#------------------------------------------------------------------------------
#$Date: 2021-05-27 10:45:12 +0300 (Thu, 27 May 2021) $
#$Revision: 265543 $
#$URL: file:///home/coder/svn-repositories/cod/cif/1/56/29/1562912.cif $
#------------------------------------------------------------------------------
#
# This file is available in the Crystallography Open Database (COD),
# http://www.crystallography.net/
#
# All data on this site have been placed in the public domain by the
# contributors.
#
data_1562912
loop_
_publ_author_name
'Jung, Yaho'
'Nam, Gnu'
'Jeon, Jieun'
'Kim, Youngjo'
'You, Tae-Soo'
_publ_section_title
;
 Crystal structure and chemical bonding of novel Li-containing polar
 intermetallic compound La11Li12Ge16
;
_journal_name_full               'Journal of Solid State Chemistry'
_journal_page_first              543
_journal_page_last               549
_journal_paper_doi               10.1016/j.jssc.2012.07.034
_journal_volume                  196
_journal_year                    2012
_chemical_formula_moiety         'La11 Li12 Ge16'
_chemical_formula_sum            'Ge16 La11 Li12'
_chemical_formula_weight         2772.73
_space_group_IT_number           71
_space_group_name_Hall           '-I 2 2'
_space_group_name_H-M_alt        'I m m m'
_symmetry_cell_setting           orthorhombic
_symmetry_space_group_name_Hall  '-I 2 2'
_symmetry_space_group_name_H-M   'I m m m'
_atom_sites_solution_hydrogens   .
_atom_sites_solution_primary     direct
_atom_sites_solution_secondary   difmap
_audit_creation_method           SHELXL-97
_cell_angle_alpha                90.00
_cell_angle_beta                 90.00
_cell_angle_gamma                90.00
_cell_formula_units_Z            2
_cell_length_a                   4.5244(4)
_cell_length_b                   6.9932(6)
_cell_length_c                   53.043(5)
_cell_measurement_reflns_used    1989
_cell_measurement_temperature    296(2)
_cell_measurement_theta_max      34.10
_cell_measurement_theta_min      3.07
_cell_volume                     1678.3(3)
_computing_cell_refinement       'Bruker SAINT'
_computing_data_collection       'Bruker APEX2'
_computing_data_reduction        'Bruker SAINT'
_computing_molecular_graphics    'Bruker SHELXTL'
_computing_publication_material  'Bruker SHELXTL'
_computing_structure_refinement  'SHELXL-97 (Sheldrick, 2008)'
_computing_structure_solution    'SHELXS-97 (Sheldrick, 2008)'
_diffrn_ambient_temperature      296(2)
_diffrn_measured_fraction_theta_full 0.983
_diffrn_measured_fraction_theta_max 0.983
_diffrn_measurement_device_type  'Bruker APEX-II CCD'
_diffrn_measurement_method       'φ and ω scans'
_diffrn_radiation_monochromator  graphite
_diffrn_radiation_source         'fine-focus sealed tube'
_diffrn_radiation_type           MoK\a
_diffrn_radiation_wavelength     0.71073
_diffrn_reflns_av_R_equivalents  0.0210
_diffrn_reflns_av_sigmaI/netI    0.0203
_diffrn_reflns_limit_h_max       6
_diffrn_reflns_limit_h_min       -4
_diffrn_reflns_limit_k_max       3
_diffrn_reflns_limit_k_min       -9
_diffrn_reflns_limit_l_max       58
_diffrn_reflns_limit_l_min       -70
_diffrn_reflns_number            5106
_diffrn_reflns_theta_full        29.13
_diffrn_reflns_theta_max         29.13
_diffrn_reflns_theta_min         2.94
_exptl_absorpt_coefficient_mu    27.708
_exptl_absorpt_correction_type   none
_exptl_crystal_colour            Silver
_exptl_crystal_density_diffrn    5.487
_exptl_crystal_density_meas      5.487
_exptl_crystal_density_method    'not measured'
_exptl_crystal_description       block
_exptl_crystal_F_000             2350
_exptl_crystal_size_max          0.04
_exptl_crystal_size_mid          0.02
_exptl_crystal_size_min          0.02
_refine_diff_density_max         1.149
_refine_diff_density_min         -1.628
_refine_diff_density_rms         0.230
_refine_ls_extinction_coef       0.000309(15)
_refine_ls_extinction_expression Fc^*^=kFc[1+0.001xFc²λ³/sin(2θ)]^-1/4^
_refine_ls_extinction_method     SHELXL
_refine_ls_goodness_of_fit_ref   1.085
_refine_ls_hydrogen_treatment    .
_refine_ls_matrix_type           full
_refine_ls_number_parameters     71
_refine_ls_number_reflns         1358
_refine_ls_number_restraints     0
_refine_ls_restrained_S_all      1.085
_refine_ls_R_factor_all          0.0274
_refine_ls_R_factor_gt           0.0217
_refine_ls_shift/su_max          0.002
_refine_ls_shift/su_mean         0.000
_refine_ls_structure_factor_coef Fsqd
_refine_ls_weighting_details
'calc w=1/[σ²(Fo²)+(0.0186P)²+7.1558P] where P=(Fo²+2Fc²)/3'
_refine_ls_weighting_scheme      calc
_refine_ls_wR_factor_gt          0.0488
_refine_ls_wR_factor_ref         0.0507
_reflns_number_gt                1164
_reflns_number_total             1358
_reflns_threshold_expression     >2sigma(I)
_cod_data_source_file            JSSC-2012-196-543.cif
_cod_data_source_block           La11Li12Ge16
_cod_depositor_comments
;
The following automatic conversions were performed:

data item '_symmetry_cell_setting' value 'Orthorhombic' was changed
to 'orthorhombic' in accordance with the built-in table derived from
the CIF Core dictionary named 'cif_core.dic' version 2.4.5 last
updated on 2014-11-21.

Automatic conversion script
Id: cif_fix_values 8369 2020-08-20 11:38:08Z andrius 
;
_cod_original_sg_symbol_H-M      Immm
_cod_original_formula_sum        'La11 Li12 Ge16'
_cod_database_code               1562912
loop_
_symmetry_equiv_pos_as_xyz
'x, y, z'
'-x, -y, z'
'-x, y, -z'
'x, -y, -z'
'x+1/2, y+1/2, z+1/2'
'-x+1/2, -y+1/2, z+1/2'
'-x+1/2, y+1/2, -z+1/2'
'x+1/2, -y+1/2, -z+1/2'
'-x, -y, -z'
'x, y, -z'
'x, -y, z'
'-x, y, z'
'-x+1/2, -y+1/2, -z+1/2'
'x+1/2, y+1/2, -z+1/2'
'x+1/2, -y+1/2, z+1/2'
'-x+1/2, y+1/2, z+1/2'
loop_
_atom_site_label
_atom_site_type_symbol
_atom_site_fract_x
_atom_site_fract_y
_atom_site_fract_z
_atom_site_U_iso_or_equiv
_atom_site_adp_type
_atom_site_occupancy
_atom_site_symmetry_multiplicity
_atom_site_calc_flag
_atom_site_refinement_flags
_atom_site_disorder_assembly
_atom_site_disorder_group
La1 La 0.5000 0.0000 0.102640(8) 0.00909(11) Uani 1 4 d S . .
La2 La 0.5000 0.0000 0.178751(7) 0.00750(10) Uani 1 4 d S . .
La3 La 0.5000 0.0000 0.462665(8) 0.00943(10) Uani 1 4 d S . .
La4 La 0.0000 0.0000 0.282364(8) 0.00896(10) Uani 1 4 d S . .
La5 La 0.0000 0.0000 0.358376(7) 0.00751(10) Uani 1 4 d S . .
La6 La 0.0000 0.0000 0.0000 0.00853(13) Uani 1 8 d S . .
Ge1 Ge 0.0000 0.17972(7) 0.138588(10) 0.00920(13) Uani 1 2 d S . .
Ge2 Ge 0.0000 0.32021(8) 0.181967(10) 0.00906(13) Uani 1 2 d S . .
Ge3 Ge 0.5000 0.0000 0.239126(14) 0.01028(17) Uani 1 4 d S . .
Ge4 Ge 0.0000 0.0000 0.060266(14) 0.01047(17) Uani 1 4 d S . .
Ge5 Ge 0.0000 0.0000 0.418452(14) 0.01084(17) Uani 1 4 d S . .
Ge6 Ge 0.0000 0.18162(10) 0.5000 0.00928(16) Uani 1 4 d S . .
Li1 Li 0.0000 0.1875(13) 0.22788(19) 0.018(2) Uani 1 2 d S . .
Li2 Li 0.0000 0.3132(12) 0.09225(18) 0.017(2) Uani 1 2 d S . .
Li3 Li 0.0000 0.3093(14) 0.45223(17) 0.0146(19) Uani 1 2 d S . .
loop_
_atom_type_symbol
_atom_type_description
_atom_type_scat_dispersion_real
_atom_type_scat_dispersion_imag
_atom_type_scat_source
Li Li -0.0003 0.0001 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
Ge Ge 0.1547 1.8001 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
La La -0.2871 2.4523 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
loop_
_geom_angle_atom_site_label_1
_geom_angle_atom_site_label_2
_geom_angle_atom_site_label_3
_geom_angle
_geom_angle_site_symmetry_1
_geom_angle_site_symmetry_3
Ge4 La1 Ge4 90.37(2) . 1_655
Ge4 La1 Li2 51.43(16) . 2
Ge4 La1 Li2 112.37(15) 1_655 2
Ge4 La1 Li2 112.37(15) . 1_655
Ge4 La1 Li2 51.43(16) 1_655 1_655
Li2 La1 Li2 160.2(3) 2 1_655
Ge4 La1 Li2 112.37(15) . 2_655
Ge4 La1 Li2 51.43(16) 1_655 2_655
Li2 La1 Li2 90.1(2) 2 2_655
Li2 La1 Li2 86.5(2) 1_655 2_655
Ge4 La1 Li2 51.43(16) . .
Ge4 La1 Li2 112.37(15) 1_655 .
Li2 La1 Li2 86.5(2) 2 .
Li2 La1 Li2 90.1(2) 1_655 .
Li2 La1 Li2 160.2(3) 2_655 .
Ge4 La1 Li3 50.15(7) . 14_545
Ge4 La1 Li3 50.15(7) 1_655 14_545
Li2 La1 Li3 63.8(2) 2 14_545
Li2 La1 Li3 97.4(2) 1_655 14_545
Li2 La1 Li3 63.8(2) 2_655 14_545
Li2 La1 Li3 97.4(2) . 14_545
Ge4 La1 Li3 50.15(7) . 13
Ge4 La1 Li3 50.15(7) 1_655 13
Li2 La1 Li3 97.4(2) 2 13
Li2 La1 Li3 63.8(2) 1_655 13
Li2 La1 Li3 97.4(2) 2_655 13
Li2 La1 Li3 63.8(2) . 13
Li3 La1 Li3 49.2(3) 14_545 13
Ge4 La1 Ge1 85.346(13) . .
Ge4 La1 Ge1 156.537(10) 1_655 .
Li2 La1 Ge1 82.65(13) 2 .
Li2 La1 Ge1 109.42(14) 1_655 .
Li2 La1 Ge1 150.25(17) 2_655 .
Li2 La1 Ge1 48.42(17) . .
Li3 La1 Ge1 134.60(3) 14_545 .
Li3 La1 Ge1 112.11(11) 13 .
Ge4 La1 Ge1 156.537(10) . 1_655
Ge4 La1 Ge1 85.347(13) 1_655 1_655
Li2 La1 Ge1 150.25(17) 2 1_655
Li2 La1 Ge1 48.42(17) 1_655 1_655
Li2 La1 Ge1 82.65(13) 2_655 1_655
Li2 La1 Ge1 109.42(14) . 1_655
Li3 La1 Ge1 134.60(3) 14_545 1_655
Li3 La1 Ge1 112.11(11) 13 1_655
Ge1 La1 Ge1 89.456(17) . 1_655
Ge4 La1 Ge1 156.537(10) . 2_655
Ge4 La1 Ge1 85.347(13) 1_655 2_655
Li2 La1 Ge1 109.42(14) 2 2_655
Li2 La1 Ge1 82.65(13) 1_655 2_655
Li2 La1 Ge1 48.42(17) 2_655 2_655
Li2 La1 Ge1 150.25(17) . 2_655
Li3 La1 Ge1 112.11(11) 14_545 2_655
Li3 La1 Ge1 134.60(3) 13 2_655
Ge1 La1 Ge1 107.23(2) . 2_655
Ge1 La1 Ge1 46.033(19) 1_655 2_655
Ge4 La1 Ge1 85.346(13) . 2
Ge4 La1 Ge1 156.536(10) 1_655 2
Li2 La1 Ge1 48.42(17) 2 2
Li2 La1 Ge1 150.25(17) 1_655 2
Li2 La1 Ge1 109.42(14) 2_655 2
Li2 La1 Ge1 82.65(13) . 2
Li3 La1 Ge1 112.11(11) 14_545 2
Li3 La1 Ge1 134.60(3) 13 2
Ge1 La1 Ge1 46.032(19) . 2
Ge1 La1 Ge1 107.23(2) 1_655 2
Ge1 La1 Ge1 89.456(17) 2_655 2
Ge2 La2 Ge2 90.417(15) . 1_655
Ge2 La2 Ge2 89.255(15) . 2
Ge2 La2 Ge2 173.86(2) 1_655 2
Ge2 La2 Ge2 173.86(2) . 2_655
Ge2 La2 Ge2 89.255(15) 1_655 2_655
Ge2 La2 Ge2 90.417(15) 2 2_655
Ge2 La2 Ge3 86.932(12) . .
Ge2 La2 Ge3 86.930(12) 1_655 .
Ge2 La2 Ge3 86.930(12) 2 .
Ge2 La2 Ge3 86.930(12) 2_655 .
Ge2 La2 Ge1 44.899(13) . .
Ge2 La2 Ge1 104.453(13) 1_655 .
Ge2 La2 Ge1 79.542(12) 2 .
Ge2 La2 Ge1 140.932(17) 2_655 .
Ge3 La2 Ge1 129.461(9) . .
Ge2 La2 Ge1 79.541(12) . 2
Ge2 La2 Ge1 140.932(17) 1_655 2
Ge2 La2 Ge1 44.901(13) 2 2
Ge2 La2 Ge1 104.453(13) 2_655 2
Ge3 La2 Ge1 129.461(10) . 2
Ge1 La2 Ge1 44.044(18) . 2
Ge2 La2 Ge1 104.452(13) . 1_655
Ge2 La2 Ge1 44.901(13) 1_655 1_655
Ge2 La2 Ge1 140.932(17) 2 1_655
Ge2 La2 Ge1 79.542(12) 2_655 1_655
Ge3 La2 Ge1 129.461(10) . 1_655
Ge1 La2 Ge1 84.892(16) . 1_655
Ge1 La2 Ge1 101.079(19) 2 1_655
Ge2 La2 Ge1 140.930(17) . 2_655
Ge2 La2 Ge1 79.542(12) 1_655 2_655
Ge2 La2 Ge1 104.453(13) 2 2_655
Ge2 La2 Ge1 44.901(13) 2_655 2_655
Ge3 La2 Ge1 129.461(10) . 2_655
Ge1 La2 Ge1 101.078(19) . 2_655
Ge1 La2 Ge1 84.892(16) 2 2_655
Ge1 La2 Ge1 44.044(18) 1_655 2_655
Ge2 La2 Li1 98.49(11) . 1_655
Ge2 La2 Li1 43.76(13) 1_655 1_655
Ge2 La2 Li1 130.29(13) 2 1_655
Ge2 La2 Li1 77.10(11) 2_655 1_655
Ge3 La2 Li1 45.10(12) . 1_655
Ge1 La2 Li1 136.80(13) . 1_655
Ge1 La2 Li1 174.51(11) 2 1_655
Ge1 La2 Li1 84.37(12) 1_655 1_655
Ge1 La2 Li1 99.68(10) 2_655 1_655
Ge2 La2 Li1 130.29(13) . 2_655
Ge2 La2 Li1 77.10(11) 1_655 2_655
Ge2 La2 Li1 98.49(11) 2 2_655
Ge2 La2 Li1 43.76(13) 2_655 2_655
Ge3 La2 Li1 45.10(12) . 2_655
Ge1 La2 Li1 174.51(11) . 2_655
Ge1 La2 Li1 136.80(13) 2 2_655
Ge1 La2 Li1 99.68(10) 1_655 2_655
Ge1 La2 Li1 84.37(12) 2_655 2_655
Li1 La2 Li1 41.6(3) 1_655 2_655
Ge2 La2 Li1 77.11(11) . 2
Ge2 La2 Li1 130.29(13) 1_655 2
Ge2 La2 Li1 43.76(13) 2 2
Ge2 La2 Li1 98.49(11) 2_655 2
Ge3 La2 Li1 45.10(12) . 2
Ge1 La2 Li1 99.68(10) . 2
Ge1 La2 Li1 84.37(12) 2 2
Ge1 La2 Li1 174.51(11) 1_655 2
Ge1 La2 Li1 136.80(13) 2_655 2
Li1 La2 Li1 90.2(2) 1_655 2
Li1 La2 Li1 75.59(19) 2_655 2
Li3 La3 Li3 85.8(3) . 2
Li3 La3 Li3 90.8(3) . 1_655
Li3 La3 Li3 159.9(3) 2 1_655
Li3 La3 Li3 159.9(3) . 2_655
Li3 La3 Li3 90.8(2) 2 2_655
Li3 La3 Li3 85.8(3) 1_655 2_655
Li3 La3 Li2 96.87(19) . 14_545
Li3 La3 Li2 64.06(19) 2 14_545
Li3 La3 Li2 96.9(2) 1_655 14_545
Li3 La3 Li2 64.06(19) 2_655 14_545
Li3 La3 Li2 64.07(19) . 13
Li3 La3 Li2 96.9(2) 2 13
Li3 La3 Li2 64.06(19) 1_655 13
Li3 La3 Li2 96.87(19) 2_655 13
Li2 La3 Li2 48.3(3) 14_545 13
Li3 La3 Ge5 51.72(16) . .
Li3 La3 Ge5 51.72(16) 2 .
Li3 La3 Ge5 111.64(15) 1_655 .
Li3 La3 Ge5 111.64(15) 2_655 .
Li2 La3 Ge5 48.95(6) 14_545 .
Li2 La3 Ge5 48.95(7) 13 .
Li3 La3 Ge5 111.65(15) . 1_655
Li3 La3 Ge5 111.64(15) 2 1_655
Li3 La3 Ge5 51.72(16) 1_655 1_655
Li3 La3 Ge5 51.72(16) 2_655 1_655
Li2 La3 Ge5 48.95(6) 14_545 1_655
Li2 La3 Ge5 48.95(6) 13 1_655
Ge5 La3 Ge5 87.93(2) . 1_655
Li3 La3 Ge6 109.52(15) . 1_655
Li3 La3 Ge6 149.75(17) 2 1_655
Li3 La3 Ge6 49.27(16) 1_655 1_655
Li3 La3 Ge6 82.94(13) 2_655 1_655
Li2 La3 Ge6 135.47(3) 14_545 1_655
Li2 La3 Ge6 113.23(11) 13 1_655
Ge5 La3 Ge6 156.621(13) . 1_655
Ge5 La3 Ge6 87.451(11) 1_655 1_655
Li3 La3 Ge6 49.27(16) . .
Li3 La3 Ge6 82.94(13) 2 .
Li3 La3 Ge6 109.52(15) 1_655 .
Li3 La3 Ge6 149.75(17) 2_655 .
Li2 La3 Ge6 135.47(3) 14_545 .
Li2 La3 Ge6 113.23(11) 13 .
Ge5 La3 Ge6 87.449(11) . .
Ge5 La3 Ge6 156.620(13) 1_655 .
Ge6 La3 Ge6 87.754(14) 1_655 .
Li3 La3 Ge6 149.74(17) . 9_656
Li3 La3 Ge6 109.52(15) 2 9_656
Li3 La3 Ge6 82.94(13) 1_655 9_656
Li3 La3 Ge6 49.27(16) 2_655 9_656
Li2 La3 Ge6 113.23(11) 14_545 9_656
Li2 La3 Ge6 135.47(3) 13 9_656
Ge5 La3 Ge6 156.621(13) . 9_656
Ge5 La3 Ge6 87.451(11) 1_655 9_656
Ge6 La3 Ge6 45.80(2) 1_655 9_656
Ge6 La3 Ge6 105.289(15) . 9_656
Li3 La3 Ge6 82.94(13) . 9_556
Li3 La3 Ge6 49.27(16) 2 9_556
Li3 La3 Ge6 149.75(17) 1_655 9_556
Li3 La3 Ge6 109.52(15) 2_655 9_556
Li2 La3 Ge6 113.23(11) 14_545 9_556
Li2 La3 Ge6 135.47(3) 13 9_556
Ge5 La3 Ge6 87.449(11) . 9_556
Ge5 La3 Ge6 156.620(13) 1_655 9_556
Ge6 La3 Ge6 105.289(15) 1_655 9_556
Ge6 La3 Ge6 45.80(2) . 9_556
Ge6 La3 Ge6 87.754(14) 9_656 9_556
Li1 La4 Li1 48.8(3) . 2
Li1 La4 Li1 97.35(12) . 14_445
Li1 La4 Li1 64.0(2) 2 14_445
Li1 La4 Li1 64.0(2) . 13
Li1 La4 Li1 97.35(12) 2 13
Li1 La4 Li1 160.4(4) 14_445 13
Li1 La4 Li1 97.35(12) . 14_545
Li1 La4 Li1 64.0(2) 2 14_545
Li1 La4 Li1 90.3(2) 14_445 14_545
Li1 La4 Li1 86.4(2) 13 14_545
Li1 La4 Li1 64.0(2) . 13_455
Li1 La4 Li1 97.35(12) 2 13_455
Li1 La4 Li1 86.4(2) 14_445 13_455
Li1 La4 Li1 90.3(2) 13 13_455
Li1 La4 Li1 160.4(4) 14_545 13_455
Li1 La4 Ge2 112.05(11) . 13
Li1 La4 Ge2 134.38(3) 2 13
Li1 La4 Ge2 150.35(18) 14_445 13
Li1 La4 Ge2 48.07(17) 13 13
Li1 La4 Ge2 82.46(13) 14_545 13
Li1 La4 Ge2 109.39(15) 13_455 13
Li1 La4 Ge2 134.38(3) . 14_545
Li1 La4 Ge2 112.05(11) 2 14_545
Li1 La4 Ge2 109.39(15) 14_445 14_545
Li1 La4 Ge2 82.46(13) 13 14_545
Li1 La4 Ge2 48.07(17) 14_545 14_545
Li1 La4 Ge2 150.35(18) 13_455 14_545
Ge2 La4 Ge2 46.180(19) 13 14_545
Li1 La4 Ge2 134.38(3) . 14_445
Li1 La4 Ge2 112.05(11) 2 14_445
Li1 La4 Ge2 48.07(17) 14_445 14_445
Li1 La4 Ge2 150.35(18) 13 14_445
Li1 La4 Ge2 109.39(15) 14_545 14_445
Li1 La4 Ge2 82.46(13) 13_455 14_445
Ge2 La4 Ge2 107.67(2) 13 14_445
Ge2 La4 Ge2 89.763(17) 14_545 14_445
Li1 La4 Ge2 112.05(11) . 13_455
Li1 La4 Ge2 134.38(3) 2 13_455
Li1 La4 Ge2 82.46(13) 14_445 13_455
Li1 La4 Ge2 109.39(15) 13 13_455
Li1 La4 Ge2 150.35(18) 14_545 13_455
Li1 La4 Ge2 48.07(17) 13_455 13_455
Ge2 La4 Ge2 89.763(17) 13 13_455
Ge2 La4 Ge2 107.67(2) 14_545 13_455
Ge2 La4 Ge2 46.181(19) 14_445 13_455
Li1 La4 Ge3 49.59(7) . 1_455
Li1 La4 Ge3 49.58(7) 2 1_455
Li1 La4 Ge3 51.77(17) 14_445 1_455
Li1 La4 Ge3 112.12(15) 13 1_455
Li1 La4 Ge3 112.12(15) 14_545 1_455
Li1 La4 Ge3 51.77(17) 13_455 1_455
Ge2 La4 Ge3 156.302(11) 13 1_455
Ge2 La4 Ge3 156.302(11) 14_545 1_455
Ge2 La4 Ge3 85.675(13) 14_445 1_455
Ge2 La4 Ge3 85.675(13) 13_455 1_455
Li1 La4 Ge3 49.58(7) . .
Li1 La4 Ge3 49.58(7) 2 .
Li1 La4 Ge3 112.12(15) 14_445 .
Li1 La4 Ge3 51.77(17) 13 .
Li1 La4 Ge3 51.77(17) 14_545 .
Li1 La4 Ge3 112.12(15) 13_455 .
Ge2 La4 Ge3 85.677(13) 13 .
Ge2 La4 Ge3 85.677(13) 14_545 .
Ge2 La4 Ge3 156.302(11) 14_445 .
Ge2 La4 Ge3 156.302(11) 13_455 .
Ge3 La4 Ge3 89.22(2) 1_455 .
Ge5 La5 Ge1 87.105(12) . 13
Ge5 La5 Ge1 87.105(12) . 14_445
Ge1 La5 Ge1 174.21(2) 13 14_445
Ge5 La5 Ge1 87.105(12) . 14_545
Ge1 La5 Ge1 89.284(15) 13 14_545
Ge1 La5 Ge1 90.424(15) 14_445 14_545
Ge5 La5 Ge1 87.105(12) . 13_455
Ge1 La5 Ge1 90.424(15) 13 13_455
Ge1 La5 Ge1 89.284(15) 14_445 13_455
Ge1 La5 Ge1 174.21(2) 14_545 13_455
Ge5 La5 Ge2 129.586(9) . 14_445
Ge1 La5 Ge2 140.655(17) 13 14_445
Ge1 La5 Ge2 44.850(14) 14_445 14_445
Ge1 La5 Ge2 104.312(13) 14_545 14_445
Ge1 La5 Ge2 79.466(12) 13_455 14_445
Ge5 La5 Ge2 129.586(9) . 13_455
Ge1 La5 Ge2 104.312(13) 13 13_455
Ge1 La5 Ge2 79.466(12) 14_445 13_455
Ge1 La5 Ge2 140.655(17) 14_545 13_455
Ge1 La5 Ge2 44.850(14) 13_455 13_455
Ge2 La5 Ge2 43.972(18) 14_445 13_455
Ge5 La5 Ge2 129.586(9) . 14_545
Ge1 La5 Ge2 79.466(12) 13 14_545
Ge1 La5 Ge2 104.312(13) 14_445 14_545
Ge1 La5 Ge2 44.850(14) 14_545 14_545
Ge1 La5 Ge2 140.655(17) 13_455 14_545
Ge2 La5 Ge2 84.694(16) 14_445 14_545
Ge2 La5 Ge2 100.827(19) 13_455 14_545
Ge5 La5 Ge2 129.586(9) . 13
Ge1 La5 Ge2 44.850(14) 13 13
Ge1 La5 Ge2 140.655(17) 14_445 13
Ge1 La5 Ge2 79.466(12) 14_545 13
Ge1 La5 Ge2 104.312(13) 13_455 13
Ge2 La5 Ge2 100.827(19) 14_445 13
Ge2 La5 Ge2 84.694(16) 13_455 13
Ge2 La5 Ge2 43.972(18) 14_545 13
Ge5 La5 Li2 44.93(12) . 13
Ge1 La5 Li2 44.11(13) 13 13
Ge1 La5 Li2 130.28(13) 14_445 13
Ge1 La5 Li2 77.20(11) 14_545 13
Ge1 La5 Li2 98.63(11) 13_455 13
Ge2 La5 Li2 174.47(11) 14_445 13
Ge2 La5 Li2 136.96(13) 13_455 13
Ge2 La5 Li2 99.87(9) 14_545 13
Ge2 La5 Li2 84.66(12) 13 13
Ge5 La5 Li2 44.93(12) . 14_545
Ge1 La5 Li2 77.20(11) 13 14_545
Ge1 La5 Li2 98.63(11) 14_445 14_545
Ge1 La5 Li2 44.11(13) 14_545 14_545
Ge1 La5 Li2 130.28(13) 13_455 14_545
Ge2 La5 Li2 136.96(13) 14_445 14_545
Ge2 La5 Li2 174.47(11) 13_455 14_545
Ge2 La5 Li2 84.66(12) 14_545 14_545
Ge2 La5 Li2 99.87(9) 13 14_545
Li2 La5 Li2 41.4(3) 13 14_545
Ge5 La5 Li2 44.93(12) . 13_455
Ge1 La5 Li2 98.63(11) 13 13_455
Ge1 La5 Li2 77.20(11) 14_445 13_455
Ge1 La5 Li2 130.28(13) 14_545 13_455
Ge1 La5 Li2 44.11(13) 13_455 13_455
Ge2 La5 Li2 99.87(9) 14_445 13_455
Ge2 La5 Li2 84.66(12) 13_455 13_455
Ge2 La5 Li2 174.47(11) 14_545 13_455
Ge2 La5 Li2 136.96(13) 13 13_455
Li2 La5 Li2 75.41(18) 13 13_455
Li2 La5 Li2 89.9(2) 14_545 13_455
Ge6 La6 Ge6 180.000(19) 13 5_444
Ge6 La6 Ge6 90.91(2) 13 13_455
Ge6 La6 Ge6 89.09(2) 5_444 13_455
Ge6 La6 Ge6 89.09(2) 13 5_544
Ge6 La6 Ge6 90.91(2) 5_444 5_544
Ge6 La6 Ge6 180.0 13_455 5_544
Ge6 La6 Ge4 90.0 13 9
Ge6 La6 Ge4 90.0 5_444 9
Ge6 La6 Ge4 90.0 13_455 9
Ge6 La6 Ge4 90.0 5_544 9
Ge6 La6 Ge4 90.0 13 .
Ge6 La6 Ge4 90.0 5_444 .
Ge6 La6 Ge4 90.0 13_455 .
Ge6 La6 Ge4 90.0 5_544 .
Ge4 La6 Ge4 180.0 9 .
Ge6 La6 Li3 45.72(13) 13 13
Ge6 La6 Li3 134.28(13) 5_444 13
Ge6 La6 Li3 100.69(12) 13_455 13
Ge6 La6 Li3 79.31(12) 5_544 13
Ge4 La6 Li3 133.97(12) 9 13
Ge4 La6 Li3 46.03(12) . 13
Ge6 La6 Li3 134.28(13) 13 5_444
Ge6 La6 Li3 45.72(13) 5_444 5_444
Ge6 La6 Li3 79.31(12) 13_455 5_444
Ge6 La6 Li3 100.69(12) 5_544 5_444
Ge4 La6 Li3 46.03(12) 9 5_444
Ge4 La6 Li3 133.97(12) . 5_444
Li3 La6 Li3 180.0(2) 13 5_444
Ge6 La6 Li3 79.31(12) 13 14_545
Ge6 La6 Li3 100.69(12) 5_444 14_545
Ge6 La6 Li3 134.28(13) 13_455 14_545
Ge6 La6 Li3 45.72(13) 5_544 14_545
Ge4 La6 Li3 133.97(12) 9 14_545
Ge4 La6 Li3 46.03(12) . 14_545
Li3 La6 Li3 42.9(3) 13 14_545
Li3 La6 Li3 137.1(3) 5_444 14_545
Ge6 La6 Li3 100.69(12) 13 6_454
Ge6 La6 Li3 79.31(12) 5_444 6_454
Ge6 La6 Li3 45.72(13) 13_455 6_454
Ge6 La6 Li3 134.28(13) 5_544 6_454
Ge4 La6 Li3 46.03(12) 9 6_454
Ge4 La6 Li3 133.97(12) . 6_454
Li3 La6 Li3 137.1(3) 13 6_454
Li3 La6 Li3 42.9(3) 5_444 6_454
Li3 La6 Li3 180.0(2) 14_545 6_454
Ge6 La6 Li3 100.69(12) 13 13_455
Ge6 La6 Li3 79.31(12) 5_444 13_455
Ge6 La6 Li3 45.72(13) 13_455 13_455
Ge6 La6 Li3 134.28(13) 5_544 13_455
Ge4 La6 Li3 133.97(12) 9 13_455
Ge4 La6 Li3 46.03(12) . 13_455
Li3 La6 Li3 76.62(18) 13 13_455
Li3 La6 Li3 103.38(18) 5_444 13_455
Li3 La6 Li3 92.1(2) 14_545 13_455
Li3 La6 Li3 87.9(2) 6_454 13_455
Ge6 La6 Li3 79.31(12) 13 5_544
Ge6 La6 Li3 100.69(12) 5_444 5_544
Ge6 La6 Li3 134.28(13) 13_455 5_544
Ge6 La6 Li3 45.72(13) 5_544 5_544
Ge4 La6 Li3 46.03(12) 9 5_544
Ge4 La6 Li3 133.97(12) . 5_544
Li3 La6 Li3 103.38(18) 13 5_544
Li3 La6 Li3 76.62(18) 5_444 5_544
Li3 La6 Li3 87.9(2) 14_545 5_544
Li3 La6 Li3 92.1(2) 6_454 5_544
Li3 La6 Li3 180.0(2) 13_455 5_544
Ge2 Ge1 Ge1 113.121(19) . 2
Ge2 Ge1 Li2 136.1(2) . .
Ge1 Ge1 Li2 110.79(19) 2 .
Ge2 Ge1 La5 71.193(16) . 13
Ge1 Ge1 La5 134.642(7) 2 13
Li2 Ge1 La5 78.34(13) . 13
Ge2 Ge1 La5 71.193(16) . 13_455
Ge1 Ge1 La5 134.642(8) 2 13_455
Li2 Ge1 La5 78.34(13) . 13_455
La5 Ge1 La5 90.424(15) 13 13_455
Ge2 Ge1 La1 134.353(10) . .
Ge1 Ge1 La1 66.984(9) 2 .
Li2 Ge1 La1 65.43(12) . .
La5 Ge1 La1 78.770(9) 13 .
La5 Ge1 La1 143.53(2) 13_455 .
Ge2 Ge1 La1 134.354(10) . 1_455
Ge1 Ge1 La1 66.984(9) 2 1_455
Li2 Ge1 La1 65.43(12) . 1_455
La5 Ge1 La1 143.53(2) 13 1_455
La5 Ge1 La1 78.770(9) 13_455 1_455
La1 Ge1 La1 89.455(17) . 1_455
Ge2 Ge1 La2 64.072(15) . 1_455
Ge1 Ge1 La2 67.978(9) 2 1_455
Li2 Ge1 La2 136.66(4) . 1_455
La5 Ge1 La2 135.265(19) 13 1_455
La5 Ge1 La2 75.663(9) 13_455 1_455
La1 Ge1 La2 134.857(17) . 1_455
La1 Ge1 La2 75.844(11) 1_455 1_455
Ge2 Ge1 La2 64.071(14) . .
Ge1 Ge1 La2 67.978(9) 2 .
Li2 Ge1 La2 136.66(4) . .
La5 Ge1 La2 75.664(9) 13 .
La5 Ge1 La2 135.263(19) 13_455 .
La1 Ge1 La2 75.844(11) . .
La1 Ge1 La2 134.858(17) 1_455 .
La2 Ge1 La2 84.893(16) 1_455 .
Ge1 Ge2 Ge2 113.124(19) . 2_565
Ge1 Ge2 Li1 136.0(2) . .
Ge2 Ge2 Li1 110.9(2) 2_565 .
Ge1 Ge2 La2 71.030(16) . .
Ge2 Ge2 La2 134.627(8) 2_565 .
Li1 Ge2 La2 78.45(14) . .
Ge1 Ge2 La2 71.028(16) . 1_455
Ge2 Ge2 La2 134.627(8) 2_565 1_455
Li1 Ge2 La2 78.46(14) . 1_455
La2 Ge2 La2 90.417(15) . 1_455
Ge1 Ge2 La4 134.167(10) . 13
Ge2 Ge2 La4 66.908(9) 2_565 13
Li1 Ge2 La4 65.68(13) . 13
La2 Ge2 La4 78.832(8) . 13
La2 Ge2 La4 143.89(2) 1_455 13
Ge1 Ge2 La4 134.167(10) . 13_455
Ge2 Ge2 La4 66.908(9) 2_565 13_455
Li1 Ge2 La4 65.68(13) . 13_455
La2 Ge2 La4 143.89(2) . 13_455
La2 Ge2 La4 78.834(9) 1_455 13_455
La4 Ge2 La4 89.760(17) 13 13_455
Ge1 Ge2 La5 63.959(14) . 13_455
Ge2 Ge2 La5 68.014(9) 2_565 13_455
Li1 Ge2 La5 136.78(4) . 13_455
La2 Ge2 La5 134.989(19) . 13_455
La2 Ge2 La5 75.571(9) 1_455 13_455
La4 Ge2 La5 134.794(18) 13 13_455
La4 Ge2 La5 75.753(11) 13_455 13_455
Ge1 Ge2 La5 63.959(14) . 13
Ge2 Ge2 La5 68.014(9) 2_565 13
Li1 Ge2 La5 136.78(4) . 13
La2 Ge2 La5 75.572(9) . 13
La2 Ge2 La5 134.987(19) 1_455 13
La4 Ge2 La5 75.753(11) 13 13
La4 Ge2 La5 134.794(18) 13_455 13
La5 Ge2 La5 84.696(16) 13_455 13
Li1 Ge3 Li1 58.5(3) . 2
Li1 Ge3 Li1 115.0(3) . 1_655
Li1 Ge3 Li1 154.3(4) 2 1_655
Li1 Ge3 Li1 154.3(4) . 2_655
Li1 Ge3 Li1 115.0(3) 2 2_655
Li1 Ge3 Li1 58.5(3) 1_655 2_655
Li1 Ge3 Li1 76.0(2) . 13
Li1 Ge3 Li1 121.38(14) 2 13
Li1 Ge3 Li1 76.0(2) 1_655 13
Li1 Ge3 Li1 121.38(14) 2_655 13
Li1 Ge3 Li1 121.38(14) . 14_545
Li1 Ge3 Li1 76.0(2) 2 14_545
Li1 Ge3 Li1 121.38(14) 1_655 14_545
Li1 Ge3 Li1 76.0(2) 2_655 14_545
Li1 Ge3 Li1 102.6(4) 13 14_545
Li1 Ge3 La2 77.1(2) . .
Li1 Ge3 La2 77.1(2) 2 .
Li1 Ge3 La2 77.1(2) 1_655 .
Li1 Ge3 La2 77.1(2) 2_655 .
Li1 Ge3 La2 128.69(19) 13 .
Li1 Ge3 La2 128.69(19) 14_545 .
Li1 Ge3 La4 138.7(2) . 1_655
Li1 Ge3 La4 138.7(2) 2 1_655
Li1 Ge3 La4 64.28(19) 1_655 1_655
Li1 Ge3 La4 64.28(19) 2_655 1_655
Li1 Ge3 La4 63.57(12) 13 1_655
Li1 Ge3 La4 63.57(12) 14_545 1_655
La2 Ge3 La4 135.393(11) . 1_655
Li1 Ge3 La4 64.28(19) . .
Li1 Ge3 La4 64.28(19) 2 .
Li1 Ge3 La4 138.7(2) 1_655 .
Li1 Ge3 La4 138.7(2) 2_655 .
Li1 Ge3 La4 63.57(12) 13 .
Li1 Ge3 La4 63.57(12) 14_545 .
La2 Ge3 La4 135.393(11) . .
La4 Ge3 La4 89.21(2) 1_655 .
Li3 Ge4 Li3 151.7(4) 14_445 13
Li3 Ge4 Li3 59.0(4) 14_445 13_455
Li3 Ge4 Li3 113.3(3) 13 13_455
Li3 Ge4 Li3 113.3(3) 14_445 14_545
Li3 Ge4 Li3 59.0(4) 13 14_545
Li3 Ge4 Li3 151.7(4) 13_455 14_545
Li3 Ge4 Li2 122.63(17) 14_445 .
Li3 Ge4 Li2 76.1(2) 13 .
Li3 Ge4 Li2 76.1(2) 13_455 .
Li3 Ge4 Li2 122.63(17) 14_545 .
Li3 Ge4 Li2 76.1(2) 14_445 2
Li3 Ge4 Li2 122.63(17) 13 2
Li3 Ge4 Li2 122.63(17) 13_455 2
Li3 Ge4 Li2 76.1(2) 14_545 2
Li2 Ge4 Li2 104.5(4) . 2
Li3 Ge4 La1 65.17(18) 14_445 1_455
Li3 Ge4 La1 139.9(2) 13 1_455
Li3 Ge4 La1 65.17(18) 13_455 1_455
Li3 Ge4 La1 139.9(2) 14_545 1_455
Li2 Ge4 La1 64.43(12) . 1_455
Li2 Ge4 La1 64.43(12) 2 1_455
Li3 Ge4 La1 139.9(2) 14_445 .
Li3 Ge4 La1 65.17(18) 13 .
Li3 Ge4 La1 139.9(2) 13_455 .
Li3 Ge4 La1 65.17(18) 14_545 .
Li2 Ge4 La1 64.43(12) . .
Li2 Ge4 La1 64.43(12) 2 .
La1 Ge4 La1 90.37(2) 1_455 .
Li3 Ge4 La6 75.83(19) 14_445 .
Li3 Ge4 La6 75.83(19) 13 .
Li3 Ge4 La6 75.83(19) 13_455 .
Li3 Ge4 La6 75.83(19) 14_545 .
Li2 Ge4 La6 127.77(19) . .
Li2 Ge4 La6 127.77(19) 2 .
La1 Ge4 La6 134.814(11) 1_455 .
La1 Ge4 La6 134.815(11) . .
Li2 Ge5 Li2 155.5(4) 14_445 13
Li2 Ge5 Li2 58.5(3) 14_445 13_455
Li2 Ge5 Li2 115.6(3) 13 13_455
Li2 Ge5 Li2 115.6(3) 14_445 14_545
Li2 Ge5 Li2 58.5(3) 13 14_545
Li2 Ge5 Li2 155.5(4) 13_455 14_545
Li2 Ge5 Li3 76.1(2) 14_445 2
Li2 Ge5 Li3 120.79(17) 13 2
Li2 Ge5 Li3 120.79(17) 13_455 2
Li2 Ge5 Li3 76.1(2) 14_545 2
Li2 Ge5 Li3 120.79(17) 14_445 .
Li2 Ge5 Li3 76.1(2) 13 .
Li2 Ge5 Li3 76.1(2) 13_455 .
Li2 Ge5 Li3 120.79(17) 14_545 .
Li3 Ge5 Li3 100.7(4) 2 .
Li2 Ge5 La5 77.7(2) 14_445 .
Li2 Ge5 La5 77.7(2) 13 .
Li2 Ge5 La5 77.7(2) 13_455 .
Li2 Ge5 La5 77.7(2) 14_545 .
Li3 Ge5 La5 129.64(19) 2 .
Li3 Ge5 La5 129.64(19) . .
Li2 Ge5 La3 64.24(19) 14_445 1_455
Li2 Ge5 La3 137.8(2) 13 1_455
Li2 Ge5 La3 64.24(19) 13_455 1_455
Li2 Ge5 La3 137.8(2) 14_545 1_455
Li3 Ge5 La3 62.67(12) 2 1_455
Li3 Ge5 La3 62.67(12) . 1_455
La5 Ge5 La3 136.030(11) . 1_455
Li2 Ge5 La3 137.8(2) 14_445 .
Li2 Ge5 La3 64.24(19) 13 .
Li2 Ge5 La3 137.8(2) 13_455 .
Li2 Ge5 La3 64.24(19) 14_545 .
Li3 Ge5 La3 62.67(12) 2 .
Li3 Ge5 La3 62.66(12) . .
La5 Ge5 La3 136.032(11) . .
La3 Ge5 La3 87.94(2) 1_455 .
Ge6 Ge6 Li3 109.4(2) 9_556 .
Ge6 Ge6 Li3 109.4(2) 9_556 10_556
Li3 Ge6 Li3 141.2(4) . 10_556
Ge6 Ge6 La6 134.544(10) 9_556 5
Li3 Ge6 La6 76.52(15) . 5
Li3 Ge6 La6 76.52(15) 10_556 5
Ge6 Ge6 La6 134.544(10) 9_556 5_455
Li3 Ge6 La6 76.52(14) . 5_455
Li3 Ge6 La6 76.52(14) 10_556 5_455
La6 Ge6 La6 90.91(2) 5 5_455
Ge6 Ge6 La3 67.098(12) 9_556 .
Li3 Ge6 La3 63.71(13) . .
Li3 Ge6 La3 134.55(5) 10_556 .
La6 Ge6 La3 77.231(6) 5 .
La6 Ge6 La3 140.082(12) 5_455 .
Ge6 Ge6 La3 67.099(12) 9_556 1_455
Li3 Ge6 La3 63.70(14) . 1_455
Li3 Ge6 La3 134.56(5) 10_556 1_455
La6 Ge6 La3 140.080(12) 5 1_455
La6 Ge6 La3 77.232(6) 5_455 1_455
La3 Ge6 La3 87.752(14) . 1_455
Ge6 Ge6 La3 67.099(12) 9_556 9_656
Li3 Ge6 La3 134.56(5) . 9_656
Li3 Ge6 La3 63.70(13) 10_556 9_656
La6 Ge6 La3 77.232(6) 5 9_656
La6 Ge6 La3 140.080(12) 5_455 9_656
La3 Ge6 La3 74.713(15) . 9_656
La3 Ge6 La3 134.20(2) 1_455 9_656
Ge6 Ge6 La3 67.099(12) 9_556 9_556
Li3 Ge6 La3 134.56(5) . 9_556
Li3 Ge6 La3 63.70(14) 10_556 9_556
La6 Ge6 La3 140.080(12) 5 9_556
La6 Ge6 La3 77.232(6) 5_455 9_556
La3 Ge6 La3 134.20(2) . 9_556
La3 Ge6 La3 74.716(15) 1_455 9_556
La3 Ge6 La3 87.750(14) 9_656 9_556
Ge2 Li1 Li1 110.9(2) . 2
Ge2 Li1 Ge3 112.5(2) . .
Li1 Li1 Ge3 60.73(17) 2 .
Ge2 Li1 Ge3 112.5(2) . 1_455
Li1 Li1 Ge3 60.73(17) 2 1_455
Ge3 Li1 Ge3 115.0(3) . 1_455
Ge2 Li1 Ge3 107.8(3) . 13
Li1 Li1 Ge3 141.32(19) 2 13
Ge3 Li1 Ge3 104.0(2) . 13
Ge3 Li1 Ge3 104.0(2) 1_455 13
Ge2 Li1 La4 176.5(4) . .
Li1 Li1 La4 65.60(17) 2 .
Ge3 Li1 La4 66.13(19) . .
Ge3 Li1 La4 66.13(19) 1_455 .
Ge3 Li1 La4 75.7(2) 13 .
Ge2 Li1 La4 66.24(17) . 13
Li1 Li1 La4 133.21(12) 2 13
Ge3 Li1 La4 76.99(5) . 13
Ge3 Li1 La4 166.0(3) 1_455 13
Ge3 Li1 La4 64.66(17) 13 13
La4 Li1 La4 116.0(2) . 13
Ge2 Li1 La4 66.24(17) . 13_455
Li1 Li1 La4 133.21(12) 2 13_455
Ge3 Li1 La4 166.0(3) . 13_455
Ge3 Li1 La4 76.99(5) 1_455 13_455
Ge3 Li1 La4 64.66(17) 13 13_455
La4 Li1 La4 116.0(2) . 13_455
La4 Li1 La4 90.3(2) 13 13_455
Ge2 Li1 Li1 123.9(3) . 13
Li1 Li1 Li1 105.0(3) 2 13
Ge3 Li1 Li1 53.60(13) . 13
Ge3 Li1 Li1 122.5(5) 1_455 13
Ge3 Li1 Li1 50.4(3) 13 13
La4 Li1 Li1 58.2(3) . 13
La4 Li1 Li1 57.72(18) 13 13
La4 Li1 Li1 114.6(4) 13_455 13
Ge2 Li1 Li1 123.9(3) . 13_455
Li1 Li1 Li1 105.0(3) 2 13_455
Ge3 Li1 Li1 122.5(5) . 13_455
Ge3 Li1 Li1 53.60(13) 1_455 13_455
Ge3 Li1 Li1 50.4(3) 13 13_455
La4 Li1 Li1 58.2(3) . 13_455
La4 Li1 Li1 114.6(4) 13 13_455
La4 Li1 Li1 57.72(18) 13_455 13_455
Li1 Li1 Li1 84.2(5) 13 13_455
Ge2 Li1 La2 57.78(16) . .
Li1 Li1 La2 69.19(13) 2 .
Ge3 Li1 La2 57.76(13) . .
Ge3 Li1 La2 120.0(3) 1_455 .
Ge3 Li1 La2 135.93(16) 13 .
La4 Li1 La2 119.7(2) . .
La4 Li1 La2 71.86(12) 13 .
La4 Li1 La2 123.9(3) 13_455 .
Li1 Li1 La2 99.91(14) 13 .
Li1 Li1 La2 173.5(4) 13_455 .
Ge2 Li1 La2 57.78(16) . 1_455
Li1 Li1 La2 69.19(13) 2 1_455
Ge3 Li1 La2 120.0(3) . 1_455
Ge3 Li1 La2 57.76(13) 1_455 1_455
Ge3 Li1 La2 135.93(16) 13 1_455
La4 Li1 La2 119.7(2) . 1_455
La4 Li1 La2 123.9(3) 13 1_455
La4 Li1 La2 71.86(12) 13_455 1_455
Li1 Li1 La2 173.5(4) 13 1_455
Li1 Li1 La2 99.91(14) 13_455 1_455
La2 Li1 La2 75.58(19) . 1_455
Li2 Li2 Ge1 110.79(19) 2_565 .
Li2 Li2 Ge5 60.74(16) 2_565 13
Ge1 Li2 Ge5 111.8(2) . 13
Li2 Li2 Ge5 60.74(16) 2_565 13_455
Ge1 Li2 Ge5 111.8(2) . 13_455
Ge5 Li2 Ge5 115.6(3) 13 13_455
Li2 Li2 Ge4 142.23(19) 2_565 .
Ge1 Li2 Ge4 107.0(3) . .
Ge5 Li2 Ge4 104.9(2) 13 .
Ge5 Li2 Ge4 104.9(2) 13_455 .
Li2 Li2 La3 65.84(16) 2_565 13
Ge1 Li2 La3 176.6(4) . 13
Ge5 Li2 La3 66.81(19) 13 13
Ge5 Li2 La3 66.81(19) 13_455 13
Ge4 Li2 La3 76.4(2) . 13
Li2 Li2 La1 133.25(12) 2_565 1_455
Ge1 Li2 La1 66.15(17) . 1_455
Ge5 Li2 La1 166.0(3) 13 1_455
Ge5 Li2 La1 76.86(5) 13_455 1_455
Ge4 Li2 La1 64.15(16) . 1_455
La3 Li2 La1 116.0(2) 13 1_455
Li2 Li2 La1 133.25(12) 2_565 .
Ge1 Li2 La1 66.15(17) . .
Ge5 Li2 La1 76.86(5) 13 .
Ge5 Li2 La1 166.0(3) 13_455 .
Ge4 Li2 La1 64.15(16) . .
La3 Li2 La1 116.0(2) 13 .
La1 Li2 La1 90.1(2) 1_455 .
Li2 Li2 Li3 104.7(2) 2_565 13_455
Ge1 Li2 Li3 124.3(3) . 13_455
Ge5 Li2 Li3 122.8(4) 13 13_455
Ge5 Li2 Li3 53.77(17) 13_455 13_455
Ge4 Li2 Li3 51.1(2) . 13_455
La3 Li2 Li3 57.8(2) 13 13_455
La1 Li2 Li3 58.19(17) 1_455 13_455
La1 Li2 Li3 114.9(3) . 13_455
Li2 Li2 Li3 104.7(2) 2_565 13
Ge1 Li2 Li3 124.3(3) . 13
Ge5 Li2 Li3 53.77(17) 13 13
Ge5 Li2 Li3 122.8(4) 13_455 13
Ge4 Li2 Li3 51.1(2) . 13
La3 Li2 Li3 57.8(2) 13 13
La1 Li2 Li3 114.9(3) 1_455 13
La1 Li2 Li3 58.20(17) . 13
Li3 Li2 Li3 84.1(3) 13_455 13
Li2 Li2 La5 69.31(13) 2_565 13
Ge1 Li2 La5 57.56(16) . 13
Ge5 Li2 La5 57.33(12) 13 13
Ge5 Li2 La5 119.7(3) 13_455 13
Ge4 Li2 La5 135.47(16) . 13
La3 Li2 La5 120.09(19) 13 13
La1 Li2 La5 123.6(3) 1_455 13
La1 Li2 La5 71.77(11) . 13
Li3 Li2 La5 173.4(3) 13_455 13
Li3 Li2 La5 100.05(11) 13 13
Li2 Li2 La5 69.31(13) 2_565 13_455
Ge1 Li2 La5 57.56(16) . 13_455
Ge5 Li2 La5 119.7(3) 13 13_455
Ge5 Li2 La5 57.33(12) 13_455 13_455
Ge4 Li2 La5 135.47(16) . 13_455
La3 Li2 La5 120.09(19) 13 13_455
La1 Li2 La5 71.77(11) 1_455 13_455
La1 Li2 La5 123.6(3) . 13_455
Li3 Li2 La5 100.05(11) 13_455 13_455
Li3 Li2 La5 173.4(3) 13 13_455
La5 Li2 La5 75.41(18) 13 13_455
Li3 Li3 Ge6 109.4(2) 2_565 .
Li3 Li3 Ge4 60.50(18) 2_565 13
Ge6 Li3 Ge4 113.2(2) . 13
Li3 Li3 Ge4 60.50(18) 2_565 13_455
Ge6 Li3 Ge4 113.2(2) . 13_455
Ge4 Li3 Ge4 113.3(3) 13 13_455
Li3 Li3 Ge5 140.35(19) 2_565 .
Ge6 Li3 Ge5 110.2(3) . .
Ge4 Li3 Ge5 102.9(2) 13 .
Ge4 Li3 Ge5 102.9(2) 13_455 .
Li3 Li3 La3 132.88(13) 2_565 1_455
Ge6 Li3 La3 67.03(18) . 1_455
Ge4 Li3 La3 166.5(3) 13 1_455
Ge4 Li3 La3 77.48(5) 13_455 1_455
Ge5 Li3 La3 65.61(18) . 1_455
Li3 Li3 La3 132.88(13) 2_565 .
Ge6 Li3 La3 67.03(18) . .
Ge4 Li3 La3 77.48(5) 13 .
Ge4 Li3 La3 166.5(3) 13_455 .
Ge5 Li3 La3 65.61(18) . .
La3 Li3 La3 90.8(2) 1_455 .
Li3 Li3 La1 65.37(17) 2_565 13
Ge6 Li3 La1 174.8(4) . 13
Ge4 Li3 La1 64.68(18) 13 13
Ge4 Li3 La1 64.68(18) 13_455 13
Ge5 Li3 La1 75.0(2) . 13
La3 Li3 La1 116.2(2) 1_455 13
La3 Li3 La1 116.2(2) . 13
Li3 Li3 Li2 104.7(2) 2_565 13_455
Ge6 Li3 Li2 125.1(3) . 13_455
Ge4 Li3 Li2 120.9(3) 13 13_455
Ge4 Li3 Li2 52.75(16) 13_455 13_455
Ge5 Li3 Li2 50.16(19) . 13_455
La3 Li3 Li2 58.17(17) 1_455 13_455
La3 Li3 Li2 115.2(3) . 13_455
La1 Li3 Li2 58.0(2) 13 13_455
Li3 Li3 Li2 104.7(2) 2_565 13
Ge6 Li3 Li2 125.1(3) . 13
Ge4 Li3 Li2 52.75(16) 13 13
Ge4 Li3 Li2 120.9(3) 13_455 13
Ge5 Li3 Li2 50.16(19) . 13
La3 Li3 Li2 115.2(3) 1_455 13
La3 Li3 Li2 58.18(17) . 13
La1 Li3 Li2 58.0(2) 13 13
Li2 Li3 Li2 84.0(3) 13_455 13
Li3 Li3 La6 68.56(15) 2_565 5
Ge6 Li3 La6 57.76(15) . 5
Ge4 Li3 La6 58.14(12) 13 5
Ge4 Li3 La6 120.5(3) 13_455 5
Ge5 Li3 La6 136.42(17) . 5
La3 Li3 La6 124.7(3) 1_455 5
La3 Li3 La6 71.74(11) . 5
La1 Li3 La6 118.6(2) 13 5
Li2 Li3 La6 173.0(3) 13_455 5
Li2 Li3 La6 99.35(12) 13 5
Li3 Li3 La6 68.56(14) 2_565 5_455
Ge6 Li3 La6 57.76(15) . 5_455
Ge4 Li3 La6 120.5(3) 13 5_455
Ge4 Li3 La6 58.14(12) 13_455 5_455
Ge5 Li3 La6 136.42(17) . 5_455
La3 Li3 La6 71.74(11) 1_455 5_455
La3 Li3 La6 124.7(3) . 5_455
La1 Li3 La6 118.6(2) 13 5_455
Li2 Li3 La6 99.35(12) 13_455 5_455
Li2 Li3 La6 173.0(3) 13 5_455
La6 Li3 La6 76.62(18) 5 5_455
loop_
_geom_bond_atom_site_label_1
_geom_bond_atom_site_label_2
_geom_bond_distance
_geom_bond_site_symmetry_2
La1 Ge4 3.1890(6) .
La1 Ge4 3.1890(6) 1_655
La1 Li2 3.196(6) 2
La1 Li2 3.196(6) 1_655
La1 Li2 3.196(6) 2_655
La1 Li2 3.196(6) .
La1 Li3 3.202(9) 14_545
La1 Li3 3.202(9) 13
La1 Ge1 3.2145(5) .
La1 Ge1 3.2145(5) 1_655
La1 Ge1 3.2145(5) 2_655
La1 Ge1 3.2145(5) 2
La2 Ge2 3.1876(4) .
La2 Ge2 3.1877(4) 1_655
La2 Ge2 3.1877(4) 2
La2 Ge2 3.1877(4) 2_655
La2 Ge3 3.2025(9) .
La2 Ge1 3.3519(5) .
La2 Ge1 3.3519(5) 2
La2 Ge1 3.3519(5) 1_655
La2 Ge1 3.3519(5) 2_655
La2 Li1 3.691(8) 1_655
La2 Li1 3.691(8) 2_655
La2 Li1 3.691(8) 2
La3 Li3 3.178(7) .
La3 Li3 3.178(7) 2
La3 Li3 3.178(7) 1_655
La3 Li3 3.178(7) 2_655
La3 Li2 3.193(10) 14_545
La3 Li2 3.193(10) 13
La3 Ge5 3.2584(6) .
La3 Ge5 3.2585(6) 1_655
La3 Ge6 3.2638(4) 1_655
La3 Ge6 3.2638(4) .
La3 Ge6 3.2638(4) 9_656
La3 Ge6 3.2638(4) 9_556
La4 Li1 3.174(10) .
La4 Li1 3.174(10) 2
La4 Li1 3.192(6) 14_445
La4 Li1 3.192(6) 13
La4 Li1 3.192(6) 14_545
La4 Li1 3.192(6) 13_455
La4 Ge2 3.2059(5) 13
La4 Ge2 3.2059(5) 14_545
La4 Ge2 3.2059(5) 14_445
La4 Ge2 3.2059(5) 13_455
La4 Ge3 3.2213(6) 1_455
La4 Ge3 3.2214(6) .
La5 Ge5 3.1866(9) .
La5 Ge1 3.1875(4) 13
La5 Ge1 3.1875(4) 14_445
La5 Ge1 3.1875(4) 14_545
La5 Ge1 3.1875(4) 13_455
La5 Ge2 3.3583(5) 14_445
La5 Ge2 3.3583(5) 13_455
La5 Ge2 3.3583(5) 14_545
La5 Ge2 3.3583(5) 13
La5 Li2 3.699(8) 13
La5 Li2 3.699(8) 14_545
La5 Li2 3.699(8) 13_455
La6 Ge6 3.1741(5) 13
La6 Ge6 3.1741(5) 5_444
La6 Ge6 3.1741(5) 13_455
La6 Ge6 3.1741(5) 5_544
La6 Ge4 3.1966(8) 9
La6 Ge4 3.1967(8) .
La6 Li3 3.649(7) 13
La6 Li3 3.649(7) 5_444
La6 Li3 3.649(7) 14_545
La6 Li3 3.649(7) 6_454
La6 Li3 3.649(7) 13_455
La6 Li3 3.649(7) 5_544
Ge1 Ge2 2.5019(8) .
Ge1 Ge1 2.5137(11) 2
Ge1 Li2 2.629(10) .
Ge1 La5 3.1875(4) 13
Ge1 La5 3.1875(4) 13_455
Ge1 La1 3.2146(5) 1_455
Ge1 La2 3.3519(5) 1_455
Ge2 Ge2 2.5146(11) 2_565
Ge2 Li1 2.606(10) .
Ge2 La2 3.1877(4) 1_455
Ge2 La4 3.2059(5) 13
Ge2 La4 3.2059(5) 13_455
Ge2 La5 3.3582(5) 13_455
Ge2 La5 3.3582(5) 13
Ge3 Li1 2.682(5) .
Ge3 Li1 2.682(5) 2
Ge3 Li1 2.682(5) 1_655
Ge3 Li1 2.682(5) 2_655
Ge3 Li1 2.800(10) 13
Ge3 Li1 2.800(10) 14_545
Ge3 La4 3.2214(6) 1_655
Ge4 Li3 2.709(5) 14_445
Ge4 Li3 2.709(5) 13
Ge4 Li3 2.709(5) 13_455
Ge4 Li3 2.709(5) 14_545
Ge4 Li2 2.770(9) .
Ge4 Li2 2.770(9) 2
Ge4 La1 3.1889(6) 1_455
Ge5 Li2 2.673(5) 14_445
Ge5 Li2 2.673(5) 13
Ge5 Li2 2.673(5) 13_455
Ge5 Li2 2.673(5) 14_545
Ge5 Li3 2.808(10) 2
Ge5 Li3 2.809(10) .
Ge5 La3 3.2583(6) 1_455
Ge6 Ge6 2.5403(15) 9_556
Ge6 Li3 2.686(9) .
Ge6 Li3 2.686(9) 10_556
Ge6 La6 3.1741(5) 5
Ge6 La6 3.1741(5) 5_455
Ge6 La3 3.2639(4) 1_455
Ge6 La3 3.2639(4) 9_656
Ge6 La3 3.2639(4) 9_556
Li1 Li1 2.622(18) 2
Li1 Ge3 2.682(5) 1_455
Li1 Ge3 2.800(10) 13
Li1 La4 3.192(6) 13
Li1 La4 3.192(6) 13_455
Li1 Li1 3.375(15) 13
Li1 Li1 3.375(15) 13_455
Li1 La2 3.692(8) 1_455
Li2 Li2 2.613(17) 2_565
Li2 Ge5 2.673(5) 13
Li2 Ge5 2.673(5) 13_455
Li2 La3 3.193(10) 13
Li2 La1 3.196(6) 1_455
Li2 Li3 3.379(11) 13_455
Li2 Li3 3.379(11) 13
Li2 La5 3.699(8) 13
Li2 La5 3.699(8) 13_455
Li3 Li3 2.668(19) 2_565
Li3 Ge4 2.709(5) 13
Li3 Ge4 2.709(5) 13_455
Li3 La3 3.178(7) 1_455
Li3 La1 3.202(9) 13
Li3 Li2 3.379(11) 13_455
Li3 Li2 3.379(11) 13
Li3 La6 3.649(7) 5
Li3 La6 3.649(7) 5_455
