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#$Date: 2021-06-23 12:01:53 +0300 (Wed, 23 Jun 2021) $
#$Revision: 266635 $
#$URL: file:///home/coder/svn-repositories/cod/cif/1/56/36/1563654.cif $
#------------------------------------------------------------------------------
#
# This file is available in the Crystallography Open Database (COD),
# http://www.crystallography.net/
#
# All data on this site have been placed in the public domain by the
# contributors.
#
data_1563654
loop_
_publ_author_name
'Lipatov, Alexey'
'Gribanov, Alexander'
'Grytsiv, Andriy'
'Safronov, Sergey'
'Rogl, Peter'
'Rousnyak, Julia'
'Seropegin, Yurii'
'Giester, Gerald'
_publ_section_title
;
 The ternary system cerium--rhodium--silicon
;
_journal_issue                   4
_journal_name_full               'Journal of Solid State Chemistry'
_journal_page_first              829
_journal_page_last               843
_journal_paper_doi               10.1016/j.jssc.2010.01.029
_journal_volume                  183
_journal_year                    2010
_chemical_formula_sum            'Ce2 Rh3 Si5'
_chemical_formula_weight         729.42
_space_group_IT_number           72
_space_group_name_Hall           '-I 2 2c'
_space_group_name_H-M_alt        'I b a m'
_symmetry_cell_setting           orthorhombic
_symmetry_space_group_name_H-M   'I b a m'
_atom_sites_solution_hydrogens   geom
_atom_sites_solution_primary     direct
_atom_sites_solution_secondary   difmap
_audit_creation_method           SHELXL-97
_cell_angle_alpha                90.00
_cell_angle_beta                 90.00
_cell_angle_gamma                90.00
_cell_formula_units_Z            4
_cell_length_a                   9.9118(2)
_cell_length_b                   11.7558(3)
_cell_length_c                   5.83130(10)
_cell_measurement_temperature    298(2)
_cell_volume                     679.47(2)
_computing_structure_refinement  'SHELXL-97 (Sheldrick, 1997)'
_computing_structure_solution    'SHELXS-97 (Sheldrick, 1990)'
_diffrn_ambient_temperature      298(2)
_diffrn_measured_fraction_theta_full 0.971
_diffrn_measured_fraction_theta_max 0.971
_diffrn_radiation_monochromator  graphite
_diffrn_radiation_source         'fine-focus sealed tube'
_diffrn_radiation_type           MoK\a
_diffrn_radiation_wavelength     0.71069
_diffrn_reflns_av_R_equivalents  0.0122
_diffrn_reflns_av_sigmaI/netI    0.0167
_diffrn_reflns_limit_h_max       16
_diffrn_reflns_limit_h_min       -15
_diffrn_reflns_limit_k_max       19
_diffrn_reflns_limit_k_min       -19
_diffrn_reflns_limit_l_max       9
_diffrn_reflns_limit_l_min       -9
_diffrn_reflns_number            1516
_diffrn_reflns_theta_full        36.25
_diffrn_reflns_theta_max         36.25
_diffrn_reflns_theta_min         2.69
_exptl_absorpt_coefficient_mu    21.028
_exptl_absorpt_correction_T_max  0.5711
_exptl_absorpt_correction_T_min  0.5711
_exptl_crystal_density_diffrn    7.130
_exptl_crystal_density_method    'not measured'
_exptl_crystal_F_000             1284
_exptl_crystal_size_max          0.03
_exptl_crystal_size_mid          0.03
_exptl_crystal_size_min          0.03
_refine_diff_density_max         8.044
_refine_diff_density_min         -2.774
_refine_diff_density_rms         0.447
_refine_ls_extinction_coef       0.00116(13)
_refine_ls_extinction_expression Fc^*^=kFc[1+0.001xFc²λ³/sin(2θ)]^-1/4^
_refine_ls_extinction_method     SHELXL
_refine_ls_goodness_of_fit_ref   0.891
_refine_ls_hydrogen_treatment    mixed
_refine_ls_matrix_type           full
_refine_ls_number_parameters     37
_refine_ls_number_reflns         863
_refine_ls_number_restraints     0
_refine_ls_restrained_S_all      0.891
_refine_ls_R_factor_all          0.0273
_refine_ls_R_factor_gt           0.0258
_refine_ls_shift/su_max          0.002
_refine_ls_shift/su_mean         0.001
_refine_ls_structure_factor_coef Fsqd
_refine_ls_weighting_details
'calc w=1/[σ²(Fo²)+(0.0505P)²+13.2122P] where P=(Fo²+2Fc²)/3'
_refine_ls_weighting_scheme      calc
_refine_ls_wR_factor_gt          0.0635
_refine_ls_wR_factor_ref         0.0646
_reflns_number_gt                829
_reflns_number_total             863
_reflns_threshold_expression     >2sigma(I)
_cod_data_source_file            JSSC-2010-183-829.cif
_cod_data_source_block           ce2rh3si5
_cod_original_sg_symbol_H-M      Ibam
_cod_database_code               1563654
loop_
_symmetry_equiv_pos_as_xyz
'x, y, z'
'-x, -y, z'
'-x, y, -z+1/2'
'x, -y, -z+1/2'
'x+1/2, y+1/2, z+1/2'
'-x+1/2, -y+1/2, z+1/2'
'-x+1/2, y+1/2, -z+1'
'x+1/2, -y+1/2, -z+1'
'-x, -y, -z'
'x, y, -z'
'x, -y, z-1/2'
'-x, y, z-1/2'
'-x+1/2, -y+1/2, -z+1/2'
'x+1/2, y+1/2, -z+1/2'
'x+1/2, -y+1/2, z'
'-x+1/2, y+1/2, z'
loop_
_atom_site_label
_atom_site_type_symbol
_atom_site_fract_x
_atom_site_fract_y
_atom_site_fract_z
_atom_site_U_iso_or_equiv
_atom_site_adp_type
_atom_site_occupancy
_atom_site_symmetry_multiplicity
_atom_site_calc_flag
_atom_site_refinement_flags
_atom_site_disorder_assembly
_atom_site_disorder_group
Ce1 Ce 0.26613(3) 0.36895(2) 0.0000 0.00590(10) Uani 1.02(3) 2 d SP . .
Rh2 Rh 0.10786(4) 0.13811(3) 0.0000 0.00664(13) Uani 0.97(3) 2 d SP . .
Rh3 Rh 0.5000 0.0000 0.2500 0.00594(15) Uani 0.97(3) 4 d SP . .
Si4 Si 0.34676(16) 0.10681(13) 0.0000 0.0107(4) Uani 1.04(3) 2 d SP . .
Si5 Si 0.0000 0.27509(13) 0.2500 0.0083(4) Uani 1.01(3) 2 d SP . .
Si6 Si 0.0000 0.0000 0.2500 0.0070(5) Uani 1.04(3) 4 d SP . .
loop_
_atom_type_symbol
_atom_type_description
_atom_type_scat_dispersion_real
_atom_type_scat_dispersion_imag
_atom_type_scat_source
Ce Ce -0.2486 2.6331 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
Rh Rh -1.1178 0.9187 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
Si Si 0.0817 0.0704 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
loop_
_geom_angle_atom_site_label_1
_geom_angle_atom_site_label_2
_geom_angle_atom_site_label_3
_geom_angle
_geom_angle_site_symmetry_1
_geom_angle_site_symmetry_3
Si4 Ce1 Rh2 128.16(3) 7_554 .
Si4 Ce1 Si4 77.47(3) 7_554 13_554
Rh2 Ce1 Si4 84.27(3) . 13_554
Si4 Ce1 Si4 77.47(3) 7_554 13
Rh2 Ce1 Si4 84.27(3) . 13
Si4 Ce1 Si4 136.79(5) 13_554 13
Si4 Ce1 Si6 79.56(3) 7_554 13
Rh2 Ce1 Si6 142.535(8) . 13
Si4 Ce1 Si6 130.55(3) 13_554 13
Si4 Ce1 Si6 77.72(3) 13 13
Si4 Ce1 Si6 79.56(3) 7_554 5_554
Rh2 Ce1 Si6 142.535(8) . 5_554
Si4 Ce1 Si6 77.72(3) 13_554 5_554
Si4 Ce1 Si6 130.55(3) 13 5_554
Si6 Ce1 Si6 55.288(5) 13 5_554
Si4 Ce1 Rh2 99.818(13) 7_554 13
Rh2 Ce1 Rh2 100.042(8) . 13
Si4 Ce1 Rh2 175.69(3) 13_554 13
Si4 Ce1 Rh2 44.64(3) 13 13
Si6 Ce1 Rh2 45.256(7) 13 13
Si6 Ce1 Rh2 98.554(9) 5_554 13
Si4 Ce1 Rh2 99.818(13) 7_554 13_554
Rh2 Ce1 Rh2 100.042(8) . 13_554
Si4 Ce1 Rh2 44.64(3) 13_554 13_554
Si4 Ce1 Rh2 175.69(3) 13 13_554
Si6 Ce1 Rh2 98.554(9) 13 13_554
Si6 Ce1 Rh2 45.256(7) 5_554 13_554
Rh2 Ce1 Rh2 133.529(16) 13 13_554
Si4 Ce1 Si4 172.73(2) 7_554 .
Rh2 Ce1 Si4 44.57(3) . .
Si4 Ce1 Si4 100.23(3) 13_554 .
Si4 Ce1 Si4 100.23(3) 13 .
Si6 Ce1 Si4 106.82(3) 13 .
Si6 Ce1 Si4 106.82(3) 5_554 .
Rh2 Ce1 Si4 82.869(14) 13 .
Rh2 Ce1 Si4 82.869(14) 13_554 .
Si4 Ce1 Si5 90.79(4) 7_554 10
Rh2 Ce1 Si5 44.85(3) . 10
Si4 Ce1 Si5 46.82(3) 13_554 10
Si4 Ce1 Si5 99.22(3) 13 10
Si6 Ce1 Si5 170.29(3) 13 10
Si6 Ce1 Si5 124.345(11) 5_554 10
Rh2 Ce1 Si5 137.048(15) 13 10
Rh2 Ce1 Si5 84.097(7) 13_554 10
Si4 Ce1 Si5 82.74(4) . 10
Si4 Ce1 Si5 90.79(4) 7_554 .
Rh2 Ce1 Si5 44.85(3) . .
Si4 Ce1 Si5 99.22(3) 13_554 .
Si4 Ce1 Si5 46.82(3) 13 .
Si6 Ce1 Si5 124.345(11) 13 .
Si6 Ce1 Si5 170.29(3) 5_554 .
Rh2 Ce1 Si5 84.097(7) 13 .
Rh2 Ce1 Si5 137.048(15) 13_554 .
Si4 Ce1 Si5 82.74(4) . .
Si5 Ce1 Si5 54.030(11) 10 .
Si4 Ce1 Si5 139.09(3) 7_554 13
Rh2 Ce1 Si5 84.55(2) . 13
Si4 Ce1 Si5 136.52(3) 13_554 13
Si4 Ce1 Si5 83.32(3) 13 13
Si6 Ce1 Si5 61.09(2) 13 13
Si6 Ce1 Si5 86.375(17) 5_554 13
Rh2 Ce1 Si5 44.502(15) 13 13
Rh2 Ce1 Si5 96.829(9) 13_554 13
Si4 Ce1 Si5 46.38(3) . 13
Si5 Ce1 Si5 128.068(9) 10 13
Si5 Ce1 Si5 101.845(7) . 13
Si4 Rh2 Si5 122.58(3) . .
Si4 Rh2 Si5 122.58(3) . 10
Si5 Rh2 Si5 74.05(4) . 10
Si4 Rh2 Si6 109.40(3) . 9
Si5 Rh2 Si6 127.69(2) . 9
Si5 Rh2 Si6 83.62(3) 10 9
Si4 Rh2 Si6 109.40(3) . .
Si5 Rh2 Si6 83.62(3) . .
Si5 Rh2 Si6 127.69(2) 10 .
Si6 Rh2 Si6 73.736(11) 9 .
Si4 Rh2 Ce1 68.80(4) . .
Si5 Rh2 Ce1 69.21(3) . .
Si5 Rh2 Ce1 69.21(3) 10 .
Si6 Rh2 Ce1 143.003(5) 9 .
Si6 Rh2 Ce1 143.003(5) . .
Si4 Rh2 Ce1 66.859(8) . 13
Si5 Rh2 Ce1 68.771(11) . 13
Si5 Rh2 Ce1 138.12(3) 10 13
Si6 Rh2 Ce1 134.994(13) 9 13
Si6 Rh2 Ce1 66.698(5) . 13
Ce1 Rh2 Ce1 79.958(8) . 13
Si4 Rh2 Ce1 66.859(8) . 13_554
Si5 Rh2 Ce1 138.12(3) . 13_554
Si5 Rh2 Ce1 68.771(11) 10 13_554
Si6 Rh2 Ce1 66.698(5) 9 13_554
Si6 Rh2 Ce1 134.994(13) . 13_554
Ce1 Rh2 Ce1 79.958(8) . 13_554
Ce1 Rh2 Ce1 133.529(16) 13 13_554
Si4 Rh2 Ce1 169.77(4) . 15_455
Si5 Rh2 Ce1 64.839(15) . 15_455
Si5 Rh2 Ce1 64.839(15) 10 15_455
Si6 Rh2 Ce1 62.858(9) 9 15_455
Si6 Rh2 Ce1 62.858(9) . 15_455
Ce1 Rh2 Ce1 121.434(13) . 15_455
Ce1 Rh2 Ce1 113.134(8) 13 15_455
Ce1 Rh2 Ce1 113.134(8) 13_554 15_455
Si4 Rh2 Ce1 59.63(4) . 7_544
Si5 Rh2 Ce1 141.34(2) . 7_544
Si5 Rh2 Ce1 141.34(2) 10 7_544
Si6 Rh2 Ce1 62.616(9) 9 7_544
Si6 Rh2 Ce1 62.616(9) . 7_544
Ce1 Rh2 Ce1 128.428(13) . 7_544
Ce1 Rh2 Ce1 80.279(9) 13 7_544
Ce1 Rh2 Ce1 80.279(9) 13_554 7_544
Ce1 Rh2 Ce1 110.139(11) 15_455 7_544
Si4 Rh3 Si4 118.37(7) 3_655 .
Si4 Rh3 Si4 107.01(4) 3_655 11_556
Si4 Rh3 Si4 103.42(7) . 11_556
Si4 Rh3 Si4 103.42(7) 3_655 9_655
Si4 Rh3 Si4 107.01(4) . 9_655
Si4 Rh3 Si4 118.37(7) 11_556 9_655
Si4 Rh3 Si5 120.81(3) 3_655 14_545
Si4 Rh3 Si5 120.81(4) . 14_545
Si4 Rh3 Si5 59.19(4) 11_556 14_545
Si4 Rh3 Si5 59.19(3) 9_655 14_545
Si4 Rh3 Si5 59.19(3) 3_655 13
Si4 Rh3 Si5 59.19(4) . 13
Si4 Rh3 Si5 120.81(4) 11_556 13
Si4 Rh3 Si5 120.81(3) 9_655 13
Si5 Rh3 Si5 180.0 14_545 13
Si4 Rh3 Rh3 126.49(2) 3_655 9_655
Si4 Rh3 Rh3 53.51(2) . 9_655
Si4 Rh3 Rh3 126.49(2) 11_556 9_655
Si4 Rh3 Rh3 53.51(2) 9_655 9_655
Si5 Rh3 Rh3 90.0 14_545 9_655
Si5 Rh3 Rh3 90.0 13 9_655
Si4 Rh3 Rh3 53.51(2) 3_655 9_656
Si4 Rh3 Rh3 126.49(2) . 9_656
Si4 Rh3 Rh3 53.51(2) 11_556 9_656
Si4 Rh3 Rh3 126.49(2) 9_655 9_656
Si5 Rh3 Rh3 90.0 14_545 9_656
Si5 Rh3 Rh3 90.0 13 9_656
Rh3 Rh3 Rh3 180.0 9_655 9_656
Si4 Rh3 Ce1 166.45(3) 3_655 7_544
Si4 Rh3 Ce1 59.61(4) . 7_544
Si4 Rh3 Ce1 62.62(2) 11_556 7_544
Si4 Rh3 Ce1 89.63(4) 9_655 7_544
Si5 Rh3 Ce1 62.925(4) 14_545 7_544
Si5 Rh3 Ce1 117.075(4) 13 7_544
Rh3 Rh3 Ce1 64.488(2) 9_655 7_544
Rh3 Rh3 Ce1 115.512(2) 9_656 7_544
Si4 Rh3 Ce1 89.63(4) 3_655 13
Si4 Rh3 Ce1 62.62(2) . 13
Si4 Rh3 Ce1 59.61(4) 11_556 13
Si4 Rh3 Ce1 166.45(3) 9_655 13
Si5 Rh3 Ce1 117.075(4) 14_545 13
Si5 Rh3 Ce1 62.925(4) 13 13
Rh3 Rh3 Ce1 115.512(2) 9_655 13
Rh3 Rh3 Ce1 64.488(2) 9_656 13
Ce1 Rh3 Ce1 77.604(7) 7_544 13
Si4 Rh3 Ce1 62.62(2) 3_655 15
Si4 Rh3 Ce1 89.63(4) . 15
Si4 Rh3 Ce1 166.45(3) 11_556 15
Si4 Rh3 Ce1 59.61(4) 9_655 15
Si5 Rh3 Ce1 117.075(4) 14_545 15
Si5 Rh3 Ce1 62.925(4) 13 15
Rh3 Rh3 Ce1 64.488(2) 9_655 15
Rh3 Rh3 Ce1 115.512(2) 9_656 15
Ce1 Rh3 Ce1 128.976(4) 7_544 15
Ce1 Rh3 Ce1 125.850(8) 13 15
Si4 Rh3 Ce1 59.61(4) 3_655 5_545
Si4 Rh3 Ce1 166.45(3) . 5_545
Si4 Rh3 Ce1 89.63(4) 11_556 5_545
Si4 Rh3 Ce1 62.62(2) 9_655 5_545
Si5 Rh3 Ce1 62.925(4) 14_545 5_545
Si5 Rh3 Ce1 117.075(4) 13 5_545
Rh3 Rh3 Ce1 115.512(2) 9_655 5_545
Rh3 Rh3 Ce1 64.488(2) 9_656 5_545
Ce1 Rh3 Ce1 125.850(8) 7_544 5_545
Ce1 Rh3 Ce1 128.976(4) 13 5_545
Ce1 Rh3 Ce1 77.604(7) 15 5_545
Rh2 Si4 Rh3 133.70(5) . .
Rh2 Si4 Rh3 133.70(5) . 9_655
Rh3 Si4 Rh3 72.99(4) . 9_655
Rh2 Si4 Si5 120.70(5) . 13
Rh3 Si4 Si5 64.22(4) . 13
Rh3 Si4 Si5 104.63(6) 9_655 13
Rh2 Si4 Si5 120.70(5) . 6_554
Rh3 Si4 Si5 104.63(6) . 6_554
Rh3 Si4 Si5 64.22(4) 9_655 6_554
Si5 Si4 Si5 70.63(5) 13 6_554
Rh2 Si4 Ce1 77.02(5) . 7_544
Rh3 Si4 Ce1 75.80(4) . 7_544
Rh3 Si4 Ce1 75.80(4) 9_655 7_544
Si5 Si4 Ce1 137.30(5) 13 7_544
Si5 Si4 Ce1 137.30(5) 6_554 7_544
Rh2 Si4 Ce1 68.50(3) . 13_554
Rh3 Si4 Ce1 145.14(5) . 13_554
Rh3 Si4 Ce1 73.423(8) 9_655 13_554
Si5 Si4 Ce1 134.62(6) 13 13_554
Si5 Si4 Ce1 68.124(13) 6_554 13_554
Ce1 Si4 Ce1 87.24(3) 7_544 13_554
Rh2 Si4 Ce1 68.50(3) . 13
Rh3 Si4 Ce1 73.423(8) . 13
Rh3 Si4 Ce1 145.14(5) 9_655 13
Si5 Si4 Ce1 68.124(13) 13 13
Si5 Si4 Ce1 134.62(6) 6_554 13
Ce1 Si4 Ce1 87.24(3) 7_544 13
Ce1 Si4 Ce1 136.79(5) 13_554 13
Rh2 Si4 Ce1 66.63(4) . .
Rh3 Si4 Ce1 130.65(4) . .
Rh3 Si4 Ce1 130.65(4) 9_655 .
Si5 Si4 Ce1 67.56(4) 13 .
Si5 Si4 Ce1 67.56(4) 6_554 .
Ce1 Si4 Ce1 143.65(6) 7_544 .
Ce1 Si4 Ce1 79.77(3) 13_554 .
Ce1 Si4 Ce1 79.77(3) 13 .
Rh2 Si5 Rh2 96.61(6) . 3
Rh2 Si5 Si4 116.64(3) . 13
Rh2 Si5 Si4 106.50(2) 3 13
Rh2 Si5 Si4 106.50(2) . 15_455
Rh2 Si5 Si4 116.64(3) 3 15_455
Si4 Si5 Si4 113.19(9) 13 15_455
Rh2 Si5 Rh3 131.69(3) . 13
Rh2 Si5 Rh3 131.69(3) 3 13
Si4 Si5 Rh3 56.60(4) 13 13
Si4 Si5 Rh3 56.60(4) 15_455 13
Rh2 Si5 Ce1 65.936(10) . .
Rh2 Si5 Ce1 149.90(4) 3 .
Si4 Si5 Ce1 65.06(3) 13 .
Si4 Si5 Ce1 92.47(4) 15_455 .
Rh3 Si5 Ce1 69.89(3) 13 .
Rh2 Si5 Ce1 149.90(4) . 3
Rh2 Si5 Ce1 65.936(10) 3 3
Si4 Si5 Ce1 92.47(4) 13 3
Si4 Si5 Ce1 65.06(3) 15_455 3
Rh3 Si5 Ce1 69.89(3) 13 3
Ce1 Si5 Ce1 139.78(6) . 3
Rh2 Si5 Ce1 72.27(3) . 15_455
Rh2 Si5 Ce1 66.73(2) 3 15_455
Si4 Si5 Ce1 170.04(3) 13 15_455
Si4 Si5 Ce1 66.06(3) 15_455 15_455
Rh3 Si5 Ce1 121.73(2) 13 15_455
Ce1 Si5 Ce1 124.533(11) . 15_455
Ce1 Si5 Ce1 78.155(7) 3 15_455
Rh2 Si5 Ce1 66.73(2) . 13
Rh2 Si5 Ce1 72.27(3) 3 13
Si4 Si5 Ce1 66.06(3) 13 13
Si4 Si5 Ce1 170.04(3) 15_455 13
Rh3 Si5 Ce1 121.73(2) 13 13
Ce1 Si5 Ce1 78.155(7) . 13
Ce1 Si5 Ce1 124.533(11) 3 13
Ce1 Si5 Ce1 116.54(5) 15_455 13
Rh2 Si6 Rh2 127.795(18) 9 3
Rh2 Si6 Rh2 106.264(11) 9 .
Rh2 Si6 Rh2 96.148(15) 3 .
Rh2 Si6 Rh2 96.148(15) 9 11_556
Rh2 Si6 Rh2 106.264(11) 3 11_556
Rh2 Si6 Rh2 127.795(18) . 11_556
Rh2 Si6 Ce1 158.528(10) 9 13
Rh2 Si6 Ce1 73.657(11) 3 13
Rh2 Si6 Ce1 68.047(7) . 13
Rh2 Si6 Ce1 74.017(10) 11_556 13
Rh2 Si6 Ce1 74.017(10) 9 15_455
Rh2 Si6 Ce1 68.047(7) 3 15_455
Rh2 Si6 Ce1 73.657(11) . 15_455
Rh2 Si6 Ce1 158.528(10) 11_556 15_455
Ce1 Si6 Ce1 121.277(9) 13 15_455
Rh2 Si6 Ce1 68.047(7) 9 5_445
Rh2 Si6 Ce1 74.017(10) 3 5_445
Rh2 Si6 Ce1 158.528(10) . 5_445
Rh2 Si6 Ce1 73.657(10) 11_556 5_445
Ce1 Si6 Ce1 124.712(5) 13 5_445
Ce1 Si6 Ce1 84.916(9) 15_455 5_445
Rh2 Si6 Ce1 73.657(10) 9 7_544
Rh2 Si6 Ce1 158.528(10) 3 7_544
Rh2 Si6 Ce1 74.017(10) . 7_544
Rh2 Si6 Ce1 68.047(7) 11_556 7_544
Ce1 Si6 Ce1 84.916(9) 13 7_544
Ce1 Si6 Ce1 124.712(5) 15_455 7_544
Ce1 Si6 Ce1 121.277(9) 5_445 7_544
loop_
_geom_bond_atom_site_label_1
_geom_bond_atom_site_label_2
_geom_bond_distance
_geom_bond_site_symmetry_2
Ce1 Si4 3.0118(16) 7_554
Ce1 Rh2 3.1346(5) .
Ce1 Si4 3.1360(6) 13_554
Ce1 Si4 3.1360(6) 13
Ce1 Si6 3.1420(2) 13
Ce1 Si6 3.1420(2) 5_554
Ce1 Rh2 3.17301(19) 13
Ce1 Rh2 3.17301(19) 13_554
Ce1 Si4 3.1836(15) .
Ce1 Si5 3.2095(6) 10
Ce1 Si5 3.2095(6) .
Ce1 Si5 3.2196(8) 13
Rh2 Si4 2.3964(16) .
Rh2 Si5 2.4210(11) .
Rh2 Si5 2.4210(11) 10
Rh2 Si6 2.4298(3) 9
Rh2 Si6 2.4298(3) .
Rh2 Ce1 3.17301(19) 13
Rh2 Ce1 3.17301(19) 13_554
Rh2 Ce1 3.3882(5) 15_455
Rh2 Ce1 3.4017(5) 7_544
Rh3 Si4 2.4513(12) 3_655
Rh3 Si4 2.4513(12) .
Rh3 Si4 2.4513(12) 11_556
Rh3 Si4 2.4513(12) 9_655
Rh3 Si5 2.6440(16) 14_545
Rh3 Si5 2.6440(16) 13
Rh3 Rh3 2.9157 9_655
Rh3 Rh3 2.9156 9_656
Rh3 Ce1 3.3848(3) 7_544
Rh3 Ce1 3.3848(3) 13
Rh3 Ce1 3.3848(3) 15
Rh3 Ce1 3.3848(3) 5_545
Si4 Rh3 2.4513(12) 9_655
Si4 Si5 2.5218(16) 13
Si4 Si5 2.5218(16) 6_554
Si4 Ce1 3.0118(16) 7_544
Si4 Ce1 3.1360(6) 13_554
Si4 Ce1 3.1360(6) 13
Si5 Rh2 2.4210(11) 3
Si5 Si4 2.5218(16) 13
Si5 Si4 2.5218(16) 15_455
Si5 Rh3 2.6440(16) 13
Si5 Ce1 3.2095(6) 3
Si5 Ce1 3.2196(8) 15_455
Si5 Ce1 3.2196(8) 13
Si6 Rh2 2.4298(3) 9
Si6 Rh2 2.4298(3) 3
Si6 Rh2 2.4298(3) 11_556
Si6 Ce1 3.1420(2) 13
Si6 Ce1 3.1420(2) 15_455
Si6 Ce1 3.1420(2) 5_445
Si6 Ce1 3.1420(2) 7_544
