb5 Na11 130.64(13) . .
O2 Yb5 Na11 130.64(13) 3 .
O2 Yb5 Na11 130.64(13) 2 .
Na11 Yb5 Na11 180.0 4 .
O5 Yb5 Si2 20.08(14) 2 2
O5 Yb5 Si2 80.07(14) 3 2
O5 Yb5 Si2 103.07(15) . 2
O2 Yb5 Si2 117.98(14) . 2
O2 Yb5 Si2 141.56(14) 3 2
O2 Yb5 Si2 69.87(13) 2 2
Na11 Yb5 Si2 117.70(5) 4 2
Na11 Yb5 Si2 62.30(5) . 2
O5 Yb5 Si2 103.07(15) 2 3
O5 Yb5 Si2 20.08(14) 3 3
O5 Yb5 Si2 80.07(14) . 3
O2 Yb5 Si2 141.56(14) . 3
O2 Yb5 Si2 69.87(13) 3 3
O2 Yb5 Si2 117.98(14) 2 3
Na11 Yb5 Si2 117.70(5) 4 3
Na11 Yb5 Si2 62.30(5) . 3
Si2 Yb5 Si2 100.13(6) 2 3
O5 Yb5 Si2 80.07(14) 2 .
O5 Yb5 Si2 103.07(15) 3 .
O5 Yb5 Si2 20.08(14) . .
O2 Yb5 Si2 69.87(13) . .
O2 Yb5 Si2 117.98(14) 3 .
O2 Yb5 Si2 141.56(14) 2 .
Na11 Yb5 Si2 117.70(5) 4 .
Na11 Yb5 Si2 62.30(5) . .
Si2 Yb5 Si2 100.13(6) 2 .
Si2 Yb5 Si2 100.13(6) 3 .
O5 Yb5 Si1 108.90(13) 2 .
O5 Yb5 Si1 145.07(14) 3 .
O5 Yb5 Si1 66.03(14) . .
O2 Yb5 Si1 20.38(13) . .
O2 Yb5 Si1 88.20(14) 3 .
O2 Yb5 Si1 102.27(15) 2 .
Na11 Yb5 Si1 67.23(5) 4 .
Na11 Yb5 Si1 112.77(5) . .
Si2 Yb5 Si1 122.49(5) 2 .
Si2 Yb5 Si1 129.57(5) 3 .
Si2 Yb5 Si1 50.62(5) . .
O4 Si1 O3 110.4(3) . .
O4 Si1 O2 112.9(3) . .
O3 Si1 O2 110.9(3) . .
O4 Si1 O1 102.9(3) . .
O3 Si1 O1 111.1(3) . .
O2 Si1 O1 108.4(3) . .
O4 Si1 Na5 55.7(2) . 4
O3 Si1 Na5 76.6(2) . 4
O2 Si1 Na5 86.4(2) . 4
O1 Si1 Na5 158.2(2) . 4
O4 Si1 Na2 47.0(2) . .
O3 Si1 Na2 77.8(2) . .
O2 Si1 Na2 159.2(2) . .
O1 Si1 Na2 84.5(2) . .
Na5 Si1 Na2 77.07(11) 4 .
O4 Si1 Na6 135.1(2) . .
O3 Si1 Na6 42.9(2) . .
O2 Si1 Na6 68.5(2) . .
O1 Si1 Na6 119.6(2) . .
Na5 Si1 Na6 80.33(11) 4 .
Na2 Si1 Na6 119.95(12) . .
O4 Si1 Na6 71.7(2) . 2
O3 Si1 Na6 144.7(2) . 2
O2 Si1 Na6 44.7(2) . 2
O1 Si1 Na6 102.3(2) . 2
Na5 Si1 Na6 76.69(12) 4 2
Na2 Si1 Na6 117.80(12) . 2
Na6 Si1 Na6 109.58(14) . 2
O4 Si1 Na4 59.8(3) . .
O3 Si1 Na4 144.9(2) . .
O2 Si1 Na4 103.5(2) . .
O1 Si1 Na4 48.9(3) . .
Na5 Si1 Na4 113.1(2) 4 .
Na2 Si1 Na4 72.27(14) . .
Na6 Si1 Na4 164.6(2) . .
Na6 Si1 Na4 68.25(14) 2 .
O4 Si1 Yb5 136.9(2) . .
O3 Si1 Yb5 105.5(2) . .
O2 Si1 Yb5 28.70(18) . .
O1 Si1 Yb5 85.3(2) . .
Na5 Si1 Yb5 113.00(10) 4 .
Na2 Si1 Yb5 169.81(10) . .
Na6 Si1 Yb5 65.19(7) . .
Na6 Si1 Yb5 65.13(8) 2 .
Na4 Si1 Yb5 101.27(15) . .
O4 Si1 Na1 118.6(2) . .
O3 Si1 Na1 47.1(3) . .
O2 Si1 Na1 128.4(2) . .
O1 Si1 Na1 64.0(3) . .
Na5 Si1 Na1 119.5(2) 4 .
Na2 Si1 Na1 71.65(13) . .
Na6 Si1 Na1 72.95(15) . .
Na6 Si1 Na1 163.6(2) 2 .
Na4 Si1 Na1 104.8(3) . .
Yb5 Si1 Na1 103.23(14) . .
O4 Si1 Yb2 85.4(2) . .
O3 Si1 Yb2 25.0(2) . .
O2 Si1 Yb2 124.8(2) . .
O1 Si1 Yb2 117.7(2) . .
Na5 Si1 Yb2 60.99(9) 4 .
Na2 Si1 Yb2 57.03(8) . .
Na6 Si1 Yb2 63.28(7) . .
Na6 Si1 Yb2 137.62(10) 2 .
Na4 Si1 Yb2 129.20(12) . .
Yb5 Si1 Yb2 128.36(6) . .
Na1 Si1 Yb2 58.5(2) . .
O7 Si2 O6 111.6(3) . .
O7 Si2 O5 113.5(3) . .
O6 Si2 O5 109.7(3) . .
O7 Si2 O1 105.9(3) . .
O6 Si2 O1 106.0(3) . .
O5 Si2 O1 109.9(3) . .
O7 Si2 Na5 124.3(2) . .
O6 Si2 Na5 62.2(2) . .
O5 Si2 Na5 48.1(2) . .
O1 Si2 Na5 129.6(2) . .
O7 Si2 Na8 77.8(2) . .
O6 Si2 Na8 53.3(2) . .
O5 Si2 Na8 163.0(2) . .
O1 Si2 Na8 77.3(2) . .
Na5 Si2 Na8 115.25(12) . .
O7 Si2 Na6 45.5(2) . 4_554
O6 Si2 Na6 78.5(2) . 4_554
O5 Si2 Na6 98.4(2) . 4_554
O1 Si2 Na6 147.2(2) . 4_554
Na5 Si2 Na6 81.77(13) . 4_554
Na8 Si2 Na6 80.27(11) . 4_554
O7 Si2 Na1 142.2(3) . .
O6 Si2 Na1 41.3(3) . .
O5 Si2 Na1 102.5(2) . .
O1 Si2 Na1 70.6(3) . .
Na5 Si2 Na1 72.52(14) . .
Na8 Si2 Na1 64.60(16) . .
Na6 Si2 Na1 119.8(3) 4_554 .
O7 Si2 Na5 39.8(2) . 2
O6 Si2 Na5 150.0(3) . 2
O5 Si2 Na5 83.1(2) . 2
O1 Si2 Na5 94.1(2) . 2
Na5 Si2 Na5 120.28(15) . 2
Na8 Si2 Na5 112.27(12) . 2
Na6 Si2 Na5 72.72(11) 4_554 2
Na1 Si2 Na5 164.7(2) . 2
O7 Si2 Yb5 108.9(2) . .
O6 Si2 Yb5 132.3(2) . .
O5 Si2 Yb5 28.14(19) . .
O1 Si2 Yb5 85.6(2) . .
Na5 Si2 Yb5 74.67(9) . .
Na8 Si2 Yb5 162.89(11) . .
Na6 Si2 Yb5 115.87(10) 4_554 .
Na1 Si2 Yb5 108.3(2) . .
Na5 Si2 Yb5 70.13(8) 2 .
O11 Si3 O9 110.4(3) . .
O11 Si3 O10 112.7(3) . .
O9 Si3 O10 110.0(3) . .
O11 Si3 O8 108.2(3) . .
O9 Si3 O8 106.2(3) . .
O10 Si3 O8 109.3(3) . .
O11 Si3 Na3 74.0(2) . 2
O9 Si3 Na3 50.6(2) . 2
O10 Si3 Na3 159.3(2) . 2
O8 Si3 Na3 85.7(2) . 2
O11 Si3 Na2 152.7(2) . .
O9 Si3 Na2 70.7(2) . .
O10 Si3 Na2 46.8(2) . .
O8 Si3 Na2 97.1(2) . .
Na3 Si3 Na2 119.07(13) 2 .
O11 Si3 Na7 82.8(2) . 4
O9 Si3 Na7 49.65(19) . 4
O10 Si3 Na7 84.9(2) . 4
O8 Si3 Na7 155.7(2) . 4
Na3 Si3 Na7 76.39(11) 2 4
Na2 Si3 Na7 77.94(11) . 4
O11 Si3 Na2 46.9(2) . 3_565
O9 Si3 Na2 124.6(2) . 3_565
O10 Si3 Na2 65.9(2) . 3_565
O8 Si3 Na2 128.0(2) . 3_565
Na3 Si3 Na2 116.53(12) 2 3_565
Na2 Si3 Na2 108.73(14) . 3_565
Na7 Si3 Na2 75.48(11) 4 3_565
O11 Si3 Na4 134.8(2) . .
O9 Si3 Na4 68.9(3) . .
O10 Si3 Na4 109.3(2) . .
O8 Si3 Na4 39.9(3) . .
Na3 Si3 Na4 72.82(15) 2 .
Na2 Si3 Na4 72.06(14) . .
Na7 Si3 Na4 117.5(2) 4 .
Na2 Si3 Na4 166.3(2) 3_565 .
O11 Si3 Yb3 104.2(2) . .
O9 Si3 Yb3 136.0(2) . .
O10 Si3 Yb3 28.76(19) . .
O8 Si3 Yb3 87.32(19) . .
Na3 Si3 Yb3 171.84(12) 2 .
Na2 Si3 Yb3 66.10(8) . .
Na7 Si3 Yb3 111.48(9) 4 .
Na2 Si3 Yb3 65.01(7) 3_565 .
Na4 Si3 Yb3 104.29(15) . .
O11 Si3 Yb2 27.28(19) . 3_565
O9 Si3 Yb2 84.2(2) . 3_565
O10 Si3 Yb2 117.5(2) . 3_565
O8 Si3 Yb2 124.9(2) . 3_565
Na3 Si3 Yb2 59.21(8) 2 3_565
Na2 Si3 Yb2 135.95(10) . 3_565
Na7 Si3 Yb2 58.42(8) 4 3_565
Na2 Si3 Yb2 57.50(7) 3_565 3_565
Na4 Si3 Yb2 131.68(12) . 3_565
Yb3 Si3 Yb2 122.37(6) . 3_565
O11 Si3 Na1 36.6(3) . 3_565
O9 Si3 Na1 124.0(3) . 3_565
O10 Si3 Na1 123.8(2) . 3_565
O8 Si3 Na1 71.7(3) . 3_565
Na3 Si3 Na1 73.77(16) 2 3_565
Na2 Si3 Na1 163.0(2) . 3_565
Na7 Si3 Na1 117.5(2) 4 3_565
Na2 Si3 Na1 71.17(14) 3_565 3_565
Na4 Si3 Na1 104.0(3) . 3_565
Yb3 Si3 Na1 99.95(16) . 3_565
Yb2 Si3 Na1 59.1(2) 3_565 3_565
O12 Si4 O14 112.3(3) . .
O12 Si4 O13 112.4(3) . .
O14 Si4 O13 109.8(3) . .
O12 Si4 O8 104.9(3) . .
O14 Si4 O8 107.6(3) . .
O13 Si4 O8 109.6(3) . .
O12 Si4 Na3 57.3(2) . 4_554
O14 Si4 Na3 67.6(2) . 4_554
O13 Si4 Na3 96.5(2) . 4_554
O8 Si4 Na3 153.1(2) . 4_554
O12 Si4 Na8 127.8(2) . 3_565
O14 Si4 Na8 64.5(2) . 3_565
O13 Si4 Na8 45.4(2) . 3_565
O8 Si4 Na8 126.3(2) . 3_565
Na3 Si4 Na8 77.00(12) 4_554 3_565
O12 Si4 Na7 86.7(2) . 2
O14 Si4 Na7 43.8(2) . 2
O13 Si4 Na7 153.3(2) . 2
O8 Si4 Na7 81.5(2) . 2
Na3 Si4 Na7 77.68(11) 4_554 2
Na8 Si4 Na7 108.27(11) 3_565 2
O12 Si4 Na8 37.1(2) . .
O14 Si4 Na8 145.6(2) . .
O13 Si4 Na8 81.1(2) . .
O8 Si4 Na8 98.4(2) . .
Na3 Si4 Na8 78.95(11) 4_554 .
Na8 Si4 Na8 116.55(13) 3_565 .
Na7 Si4 Na8 122.28(11) 2 .
O12 Si4 Na4 66.7(3) . .
O14 Si4 Na4 115.5(2) . .
O13 Si4 Na4 130.9(3) . .
O8 Si4 Na4 38.9(3) . .
Na3 Si4 Na4 117.3(2) 4_554 .
Na8 Si4 Na4 165.2(2) 3_565 .
Na7 Si4 Na4 73.02(14) 2 .
Na8 Si4 Na4 72.45(13) . .
O12 Si4 Na1 152.8(2) . 3_565
O14 Si4 Na1 45.8(3) . 3_565
O13 Si4 Na1 92.8(2) . 3_565
O8 Si4 Na1 74.4(3) . 3_565
Na3 Si4 Na1 111.6(2) 4_554 3_565
Na8 Si4 Na1 63.59(15) 3_565 3_565
Na7 Si4 Na1 66.21(14) 2 3_565
Na8 Si4 Na1 168.5(2) . 3_565
Na4 Si4 Na1 105.1(3) . 3_565
O12 Si4 Yb3 105.5(2) . .
O14 Si4 Yb3 133.7(2) . .
O13 Si4 Yb3 27.57(19) . .
O8 Si4 Yb3 86.79(18) . .
Na3 Si4 Yb3 116.16(10) 4_554 .
Na8 Si4 Yb3 71.45(8) 3_565 .
Na7 Si4 Yb3 164.99(11) 2 .
Na8 Si4 Yb3 68.60(7) . .
Na4 Si4 Yb3 103.34(16) . .
Na1 Si4 Yb3 101.64(16) 3_565 .
O12 Si4 Yb1 24.90(18) . .
O14 Si4 Yb1 93.6(2) . .
O13 Si4 Yb1 136.6(2) . .
O8 Si4 Yb1 96.49(18) . .
Na3 Si4 Yb1 58.60(8) 4_554 .
Na8 Si4 Yb1 135.49(10) 3_565 .
Na7 Si4 Yb1 62.01(8) 2 .
Na8 Si4 Yb1 60.69(7) . .
Na4 Si4 Yb1 58.7(2) . .
Na1 Si4 Yb1 128.21(13) 3_565 .
Yb3 Si4 Yb1 129.14(6) . .
O17 Si5 O16 112.6(3) . .
O17 Si5 O18 109.9(3) . .
O16 Si5 O18 112.2(3) . .
O17 Si5 O15 108.5(3) . .
O16 Si5 O15 107.9(3) . .
O18 Si5 O15 105.3(3) . .
O17 Si5 Na3 44.50(19) . .
O16 Si5 Na3 68.7(2) . .
O18 Si5 Na3 122.3(2) . .
O15 Si5 Na3 130.2(2) . .
O17 Si5 Na8 92.8(2) . 4
O16 Si5 Na8 81.9(2) . 4
O18 Si5 Na8 45.8(2) . 4
O15 Si5 Na8 149.8(2) . 4
Na3 Si5 Na8 79.97(12) . 4
O17 Si5 Na6 156.9(2) . .
O16 Si5 Na6 45.3(2) . .
O18 Si5 Na6 79.6(2) . .
O15 Si5 Na6 88.1(2) . .
Na3 Si5 Na6 112.47(12) . .
Na8 Si5 Na6 78.84(10) 4 .
O17 Si5 Na3 78.70(19) . 3_665
O16 Si5 Na3 151.4(2) . 3_665
O18 Si5 Na3 40.7(2) . 3_665
O15 Si5 Na3 91.9(2) . 3_665
Na3 Si5 Na3 114.03(13) . 3_665
Na8 Si5 Na3 71.06(10) 4 3_665
Na6 Si5 Na3 117.68(12) . 3_665
O17 Si5 Yb4 31.16(18) . .
O16 Si5 Yb4 133.3(2) . .
O18 Si5 Yb4 109.9(2) . .
O15 Si5 Yb4 78.90(19) . .
Na3 Si5 Yb4 72.37(8) . .
Na8 Si5 Yb4 115.67(10) 4 .
Na6 Si5 Yb4 165.49(10) . .
Na3 Si5 Yb4 69.69(7) 3_665 .
O17 Si5 Na4 101.3(2) . 3
O16 Si5 Na4 37.8(3) . 3
O18 Si5 Na4 144.9(2) . 3
O15 Si5 Na4 78.6(3) . 3
Na3 Si5 Na4 71.09(15) . 3
Na8 Si5 Na4 118.9(2) 4 3
Na6 Si5 Na4 65.54(14) . 3
Na3 Si5 Na4 169.9(2) 3_665 3
Yb4 Si5 Na4 105.07(15) . 3
O17 Si5 Na1 129.9(2) . .
O16 Si5 Na1 113.0(2) . .
O18 Si5 Na1 70.0(3) . .
O15 Si5 Na1 36.5(3) . .
Na3 Si5 Na1 166.7(2) . .
Na8 Si5 Na1 113.3(2) 4 .
Na6 Si5 Na1 72.89(14) . .
Na3 Si5 Na1 71.30(14) 3_665 .
Yb4 Si5 Na1 99.55(16) . .
Na4 Si5 Na1 101.8(3) 3 .
O20 Si6 O19 111.6(3) . .
O20 Si6 O21 110.6(3) . .
O19 Si6 O21 111.7(3) . .
O20 Si6 O15 109.3(3) . .
O19 Si6 O15 108.9(3) . .
O21 Si6 O15 104.5(3) . .
O20 Si6 Na5 160.2(2) . .
O19 Si6 Na5 54.0(2) . .
O21 Si6 Na5 69.0(2) . .
O15 Si6 Na5 89.4(2) . .
O20 Si6 Na7 45.31(19) . .
O19 Si6 Na7 66.8(2) . .
O21 Si6 Na7 122.5(2) . .
O15 Si6 Na7 131.3(2) . .
Na5 Si6 Na7 117.10(13) . .
O20 Si6 Na2 87.4(2) . 4_554
O19 Si6 Na2 87.2(2) . 4_554
O21 Si6 Na2 44.65(19) . 4_554
O15 Si6 Na2 149.1(2) . 4_554
Na5 Si6 Na2 78.89(12) . 4_554
Na7 Si6 Na2 78.91(12) . 4_554
O20 Si6 Na7 75.15(19) . 3_665
O19 Si6 Na7 160.4(2) . 3_665
O21 Si6 Na7 49.8(2) . 3_665
O15 Si6 Na7 84.7(2) . 3_665
Na5 Si6 Na7 114.07(12) . 3_665
Na7 Si6 Na7 115.09(13) . 3_665
Na2 Si6 Na7 74.52(11) 4_554 3_665
O20 Si6 Na1 128.0(2) . .
O19 Si6 Na1 117.3(2) . .
O21 Si6 Na1 66.5(3) . .
O15 Si6 Na1 38.5(3) . .
Na5 Si6 Na1 70.88(14) . .
Na7 Si6 Na1 169.1(2) . .
Na2 Si6 Na1 110.8(3) 4_554 .
Na7 Si6 Na1 64.77(15) 3_665 .
O20 Si6 Na4 107.0(2) . 3
O19 Si6 Na4 33.9(3) . 3
O21 Si6 Na4 137.9(3) . 3
O15 Si6 Na4 79.8(3) . 3
Na5 Si6 Na4 69.18(15) . 3
Na7 Si6 Na4 73.92(13) . 3
Na2 Si6 Na4 121.0(2) 4_554 3
Na7 Si6 Na4 164.2(2) 3_665 3
Na1 Si6 Na4 103.8(3) . 3
O20 Si6 Yb4 30.85(18) . .
O19 Si6 Yb4 127.6(2) . .
O21 Si6 Yb4 116.2(2) . .
O15 Si6 Yb4 78.71(18) . .
Na5 Si6 Yb4 167.86(11) . .
Na7 Si6 Yb4 70.36(8) . .
Na2 Si6 Yb4 112.69(10) 4_554 .
Na7 Si6 Yb4 67.68(7) 3_665 .
Na1 Si6 Yb4 100.52(16) . .
Na4 Si6 Yb4 105.81(16) 3 .
O6 Na1 O15 107.8(4) . .
O6 Na1 O11 136.8(3) . 2_665
O15 Na1 O11 114.9(5) . 2_665
O6 Na1 O14 74.1(4) . 2_665
O15 Na1 O14 107.4(4) . 2_665
O11 Na1 O14 98.5(2) 2_665 2_665
O6 Na1 O3 101.8(2) . .
O15 Na1 O3 93.7(4) . .
O11 Na1 O3 69.9(4) 2_665 .
O14 Na1 O3 158.8(3) 2_665 .
O6 Na1 Si2 26.72(14) . .
O15 Na1 Si2 112.7(2) . .
O11 Na1 Si2 121.6(3) 2_665 .
O14 Na1 Si2 97.7(4) 2_665 .
O3 Na1 Si2 75.26(17) . .
O6 Na1 Yb2 39.8(3) . 4_554
O15 Na1 Yb2 93.2(4) . 4_554
O11 Na1 Yb2 138.8(3) 2_665 4_554
O14 Na1 Yb2 42.3(2) 2_665 4_554
O3 Na1 Yb2 140.9(3) . 4_554
Si2 Na1 Yb2 66.6(2) . 4_554
O6 Na1 Si6 86.5(3) . .
O15 Na1 Si6 26.17(17) . .
O11 Na1 Si6 136.3(3) 2_665 .
O14 Na1 Si6 87.3(3) 2_665 .
O3 Na1 Si6 113.5(3) . .
Si2 Na1 Si6 100.1(2) . .
Yb2 Na1 Si6 67.0(2) 4_554 .
O6 Na1 Si4 91.6(4) . 2_665
O15 Na1 Si4 121.7(3) . 2_665
O11 Na1 Si4 71.88(17) 2_665 2_665
O14 Na1 Si4 26.79(12) 2_665 2_665
O3 Na1 Si4 136.2(3) . 2_665
Si2 Na1 Si4 108.5(3) . 2_665
Yb2 Na1 Si4 67.7(2) 4_554 2_665
Si6 Na1 Si4 108.8(3) . 2_665
O6 Na1 Na8 47.6(2) . .
O15 Na1 Na8 149.1(6) . .
O11 Na1 Na8 93.4(2) 2_665 .
O14 Na1 Na8 53.3(2) 2_665 .
O3 Na1 Na8 108.4(2) . .
Si2 Na1 Na8 55.71(16) . .
Yb2 Na1 Na8 56.0(2) 4_554 .
Si6 Na1 Na8 122.9(4) . .
Si4 Na1 Na8 53.55(16) 2_665 .
O6 Na1 Yb2 140.5(3) . .
O15 Na1 Yb2 88.3(4) . .
O11 Na1 Yb2 39.4(2) 2_665 .
O14 Na1 Yb2 136.2(3) 2_665 .
O3 Na1 Yb2 39.9(2) . .
Si2 Na1 Yb2 113.8(3) . .
Yb2 Na1 Yb2 178.22(16) 4_554 .
Si6 Na1 Yb2 114.4(3) . .
Si4 Na1 Yb2 110.6(2) 2_665 .
Na8 Na1 Yb2 122.6(2) . .
O6 Na1 Si5 127.2(2) . .
O15 Na1 Si5 24.92(19) . .
O11 Na1 Si5 92.6(4) 2_665 .
O14 Na1 Si5 124.4(2) 2_665 .
O3 Na1 Si5 75.0(3) . .
Si2 Na1 Si5 121.64(15) . .
Yb2 Na1 Si5 118.1(2) 4_554 .
Si6 Na1 Si5 51.09(9) . .
Si4 Na1 Si5 127.57(17) 2_665 .
Na8 Na1 Si5 173.9(4) . .
Yb2 Na1 Si5 63.4(2) . .
O10 Na2 O21 127.0(2) . 4
O10 Na2 O4 121.4(2) . .
O21 Na2 O4 86.1(2) 4 .
O10 Na2 O11 120.4(2) . 2_665
O21 Na2 O11 77.0(2) 4 2_665
O4 Na2 O11 112.9(2) . 2_665
O10 Na2 O10 64.5(2) . 2_665
O21 Na2 O10 97.0(2) 4 2_665
O4 Na2 O10 169.4(2) . 2_665
O11 Na2 O10 58.37(17) 2_665 2_665
O10 Na2 O9 57.52(17) . .
O21 Na2 O9 106.9(2) 4 .
O4 Na2 O9 67.70(17) . .
O11 Na2 O9 176.1(2) 2_665 .
O10 Na2 O9 120.52(18) 2_665 .
O10 Na2 Si3 30.16(13) . .
O21 Na2 Si3 129.63(19) 4 .
O4 Na2 Si3 91.26(17) . .
O11 Na2 Si3 146.54(19) 2_665 .
O10 Na2 Si3 94.47(14) 2_665 .
O9 Na2 Si3 30.34(10) . .
O10 Na2 Si1 136.5(2) . .
O21 Na2 Si1 90.29(17) 4 .
O4 Na2 Si1 28.95(13) . .
O11 Na2 Si1 86.13(16) 2_665 .
O10 Na2 Si1 140.58(17) 2_665 .
O9 Na2 Si1 93.70(15) . .
Si3 Na2 Si1 110.35(14) . .
O10 Na2 Si6 104.60(19) . 4
O21 Na2 Si6 29.12(12) 4 4
O4 Na2 Si6 82.57(17) . 4
O11 Na2 Si6 104.95(19) 2_665 4
O10 Na2 Si6 105.05(16) 2_665 4
O9 Na2 Si6 78.89(14) . 4
Si3 Na2 Si6 100.66(12) . 4
Si1 Na2 Si6 99.98(11) . 4
O10 Na2 Si3 93.26(17) . 2_665
O21 Na2 Si3 85.22(18) 4 2_665
O4 Na2 Si3 141.56(18) . 2_665
O11 Na2 Si3 28.72(13) 2_665 2_665
O10 Na2 Si3 29.70(11) 2_665 2_665
O9 Na2 Si3 150.19(16) . 2_665
Si3 Na2 Si3 122.46(13) . 2_665
Si1 Na2 Si3 113.77(13) . 2_665
Si6 Na2 Si3 105.97(13) 4 2_665
O10 Na2 Na9 49.6(2) . .
O21 Na2 Na9 80.7(3) 4 .
O4 Na2 Na9 143.7(3) . .
O11 Na2 Na9 96.82(18) 2_665 .
O10 Na2 Na9 46.9(2) 2_665 .
O9 Na2 Na9 84.03(13) . .
Si3 Na2 Na9 72.35(12) . .
Si1 Na2 Na9 169.5(3) . .
Si6 Na2 Na9 69.6(3) 4 .
Si3 Na2 Na9 70.93(13) 2_665 .
O10 Na2 Yb2 155.0(2) . .
O21 Na2 Yb2 42.53(12) 4 .
O4 Na2 Yb2 83.04(15) . .
O11 Na2 Yb2 42.91(13) 2_665 .
O10 Na2 Yb2 92.39(14) 2_665 .
O9 Na2 Yb2 140.34(16) . .
Si3 Na2 Yb2 170.41(15) . .
Si1 Na2 Yb2 67.56(8) . .
Si6 Na2 Yb2 71.02(9) 4 .
Si3 Na2 Yb2 65.64(9) 2_665 .
Na9 Na2 Yb2 108.02(18) . .
O17 Na3 O18 108.4(2) . 2_655
O17 Na3 O9 129.8(2) . 3
O18 Na3 O9 120.5(2) 2_655 3
O17 Na3 O12 94.0(2) . 4
O18 Na3 O12 117.3(2) 2_655 4
O9 Na3 O12 73.88(19) 3 4
O17 Na3 O14 140.4(2) . 4
O18 Na3 O14 67.92(19) 2_655 4
O9 Na3 O14 73.58(18) 3 4
O12 Na3 O14 58.85(17) 4 4
O17 Na3 O16 59.95(18) . .
O18 Na3 O16 168.3(2) 2_655 .
O9 Na3 O16 70.71(18) 3 .
O12 Na3 O16 67.21(17) 4 .
O14 Na3 O16 121.2(2) 4 .
O17 Na3 Si4 111.43(19) . 4
O18 Na3 Si4 86.17(19) 2_655 4
O9 Na3 Si4 83.47(17) 3 4
O12 Na3 Si4 31.78(12) 4 4
O14 Na3 Si4 31.53(12) 4 4
O16 Na3 Si4 98.99(16) . 4
O17 Na3 Si3 134.1(2) . 3
O18 Na3 Si3 100.24(17) 2_655 3
O9 Na3 Si3 30.80(12) 3 3
O12 Na3 Si3 103.89(17) 4 3
O14 Na3 Si3 83.40(14) 4 3
O16 Na3 Si3 88.56(15) . 3
Si4 Na3 Si3 105.45(13) 4 3
O17 Na3 Si5 29.59(13) . .
O18 Na3 Si5 137.88(18) 2_655 .
O9 Na3 Si5 101.23(17) 3 .
O12 Na3 Si5 77.22(15) 4 .
O14 Na3 Si5 135.68(18) 4 .
O16 Na3 Si5 30.59(11) . .
Si4 Na3 Si5 104.92(13) 4 .
Si3 Na3 Si5 114.89(14) 3 .
O17 Na3 Yb1 97.78(17) . 4
O18 Na3 Yb1 148.8(2) 2_655 4
O9 Na3 Yb1 41.77(12) 3 4
O12 Na3 Yb1 42.26(12) 4 4
O14 Na3 Yb1 81.18(14) 4 4
O16 Na3 Yb1 41.75(11) . 4
Si4 Na3 Yb1 68.34(9) 4 4
Si3 Na3 Yb1 71.30(9) 3 4
Si5 Na3 Yb1 68.93(9) . 4
O17 Na3 Yb2 150.1(2) . 2_655
O18 Na3 Yb2 41.67(13) 2_655 2_655
O9 Na3 Yb2 79.52(14) 3 2_655
O12 Na3 Yb2 101.21(17) 4 2_655
O14 Na3 Yb2 42.60(11) 4 2_655
O16 Na3 Yb2 149.96(16) . 2_655
Si4 Na3 Yb2 73.21(10) 4 2_655
Si3 Na3 Yb2 66.71(8) 3 2_655
Si5 Na3 Yb2 177.93(16) . 2_655
Yb1 Na3 Yb2 110.84(11) 4 2_655
O17 Na3 Na10 50.0(3) . 4
O18 Na3 Na10 76.79(15) 2_655 4
O9 Na3 Na10 149.0(3) 3 4
O12 Na3 Na10 75.3(3) 4 4
O14 Na3 Na10 92.8(3) 4 4
O16 Na3 Na10 94.79(14) . 4
Si4 Na3 Na10 71.6(3) 4 4
Si3 Na3 Na10 175.8(3) 3 4
Si5 Na3 Na10 69.02(14) . 4
Yb1 Na3 Na10 109.73(19) 4 4
Yb2 Na3 Na10 109.35(17) 2_655 4
O19 Na4 O8 103.0(4) 2 .
O19 Na4 O16 97.5(2) 2 2
O8 Na4 O16 110.7(4) . 2
O19 Na4 O1 111.9(4) 2 .
O8 Na4 O1 117.0(3) . .
O16 Na4 O1 114.4(4) 2 .
O19 Na4 O4 152.9(2) 2 .
O8 Na4 O4 104.0(4) . .
O16 Na4 O4 71.0(4) 2 .
O1 Na4 O4 56.2(2) . .
O19 Na4 Si1 130.1(3) 2 .
O8 Na4 Si1 121.6(3) . .
O16 Na4 Si1 87.3(3) 2 .
O1 Na4 Si1 29.48(16) . .
O4 Na4 Si1 29.09(12) . .
O19 Na4 Si3 126.5(3) 2 .
O8 Na4 Si3 26.71(17) . .
O16 Na4 Si3 92.8(4) 2 .
O1 Na4 Si3 110.9(3) . .
O4 Na4 Si3 79.5(3) . .
Si1 Na4 Si3 102.6(3) . .
O19 Na4 Si4 86.3(3) 2 .
O8 Na4 Si4 26.51(17) . .
O16 Na4 Si4 134.1(3) 2 .
O1 Na4 Si4 106.1(3) . .
O4 Na4 Si4 119.6(2) . .
Si1 Na4 Si4 124.36(15) . .
Si3 Na4 Si4 51.76(8) . .
O19 Na4 Yb1 40.8(3) 2 .
O8 Na4 Yb1 88.6(4) . .
O16 Na4 Yb1 138.1(3) 2 .
O1 Na4 Yb1 85.9(3) . .
O4 Na4 Yb1 141.8(2) . .
Si1 Na4 Yb1 114.5(2) . .
Si3 Na4 Yb1 114.7(2) . .
Si4 Na4 Yb1 62.9(2) . .
O19 Na4 Si6 23.39(13) 2 2
O8 Na4 Si6 106.0(3) . 2
O16 Na4 Si6 74.75(17) 2 2
O1 Na4 Si6 126.5(3) . 2
O4 Na4 Si6 140.5(3) . 2
Si1 Na4 Si6 132.44(14) . 2
Si3 Na4 Si6 121.52(14) . 2
Si4 Na4 Si6 98.2(3) . 2
Yb1 Na4 Si6 64.1(2) . 2
O19 Na4 Yb1 137.7(3) 2 6
O8 Na4 Yb1 92.2(4) . 6
O16 Na4 Yb1 40.4(2) 2 6
O1 Na4 Yb1 94.9(3) . 6
O4 Na4 Yb1 39.2(2) . 6
Si1 Na4 Yb1 66.1(2) . 6
Si3 Na4 Yb1 66.2(2) . 6
Si4 Na4 Yb1 118.0(2) . 6
Yb1 Na4 Yb1 178.48(17) . 6
Si6 Na4 Yb1 114.4(2) 2 6
O19 Na4 Si5 74.44(17) 2 2
O8 Na4 Si5 108.5(3) . 2
O16 Na4 Si5 24.24(13) 2 2
O1 Na4 Si5 130.2(3) . 2
O4 Na4 Si5 95.0(3) . 2
Si1 Na4 Si5 107.7(3) . 2
Si3 Na4 Si5 100.4(3) . 2
Si4 Na4 Si5 123.71(14) . 2
Yb1 Na4 Si5 115.2(2) . 2
Si6 Na4 Si5 51.19(8) 2 2
Yb1 Na4 Si5 63.3(2) 6 2
O5 Na5 O7 102.0(2) . 3
O5 Na5 O19 144.4(3) . .
O7 Na5 O19 77.5(2) 3 .
O5 Na5 O4 140.0(3) . 4_554
O7 Na5 O4 72.14(19) 3 4_554
O19 Na5 O4 74.46(19) . 4_554
O5 Na5 O6 62.42(19) . .
O7 Na5 O6 161.6(2) 3 .
O19 Na5 O6 120.8(2) . .
O4 Na5 O6 112.7(2) 4_554 .
O5 Na5 O21 128.3(2) . .
O7 Na5 O21 129.5(2) 3 .
O19 Na5 O21 59.50(16) . .
O4 Na5 O21 71.88(18) 4_554 .
O6 Na5 O21 67.47(17) . .
O5 Na5 Si6 134.2(2) . .
O7 Na5 Si6 109.44(19) 3 .
O19 Na5 Si6 32.05(12) . .
O4 Na5 Si6 82.45(16) 4_554 .
O6 Na5 Si6 88.93(17) . .
O21 Na5 Si6 31.66(11) . .
O5 Na5 Si2 31.21(15) . .
O7 Na5 Si2 131.6(2) 3 .
O19 Na5 Si2 143.6(2) . .
O4 Na5 Si2 129.6(2) 4_554 .
O6 Na5 Si2 31.49(12) . .
O21 Na5 Si2 98.74(15) . .
Si6 Na5 Si2 115.52(14) . .
O5 Na5 Yb1 146.9(2) . 3
O7 Na5 Yb1 44.91(13) 3 3
O19 Na5 Yb1 45.37(13) . 3
O4 Na5 Yb1 43.13(11) 4_554 3
O6 Na5 Yb1 149.59(19) . 3
O21 Na5 Yb1 84.78(14) . 3
Si6 Na5 Yb1 71.82(10) . 3
Si2 Na5 Yb1 170.51(17) . 3
O5 Na5 Si1 111.6(2) . 4_554
O7 Na5 Si1 84.47(17) 3 4_554
O19 Na5 Si1 103.83(19) . 4_554
O4 Na5 Si1 30.04(12) 4_554 4_554
O6 Na5 Si1 92.22(18) . 4_554
O21 Na5 Si1 81.71(15) . 4_554
Si6 Na5 Si1 104.05(13) . 4_554
Si2 Na5 Si1 100.80(14) . 4_554
Yb1 Na5 Si1 70.87(10) 3 4_554
O5 Na5 Si2 80.04(18) . 3
O7 Na5 Si2 24.69(13) 3 3
O19 Na5 Si2 88.90(16) . 3
O4 Na5 Si2 96.22(17) 4_554 3
O6 Na5 Si2 142.45(18) . 3
O21 Na5 Si2 147.98(17) . 3
Si6 Na5 Si2 119.32(14) . 3
Si2 Na5 Si2 111.13(14) . 3
Yb1 Na5 Si2 67.63(9) 3 3
Si1 Na5 Si2 102.98(13) 4_554 3
O5 Na5 Yb2 99.10(18) . 4_554
O7 Na5 Yb2 148.0(2) 3 4_554
O19 Na5 Yb2 98.63(16) . 4_554
O4 Na5 Yb2 76.21(15) 4_554 4_554
O6 Na5 Yb2 39.03(12) . 4_554
O21 Na5 Yb2 39.41(10) . 4_554
Si6 Na5 Yb2 70.31(9) . 4_554
Si2 Na5 Yb2 68.17(9) . 4_554
Yb1 Na5 Yb2 110.83(12) 3 4_554
Si1 Na5 Yb2 65.40(10) 4_554 4_554
Si2 Na5 Yb2 167.32(16) 3 4_554
O3 Na6 O2 122.8(2) . 3
O3 Na6 O7 116.9(3) . 4
O2 Na6 O7 95.8(2) 3 4
O3 Na6 O16 113.5(2) . .
O2 Na6 O16 117.1(2) 3 .
O7 Na6 O16 81.3(2) 4 .
O3 Na6 O2 58.49(18) . .
O2 Na6 O2 65.1(2) 3 .
O7 Na6 O2 117.0(2) 4 .
O16 Na6 O2 161.6(2) . .
O3 Na6 Si1 28.67(14) . .
O2 Na6 Si1 94.20(17) 3 .
O7 Na6 Si1 123.9(2) 4 .
O16 Na6 Si1 138.67(19) . .
O2 Na6 Si1 30.03(11) . .
O3 Na6 Si1 150.1(2) . 3
O2 Na6 Si1 29.00(13) 3 3
O7 Na6 Si1 84.62(17) 4 3
O16 Na6 Si1 89.01(17) . 3
O2 Na6 Si1 93.99(14) . 3
Si1 Na6 Si1 122.41(12) . 3
O3 Na6 Si2 89.3(2) . 4
O2 Na6 Si2 107.71(19) 3 4
O7 Na6 Si2 28.33(13) 4 4
O16 Na6 Si2 98.29(19) . 4
O2 Na6 Si2 98.09(15) . 4
Si1 Na6 Si2 96.70(12) . 4
Si1 Na6 Si2 107.44(13) 3 4
O3 Na6 Si5 85.01(17) . .
O2 Na6 Si5 140.3(2) 3 .
O7 Na6 Si5 94.90(17) 4 .
O16 Na6 Si5 28.46(13) . .
O2 Na6 Si5 138.99(16) . .
Si1 Na6 Si5 110.89(12) . .
Si1 Na6 Si5 115.20(13) 3 .
Si2 Na6 Si5 99.57(12) 4 .
O3 Na6 Yb1 140.7(2) . 4
O2 Na6 Yb1 95.52(17) 3 4
O7 Na6 Yb1 43.34(13) 4 4
O16 Na6 Yb1 43.44(14) . 4
O2 Na6 Yb1 153.19(17) . 4
Si1 Na6 Yb1 164.78(15) . 4
Si1 Na6 Yb1 69.17(9) 3 4
Si2 Na6 Yb1 69.17(9) 4 4
Si5 Na6 Yb1 67.71(9) . 4
O3 Na6 Na11 93.86(19) . 4
O2 Na6 Na11 50.5(3) 3 4
O7 Na6 Na11 73.2(3) 4 4
O16 Na6 Na11 149.1(3) . 4
O2 Na6 Na11 47.6(3) . 4
Si1 Na6 Na11 71.77(15) . 4
Si1 Na6 Na11 71.70(15) 3 4
Si2 Na6 Na11 66.5(3) 4 4
Si5 Na6 Na11 166.1(4) . 4
Yb1 Na6 Na11 105.9(2) 4 4
O3 Na6 Yb2 37.14(14) . .
O2 Na6 Yb2 154.1(2) 3 .
O7 Na6 Yb2 86.99(17) 4 .
O16 Na6 Yb2 88.71(16) . .
O2 Na6 Yb2 90.73(13) . .
Si1 Na6 Yb2 63.65(8) . .
Si1 Na6 Yb2 171.55(14) 3 .
Si2 Na6 Yb2 64.88(9) 4 .
Si5 Na6 Yb2 64.50(7) . .
Yb1 Na6 Yb2 103.83(10) 4 .
Na11 Na6 Yb2 106.8(2) 4 .
O20 Na7 O14 161.1(3) . 3
O20 Na7 O9 109.4(2) . 4_554
O14 Na7 O9 83.4(2) 3 4_554
O20 Na7 O21 110.6(2) . 2_655
O14 Na7 O21 76.96(19) 3 2_655
O9 Na7 O21 107.9(2) 4_554 2_655
O20 Na7 O19 61.83(18) . .
O14 Na7 O19 111.1(2) 3 .
O9 Na7 O19 73.86(18) 4_554 .
O21 Na7 O19 172.0(2) 2_655 .
O20 Na7 Si6 30.54(14) . .
O14 Na7 Si6 141.2(2) 3 .
O9 Na7 Si6 89.88(16) 4_554 .
O21 Na7 Si6 140.68(17) 2_655 .
O19 Na7 Si6 31.50(11) . .
O20 Na7 Si4 136.7(2) . 3
O14 Na7 Si4 29.28(14) 3 3
O9 Na7 Si4 80.13(15) 4_554 3
O21 Na7 Si4 105.65(15) 2_655 3
O19 Na7 Si4 82.33(14) . 3
Si6 Na7 Si4 111.93(14) . 3
O20 Na7 Si3 107.20(19) . 4_554
O14 Na7 Si3 90.80(19) 3 4_554
O9 Na7 Si3 29.39(12) 4_554 4_554
O21 Na7 Si3 82.05(16) 2_655 4_554
O19 Na7 Si3 97.50(16) . 4_554
Si6 Na7 Si3 101.74(12) . 4_554
Si4 Na7 Si3 100.38(11) 3 4_554
O20 Na7 Yb2 150.6(2) . 6_654
O14 Na7 Yb2 43.49(14) 3 6_654
O9 Na7 Yb2 78.50(15) 4_554 6_654
O21 Na7 Yb2 41.85(11) 2_655 6_654
O19 Na7 Yb2 144.83(15) . 6_654
Si6 Na7 Yb2 167.14(15) . 6_654
Si4 Na7 Yb2 71.77(7) 3 6_654
Si3 Na7 Yb2 65.41(9) 4_554 6_654
O20 Na7 Si6 86.33(17) . 2_655
O14 Na7 Si6 95.07(17) 3 2_655
O9 Na7 Si6 132.85(19) 4_554 2_655
O21 Na7 Si6 28.74(11) 2_655 2_655
O19 Na7 Si6 145.82(16) . 2_655
Si6 Na7 Si6 116.59(12) . 2_655
Si4 Na7 Si6 118.69(12) 3 2_655
Si3 Na7 Si6 103.98(13) 4_554 2_655
Yb2 Na7 Si6 69.24(8) 6_654 2_655
O20 Na7 Na9 48.9(2) . 4_554
O14 Na7 Na9 147.9(3) 3 4_554
O9 Na7 Na9 90.0(3) 4_554 4_554
O21 Na7 Na9 75.33(14) 2_655 4_554
O19 Na7 Na9 96.96(13) . 4_554
Si6 Na7 Na9 69.74(12) . 4_554
Si4 Na7 Na9 169.9(3) 3 4_554
Si3 Na7 Na9 69.7(2) 4_554 4_554
Yb2 Na7 Na9 104.45(18) 6_654 4_554
Si6 Na7 Na9 66.95(12) 2_655 4_554
O20 Na7 Yb1 96.35(17) . 3
O14 Na7 Yb1 85.11(16) 3 3
O9 Na7 Yb1 38.44(12) 4_554 3
O21 Na7 Yb1 144.15(17) 2_655 3
O19 Na7 Yb1 40.16(11) . 3
Si6 Na7 Yb1 67.00(8) . 3
Si4 Na7 Yb1 64.48(8) 3 3
Si3 Na7 Yb1 67.26(9) 4_554 3
Yb2 Na7 Yb1 105.60(10) 6_654 3
Si6 Na7 Yb1 171.24(15) 2_655 3
Na9 Na7 Yb1 108.69(16) 4_554 3
O13 Na8 O12 108.3(2) 2_665 .
O13 Na8 O18 103.5(2) 2_665 4_554
O12 Na8 O18 107.9(2) . 4_554
O13 Na8 O6 122.5(2) 2_665 .
O12 Na8 O6 125.5(2) . .
O18 Na8 O6 79.8(2) 4_554 .
O13 Na8 O14 61.76(18) 2_665 2_665
O12 Na8 O14 166.7(2) . 2_665
O18 Na8 O14 68.51(18) 4_554 2_665
O6 Na8 O14 67.21(17) . 2_665
O13 Na8 Si4 30.49(14) 2_665 2_665
O12 Na8 Si4 137.86(19) . 2_665
O18 Na8 Si4 84.80(16) 4_554 2_665
O6 Na8 Si4 95.93(17) . 2_665
O14 Na8 Si4 31.32(11) 2_665 2_665
O13 Na8 Si2 139.5(2) 2_665 .
O12 Na8 Si2 96.88(18) . .
O18 Na8 Si2 98.03(17) 4_554 .
O6 Na8 Si2 30.23(13) . .
O14 Na8 Si2 96.27(15) 2_665 .
Si4 Na8 Si2 121.60(13) 2_665 .
O13 Na8 Yb2 103.97(18) 2_665 4_554
O12 Na8 Yb2 141.5(2) . 4_554
O18 Na8 Yb2 43.04(13) 4_554 4_554
O6 Na8 Yb2 42.50(13) . 4_554
O14 Na8 Yb2 43.72(11) 2_665 4_554
Si4 Na8 Yb2 73.86(9) 2_665 4_554
Si2 Na8 Yb2 70.25(8) . 4_554
O13 Na8 Si5 114.1(2) 2_665 4_554
O12 Na8 Si5 78.81(18) . 4_554
O18 Na8 Si5 29.06(13) 4_554 4_554
O6 Na8 Si5 96.12(17) . 4_554
O14 Na8 Si5 96.95(15) 2_665 4_554
Si4 Na8 Si5 106.90(12) 2_665 4_554
Si2 Na8 Si5 101.32(11) . 4_554
Yb2 Na8 Si5 69.08(8) 4_554 4_554
O13 Na8 Si4 84.66(17) 2_665 .
O12 Na8 Si4 25.09(13) . .
O18 Na8 Si4 123.22(18) 4_554 .
O6 Na8 Si4 141.43(18) . .
O14 Na8 Si4 146.42(17) 2_665 .
Si4 Na8 Si4 115.10(12) 2_665 .
Si2 Na8 Si4 111.30(12) . .
Yb2 Na8 Si4 164.80(14) 4_554 .
Si5 Na8 Si4 96.05(11) 4_554 .
O13 Na8 Na10 54.1(3) 2_665 .
O12 Na8 Na10 75.86(16) . .
O18 Na8 Na10 73.8(3) 4_554 .
O6 Na8 Na10 150.7(2) . .
O14 Na8 Na10 90.92(14) 2_665 .
Si4 Na8 Na10 69.35(13) 2_665 .
Si2 Na8 Na10 166.4(3) . .
Yb2 Na8 Na10 108.2(2) 4_554 .
Si5 Na8 Na10 66.2(3) 4_554 .
Si4 Na8 Na10 66.54(13) . .
O13 Na8 Na1 82.10(19) 2_665 .
O12 Na8 Na1 143.7(3) . .
O18 Na8 Na1 102.9(3) 4_554 .
O6 Na8 Na1 42.9(2) . .
O14 Na8 Na1 47.25(18) 2_665 .
Si4 Na8 Na1 62.86(11) 2_665 .
Si2 Na8 Na1 59.69(11) . .
Yb2 Na8 Na1 60.7(2) 4_554 .
Si5 Na8 Na1 129.7(2) 4_554 .
Si4 Na8 Na1 133.8(2) . .
Na10 Na8 Na1 132.16(18) . .
O10 Na9 O10 70.9(4) . 3_565
O10 Na9 O10 70.9(4) . 2_665
O10 Na9 O10 70.9(4) 3_565 2_665
O10 Na9 O20 124.38(16) . 5_565
O10 Na9 O20 100.20(15) 3_565 5_565
O10 Na9 O20 159.82(17) 2_665 5_565
O10 Na9 O20 100.20(16) . 4
O10 Na9 O20 159.82(16) 3_565 4
O10 Na9 O20 124.38(16) 2_665 4
O20 Na9 O20 69.3(4) 5_565 4
O10 Na9 O20 159.82(16) . 6_665
O10 Na9 O20 124.38(16) 3_565 6_665
O10 Na9 O20 100.20(16) 2_665 6_665
O20 Na9 O20 69.3(4) 5_565 6_665
O20 Na9 O20 69.3(4) 4 6_665
O10 Na9 Na2 60.7(2) . 3_565
O10 Na9 Na2 45.84(18) 3_565 3_565
O10 Na9 Na2 108.3(5) 2_665 3_565
O20 Na9 Na2 74.05(14) 5_565 3_565
O20 Na9 Na2 113.99(19) 4 3_565
O20 Na9 Na2 139.0(3) 6_665 3_565
O10 Na9 Na2 108.3(5) . 2_665
O10 Na9 Na2 60.7(2) 3_565 2_665
O10 Na9 Na2 45.84(18) 2_665 2_665
O20 Na9 Na2 113.99(19) 5_565 2_665
O20 Na9 Na2 139.0(3) 4 2_665
O20 Na9 Na2 74.05(14) 6_665 2_665
Na2 Na9 Na2 105.7(3) 3_565 2_665
O10 Na9 Na2 45.84(18) . .
O10 Na9 Na2 108.3(5) 3_565 .
O10 Na9 Na2 60.7(2) 2_665 .
O20 Na9 Na2 139.0(3) 5_565 .
O20 Na9 Na2 74.05(14) 4 .
O20 Na9 Na2 113.99(19) 6_665 .
Na2 Na9 Na2 105.7(3) 3_565 .
Na2 Na9 Na2 105.7(3) 2_665 .
O10 Na9 Yb3 42.0(3) . .
O10 Na9 Yb3 42.0(3) 3_565 .
O10 Na9 Yb3 42.0(3) 2_665 .
O20 Na9 Yb3 138.9(2) 5_565 .
O20 Na9 Yb3 138.9(2) 4 .
O20 Na9 Yb3 138.9(2) 6_665 .
Na2 Na9 Yb3 66.9(2) 3_565 .
Na2 Na9 Yb3 66.9(2) 2_665 .
Na2 Na9 Yb3 66.9(2) . .
O10 Na9 Na7 133.9(3) . 5_565
O10 Na9 Na7 71.00(13) 3_565 5_565
O10 Na9 Na7 118.4(2) 2_665 5_565
O20 Na9 Na7 42.00(16) 5_565 5_565
O20 Na9 Na7 106.9(5) 4 5_565
O20 Na9 Na7 66.2(2) 6_665 5_565
Na2 Na9 Na7 74.30(10) 3_565 5_565
Na2 Na9 Na7 73.46(10) 2_665 5_565
Na2 Na9 Na7 179.0(4) . 5_565
Yb3 Na9 Na7 112.2(2) . 5_565
O10 Na9 Na7 71.00(13) . 4
O10 Na9 Na7 118.4(2) 3_565 4
O10 Na9 Na7 133.9(3) 2_665 4
O20 Na9 Na7 66.2(2) 5_565 4
O20 Na9 Na7 42.00(16) 4 4
O20 Na9 Na7 106.9(5) 6_665 4
Na2 Na9 Na7 73.46(10) 3_565 4
Na2 Na9 Na7 179.0(4) 2_665 4
Na2 Na9 Na7 74.30(10) . 4
Yb3 Na9 Na7 112.2(2) . 4
Na7 Na9 Na7 106.6(3) 5_565 4
O17 Na10 O17 70.8(4) 5_564 4_554
O17 Na10 O17 70.8(4) 5_564 6_664
O17 Na10 O17 70.8(4) 4_554 6_664
O17 Na10 O13 113.04(15) 5_564 .
O17 Na10 O13 111.23(16) 4_554 .
O17 Na10 O13 176.0(5) 6_664 .
O17 Na10 O13 111.23(15) 5_564 3_565
O17 Na10 O13 176.0(5) 4_554 3_565
O17 Na10 O13 113.03(15) 6_664 3_565
O13 Na10 O13 64.8(4) . 3_565
O17 Na10 O13 176.0(5) 5_564 2_665
O17 Na10 O13 113.03(15) 4_554 2_665
O17 Na10 O13 111.23(15) 6_664 2_665
O13 Na10 O13 64.8(4) . 2_665
O13 Na10 O13 64.8(4) 3_565 2_665
O17 Na10 Na3 70.3(3) 5_564 4_554
O17 Na10 Na3 43.35(16) 4_554 4_554
O17 Na10 Na3 110.9(5) 6_664 4_554
O13 Na10 Na3 72.07(15) . 4_554
O13 Na10 Na3 133.5(4) 3_565 4_554
O13 Na10 Na3 111.5(2) 2_665 4_554
O17 Na10 Na3 43.35(16) 5_564 5_564
O17 Na10 Na3 110.9(5) 4_554 5_564
O17 Na10 Na3 70.3(3) 6_664 5_564
O13 Na10 Na3 111.5(2) . 5_564
O13 Na10 Na3 72.07(15) 3_565 5_564
O13 Na10 Na3 133.5(4) 2_665 5_564
Na3 Na10 Na3 110.4(3) 4_554 5_564
O17 Na10 Na3 110.9(5) 5_564 6_664
O17 Na10 Na3 70.3(3) 4_554 6_664
O17 Na10 Na3 43.35(16) 6_664 6_664
O13 Na10 Na3 133.5(4) . 6_664
O13 Na10 Na3 111.5(2) 3_565 6_664
O13 Na10 Na3 72.07(15) 2_665 6_664
Na3 Na10 Na3 110.4(3) 4_554 6_664
Na3 Na10 Na3 110.4(3) 5_564 6_664
O17 Na10 Yb4 42.0(3) 5_564 4_554
O17 Na10 Yb4 42.0(3) 4_554 4_554
O17 Na10 Yb4 42.0(3) 6_664 4_554
O13 Na10 Yb4 141.7(2) . 4_554
O13 Na10 Yb4 141.7(2) 3_565 4_554
O13 Na10 Yb4 141.7(2) 2_665 4_554
Na3 Na10 Yb4 71.5(3) 4_554 4_554
Na3 Na10 Yb4 71.5(3) 5_564 4_554
Na3 Na10 Yb4 71.5(3) 6_664 4_554
O17 Na10 Na8 74.11(12) 5_564 3_565
O17 Na10 Na8 110.62(18) 4_554 3_565
O17 Na10 Na8 142.0(4) 6_664 3_565
O13 Na10 Na8 41.12(16) . 3_565
O13 Na10 Na8 67.2(3) 3_565 3_565
O13 Na10 Na8 103.0(5) 2_665 3_565
Na3 Na10 Na8 69.09(9) 4_554 3_565
Na3 Na10 Na8 74.41(10) 5_564 3_565
Na3 Na10 Na8 174.6(5) 6_664 3_565
Yb4 Na10 Na8 112.9(3) 4_554 3_565
O17 Na10 Na8 142.0(4) 5_564 .
O17 Na10 Na8 74.11(12) 4_554 .
O17 Na10 Na8 110.62(18) 6_664 .
O13 Na10 Na8 67.2(3) . .
O13 Na10 Na8 103.0(5) 3_565 .
O13 Na10 Na8 41.12(16) 2_665 .
Na3 Na10 Na8 74.41(10) 4_554 .
Na3 Na10 Na8 174.6(5) 5_564 .
Na3 Na10 Na8 69.09(9) 6_664 .
Yb4 Na10 Na8 112.9(3) 4_554 .
Na8 Na10 Na8 105.9(3) 3_565 .
O2 Na11 O2 69.5(5) 5_554 6_554
O2 Na11 O2 69.5(5) 5_554 4_554
O2 Na11 O2 69.5(5) 6_554 4_554
O2 Na11 O5 170.59(17) 5_554 .
O2 Na11 O5 117.59(16) 6_554 .
O2 Na11 O5 106.35(15) 4_554 .
O2 Na11 O5 106.35(15) 5_554 3
O2 Na11 O5 170.59(17) 6_554 3
O2 Na11 O5 117.60(16) 4_554 3
O5 Na11 O5 67.6(5) . 3
O2 Na11 O5 117.60(16) 5_554 2
O2 Na11 O5 106.35(15) 6_554 2
O2 Na11 O5 170.59(17) 4_554 2
O5 Na11 O5 67.6(5) . 2
O5 Na11 O5 67.6(5) 3 2
O2 Na11 Na6 59.8(3) 5_554 5_554
O2 Na11 Na6 105.8(6) 6_554 5_554
O2 Na11 Na6 44.7(2) 4_554 5_554
O5 Na11 Na6 111.2(2) . 5_554
O5 Na11 Na6 78.18(14) 3 5_554
O5 Na11 Na6 143.4(4) 2 5_554
O2 Na11 Na6 44.7(2) 5_554 6_554
O2 Na11 Na6 59.8(3) 6_554 6_554
O2 Na11 Na6 105.8(6) 4_554 6_554
O5 Na11 Na6 143.4(4) . 6_554
O5 Na11 Na6 111.2(2) 3 6_554
O5 Na11 Na6 78.18(14) 2 6_554
Na6 Na11 Na6 103.8(4) 5_554 6_554
O2 Na11 Na6 105.8(6) 5_554 4_554
O2 Na11 Na6 44.7(2) 6_554 4_554
O2 Na11 Na6 59.8(3) 4_554 4_554
O5 Na11 Na6 78.18(14) . 4_554
O5 Na11 Na6 143.4(4) 3 4_554
O5 Na11 Na6 111.2(2) 2 4_554
Na6 Na11 Na6 103.8(4) 5_554 4_554
Na6 Na11 Na6 103.8(4) 6_554 4_554
O2 Na11 Yb5 41.2(3) 5_554 4_554
O2 Na11 Yb5 41.2(3) 6_554 4_554
O2 Na11 Yb5 41.2(3) 4_554 4_554
O5 Na11 Yb5 140.1(3) . 4_554
O5 Na11 Yb5 140.1(3) 3 4_554
O5 Na11 Yb5 140.1(3) 2 4_554
Na6 Na11 Yb5 65.3(3) 5_554 4_554
Na6 Na11 Yb5 65.3(3) 6_554 4_554
Na6 Na11 Yb5 65.3(3) 4_554 4_554
O2 Na11 Yb5 138.8(3) 5_554 .
O2 Na11 Yb5 138.8(3) 6_554 .
O2 Na11 Yb5 138.8(3) 4_554 .
O5 Na11 Yb5 39.9(3) . .
O5 Na11 Yb5 39.9(3) 3 .
O5 Na11 Yb5 39.9(3) 2 .
Na6 Na11 Yb5 114.7(3) 5_554 .
Na6 Na11 Yb5 114.7(3) 6_554 .
Na6 Na11 Yb5 114.7(3) 4_554 .
Yb5 Na11 Yb5 180.0 4_554 .
O2 Na11 Na5 68.66(13) 5_554 3
O2 Na11 Na5 130.1(4) 6_554 3
O2 Na11 Na5 117.8(3) 4_554 3
O5 Na11 Na5 107.5(6) . 3
O5 Na11 Na5 42.04(17) 3 3
O5 Na11 Na5 71.4(3) 2 3
Na6 Na11 Na5 74.72(10) 5_554 3
Na6 Na11 Na5 71.49(9) 6_554 3
Na6 Na11 Na5 174.3(6) 4_554 3
Yb5 Na11 Na5 109.3(3) 4_554 3
Yb5 Na11 Na5 70.7(3) . 3
Si1 O1 Si2 130.0(3) . .
Si1 O1 Na4 101.7(4) . .
Si2 O1 Na4 117.4(4) . .
Si1 O2 Yb5 130.9(3) . .
Si1 O2 Na6 106.3(3) . 2
Yb5 O2 Na6 104.6(2) . 2
Si1 O2 Na11 130.2(4) . 4
Yb5 O2 Na11 89.5(3) . 4
Na6 O2 Na11 84.8(2) 2 4
Si1 O2 Na6 81.5(2) . .
Yb5 O2 Na6 86.16(18) . .
Na6 O2 Na6 155.0(3) 2 .
Na11 O2 Na6 72.59(15) 4 .
Si1 O3 Yb2 137.1(3) . .
Si1 O3 Na6 108.4(3) . .
Yb2 O3 Na6 104.4(2) . .
Si1 O3 Na1 106.8(3) . .
Yb2 O3 Na1 89.3(3) . .
Na6 O3 Na1 106.4(3) . .
Si1 O4 Yb1 152.5(3) . 6
Si1 O4 Na2 104.1(3) . .
Yb1 O4 Na2 103.4(2) 6 .
Si1 O4 Na5 94.3(3) . 4
Yb1 O4 Na5 81.06(19) 6 4
Na2 O4 Na5 103.9(2) . 4
Si1 O4 Na4 91.1(3) . .
Yb1 O4 Na4 85.4(2) 6 .
Na2 O4 Na4 93.1(2) . .
Na5 O4 Na4 160.3(3) 4 .
Si2 O5 Yb5 131.8(3) . .
Si2 O5 Na5 100.7(3) . .
Yb5 O5 Na5 123.7(2) . .
Si2 O5 Na11 112.1(3) . .
Yb5 O5 Na11 89.5(3) . .
Na5 O5 Na11 87.5(3) . .
Si2 O6 Yb2 151.7(4) . 4_554
Si2 O6 Na1 111.9(4) . .
Yb2 O6 Na1 96.3(3) 4_554 .
Si2 O6 Na8 96.4(3) . .
Yb2 O6 Na8 85.1(2) 4_554 .
Na1 O6 Na8 89.5(2) . .
Si2 O6 Na5 86.3(3) . .
Yb2 O6 Na5 89.2(2) 4_554 .
Na1 O6 Na5 95.9(3) . .
Na8 O6 Na5 172.6(3) . .
Si2 O7 Yb1 147.5(3) . .
Si2 O7 Na6 106.2(3) . 4_554
Yb1 O7 Na6 89.2(2) . 4_554
Si2 O7 Na5 115.5(3) . 2
Yb1 O7 Na5 84.34(19) . 2
Na6 O7 Na5 109.8(2) 4_554 2
Si3 O8 Si4 125.8(3) . .
Si3 O8 Na4 113.4(4) . .
Si4 O8 Na4 114.6(4) . .
Si3 O9 Yb1 158.0(3) . 6
Si3 O9 Na3 98.6(3) . 2
Yb1 O9 Na3 90.27(18) 6 2
Si3 O9 Na7 101.0(2) . 4
Yb1 O9 Na7 96.1(2) 6 4
Na3 O9 Na7 105.1(2) 2 4
Si3 O9 Na2 79.0(2) . .
Yb1 O9 Na2 86.54(18) 6 .
Na3 O9 Na2 162.4(3) 2 .
Na7 O9 Na2 92.47(19) 4 .
Si3 O10 Yb3 131.0(3) . .
Si3 O10 Na2 103.0(3) . .
Yb3 O10 Na2 105.1(2) . .
Si3 O10 Na9 132.2(3) . .
Yb3 O10 Na9 90.0(3) . .
Na2 O10 Na9 84.5(2) . .
Si3 O10 Na2 84.4(2) . 3_565
Yb3 O10 Na2 87.36(18) . 3_565
Na2 O10 Na2 153.9(3) . 3_565
Na9 O10 Na2 72.43(15) . 3_565
Si3 O11 Yb2 133.4(3) . 3_565
Si3 O11 Na1 120.2(4) . 3_565
Yb2 O11 Na1 96.5(3) 3_565 3_565
Si3 O11 Na2 104.3(3) . 3_565
Yb2 O11 Na2 88.6(2) 3_565 3_565
Na1 O11 Na2 107.9(3) 3_565 3_565
Si4 O12 Yb1 137.2(3) . .
Si4 O12 Na8 117.8(3) . .
Yb1 O12 Na8 102.2(2) . .
Si4 O12 Na3 90.9(2) . 4_554
Yb1 O12 Na3 85.9(2) . 4_554
Na8 O12 Na3 114.1(2) . 4_554
Si4 O13 Yb3 132.5(3) . .
Si4 O13 Na8 104.2(3) . 3_565
Yb3 O13 Na8 119.7(2) . 3_565
Si4 O13 Na10 112.4(3) . .
Yb3 O13 Na10 89.9(3) . .
Na8 O13 Na10 84.8(2) 3_565 .
Si4 O14 Yb2 153.5(3) . 5_564
Si4 O14 Na7 106.9(3) . 2
Yb2 O14 Na7 92.5(2) 5_564 2
Si4 O14 Na1 107.4(3) . 3_565
Yb2 O14 Na1 87.9(3) 5_564 3_565
Na7 O14 Na1 95.5(2) 2 3_565
Si4 O14 Na8 84.2(2) . 3_565
Yb2 O14 Na8 77.38(17) 5_564 3_565
Na7 O14 Na8 168.8(3) 2 3_565
Na1 O14 Na8 79.5(2) 3_565 3_565
Si4 O14 Na3 80.9(2) . 4_554
Yb2 O14 Na3 78.78(17) 5_564 4_554
Na7 O14 Na3 97.9(2) 2 4_554
Na1 O14 Na3 161.4(3) 3_565 4_554
Na8 O14 Na3 84.96(18) 3_565 4_554
Si5 O15 Si6 126.1(3) . .
Si5 O15 Na1 118.5(4) . .
Si6 O15 Na1 115.3(4) . .
Si5 O16 Yb1 139.8(3) . 4
Si5 O16 Na6 106.3(3) . .
Yb1 O16 Na6 88.9(2) 4 .
Si5 O16 Na4 118.0(3) . 3
Yb1 O16 Na4 95.4(3) 4 3
Na6 O16 Na4 98.4(2) . 3
Si5 O16 Na3 80.7(2) . .
Yb1 O16 Na3 76.70(17) 4 .
Na6 O16 Na3 163.5(3) . .
Na4 O16 Na3 91.1(2) 3 .
Si5 O17 Yb4 127.2(3) . .
Si5 O17 Na3 105.9(3) . .
Yb4 O17 Na3 119.0(2) . .
Si5 O17 Na10 121.7(3) . 4
Yb4 O17 Na10 88.9(3) . 4
Na3 O17 Na10 86.6(2) . 4
Si5 O18 Yb2 145.9(3) . .
Si5 O18 Na3 112.8(3) . 3_665
Yb2 O18 Na3 92.12(19) . 3_665
Si5 O18 Na8 105.1(3) . 4
Yb2 O18 Na8 88.4(2) . 4
Na3 O18 Na8 106.7(2) 3_665 4
Si6 O19 Yb1 138.7(3) . 3
Si6 O19 Na4 122.7(4) . 3
Yb1 O19 Na4 97.9(3) 3 3
Si6 O19 Na5 93.9(2) . .
Yb1 O19 Na5 83.4(2) 3 .
Na4 O19 Na5 102.1(2) 3 .
Si6 O19 Na7 81.7(2) . .
Yb1 O19 Na7 85.25(17) 3 .
Na4 O19 Na7 99.2(2) 3 .
Na5 O19 Na7 157.1(3) . .
Si6 O20 Na7 104.1(3) . .
Si6 O20 Yb4 127.7(3) . .
Na7 O20 Yb4 114.5(2) . .
Si6 O20 Na9 124.2(3) . 4_554
Na7 O20 Na9 89.1(2) . 4_554
Yb4 O20 Na9 91.3(3) . 4_554
Si6 O21 Yb2 157.3(3) . 4_554
Si6 O21 Na2 106.2(2) . 4_554
Yb2 O21 Na2 91.40(19) 4_554 4_554
Si6 O21 Na7 101.4(3) . 3_665
Yb2 O21 Na7 86.71(18) 4_554 3_665
Na2 O21 Na7 106.3(2) 4_554 3_665
Si6 O21 Na5 79.3(2) . .
Yb2 O21 Na5 84.20(18) 4_554 .
Na2 O21 Na5 98.1(2) 4_554 .
Na7 O21 Na5 154.1(2) 3_665 .
loop_
_geom_bond_atom_site_label_1
_geom_bond_atom_site_label_2
_geom_bond_distance
_geom_bond_site_symmetry_2
Yb1 O4 2.179(5) 6_554
Yb1 O9 2.180(4) 6_554
Yb1 O12 2.206(5) .
Yb1 O7 2.234(5) .
Yb1 O16 2.239(5) 4_554
Yb1 O19 2.256(5) 2
Yb1 Na5 3.149(4) 2
Yb1 Na6 3.255(4) 4_554
Yb1 Na3 3.272(4) 4_554
Yb1 Na4 3.418(13) .
Yb1 Na4 3.440(13) 6_554
Yb1 Na7 3.486(4) 2
Yb2 O6 2.178(5) 4
Yb2 O18 2.193(5) .
Yb2 O21 2.206(4) 4
Yb2 O11 2.222(5) 2_665
Yb2 O3 2.233(5) .
Yb2 O14 2.275(5) 5_665
Yb2 Na8 3.212(4) 4
Yb2 Na2 3.263(4) .
Yb2 Na3 3.296(4) 3_665
Yb2 Na7 3.302(4) 6_665
Yb2 Na1 3.378(14) 4
Yb2 Na5 3.457(4) 4
Yb3 O13 2.210(5) .
Yb3 O13 2.210(5) 3_565
Yb3 O13 2.210(5) 2_665
Yb3 O10 2.238(5) .
Yb3 O10 2.238(5) 3_565
Yb3 O10 2.238(5) 2_665
Yb3 Na9 3.343(15) .
Yb3 Si3 3.513(2) .
Yb3 Si3 3.513(2) 3_565
Yb3 Si3 3.513(2) 2_665
Yb3 Si4 3.519(2) 3_565
Yb3 Si4 3.519(2) 2_665
Yb4 O20 2.252(5) 2_655
Yb4 O20 2.252(5) 3_665
Yb4 O20 2.252(5) .
Yb4 O17 2.254(5) 2_655
Yb4 O17 2.254(5) 3_665
Yb4 O17 2.254(5) .
Yb4 Na10 3.368(17) 4
Yb4 Na9 3.427(15) 4_554
Yb4 Si5 3.471(2) .
Yb4 Si5 3.471(2) 2_655
Yb4 Si5 3.471(2) 3_665
Yb4 Si6 3.476(2) 2_655
Yb5 O5 2.217(5) 2
Yb5 O5 2.217(5) 3
Yb5 O5 2.217(5) .
Yb5 O2 2.239(5) .
Yb5 O2 2.239(5) 3
Yb5 O2 2.239(5) 2
Yb5 Na11 3.40(2) 4
Yb5 Na11 3.45(2) .
Yb5 Si2 3.506(2) 2
Yb5 Si2 3.506(2) 3
Yb5 Si2 3.506(2) .
Yb5 Si1 3.522(2) .
Si1 O4 1.598(5) .
Si1 O3 1.621(6) .
Si1 O2 1.623(5) .
Si1 O1 1.651(6) .
Si1 Na5 3.183(4) 4
Si1 Na2 3.202(5) .
Si1 Na6 3.207(4) .
Si1 Na6 3.212(5) 2
Si1 Na4 3.285(7) .
Si1 Na1 3.523(8) .
Si2 O7 1.597(5) .
Si2 O6 1.602(6) .
Si2 O5 1.614(6) .
Si2 O1 1.665(6) .
Si2 Na5 3.061(5) .
Si2 Na8 3.163(4) .
Si2 Na6 3.233(4) 4_554
Si2 Na1 3.305(8) .
Si2 Na5 3.453(5) 2
Si3 O11 1.607(5) .
Si3 O9 1.609(5) .
Si3 O10 1.612(5) .
Si3 O8 1.650(5) .
Si3 Na3 3.108(4) 2
Si3 Na2 3.127(4) .
Si3 Na7 3.219(4) 4
Si3 Na2 3.239(5) 3_565
Si3 Na4 3.369(7) .
Si3 Yb2 3.524(2) 3_565
Si3 Na1 3.528(8) 3_565
Si4 O12 1.614(5) .
Si4 O14 1.623(5) .
Si4 O13 1.625(6) .
Si4 O8 1.673(5) .
Si4 Na3 3.064(5) 4_554
Si4 Na8 3.106(4) 3_565
Si4 Na7 3.174(4) 2
Si4 Na8 3.367(4) .
Si4 Na4 3.409(7) .
Si4 Na1 3.436(8) 3_565
Si5 O17 1.608(5) .
Si5 O16 1.615(5) .
Si5 O18 1.630(5) .
Si5 O15 1.673(5) .
Si5 Na3 3.132(4) .
Si5 Na8 3.240(4) 4
Si5 Na6 3.253(4) .
Si5 Na3 3.367(4) 3_665
Si5 Na4 3.474(7) 3
Si5 Na1 3.488(9) .
Si6 O20 1.608(5) .
Si6 O19 1.621(5) .
Si6 O21 1.627(5) .
Si6 O15 1.676(5) .
Si6 Na5 3.047(5) .
Si6 Na7 3.069(4) .
Si6 Na2 3.211(4) 4_554
Si6 Na7 3.317(4) 3_665
Si6 Na1 3.433(7) .
Si6 Na4 3.434(8) 3
Na1 O6 2.353(13) .
Na1 O15 2.364(7) .
Na1 O11 2.435(12) 2_665
Na1 O14 2.583(13) 2_665
Na1 O3 2.696(13) .
Na1 Yb2 3.378(14) 4_554
Na1 Si4 3.436(8) 2_665
Na1 Na8 3.458(10) .
Na2 O10 2.340(6) .
Na2 O21 2.350(6) 4
Na2 O4 2.413(7) .
Na2 O11 2.443(7) 2_665
Na2 O10 2.970(7) 2_665
Na2 O9 3.007(6) .
Na2 Si6 3.211(4) 4
Na2 Si3 3.239(5) 2_665
Na2 Na9 3.247(7) .
Na3 O17 2.282(6) .
Na3 O18 2.381(6) 2_655
Na3 O9 2.430(6) 3
Na3 O12 2.579(7) 4
Na3 O14 2.869(6) 4
Na3 O16 2.956(7) .
Na3 Si4 3.064(5) 4
Na3 Si3 3.108(4) 3
Na3 Yb1 3.272(4) 4
Na3 Yb2 3.296(4) 2_655
Na3 Na10 3.320(7) 4
Na4 O19 2.276(12) 2
Na4 O8 2.355(6) .
Na4 O16 2.410(11) 2
Na4 O1 2.527(7) .
Na4 O4 2.840(12) .
Na4 Si6 3.434(8) 2
Na4 Yb1 3.439(13) 6
Na4 Si5 3.474(7) 2
Na5 O5 2.318(6) .
Na5 O7 2.451(6) 3
Na5 O19 2.471(7) .
Na5 O4 2.637(7) 4_554
Na5 O6 2.715(7) .
Na5 O21 2.894(7) .
Na5 Yb1 3.149(4) 3
Na5 Si1 3.183(4) 4_554
Na5 Si2 3.453(5) 3
Na5 Yb2 3.458(4) 4_554
Na6 O3 2.302(7) .
Na6 O2 2.353(6) 3
Na6 O7 2.400(7) 4
Na6 O16 2.407(7) .
Na6 O2 3.017(6) .
Na6 Si1 3.212(4) 3
Na6 Si2 3.233(4) 4
Na6 Yb1 3.255(4) 4
Na6 Na11 3.332(10) 4
Na7 O20 2.250(6) .
Na7 O14 2.295(6) 3
Na7 O9 2.499(6) 4_554
Na7 O21 2.586(7) 2_655
Na7 O19 2.851(6) .
Na7 Si4 3.174(4) 3
Na7 Si3 3.219(4) 4_554
Na7 Yb2 3.302(4) 6_654
Na7 Si6 3.317(4) 2_655
Na7 Na9 3.362(7) 4_554
Na7 Yb1 3.486(4) 3
Na8 O13 2.279(6) 2_665
Na8 O12 2.297(6) .
Na8 O18 2.407(7) 4_554
Na8 O6 2.553(7) .
Na8 O14 2.818(6) 2_665
Na8 Si4 3.106(4) 2_665
Na8 Yb2 3.212(4) 4_554
Na8 Si5 3.240(4) 4_554
Na8 Na10 3.451(8) .
Na9 O10 2.485(12) .
Na9 O10 2.485(12) 3_565
Na9 O10 2.485(12) 2_665
Na9 O20 2.532(12) 5_565
Na9 O20 2.532(12) 4
Na9 O20 2.532(12) 6_665
Na9 Na2 3.247(7) 3_565
Na9 Na2 3.247(7) 2_665
Na9 Na7 3.362(7) 5_565
Na9 Na7 3.362(7) 4
Na10 O17 2.548(14) 5_564
Na10 O17 2.548(14) 4_554
Na10 O17 2.548(14) 6_664
Na10 O13 2.807(15) .
Na10 O13 2.807(15) 3_565
Na10 O13 2.807(15) 2_665
Na10 Na3 3.320(7) 4_554
Na10 Na3 3.320(7) 5_564
Na10 Na3 3.320(7) 6_664
Na10 Yb4 3.368(17) 4_554
Na10 Na8 3.451(8) 3_565
Na11 O2 2.581(17) 5_554
Na11 O2 2.581(17) 6_554
Na11 O2 2.581(17) 4_554
Na11 O5 2.667(17) .
Na11 O5 2.667(17) 3
Na11 O5 2.667(17) 2
Na11 Na6 3.332(10) 5_554
Na11 Na6 3.332(10) 6_554
Na11 Na6 3.332(10) 4_554
Na11 Yb5 3.40(2) 4_554
Na11 Na5 3.458(8) 3
O2 Na6 2.353(6) 2
O2 Na11 2.581(17) 4
O4 Yb1 2.179(5) 6
O4 Na5 2.637(7) 4
O6 Yb2 2.178(5) 4_554
O7 Na6 2.400(7) 4_554
O7 Na5 2.450(6) 2
O9 Yb1 2.180(4) 6
O9 Na3 2.430(6) 2
O9 Na7 2.499(6) 4
O10 Na2 2.970(7) 3_565
O11 Yb2 2.222(5) 3_565
O11 Na1 2.435(12) 3_565
O11 Na2 2.443(7) 3_565
O12 Na3 2.579(7) 4_554
O13 Na8 2.279(6) 3_565
O14 Yb2 2.275(5) 5_564
O14 Na7 2.295(6) 2
O14 Na1 2.583(13) 3_565
O14 Na8 2.818(6) 3_565
O14 Na3 2.869(7) 4_554
O16 Yb1 2.239(5) 4
O16 Na4 2.410(11) 3
O17 Na10 2.548(14) 4
O18 Na3 2.381(6) 3_665
O18 Na8 2.407(7) 4
O19 Yb1 2.256(5) 3
O19 Na4 2.276(12) 3
O20 Na9 2.532(12) 4_554
O21 Yb2 2.206(4) 4_554
O21 Na2 2.350(6) 4_554
O21 Na7 2.586(7) 3_665
