#------------------------------------------------------------------------------
#$Date: 2021-06-05 04:22:50 +0300 (Sat, 05 Jun 2021) $
#$Revision: 265817 $
#$URL: file:///home/coder/svn-repositories/cod/cif/1/56/31/1563158.cif $
#------------------------------------------------------------------------------
#
# This file is available in the Crystallography Open Database (COD),
# http://www.crystallography.net/
#
# All data on this site have been placed in the public domain by the
# contributors.
#
data_1563158
loop_
_publ_author_name
'Tan, Jin-Fay'
'Bormann, Carl Thomas'
'Severin, Kay'
'Cramer, Nicolai'
_publ_section_title
;
 Alkynyl Triazenes Enable Divergent Syntheses of 2-Pyrones
;
_journal_name_full               'Chemical Science'
_journal_paper_doi               10.1039/D1SC02583J
_journal_year                    2021
_chemical_formula_moiety         'C17 H11 F O2'
_chemical_formula_sum            'C17 H11 F O2'
_chemical_formula_weight         266.26
_space_group_crystal_system      monoclinic
_space_group_IT_number           14
_space_group_name_Hall           '-P 2yn'
_space_group_name_H-M_alt        'P 1 21/n 1'
_atom_sites_solution_hydrogens   difmap
_atom_sites_solution_primary     dual
_atom_sites_solution_secondary   difmap
_audit_creation_date             2020-11-04
_audit_creation_method
;
Olex2 1.3
(compiled 2020.07.31 svn.rc2a77460 for OlexSys, GUI svn.r6145)
;
_audit_update_record
;
2021-04-06 deposited with the CCDC.	2021-06-04 downloaded from the CCDC.
;
_cell_angle_alpha                90
_cell_angle_beta                 97.117(2)
_cell_angle_gamma                90
_cell_formula_units_Z            4
_cell_length_a                   6.12164(16)
_cell_length_b                   18.5825(5)
_cell_length_c                   11.3690(2)
_cell_measurement_reflns_used    6150
_cell_measurement_temperature    140.00(10)
_cell_measurement_theta_max      76.5240
_cell_measurement_theta_min      4.5500
_cell_volume                     1283.32(5)
_computing_cell_refinement       'CrysAlisPro 1.171.40.84a (Rigaku OD, 2020)'
_computing_data_collection       'CrysAlisPro 1.171.40.84a (Rigaku OD, 2020)'
_computing_data_reduction        'CrysAlisPro 1.171.40.84a (Rigaku OD, 2020)'
_computing_molecular_graphics    'Olex2 1.3 (Dolomanov et al., 2009)'
_computing_publication_material  'Olex2 1.3 (Dolomanov et al., 2009)'
_computing_structure_refinement  'SHELXL 2018/3 (Sheldrick, 2015)'
_computing_structure_solution    'SHELXT (Sheldrick, 2015)'
_diffrn_ambient_environment      N~2~
_diffrn_ambient_temperature      140.00(10)
_diffrn_detector                 'CCD plate'
_diffrn_detector_area_resol_mean 10.2665
_diffrn_detector_type            Atlas
_diffrn_measured_fraction_theta_full 1.000
_diffrn_measured_fraction_theta_max 0.995
_diffrn_measurement_details
;
List of Runs (angles in degrees, time in seconds):

  # Type    Start    End  Width  tₑₓₚ   ω     θ     κ     φ   Frames
#--------------------------------------------------------------------------
  1  ω    -98.00 -49.00   1.00    1.50    --  -43.01-165.00 -21.00   49
  2  ω    -84.00 -37.00   1.00    1.50    --  -43.01 116.00-145.00   47
  3  ω    -95.00 -70.00   1.00    1.50    --  -43.01 165.00   2.00   25
  4  ω     33.00  58.00   1.00    1.50    --   43.01-116.00 126.00   25
  5  ω     92.00 124.00   1.00    1.50    --   43.01-165.00 -21.00   32
  6  ω     73.00  98.00   1.00    6.00    --  112.00-116.00 126.00   25
  7  ω     76.00 101.00   1.00    6.00    --  112.00-165.00 -21.00   25
  8  ω     89.00 114.00   1.00    6.00    --  112.00 165.00   2.00   25
  9  ω    104.00 139.00   1.00    6.00    --  112.00 116.00-145.00   35
 10  ω    -53.00 -19.00   1.00    1.50    --  -43.01 -37.00 -60.00   34
 11  ω   -115.00 -58.00   1.00    1.50    --  -43.01 -37.00 -60.00   57
 12  ω    -31.00  67.00   1.00    1.50    --   43.01 -37.00-180.00   98
 13  ω     16.00  60.00   1.00    1.50    --   43.01 -37.00 -30.00   44
 14  ω    -21.00   4.00   1.00    1.50    --   43.01 -37.00 -30.00   25
 15  ω     13.00  66.00   1.00    1.50    --   43.01 -99.00 150.00   53
 16  ω    137.00 163.00   1.00    6.00    --  112.00 111.00-180.00   26
 17  ω     36.00 109.00   1.00    6.00    --  112.00-111.00 150.00   73
 18  ω    153.00 178.00   1.00    6.00    --  112.00  61.00-180.00   25
 19  ω    109.00 175.00   1.00    6.00    --  112.00  77.00  60.00   66
 20  ω     62.00 101.00   1.00    6.00    --  112.00-111.00 -60.00   39
 21  ω     69.00 109.00   1.00    6.00    --  112.00-111.00-150.00   40
 22  ω     32.00  67.00   1.00    6.00    --  112.00 -94.00 120.00   35
 23  ω     63.00  96.00   1.00    6.00    --  112.00-111.00 -30.00   33
 24  ω    109.00 178.00   1.00    6.00    --  112.00 111.00 -90.00   69
 25  ω     30.00  64.00   1.00    6.00    --  112.00 -94.00 -30.00   34
 26  ω     98.00 174.00   1.00    6.00    --  112.00  45.00  30.00   76
 27  ω     59.00  85.00   1.00    6.00    --  112.00-111.00  60.00   26
 28  ω    104.00 171.00   1.00    6.00    --  112.00 111.00 120.00   67
 29  ω    107.00 177.00   1.00    6.00    --  112.00  45.00   0.00   70
 30  ω     39.00 106.00   1.00    6.00    --  112.00 -45.00 120.00   67
 31  ω     73.00  99.00   1.00    6.00    --  112.00-111.00-120.00   26
 32  ω    110.00 150.00   1.00    6.00    --  112.00  77.00 -90.00   40
 33  ω     46.00 109.00   1.00    6.00    --  112.00-111.00   0.00   63
 34  ω     37.00  62.00   1.00    6.00    --  112.00-111.00  90.00   25
 35  ω     65.00 106.00   1.00    6.00    --  112.00-111.00  90.00   41
 36  ω    103.00 128.00   1.00    6.00    --  112.00  61.00-180.00   25
 37  ω     82.00 107.00   1.00    6.00    --  112.00 -94.00 120.00   25
 38  ω     77.00 108.00   1.00    6.00    --  112.00-111.00  30.00   31
 39  ω     42.00 109.00   1.00    6.00    --  112.00-111.00 -90.00   67
 40  ω    125.00 165.00   1.00    6.00    --  112.00 111.00 150.00   40
 41  ω    106.00 152.00   1.00    6.00    --  112.00  77.00 120.00   46
;
_diffrn_measurement_device       'four-circle diffractometer'
_diffrn_measurement_device_type  'SuperNova, Dual, Cu at home/near, Atlas'
_diffrn_measurement_method       'ω scans'
_diffrn_orient_matrix_type
'CrysAlisPro convention (1999,Acta A55,543-557)'
_diffrn_orient_matrix_UB_11      -0.0145070000
_diffrn_orient_matrix_UB_12      -0.0808125000
_diffrn_orient_matrix_UB_13      0.0283651000
_diffrn_orient_matrix_UB_21      -0.2124182000
_diffrn_orient_matrix_UB_22      0.0136544000
_diffrn_orient_matrix_UB_23      0.0563713000
_diffrn_orient_matrix_UB_31      -0.1377147000
_diffrn_orient_matrix_UB_32      -0.0125896000
_diffrn_orient_matrix_UB_33      -0.1211002000
_diffrn_radiation_monochromator  mirror
_diffrn_radiation_probe          x-ray
_diffrn_radiation_type           'Cu K\a'
_diffrn_radiation_wavelength     1.54184
_diffrn_reflns_av_R_equivalents  0.0266
_diffrn_reflns_av_unetI/netI     0.0172
_diffrn_reflns_Laue_measured_fraction_full 1.000
_diffrn_reflns_Laue_measured_fraction_max 0.995
_diffrn_reflns_limit_h_max       7
_diffrn_reflns_limit_h_min       -7
_diffrn_reflns_limit_k_max       23
_diffrn_reflns_limit_k_min       -23
_diffrn_reflns_limit_l_max       10
_diffrn_reflns_limit_l_min       -14
_diffrn_reflns_number            14068
_diffrn_reflns_point_group_measured_fraction_full 1.000
_diffrn_reflns_point_group_measured_fraction_max 0.995
_diffrn_reflns_theta_full        67.684
_diffrn_reflns_theta_max         76.661
_diffrn_reflns_theta_min         4.585
_diffrn_source                   'micro-focus sealed X-ray tube'
_diffrn_source_type              'SuperNova (Cu) X-ray Source'
_exptl_absorpt_coefficient_mu    0.823
_exptl_absorpt_correction_T_max  1.000
_exptl_absorpt_correction_T_min  0.503
_exptl_absorpt_correction_type   gaussian
_exptl_absorpt_process_details
;
CrysAlisPro 1.171.40.84a (Rigaku Oxford Diffraction, 2020)
Numerical absorption correction based on gaussian integration over
a multifaceted crystal model.
Empirical absorption correction using spherical harmonics,
implemented in SCALE3 ABSPACK scaling algorithm.
;
_exptl_crystal_colour            'clear pale colourless'
_exptl_crystal_density_diffrn    1.378
_exptl_crystal_description       prism
_exptl_crystal_F_000             552
_exptl_crystal_size_max          0.609
_exptl_crystal_size_mid          0.105
_exptl_crystal_size_min          0.083
_refine_diff_density_max         0.221
_refine_diff_density_min         -0.173
_refine_diff_density_rms         0.034
_refine_ls_extinction_coef       0.0020(4)
_refine_ls_extinction_expression Fc^*^=kFc[1+0.001xFc²λ³/sin(2θ)]^-1/4^
_refine_ls_extinction_method     'SHELXL-2018/3 (Sheldrick 2018)'
_refine_ls_goodness_of_fit_ref   1.035
_refine_ls_hydrogen_treatment    refall
_refine_ls_matrix_type           full
_refine_ls_number_parameters     226
_refine_ls_number_reflns         2685
_refine_ls_number_restraints     0
_refine_ls_restrained_S_all      1.035
_refine_ls_R_factor_all          0.0369
_refine_ls_R_factor_gt           0.0328
_refine_ls_shift/su_max          0.001
_refine_ls_shift/su_mean         0.000
_refine_ls_structure_factor_coef Fsqd
_refine_ls_weighting_details
'w=1/[σ²(Fo²)+(0.0524P)²+0.1936P] where P=(Fo²+2Fc²)/3'
_refine_ls_weighting_scheme      calc
_refine_ls_wR_factor_gt          0.0881
_refine_ls_wR_factor_ref         0.0920
_reflns_Friedel_coverage         0.000
_reflns_number_gt                2402
_reflns_number_total             2685
_reflns_threshold_expression     'I > 2σ(I)'
_cod_data_source_file            d1sc02583j2.cif
_cod_data_source_block           jft-r263
_cod_original_cell_volume        1283.32(6)
_cod_database_code               1563158
_shelx_shelxl_version_number     2018/3
_chemical_oxdiff_formula         'C17 H11 O2 F1'
_shelx_space_group_comment
;
The symmetry employed for this shelxl refinement is uniquely defined
by the following loop, which should always be used as a source of
symmetry information in preference to the above space-group names.
They are only intended as comments.
;
_shelx_estimated_absorpt_t_max   0.935
_shelx_estimated_absorpt_t_min   0.634
_reflns_odcompleteness_completeness 99.93
_reflns_odcompleteness_iscentric 1
_reflns_odcompleteness_theta     74.33
_olex2_refinement_description
;
;
_olex2_submission_special_instructions 'No special instructions were received'
_oxdiff_exptl_absorpt_empirical_details
;
Empirical correction (ABSPACK) includes:
- Absorption correction using spherical harmonics
- Frame scaling
- Detector area scaling
- B-factor correction
;
_oxdiff_exptl_absorpt_empirical_full_max 2.092
_oxdiff_exptl_absorpt_empirical_full_min 0.679
loop_
_space_group_symop_operation_xyz
'x, y, z'
'-x+1/2, y+1/2, -z+1/2'
'-x, -y, -z'
'x-1/2, -y-1/2, z-1/2'
loop_
_atom_site_label
_atom_site_type_symbol
_atom_site_fract_x
_atom_site_fract_y
_atom_site_fract_z
_atom_site_U_iso_or_equiv
_atom_site_adp_type
_atom_site_occupancy
_atom_site_site_symmetry_order
_atom_site_calc_flag
_atom_site_refinement_flags_posn
_atom_site_refinement_flags_adp
_atom_site_refinement_flags_occupancy
_atom_site_disorder_assembly
_atom_site_disorder_group
F1 F 0.48244(15) 0.92757(4) 0.55558(7) 0.0491(2) Uani 1 1 d . . . . .
O1 O 0.62955(14) 0.83856(4) 0.66147(7) 0.0382(2) Uani 1 1 d . . . . .
O2 O 0.80297(14) 0.75240(5) 0.77076(7) 0.0431(2) Uani 1 1 d . . . . .
C1 C 0.4630(2) 0.85839(6) 0.58163(10) 0.0363(2) Uani 1 1 d . . . . .
C2 C 0.64235(18) 0.76687(6) 0.70285(9) 0.0332(2) Uani 1 1 d . . . . .
C3 C 0.46214(16) 0.71940(6) 0.65874(8) 0.0289(2) Uani 1 1 d . . . . .
C4 C 0.30168(16) 0.74254(6) 0.57188(8) 0.0282(2) Uani 1 1 d . . . . .
C5 C 0.30234(19) 0.81620(6) 0.53242(9) 0.0339(2) Uani 1 1 d . . . . .
H5 H 0.197(2) 0.8349(8) 0.4713(13) 0.039(4) Uiso 1 1 d . . . . .
C6 C 0.46717(16) 0.64785(6) 0.71713(8) 0.0293(2) Uani 1 1 d . . . . .
C7 C 0.64714(18) 0.60188(7) 0.71694(9) 0.0354(2) Uani 1 1 d . . . . .
H7 H 0.770(3) 0.6162(8) 0.6756(14) 0.046(4) Uiso 1 1 d . . . . .
C8 C 0.6516(2) 0.53631(7) 0.77589(10) 0.0413(3) Uani 1 1 d . . . . .
H8 H 0.778(3) 0.5043(9) 0.7770(15) 0.058(5) Uiso 1 1 d . . . . .
C9 C 0.4777(2) 0.51623(7) 0.83620(10) 0.0420(3) Uani 1 1 d . . . . .
H9 H 0.485(3) 0.4706(9) 0.8800(15) 0.051(4) Uiso 1 1 d . . . . .
C10 C 0.2980(2) 0.56168(7) 0.83641(10) 0.0399(3) Uani 1 1 d . . . . .
H10 H 0.173(3) 0.5475(9) 0.8771(15) 0.052(4) Uiso 1 1 d . . . . .
C11 C 0.29193(18) 0.62725(6) 0.77736(9) 0.0328(2) Uani 1 1 d . . . . .
H11 H 0.162(3) 0.6600(8) 0.7757(13) 0.041(4) Uiso 1 1 d . . . . .
C12 C 0.12709(16) 0.69502(6) 0.51209(8) 0.0278(2) Uani 1 1 d . . . . .
C13 C -0.08246(17) 0.72297(6) 0.47637(9) 0.0328(2) Uani 1 1 d . . . . .
H13 H -0.116(2) 0.7721(8) 0.4941(13) 0.036(3) Uiso 1 1 d . . . . .
C14 C -0.24538(19) 0.68061(8) 0.41438(10) 0.0410(3) Uani 1 1 d . . . . .
H14 H -0.387(3) 0.7013(10) 0.3887(16) 0.058(5) Uiso 1 1 d . . . . .
C15 C -0.2001(2) 0.61016(8) 0.38721(10) 0.0433(3) Uani 1 1 d . . . . .
H15 H -0.313(3) 0.5796(9) 0.3437(15) 0.054(4) Uiso 1 1 d . . . . .
C16 C 0.0079(2) 0.58183(7) 0.42074(10) 0.0385(3) Uani 1 1 d . . . . .
H16 H 0.042(3) 0.5322(9) 0.4009(14) 0.049(4) Uiso 1 1 d . . . . .
C17 C 0.17098(18) 0.62397(6) 0.48281(9) 0.0317(2) Uani 1 1 d . . . . .
H17 H 0.319(2) 0.6042(8) 0.5041(12) 0.036(3) Uiso 1 1 d . . . . .
loop_
_atom_type_symbol
_atom_type_description
_atom_type_scat_dispersion_real
_atom_type_scat_dispersion_imag
_atom_type_scat_source
C C 0.0181 0.0091 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
H H 0.0000 0.0000 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
F F 0.0727 0.0534 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
O O 0.0492 0.0322 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
loop_
_exptl_crystal_face_index_h
_exptl_crystal_face_index_k
_exptl_crystal_face_index_l
_exptl_crystal_face_perp_dist
0 1 2 0.0491
-2 1 0 0.3084
0 -10 -4 0.0610
0 9 5 0.0417
0 12 0 0.0415
0 -12 0 0.0415
0 0 -7 0.0557
0 0 7 0.0484
2 3 -6 0.1679
-3 -5 3 0.2659
-1 5 2 0.1530
0 -1 1 0.0441
0 1 -1 0.0498
3 -5 0 0.2423
loop_
_geom_angle_atom_site_label_1
_geom_angle_atom_site_label_2
_geom_angle_atom_site_label_3
_geom_angle
_geom_angle_site_symmetry_1
_geom_angle_site_symmetry_3
_geom_angle_publ_flag
C1 O1 C2 119.66(8) . . ?
F1 C1 O1 109.74(10) . . ?
C5 C1 F1 124.10(11) . . ?
C5 C1 O1 126.14(11) . . ?
O1 C2 C3 116.72(9) . . ?
O2 C2 O1 115.59(10) . . ?
O2 C2 C3 127.70(11) . . ?
C2 C3 C6 114.62(9) . . ?
C4 C3 C2 120.23(10) . . ?
C4 C3 C6 125.13(9) . . ?
C3 C4 C5 119.48(9) . . ?
C3 C4 C12 123.61(9) . . ?
C5 C4 C12 116.88(9) . . ?
C1 C5 C4 117.45(10) . . ?
C7 C6 C3 121.38(10) . . ?
C7 C6 C11 119.21(10) . . ?
C11 C6 C3 119.37(10) . . ?
C8 C7 C6 120.33(11) . . ?
C9 C8 C7 120.27(11) . . ?
C10 C9 C8 119.63(11) . . ?
C9 C10 C11 120.46(11) . . ?
C10 C11 C6 120.10(11) . . ?
C13 C12 C4 119.68(9) . . ?
C17 C12 C4 121.52(9) . . ?
C17 C12 C13 118.64(10) . . ?
C14 C13 C12 120.77(11) . . ?
C15 C14 C13 119.89(11) . . ?
C14 C15 C16 120.07(10) . . ?
C15 C16 C17 120.18(11) . . ?
C16 C17 C12 120.43(10) . . ?
loop_
_geom_bond_atom_site_label_1
_geom_bond_atom_site_label_2
_geom_bond_distance
_geom_bond_site_symmetry_2
_geom_bond_publ_flag
F1 C1 1.3280(13) . ?
O1 C1 1.3305(15) . ?
O1 C2 1.4119(14) . ?
O2 C2 1.2030(14) . ?
C1 C5 1.3259(16) . ?
C2 C3 1.4523(14) . ?
C3 C4 1.3728(14) . ?
C3 C6 1.4847(14) . ?
C4 C5 1.4407(14) . ?
C4 C12 1.4846(14) . ?
C6 C7 1.3944(15) . ?
C6 C11 1.3959(15) . ?
C7 C8 1.3892(17) . ?
C8 C9 1.387(2) . ?
C9 C10 1.3870(19) . ?
C10 C11 1.3894(16) . ?
C12 C13 1.3968(14) . ?
C12 C17 1.3959(15) . ?
C13 C14 1.3917(16) . ?
C14 C15 1.381(2) . ?
C15 C16 1.3872(18) . ?
C16 C17 1.3901(15) . ?
loop_
_geom_torsion_atom_site_label_1
_geom_torsion_atom_site_label_2
_geom_torsion_atom_site_label_3
_geom_torsion_atom_site_label_4
_geom_torsion
_geom_torsion_site_symmetry_1
_geom_torsion_site_symmetry_2
_geom_torsion_site_symmetry_3
_geom_torsion_site_symmetry_4
_geom_torsion_publ_flag
F1 C1 C5 C4 -178.81(10) . . . . ?
O1 C1 C5 C4 2.62(18) . . . . ?
O1 C2 C3 C4 6.55(14) . . . . ?
O1 C2 C3 C6 -171.92(8) . . . . ?
O2 C2 C3 C4 -173.27(11) . . . . ?
O2 C2 C3 C6 8.27(16) . . . . ?
C1 O1 C2 O2 176.73(10) . . . . ?
C1 O1 C2 C3 -3.10(14) . . . . ?
C2 O1 C1 F1 179.78(9) . . . . ?
C2 O1 C1 C5 -1.49(17) . . . . ?
C2 C3 C4 C5 -5.57(15) . . . . ?
C2 C3 C4 C12 172.59(9) . . . . ?
C2 C3 C6 C7 -58.04(13) . . . . ?
C2 C3 C6 C11 119.48(10) . . . . ?
C3 C4 C5 C1 1.06(15) . . . . ?
C3 C4 C12 C13 146.16(10) . . . . ?
C3 C4 C12 C17 -38.48(15) . . . . ?
C3 C6 C7 C8 177.63(10) . . . . ?
C3 C6 C11 C10 -177.48(9) . . . . ?
C4 C3 C6 C7 123.58(12) . . . . ?
C4 C3 C6 C11 -58.89(14) . . . . ?
C4 C12 C13 C14 176.44(10) . . . . ?
C4 C12 C17 C16 -176.26(10) . . . . ?
C5 C4 C12 C13 -35.64(14) . . . . ?
C5 C4 C12 C17 139.72(10) . . . . ?
C6 C3 C4 C5 172.72(9) . . . . ?
C6 C3 C4 C12 -9.12(16) . . . . ?
C6 C7 C8 C9 -0.47(17) . . . . ?
C7 C6 C11 C10 0.11(15) . . . . ?
C7 C8 C9 C10 0.63(18) . . . . ?
C8 C9 C10 C11 -0.43(18) . . . . ?
C9 C10 C11 C6 0.06(17) . . . . ?
C11 C6 C7 C8 0.10(16) . . . . ?
C12 C4 C5 C1 -177.22(10) . . . . ?
C12 C13 C14 C15 -0.26(17) . . . . ?
C13 C12 C17 C16 -0.86(15) . . . . ?
C13 C14 C15 C16 -0.54(18) . . . . ?
C14 C15 C16 C17 0.64(18) . . . . ?
C15 C16 C17 C12 0.08(17) . . . . ?
C17 C12 C13 C14 0.95(15) . . . . ?
loop_
_exptl_oxdiff_crystal_face_indexfrac_h
_exptl_oxdiff_crystal_face_indexfrac_k
_exptl_oxdiff_crystal_face_indexfrac_l
_exptl_oxdiff_crystal_face_x
_exptl_oxdiff_crystal_face_y
_exptl_oxdiff_crystal_face_z
0.0001 0.9995 1.9997 -0.0240 0.1264 -0.2548
-2.0002 1.0008 0.0015 -0.0518 0.4386 0.2627
0.2658 -10.0498 -4.0786 0.6926 -0.4236 0.5838
0.0916 9.1768 4.7262 -0.6089 0.3723 -0.7005
0.1252 12.0517 -0.1669 -0.9805 0.1286 -0.1488
-0.1252 -12.0517 0.1669 0.9805 -0.1286 0.1488
-0.0544 0.4355 -7.3051 -0.2416 -0.3943 0.8867
0.0399 -0.4545 7.3083 0.2435 0.3973 -0.8848
2.1579 3.2328 -6.3245 -0.4719 -0.7707 0.4280
-3.3865 -4.6208 3.3892 0.5187 0.8473 0.1141
-0.9995 5.0000 2.0002 -0.3328 0.3933 -0.1675
-0.0002 -1.0003 1.0000 0.1092 0.0428 -0.1085
0.0002 1.0003 -1.0000 -0.1092 -0.0428 0.1085
2.9998 -5.0013 -0.0020 0.3606 -0.7056 -0.3499
