#------------------------------------------------------------------------------
#$Date: 2021-06-16 10:59:23 +0300 (Wed, 16 Jun 2021) $
#$Revision: 266485 $
#$URL: file:///home/coder/svn-repositories/cod/cif/1/56/35/1563510.cif $
#------------------------------------------------------------------------------
#
# This file is available in the Crystallography Open Database (COD),
# http://www.crystallography.net/
#
# All data on this site have been placed in the public domain by the
# contributors.
#
data_1563510
loop_
_publ_author_name
'Menard, Melissa C.'
'Xiong, Yimin'
'Karki, Amar B.'
'Drake, Brenton L.'
'Adams, Philip W.'
'Fronczek, Frank R.'
'Young, David P.'
'Chan, Julia Y.'
_publ_section_title
;
 Crystal growth and properties of Ln2Ag1−xGa10−y (Ln=La,
 Ce), a disordered variant of the Ce2NiGa10-structure type
;
_journal_issue                   9
_journal_name_full               'Journal of Solid State Chemistry'
_journal_page_first              1935
_journal_page_last               1942
_journal_paper_doi               10.1016/j.jssc.2010.06.011
_journal_volume                  183
_journal_year                    2010
_chemical_formula_moiety         'Ag0.7 Ce2 Ga9.08'
_chemical_formula_sum            'Ag0.7 Ce2 Ga9.08'
_chemical_formula_weight         988.80
_space_group_IT_number           139
_space_group_name_Hall           '-I 4 2'
_space_group_name_H-M_alt        'I 4/m m m'
_symmetry_cell_setting           tetragonal
_symmetry_space_group_name_H-M   'I 4/m m m'
_atom_sites_solution_primary     direct
_atom_sites_solution_secondary   difmap
_audit_creation_method           SHELXL-97
_cell_angle_alpha                90.00
_cell_angle_beta                 90.00
_cell_angle_gamma                90.00
_cell_formula_units_Z            2
_cell_length_a                   4.2769(6)
_cell_length_b                   4.2769(6)
_cell_length_c                   26.0750(15)
_cell_measurement_reflns_used    4104
_cell_measurement_temperature    100(2)
_cell_measurement_theta_max      31.00
_cell_measurement_theta_min      1.00
_cell_volume                     476.96(10)
_computing_cell_refinement
'Denzo and Scalepack (Otowinowski& Minor1997)'
_computing_data_collection       'COLLECT (Nonius 1999)'
_computing_data_reduction
'Denzo and Scalepack (Otowinowski& Minor1997)'
_computing_molecular_graphics    'ORTEP-3 for Windows (Farrugia 1997)'
_computing_publication_material  'SHELXL-97 (Sheldrick 1997)'
_computing_structure_refinement  'SHELXL-97 (Sheldrick, 2008)'
_computing_structure_solution    'SHELXS-97 (Sheldrick, 1997)'
_diffrn_ambient_temperature      100(2)
_diffrn_measured_fraction_theta_full 0.993
_diffrn_measured_fraction_theta_max 0.993
_diffrn_measurement_device_type  'Nonius KappaCCD (with Oxford Cryostream)'
_diffrn_measurement_method       'ω and φ scans'
_diffrn_radiation_monochromator  graphite
_diffrn_radiation_source         'fine-focus sealed tube'
_diffrn_radiation_type           MoK\a
_diffrn_radiation_wavelength     0.71073
_diffrn_reflns_av_R_equivalents  0.0425
_diffrn_reflns_av_sigmaI/netI    0.0391
_diffrn_reflns_limit_h_max       6
_diffrn_reflns_limit_h_min       -6
_diffrn_reflns_limit_k_max       6
_diffrn_reflns_limit_k_min       -4
_diffrn_reflns_limit_l_max       37
_diffrn_reflns_limit_l_min       -37
_diffrn_reflns_number            768
_diffrn_reflns_theta_full        30.95
_diffrn_reflns_theta_max         30.95
_diffrn_reflns_theta_min         4.69
_diffrn_standards_number         0
_exptl_absorpt_coefficient_mu    35.871
_exptl_absorpt_correction_T_max  0.4125
_exptl_absorpt_correction_T_min  0.4125
_exptl_absorpt_correction_type   multi-scan
_exptl_absorpt_process_details   'HKL Scalepack (Otowinowski& Minor1997)'
_exptl_crystal_colour            silver
_exptl_crystal_density_diffrn    6.887
_exptl_crystal_density_method    'not measured'
_exptl_crystal_description       plate
_exptl_crystal_F_000             861
_exptl_crystal_size_max          0.03
_exptl_crystal_size_mid          0.03
_exptl_crystal_size_min          0.03
_refine_diff_density_max         2.108
_refine_diff_density_min         -1.334
_refine_diff_density_rms         0.338
_refine_ls_extinction_coef       0.0026(3)
_refine_ls_extinction_expression Fc^*^=kFc[1+0.001xFc²λ³/sin(2θ)]^-1/4^
_refine_ls_extinction_method     SHELXL
_refine_ls_goodness_of_fit_ref   1.154
_refine_ls_matrix_type           full
_refine_ls_number_parameters     20
_refine_ls_number_reflns         279
_refine_ls_number_restraints     0
_refine_ls_restrained_S_all      1.154
_refine_ls_R_factor_all          0.0321
_refine_ls_R_factor_gt           0.0279
_refine_ls_shift/su_max          0.000
_refine_ls_shift/su_mean         0.000
_refine_ls_structure_factor_coef Fsqd
_refine_ls_weighting_details
'calc w=1/[σ²(Fo²)+(0.0235P)²+8.9000P] where P=(Fo²+2Fc²)/3'
_refine_ls_weighting_scheme      calc
_refine_ls_wR_factor_gt          0.0677
_refine_ls_wR_factor_ref         0.0695
_reflns_number_gt                245
_reflns_number_total             279
_reflns_threshold_expression     I>2σ(I)
_cod_data_source_file            JSSC-2010-183-1935.cif
_cod_data_source_block           mm68
_cod_depositor_comments
;
The following automatic conversions were performed:

data item '_symmetry_cell_setting' value 'Tetragonal' was changed to
'tetragonal' in accordance with the built-in table derived from the
CIF Core dictionary named 'cif_core.dic' version 2.4.5 last updated
on 2014-11-21.

Automatic conversion script
Id: cif_fix_values 8369 2020-08-20 11:38:08Z andrius 
;
_cod_database_code               1563510
loop_
_symmetry_equiv_pos_as_xyz
'x, y, z'
'x, -y, -z'
'-x, -y, z'
'-x, y, -z'
'y, x, -z'
'y, -x, z'
'-y, x, z'
'-y, -x, -z'
'x+1/2, y+1/2, z+1/2'
'x+1/2, -y+1/2, -z+1/2'
'-x+1/2, -y+1/2, z+1/2'
'-x+1/2, y+1/2, -z+1/2'
'y+1/2, x+1/2, -z+1/2'
'y+1/2, -x+1/2, z+1/2'
'-y+1/2, x+1/2, z+1/2'
'-y+1/2, -x+1/2, -z+1/2'
'-x, -y, -z'
'-x, y, z'
'x, y, -z'
'x, -y, z'
'-y, -x, z'
'-y, x, -z'
'y, -x, -z'
'y, x, z'
'-x+1/2, -y+1/2, -z+1/2'
'-x+1/2, y+1/2, z+1/2'
'x+1/2, y+1/2, -z+1/2'
'x+1/2, -y+1/2, z+1/2'
'-y+1/2, -x+1/2, z+1/2'
'-y+1/2, x+1/2, -z+1/2'
'y+1/2, -x+1/2, -z+1/2'
'y+1/2, x+1/2, z+1/2'
loop_
_atom_site_label
_atom_site_type_symbol
_atom_site_fract_x
_atom_site_fract_y
_atom_site_fract_z
_atom_site_U_iso_or_equiv
_atom_site_adp_type
_atom_site_occupancy
_atom_site_symmetry_multiplicity
_atom_site_calc_flag
_atom_site_refinement_flags
_atom_site_disorder_assembly
_atom_site_disorder_group
Ce1 Ce 0.0000 0.0000 0.35253(2) 0.0053(3) Uani 1 8 d S . .
Ga3 Ga 0.0000 0.0000 0.09831(5) 0.0067(4) Uani 1 8 d S . .
Ga4 Ga 0.0000 0.0000 0.19312(5) 0.0065(3) Uani 1 8 d S . .
Ag1 Ag 0.0000 0.5000 0.2500 0.0064(3) Uani 0.35 8 d SP . .
Ga1 Ga 0.0000 0.5000 0.2500 0.0064(3) Uani 0.65 8 d SP . .
Ga5 Ga 0.0000 0.0000 0.5000 0.008(6) Uani 0.06 16 d SP . .
Ga2 Ga 0.0000 0.5000 0.9528(2) 0.0059(10) Uiso 0.19 4 d SP . .
Ga6 Ga 0.0000 0.3709(5) 0.45618(7) 0.0041(4) Uiso 0.37 2 d SP . .
loop_
_atom_type_symbol
_atom_type_description
_atom_type_scat_dispersion_real
_atom_type_scat_dispersion_imag
_atom_type_scat_source
Ce Ce -0.2486 2.6331 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
Ag Ag -0.8971 1.1015 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
Ga Ga 0.2307 1.6083 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
loop_
_geom_angle_atom_site_label_1
_geom_angle_atom_site_label_2
_geom_angle_atom_site_label_3
_geom_angle
_geom_angle_site_symmetry_1
_geom_angle_site_symmetry_3
Ga6 Ce1 Ga6 41.95(5) 6 .
Ga6 Ce1 Ga6 60.83(7) 6 21
Ga6 Ce1 Ga6 41.95(5) . 21
Ga6 Ce1 Ga6 41.95(5) 6 3
Ga6 Ce1 Ga6 60.83(7) . 3
Ga6 Ce1 Ga6 41.95(5) 21 3
Ga6 Ce1 Ga4 130.46(3) 6 25_445
Ga6 Ce1 Ga4 130.46(3) . 25_445
Ga6 Ce1 Ga4 89.01(3) 21 25_445
Ga6 Ce1 Ga4 89.01(3) 3 25_445
Ga6 Ce1 Ga4 89.01(3) 6 25
Ga6 Ce1 Ga4 89.01(3) . 25
Ga6 Ce1 Ga4 130.46(3) 21 25
Ga6 Ce1 Ga4 130.46(3) 3 25
Ga4 Ce1 Ga4 137.03(4) 25_445 25
Ga6 Ce1 Ga4 130.46(3) 6 25_455
Ga6 Ce1 Ga4 89.01(3) . 25_455
Ga6 Ce1 Ga4 89.01(3) 21 25_455
Ga6 Ce1 Ga4 130.46(3) 3 25_455
Ga4 Ce1 Ga4 82.290(15) 25_445 25_455
Ga4 Ce1 Ga4 82.290(15) 25 25_455
Ga6 Ce1 Ga4 89.01(3) 6 25_545
Ga6 Ce1 Ga4 130.46(3) . 25_545
Ga6 Ce1 Ga4 130.46(3) 21 25_545
Ga6 Ce1 Ga4 89.01(3) 3 25_545
Ga4 Ce1 Ga4 82.290(15) 25_445 25_545
Ga4 Ce1 Ga4 82.290(15) 25 25_545
Ga4 Ce1 Ga4 137.03(4) 25_455 25_545
Ga6 Ce1 Ga3 48.23(3) 6 25
Ga6 Ce1 Ga3 48.23(3) . 25
Ga6 Ce1 Ga3 89.60(4) 21 25
Ga6 Ce1 Ga3 89.60(4) 3 25
Ga4 Ce1 Ga3 178.51(3) 25_445 25
Ga4 Ce1 Ga3 44.46(3) 25 25
Ga4 Ce1 Ga3 98.218(11) 25_455 25
Ga4 Ce1 Ga3 98.218(11) 25_545 25
Ga6 Ce1 Ga3 89.60(4) 6 25_445
Ga6 Ce1 Ga3 89.60(4) . 25_445
Ga6 Ce1 Ga3 48.23(3) 21 25_445
Ga6 Ce1 Ga3 48.23(3) 3 25_445
Ga4 Ce1 Ga3 44.46(3) 25_445 25_445
Ga4 Ce1 Ga3 178.51(3) 25 25_445
Ga4 Ce1 Ga3 98.218(11) 25_455 25_445
Ga4 Ce1 Ga3 98.218(11) 25_545 25_445
Ga3 Ce1 Ga3 134.06(4) 25 25_445
Ga6 Ce1 Ga3 48.23(3) 6 25_545
Ga6 Ce1 Ga3 89.60(4) . 25_545
Ga6 Ce1 Ga3 89.60(4) 21 25_545
Ga6 Ce1 Ga3 48.23(3) 3 25_545
Ga4 Ce1 Ga3 98.218(11) 25_445 25_545
Ga4 Ce1 Ga3 98.218(11) 25 25_545
Ga4 Ce1 Ga3 178.51(3) 25_455 25_545
Ga4 Ce1 Ga3 44.46(3) 25_545 25_545
Ga3 Ce1 Ga3 81.240(15) 25 25_545
Ga3 Ce1 Ga3 81.240(15) 25_445 25_545
Ga6 Ce1 Ga3 89.60(4) 6 25_455
Ga6 Ce1 Ga3 48.23(3) . 25_455
Ga6 Ce1 Ga3 48.23(3) 21 25_455
Ga6 Ce1 Ga3 89.60(4) 3 25_455
Ga4 Ce1 Ga3 98.218(11) 25_445 25_455
Ga4 Ce1 Ga3 98.218(11) 25 25_455
Ga4 Ce1 Ga3 44.46(3) 25_455 25_455
Ga4 Ce1 Ga3 178.51(3) 25_545 25_455
Ga3 Ce1 Ga3 81.240(15) 25 25_455
Ga3 Ce1 Ga3 81.240(15) 25_445 25_455
Ga3 Ce1 Ga3 134.06(4) 25_545 25_455
Ga4 Ga3 Ga2 121.93(10) . 5_456
Ga4 Ga3 Ga2 121.93(10) . 17_556
Ga2 Ga3 Ga2 73.76(10) 5_456 17_556
Ga4 Ga3 Ga2 121.93(10) . 5_556
Ga2 Ga3 Ga2 116.1(2) 5_456 5_556
Ga2 Ga3 Ga2 73.76(10) 17_556 5_556
Ga4 Ga3 Ga2 121.93(10) . 17_566
Ga2 Ga3 Ga2 73.76(10) 5_456 17_566
Ga2 Ga3 Ga2 116.1(2) 17_556 17_566
Ga2 Ga3 Ga2 73.76(10) 5_556 17_566
Ga4 Ga3 Ga6 122.75(4) . 13_445
Ga2 Ga3 Ga6 62.32(6) 5_456 13_445
Ga2 Ga3 Ga6 12.25(5) 17_556 13_445
Ga2 Ga3 Ga6 83.82(6) 5_556 13_445
Ga2 Ga3 Ga6 113.89(10) 17_566 13_445
Ga4 Ga3 Ga6 122.75(4) . 27_445
Ga2 Ga3 Ga6 12.25(5) 5_456 27_445
Ga2 Ga3 Ga6 62.32(6) 17_556 27_445
Ga2 Ga3 Ga6 113.89(10) 5_556 27_445
Ga2 Ga3 Ga6 83.82(6) 17_566 27_445
Ga6 Ga3 Ga6 50.58(9) 13_445 27_445
Ga4 Ga3 Ga6 122.75(4) . 30_545
Ga2 Ga3 Ga6 83.82(6) 5_456 30_545
Ga2 Ga3 Ga6 12.25(5) 17_556 30_545
Ga2 Ga3 Ga6 62.32(6) 5_556 30_545
Ga2 Ga3 Ga6 113.89(10) 17_566 30_545
Ga6 Ga3 Ga6 24.27(9) 13_445 30_545
Ga6 Ga3 Ga6 72.98(4) 27_445 30_545
Ga4 Ga3 Ga6 122.75(4) . 25_455
Ga2 Ga3 Ga6 12.25(5) 5_456 25_455
Ga2 Ga3 Ga6 83.82(6) 17_556 25_455
Ga2 Ga3 Ga6 113.89(10) 5_556 25_455
Ga2 Ga3 Ga6 62.32(6) 17_566 25_455
Ga6 Ga3 Ga6 72.98(4) 13_445 25_455
Ga6 Ga3 Ga6 24.27(9) 27_445 25_455
Ga6 Ga3 Ga6 92.85(9) 30_545 25_455
Ga4 Ga3 Ga6 122.75(4) . 30
Ga2 Ga3 Ga6 83.82(6) 5_456 30
Ga2 Ga3 Ga6 113.89(10) 17_556 30
Ga2 Ga3 Ga6 62.32(6) 5_556 30
Ga2 Ga3 Ga6 12.25(5) 17_566 30
Ga6 Ga3 Ga6 114.50(8) 13_445 30
Ga6 Ga3 Ga6 92.85(9) 27_445 30
Ga6 Ga3 Ga6 109.04(7) 30_545 30
Ga6 Ga3 Ga6 72.98(4) 25_455 30
Ga4 Ga3 Ga6 122.75(4) . 25
Ga2 Ga3 Ga6 113.89(10) 5_456 25
Ga2 Ga3 Ga6 83.82(6) 17_556 25
Ga2 Ga3 Ga6 12.25(5) 5_556 25
Ga2 Ga3 Ga6 62.32(6) 17_566 25
Ga6 Ga3 Ga6 92.85(9) 13_445 25
Ga6 Ga3 Ga6 114.50(8) 27_445 25
Ga6 Ga3 Ga6 72.98(4) 30_545 25
Ga6 Ga3 Ga6 109.04(7) 25_455 25
Ga6 Ga3 Ga6 50.58(9) 30 25
Ga4 Ga3 Ga6 122.75(4) . 13_455
Ga2 Ga3 Ga6 62.32(6) 5_456 13_455
Ga2 Ga3 Ga6 113.89(10) 17_556 13_455
Ga2 Ga3 Ga6 83.82(6) 5_556 13_455
Ga2 Ga3 Ga6 12.25(5) 17_566 13_455
Ga6 Ga3 Ga6 109.04(7) 13_445 13_455
Ga6 Ga3 Ga6 72.98(4) 27_445 13_455
Ga6 Ga3 Ga6 114.50(8) 30_545 13_455
Ga6 Ga3 Ga6 50.58(9) 25_455 13_455
Ga6 Ga3 Ga6 24.27(9) 30 13_455
Ga6 Ga3 Ga6 72.98(4) 25 13_455
Ga3 Ga4 Ga1 124.74(2) . 25
Ga3 Ga4 Ag1 124.74(2) . .
Ga1 Ga4 Ag1 71.05(2) 25 .
Ga3 Ga4 Ag1 124.74(2) . 25
Ga1 Ga4 Ag1 0.0 25 25
Ag1 Ga4 Ag1 71.05(2) . 25
Ga3 Ga4 Ga1 124.74(2) . 25_455
Ga1 Ga4 Ga1 110.51(5) 25 25_455
Ag1 Ga4 Ga1 71.05(2) . 25_455
Ag1 Ga4 Ga1 110.51(5) 25 25_455
Ga3 Ga4 Ga1 124.74(2) . 1_545
Ga1 Ga4 Ga1 71.05(2) 25 1_545
Ag1 Ga4 Ga1 110.51(5) . 1_545
Ag1 Ga4 Ga1 71.05(2) 25 1_545
Ga1 Ga4 Ga1 71.05(2) 25_455 1_545
Ga3 Ga4 Ag1 124.74(2) . 25_455
Ga1 Ga4 Ag1 110.51(5) 25 25_455
Ag1 Ga4 Ag1 71.05(2) . 25_455
Ag1 Ga4 Ag1 110.51(5) 25 25_455
Ga1 Ga4 Ag1 0.0 25_455 25_455
Ga1 Ga4 Ag1 71.05(2) 1_545 25_455
Ga3 Ga4 Ag1 124.74(2) . 1_545
Ga1 Ga4 Ag1 71.05(2) 25 1_545
Ag1 Ga4 Ag1 110.51(5) . 1_545
Ag1 Ga4 Ag1 71.05(2) 25 1_545
Ga1 Ga4 Ag1 71.05(2) 25_455 1_545
Ga1 Ga4 Ag1 0.0 1_545 1_545
Ag1 Ga4 Ag1 71.05(2) 25_455 1_545
Ga3 Ga4 Ce1 68.51(2) . 25_445
Ga1 Ga4 Ce1 138.538(13) 25 25_445
Ag1 Ga4 Ce1 138.538(13) . 25_445
Ag1 Ga4 Ce1 138.538(13) 25 25_445
Ga1 Ga4 Ce1 70.614(10) 25_455 25_445
Ga1 Ga4 Ce1 70.614(10) 1_545 25_445
Ag1 Ga4 Ce1 70.614(10) 25_455 25_445
Ag1 Ga4 Ce1 70.614(10) 1_545 25_445
Ga3 Ga4 Ce1 68.51(2) . 25
Ga1 Ga4 Ce1 70.614(10) 25 25
Ag1 Ga4 Ce1 70.614(10) . 25
Ag1 Ga4 Ce1 70.614(10) 25 25
Ga1 Ga4 Ce1 138.538(13) 25_455 25
Ga1 Ga4 Ce1 138.538(13) 1_545 25
Ag1 Ga4 Ce1 138.538(13) 25_455 25
Ag1 Ga4 Ce1 138.538(13) 1_545 25
Ce1 Ga4 Ce1 137.03(4) 25_445 25
Ga3 Ga4 Ce1 68.51(2) . 25_545
Ga1 Ga4 Ce1 70.614(10) 25 25_545
Ag1 Ga4 Ce1 138.538(13) . 25_545
Ag1 Ga4 Ce1 70.614(10) 25 25_545
Ga1 Ga4 Ce1 138.538(13) 25_455 25_545
Ga1 Ga4 Ce1 70.614(10) 1_545 25_545
Ag1 Ga4 Ce1 138.538(13) 25_455 25_545
Ag1 Ga4 Ce1 70.614(10) 1_545 25_545
Ce1 Ga4 Ce1 82.290(15) 25_445 25_545
Ce1 Ga4 Ce1 82.290(15) 25 25_545
Ga4 Ag1 Ga4 108.95(2) 25 .
Ga4 Ag1 Ga4 110.51(5) 25 25_455
Ga4 Ag1 Ga4 108.95(2) . 25_455
Ga4 Ag1 Ga4 108.95(2) 25 1_565
Ga4 Ag1 Ga4 110.51(5) . 1_565
Ga4 Ag1 Ga4 108.95(2) 25_455 1_565
Ga4 Ag1 Ga1 54.476(11) 25 25_565
Ga4 Ag1 Ga1 125.524(11) . 25_565
Ga4 Ag1 Ga1 125.524(11) 25_455 25_565
Ga4 Ag1 Ga1 54.476(11) 1_565 25_565
Ga4 Ag1 Ga1 125.524(11) 25 25_455
Ga4 Ag1 Ga1 54.476(11) . 25_455
Ga4 Ag1 Ga1 54.476(11) 25_455 25_455
Ga4 Ag1 Ga1 125.524(11) 1_565 25_455
Ga1 Ag1 Ga1 180.0 25_565 25_455
Ga4 Ag1 Ag1 54.476(11) 25 25_565
Ga4 Ag1 Ag1 125.524(11) . 25_565
Ga4 Ag1 Ag1 125.524(11) 25_455 25_565
Ga4 Ag1 Ag1 54.476(11) 1_565 25_565
Ga1 Ag1 Ag1 0.0 25_565 25_565
Ga1 Ag1 Ag1 180.0 25_455 25_565
Ga4 Ag1 Ag1 125.524(11) 25 25_455
Ga4 Ag1 Ag1 54.476(11) . 25_455
Ga4 Ag1 Ag1 54.476(11) 25_455 25_455
Ga4 Ag1 Ag1 125.524(11) 1_565 25_455
Ga1 Ag1 Ag1 180.0 25_565 25_455
Ga1 Ag1 Ag1 0.0 25_455 25_455
Ag1 Ag1 Ag1 180.0 25_565 25_455
Ga4 Ag1 Ga1 125.524(11) 25 25_465
Ga4 Ag1 Ga1 125.524(11) . 25_465
Ga4 Ag1 Ga1 54.476(11) 25_455 25_465
Ga4 Ag1 Ga1 54.476(11) 1_565 25_465
Ga1 Ag1 Ga1 90.0 25_565 25_465
Ga1 Ag1 Ga1 90.0 25_455 25_465
Ag1 Ag1 Ga1 90.0 25_565 25_465
Ag1 Ag1 Ga1 90.0 25_455 25_465
Ga4 Ag1 Ga1 54.476(11) 25 25
Ga4 Ag1 Ga1 54.476(11) . 25
Ga4 Ag1 Ga1 125.524(11) 25_455 25
Ga4 Ag1 Ga1 125.524(11) 1_565 25
Ga1 Ag1 Ga1 90.0 25_565 25
Ga1 Ag1 Ga1 90.0 25_455 25
Ag1 Ag1 Ga1 90.0 25_565 25
Ag1 Ag1 Ga1 90.0 25_455 25
Ga1 Ag1 Ga1 180.0 25_465 25
Ga4 Ag1 Ag1 54.476(11) 25 25
Ga4 Ag1 Ag1 54.476(11) . 25
Ga4 Ag1 Ag1 125.524(11) 25_455 25
Ga4 Ag1 Ag1 125.524(11) 1_565 25
Ga1 Ag1 Ag1 90.0 25_565 25
Ga1 Ag1 Ag1 90.0 25_455 25
Ag1 Ag1 Ag1 90.0 25_565 25
Ag1 Ag1 Ag1 90.0 25_455 25
Ga1 Ag1 Ag1 180.0 25_465 25
Ga1 Ag1 Ag1 0.0 25 25
Ga4 Ag1 Ag1 125.524(11) 25 25_465
Ga4 Ag1 Ag1 125.524(11) . 25_465
Ga4 Ag1 Ag1 54.476(11) 25_455 25_465
Ga4 Ag1 Ag1 54.476(11) 1_565 25_465
Ga1 Ag1 Ag1 90.0 25_565 25_465
Ga1 Ag1 Ag1 90.0 25_455 25_465
Ag1 Ag1 Ag1 90.0 25_565 25_465
Ag1 Ag1 Ag1 90.0 25_455 25_465
Ga1 Ag1 Ag1 0.0 25_465 25_465
Ga1 Ag1 Ag1 180.0 25 25_465
Ag1 Ag1 Ag1 180.0 25 25_465
Ga6 Ga5 Ga6 70.02(6) 5_556 19_556
Ga6 Ga5 Ga6 108.47(11) 5_556 22_556
Ga6 Ga5 Ga6 70.02(6) 19_556 22_556
Ga6 Ga5 Ga6 70.02(6) 5_556 17_556
Ga6 Ga5 Ga6 108.47(11) 19_556 17_556
Ga6 Ga5 Ga6 70.02(6) 22_556 17_556
Ga6 Ga5 Ga6 109.98(6) 5_556 .
Ga6 Ga5 Ga6 71.53(11) 19_556 .
Ga6 Ga5 Ga6 109.98(6) 22_556 .
Ga6 Ga5 Ga6 180.00(8) 17_556 .
Ga6 Ga5 Ga6 180.000(1) 5_556 21
Ga6 Ga5 Ga6 109.98(6) 19_556 21
Ga6 Ga5 Ga6 71.53(11) 22_556 21
Ga6 Ga5 Ga6 109.98(6) 17_556 21
Ga6 Ga5 Ga6 70.02(6) . 21
Ga6 Ga5 Ga6 109.98(6) 5_556 3
Ga6 Ga5 Ga6 180.000(1) 19_556 3
Ga6 Ga5 Ga6 109.98(6) 22_556 3
Ga6 Ga5 Ga6 71.53(11) 17_556 3
Ga6 Ga5 Ga6 108.47(11) . 3
Ga6 Ga5 Ga6 70.02(6) 21 3
Ga6 Ga5 Ga6 71.53(11) 5_556 6
Ga6 Ga5 Ga6 109.98(6) 19_556 6
Ga6 Ga5 Ga6 180.00(8) 22_556 6
Ga6 Ga5 Ga6 109.98(6) 17_556 6
Ga6 Ga5 Ga6 70.02(6) . 6
Ga6 Ga5 Ga6 108.47(11) 21 6
Ga6 Ga5 Ga6 70.02(6) 3 6
Ga6 Ga5 Ga2 106.95(5) 5_556 29_544
Ga6 Ga5 Ga2 174.16(14) 19_556 29_544
Ga6 Ga5 Ga2 106.95(5) 22_556 29_544
Ga6 Ga5 Ga2 65.69(9) 17_556 29_544
Ga6 Ga5 Ga2 114.31(9) . 29_544
Ga6 Ga5 Ga2 73.05(5) 21 29_544
Ga6 Ga5 Ga2 5.84(14) 3 29_544
Ga6 Ga5 Ga2 73.05(5) 6 29_544
Ga6 Ga5 Ga2 5.84(14) 5_556 25_556
Ga6 Ga5 Ga2 73.05(5) 19_556 25_556
Ga6 Ga5 Ga2 114.31(9) 22_556 25_556
Ga6 Ga5 Ga2 73.05(5) 17_556 25_556
Ga6 Ga5 Ga2 106.95(5) . 25_556
Ga6 Ga5 Ga2 174.16(14) 21 25_556
Ga6 Ga5 Ga2 106.95(5) 3 25_556
Ga6 Ga5 Ga2 65.69(9) 6 25_556
Ga2 Ga5 Ga2 104.41(9) 29_544 25_556
Ga6 Ga5 Ga2 174.16(14) 5_556 9_444
Ga6 Ga5 Ga2 106.95(5) 19_556 9_444
Ga6 Ga5 Ga2 65.69(9) 22_556 9_444
Ga6 Ga5 Ga2 106.95(5) 17_556 9_444
Ga6 Ga5 Ga2 73.05(5) . 9_444
Ga6 Ga5 Ga2 5.84(14) 21 9_444
Ga6 Ga5 Ga2 73.05(5) 3 9_444
Ga6 Ga5 Ga2 114.31(9) 6 9_444
Ga2 Ga5 Ga2 75.59(9) 29_544 9_444
Ga2 Ga5 Ga2 180.0 25_556 9_444
Ga6 Ga5 Ga2 73.05(5) 5_556 13_456
Ga6 Ga5 Ga2 5.84(14) 19_556 13_456
Ga6 Ga5 Ga2 73.05(5) 22_556 13_456
Ga6 Ga5 Ga2 114.31(9) 17_556 13_456
Ga6 Ga5 Ga2 65.69(9) . 13_456
Ga6 Ga5 Ga2 106.95(5) 21 13_456
Ga6 Ga5 Ga2 174.16(14) 3 13_456
Ga6 Ga5 Ga2 106.95(5) 6 13_456
Ga2 Ga5 Ga2 180.0(2) 29_544 13_456
Ga2 Ga5 Ga2 75.59(9) 25_556 13_456
Ga2 Ga5 Ga2 104.41(9) 9_444 13_456
Ga6 Ga2 Ga6 161.9(13) 14_455 29
Ga6 Ga2 Ga6 94.0(7) 14_455 30_556
Ga6 Ga2 Ga6 67.8(6) 29 30_556
Ga6 Ga2 Ga6 67.8(6) 14_455 13_456
Ga6 Ga2 Ga6 94.0(7) 29 13_456
Ga6 Ga2 Ga6 26.19(12) 30_556 13_456
Ga6 Ga2 Ga2 80.9(6) 14_455 17_567
Ga6 Ga2 Ga2 80.9(6) 29 17_567
Ga6 Ga2 Ga2 13.09(6) 30_556 17_567
Ga6 Ga2 Ga2 13.09(6) 13_456 17_567
Ga6 Ga2 Ga5 141.0(7) 14_455 9
Ga6 Ga2 Ga5 20.9(5) 29 9
Ga6 Ga2 Ga5 46.98(9) 30_556 9
Ga6 Ga2 Ga5 73.17(15) 13_456 9
Ga2 Ga2 Ga5 60.08(10) 17_567 9
Ga6 Ga2 Ga5 20.9(5) 14_455 9_455
Ga6 Ga2 Ga5 141.0(7) 29 9_455
Ga6 Ga2 Ga5 73.17(15) 30_556 9_455
Ga6 Ga2 Ga5 46.98(9) 13_456 9_455
Ga2 Ga2 Ga5 60.08(10) 17_567 9_455
Ga5 Ga2 Ga5 120.2(2) 9 9_455
Ga6 Ga2 Ga3 94.8(3) 14_455 17_556
Ga6 Ga2 Ga3 94.8(3) 29 17_556
Ga6 Ga2 Ga3 121.01(9) 30_556 17_556
Ga6 Ga2 Ga3 121.01(9) 13_456 17_556
Ga2 Ga2 Ga3 121.93(10) 17_567 17_556
Ga5 Ga2 Ga3 105.296(13) 9 17_556
Ga5 Ga2 Ga3 105.296(13) 9_455 17_556
Ga6 Ga2 Ga3 94.8(3) 14_455 17_566
Ga6 Ga2 Ga3 94.8(3) 29 17_566
Ga6 Ga2 Ga3 121.01(9) 30_556 17_566
Ga6 Ga2 Ga3 121.01(9) 13_456 17_566
Ga2 Ga2 Ga3 121.93(10) 17_567 17_566
Ga5 Ga2 Ga3 105.296(13) 9 17_566
Ga5 Ga2 Ga3 105.296(13) 9_455 17_566
Ga3 Ga2 Ga3 116.1(2) 17_556 17_566
Ga6 Ga2 Ga6 37.07(9) 14_455 11_455
Ga6 Ga2 Ga6 142.0(2) 29 11_455
Ga6 Ga2 Ga6 98.61(16) 30_556 11_455
Ga6 Ga2 Ga6 77.64(12) 13_456 11_455
Ga2 Ga2 Ga6 88.11(13) 17_567 11_455
Ga5 Ga2 Ga6 132.78(16) 9 11_455
Ga5 Ga2 Ga6 44.59(5) 9_455 11_455
Ga3 Ga2 Ga6 60.80(5) 17_556 11_455
Ga3 Ga2 Ga6 121.52(12) 17_566 11_455
Ga6 Ga2 Ga6 142.0(2) 14_455 9
Ga6 Ga2 Ga6 37.07(9) 29 9
Ga6 Ga2 Ga6 77.64(12) 30_556 9
Ga6 Ga2 Ga6 98.61(16) 13_456 9
Ga2 Ga2 Ga6 88.11(13) 17_567 9
Ga5 Ga2 Ga6 44.59(5) 9 9
Ga5 Ga2 Ga6 132.78(16) 9_455 9
Ga3 Ga2 Ga6 121.52(12) 17_556 9
Ga3 Ga2 Ga6 60.80(5) 17_566 9
Ga6 Ga2 Ga6 176.2(3) 11_455 9
Ga6 Ga2 Ga6 142.0(2) 14_455 11
Ga6 Ga2 Ga6 37.07(9) 29 11
Ga6 Ga2 Ga6 77.64(12) 30_556 11
Ga6 Ga2 Ga6 98.61(16) 13_456 11
Ga2 Ga2 Ga6 88.11(13) 17_567 11
Ga5 Ga2 Ga6 44.59(5) 9 11
Ga5 Ga2 Ga6 132.78(16) 9_455 11
Ga3 Ga2 Ga6 60.80(5) 17_556 11
Ga3 Ga2 Ga6 121.52(12) 17_566 11
Ga6 Ga2 Ga6 106.78(8) 11_455 11
Ga6 Ga2 Ga6 73.09(7) 9 11
Ga2 Ga6 Ga6 9.1(6) 29_554 3_565
Ga2 Ga6 Ga5 153.3(7) 29_554 .
Ga6 Ga6 Ga5 144.23(6) 3_565 .
Ga2 Ga6 Ga6 134.29(10) 29_554 21
Ga6 Ga6 Ga6 135.000(3) 3_565 21
Ga5 Ga6 Ga6 54.99(3) . 21
Ga2 Ga6 Ga6 134.29(10) 29_554 6
Ga6 Ga6 Ga6 135.000(2) 3_565 6
Ga5 Ga6 Ga6 54.99(3) . 6
Ga6 Ga6 Ga6 90.000(1) 21 6
Ga2 Ga6 Ga6 99.1(6) 29_554 19_556
Ga6 Ga6 Ga6 90.000(1) 3_565 19_556
Ga5 Ga6 Ga6 54.23(6) . 19_556
Ga6 Ga6 Ga6 90.000(1) 21 19_556
Ga6 Ga6 Ga6 90.0 6 19_556
Ga2 Ga6 Ga2 86.0(7) 29_554 13_456
Ga6 Ga6 Ga2 76.91(6) 3_565 13_456
Ga5 Ga6 Ga2 67.33(5) . 13_456
Ga6 Ga6 Ga2 99.22(4) 21 13_456
Ga6 Ga6 Ga2 99.22(4) 6 13_456
Ga6 Ga6 Ga2 13.09(6) 19_556 13_456
Ga2 Ga6 Ga6 73.3(6) 29_554 17_566
Ga6 Ga6 Ga6 64.21(9) 3_565 17_566
Ga5 Ga6 Ga6 80.02(9) . 17_566
Ga6 Ga6 Ga6 107.91(6) 21 17_566
Ga6 Ga6 Ga6 107.91(6) 6 17_566
Ga6 Ga6 Ga6 25.79(9) 19_556 17_566
Ga2 Ga6 Ga6 12.69(6) 13_456 17_566
Ga2 Ga6 Ga3 73.0(3) 29_554 25_455
Ga6 Ga6 Ga3 77.86(5) 3_565 25_455
Ga5 Ga6 Ga3 119.13(5) . 25_455
Ga6 Ga6 Ga3 64.71(4) 21 25_455
Ga6 Ga6 Ga3 136.43(5) 6 25_455
Ga6 Ga6 Ga3 122.75(4) 19_556 25_455
Ga2 Ga6 Ga3 118.64(6) 13_456 25_455
Ga6 Ga6 Ga3 113.31(7) 17_566 25_455
Ga2 Ga6 Ga3 73.0(3) 29_554 25
Ga6 Ga6 Ga3 77.86(5) 3_565 25
Ga5 Ga6 Ga3 119.13(5) . 25
Ga6 Ga6 Ga3 136.43(5) 21 25
Ga6 Ga6 Ga3 64.71(4) 6 25
Ga6 Ga6 Ga3 122.75(4) 19_556 25
Ga2 Ga6 Ga3 118.64(6) 13_456 25
Ga6 Ga6 Ga3 113.31(7) 17_566 25
Ga3 Ga6 Ga3 109.04(7) 25_455 25
Ga2 Ga6 Ga2 125.65(13) 29_554 9_444
Ga6 Ga6 Ga2 126.55(4) 3_565 9_444
Ga5 Ga6 Ga2 62.36(8) . 9_444
Ga6 Ga6 Ga2 8.64(4) 21 9_444
Ga6 Ga6 Ga2 98.43(4) 6 9_444
Ga6 Ga6 Ga2 91.89(13) 19_556 9_444
Ga2 Ga6 Ga2 99.62(12) 13_456 9_444
Ga6 Ga6 Ga2 106.78(14) 17_566 9_444
Ga3 Ga6 Ga2 56.88(8) 25_455 9_444
Ga3 Ga6 Ga2 139.55(15) 25 9_444
Ga2 Ga6 Ga2 125.65(13) 29_554 9_544
Ga6 Ga6 Ga2 126.55(4) 3_565 9_544
Ga5 Ga6 Ga2 62.36(8) . 9_544
Ga6 Ga6 Ga2 98.43(4) 21 9_544
Ga6 Ga6 Ga2 8.64(4) 6 9_544
Ga6 Ga6 Ga2 91.89(13) 19_556 9_544
Ga2 Ga6 Ga2 99.62(12) 13_456 9_544
Ga6 Ga6 Ga2 106.78(14) 17_566 9_544
Ga3 Ga6 Ga2 139.55(15) 25_455 9_544
Ga3 Ga6 Ga2 56.88(8) 25 9_544
Ga2 Ga6 Ga2 106.78(8) 9_444 9_544
loop_
_geom_bond_atom_site_label_1
_geom_bond_atom_site_label_2
_geom_bond_distance
_geom_bond_site_symmetry_2
Ce1 Ga6 3.134(2) 6
Ce1 Ga6 3.134(2) .
Ce1 Ga6 3.134(2) 21
Ce1 Ga6 3.134(2) 3
Ce1 Ga4 3.2501(6) 25_445
Ce1 Ga4 3.2501(6) 25
Ce1 Ga4 3.2501(6) 25_455
Ce1 Ga4 3.2501(6) 25_545
Ce1 Ga3 3.2847(6) 25
Ce1 Ga3 3.2847(6) 25_445
Ce1 Ga3 3.2847(6) 25_545
Ce1 Ga3 3.2847(6) 25_455
Ga3 Ga4 2.4723(18) .
Ga3 Ga2 2.520(3) 5_456
Ga3 Ga2 2.520(3) 17_556
Ga3 Ga2 2.520(3) 5_556
Ga3 Ga2 2.520(3) 17_566
Ga3 Ga6 2.6260(12) 13_445
Ga3 Ga6 2.6260(12) 27_445
Ga3 Ga6 2.6260(12) 30_545
Ga3 Ga6 2.6260(12) 25_455
Ga3 Ga6 2.6260(12) 30
Ga3 Ga6 2.6260(12) 25
Ga3 Ga6 2.6260(12) 13_455
Ga4 Ga1 2.6024(8) 25
Ga4 Ag1 2.6024(8) .
Ga4 Ag1 2.6024(8) 25
Ga4 Ga1 2.6024(8) 25_455
Ga4 Ga1 2.6024(8) 1_545
Ga4 Ag1 2.6024(8) 25_455
Ga4 Ag1 2.6024(8) 1_545
Ga4 Ce1 3.2501(6) 25_445
Ga4 Ce1 3.2501(6) 25
Ga4 Ce1 3.2501(6) 25_545
Ag1 Ga4 2.6024(8) 25
Ag1 Ga4 2.6024(8) 25_455
Ag1 Ga4 2.6024(8) 1_565
Ag1 Ga1 3.0242(4) 25_565
Ag1 Ga1 3.0242(4) 25_455
Ag1 Ag1 3.0242(4) 25_565
Ag1 Ag1 3.0242(4) 25_455
Ag1 Ga1 3.0242(4) 25_465
Ag1 Ga1 3.0242(4) 25
Ag1 Ag1 3.0242(4) 25
Ag1 Ag1 3.0242(4) 25_465
Ga5 Ga6 1.955(2) 5_556
Ga5 Ga6 1.955(2) 19_556
Ga5 Ga6 1.955(2) 22_556
Ga5 Ga6 1.955(2) 17_556
Ga5 Ga6 1.955(2) .
Ga5 Ga6 1.955(2) 21
Ga5 Ga6 1.955(2) 3
Ga5 Ga6 1.955(2) 6
Ga5 Ga2 2.467(3) 29_544
Ga5 Ga2 2.467(3) 25_556
Ga5 Ga2 2.467(3) 9_444
Ga5 Ga2 2.467(3) 13_456
Ga2 Ga6 0.559(2) 14_455
Ga2 Ga6 0.559(2) 29
Ga2 Ga6 2.437(4) 30_556
Ga2 Ga6 2.437(4) 13_456
Ga2 Ga2 2.461(10) 17_567
Ga2 Ga5 2.467(3) 9
Ga2 Ga5 2.467(3) 9_455
Ga2 Ga3 2.520(3) 17_556
Ga2 Ga3 2.520(3) 17_566
Ga2 Ga6 2.6641(14) 11_455
Ga2 Ga6 2.6641(14) 9
Ga2 Ga6 2.6641(14) 11
Ga6 Ga2 0.559(2) 29_554
Ga6 Ga6 1.104(4) 3_565
Ga6 Ga6 2.243(3) 21
Ga6 Ga6 2.243(3) 6
Ga6 Ga6 2.285(3) 19_556
Ga6 Ga2 2.437(4) 13_456
Ga6 Ga6 2.538(4) 17_566
Ga6 Ga3 2.6260(12) 25_455
Ga6 Ga3 2.6260(12) 25
Ga6 Ga2 2.6641(14) 9_444
Ga6 Ga2 2.6641(14) 9_544
