#------------------------------------------------------------------------------
#$Date: 2021-05-31 11:41:46 +0300 (Mon, 31 May 2021) $
#$Revision: 265630 $
#$URL: file:///home/coder/svn-repositories/cod/cif/1/56/30/1563003.cif $
#------------------------------------------------------------------------------
#
# This file is available in the Crystallography Open Database (COD),
# http://www.crystallography.net/
#
# All data on this site have been placed in the public domain by the
# contributors.
#
data_1563003
loop_
_publ_author_name
'Tang, Qun'
'Liu, Shu-Xia'
'Liang, Da-Dong'
'Ma, Feng-Ji'
'Ren, Guo-Jian'
'Wei, Feng'
'Yang, Yuan'
'Li, Cong-Cong'
_publ_section_title
;
 Lanthanide-organic complexes based on polyoxometalates: Solvent effect on
 the luminescence properties
;
_journal_name_full               'Journal of Solid State Chemistry'
_journal_page_first              85
_journal_page_last               91
_journal_paper_doi               10.1016/j.jssc.2012.02.006
_journal_volume                  190
_journal_year                    2012
_chemical_formula_moiety         'C52 H68 Eu2 N16 O32, O19 W6'
_chemical_formula_sum            'C52 H68 Eu2 N16 O51 W6'
_chemical_formula_weight         3140.20
_space_group_IT_number           2
_space_group_name_Hall           '-P 1'
_space_group_name_H-M_alt        'P -1'
_symmetry_cell_setting           triclinic
_symmetry_space_group_name_H-M   'P -1'
_atom_sites_solution_hydrogens   geom
_atom_sites_solution_primary     direct
_atom_sites_solution_secondary   difmap
_audit_creation_method           SHELXL-97
_cell_angle_alpha                109.352(12)
_cell_angle_beta                 110.565(14)
_cell_angle_gamma                98.394(11)
_cell_formula_units_Z            1
_cell_length_a                   12.865(2)
_cell_length_b                   13.2016(18)
_cell_length_c                   15.054(3)
_cell_measurement_temperature    293(2)
_cell_measurement_theta_max      25.1
_cell_measurement_theta_min      2.92
_cell_volume                     2156.6(7)
_computing_cell_refinement       'Bruker FRAMBO'
_computing_data_collection       'Bruker FRAMBO'
_computing_data_reduction        'Bruker SAINT'
_computing_molecular_graphics    'Bruker SHELXTL'
_computing_publication_material  'Bruker SHELXTL'
_computing_structure_refinement  'SHELXL-97 (Sheldrick, 1997)'
_computing_structure_solution    'SHELXS-97 (Sheldrick, 1990)'
_diffrn_ambient_temperature      293(2)
_diffrn_detector_area_resol_mean '100x100 microns'
_diffrn_measured_fraction_theta_full 0.990
_diffrn_measured_fraction_theta_max 0.990
_diffrn_measurement_device_type  'multiwire proportional'
_diffrn_measurement_method       'phi and omega scans'
_diffrn_radiation_monochromator  graphite
_diffrn_radiation_source         'fine-focus sealed tube'
_diffrn_radiation_type           MoK\a
_diffrn_radiation_wavelength     0.71073
_diffrn_reflns_av_R_equivalents  0.0593
_diffrn_reflns_av_sigmaI/netI    0.1710
_diffrn_reflns_limit_h_max       15
_diffrn_reflns_limit_h_min       -15
_diffrn_reflns_limit_k_max       15
_diffrn_reflns_limit_k_min       -14
_diffrn_reflns_limit_l_max       14
_diffrn_reflns_limit_l_min       -17
_diffrn_reflns_number            13499
_diffrn_reflns_theta_full        25.10
_diffrn_reflns_theta_max         25.10
_diffrn_reflns_theta_min         2.92
_exptl_absorpt_coefficient_mu    9.506
_exptl_absorpt_correction_T_max  0.219
_exptl_absorpt_correction_T_min  0.072
_exptl_absorpt_correction_type   multi-scan
_exptl_crystal_colour            'pale yellow'
_exptl_crystal_density_diffrn    2.418
_exptl_crystal_density_meas      2.418
_exptl_crystal_density_method    'not measured'
_exptl_crystal_description       block
_exptl_crystal_F_000             1470
_exptl_crystal_size_max          0.30
_exptl_crystal_size_mid          0.27
_exptl_crystal_size_min          0.16
_refine_diff_density_max         2.340
_refine_diff_density_min         -3.359
_refine_diff_density_rms         0.197
_refine_ls_extinction_method     none
_refine_ls_goodness_of_fit_ref   1.034
_refine_ls_hydrogen_treatment    none
_refine_ls_matrix_type           full
_refine_ls_number_parameters     582
_refine_ls_number_reflns         7605
_refine_ls_number_restraints     0
_refine_ls_restrained_S_all      1.034
_refine_ls_R_factor_all          0.1655
_refine_ls_R_factor_gt           0.0702
_refine_ls_shift/su_max          0.001
_refine_ls_shift/su_mean         0.000
_refine_ls_structure_factor_coef Fsqd
_refine_ls_weighting_details
'calc w=1/[σ²(Fo²)+(0.0531P)²+0.0000P] where P=(Fo²+2Fc²)/3'
_refine_ls_weighting_scheme      calc
_refine_ls_wR_factor_gt          0.1415
_refine_ls_wR_factor_ref         0.1557
_reflns_number_gt                3106
_reflns_number_total             7682
_reflns_threshold_expression     >2sigma(I)
_cod_data_source_file            JSSC-2012-190-85.cif
_cod_data_source_block           compound-4
_cod_depositor_comments
;
The following automatic conversions were performed:

data item '_symmetry_cell_setting' value 'Triclinic' was changed to
'triclinic' in accordance with the built-in table derived from the
CIF Core dictionary named 'cif_core.dic' version 2.4.5 last updated
on 2014-11-21.

Automatic conversion script
Id: cif_fix_values 8369 2020-08-20 11:38:08Z andrius 
;
_cod_database_code               1563003
loop_
_symmetry_equiv_pos_as_xyz
'x, y, z'
'-x, -y, -z'
loop_
_atom_site_label
_atom_site_type_symbol
_atom_site_fract_x
_atom_site_fract_y
_atom_site_fract_z
_atom_site_U_iso_or_equiv
_atom_site_adp_type
_atom_site_occupancy
_atom_site_symmetry_multiplicity
_atom_site_calc_flag
_atom_site_refinement_flags
_atom_site_disorder_assembly
_atom_site_disorder_group
C1 C 0.2150(14) 0.509(2) 0.0845(13) 0.067(6) Uani 1 1 d . . .
C2 C 0.3377(14) 0.5033(17) 0.1065(12) 0.048(5) Uani 1 1 d . . .
C3 C 0.4252(14) 0.6068(18) 0.1607(12) 0.055(5) Uani 1 1 d . . .
H3 H 0.4097 0.6748 0.1845 0.066 Uiso 1 1 calc R . .
C4 C 0.3624(18) 0.4063(16) 0.0705(12) 0.065(5) Uani 1 1 d . . .
H4 H 0.3033 0.3384 0.0340 0.078 Uiso 1 1 calc R . .
C5 C 0.5615(19) 0.509(3) 0.1372(17) 0.080(7) Uani 1 1 d . . .
H5 H 0.6360 0.5104 0.1423 0.096 Uiso 1 1 calc R . .
C6 C 0.5377(17) 0.600(2) 0.1766(15) 0.069(6) Uani 1 1 d . . .
C7 C -0.0800(16) 0.4991(19) 0.2385(12) 0.055(5) Uani 1 1 d . . .
C8 C -0.0500(17) 0.502(2) 0.1523(15) 0.070(6) Uani 1 1 d . . .
C9 C -0.1251(17) 0.399(2) 0.2341(14) 0.069(6) Uani 1 1 d . . .
H9 H -0.1388 0.3339 0.1770 0.083 Uiso 1 1 calc R . .
C10 C -0.0598(13) 0.5940(15) 0.3226(12) 0.052(5) Uani 1 1 d . . .
H10 H -0.0280 0.6643 0.3268 0.062 Uiso 1 1 calc R . .
C11 C -0.0861(15) 0.5855(17) 0.3998(12) 0.056(5) Uani 1 1 d . . .
C12 C -0.1301(16) 0.484(2) 0.3977(16) 0.069(6) Uani 1 1 d . . .
H12 H -0.1452 0.4801 0.4526 0.083 Uiso 1 1 calc R . .
C13 C 0.474(2) 0.408(2) 0.0876(15) 0.076(7) Uani 1 1 d . . .
C14 C -0.1519(16) 0.389(2) 0.3134(18) 0.071(6) Uani 1 1 d . . .
C15 C 0.228(3) 0.7936(17) 0.3251(16) 0.106(9) Uani 1 1 d . . .
H15 H 0.2221 0.7188 0.3133 0.127 Uiso 1 1 calc R . .
C16 C -0.061(2) 0.854(2) 0.208(2) 0.111(9) Uani 1 1 d . . .
H16 H -0.0239 0.8279 0.2570 0.133 Uiso 1 1 calc R . .
C17 C -0.074(3) 0.803(2) -0.087(2) 0.162(15) Uani 1 1 d . . .
H17 H -0.1418 0.7651 -0.0885 0.195 Uiso 1 1 calc R . .
C18 C -0.189(4) 0.904(4) -0.140(5) 0.33(3) Uani 1 1 d . . .
H18A H -0.2436 0.8602 -0.1266 0.488 Uiso 1 1 calc R . .
H18B H -0.2292 0.9096 -0.2045 0.488 Uiso 1 1 calc R . .
H18C H -0.1529 0.9774 -0.0844 0.488 Uiso 1 1 calc R . .
C19 C -0.076(5) 0.849(3) -0.224(3) 0.31(3) Uani 1 1 d . . .
H19A H -0.0479 0.7852 -0.2436 0.461 Uiso 1 1 calc R . .
H19B H -0.0158 0.9166 -0.2002 0.461 Uiso 1 1 calc R . .
H19C H -0.1425 0.8426 -0.2823 0.461 Uiso 1 1 calc R . .
C20 C 0.294(4) 0.861(2) 0.104(3) 0.125(14) Uani 1 1 d . . .
H20 H 0.3391 0.8147 0.1208 0.150 Uiso 1 1 calc R . .
C21 C 0.380(4) 0.962(3) 0.039(3) 0.207(19) Uani 1 1 d . . .
H21A H 0.3771 0.8970 -0.0160 0.310 Uiso 1 1 calc R . .
H21B H 0.4486 1.0216 0.0630 0.310 Uiso 1 1 calc R . .
H21C H 0.3123 0.9857 0.0132 0.310 Uiso 1 1 calc R . .
C22 C 0.485(4) 0.987(3) 0.206(4) 0.38(5) Uani 1 1 d . . .
H22A H 0.4759 1.0463 0.2583 0.568 Uiso 1 1 calc R . .
H22B H 0.5437 1.0179 0.1893 0.568 Uiso 1 1 calc R . .
H22C H 0.5069 0.9328 0.2325 0.568 Uiso 1 1 calc R . .
C23 C 0.319(4) 0.845(3) 0.5082(17) 0.23(2) Uani 1 1 d . . .
H23A H 0.4018 0.8731 0.5460 0.352 Uiso 1 1 calc R . .
H23B H 0.2940 0.7652 0.4858 0.352 Uiso 1 1 calc R . .
H23C H 0.2838 0.8798 0.5525 0.352 Uiso 1 1 calc R . .
C24 C -0.112(3) 0.963(2) 0.341(3) 0.21(2) Uani 1 1 d . . .
H24A H -0.0353 0.9867 0.3957 0.319 Uiso 1 1 calc R . .
H24B H -0.1610 0.9041 0.3462 0.319 Uiso 1 1 calc R . .
H24C H -0.1438 1.0250 0.3482 0.319 Uiso 1 1 calc R . .
C25 C -0.180(5) 0.965(5) 0.190(4) 0.29(3) Uani 1 1 d . . .
H25A H -0.1358 1.0334 0.1953 0.436 Uiso 1 1 calc R . .
H25B H -0.2379 0.9800 0.2152 0.436 Uiso 1 1 calc R . .
H25C H -0.2174 0.9111 0.1190 0.436 Uiso 1 1 calc R . .
C26 C 0.255(3) 0.977(3) 0.447(2) 0.27(3) Uani 1 1 d . . .
H26A H 0.1910 0.9700 0.3857 0.400 Uiso 1 1 calc R . .
H26B H 0.3205 1.0374 0.4651 0.400 Uiso 1 1 calc R . .
H26C H 0.2324 0.9930 0.5036 0.400 Uiso 1 1 calc R . .
Eu1 Eu 0.05673(8) 0.69016(8) 0.07176(6) 0.0525(3) Uani 1 1 d . . .
N1 N -0.0649(15) 0.686(2) 0.4912(13) 0.086(6) Uani 1 1 d . . .
N2 N 0.634(2) 0.709(2) 0.234(2) 0.122(8) Uani 1 1 d . . .
N3 N -0.204(2) 0.279(3) 0.306(3) 0.118(8) Uani 1 1 d . . .
N4 N 0.505(3) 0.307(2) 0.0478(18) 0.123(10) Uani 1 1 d . . .
N5 N 0.2864(17) 0.8694(17) 0.4266(13) 0.098(6) Uani 1 1 d . . .
N6 N -0.109(2) 0.9235(17) 0.2487(17) 0.103(7) Uani 1 1 d . . .
N7 N -0.1054(16) 0.8514(15) -0.1474(13) 0.084(5) Uani 1 1 d . . .
N8 N 0.3805(15) 0.9357(16) 0.1178(12) 0.069(5) Uani 1 1 d . . .
O1 O 0.1994(10) 0.6004(13) 0.1220(10) 0.082(4) Uani 1 1 d . . .
O2 O -0.0033(14) 0.6005(16) 0.1639(10) 0.095(5) Uani 1 1 d . . .
O3 O -0.1363(11) 0.5887(12) -0.0351(9) 0.068(4) Uani 1 1 d . . .
O4 O 0.0647(10) 0.5810(13) -0.0796(9) 0.098(5) Uani 1 1 d . . .
O5 O 0.4179(14) 0.6137(12) 0.3903(9) 0.099(5) Uani 1 1 d . . .
O6 O 0.5000 0.5000 0.5000 0.056(4) Uani 1 2 d S . .
O7 O 0.6288(12) 0.6041(13) 0.7020(9) 0.102(5) Uani 1 1 d . . .
O8 O -0.0456(17) 0.7766(17) 0.4794(13) 0.137(8) Uani 1 1 d . . .
O9 O 0.5982(17) 0.7985(19) 0.2535(17) 0.159(8) Uani 1 1 d . . .
O10 O -0.0623(13) 0.6841(16) 0.5702(11) 0.124(7) Uani 1 1 d . . .
O11 O 0.8173(15) 0.524(2) 0.6923(13) 0.183(10) Uani 1 1 d . . .
O12 O -0.1927(19) 0.275(2) 0.389(2) 0.152(9) Uani 1 1 d . . .
O13 O -0.238(2) 0.1988(18) 0.223(2) 0.170(10) Uani 1 1 d . . .
O14 O 0.5960(18) 0.305(2) 0.0494(15) 0.171(11) Uani 1 1 d . . .
O15 O -0.0459(15) 0.8134(13) 0.1410(14) 0.123(7) Uani 1 1 d . . .
O16 O 0.430(3) 0.218(2) 0.0040(19) 0.168(11) Uani 1 1 d . . .
O17 O 0.186(2) 0.8100(16) 0.2533(11) 0.170(10) Uani 1 1 d . . .
O18 O 0.7254(18) 0.708(2) 0.241(2) 0.215(13) Uani 1 1 d . . .
O19 O 0.542(3) 0.302(3) 0.2586(14) 0.275(18) Uani 1 1 d . . .
O20 O 0.7047(12) 0.6310(18) 0.5728(13) 0.153(8) Uani 1 1 d . . .
O21 O -0.0048(15) 0.7850(16) -0.0360(15) 0.131(7) Uani 1 1 d . . .
O22 O 0.2259(14) 0.8117(18) 0.091(2) 0.145(10) Uani 1 1 d . . .
O23 O 0.6666(14) 0.4176(17) 0.4783(10) 0.135(7) Uani 1 1 d . . .
O24 O 0.626(2) 0.762(2) 0.459(2) 0.248(14) Uani 1 1 d . . .
O25 O 0.5698(11) 0.502(2) 0.3702(9) 0.155(10) Uani 1 1 d . . .
O26 O 0.5308(14) 0.7112(14) 0.5982(9) 0.123(6) Uani 1 1 d . . .
W1 W 0.68354(7) 0.51068(11) 0.61170(7) 0.0943(4) Uani 1 1 d . . .
W2 W 0.52271(13) 0.38184(14) 0.36002(8) 0.1159(6) Uani 1 1 d . . .
W3 W 0.57540(10) 0.65045(12) 0.47540(9) 0.1207(5) Uani 1 1 d . . .
loop_
_atom_type_symbol
_atom_type_description
_atom_type_scat_dispersion_real
_atom_type_scat_dispersion_imag
_atom_type_scat_source
C C 0.0033 0.0016 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
H H 0.0000 0.0000 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
N N 0.0061 0.0033 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
O O 0.0106 0.0060 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
Eu Eu -0.1578 3.6682 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
W W -0.8490 6.8722 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
loop_
_geom_angle_atom_site_label_1
_geom_angle_atom_site_label_2
_geom_angle_atom_site_label_3
_geom_angle
_geom_angle_site_symmetry_1
_geom_angle_site_symmetry_3
O1 C1 O3 126.1(15) . 2_565
O1 C1 C2 119(2) . .
O3 C1 C2 114(2) 2_565 .
C4 C2 C3 120.9(15) . .
C4 C2 C1 123(2) . .
C3 C2 C1 116.2(17) . .
C2 C3 C6 115.4(18) . .
C2 C4 C13 120(2) . .
C6 C5 C13 119(2) . .
C5 C6 C3 124(2) . .
C5 C6 N2 118(2) . .
C3 C6 N2 117(2) . .
C9 C7 C10 119.3(16) . .
C9 C7 C8 117.9(19) . .
C10 C7 C8 123(2) . .
O4 C8 O2 122.4(19) 2_565 .
O4 C8 C7 123(2) 2_565 .
O2 C8 C7 114.3(19) . .
C7 C9 C14 121.2(18) . .
C11 C10 C7 119.8(18) . .
C10 C11 C12 121.9(16) . .
C10 C11 N1 121(2) . .
C12 C11 N1 117(2) . .
C11 C12 C14 118.6(19) . .
C4 C13 C5 120.4(19) . .
C4 C13 N4 122(3) . .
C5 C13 N4 117(3) . .
C9 C14 C12 119(2) . .
C9 C14 N3 120(2) . .
C12 C14 N3 121(3) . .
O17 C15 N5 128(2) . .
O15 C16 N6 146(3) . .
O21 C17 N7 148(4) . .
O22 C20 N8 173(5) . .
O4 Eu1 O3 77.8(4) . .
O4 Eu1 O2 118.5(6) . .
O3 Eu1 O2 74.5(5) . .
O4 Eu1 O21 77.0(6) . .
O3 Eu1 O21 76.4(5) . .
O2 Eu1 O21 142.5(5) . .
O4 Eu1 O1 74.2(5) . .
O3 Eu1 O1 121.5(5) . .
O2 Eu1 O1 75.7(5) . .
O21 Eu1 O1 140.9(5) . .
O4 Eu1 O22 82.0(7) . .
O3 Eu1 O22 146.1(8) . .
O2 Eu1 O22 139.4(8) . .
O21 Eu1 O22 72.7(8) . .
O1 Eu1 O22 77.6(7) . .
O4 Eu1 O15 143.6(5) . .
O3 Eu1 O15 77.2(5) . .
O2 Eu1 O15 79.1(5) . .
O21 Eu1 O15 71.8(6) . .
O1 Eu1 O15 142.0(5) . .
O22 Eu1 O15 105.4(6) . .
O4 Eu1 O17 139.7(6) . .
O3 Eu1 O17 141.1(7) . .
O2 Eu1 O17 76.1(7) . .
O21 Eu1 O17 115.5(7) . .
O1 Eu1 O17 74.0(6) . .
O22 Eu1 O17 67.5(9) . .
O15 Eu1 O17 72.7(7) . .
O10 N1 O8 122(2) . .
O10 N1 C11 124(2) . .
O8 N1 C11 113.5(18) . .
O18 N2 O9 125(3) . .
O18 N2 C6 119(3) . .
O9 N2 C6 114(2) . .
O12 N3 O13 126(3) . .
O12 N3 C14 115(3) . .
O13 N3 C14 118(3) . .
O14 N4 O16 117(3) . .
O14 N4 C13 125(3) . .
O16 N4 C13 118(3) . .
C23 N5 C15 126(2) . .
C23 N5 C26 113(2) . .
C15 N5 C26 113(2) . .
C16 N6 C25 120(3) . .
C16 N6 C24 134(3) . .
C25 N6 C24 106(3) . .
C17 N7 C19 127(3) . .
C17 N7 C18 117(3) . .
C19 N7 C18 116(3) . .
C20 N8 C21 120(3) . .
C20 N8 C22 126(4) . .
C21 N8 C22 114(4) . .
C1 O1 Eu1 136.8(11) . .
C8 O2 Eu1 139.8(12) . .
C1 O3 Eu1 147.5(12) 2_565 .
C8 O4 Eu1 158.6(17) 2_565 .
W3 O5 W1 116.4(6) . 2_666
W3 O6 W2 89.42(6) 2_666 2_666
W3 O6 W2 90.58(6) 2_666 .
W2 O6 W2 180.0 2_666 .
W3 O6 W1 88.79(4) 2_666 .
W2 O6 W1 90.01(4) 2_666 .
W2 O6 W1 89.99(4) . .
W3 O6 W1 91.21(4) 2_666 2_666
W2 O6 W1 89.99(4) 2_666 2_666
W2 O6 W1 90.01(4) . 2_666
W1 O6 W1 180.0 . 2_666
W2 O7 W1 117.6(6) 2_666 .
C16 O15 Eu1 145(2) . .
C15 O17 Eu1 134.1(19) . .
W1 O20 W3 120.2(8) . .
C17 O21 Eu1 149(2) . .
C20 O22 Eu1 176(4) . .
W1 O23 W2 118.4(6) . .
W2 O25 W3 127.6(10) . .
W2 O26 W3 118.7(8) 2_666 .
O11 W1 O20 103.7(10) . .
O11 W1 O23 104.6(8) . .
O20 W1 O23 86.3(8) . .
O11 W1 O5 106.0(9) . 2_666
O20 W1 O5 150.1(6) . 2_666
O23 W1 O5 89.3(7) . 2_666
O11 W1 O7 103.4(8) . .
O20 W1 O7 84.7(8) . .
O23 W1 O7 151.9(5) . .
O5 W1 O7 85.5(6) 2_666 .
O11 W1 O6 177.7(9) . .
O20 W1 O6 74.0(4) . .
O23 W1 O6 76.0(4) . .
O5 W1 O6 76.3(4) 2_666 .
O7 W1 O6 76.0(3) . .
O11 W1 W3 137.1(8) . 2_666
O20 W1 W3 119.1(4) . 2_666
O23 W1 W3 81.4(6) . 2_666
O5 W1 W3 31.2(4) 2_666 2_666
O7 W1 W3 79.9(5) . 2_666
O6 W1 W3 45.11(3) . 2_666
O25 W2 O19 102.1(12) . .
O25 W2 O26 152.9(6) . 2_666
O19 W2 O26 104.8(12) . 2_666
O25 W2 O7 86.4(6) . 2_666
O19 W2 O7 103.8(9) . 2_666
O26 W2 O7 90.4(7) 2_666 2_666
O25 W2 O23 85.4(7) . .
O19 W2 O23 104.2(9) . .
O26 W2 O23 84.9(7) 2_666 .
O7 W2 O23 151.9(5) 2_666 .
O25 W2 O6 75.0(4) . .
O19 W2 O6 177.1(12) . .
O26 W2 O6 78.1(4) 2_666 .
O7 W2 O6 76.4(4) 2_666 .
O23 W2 O6 75.6(4) . .
O24 W3 O5 100.0(8) . .
O24 W3 O20 107.0(9) . .
O5 W3 O20 153.0(7) . .
O24 W3 O26 105.5(13) . .
O5 W3 O26 85.6(6) . .
O20 W3 O26 85.4(7) . .
O24 W3 O25 114.0(13) . .
O5 W3 O25 85.6(5) . .
O20 W3 O25 85.3(7) . .
O26 W3 O25 140.4(8) . .
O24 W3 W1 132.4(8) . 2_666
O5 W3 W1 32.4(4) . 2_666
O20 W3 W1 120.5(5) . 2_666
O26 W3 W1 76.6(5) . 2_666
O25 W3 W1 75.4(5) . 2_666
loop_
_geom_bond_atom_site_label_1
_geom_bond_atom_site_label_2
_geom_bond_distance
_geom_bond_site_symmetry_2
C1 O1 1.23(2) .
C1 O3 1.30(2) 2_565
C1 C2 1.51(2) .
C2 C4 1.35(2) .
C2 C3 1.40(2) .
C3 C6 1.40(2) .
C4 C13 1.37(3) .
C5 C6 1.30(3) .
C5 C13 1.38(3) .
C6 N2 1.49(3) .
C7 C9 1.34(3) .
C7 C10 1.36(2) .
C7 C8 1.49(2) .
C8 O4 1.19(2) 2_565
C8 O2 1.28(2) .
C9 C14 1.39(3) .
C10 C11 1.35(2) .
C11 C12 1.36(2) .
C11 N1 1.46(2) .
C12 C14 1.36(2) .
C13 N4 1.45(3) .
C14 N3 1.46(3) .
C15 O17 1.13(2) .
C15 N5 1.36(2) .
C16 O15 1.07(2) .
C16 N6 1.29(3) .
C17 O21 1.07(2) .
C17 N7 1.26(3) .
C18 N7 1.38(3) .
C19 N7 1.32(3) .
C20 O22 0.93(3) .
C20 N8 1.28(3) .
C21 N8 1.34(3) .
C22 N8 1.38(4) .
C23 N5 1.31(3) .
C24 N6 1.34(3) .
C25 N6 1.35(5) .
C26 N5 1.50(3) .
Eu1 O4 2.305(12) .
Eu1 O3 2.311(14) .
Eu1 O2 2.344(15) .
Eu1 O21 2.358(15) .
Eu1 O1 2.367(12) .
Eu1 O22 2.369(19) .
Eu1 O15 2.439(14) .
Eu1 O17 2.432(13) .
N1 O10 1.185(19) .
N1 O8 1.27(2) .
N2 O18 1.15(2) .
N2 O9 1.31(3) .
N3 O12 1.23(3) .
N3 O13 1.21(3) .
N4 O14 1.16(3) .
N4 O16 1.20(3) .
O3 C1 1.30(2) 2_565
O4 C8 1.19(2) 2_565
O5 W3 1.860(15) .
O5 W1 1.927(14) 2_666
O6 W3 2.2803(12) 2_666
O6 W2 2.3121(11) 2_666
O6 W2 2.3121(11) .
O6 W1 2.3193(9) .
O6 W1 2.3193(9) 2_666
O7 W2 1.910(13) 2_666
O7 W1 1.919(13) .
O11 W1 1.665(14) .
O19 W2 1.669(15) .
O20 W1 1.882(19) .
O20 W3 1.908(14) .
O23 W1 1.890(13) .
O23 W2 1.922(15) .
O24 W3 1.66(3) .
O25 W2 1.54(3) .
O25 W3 2.047(16) .
O26 W2 1.717(19) 2_666
O26 W3 2.071(14) .
W1 O5 1.927(14) 2_666
W1 W3 3.2179(17) 2_666
W2 O26 1.717(19) 2_666
W2 O7 1.910(13) 2_666
W3 W1 3.2179(17) 2_666
