#------------------------------------------------------------------------------
#$Date: 2021-05-17 10:03:49 +0300 (Mon, 17 May 2021) $
#$Revision: 265260 $
#$URL: file:///home/coder/svn-repositories/cod/cif/1/56/25/1562572.cif $
#------------------------------------------------------------------------------
#
# This file is available in the Crystallography Open Database (COD),
# http://www.crystallography.net/
#
# All data on this site have been placed in the public domain by the
# contributors.
#
data_1562572
loop_
_publ_author_name
'Wang, Jian'
'Xia, Sheng-Qing'
'Tao, Xu-Tang'
'Schäfer, Marion C.'
'Bobev, Svilen'
_publ_section_title
;
 New ternary phosphides and arsenides. Syntheses, crystal structures,
 physical properties of Eu2ZnP2, Eu2Zn2P3 and Eu2Cd2As3
;
_journal_name_full               'Journal of Solid State Chemistry'
_journal_page_first              116
_journal_page_last               121
_journal_paper_doi               10.1016/j.jssc.2013.06.029
_journal_volume                  205
_journal_year                    2013
_chemical_formula_moiety         'Eu2 Zn2 P3'
_chemical_formula_sum            'Eu2 P3 Zn2'
_chemical_formula_weight         527.57
_space_group_IT_number           12
_space_group_name_Hall           '-C 2y'
_space_group_name_H-M_alt        'C 1 2/m 1'
_symmetry_cell_setting           monoclinic
_symmetry_space_group_name_H-M   'C 1 2/m 1'
_atom_sites_solution_hydrogens   .
_atom_sites_solution_primary     direct
_atom_sites_solution_secondary   difmap
_audit_creation_method           SHELXL-97
_cell_angle_alpha                90.00
_cell_angle_beta                 126.647(4)
_cell_angle_gamma                90.00
_cell_formula_units_Z            4
_cell_length_a                   15.653(5)
_cell_length_b                   4.1271(13)
_cell_length_c                   11.552(4)
_cell_measurement_reflns_used    967
_cell_measurement_temperature    200(2)
_cell_measurement_theta_max      28.05
_cell_measurement_theta_min      4.89
_cell_volume                     598.8(3)
_computing_cell_refinement       'Bruker SMART'
_computing_data_collection       'Bruker SMART'
_computing_data_reduction        'Bruker SAINT'
_computing_molecular_graphics    'Bruker SHELXTL'
_computing_publication_material  'Bruker SHELXTL'
_computing_structure_refinement  'SHELXL-97 (Sheldrick, 1997)'
_computing_structure_solution    'SHELXS-97 (Sheldrick, 1990)'
_diffrn_ambient_temperature      200(2)
_diffrn_measured_fraction_theta_full 0.998
_diffrn_measured_fraction_theta_max 0.998
_diffrn_measurement_device_type  'CCD area detector'
_diffrn_measurement_method       'phi and omega scans'
_diffrn_radiation_monochromator  graphite
_diffrn_radiation_source         'fine-focus sealed tube'
_diffrn_radiation_type           MoK\a
_diffrn_radiation_wavelength     0.71073
_diffrn_reflns_av_R_equivalents  0.0556
_diffrn_reflns_av_sigmaI/netI    0.0454
_diffrn_reflns_limit_h_max       20
_diffrn_reflns_limit_h_min       -20
_diffrn_reflns_limit_k_max       5
_diffrn_reflns_limit_k_min       -5
_diffrn_reflns_limit_l_max       15
_diffrn_reflns_limit_l_min       -15
_diffrn_reflns_number            3812
_diffrn_reflns_theta_full        28.29
_diffrn_reflns_theta_max         28.29
_diffrn_reflns_theta_min         2.20
_exptl_absorpt_coefficient_mu    29.226
_exptl_absorpt_correction_T_max  0.6521
_exptl_absorpt_correction_T_min  0.1979
_exptl_absorpt_correction_type   multi-scan
_exptl_absorpt_process_details   'SADABS (Sheldrick, 2003)'
_exptl_crystal_colour            black
_exptl_crystal_density_diffrn    5.852
_exptl_crystal_density_method    'not measured'
_exptl_crystal_description       irregular
_exptl_crystal_F_000             924
_exptl_crystal_size_max          0.08
_exptl_crystal_size_mid          0.03
_exptl_crystal_size_min          0.02
_refine_diff_density_max         1.565
_refine_diff_density_min         -1.698
_refine_diff_density_rms         0.377
_refine_ls_extinction_coef       0.00090(10)
_refine_ls_extinction_expression Fc^*^=kFc[1+0.001xFc²λ³/sin(2θ)]^-1/4^
_refine_ls_extinction_method     SHELXL
_refine_ls_goodness_of_fit_ref   1.025
_refine_ls_hydrogen_treatment    .
_refine_ls_matrix_type           full
_refine_ls_number_parameters     44
_refine_ls_number_reflns         845
_refine_ls_number_restraints     0
_refine_ls_restrained_S_all      1.025
_refine_ls_R_factor_all          0.0378
_refine_ls_R_factor_gt           0.0292
_refine_ls_shift/su_max          0.000
_refine_ls_shift/su_mean         0.000
_refine_ls_structure_factor_coef Fsqd
_refine_ls_weighting_details
'calc w=1/[σ²(Fo²)+(0.0256P)²] where P=(Fo²+2Fc²)/3'
_refine_ls_weighting_scheme      calc
_refine_ls_wR_factor_gt          0.0597
_refine_ls_wR_factor_ref         0.0637
_reflns_number_gt                718
_reflns_number_total             845
_reflns_threshold_expression     >2sigma(I)
_cod_data_source_file            JSSC-2013-205-116.cif
_cod_data_source_block           I
_cod_depositor_comments
;
The following automatic conversions were performed:

data item '_symmetry_cell_setting' value 'Monoclinic' was changed to
'monoclinic' in accordance with the built-in table derived from the
CIF Core dictionary named 'cif_core.dic' version 2.4.5 last updated
on 2014-11-21.

Automatic conversion script
Id: cif_fix_values 8369 2020-08-20 11:38:08Z andrius 
;
_cod_original_sg_symbol_H-M      C2/m
_cod_database_code               1562572
loop_
_symmetry_equiv_pos_as_xyz
'x, y, z'
'-x, y, -z'
'x+1/2, y+1/2, z'
'-x+1/2, y+1/2, -z'
'-x, -y, -z'
'x, -y, z'
'-x+1/2, -y+1/2, -z'
'x+1/2, -y+1/2, z'
loop_
_atom_site_label
_atom_site_type_symbol
_atom_site_fract_x
_atom_site_fract_y
_atom_site_fract_z
_atom_site_U_iso_or_equiv
_atom_site_adp_type
_atom_site_occupancy
_atom_site_symmetry_multiplicity
_atom_site_calc_flag
_atom_site_refinement_flags
_atom_site_disorder_assembly
_atom_site_disorder_group
Eu1 Eu 0.26968(4) 0.0000 0.66711(6) 0.00825(17) Uani 1 2 d S . .
Eu2 Eu 0.39134(4) 0.0000 0.04781(6) 0.00892(17) Uani 1 2 d S . .
Zn1 Zn 0.04032(10) 0.0000 0.31618(14) 0.0103(3) Uani 1 2 d S . .
Zn2 Zn 0.40964(10) 0.0000 0.34825(14) 0.0105(3) Uani 1 2 d S . .
P1 P 0.0711(2) 0.0000 0.1171(3) 0.0082(6) Uani 1 2 d S . .
P2 P 0.1510(2) 0.0000 0.7962(3) 0.0080(6) Uani 1 2 d S . .
P3 P 0.3875(2) 0.0000 0.5401(3) 0.0081(6) Uani 1 2 d S . .
loop_
_atom_type_symbol
_atom_type_description
_atom_type_scat_dispersion_real
_atom_type_scat_dispersion_imag
_atom_type_scat_source
P P 0.1023 0.0942 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
Zn Zn 0.2839 1.4301 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
Eu Eu -0.1578 3.6682 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
loop_
_geom_angle_atom_site_label_1
_geom_angle_atom_site_label_2
_geom_angle_atom_site_label_3
_geom_angle
_geom_angle_site_symmetry_1
_geom_angle_site_symmetry_3
P3 Eu1 P2 179.87(8) . .
P3 Eu1 P3 93.50(7) . 7_546
P2 Eu1 P3 86.59(7) . 7_546
P3 Eu1 P3 93.50(7) . 7_556
P2 Eu1 P3 86.59(7) . 7_556
P3 Eu1 P3 86.86(8) 7_546 7_556
P3 Eu1 P1 87.60(7) . 7_556
P2 Eu1 P1 92.31(7) . 7_556
P3 Eu1 P1 178.63(7) 7_546 7_556
P3 Eu1 P1 93.89(6) 7_556 7_556
P3 Eu1 P1 87.60(7) . 7_546
P2 Eu1 P1 92.31(7) . 7_546
P3 Eu1 P1 93.89(6) 7_546 7_546
P3 Eu1 P1 178.63(7) 7_556 7_546
P1 Eu1 P1 85.34(8) 7_556 7_546
P3 Eu1 Zn2 135.40(4) . 7_546
P2 Eu1 Zn2 44.67(4) . 7_546
P3 Eu1 Zn2 44.24(6) 7_546 7_546
P3 Eu1 Zn2 96.75(5) 7_556 7_546
P1 Eu1 Zn2 134.48(6) 7_556 7_546
P1 Eu1 Zn2 83.02(5) 7_546 7_546
P3 Eu1 Zn2 135.40(4) . 7_556
P2 Eu1 Zn2 44.67(4) . 7_556
P3 Eu1 Zn2 96.75(5) 7_546 7_556
P3 Eu1 Zn2 44.24(6) 7_556 7_556
P1 Eu1 Zn2 83.02(5) 7_556 7_556
P1 Eu1 Zn2 134.48(6) 7_546 7_556
Zn2 Eu1 Zn2 74.68(4) 7_546 7_556
P3 Eu1 Zn1 86.39(7) . .
P2 Eu1 Zn1 93.74(7) . .
P3 Eu1 Zn1 44.08(4) 7_546 .
P3 Eu1 Zn1 44.08(4) 7_556 .
P1 Eu1 Zn1 136.88(4) 7_556 .
P1 Eu1 Zn1 136.88(4) 7_546 .
Zn2 Eu1 Zn1 72.05(3) 7_546 .
Zn2 Eu1 Zn1 72.05(3) 7_556 .
P3 Eu1 Zn1 43.45(4) . 7_556
P2 Eu1 Zn1 136.48(4) . 7_556
P3 Eu1 Zn1 135.10(6) 7_546 7_556
P3 Eu1 Zn1 84.51(5) 7_556 7_556
P1 Eu1 Zn1 46.17(6) 7_556 7_556
P1 Eu1 Zn1 95.75(5) 7_546 7_556
Zn2 Eu1 Zn1 178.44(2) 7_546 7_556
Zn2 Eu1 Zn1 106.88(3) 7_556 7_556
Zn1 Eu1 Zn1 108.40(3) . 7_556
P3 Eu1 Zn1 43.45(4) . 7_546
P2 Eu1 Zn1 136.48(4) . 7_546
P3 Eu1 Zn1 84.51(5) 7_546 7_546
P3 Eu1 Zn1 135.10(6) 7_556 7_546
P1 Eu1 Zn1 95.75(5) 7_556 7_546
P1 Eu1 Zn1 46.17(6) 7_546 7_546
Zn2 Eu1 Zn1 106.88(3) 7_546 7_546
Zn2 Eu1 Zn1 178.44(2) 7_556 7_546
Zn1 Eu1 Zn1 108.40(3) . 7_546
Zn1 Eu1 Zn1 71.56(4) 7_556 7_546
P3 Eu1 Eu2 124.95(6) . 1_556
P2 Eu1 Eu2 54.92(6) . 1_556
P3 Eu1 Eu2 123.93(5) 7_546 1_556
P3 Eu1 Eu2 123.93(5) 7_556 1_556
P1 Eu1 Eu2 54.71(5) 7_556 1_556
P1 Eu1 Eu2 54.71(5) 7_546 1_556
Zn2 Eu1 Eu2 83.23(3) 7_546 1_556
Zn2 Eu1 Eu2 83.23(3) 7_556 1_556
Zn1 Eu1 Eu2 148.66(3) . 1_556
Zn1 Eu1 Eu2 96.84(3) 7_556 1_556
Zn1 Eu1 Eu2 96.84(3) 7_546 1_556
P2 Eu2 P2 84.75(7) 7_556 7_546
P2 Eu2 P2 89.08(7) 7_556 1_554
P2 Eu2 P2 89.08(7) 7_546 1_554
P2 Eu2 P1 178.57(8) 7_556 7_545
P2 Eu2 P1 95.77(5) 7_546 7_545
P2 Eu2 P1 89.59(7) 1_554 7_545
P2 Eu2 P1 95.77(5) 7_556 7
P2 Eu2 P1 178.57(8) 7_546 7
P2 Eu2 P1 89.59(7) 1_554 7
P1 Eu2 P1 83.67(7) 7_545 7
P2 Eu2 P1 83.37(6) 7_556 3
P2 Eu2 P1 139.35(7) 7_546 3
P2 Eu2 P1 129.32(5) 1_554 3
P1 Eu2 P1 97.05(4) 7_545 3
P1 Eu2 P1 42.08(10) 7 3
P2 Eu2 P1 139.35(7) 7_556 3_545
P2 Eu2 P1 83.37(6) 7_546 3_545
P2 Eu2 P1 129.32(5) 1_554 3_545
P1 Eu2 P1 42.08(10) 7_545 3_545
P1 Eu2 P1 97.05(4) 7 3_545
P1 Eu2 P1 80.85(7) 3 3_545
P2 Eu2 Zn1 45.46(6) 7_556 3
P2 Eu2 Zn1 98.62(6) 7_546 3
P2 Eu2 Zn1 132.17(3) 1_554 3
P1 Eu2 Zn1 135.65(6) 7_545 3
P1 Eu2 Zn1 82.68(5) 7 3
P1 Eu2 Zn1 47.83(5) 3 3
P1 Eu2 Zn1 98.50(5) 3_545 3
P2 Eu2 Zn1 98.62(6) 7_556 3_545
P2 Eu2 Zn1 45.46(6) 7_546 3_545
P2 Eu2 Zn1 132.17(3) 1_554 3_545
P1 Eu2 Zn1 82.68(5) 7_545 3_545
P1 Eu2 Zn1 135.65(6) 7 3_545
P1 Eu2 Zn1 98.50(5) 3 3_545
P1 Eu2 Zn1 47.83(5) 3_545 3_545
Zn1 Eu2 Zn1 78.32(4) 3 3_545
P2 Eu2 Zn2 45.24(4) 7_556 .
P2 Eu2 Zn2 45.24(4) 7_546 .
P2 Eu2 Zn2 106.36(6) 1_554 .
P1 Eu2 Zn2 135.80(4) 7_545 .
P1 Eu2 Zn2 135.80(4) 7 .
P1 Eu2 Zn2 103.08(6) 3 .
P1 Eu2 Zn2 103.08(6) 3_545 .
Zn1 Eu2 Zn2 55.85(3) 3 .
Zn1 Eu2 Zn2 55.85(3) 3_545 .
P2 Eu2 Eu1 125.20(5) 7_556 1_554
P2 Eu2 Eu1 125.20(5) 7_546 1_554
P2 Eu2 Eu1 52.53(5) 1_554 1_554
P1 Eu2 Eu1 53.44(5) 7_545 1_554
P1 Eu2 Eu1 53.44(5) 7 1_554
P1 Eu2 Eu1 92.91(5) 3 1_554
P1 Eu2 Eu1 92.91(5) 3_545 1_554
Zn1 Eu2 Eu1 135.75(2) 3 1_554
Zn1 Eu2 Eu1 135.75(2) 3_545 1_554
Zn2 Eu2 Eu1 158.88(3) . 1_554
P2 Eu2 Eu2 47.62(4) 7_556 1_565
P2 Eu2 Eu2 132.38(4) 7_546 1_565
P2 Eu2 Eu2 90.0 1_554 1_565
P1 Eu2 Eu2 131.84(4) 7_545 1_565
P1 Eu2 Eu2 48.16(4) 7 1_565
P1 Eu2 Eu2 49.57(3) 3 1_565
P1 Eu2 Eu2 130.43(3) 3_545 1_565
Zn1 Eu2 Eu2 50.839(19) 3 1_565
Zn1 Eu2 Eu2 129.162(19) 3_545 1_565
Zn2 Eu2 Eu2 90.0 . 1_565
Eu1 Eu2 Eu2 90.0 1_554 1_565
P2 Zn1 P3 106.33(8) 5_556 7_556
P2 Zn1 P3 106.33(8) 5_556 7_546
P3 Zn1 P3 114.04(12) 7_556 7_546
P2 Zn1 P1 110.01(10) 5_556 .
P3 Zn1 P1 109.98(8) 7_556 .
P3 Zn1 P1 109.98(7) 7_546 .
P2 Zn1 Zn2 51.29(5) 5_556 3_445
P3 Zn1 Zn2 123.47(8) 7_556 3_445
P3 Zn1 Zn2 55.07(7) 7_546 3_445
P1 Zn1 Zn2 126.14(5) . 3_445
P2 Zn1 Zn2 51.29(5) 5_556 3_455
P3 Zn1 Zn2 55.07(7) 7_556 3_455
P3 Zn1 Zn2 123.47(8) 7_546 3_455
P1 Zn1 Zn2 126.14(5) . 3_455
Zn2 Zn1 Zn2 84.14(5) 3_445 3_455
P2 Zn1 Eu2 62.83(5) 5_556 3_445
P3 Zn1 Eu2 161.85(7) 7_556 3_445
P3 Zn1 Eu2 83.73(6) 7_546 3_445
P1 Zn1 Eu2 64.37(5) . 3_445
Zn2 Zn1 Eu2 62.73(3) 3_445 3_445
Zn2 Zn1 Eu2 112.84(5) 3_455 3_445
P2 Zn1 Eu2 62.83(5) 5_556 3_455
P3 Zn1 Eu2 83.73(6) 7_556 3_455
P3 Zn1 Eu2 161.85(7) 7_546 3_455
P1 Zn1 Eu2 64.37(5) . 3_455
Zn2 Zn1 Eu2 112.84(5) 3_445 3_455
Zn2 Zn1 Eu2 62.73(3) 3_455 3_455
Eu2 Zn1 Eu2 78.32(4) 3_445 3_455
P2 Zn1 Eu1 134.92(8) 5_556 .
P3 Zn1 Eu1 58.09(6) 7_556 .
P3 Zn1 Eu1 58.09(6) 7_546 .
P1 Zn1 Eu1 115.07(8) . .
Zn2 Zn1 Eu1 99.11(4) 3_445 .
Zn2 Zn1 Eu1 99.11(4) 3_455 .
Eu2 Zn1 Eu1 140.01(2) 3_445 .
Eu2 Zn1 Eu1 140.01(2) 3_455 .
P2 Zn1 Eu1 138.77(4) 5_556 7_556
P3 Zn1 Eu1 55.94(7) 7_556 7_556
P3 Zn1 Eu1 114.89(8) 7_546 7_556
P1 Zn1 Eu1 57.10(5) . 7_556
Zn2 Zn1 Eu1 169.66(5) 3_445 7_556
Zn2 Zn1 Eu1 101.55(3) 3_455 7_556
Eu2 Zn1 Eu1 121.47(4) 3_445 7_556
Eu2 Zn1 Eu1 77.50(3) 3_455 7_556
Eu1 Zn1 Eu1 71.60(3) . 7_556
P2 Zn1 Eu1 138.77(4) 5_556 7_546
P3 Zn1 Eu1 114.89(8) 7_556 7_546
P3 Zn1 Eu1 55.94(7) 7_546 7_546
P1 Zn1 Eu1 57.10(5) . 7_546
Zn2 Zn1 Eu1 101.55(3) 3_445 7_546
Zn2 Zn1 Eu1 169.66(5) 3_455 7_546
Eu2 Zn1 Eu1 77.50(3) 3_445 7_546
Eu2 Zn1 Eu1 121.47(4) 3_455 7_546
Eu1 Zn1 Eu1 71.60(3) . 7_546
Eu1 Zn1 Eu1 71.56(4) 7_556 7_546
P3 Zn2 P2 114.17(7) . 7_546
P3 Zn2 P2 114.17(7) . 7_556
P2 Zn2 P2 114.03(12) 7_546 7_556
P3 Zn2 P3 109.93(9) . 5_656
P2 Zn2 P3 101.41(8) 7_546 5_656
P2 Zn2 P3 101.41(8) 7_556 5_656
P3 Zn2 Zn2 57.86(8) . 5_656
P2 Zn2 Zn2 121.45(6) 7_546 5_656
P2 Zn2 Zn2 121.45(6) 7_556 5_656
P3 Zn2 Zn2 52.07(7) 5_656 5_656
P3 Zn2 Zn1 125.04(5) . 3
P2 Zn2 Zn1 119.72(8) 7_546 3
P2 Zn2 Zn1 51.08(7) 7_556 3
P3 Zn2 Zn1 50.36(4) 5_656 3
Zn2 Zn2 Zn1 84.67(5) 5_656 3
P3 Zn2 Zn1 125.04(5) . 3_545
P2 Zn2 Zn1 51.08(7) 7_546 3_545
P2 Zn2 Zn1 119.72(8) 7_556 3_545
P3 Zn2 Zn1 50.36(4) 5_656 3_545
Zn2 Zn2 Zn1 84.67(5) 5_656 3_545
Zn1 Zn2 Zn1 84.14(5) 3 3_545
P3 Zn2 Eu2 169.46(9) . .
P2 Zn2 Eu2 62.09(6) 7_546 .
P2 Zn2 Eu2 62.09(6) 7_556 .
P3 Zn2 Eu2 80.61(7) 5_656 .
Zn2 Zn2 Eu2 132.68(7) 5_656 .
Zn1 Zn2 Eu2 61.42(3) 3 .
Zn1 Zn2 Eu2 61.42(3) 3_545 .
P3 Zn2 Eu1 59.14(5) . 7_546
P2 Zn2 Eu1 58.89(7) 7_546 7_546
P2 Zn2 Eu1 120.05(8) 7_556 7_546
P3 Zn2 Eu1 138.24(4) 5_656 7_546
Zn2 Zn2 Eu1 103.97(5) 5_656 7_546
Zn1 Zn2 Eu1 170.66(5) 3 7_546
Zn1 Zn2 Eu1 100.01(3) 3_545 7_546
Eu2 Zn2 Eu1 113.16(3) . 7_546
P3 Zn2 Eu1 59.14(5) . 7_556
P2 Zn2 Eu1 120.05(8) 7_546 7_556
P2 Zn2 Eu1 58.89(7) 7_556 7_556
P3 Zn2 Eu1 138.24(4) 5_656 7_556
Zn2 Zn2 Eu1 103.97(5) 5_656 7_556
Zn1 Zn2 Eu1 100.01(3) 3 7_556
Zn1 Zn2 Eu1 170.66(5) 3_545 7_556
Eu2 Zn2 Eu1 113.16(3) . 7_556
Eu1 Zn2 Eu1 74.68(4) 7_546 7_556
P1 P1 Zn1 119.16(18) 5 .
P1 P1 Eu1 136.21(5) 5 7_556
Zn1 P1 Eu1 76.73(7) . 7_556
P1 P1 Eu1 136.21(5) 5 7_546
Zn1 P1 Eu1 76.73(7) . 7_546
Eu1 P1 Eu1 85.34(7) 7_556 7_546
P1 P1 Eu2 71.06(10) 5 7_545
Zn1 P1 Eu2 138.06(4) . 7_545
Eu1 P1 Eu2 126.34(9) 7_556 7_545
Eu1 P1 Eu2 71.85(4) 7_546 7_545
P1 P1 Eu2 71.06(10) 5 7
Zn1 P1 Eu2 138.06(4) . 7
Eu1 P1 Eu2 71.85(4) 7_556 7
Eu1 P1 Eu2 126.34(9) 7_546 7
Eu2 P1 Eu2 83.67(7) 7_545 7
P1 P1 Eu2 66.86(10) 5 3_445
Zn1 P1 Eu2 67.79(6) . 3_445
Eu1 P1 Eu2 144.52(10) 7_556 3_445
Eu1 P1 Eu2 86.29(4) 7_546 3_445
Eu2 P1 Eu2 82.95(4) 7_545 3_445
Eu2 P1 Eu2 137.92(10) 7 3_445
P1 P1 Eu2 66.86(10) 5 3_455
Zn1 P1 Eu2 67.79(6) . 3_455
Eu1 P1 Eu2 86.29(4) 7_556 3_455
Eu1 P1 Eu2 144.52(10) 7_546 3_455
Eu2 P1 Eu2 137.92(10) 7_545 3_455
Eu2 P1 Eu2 82.95(4) 7 3_455
Eu2 P1 Eu2 80.85(7) 3_445 3_455
Zn1 P2 Zn2 77.63(8) 5_556 7_546
Zn1 P2 Zn2 77.63(8) 5_556 7_556
Zn2 P2 Zn2 114.03(12) 7_546 7_556
Zn1 P2 Eu1 131.35(11) 5_556 .
Zn2 P2 Eu1 76.45(7) 7_546 .
Zn2 P2 Eu1 76.45(7) 7_556 .
Zn1 P2 Eu2 71.71(6) 5_556 7_556
Zn2 P2 Eu2 146.40(11) 7_546 7_556
Zn2 P2 Eu2 72.68(5) 7_556 7_556
Eu1 P2 Eu2 135.18(5) . 7_556
Zn1 P2 Eu2 71.71(6) 5_556 7_546
Zn2 P2 Eu2 72.68(5) 7_546 7_546
Zn2 P2 Eu2 146.40(11) 7_556 7_546
Eu1 P2 Eu2 135.18(5) . 7_546
Eu2 P2 Eu2 84.75(7) 7_556 7_546
Zn1 P2 Eu2 156.10(12) 5_556 1_556
Zn2 P2 Eu2 113.49(7) 7_546 1_556
Zn2 P2 Eu2 113.49(7) 7_556 1_556
Eu1 P2 Eu2 72.55(7) . 1_556
Eu2 P2 Eu2 90.92(7) 7_556 1_556
Eu2 P2 Eu2 90.92(7) 7_546 1_556
Zn2 P3 Zn1 110.85(8) . 7_556
Zn2 P3 Zn1 110.85(8) . 7_546
Zn1 P3 Zn1 114.04(12) 7_556 7_546
Zn2 P3 Zn2 70.07(9) . 5_656
Zn1 P3 Zn2 74.58(7) 7_556 5_656
Zn1 P3 Zn2 74.58(7) 7_546 5_656
Zn2 P3 Eu1 156.60(12) . .
Zn1 P3 Eu1 80.62(7) 7_556 .
Zn1 P3 Eu1 80.62(7) 7_546 .
Zn2 P3 Eu1 133.33(11) 5_656 .
Zn2 P3 Eu1 76.63(7) . 7_546
Zn1 P3 Eu1 160.48(11) 7_556 7_546
Zn1 P3 Eu1 77.83(4) 7_546 7_546
Zn2 P3 Eu1 124.63(7) 5_656 7_546
Eu1 P3 Eu1 86.50(7) . 7_546
Zn2 P3 Eu1 76.63(7) . 7_556
Zn1 P3 Eu1 77.83(4) 7_556 7_556
Zn1 P3 Eu1 160.48(11) 7_546 7_556
Zn2 P3 Eu1 124.63(7) 5_656 7_556
Eu1 P3 Eu1 86.50(7) . 7_556
Eu1 P3 Eu1 86.86(8) 7_546 7_556
loop_
_geom_bond_atom_site_label_1
_geom_bond_atom_site_label_2
_geom_bond_distance
_geom_bond_site_symmetry_2
Eu1 P3 2.963(3) .
Eu1 P2 2.996(3) .
Eu1 P3 3.002(2) 7_546
Eu1 P3 3.002(2) 7_556
Eu1 P1 3.045(2) 7_556
Eu1 P1 3.045(2) 7_546
Eu1 Zn2 3.4021(13) 7_546
Eu1 Zn2 3.4021(13) 7_556
Eu1 Zn1 3.4568(16) .
Eu2 P2 3.062(2) 7_556
Eu2 P2 3.062(2) 7_546
Eu2 P2 3.090(3) 1_554
Eu2 P1 3.094(2) 7_545
Eu2 P1 3.094(2) 7
Eu2 P1 3.182(2) 3
Eu2 P1 3.182(2) 3_545
Eu2 Zn1 3.2676(13) 3
Eu2 Zn1 3.2676(13) 3_545
Eu2 Zn2 3.3077(17) .
Zn1 P2 2.453(3) 5_556
Zn1 P3 2.4600(18) 7_556
Zn1 P3 2.4600(18) 7_546
Zn1 P1 2.616(3) .
Zn1 Zn2 3.0796(15) 3_445
Zn1 Zn2 3.0796(15) 3_455
Zn1 Eu2 3.2677(13) 3_445
Zn1 Eu2 3.2676(13) 3_455
Zn2 P3 2.440(3) .
Zn2 P2 2.4601(18) 7_546
Zn2 P2 2.4601(18) 7_556
Zn2 P3 2.619(3) 5_656
Zn2 Zn2 2.908(3) 5_656
Zn2 Zn1 3.0796(15) 3
Zn2 Zn1 3.0796(15) 3_545
Zn2 Eu1 3.4021(13) 7_546
Zn2 Eu1 3.4021(13) 7_556
P1 P1 2.255(6) 5
P1 Eu1 3.044(2) 7_556
P1 Eu1 3.044(2) 7_546
P1 Eu2 3.094(2) 7_545
P1 Eu2 3.094(2) 7
P1 Eu2 3.182(2) 3_445
P1 Eu2 3.182(2) 3_455
P2 Zn1 2.453(3) 5_556
P2 Zn2 2.4601(18) 7_546
P2 Zn2 2.4601(18) 7_556
P2 Eu2 3.062(2) 7_556
P2 Eu2 3.062(2) 7_546
P2 Eu2 3.090(3) 1_556
P3 Zn1 2.4600(18) 7_556
P3 Zn1 2.4600(18) 7_546
P3 Zn2 2.619(3) 5_656
P3 Eu1 3.002(2) 7_546
P3 Eu1 3.002(2) 7_556
