#------------------------------------------------------------------------------
#$Date: 2021-09-06 12:57:51 +0300 (Mon, 06 Sep 2021) $
#$Revision: 268618 $
#$URL: file:///home/coder/svn-repositories/cod/cif/1/56/21/1562120.cif $
#------------------------------------------------------------------------------
#
# This file is available in the Crystallography Open Database (COD),
# http://www.crystallography.net/
#
# All data on this site have been placed in the public domain by the
# contributors.
#
data_1562120
loop_
_publ_author_name
'Lin, Shengjia'
'Wang, Lucia'
'Sharma, Abhishek'
_publ_section_title
;
 Acrylic boronate: a multifunctional C3 building block for catalytic
 synthesis of rare organoborons and chemoselective heterobifunctional
 ligations.
;
_journal_issue                   22
_journal_name_full               'Chemical science'
_journal_page_first              7924
_journal_page_last               7929
_journal_paper_doi               10.1039/d1sc00905b
_journal_volume                  12
_journal_year                    2021
_chemical_formula_moiety         'C20 H18 B N3 O4'
_chemical_formula_sum            'C20 H18 B N3 O4'
_chemical_formula_weight         375.18
_space_group_crystal_system      monoclinic
_space_group_IT_number           14
_space_group_name_Hall           '-P 2ybc'
_space_group_name_H-M_alt        'P 1 21/c 1'
_atom_sites_solution_hydrogens   geom
_atom_sites_solution_primary     dual
_audit_creation_date             2020-12-30
_audit_creation_method
;
Olex2 1.2
(compiled 2018.05.29 svn.r3508 for OlexSys, GUI svn.r5506)
;
_audit_update_record
;
2021-02-05 deposited with the CCDC.	2021-04-26 downloaded from the CCDC.
;
_cell_angle_alpha                90
_cell_angle_beta                 94.910(11)
_cell_angle_gamma                90
_cell_formula_units_Z            4
_cell_length_a                   17.1144(19)
_cell_length_b                   9.3148(9)
_cell_length_c                   12.0484(17)
_cell_measurement_reflns_used    1006
_cell_measurement_temperature    292.9(5)
_cell_measurement_theta_max      53.8950
_cell_measurement_theta_min      5.0700
_cell_volume                     1913.7(4)
_computing_cell_refinement       'CrysAlisPro 1.171.39.46 (Rigaku OD, 2018)'
_computing_data_collection       'CrysAlisPro 1.171.39.46 (Rigaku OD, 2018)'
_computing_data_reduction        'CrysAlisPro 1.171.39.46 (Rigaku OD, 2018)'
_computing_molecular_graphics    'Olex2 (Dolomanov et al., 2009)'
_computing_publication_material  'Olex2 (Dolomanov et al., 2009)'
_computing_structure_refinement  'ShelXL (Sheldrick, 2015)'
_computing_structure_solution    'ShelXT (Sheldrick, 2015)'
_diffrn_ambient_environment      air
_diffrn_ambient_temperature      292.9(5)
_diffrn_detector                 'CCD plate'
_diffrn_detector_area_resol_mean 8.0549
_diffrn_detector_type            EosS2
_diffrn_measured_fraction_theta_full 0.995
_diffrn_measured_fraction_theta_max 0.943
_diffrn_measurement_details
;
List of Runs (angles in degrees, time in seconds):

  # Type    Start    End  Width  tₑₓₚ   ω     θ     κ     φ   Frames
#--------------------------------------------------------------------------
  1  ω    -23.00   7.00   1.00    5.00    --    0.00  77.00   0.00   30
  2  ω    -24.00   7.00   1.00    5.00    --    0.00  57.00 -90.00   31
  3  ω      8.00  45.00   1.00    5.00    --    0.00  77.00   0.00   37
  4  ω     25.00  68.00   1.00    5.00    --    0.00  57.00 -90.00   43
  5  ω   -117.00 -80.00   1.00   20.00    --  -59.50 -94.00-120.00   37
  6  ω    -74.00 -26.00   1.00   20.00    --  -59.50 125.00  90.00   48
  7  ω   -120.00 -93.00   1.00   20.00    --  -59.50 -94.00 -60.00   27
  8  ω   -109.00 -80.00   1.00   20.00    --  -59.50 -94.00-150.00   29
  9  ω    -86.00 -51.00   1.00   20.00    --  -59.50 125.00-180.00   35
 10  ω   -128.00-101.00   1.00   20.00    --  -59.50 -94.00 -90.00   27
 11  ω   -133.00 -86.00   1.00   20.00    --  -59.50 -94.00 -30.00   47
 12  ω    -90.00  14.00   1.00   20.00    --  -59.50  45.00 -90.00  104
 13  ω   -124.00 -81.00   1.00   20.00    --  -59.50 -94.00   0.00   43
 14  ω    100.00 167.00   1.00   20.00    --  119.00  50.00-120.00   67
 15  ω     49.00  87.00   1.00   20.00    --  119.00 -50.00 -60.00   38
 16  ω     69.00 110.00   1.00   20.00    --  119.00-111.00-180.00   41
 17  ω    109.00 134.00   1.00   20.00    --  119.00 111.00 -60.00   25
 18  ω     94.00 174.00   1.00   20.00    --  119.00  50.00 120.00   80
 19  ω     86.00 159.00   1.00   20.00    --  119.00  37.00  30.00   73
 20  ω     93.00 120.00   1.00   20.00    --  119.00  63.00-150.00   27
 21  ω    130.00 155.00   1.00   20.00    --  119.00  63.00-150.00   25
 22  ω     77.00 104.00   1.00   20.00    --  119.00-111.00-150.00   27
 23  ω     50.00 130.00   1.00   20.00    --  119.00 -50.00-150.00   80
 24  ω     48.00 160.00   1.00   20.00    --  119.00 -91.00 -30.00  112
 25  ω     83.00 120.00   1.00   20.00    --  119.00 -77.00-180.00   37
;
_diffrn_measurement_device       'four-circle diffractometer'
_diffrn_measurement_device_type  'SuperNova, Dual, Cu at home/near, EosS2'
_diffrn_measurement_method       'ω scans'
_diffrn_orient_matrix_type
'CrysAlisPro convention (1999,Acta A55,543-557)'
_diffrn_orient_matrix_UB_11      -0.0886526000
_diffrn_orient_matrix_UB_12      -0.0230656000
_diffrn_orient_matrix_UB_13      -0.0277861000
_diffrn_orient_matrix_UB_21      -0.0104231000
_diffrn_orient_matrix_UB_22      -0.0197218000
_diffrn_orient_matrix_UB_23      0.1247003000
_diffrn_orient_matrix_UB_31      -0.0140193000
_diffrn_orient_matrix_UB_32      0.1626671000
_diffrn_orient_matrix_UB_33      0.0113535000
_diffrn_radiation_monochromator  mirror
_diffrn_radiation_probe          x-ray
_diffrn_radiation_type           CuK\a
_diffrn_radiation_wavelength     1.54184
_diffrn_reflns_av_R_equivalents  0.0577
_diffrn_reflns_av_unetI/netI     0.0979
_diffrn_reflns_Laue_measured_fraction_full 0.995
_diffrn_reflns_Laue_measured_fraction_max 0.943
_diffrn_reflns_limit_h_max       21
_diffrn_reflns_limit_h_min       -19
_diffrn_reflns_limit_k_max       11
_diffrn_reflns_limit_k_min       -8
_diffrn_reflns_limit_l_max       14
_diffrn_reflns_limit_l_min       -14
_diffrn_reflns_number            7012
_diffrn_reflns_point_group_measured_fraction_full 0.995
_diffrn_reflns_point_group_measured_fraction_max 0.943
_diffrn_reflns_theta_full        67.684
_diffrn_reflns_theta_max         77.216
_diffrn_reflns_theta_min         5.188
_diffrn_source                   'micro-focus sealed X-ray tube'
_diffrn_source_type              'SuperNova (Cu) X-ray Source'
_exptl_absorpt_coefficient_mu    0.750
_exptl_absorpt_correction_T_max  1.00000
_exptl_absorpt_correction_T_min  0.10338
_exptl_absorpt_correction_type   multi-scan
_exptl_absorpt_process_details
;
CrysAlisPro 1.171.39.46 (Rigaku Oxford Diffraction, 2018)
Empirical absorption correction using spherical harmonics,
 implemented in SCALE3 ABSPACK scaling algorithm.
;
_exptl_crystal_density_diffrn    1.302
_exptl_crystal_description       Plate
_exptl_crystal_F_000             784
_exptl_crystal_size_max          .15
_exptl_crystal_size_mid          .04
_exptl_crystal_size_min          .01
_refine_diff_density_max         0.389
_refine_diff_density_min         -0.279
_refine_diff_density_rms         0.051
_refine_ls_extinction_coef       0.0009(5)
_refine_ls_extinction_expression Fc^*^=kFc[1+0.001xFc²λ³/sin(2θ)]^-1/4^
_refine_ls_extinction_method     'SHELXL-2016/4 (Sheldrick 2016)'
_refine_ls_goodness_of_fit_ref   1.017
_refine_ls_hydrogen_treatment    constr
_refine_ls_matrix_type           full
_refine_ls_number_parameters     255
_refine_ls_number_reflns         3826
_refine_ls_number_restraints     0
_refine_ls_restrained_S_all      1.017
_refine_ls_R_factor_all          0.1838
_refine_ls_R_factor_gt           0.0929
_refine_ls_shift/su_max          0.002
_refine_ls_shift/su_mean         0.000
_refine_ls_structure_factor_coef Fsqd
_refine_ls_weighting_details
'w=1/[σ²(Fo²)+(0.1157P)²+0.1286P] where P=(Fo²+2Fc²)/3'
_refine_ls_weighting_scheme      calc
_refine_ls_wR_factor_gt          0.2320
_refine_ls_wR_factor_ref         0.2818
_reflns_Friedel_coverage         0.000
_reflns_number_gt                1616
_reflns_number_total             3826
_reflns_threshold_expression     'I > 2σ(I)'
_cod_data_source_file            d1sc00905b2.cif
_cod_data_source_block           exp_4256
_cod_depositor_comments
'Adding full bibliography for 1562119--1562120.cif.'
_cod_database_code               1562120
_shelx_shelxl_version_number     2016/4
_shelx_space_group_comment
;
The symmetry employed for this shelxl refinement is uniquely defined
by the following loop, which should always be used as a source of
symmetry information in preference to the above space-group names.
They are only intended as comments.
;
_reflns_odcompleteness_completeness 99.08
_reflns_odcompleteness_iscentric 1
_reflns_odcompleteness_theta     71.98
_olex2_refinement_description
;
1. Fixed Uiso
 At 1.2 times of:
  All C(H) groups, All C(H,H) groups
 At 1.5 times of:
  All C(H,H,H) groups
2.a Secondary CH2 refined with riding coordinates:
 C00B(H00A,H00B), C00F(H00C,H00D)
2.b Aromatic/amide H refined with riding coordinates:
 C00G(H00G), C00J(H00J), C00K(H00K), C00L(H00L), C00M(H00M), C00N(H00N),
 C00O(H00O), C00P(H00P), C00Q(H00Q), C00R(H00R), C00S(H00S)
2.c Idealised Me refined as rotating group:
 C00H(H00E,H00F,H00H)
;
_olex2_date_sample_data_collection 2020-12-28
_olex2_submission_special_instructions 'No special instructions were received'
_oxdiff_exptl_absorpt_empirical_details
;
Empirical correction (ABSPACK) includes:
- Absorption correction using spherical harmonics
- Frame scaling
;
_oxdiff_exptl_absorpt_empirical_full_max 8.818
_oxdiff_exptl_absorpt_empirical_full_min 0.508
loop_
_space_group_symop_operation_xyz
'x, y, z'
'-x, y+1/2, -z+1/2'
'-x, -y, -z'
'x, -y-1/2, z-1/2'
loop_
_atom_site_label
_atom_site_type_symbol
_atom_site_fract_x
_atom_site_fract_y
_atom_site_fract_z
_atom_site_U_iso_or_equiv
_atom_site_adp_type
_atom_site_occupancy
_atom_site_site_symmetry_order
_atom_site_calc_flag
_atom_site_refinement_flags_posn
_atom_site_refinement_flags_adp
_atom_site_refinement_flags_occupancy
_atom_site_disorder_assembly
_atom_site_disorder_group
O001 O 0.4349(2) 0.2335(4) 0.4781(3) 0.0690(10) Uani 1 1 d . . . . .
O002 O 0.47411(19) 0.3856(4) 0.6339(3) 0.0732(11) Uani 1 1 d . . . . .
N003 N 0.3861(2) 0.1857(4) 0.6540(3) 0.0576(10) Uani 1 1 d . . . . .
O004 O 0.5723(2) 0.3233(4) 0.7586(4) 0.0915(13) Uani 1 1 d . . . . .
O005 O 0.4197(2) 0.0196(5) 0.4007(3) 0.0978(14) Uani 1 1 d . . . . .
N006 N 0.2674(2) 0.3652(4) 0.5028(4) 0.0689(12) Uani 1 1 d . . . . .
N007 N 0.2230(2) 0.4777(4) 0.4612(4) 0.0682(12) Uani 1 1 d . . . . .
C008 C 0.3388(3) 0.4202(5) 0.5325(4) 0.0610(13) Uani 1 1 d . . . . .
C009 C 0.4094(3) 0.0983(6) 0.4762(4) 0.0641(14) Uani 1 1 d . . . . .
C00A C 0.5099(3) 0.2977(6) 0.7093(5) 0.0682(14) Uani 1 1 d . . . . .
C00B C 0.4636(3) 0.1636(6) 0.7214(4) 0.0641(14) Uani 1 1 d . . . . .
H00A H 0.455463 0.146843 0.799056 0.077 Uiso 1 1 calc R . . . .
H00B H 0.490907 0.081582 0.693615 0.077 Uiso 1 1 calc R . . . .
C00C C 0.2311(3) 0.7429(6) 0.4279(5) 0.0703(15) Uani 1 1 d . . . . .
C00D C 0.1445(3) 0.4478(6) 0.4182(6) 0.0768(17) Uani 1 1 d . . . . .
C00E C 0.2648(3) 0.6030(5) 0.4636(5) 0.0695(15) Uani 1 1 d . . . . .
C00F C 0.3674(3) 0.0657(5) 0.5734(4) 0.0702(15) Uani 1 1 d . . . . .
H00C H 0.384607 -0.025470 0.605799 0.084 Uiso 1 1 calc R . . . .
H00D H 0.311362 0.060812 0.552973 0.084 Uiso 1 1 calc R . . . .
C00G C 0.3381(3) 0.5687(5) 0.5107(5) 0.0717(15) Uani 1 1 d . . . . .
H00G H 0.379796 0.631833 0.525514 0.086 Uiso 1 1 calc R . . . .
C00H C 0.3231(3) 0.2097(7) 0.7289(5) 0.0777(16) Uani 1 1 d . . . . .
H00E H 0.318324 0.126633 0.775007 0.117 Uiso 1 1 calc GR . . . .
H00F H 0.274400 0.226320 0.685253 0.117 Uiso 1 1 calc GR . . . .
H00H H 0.335875 0.291818 0.775166 0.117 Uiso 1 1 calc GR . . . .
B00I B 0.4067(3) 0.3154(6) 0.5722(5) 0.0585(14) Uani 1 1 d . . . . .
C00J C 0.2558(3) 0.8079(6) 0.3346(6) 0.0877(19) Uani 1 1 d . . . . .
H00J H 0.292612 0.762131 0.294349 0.105 Uiso 1 1 calc R . . . .
C00K C 0.1785(4) 0.8114(7) 0.4874(6) 0.094(2) Uani 1 1 d . . . . .
H00K H 0.161907 0.769246 0.551241 0.113 Uiso 1 1 calc R . . . .
C00L C 0.1740(4) 1.0083(7) 0.3590(8) 0.107(2) Uani 1 1 d . . . . .
H00L H 0.154673 1.097804 0.336129 0.129 Uiso 1 1 calc R . . . .
C00M C 0.1489(4) 0.9476(7) 0.4517(8) 0.105(2) Uani 1 1 d . . . . .
H00M H 0.112507 0.994841 0.491739 0.126 Uiso 1 1 calc R . . . .
C00N C 0.0991(3) 0.3614(7) 0.4801(7) 0.097(2) Uani 1 1 d . . . . .
H00N H 0.118633 0.328251 0.549834 0.116 Uiso 1 1 calc R . . . .
C00O C 0.2263(4) 0.9424(7) 0.2993(7) 0.098(2) Uani 1 1 d . . . . .
H00O H 0.242580 0.985203 0.235443 0.118 Uiso 1 1 calc R . . . .
C00P C 0.1148(4) 0.5004(7) 0.3174(7) 0.107(2) Uani 1 1 d . . . . .
H00P H 0.145112 0.560622 0.276847 0.129 Uiso 1 1 calc R . . . .
C00Q C -0.0054(4) 0.3755(9) 0.3362(9) 0.135(3) Uani 1 1 d . . . . .
H00Q H -0.055876 0.350835 0.308136 0.162 Uiso 1 1 calc R . . . .
C00R C 0.0242(4) 0.3247(8) 0.4368(9) 0.124(3) Uani 1 1 d . . . . .
H00R H -0.006253 0.264485 0.477107 0.148 Uiso 1 1 calc R . . . .
C00S C 0.0397(5) 0.4638(9) 0.2759(8) 0.132(3) Uani 1 1 d . . . . .
H00S H 0.019538 0.498834 0.207097 0.159 Uiso 1 1 calc R . . . .
loop_
_atom_type_symbol
_atom_type_description
_atom_type_scat_dispersion_real
_atom_type_scat_dispersion_imag
_atom_type_scat_source
C C 0.0181 0.0091 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
H H 0.0000 0.0000 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
B B 0.0090 0.0039 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
N N 0.0311 0.0180 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
O O 0.0492 0.0322 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
loop_
_geom_angle_atom_site_label_1
_geom_angle_atom_site_label_2
_geom_angle_atom_site_label_3
_geom_angle
_geom_angle_site_symmetry_1
_geom_angle_site_symmetry_3
_geom_angle_publ_flag
C009 O001 B00I 111.9(4) . . ?
C00A O002 B00I 111.5(4) . . ?
C00B N003 B00I 101.7(4) . . ?
C00F N003 C00B 112.1(4) . . ?
C00F N003 B00I 102.0(4) . . ?
C00H N003 C00B 110.1(4) . . ?
C00H N003 C00F 112.5(4) . . ?
C00H N003 B00I 117.8(4) . . ?
C008 N006 N007 105.6(4) . . ?
N006 N007 C00D 117.4(4) . . ?
N006 N007 C00E 112.0(4) . . ?
C00E N007 C00D 130.5(4) . . ?
N006 C008 C00G 109.4(4) . . ?
N006 C008 B00I 118.6(4) . . ?
C00G C008 B00I 131.7(5) . . ?
O001 C009 C00F 111.5(5) . . ?
O005 C009 O001 121.7(5) . . ?
O005 C009 C00F 126.8(6) . . ?
O002 C00A C00B 111.4(5) . . ?
O004 C00A O002 123.5(5) . . ?
O004 C00A C00B 125.1(5) . . ?
N003 C00B H00A 110.4 . . ?
N003 C00B H00B 110.4 . . ?
C00A C00B N003 106.4(4) . . ?
C00A C00B H00A 110.4 . . ?
C00A C00B H00B 110.4 . . ?
H00A C00B H00B 108.6 . . ?
C00J C00C C00E 119.2(5) . . ?
C00K C00C C00E 121.5(6) . . ?
C00K C00C C00J 119.2(5) . . ?
C00N C00D N007 118.3(6) . . ?
C00P C00D N007 121.3(6) . . ?
C00P C00D C00N 120.4(6) . . ?
N007 C00E C00C 123.8(4) . . ?
N007 C00E C00G 105.6(4) . . ?
C00G C00E C00C 130.5(5) . . ?
N003 C00F H00C 110.6 . . ?
N003 C00F H00D 110.6 . . ?
C009 C00F N003 105.8(4) . . ?
C009 C00F H00C 110.6 . . ?
C009 C00F H00D 110.6 . . ?
H00C C00F H00D 108.7 . . ?
C008 C00G H00G 126.3 . . ?
C00E C00G C008 107.4(5) . . ?
C00E C00G H00G 126.3 . . ?
N003 C00H H00E 109.5 . . ?
N003 C00H H00F 109.5 . . ?
N003 C00H H00H 109.5 . . ?
H00E C00H H00F 109.5 . . ?
H00E C00H H00H 109.5 . . ?
H00F C00H H00H 109.5 . . ?
O001 B00I N003 100.6(4) . . ?
O001 B00I C008 111.7(4) . . ?
O002 B00I O001 108.8(4) . . ?
O002 B00I N003 103.1(4) . . ?
O002 B00I C008 114.1(5) . . ?
C008 B00I N003 117.3(4) . . ?
C00C C00J H00J 119.6 . . ?
C00C C00J C00O 120.8(6) . . ?
C00O C00J H00J 119.6 . . ?
C00C C00K H00K 120.1 . . ?
C00C C00K C00M 119.8(7) . . ?
C00M C00K H00K 120.1 . . ?
C00M C00L H00L 119.2 . . ?
C00O C00L H00L 119.2 . . ?
C00O C00L C00M 121.6(6) . . ?
C00K C00M H00M 120.3 . . ?
C00L C00M C00K 119.5(6) . . ?
C00L C00M H00M 120.3 . . ?
C00D C00N H00N 120.5 . . ?
C00D C00N C00R 119.1(7) . . ?
C00R C00N H00N 120.5 . . ?
C00J C00O H00O 120.5 . . ?
C00L C00O C00J 119.0(7) . . ?
C00L C00O H00O 120.5 . . ?
C00D C00P H00P 120.1 . . ?
C00D C00P C00S 119.7(7) . . ?
C00S C00P H00P 120.1 . . ?
C00R C00Q H00Q 120.1 . . ?
C00R C00Q C00S 119.8(7) . . ?
C00S C00Q H00Q 120.1 . . ?
C00N C00R H00R 119.6 . . ?
C00Q C00R C00N 120.8(8) . . ?
C00Q C00R H00R 119.6 . . ?
C00P C00S H00S 119.9 . . ?
C00Q C00S C00P 120.2(8) . . ?
C00Q C00S H00S 119.9 . . ?
loop_
_geom_bond_atom_site_label_1
_geom_bond_atom_site_label_2
_geom_bond_distance
_geom_bond_site_symmetry_2
_geom_bond_publ_flag
O001 C009 1.332(6) . ?
O001 B00I 1.481(7) . ?
O002 C00A 1.332(6) . ?
O002 B00I 1.471(7) . ?
N003 C00B 1.509(6) . ?
N003 C00F 1.497(6) . ?
N003 C00H 1.481(6) . ?
N003 B00I 1.617(7) . ?
O004 C00A 1.202(6) . ?
O005 C009 1.193(6) . ?
N006 N007 1.364(5) . ?
N006 C008 1.345(6) . ?
N007 C00D 1.426(6) . ?
N007 C00E 1.367(6) . ?
C008 C00G 1.407(7) . ?
C008 B00I 1.561(7) . ?
C009 C00F 1.458(7) . ?
C00A C00B 1.493(7) . ?
C00B H00A 0.9700 . ?
C00B H00B 0.9700 . ?
C00C C00E 1.474(7) . ?
C00C C00J 1.376(8) . ?
C00C C00K 1.357(8) . ?
C00D C00N 1.380(8) . ?
C00D C00P 1.367(9) . ?
C00E C00G 1.370(7) . ?
C00F H00C 0.9700 . ?
C00F H00D 0.9700 . ?
C00G H00G 0.9300 . ?
C00H H00E 0.9600 . ?
C00H H00F 0.9600 . ?
C00H H00H 0.9600 . ?
C00J H00J 0.9300 . ?
C00J C00O 1.404(8) . ?
C00K H00K 0.9300 . ?
C00K C00M 1.419(9) . ?
C00L H00L 0.9300 . ?
C00L C00M 1.355(9) . ?
C00L C00O 1.343(9) . ?
C00M H00M 0.9300 . ?
C00N H00N 0.9300 . ?
C00N C00R 1.386(9) . ?
C00O H00O 0.9300 . ?
C00P H00P 0.9300 . ?
C00P C00S 1.382(9) . ?
C00Q H00Q 0.9300 . ?
C00Q C00R 1.358(11) . ?
C00Q C00S 1.376(10) . ?
C00R H00R 0.9300 . ?
C00S H00S 0.9300 . ?
