#------------------------------------------------------------------------------
#$Date: 2021-05-17 11:51:31 +0300 (Mon, 17 May 2021) $
#$Revision: 265274 $
#$URL: file:///home/coder/svn-repositories/cod/cif/1/56/26/1562602.cif $
#------------------------------------------------------------------------------
#
# This file is available in the Crystallography Open Database (COD),
# http://www.crystallography.net/
#
# All data on this site have been placed in the public domain by the
# contributors.
#
data_1562602
loop_
_publ_author_name
'Chen, Hong-Xia'
'Ma, Yong'
'Zhou, Feng'
'Wu, Bing'
'Xu, Qing-Feng'
'Lu, Jian-Mei'
'Ge, Jian-Feng'
_publ_section_title
;
 Synthesis, structures of four coordination compounds constructed from
 o-methacrylamidobenzoic acid and their relationship between structure and
 solid state luminescence
;
_journal_name_full               'Journal of Solid State Chemistry'
_journal_page_first              1
_journal_page_last               7
_journal_paper_doi               10.1016/j.jssc.2013.03.055
_journal_volume                  203
_journal_year                    2013
_chemical_formula_moiety         'C70 H52 Cl N10 O6 Pb2, 2(H2 O), Cl'
_chemical_formula_sum            'C70 H56 Cl2 N10 O8 Pb2'
_chemical_formula_weight         1650.53
_space_group_IT_number           15
_space_group_name_Hall           '-C 2yc'
_space_group_name_H-M_alt        'C 1 2/c 1'
_symmetry_cell_setting           monoclinic
_symmetry_Int_Tables_number      15
_symmetry_space_group_name_Hall  '-C 2yc'
_symmetry_space_group_name_H-M   'C 1 2/c 1'
_atom_sites_solution_hydrogens   geom
_atom_sites_solution_primary     direct
_atom_sites_solution_secondary   difmap
_audit_creation_method           SHELXL-97
_cell_angle_alpha                90.00
_cell_angle_beta                 118.263(3)
_cell_angle_gamma                90.00
_cell_formula_units_Z            4
_cell_length_a                   32.394(4)
_cell_length_b                   10.3254(12)
_cell_length_c                   21.126(3)
_cell_measurement_reflns_used    13985
_cell_measurement_temperature    223(2)
_cell_measurement_theta_max      27.5
_cell_measurement_theta_min      3.1
_cell_volume                     6223.8(14)
_computing_cell_refinement       CrystalClear
_computing_data_collection       CrystalClear
_computing_data_reduction        CrystalStructure
_computing_publication_material  'CrystalStructure 3.7.0'
_computing_structure_refinement  'SHELXL-97 (Sheldrick, 1997)'
_computing_structure_solution    'SHELXS-97 (Sheldrick, 1990)'
_diffrn_ambient_temperature      223(2)
_diffrn_detector_area_resol_mean 14.63
_diffrn_measured_fraction_theta_full 0.991
_diffrn_measured_fraction_theta_max 0.991
_diffrn_measurement_device_type  'Rigaku Saturn'
_diffrn_measurement_method       ω
_diffrn_radiation_monochromator  graphite
_diffrn_radiation_source         'fine-focus sealed tube'
_diffrn_radiation_type           MoK\a
_diffrn_radiation_wavelength     0.71075
_diffrn_reflns_av_R_equivalents  0.0475
_diffrn_reflns_av_sigmaI/netI    0.1020
_diffrn_reflns_limit_h_max       34
_diffrn_reflns_limit_h_min       -42
_diffrn_reflns_limit_k_max       13
_diffrn_reflns_limit_k_min       -13
_diffrn_reflns_limit_l_max       27
_diffrn_reflns_limit_l_min       -20
_diffrn_reflns_number            17303
_diffrn_reflns_theta_full        27.49
_diffrn_reflns_theta_max         27.49
_diffrn_reflns_theta_min         3.13
_exptl_absorpt_coefficient_mu    5.556
_exptl_absorpt_correction_T_max  0.427
_exptl_absorpt_correction_T_min  0.150
_exptl_absorpt_correction_type   multi-scan
_exptl_absorpt_process_details   'Jacobson, R. (1998) Private communication'
_exptl_crystal_colour            yellow
_exptl_crystal_density_diffrn    1.761
_exptl_crystal_density_method    'not measured'
_exptl_crystal_description       prism
_exptl_crystal_F_000             3232
_exptl_crystal_size_max          0.60
_exptl_crystal_size_mid          0.40
_exptl_crystal_size_min          0.30
_refine_diff_density_max         2.175
_refine_diff_density_min         -2.289
_refine_diff_density_rms         0.141
_refine_ls_extinction_method     none
_refine_ls_goodness_of_fit_ref   1.068
_refine_ls_hydrogen_treatment    mixed
_refine_ls_matrix_type           full
_refine_ls_number_parameters     425
_refine_ls_number_reflns         7090
_refine_ls_number_restraints     2
_refine_ls_restrained_S_all      1.067
_refine_ls_R_factor_all          0.0654
_refine_ls_R_factor_gt           0.0505
_refine_ls_shift/su_max          0.001
_refine_ls_shift/su_mean         0.000
_refine_ls_structure_factor_coef Fsqd
_refine_ls_weighting_details
'calc w=1/[σ²(Fo²)+(0.0607P)²+0.0000P] where P=(Fo²+2Fc²)/3'
_refine_ls_weighting_scheme      calc
_refine_ls_wR_factor_gt          0.1182
_refine_ls_wR_factor_ref         0.1274
_reflns_number_gt                5755
_reflns_number_total             7090
_reflns_threshold_expression     >2sigma(I)
_cod_data_source_file            JSSC-2013-203-1.cif
_cod_data_source_block           3
_cod_original_cell_volume        6223.9(14)
_cod_original_sg_symbol_H-M      'C 2/c'
_cod_database_code               1562602
loop_
_symmetry_equiv_pos_as_xyz
'x, y, z'
'-x, y, -z+1/2'
'x+1/2, y+1/2, z'
'-x+1/2, y+1/2, -z+1/2'
'-x, -y, -z'
'x, -y, z-1/2'
'-x+1/2, -y+1/2, -z'
'x+1/2, -y+1/2, z-1/2'
loop_
_atom_site_label
_atom_site_type_symbol
_atom_site_fract_x
_atom_site_fract_y
_atom_site_fract_z
_atom_site_U_iso_or_equiv
_atom_site_adp_type
_atom_site_occupancy
_atom_site_symmetry_multiplicity
_atom_site_calc_flag
_atom_site_refinement_flags
_atom_site_disorder_assembly
_atom_site_disorder_group
Pb1 Pb 0.079042(8) 0.09429(2) 0.383051(12) 0.03744(11) Uani 1 1 d . . .
Cl1 Cl 0.0000 0.2394(2) 0.2500 0.0541(6) Uani 1 2 d S . .
Cl2 Cl 0.0000 0.6569(12) 0.2500 0.108(3) Uiso 0.44 2 d SP . .
Cl2A Cl 0.0000 0.753(2) 0.2500 0.118(6) Uiso 0.24 2 d SP . .
Cl2B Cl 0.0000 0.8973(14) 0.2500 0.109(4) Uiso 0.32 2 d SP . .
O1 O 0.12714(17) 0.0891(4) 0.3177(3) 0.0455(11) Uani 1 1 d . . .
O2 O 0.1229(2) -0.1018(5) 0.3608(3) 0.0544(13) Uani 1 1 d . . .
O3 O 0.1830(2) 0.1595(5) 0.1432(3) 0.0615(14) Uani 1 1 d . . .
O4 O 0.0134(3) 0.4615(7) 0.1520(4) 0.0778(17) Uani 1 1 d D . .
H4A H 0.003(3) 0.389(5) 0.158(6) 0.093 Uiso 1 1 d D . .
H4B H 0.017(4) 0.533(5) 0.174(5) 0.093 Uiso 1 1 d D . .
N1 N 0.1613(2) 0.1065(5) 0.2280(3) 0.0378(12) Uani 1 1 d . . .
H1 H 0.1497 0.1404 0.2539 0.045 Uiso 1 1 calc R . .
N2 N 0.07091(18) -0.0832(4) 0.4683(3) 0.0349(12) Uani 1 1 d . . .
N3 N 0.07478(18) 0.1749(5) 0.5054(3) 0.0395(12) Uani 1 1 d . . .
N4 N 0.16238(18) 0.1019(5) 0.4832(3) 0.0384(12) Uani 1 1 d . . .
N5 N 0.11936(18) 0.3215(5) 0.4076(3) 0.0415(12) Uani 1 1 d . . .
C1 C 0.1346(2) -0.0332(7) 0.3235(3) 0.0389(14) Uani 1 1 d . . .
C2 C 0.1589(2) -0.0938(6) 0.2853(3) 0.0360(14) Uani 1 1 d . . .
C3 C 0.1704(2) -0.2252(7) 0.2977(3) 0.0469(16) Uani 1 1 d . . .
H3 H 0.1632 -0.2706 0.3298 0.056 Uiso 1 1 calc R . .
C4 C 0.1919(3) -0.2899(7) 0.2646(4) 0.0515(17) Uani 1 1 d . . .
H4 H 0.1989 -0.3785 0.2733 0.062 Uiso 1 1 calc R . .
C5 C 0.2028(3) -0.2226(7) 0.2185(4) 0.0553(18) Uani 1 1 d . . .
H5 H 0.2176 -0.2660 0.1956 0.066 Uiso 1 1 calc R . .
C6 C 0.1925(3) -0.0923(6) 0.2049(4) 0.0490(18) Uani 1 1 d . . .
H6 H 0.2003 -0.0486 0.1731 0.059 Uiso 1 1 calc R . .
C7 C 0.1704(2) -0.0246(6) 0.2381(3) 0.0347(13) Uani 1 1 d . . .
C8 C 0.1677(2) 0.1916(6) 0.1835(3) 0.0371(14) Uani 1 1 d . . .
C9 C 0.1554(2) 0.3293(6) 0.1874(3) 0.0389(14) Uani 1 1 d . . .
C10 C 0.1698(3) 0.4204(7) 0.1458(4) 0.056(2) Uani 1 1 d . . .
H10A H 0.1584 0.5068 0.1470 0.084 Uiso 1 1 calc R . .
H10B H 0.1565 0.3913 0.0963 0.084 Uiso 1 1 calc R . .
H10C H 0.2037 0.4220 0.1672 0.084 Uiso 1 1 calc R . .
C11 C 0.1317(3) 0.3689(7) 0.2204(4) 0.0499(17) Uani 1 1 d . . .
H11A H 0.1215 0.3085 0.2433 0.060 Uiso 1 1 calc R . .
H11B H 0.1251 0.4574 0.2210 0.060 Uiso 1 1 calc R . .
C12 C 0.0664(2) -0.2067(6) 0.4487(4) 0.0455(15) Uani 1 1 d . . .
H12 H 0.0714 -0.2287 0.4097 0.055 Uiso 1 1 calc R . .
C13 C 0.0548(2) -0.3050(7) 0.4817(4) 0.0514(17) Uani 1 1 d . . .
H13 H 0.0520 -0.3910 0.4657 0.062 Uiso 1 1 calc R . .
C14 C 0.0473(2) -0.2731(7) 0.5389(4) 0.0473(16) Uani 1 1 d . . .
H14 H 0.0395 -0.3378 0.5627 0.057 Uiso 1 1 calc R . .
C15 C 0.0516(2) -0.1446(7) 0.5613(3) 0.0402(14) Uani 1 1 d . . .
C16 C 0.0444(2) -0.1036(8) 0.6206(4) 0.0490(18) Uani 1 1 d . . .
H16 H 0.0370 -0.1660 0.6461 0.059 Uiso 1 1 calc R . .
C17 C 0.0480(2) 0.0192(8) 0.6403(3) 0.0455(16) Uani 1 1 d . . .
H17 H 0.0430 0.0425 0.6791 0.055 Uiso 1 1 calc R . .
C18 C 0.0595(2) 0.1178(7) 0.6031(3) 0.0382(14) Uani 1 1 d . . .
C19 C 0.0622(2) 0.2491(8) 0.6214(4) 0.0513(18) Uani 1 1 d . . .
H19 H 0.0582 0.2752 0.6608 0.062 Uiso 1 1 calc R . .
C20 C 0.0705(3) 0.3379(8) 0.5818(4) 0.0559(19) Uani 1 1 d . . .
H20 H 0.0725 0.4262 0.5937 0.067 Uiso 1 1 calc R . .
C21 C 0.0761(3) 0.2984(7) 0.5234(4) 0.0518(17) Uani 1 1 d . . .
H21 H 0.0809 0.3616 0.4956 0.062 Uiso 1 1 calc R . .
C22 C 0.0662(2) 0.0831(6) 0.5442(3) 0.0322(13) Uani 1 1 d . . .
C23 C 0.06369(19) -0.0508(6) 0.5244(3) 0.0342(13) Uani 1 1 d . . .
C24 C 0.1839(2) -0.0056(7) 0.5169(3) 0.0454(16) Uani 1 1 d . . .
H24 H 0.1680 -0.0850 0.5022 0.054 Uiso 1 1 calc R . .
C25 C 0.2298(3) -0.0044(9) 0.5737(4) 0.058(2) Uani 1 1 d . . .
H25 H 0.2449 -0.0824 0.5953 0.069 Uiso 1 1 calc R . .
C26 C 0.2523(3) 0.1103(9) 0.5971(4) 0.058(2) Uani 1 1 d . . .
H26 H 0.2827 0.1118 0.6362 0.070 Uiso 1 1 calc R . .
C27 C 0.2308(2) 0.2262(8) 0.5640(3) 0.0499(18) Uani 1 1 d . . .
C28 C 0.2526(3) 0.3498(10) 0.5858(4) 0.062(2) Uani 1 1 d . . .
H28 H 0.2829 0.3555 0.6250 0.075 Uiso 1 1 calc R . .
C29 C 0.2305(3) 0.4590(9) 0.5510(4) 0.062(2) Uani 1 1 d . . .
H29 H 0.2450 0.5397 0.5677 0.074 Uiso 1 1 calc R . .
C30 C 0.1850(3) 0.4536(8) 0.4888(4) 0.0514(18) Uani 1 1 d . . .
C31 C 0.1614(3) 0.5635(7) 0.4475(5) 0.057(2) Uani 1 1 d . . .
H31 H 0.1748 0.6462 0.4616 0.069 Uiso 1 1 calc R . .
C32 C 0.1201(3) 0.5496(7) 0.3884(5) 0.0532(18) Uani 1 1 d . . .
H32 H 0.1049 0.6217 0.3596 0.064 Uiso 1 1 calc R . .
C33 C 0.0997(3) 0.4275(6) 0.3701(4) 0.0453(16) Uani 1 1 d . . .
H33 H 0.0704 0.4198 0.3289 0.054 Uiso 1 1 calc R . .
C34 C 0.1626(2) 0.3330(7) 0.4669(3) 0.0416(15) Uani 1 1 d . . .
C35 C 0.1852(2) 0.2173(7) 0.5050(3) 0.0391(14) Uani 1 1 d . . .
loop_
_atom_type_symbol
_atom_type_description
_atom_type_scat_dispersion_real
_atom_type_scat_dispersion_imag
_atom_type_scat_source
C C 0.0033 0.0016 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
H H 0.0000 0.0000 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
N N 0.0061 0.0033 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
O O 0.0106 0.0060 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
Pb Pb -3.3944 10.1111 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
Cl Cl 0.1484 0.1585 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
loop_
_geom_angle_atom_site_label_1
_geom_angle_atom_site_label_2
_geom_angle_atom_site_label_3
_geom_angle
_geom_angle_site_symmetry_1
_geom_angle_site_symmetry_3
N4 Pb1 O1 76.49(16) . .
N4 Pb1 N5 64.53(17) . .
O1 Pb1 N5 75.39(15) . .
N4 Pb1 O2 73.78(17) . .
O1 Pb1 O2 50.43(14) . .
N5 Pb1 O2 117.58(15) . .
N4 Pb1 N2 82.18(16) . .
O1 Pb1 N2 129.67(15) . .
N5 Pb1 N2 132.99(16) . .
O2 Pb1 N2 80.04(14) . .
N4 Pb1 N3 73.49(16) . .
O1 Pb1 N3 146.08(15) . .
N5 Pb1 N3 77.69(16) . .
O2 Pb1 N3 131.53(15) . .
N2 Pb1 N3 60.92(15) . .
C1 O1 Pb1 96.0(4) . .
C1 O2 Pb1 91.5(4) . .
H4A O4 H4B 131(10) . .
C8 N1 C7 130.1(5) . .
C8 N1 H1 114.9 . .
C7 N1 H1 114.9 . .
C12 N2 C23 118.1(6) . .
C12 N2 Pb1 118.8(4) . .
C23 N2 Pb1 122.3(4) . .
C21 N3 C22 118.9(6) . .
C21 N3 Pb1 123.1(4) . .
C22 N3 Pb1 117.7(4) . .
C24 N4 C35 119.2(6) . .
C24 N4 Pb1 120.5(4) . .
C35 N4 Pb1 120.3(4) . .
C33 N5 C34 117.9(6) . .
C33 N5 Pb1 124.7(5) . .
C34 N5 Pb1 117.2(4) . .
O2 C1 O1 121.5(6) . .
O2 C1 C2 119.7(6) . .
O1 C1 C2 118.8(5) . .
C3 C2 C7 119.1(6) . .
C3 C2 C1 117.6(6) . .
C7 C2 C1 123.3(6) . .
C4 C3 C2 122.1(6) . .
C4 C3 H3 118.9 . .
C2 C3 H3 118.9 . .
C3 C4 C5 118.7(7) . .
C3 C4 H4 120.7 . .
C5 C4 H4 120.7 . .
C4 C5 C6 121.3(7) . .
C4 C5 H5 119.3 . .
C6 C5 H5 119.3 . .
C5 C6 C7 120.8(6) . .
C5 C6 H6 119.6 . .
C7 C6 H6 119.6 . .
N1 C7 C6 122.3(5) . .
N1 C7 C2 119.8(5) . .
C6 C7 C2 117.9(6) . .
O3 C8 N1 123.2(6) . .
O3 C8 C9 120.4(6) . .
N1 C8 C9 116.4(5) . .
C11 C9 C8 124.0(6) . .
C11 C9 C10 122.1(6) . .
C8 C9 C10 113.7(6) . .
C9 C10 H10A 109.5 . .
C9 C10 H10B 109.5 . .
H10A C10 H10B 109.5 . .
C9 C10 H10C 109.5 . .
H10A C10 H10C 109.5 . .
H10B C10 H10C 109.5 . .
C9 C11 H11A 120.0 . .
C9 C11 H11B 120.0 . .
H11A C11 H11B 120.0 . .
N2 C12 C13 124.5(7) . .
N2 C12 H12 117.8 . .
C13 C12 H12 117.8 . .
C14 C13 C12 118.0(7) . .
C14 C13 H13 121.0 . .
C12 C13 H13 121.0 . .
C13 C14 C15 119.6(6) . .
C13 C14 H14 120.2 . .
C15 C14 H14 120.2 . .
C14 C15 C23 118.4(6) . .
C14 C15 C16 123.0(6) . .
C23 C15 C16 118.6(6) . .
C17 C16 C15 121.9(6) . .
C17 C16 H16 119.0 . .
C15 C16 H16 119.0 . .
C16 C17 C18 120.9(6) . .
C16 C17 H17 119.5 . .
C18 C17 H17 119.5 . .
C19 C18 C22 118.4(6) . .
C19 C18 C17 122.1(6) . .
C22 C18 C17 119.4(6) . .
C20 C19 C18 119.3(6) . .
C20 C19 H19 120.4 . .
C18 C19 H19 120.4 . .
C19 C20 C21 119.9(7) . .
C19 C20 H20 120.1 . .
C21 C20 H20 120.1 . .
N3 C21 C20 122.5(7) . .
N3 C21 H21 118.7 . .
C20 C21 H21 118.7 . .
N3 C22 C18 121.0(5) . .
N3 C22 C23 119.6(5) . .
C18 C22 C23 119.5(6) . .
N2 C23 C15 121.5(6) . .
N2 C23 C22 118.9(5) . .
C15 C23 C22 119.5(6) . .
N4 C24 C25 121.9(7) . .
N4 C24 H24 119.0 . .
C25 C24 H24 119.0 . .
C26 C25 C24 119.3(7) . .
C26 C25 H25 120.3 . .
C24 C25 H25 120.3 . .
C25 C26 C27 120.8(7) . .
C25 C26 H26 119.6 . .
C27 C26 H26 119.6 . .
C26 C27 C35 116.9(7) . .
C26 C27 C28 123.6(7) . .
C35 C27 C28 119.6(7) . .
C29 C28 C27 121.2(7) . .
C29 C28 H28 119.4 . .
C27 C28 H28 119.4 . .
C28 C29 C30 121.0(8) . .
C28 C29 H29 119.5 . .
C30 C29 H29 119.5 . .
C34 C30 C31 117.6(7) . .
C34 C30 C29 118.8(8) . .
C31 C30 C29 123.6(7) . .
C32 C31 C30 119.9(7) . .
C32 C31 H31 120.0 . .
C30 C31 H31 120.0 . .
C31 C32 C33 119.4(8) . .
C31 C32 H32 120.3 . .
C33 C32 H32 120.3 . .
N5 C33 C32 123.6(7) . .
N5 C33 H33 118.2 . .
C32 C33 H33 118.2 . .
N5 C34 C30 121.5(7) . .
N5 C34 C35 118.0(6) . .
C30 C34 C35 120.4(7) . .
N4 C35 C27 121.9(6) . .
N4 C35 C34 119.2(5) . .
C27 C35 C34 119.0(6) . .
loop_
_geom_bond_atom_site_label_1
_geom_bond_atom_site_label_2
_geom_bond_distance
_geom_bond_site_symmetry_2
Pb1 N4 2.522(5) .
Pb1 O1 2.525(5) .
Pb1 N5 2.615(6) .
Pb1 O2 2.640(5) .
Pb1 N2 2.669(5) .
Pb1 N3 2.780(5) .
O1 C1 1.280(8) .
O2 C1 1.244(7) .
O3 C8 1.216(7) .
O4 H4A 0.852(10) .
O4 H4B 0.850(10) .
N1 C8 1.371(8) .
N1 C7 1.380(8) .
N1 H1 0.8700 .
N2 C12 1.327(8) .
N2 C23 1.355(7) .
N3 C21 1.325(9) .
N3 C22 1.366(8) .
N4 C24 1.325(8) .
N4 C35 1.363(8) .
N5 C33 1.324(8) .
N5 C34 1.371(8) .
C1 C2 1.506(9) .
C2 C3 1.399(9) .
C2 C7 1.413(8) .
C3 C4 1.371(9) .
C3 H3 0.9400 .
C4 C5 1.373(9) .
C4 H4 0.9400 .
C5 C6 1.384(9) .
C5 H5 0.9400 .
C6 C7 1.401(9) .
C6 H6 0.9400 .
C8 C9 1.488(9) .
C9 C11 1.325(9) .
C9 C10 1.503(9) .
C10 H10A 0.9700 .
C10 H10B 0.9700 .
C10 H10C 0.9700 .
C11 H11A 0.9400 .
C11 H11B 0.9400 .
C12 C13 1.380(9) .
C12 H12 0.9400 .
C13 C14 1.379(10) .
C13 H13 0.9400 .
C14 C15 1.393(10) .
C14 H14 0.9400 .
C15 C23 1.411(9) .
C15 C16 1.441(10) .
C16 C17 1.323(10) .
C16 H16 0.9400 .
C17 C18 1.439(10) .
C17 H17 0.9400 .
C18 C19 1.401(10) .
C18 C22 1.407(8) .
C19 C20 1.352(11) .
C19 H19 0.9400 .
C20 C21 1.389(10) .
C20 H20 0.9400 .
C21 H21 0.9400 .
C22 C23 1.435(8) .
C24 C25 1.400(10) .
C24 H24 0.9400 .
C25 C26 1.356(12) .
C25 H25 0.9400 .
C26 C27 1.394(11) .
C26 H26 0.9400 .
C27 C35 1.414(9) .
C27 C28 1.426(11) .
C28 C29 1.351(13) .
C28 H28 0.9400 .
C29 C30 1.437(11) .
C29 H29 0.9400 .
C30 C34 1.405(10) .
C30 C31 1.415(12) .
C31 C32 1.337(12) .
C31 H31 0.9400 .
C32 C33 1.390(10) .
C32 H32 0.9400 .
C33 H33 0.9400 .
C34 C35 1.433(10) .
loop_
_geom_hbond_atom_site_label_D
_geom_hbond_atom_site_label_H
_geom_hbond_atom_site_label_A
_geom_hbond_distance_DH
_geom_hbond_distance_HA
_geom_hbond_distance_DA
_geom_hbond_angle_DHA
_geom_hbond_site_symmetry_A
O4 H4A Cl1 0.852(10) 2.53(7) 3.253(6) 144(9) .
O4 H4B Cl2 0.850(10) 2.32(6) 3.065(11) 146(9) .
N1 H1 O1 0.87 1.89 2.615(7) 139.9 .
loop_
_geom_torsion_atom_site_label_1
_geom_torsion_atom_site_label_2
_geom_torsion_atom_site_label_3
_geom_torsion_atom_site_label_4
_geom_torsion
_geom_torsion_site_symmetry_1
_geom_torsion_site_symmetry_2
_geom_torsion_site_symmetry_3
_geom_torsion_site_symmetry_4
N4 Pb1 O1 C1 83.9(4) . . . .
N5 Pb1 O1 C1 150.7(4) . . . .
O2 Pb1 O1 C1 3.9(4) . . . .
N2 Pb1 O1 C1 16.3(5) . . . .
N3 Pb1 O1 C1 112.1(4) . . . .
N4 Pb1 O2 C1 -89.7(4) . . . .
O1 Pb1 O2 C1 -4.0(4) . . . .
N5 Pb1 O2 C1 -40.8(4) . . . .
N2 Pb1 O2 C1 -174.4(4) . . . .
N3 Pb1 O2 C1 -138.9(4) . . . .
N4 Pb1 N2 C12 -108.4(5) . . . .
O1 Pb1 N2 C12 -43.2(5) . . . .
N5 Pb1 N2 C12 -152.2(4) . . . .
O2 Pb1 N2 C12 -33.6(5) . . . .
N3 Pb1 N2 C12 176.2(5) . . . .
N4 Pb1 N2 C23 82.5(4) . . . .
O1 Pb1 N2 C23 147.7(4) . . . .
N5 Pb1 N2 C23 38.7(5) . . . .
O2 Pb1 N2 C23 157.3(5) . . . .
N3 Pb1 N2 C23 7.1(4) . . . .
N4 Pb1 N3 C21 90.7(5) . . . .
O1 Pb1 N3 C21 62.0(6) . . . .
N5 Pb1 N3 C21 23.9(5) . . . .
O2 Pb1 N3 C21 140.0(5) . . . .
N2 Pb1 N3 C21 -179.2(6) . . . .
N4 Pb1 N3 C22 -96.2(4) . . . .
O1 Pb1 N3 C22 -124.8(4) . . . .
N5 Pb1 N3 C22 -162.9(4) . . . .
O2 Pb1 N3 C22 -46.8(5) . . . .
N2 Pb1 N3 C22 -6.0(4) . . . .
O1 Pb1 N4 C24 -96.2(5) . . . .
N5 Pb1 N4 C24 -176.2(5) . . . .
O2 Pb1 N4 C24 -43.9(4) . . . .
N2 Pb1 N4 C24 37.9(5) . . . .
N3 Pb1 N4 C24 99.8(5) . . . .
O1 Pb1 N4 C35 86.2(4) . . . .
N5 Pb1 N4 C35 6.2(4) . . . .
O2 Pb1 N4 C35 138.4(4) . . . .
N2 Pb1 N4 C35 -139.7(4) . . . .
N3 Pb1 N4 C35 -77.8(4) . . . .
N4 Pb1 N5 C33 177.6(5) . . . .
O1 Pb1 N5 C33 95.8(5) . . . .
O2 Pb1 N5 C33 124.3(5) . . . .
N2 Pb1 N5 C33 -133.0(5) . . . .
N3 Pb1 N5 C33 -105.0(5) . . . .
N4 Pb1 N5 C34 -7.5(4) . . . .
O1 Pb1 N5 C34 -89.3(4) . . . .
O2 Pb1 N5 C34 -60.8(4) . . . .
N2 Pb1 N5 C34 42.0(5) . . . .
N3 Pb1 N5 C34 69.9(4) . . . .
Pb1 O2 C1 O1 7.2(6) . . . .
Pb1 O2 C1 C2 -174.2(5) . . . .
Pb1 O1 C1 O2 -7.6(7) . . . .
Pb1 O1 C1 C2 173.8(5) . . . .
O2 C1 C2 C3 -4.4(9) . . . .
O1 C1 C2 C3 174.3(6) . . . .
O2 C1 C2 C7 175.5(6) . . . .
O1 C1 C2 C7 -5.8(9) . . . .
C7 C2 C3 C4 -1.1(10) . . . .
C1 C2 C3 C4 178.8(6) . . . .
C2 C3 C4 C5 0.8(11) . . . .
C3 C4 C5 C6 -0.3(12) . . . .
C4 C5 C6 C7 0.1(12) . . . .
C8 N1 C7 C6 5.0(11) . . . .
C8 N1 C7 C2 -177.3(6) . . . .
C5 C6 C7 N1 177.4(7) . . . .
C5 C6 C7 C2 -0.4(11) . . . .
C3 C2 C7 N1 -176.9(6) . . . .
C1 C2 C7 N1 3.2(9) . . . .
C3 C2 C7 C6 0.9(9) . . . .
C1 C2 C7 C6 -179.0(6) . . . .
C7 N1 C8 O3 1.0(11) . . . .
C7 N1 C8 C9 -178.1(6) . . . .
O3 C8 C9 C11 168.5(7) . . . .
N1 C8 C9 C11 -12.4(9) . . . .
O3 C8 C9 C10 -7.7(9) . . . .
N1 C8 C9 C10 171.5(6) . . . .
C23 N2 C12 C13 0.0(10) . . . .
Pb1 N2 C12 C13 -169.6(5) . . . .
N2 C12 C13 C14 0.0(11) . . . .
C12 C13 C14 C15 0.2(10) . . . .
C13 C14 C15 C23 -0.4(10) . . . .
C13 C14 C15 C16 -179.9(6) . . . .
C14 C15 C16 C17 -179.1(7) . . . .
C23 C15 C16 C17 1.4(10) . . . .
C15 C16 C17 C18 -0.3(10) . . . .
C16 C17 C18 C19 178.0(6) . . . .
C16 C17 C18 C22 1.2(10) . . . .
C22 C18 C19 C20 0.7(10) . . . .
C17 C18 C19 C20 -176.2(7) . . . .
C18 C19 C20 C21 0.4(11) . . . .
C22 N3 C21 C20 2.1(10) . . . .
Pb1 N3 C21 C20 175.3(5) . . . .
C19 C20 C21 N3 -1.9(12) . . . .
C21 N3 C22 C18 -1.0(9) . . . .
Pb1 N3 C22 C18 -174.5(4) . . . .
C21 N3 C22 C23 178.7(6) . . . .
Pb1 N3 C22 C23 5.2(7) . . . .
C19 C18 C22 N3 -0.4(9) . . . .
C17 C18 C22 N3 176.6(6) . . . .
C19 C18 C22 C23 180.0(6) . . . .
C17 C18 C22 C23 -3.1(9) . . . .
C12 N2 C23 C15 -0.2(9) . . . .
Pb1 N2 C23 C15 169.0(4) . . . .
C12 N2 C23 C22 -177.0(6) . . . .
Pb1 N2 C23 C22 -7.8(7) . . . .
C14 C15 C23 N2 0.4(9) . . . .
C16 C15 C23 N2 179.9(6) . . . .
C14 C15 C23 C22 177.2(6) . . . .
C16 C15 C23 C22 -3.3(9) . . . .
N3 C22 C23 N2 1.4(8) . . . .
C18 C22 C23 N2 -179.0(5) . . . .
N3 C22 C23 C15 -175.5(5) . . . .
C18 C22 C23 C15 4.2(9) . . . .
C35 N4 C24 C25 -0.9(9) . . . .
Pb1 N4 C24 C25 -178.6(5) . . . .
N4 C24 C25 C26 2.8(10) . . . .
C24 C25 C26 C27 -1.9(10) . . . .
C25 C26 C27 C35 -0.8(10) . . . .
C25 C26 C27 C28 -179.6(6) . . . .
C26 C27 C28 C29 178.8(7) . . . .
C35 C27 C28 C29 0.0(10) . . . .
C27 C28 C29 C30 -2.8(11) . . . .
C28 C29 C30 C34 3.5(10) . . . .
C28 C29 C30 C31 -175.9(7) . . . .
C34 C30 C31 C32 -2.4(10) . . . .
C29 C30 C31 C32 176.9(7) . . . .
C30 C31 C32 C33 3.0(11) . . . .
C34 N5 C33 C32 -1.3(10) . . . .
Pb1 N5 C33 C32 173.6(5) . . . .
C31 C32 C33 N5 -1.1(11) . . . .
C33 N5 C34 C30 1.8(8) . . . .
Pb1 N5 C34 C30 -173.5(4) . . . .
C33 N5 C34 C35 -176.2(5) . . . .
Pb1 N5 C34 C35 8.5(7) . . . .
C31 C30 C34 N5 0.0(9) . . . .
C29 C30 C34 N5 -179.4(6) . . . .
C31 C30 C34 C35 178.0(6) . . . .
C29 C30 C34 C35 -1.4(9) . . . .
C24 N4 C35 C27 -2.0(9) . . . .
Pb1 N4 C35 C27 175.7(4) . . . .
C24 N4 C35 C34 177.7(5) . . . .
Pb1 N4 C35 C34 -4.6(7) . . . .
C26 C27 C35 N4 2.8(9) . . . .
C28 C27 C35 N4 -178.3(6) . . . .
C26 C27 C35 C34 -176.9(6) . . . .
C28 C27 C35 C34 2.0(9) . . . .
N5 C34 C35 N4 -2.9(8) . . . .
C30 C34 C35 N4 179.1(5) . . . .
N5 C34 C35 C27 176.8(5) . . . .
C30 C34 C35 C27 -1.2(8) . . . .
