#------------------------------------------------------------------------------
#$Date: 2021-05-26 10:25:05 +0300 (Wed, 26 May 2021) $
#$Revision: 265501 $
#$URL: file:///home/coder/svn-repositories/cod/cif/1/56/28/1562860.cif $
#------------------------------------------------------------------------------
#
# This file is available in the Crystallography Open Database (COD),
# http://www.crystallography.net/
#
# All data on this site have been placed in the public domain by the
# contributors.
#
data_1562860
loop_
_publ_author_name
'Li, Xinfa'
'Cao, Rong'
_publ_section_title
;
 Syntheses, structure and properties of three-dimensional pillared-layer
 Ag(I)--Ln(III) heterometallic coordination polymers based on mixed
 isonicotinate and hemimellitate ligands
;
_journal_name_full               'Journal of Solid State Chemistry'
_journal_page_first              182
_journal_page_last               186
_journal_paper_doi               10.1016/j.jssc.2012.06.012
_journal_volume                  196
_journal_year                    2012
_chemical_formula_moiety         'C24 H14 Ag N O16 Pr2, H2 O'
_chemical_formula_sum            'C24 H16 Ag N O17 Pr2'
_chemical_formula_weight         980.07
_space_group_IT_number           2
_space_group_name_Hall           '-P 1'
_space_group_name_H-M_alt        'P -1'
_symmetry_cell_setting           triclinic
_symmetry_space_group_name_Hall  '-P 1'
_symmetry_space_group_name_H-M   'P -1'
_atom_sites_solution_hydrogens   geom
_atom_sites_solution_primary     direct
_atom_sites_solution_secondary   difmap
_audit_creation_method           SHELXL-97
_cell_angle_alpha                104.402(5)
_cell_angle_beta                 97.987(4)
_cell_angle_gamma                98.806(4)
_cell_formula_units_Z            2
_cell_length_a                   8.6146(4)
_cell_length_b                   11.8370(6)
_cell_length_c                   13.6503(8)
_cell_measurement_reflns_used    4309
_cell_measurement_temperature    293(2)
_cell_measurement_theta_max      29.1690
_cell_measurement_theta_min      2.4296
_cell_volume                     1309.32(13)
_computing_cell_refinement
;
CrysAlisPro, Agilent Technologies,
Version 1.171.34.49 (release 20-01-2011 CrysAlis171 .NET)
(compiled Jan 20 2011,15:58:25)
;
_computing_data_collection
;
CrysAlisPro, Agilent Technologies,
Version 1.171.34.49 (release 20-01-2011 CrysAlis171 .NET)
(compiled Jan 20 2011,15:58:25)
;
_computing_data_reduction
;
CrysAlisPro, Agilent Technologies,
Version 1.171.34.49 (release 20-01-2011 CrysAlis171 .NET)
(compiled Jan 20 2011,15:58:25)
;
_computing_molecular_graphics    'Bruker SHELXTL'
_computing_publication_material  'Bruker SHELXTL'
_computing_structure_refinement  'SHELXL-97 (Sheldrick, 1997)'
_computing_structure_solution    'SHELXS-97 (Sheldrick, 1990)'
_diffrn_ambient_temperature      293(2)
_diffrn_detector_area_resol_mean 16.2083
_diffrn_measured_fraction_theta_full 0.990
_diffrn_measured_fraction_theta_max 0.990
_diffrn_measurement_device_type  'Xcalibur, Eos'
_diffrn_measurement_method       'ω scans'
_diffrn_radiation_monochromator  graphite
_diffrn_radiation_source         'fine-focus sealed tube'
_diffrn_radiation_type           MoK\a
_diffrn_radiation_wavelength     0.71073
_diffrn_reflns_av_R_equivalents  0.0293
_diffrn_reflns_av_sigmaI/netI    0.0501
_diffrn_reflns_limit_h_max       10
_diffrn_reflns_limit_h_min       -10
_diffrn_reflns_limit_k_max       14
_diffrn_reflns_limit_k_min       -13
_diffrn_reflns_limit_l_max       12
_diffrn_reflns_limit_l_min       -17
_diffrn_reflns_number            9885
_diffrn_reflns_theta_full        26.75
_diffrn_reflns_theta_max         26.75
_diffrn_reflns_theta_min         2.43
_diffrn_standards_interval_count none
_diffrn_standards_interval_time  none
_exptl_absorpt_coefficient_mu    4.494
_exptl_absorpt_correction_T_max  0.5121
_exptl_absorpt_correction_T_min  0.3946
_exptl_absorpt_correction_type   multi-scan
_exptl_absorpt_process_details
;
CrysAlisPro, Agilent Technologies,
Version 1.171.34.49. 
Empirical absorption correction using spherical harmonics,
 implemented in SCALE3 ABSPACK scaling algorithm.
;
_exptl_crystal_colour            light-green
_exptl_crystal_density_diffrn    2.486
_exptl_crystal_density_method    'not measured'
_exptl_crystal_description       block-shaped
_exptl_crystal_F_000             936
_exptl_crystal_size_max          0.36
_exptl_crystal_size_mid          0.16
_exptl_crystal_size_min          0.15
_refine_diff_density_max         1.505
_refine_diff_density_min         -1.127
_refine_diff_density_rms         0.156
_refine_ls_extinction_method     none
_refine_ls_goodness_of_fit_ref   1.007
_refine_ls_hydrogen_treatment    constr
_refine_ls_matrix_type           full
_refine_ls_number_parameters     406
_refine_ls_number_reflns         5501
_refine_ls_number_restraints     6
_refine_ls_restrained_S_all      1.007
_refine_ls_R_factor_all          0.0364
_refine_ls_R_factor_gt           0.0296
_refine_ls_shift/su_max          0.001
_refine_ls_shift/su_mean         0.000
_refine_ls_structure_factor_coef Fsqd
_refine_ls_weighting_details
'calc w=1/[σ²(Fo²)+(0.0250P)²+2.5000P] where P=(Fo²+2Fc²)/3'
_refine_ls_weighting_scheme      calc
_refine_ls_wR_factor_gt          0.0667
_refine_ls_wR_factor_ref         0.0708
_reflns_number_gt                4795
_reflns_number_total             5501
_reflns_threshold_expression     >2sigma(I)
_cod_data_source_file            JSSC-2012-196-182.cif
_cod_data_source_block           Pr-Ag
_cod_depositor_comments
;
The following automatic conversions were performed:

data item '_symmetry_cell_setting' value 'Triclinic' was changed to
'triclinic' in accordance with the built-in table derived from the
CIF Core dictionary named 'cif_core.dic' version 2.4.5 last updated
on 2014-11-21.

Automatic conversion script
Id: cif_fix_values 8369 2020-08-20 11:38:08Z andrius 
;
_cod_original_cell_volume        1309.32(12)
_cod_database_code               1562860
loop_
_symmetry_equiv_pos_as_xyz
'x, y, z'
'-x, -y, -z'
loop_
_atom_site_label
_atom_site_type_symbol
_atom_site_fract_x
_atom_site_fract_y
_atom_site_fract_z
_atom_site_U_iso_or_equiv
_atom_site_adp_type
_atom_site_occupancy
_atom_site_symmetry_multiplicity
_atom_site_calc_flag
_atom_site_refinement_flags
_atom_site_disorder_assembly
_atom_site_disorder_group
Pr1 Pr 0.45579(3) 0.12143(2) 0.40200(2) 0.01149(7) Uani 1 1 d . . .
Pr2 Pr 0.18366(3) 0.38359(2) 0.389092(19) 0.01003(7) Uani 1 1 d . . .
Ag1 Ag 0.05151(5) -0.04417(4) -0.31320(3) 0.02683(11) Uani 1 1 d . . .
O1 O 0.3796(4) 0.0556(3) 0.5526(3) 0.0192(8) Uani 1 1 d . . .
O2 O 0.4561(5) 0.0520(3) 0.7114(3) 0.0251(8) Uani 1 1 d . . .
O3 O 0.2235(4) 0.2045(3) 0.4509(3) 0.0153(7) Uani 1 1 d . . .
O4 O 0.0035(4) 0.1104(3) 0.4877(3) 0.0174(7) Uani 1 1 d . . .
O5 O 0.0132(4) 0.3633(3) 0.5141(3) 0.0156(7) Uani 1 1 d . . .
O6 O -0.0272(4) 0.4804(3) 0.6580(3) 0.0219(8) Uani 1 1 d . . .
O7 O 0.7024(4) 0.1963(3) 0.3498(3) 0.0221(8) Uani 1 1 d . . .
O8 O 0.9248(4) 0.2557(3) 0.2970(3) 0.0191(8) Uani 1 1 d . . .
O9 O 0.4610(4) 0.3377(3) 0.4063(3) 0.0133(7) Uani 1 1 d . . .
O10 O 0.6802(4) 0.4785(3) 0.4458(3) 0.0201(8) Uani 1 1 d . . .
O11 O 0.3593(4) 0.5273(3) 0.3324(3) 0.0205(8) Uani 1 1 d . . .
O12 O 0.3309(6) 0.5709(4) 0.1825(4) 0.0500(13) Uani 1 1 d . . .
O13 O 0.3335(5) 0.1101(3) 0.2293(3) 0.0260(9) Uani 1 1 d . . .
O14 O 0.2035(4) 0.2568(3) 0.2235(3) 0.0218(8) Uani 1 1 d . . .
O15 O 0.6685(5) 0.2465(3) 0.5541(3) 0.0301(9) Uani 1 1 d . . .
H15B H 0.7558 0.2552 0.5319 0.045 Uiso 1 1 d R . .
H15C H 0.6599 0.3150 0.5885 0.045 Uiso 1 1 d R . .
O16 O 0.2133(4) -0.0527(3) 0.3531(3) 0.0281(9) Uani 1 1 d . . .
H16B H 0.2068 -0.0843 0.4023 0.042 Uiso 1 1 d R . .
H16C H 0.2215 -0.1056 0.3001 0.042 Uiso 1 1 d R . .
N1 N 0.1278(5) 0.0310(4) -0.1453(3) 0.0209(10) Uani 1 1 d . . .
C1 C 0.3839(5) 0.0945(4) 0.6489(4) 0.0127(10) Uani 1 1 d . . .
C2 C 0.1331(6) 0.1789(4) 0.5140(4) 0.0123(10) Uani 1 1 d . . .
C3 C 0.0308(5) 0.3976(4) 0.6107(4) 0.0131(10) Uani 1 1 d . . .
C4 C 0.2958(6) 0.1927(4) 0.6894(4) 0.0141(10) Uani 1 1 d . . .
C5 C 0.1918(5) 0.2376(4) 0.6277(4) 0.0114(9) Uani 1 1 d . . .
C6 C 0.1256(5) 0.3345(4) 0.6739(4) 0.0128(10) Uani 1 1 d . . .
C7 C 0.1533(6) 0.3777(4) 0.7798(4) 0.0183(11) Uani 1 1 d . . .
H7A H 0.1061 0.4400 0.8100 0.022 Uiso 1 1 calc R . .
C8 C 0.2498(6) 0.3303(4) 0.8415(4) 0.0205(11) Uani 1 1 d . . .
H8A H 0.2647 0.3581 0.9128 0.025 Uiso 1 1 calc R . .
C9 C 0.3235(6) 0.2413(4) 0.7962(4) 0.0175(10) Uani 1 1 d . . .
H9A H 0.3937 0.2126 0.8377 0.021 Uiso 1 1 calc R . .
C10 C 0.7792(6) 0.2530(4) 0.2986(4) 0.0168(11) Uani 1 1 d . . .
C11 C 0.5743(5) 0.4042(4) 0.3828(4) 0.0113(9) Uani 1 1 d . . .
C12 C 0.3872(6) 0.5171(4) 0.2418(4) 0.0228(12) Uani 1 1 d . . .
C13 C 0.6901(6) 0.3140(4) 0.2320(4) 0.0172(10) Uani 1 1 d . . .
C14 C 0.5827(5) 0.3835(4) 0.2704(4) 0.0131(10) Uani 1 1 d . . .
C15 C 0.4971(6) 0.4355(4) 0.2053(4) 0.0159(10) Uani 1 1 d . . .
C16 C 0.5159(7) 0.4134(5) 0.1027(4) 0.0234(12) Uani 1 1 d . . .
H16A H 0.4543 0.4444 0.0583 0.028 Uiso 1 1 calc R . .
C17 C 0.6246(7) 0.3461(5) 0.0658(4) 0.0292(13) Uani 1 1 d . . .
H17A H 0.6369 0.3328 -0.0025 0.035 Uiso 1 1 calc R . .
C18 C 0.7132(7) 0.2996(5) 0.1312(4) 0.0242(12) Uani 1 1 d . . .
H18A H 0.7900 0.2578 0.1080 0.029 Uiso 1 1 calc R . .
C19 C 0.2547(6) 0.1670(4) 0.1827(4) 0.0162(10) Uani 1 1 d . . .
C20 C 0.2153(6) 0.1220(4) 0.0674(4) 0.0147(10) Uani 1 1 d . . .
C21 C 0.0908(6) 0.1557(5) 0.0132(4) 0.0220(11) Uani 1 1 d . . .
H21A H 0.0360 0.2106 0.0471 0.026 Uiso 1 1 calc R . .
C22 C 0.0489(7) 0.1066(5) -0.0920(4) 0.0270(12) Uani 1 1 d . . .
H22A H -0.0380 0.1270 -0.1274 0.032 Uiso 1 1 calc R . .
C23 C 0.2509(7) 0.0031(4) -0.0935(4) 0.0237(12) Uani 1 1 d . . .
H23A H 0.3096 -0.0463 -0.1304 0.028 Uiso 1 1 calc R . .
C24 C 0.2973(6) 0.0432(4) 0.0126(4) 0.0235(12) Uani 1 1 d . . .
H24A H 0.3813 0.0181 0.0462 0.028 Uiso 1 1 calc R . .
O17 O 0.2363(6) -0.2228(4) 0.1886(4) 0.0665(16) Uani 1 1 d U . .
H17B H 0.2980 -0.1877 0.1572 0.100 Uiso 1 1 d R . .
H17C H 0.2662 -0.2883 0.1869 0.100 Uiso 1 1 d R . .
loop_
_atom_type_symbol
_atom_type_description
_atom_type_scat_dispersion_real
_atom_type_scat_dispersion_imag
_atom_type_scat_source
C C 0.0033 0.0016 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
H H 0.0000 0.0000 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
N N 0.0061 0.0033 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
O O 0.0106 0.0060 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
Ag Ag -0.8971 1.1015 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
Pr Pr -0.2180 2.8214 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
loop_
_geom_angle_atom_site_label_1
_geom_angle_atom_site_label_2
_geom_angle_atom_site_label_3
_geom_angle
_geom_angle_site_symmetry_1
_geom_angle_site_symmetry_3
O13 Pr1 O7 84.18(13) . .
O13 Pr1 O3 84.58(12) . .
O7 Pr1 O3 135.26(10) . .
O13 Pr1 O1 138.13(12) . .
O7 Pr1 O1 136.91(12) . .
O3 Pr1 O1 70.70(11) . .
O13 Pr1 O2 74.99(12) . 2_656
O7 Pr1 O2 71.40(12) . 2_656
O3 Pr1 O2 144.83(12) . 2_656
O1 Pr1 O2 106.55(11) . 2_656
O13 Pr1 O15 143.40(12) . .
O7 Pr1 O15 67.52(13) . .
O3 Pr1 O15 99.14(12) . .
O1 Pr1 O15 75.52(12) . .
O2 Pr1 O15 114.38(13) 2_656 .
O13 Pr1 O9 76.65(11) . .
O7 Pr1 O9 72.05(10) . .
O3 Pr1 O9 63.22(10) . .
O1 Pr1 O9 117.58(10) . .
O2 Pr1 O9 135.36(11) 2_656 .
O15 Pr1 O9 72.91(11) . .
O13 Pr1 O16 74.49(12) . .
O7 Pr1 O16 143.41(12) . .
O3 Pr1 O16 72.58(11) . .
O1 Pr1 O16 66.22(12) . .
O2 Pr1 O16 74.50(12) 2_656 .
O15 Pr1 O16 141.52(12) . .
O9 Pr1 O16 128.71(11) . .
O13 Pr1 O1 122.05(11) . 2_656
O7 Pr1 O1 84.62(10) . 2_656
O3 Pr1 O1 136.72(9) . 2_656
O1 Pr1 O1 67.07(12) . 2_656
O2 Pr1 O1 47.62(10) 2_656 2_656
O15 Pr1 O1 79.35(11) . 2_656
O9 Pr1 O1 148.88(10) . 2_656
O16 Pr1 O1 82.15(11) . 2_656
O6 Pr2 O14 102.78(12) 2_566 .
O6 Pr2 O5 87.29(11) 2_566 .
O14 Pr2 O5 133.71(11) . .
O6 Pr2 O10 94.58(12) 2_566 2_666
O14 Pr2 O10 148.28(12) . 2_666
O5 Pr2 O10 72.72(11) . 2_666
O6 Pr2 O11 72.69(12) 2_566 .
O14 Pr2 O11 81.08(11) . .
O5 Pr2 O11 143.79(11) . .
O10 Pr2 O11 79.03(12) 2_666 .
O6 Pr2 O8 75.93(12) 2_566 1_455
O14 Pr2 O8 67.74(11) . 1_455
O5 Pr2 O8 71.43(11) . 1_455
O10 Pr2 O8 143.23(11) 2_666 1_455
O11 Pr2 O8 128.85(12) . 1_455
O6 Pr2 O3 153.78(11) 2_566 .
O14 Pr2 O3 83.65(11) . .
O5 Pr2 O3 70.76(10) . .
O10 Pr2 O3 92.41(11) 2_666 .
O11 Pr2 O3 133.51(11) . .
O8 Pr2 O3 83.39(11) 1_455 .
O6 Pr2 O9 143.56(11) 2_566 .
O14 Pr2 O9 73.06(11) . .
O5 Pr2 O9 122.38(11) . .
O10 Pr2 O9 77.19(11) 2_666 .
O11 Pr2 O9 70.90(11) . .
O8 Pr2 O9 130.27(11) 1_455 .
O3 Pr2 O9 62.66(10) . .
N1 Ag1 O4 174.16(13) . 2
N1 Ag1 O8 90.72(13) . 2_655
O4 Ag1 O8 91.68(11) 2 2_655
C1 O1 Pr1 141.6(3) . .
C1 O1 Pr1 87.4(3) . 2_656
Pr1 O1 Pr1 112.93(12) . 2_656
C1 O2 Pr1 103.4(3) . 2_656
C2 O3 Pr1 129.0(3) . .
C2 O3 Pr2 116.0(3) . .
Pr1 O3 Pr2 114.36(11) . .
C2 O4 Ag1 108.6(3) . 2
C3 O5 Pr2 135.0(3) . .
C3 O6 Pr2 135.6(3) . 2_566
C10 O7 Pr1 152.2(3) . .
C10 O8 Pr2 138.2(3) . 1_655
C11 O9 Pr2 119.7(3) . .
C11 O9 Pr1 124.3(3) . .
Pr2 O9 Pr1 111.67(11) . .
C11 O10 Pr2 158.5(3) . 2_666
C12 O11 Pr2 126.9(3) . .
C19 O13 Pr1 139.4(3) . .
C19 O14 Pr2 142.7(3) . .
Pr1 O15 H15B 106.8 . .
Pr1 O15 H15C 121.9 . .
H15B O15 H15C 106.9 . .
Pr1 O16 H16B 110.6 . .
Pr1 O16 H16C 110.5 . .
H16B O16 H16C 108.7 . .
C23 N1 C22 117.6(5) . .
C23 N1 Ag1 121.9(3) . .
C22 N1 Ag1 120.5(4) . .
O2 C1 O1 121.4(4) . .
O2 C1 C4 118.3(4) . .
O1 C1 C4 120.3(4) . .
O2 C1 Pr1 53.5(2) . 2_656
O1 C1 Pr1 68.1(2) . 2_656
C4 C1 Pr1 169.8(3) . 2_656
O4 C2 O3 124.4(4) . .
O4 C2 C5 117.8(4) . .
O3 C2 C5 117.7(4) . .
O6 C3 O5 123.8(5) . .
O6 C3 C6 117.4(4) . .
O5 C3 C6 118.8(4) . .
C5 C4 C9 118.7(4) . .
C5 C4 C1 124.6(4) . .
C9 C4 C1 116.7(4) . .
C4 C5 C6 119.3(4) . .
C4 C5 C2 122.8(4) . .
C6 C5 C2 117.6(4) . .
C7 C6 C5 119.9(4) . .
C7 C6 C3 118.3(4) . .
C5 C6 C3 121.8(4) . .
C8 C7 C6 121.1(5) . .
C8 C7 H7A 119.4 . .
C6 C7 H7A 119.4 . .
C9 C8 C7 119.0(5) . .
C9 C8 H8A 120.5 . .
C7 C8 H8A 120.5 . .
C8 C9 C4 121.8(5) . .
C8 C9 H9A 119.1 . .
C4 C9 H9A 119.1 . .
O8 C10 O7 123.1(5) . .
O8 C10 C13 118.3(4) . .
O7 C10 C13 118.5(4) . .
O10 C11 O9 124.5(4) . .
O10 C11 C14 118.1(4) . .
O9 C11 C14 117.3(4) . .
O12 C12 O11 124.4(5) . .
O12 C12 C15 118.2(5) . .
O11 C12 C15 117.5(5) . .
C18 C13 C14 120.3(5) . .
C18 C13 C10 119.4(5) . .
C14 C13 C10 120.3(4) . .
C15 C14 C13 118.9(4) . .
C15 C14 C11 123.5(4) . .
C13 C14 C11 117.5(4) . .
C14 C15 C16 119.3(5) . .
C14 C15 C12 122.4(4) . .
C16 C15 C12 118.3(5) . .
C17 C16 C15 121.3(5) . .
C17 C16 H16A 119.4 . .
C15 C16 H16A 119.4 . .
C18 C17 C16 119.1(5) . .
C18 C17 H17A 120.5 . .
C16 C17 H17A 120.5 . .
C17 C18 C13 120.9(5) . .
C17 C18 H18A 119.5 . .
C13 C18 H18A 119.5 . .
O13 C19 O14 125.7(5) . .
O13 C19 C20 117.1(4) . .
O14 C19 C20 117.2(5) . .
C21 C20 C24 118.2(5) . .
C21 C20 C19 120.0(4) . .
C24 C20 C19 121.8(5) . .
C22 C21 C20 119.1(5) . .
C22 C21 H21A 120.4 . .
C20 C21 H21A 120.4 . .
N1 C22 C21 122.9(5) . .
N1 C22 H22A 118.5 . .
C21 C22 H22A 118.5 . .
N1 C23 C24 123.7(5) . .
N1 C23 H23A 118.2 . .
C24 C23 H23A 118.2 . .
C23 C24 C20 118.4(5) . .
C23 C24 H24A 120.8 . .
C20 C24 H24A 120.8 . .
H17B O17 H17C 105.3 . .
loop_
_geom_bond_atom_site_label_1
_geom_bond_atom_site_label_2
_geom_bond_distance
_geom_bond_site_symmetry_2
Pr1 O13 2.407(4) .
Pr1 O7 2.442(3) .
Pr1 O3 2.462(3) .
Pr1 O1 2.505(3) .
Pr1 O2 2.531(3) 2_656
Pr1 O15 2.538(4) .
Pr1 O9 2.539(3) .
Pr1 O16 2.582(3) .
Pr1 O1 2.846(3) 2_656
Pr2 O6 2.399(3) 2_566
Pr2 O14 2.427(3) .
Pr2 O5 2.433(3) .
Pr2 O10 2.443(3) 2_666
Pr2 O11 2.444(3) .
Pr2 O8 2.467(3) 1_455
Pr2 O3 2.521(3) .
Pr2 O9 2.523(3) .
Ag1 N1 2.205(4) .
Ag1 O4 2.270(3) 2
Ag1 O8 2.603(3) 2_655
O1 C1 1.274(6) .
O1 Pr1 2.846(3) 2_656
O2 C1 1.237(6) .
O2 Pr1 2.531(3) 2_656
O3 C2 1.298(5) .
O4 C2 1.224(5) .
O4 Ag1 2.270(3) 2
O5 C3 1.259(6) .
O6 C3 1.246(5) .
O6 Pr2 2.399(3) 2_566
O7 C10 1.266(5) .
O8 C10 1.254(6) .
O8 Pr2 2.467(3) 1_655
O9 C11 1.285(5) .
O10 C11 1.227(5) .
O10 Pr2 2.443(3) 2_666
O11 C12 1.273(6) .
O12 C12 1.240(6) .
O13 C19 1.246(6) .
O14 C19 1.246(6) .
O15 H15B 0.8500 .
O15 H15C 0.8501 .
O16 H16B 0.8499 .
O16 H16C 0.8501 .
N1 C23 1.323(7) .
N1 C22 1.338(7) .
C1 C4 1.516(6) .
C1 Pr1 3.064(5) 2_656
C2 C5 1.512(6) .
C3 C6 1.511(6) .
C4 C5 1.398(7) .
C4 C9 1.399(7) .
C5 C6 1.407(6) .
C6 C7 1.381(7) .
C7 C8 1.378(7) .
C7 H7A 0.9300 .
C8 C9 1.373(7) .
C8 H8A 0.9300 .
C9 H9A 0.9300 .
C10 C13 1.496(7) .
C11 C14 1.507(6) .
C12 C15 1.500(7) .
C13 C18 1.389(7) .
C13 C14 1.401(7) .
C14 C15 1.393(7) .
C15 C16 1.395(7) .
C16 C17 1.388(8) .
C16 H16A 0.9300 .
C17 C18 1.365(8) .
C17 H17A 0.9300 .
C18 H18A 0.9300 .
C19 C20 1.502(6) .
C20 C21 1.383(7) .
C20 C24 1.390(7) .
C21 C22 1.381(7) .
C21 H21A 0.9300 .
C22 H22A 0.9300 .
C23 C24 1.386(7) .
C23 H23A 0.9300 .
C24 H24A 0.9300 .
O17 H17B 0.8500 .
O17 H17C 0.8500 .
loop_
_geom_hbond_atom_site_label_D
_geom_hbond_atom_site_label_H
_geom_hbond_atom_site_label_A
_geom_hbond_distance_DH
_geom_hbond_distance_HA
_geom_hbond_distance_DA
_geom_hbond_angle_DHA
_geom_hbond_site_symmetry_A
O15 H15B O5 0.85 2.46 3.255(5) 156.1 1_655
O15 H15C O11 0.85 1.95 2.805(5) 179.8 2_666
O16 H16B O4 0.85 2.54 3.186(5) 133.7 2_556
O16 H16C O17 0.85 1.82 2.671(6) 178.0 .
O17 H17C O12 0.85 1.83 2.677(6) 179.7 1_545
loop_
_geom_torsion_atom_site_label_1
_geom_torsion_atom_site_label_2
_geom_torsion_atom_site_label_3
_geom_torsion_atom_site_label_4
_geom_torsion
_geom_torsion_site_symmetry_1
_geom_torsion_site_symmetry_2
_geom_torsion_site_symmetry_3
_geom_torsion_site_symmetry_4
O13 Pr1 O1 C1 -130.1(5) . . . .
O7 Pr1 O1 C1 63.9(5) . . . .
O3 Pr1 O1 C1 -72.8(5) . . . .
O2 Pr1 O1 C1 144.1(5) 2_656 . . .
O15 Pr1 O1 C1 32.5(5) . . . .
O9 Pr1 O1 C1 -29.0(5) . . . .
O16 Pr1 O1 C1 -151.7(5) . . . .
O1 Pr1 O1 C1 116.9(6) 2_656 . . .
O13 Pr1 O1 Pr1 113.03(17) . . . 2_656
O7 Pr1 O1 Pr1 -53.0(2) . . . 2_656
O3 Pr1 O1 Pr1 170.30(16) . . . 2_656
O2 Pr1 O1 Pr1 27.22(16) 2_656 . . 2_656
O15 Pr1 O1 Pr1 -84.37(15) . . . 2_656
O9 Pr1 O1 Pr1 -145.86(11) . . . 2_656
O16 Pr1 O1 Pr1 91.40(15) . . . 2_656
O1 Pr1 O1 Pr1 0.0 2_656 . . 2_656
O13 Pr1 O3 C2 134.6(4) . . . .
O7 Pr1 O3 C2 -149.3(3) . . . .
O1 Pr1 O3 C2 -11.1(4) . . . .
O2 Pr1 O3 C2 80.5(4) 2_656 . . .
O15 Pr1 O3 C2 -82.1(4) . . . .
O9 Pr1 O3 C2 -147.6(4) . . . .
O16 Pr1 O3 C2 59.2(4) . . . .
O1 Pr1 O3 C2 2.0(4) 2_656 . . .
O13 Pr1 O3 Pr2 -55.16(14) . . . .
O7 Pr1 O3 Pr2 20.9(2) . . . .
O1 Pr1 O3 Pr2 159.17(17) . . . .
O2 Pr1 O3 Pr2 -109.28(18) 2_656 . . .
O15 Pr1 O3 Pr2 88.12(15) . . . .
O9 Pr1 O3 Pr2 22.61(12) . . . .
O16 Pr1 O3 Pr2 -130.58(17) . . . .
O1 Pr1 O3 Pr2 172.25(11) 2_656 . . .
O6 Pr2 O3 C2 -31.0(5) 2_566 . . .
O14 Pr2 O3 C2 -137.1(3) . . . .
O5 Pr2 O3 C2 3.7(3) . . . .
O10 Pr2 O3 C2 74.5(3) 2_666 . . .
O11 Pr2 O3 C2 151.6(3) . . . .
O8 Pr2 O3 C2 -68.9(3) 1_455 . . .
O9 Pr2 O3 C2 148.7(3) . . . .
O6 Pr2 O3 Pr1 157.4(2) 2_566 . . .
O14 Pr2 O3 Pr1 51.30(14) . . . .
O5 Pr2 O3 Pr1 -167.87(17) . . . .
O10 Pr2 O3 Pr1 -97.12(14) 2_666 . . .
O11 Pr2 O3 Pr1 -20.0(2) . . . .
O8 Pr2 O3 Pr1 119.53(15) 1_455 . . .
O9 Pr2 O3 Pr1 -22.89(12) . . . .
O6 Pr2 O5 C3 -107.9(4) 2_566 . . .
O14 Pr2 O5 C3 147.0(4) . . . .
O10 Pr2 O5 C3 -12.2(4) 2_666 . . .
O11 Pr2 O5 C3 -52.5(5) . . . .
O8 Pr2 O5 C3 176.1(4) 1_455 . . .
O3 Pr2 O5 C3 86.7(4) . . . .
O9 Pr2 O5 C3 49.6(5) . . . .
O13 Pr1 O7 C10 32.4(7) . . . .
O3 Pr1 O7 C10 -43.8(7) . . . .
O1 Pr1 O7 C10 -156.9(6) . . . .
O2 Pr1 O7 C10 108.5(7) 2_656 . . .
O15 Pr1 O7 C10 -123.9(7) . . . .
O9 Pr1 O7 C10 -45.4(7) . . . .
O16 Pr1 O7 C10 86.4(7) . . . .
O1 Pr1 O7 C10 155.4(7) 2_656 . . .
O6 Pr2 O9 C11 -0.9(4) 2_566 . . .
O14 Pr2 O9 C11 87.8(3) . . . .
O5 Pr2 O9 C11 -140.7(3) . . . .
O10 Pr2 O9 C11 -81.1(3) 2_666 . . .
O11 Pr2 O9 C11 1.6(3) . . . .
O8 Pr2 O9 C11 126.8(3) 1_455 . . .
O3 Pr2 O9 C11 179.4(3) . . . .
O6 Pr2 O9 Pr1 -158.53(15) 2_566 . . .
O14 Pr2 O9 Pr1 -69.87(13) . . . .
O5 Pr2 O9 Pr1 61.59(16) . . . .
O10 Pr2 O9 Pr1 121.26(14) 2_666 . . .
O11 Pr2 O9 Pr1 -156.08(16) . . . .
O8 Pr2 O9 Pr1 -30.9(2) 1_455 . . .
O3 Pr2 O9 Pr1 21.70(11) . . . .
O13 Pr1 O9 C11 -88.0(4) . . . .
O7 Pr1 O9 C11 0.2(3) . . . .
O3 Pr1 O9 C11 -178.6(4) . . . .
O1 Pr1 O9 C11 134.3(3) . . . .
O2 Pr1 O9 C11 -36.2(4) 2_656 . . .
O15 Pr1 O9 C11 71.5(4) . . . .
O16 Pr1 O9 C11 -145.1(3) . . . .
O1 Pr1 O9 C11 43.5(4) 2_656 . . .
O13 Pr1 O9 Pr2 68.50(14) . . . .
O7 Pr1 O9 Pr2 156.63(16) . . . .
O3 Pr1 O9 Pr2 -22.12(12) . . . .
O1 Pr1 O9 Pr2 -69.19(16) . . . .
O2 Pr1 O9 Pr2 120.26(15) 2_656 . . .
O15 Pr1 O9 Pr2 -132.08(15) . . . .
O16 Pr1 O9 Pr2 11.3(2) . . . .
O1 Pr1 O9 Pr2 -160.03(13) 2_656 . . .
O6 Pr2 O11 C12 -92.1(4) 2_566 . . .
O14 Pr2 O11 C12 14.4(4) . . . .
O5 Pr2 O11 C12 -151.5(4) . . . .
O10 Pr2 O11 C12 169.5(4) 2_666 . . .
O8 Pr2 O11 C12 -37.4(5) 1_455 . . .
O3 Pr2 O11 C12 86.7(4) . . . .
O9 Pr2 O11 C12 89.4(4) . . . .
O7 Pr1 O13 C19 -100.9(5) . . . .
O3 Pr1 O13 C19 35.7(5) . . . .
O1 Pr1 O13 C19 88.6(5) . . . .
O2 Pr1 O13 C19 -173.2(5) 2_656 . . .
O15 Pr1 O13 C19 -62.3(6) . . . .
O9 Pr1 O13 C19 -28.0(5) . . . .
O16 Pr1 O13 C19 109.1(5) . . . .
O1 Pr1 O13 C19 179.2(5) 2_656 . . .
O6 Pr2 O14 C19 -175.6(5) 2_566 . . .
O5 Pr2 O14 C19 -77.0(5) . . . .
O10 Pr2 O14 C19 62.9(6) 2_666 . . .
O11 Pr2 O14 C19 114.6(5) . . . .
O8 Pr2 O14 C19 -106.8(5) 1_455 . . .
O3 Pr2 O14 C19 -21.4(5) . . . .
O9 Pr2 O14 C19 41.9(5) . . . .
O4 Ag1 N1 C23 -68.6(15) 2 . . .
O8 Ag1 N1 C23 45.6(4) 2_655 . . .
O4 Ag1 N1 C22 111.9(14) 2 . . .
O8 Ag1 N1 C22 -133.9(4) 2_655 . . .
Pr1 O2 C1 O1 -5.5(5) 2_656 . . .
Pr1 O2 C1 C4 172.8(3) 2_656 . . .
Pr1 O1 C1 O2 -119.9(5) . . . .
Pr1 O1 C1 O2 4.8(4) 2_656 . . .
Pr1 O1 C1 C4 61.8(7) . . . .
Pr1 O1 C1 C4 -173.5(4) 2_656 . . .
Pr1 O1 C1 Pr1 -124.7(5) . . . 2_656
Ag1 O4 C2 O3 -2.0(5) 2 . . .
Ag1 O4 C2 C5 178.0(3) 2 . . .
Pr1 O3 C2 O4 -98.0(5) . . . .
Pr2 O3 C2 O4 91.9(5) . . . .
Pr1 O3 C2 C5 82.0(5) . . . .
Pr2 O3 C2 C5 -88.1(4) . . . .
Pr2 O6 C3 O5 -1.3(7) 2_566 . . .
Pr2 O6 C3 C6 179.5(3) 2_566 . . .
Pr2 O5 C3 O6 105.7(5) . . . .
Pr2 O5 C3 C6 -75.1(5) . . . .
O2 C1 C4 C5 -170.8(4) . . . .
O1 C1 C4 C5 7.6(7) . . . .
Pr1 C1 C4 C5 -136.0(16) 2_656 . . .
O2 C1 C4 C9 9.9(6) . . . .
O1 C1 C4 C9 -171.8(4) . . . .
Pr1 C1 C4 C9 45(2) 2_656 . . .
C9 C4 C5 C6 3.7(6) . . . .
C1 C4 C5 C6 -175.7(4) . . . .
C9 C4 C5 C2 -169.8(4) . . . .
C1 C4 C5 C2 10.8(7) . . . .
O4 C2 C5 C4 95.5(5) . . . .
O3 C2 C5 C4 -84.5(5) . . . .
O4 C2 C5 C6 -78.1(5) . . . .
O3 C2 C5 C6 101.9(5) . . . .
C4 C5 C6 C7 -5.3(6) . . . .
C2 C5 C6 C7 168.6(4) . . . .
C4 C5 C6 C3 171.6(4) . . . .
C2 C5 C6 C3 -14.6(6) . . . .
O6 C3 C6 C7 -5.1(6) . . . .
O5 C3 C6 C7 175.7(4) . . . .
O6 C3 C6 C5 178.1(4) . . . .
O5 C3 C6 C5 -1.1(6) . . . .
C5 C6 C7 C8 2.3(7) . . . .
C3 C6 C7 C8 -174.7(4) . . . .
C6 C7 C8 C9 2.3(8) . . . .
C7 C8 C9 C4 -3.9(8) . . . .
C5 C4 C9 C8 0.9(7) . . . .
C1 C4 C9 C8 -179.7(4) . . . .
Pr2 O8 C10 O7 -93.8(6) 1_655 . . .
Pr2 O8 C10 C13 89.9(6) 1_655 . . .
Pr1 O7 C10 O8 -174.2(4) . . . .
Pr1 O7 C10 C13 2.2(9) . . . .
Pr2 O10 C11 O9 -19.1(12) 2_666 . . .
Pr2 O10 C11 C14 164.9(7) 2_666 . . .
Pr2 O9 C11 O10 104.1(5) . . . .
Pr1 O9 C11 O10 -101.2(5) . . . .
Pr2 O9 C11 C14 -80.0(4) . . . .
Pr1 O9 C11 C14 74.8(5) . . . .
Pr2 O11 C12 O12 104.8(6) . . . .
Pr2 O11 C12 C15 -76.0(6) . . . .
O8 C10 C13 C18 44.1(7) . . . .
O7 C10 C13 C18 -132.5(5) . . . .
O8 C10 C13 C14 -136.8(5) . . . .
O7 C10 C13 C14 46.6(7) . . . .
C18 C13 C14 C15 1.5(7) . . . .
C10 C13 C14 C15 -177.6(4) . . . .
C18 C13 C14 C11 -174.7(4) . . . .
C10 C13 C14 C11 6.2(6) . . . .
O10 C11 C14 C15 -97.9(6) . . . .
O9 C11 C14 C15 85.8(6) . . . .
O10 C11 C14 C13 78.0(6) . . . .
O9 C11 C14 C13 -98.2(5) . . . .
C13 C14 C15 C16 2.4(7) . . . .
C11 C14 C15 C16 178.4(4) . . . .
C13 C14 C15 C12 -176.3(4) . . . .
C11 C14 C15 C12 -0.4(7) . . . .
O12 C12 C15 C14 171.3(5) . . . .
O11 C12 C15 C14 -8.0(7) . . . .
O12 C12 C15 C16 -7.4(8) . . . .
O11 C12 C15 C16 173.3(5) . . . .
C14 C15 C16 C17 -3.6(8) . . . .
C12 C15 C16 C17 175.1(5) . . . .
C15 C16 C17 C18 0.8(8) . . . .
C16 C17 C18 C13 3.2(8) . . . .
C14 C13 C18 C17 -4.4(8) . . . .
C10 C13 C18 C17 174.7(5) . . . .
Pr1 O13 C19 O14 -5.4(8) . . . .
Pr1 O13 C19 C20 175.9(3) . . . .
Pr2 O14 C19 O13 -4.4(9) . . . .
Pr2 O14 C19 C20 174.3(3) . . . .
O13 C19 C20 C21 160.0(5) . . . .
O14 C19 C20 C21 -18.8(6) . . . .
O13 C19 C20 C24 -17.7(7) . . . .
O14 C19 C20 C24 163.5(4) . . . .
C24 C20 C21 C22 2.5(7) . . . .
C19 C20 C21 C22 -175.3(4) . . . .
C23 N1 C22 C21 0.1(8) . . . .
Ag1 N1 C22 C21 179.5(4) . . . .
C20 C21 C22 N1 -2.9(8) . . . .
C22 N1 C23 C24 3.1(8) . . . .
Ag1 N1 C23 C24 -176.4(4) . . . .
N1 C23 C24 C20 -3.4(8) . . . .
C21 C20 C24 C23 0.4(7) . . . .
C19 C20 C24 C23 178.2(4) . . . .
