#------------------------------------------------------------------------------
#$Date: 2021-07-03 04:08:14 +0300 (Sat, 03 Jul 2021) $
#$Revision: 266919 $
#$URL: file:///home/coder/svn-repositories/cod/cif/1/56/39/1563903.cif $
#------------------------------------------------------------------------------
#
# This file is available in the Crystallography Open Database (COD),
# http://www.crystallography.net/
#
# All data on this site have been placed in the public domain by the
# contributors.
#
data_1563903
loop_
_publ_author_name
'Yi, Hong'
'Crudden, Cathleen'
'Nambo, Masakazu'
'Aramaki, Yoshitaka'
'Veinot, Alex J.'
'Ooi, Takashi'
'Levchenko, Tetyana I.'
'Osten, Kimberly M.'
_publ_section_title
;
 Synthesis and enantioseparation of chiral Au13 nanoclusters protected by
 bis-N-heterocyclic carbene ligands
;
_journal_name_full               'Chemical Science'
_journal_paper_doi               10.1039/D1SC03076K
_journal_year                    2021
_chemical_formula_moiety         'C180 H150 Au13 Cl2 N20, 3(Cl)'
_chemical_formula_sum            'C180 H150 Au13 Cl5 N20'
_chemical_formula_weight         5331.01
_space_group_crystal_system      orthorhombic
_space_group_IT_number           33
_space_group_name_Hall           'P 2c -2n'
_space_group_name_H-M_alt        'P n a 21'
_atom_sites_solution_hydrogens   geom
_atom_sites_solution_primary     direct
_atom_sites_solution_secondary   difmap
_audit_creation_method           "'manual editing of SHELXL-2018/3 template"
_audit_update_record
;
2021-04-03 deposited with the CCDC.	2021-06-28 downloaded from the CCDC.
;
_cell_angle_alpha                90
_cell_angle_beta                 90
_cell_angle_gamma                90
_cell_formula_units_Z            4
_cell_length_a                   33.830(4)
_cell_length_b                   28.509(3)
_cell_length_c                   19.234(2)
_cell_measurement_reflns_used    23528
_cell_measurement_temperature    123(2)
_cell_measurement_theta_max      27.5
_cell_measurement_theta_min      3.1
_cell_volume                     18550(4)
_computing_cell_refinement
'CrystalClear-SM Expert 2.1 b46 (Rigaku, 2016)'
_computing_data_collection
'CrystalClear-SM Expert 2.1 b46 (Rigaku, 2016)'
_computing_data_reduction
'CrystalClear-SM Expert 2.1 b46 (Rigaku, 2016)'
_computing_structure_refinement
; SHELXL-2018/3 (Sheldrick, 2018).G. M. Sheldrick, Acta Cryst. 2008,
  A64, 112--122.
;
_computing_structure_solution
; SHELXT-2018/2 (Sheldrick, 2018). G. M. Sheldrick, Acta Cryst. 2015, A71,
  3-8.
;
_diffrn_ambient_temperature      123(2)
_diffrn_detector_area_resol_mean 5.8140
_diffrn_measured_fraction_theta_full 0.993
_diffrn_measured_fraction_theta_max 0.993
_diffrn_measurement_device_type  'Rigaku Pilatus 200K'
_diffrn_measurement_method       'profile data from ω-scans'
_diffrn_radiation_type           MoK\a
_diffrn_radiation_wavelength     0.71075
_diffrn_reflns_av_R_equivalents  0.0637
_diffrn_reflns_av_unetI/netI     0.0763
_diffrn_reflns_Laue_measured_fraction_full 0.993
_diffrn_reflns_Laue_measured_fraction_max 0.993
_diffrn_reflns_limit_h_max       43
_diffrn_reflns_limit_h_min       -43
_diffrn_reflns_limit_k_max       36
_diffrn_reflns_limit_k_min       -36
_diffrn_reflns_limit_l_max       24
_diffrn_reflns_limit_l_min       -24
_diffrn_reflns_number            181504
_diffrn_reflns_point_group_measured_fraction_full 0.972
_diffrn_reflns_point_group_measured_fraction_max 0.972
_diffrn_reflns_theta_full        25.242
_diffrn_reflns_theta_max         27.478
_diffrn_reflns_theta_min         3.073
_diffrn_source                   'Rotating Anode'
_exptl_absorpt_coefficient_mu    10.360
_exptl_absorpt_correction_T_max  1.00
_exptl_absorpt_correction_T_min  0.710
_exptl_absorpt_correction_type   multi-scan
_exptl_absorpt_process_details   '(SADABS, Bruker, 2008)'
_exptl_crystal_colour            red
_exptl_crystal_density_diffrn    1.909
_exptl_crystal_description       chip
_exptl_crystal_F_000             9928
_exptl_crystal_size_max          0.30
_exptl_crystal_size_mid          0.04
_exptl_crystal_size_min          0.01
_refine_diff_density_max         3.689
_refine_diff_density_min         -1.681
_refine_diff_density_rms         0.270
_refine_ls_abs_structure_details
;
 Refined as an inversion twin.
;
_refine_ls_abs_structure_Flack   0.035(12)
_refine_ls_extinction_method     none
_refine_ls_goodness_of_fit_ref   1.095
_refine_ls_hydrogen_treatment    constr
_refine_ls_matrix_type           full
_refine_ls_number_parameters     1649
_refine_ls_number_reflns         41330
_refine_ls_number_restraints     2009
_refine_ls_restrained_S_all      1.075
_refine_ls_R_factor_all          0.0864
_refine_ls_R_factor_gt           0.0488
_refine_ls_shift/su_max          0.001
_refine_ls_shift/su_mean         0.000
_refine_ls_structure_factor_coef Fsqd
_refine_ls_weighting_details
'w=1/[σ²(Fo²)+(0.0252P)²+290.2793P] where P=(Fo²+2Fc²)/3'
_refine_ls_weighting_scheme      calc
_refine_ls_wR_factor_gt          0.0965
_refine_ls_wR_factor_ref         0.1193
_reflns_Friedel_coverage         0.900
_reflns_Friedel_fraction_full    0.950
_reflns_Friedel_fraction_max     0.949
_reflns_number_gt                31152
_reflns_number_total             41330
_reflns_threshold_expression     'I > 2σ(I)'
_cod_data_source_file            d1sc03076k2.cif
_cod_data_source_block           au_a_x_sq
_cod_database_code               1563903
_shelx_space_group_comment
;
The symmetry employed for this shelxl refinement is uniquely defined
by the following loop, which should always be used as a source of
symmetry information in preference to the above space-group names.
They are only intended as comments.
;
loop_
_space_group_symop_operation_xyz
'x, y, z'
'-x, -y, z+1/2'
'-x+1/2, y+1/2, z+1/2'
'x+1/2, -y+1/2, z'
loop_
_atom_site_label
_atom_site_type_symbol
_atom_site_fract_x
_atom_site_fract_y
_atom_site_fract_z
_atom_site_U_iso_or_equiv
_atom_site_adp_type
_atom_site_occupancy
_atom_site_site_symmetry_order
_atom_site_calc_flag
_atom_site_refinement_flags_posn
_atom_site_refinement_flags_adp
_atom_site_refinement_flags_occupancy
_atom_site_disorder_assembly
_atom_site_disorder_group
Au1 Au 0.22923(2) 0.32983(3) 0.47936(4) 0.03164(19) Uani 1 1 d . . . . .
Au2 Au 0.26625(3) 0.32322(3) 0.34601(4) 0.03048(18) Uani 1 1 d . . . . .
Au3 Au 0.28267(2) 0.25320(3) 0.45198(4) 0.02908(18) Uani 1 1 d . . . . .
Au4 Au 0.28430(2) 0.30134(3) 0.58601(4) 0.02830(18) Uani 1 1 d . . . . .
Au5 Au 0.26994(2) 0.39984(3) 0.56151(4) 0.02869(18) Uani 1 1 d . . . . .
Au6 Au 0.25925(2) 0.41341(3) 0.41358(4) 0.03064(18) Uani 1 1 d . . . . .
Au7 Au 0.30910(2) 0.34423(3) 0.46513(4) 0.02527(16) Uani 1 1 d . . . . .
Au8 Au 0.35094(2) 0.36823(3) 0.58462(4) 0.02566(17) Uani 1 1 d . . . . .
Au9 Au 0.33563(2) 0.43560(3) 0.47533(4) 0.02730(17) Uani 1 1 d . . . . .
Au10 Au 0.33392(3) 0.38608(3) 0.34282(4) 0.02863(18) Uani 1 1 d . . . . .
Au11 Au 0.34877(3) 0.28799(3) 0.37134(4) 0.02816(18) Uani 1 1 d . . . . .
Au12 Au 0.35868(2) 0.27614(3) 0.52191(4) 0.02684(17) Uani 1 1 d . . . . .
Au13 Au 0.38861(2) 0.35826(3) 0.45206(4) 0.02763(17) Uani 1 1 d . . . . .
Cl1 Cl 0.16017(16) 0.3195(2) 0.4892(3) 0.0472(16) Uani 1 1 d . . . . .
Cl2 Cl 0.45577(18) 0.3702(3) 0.4578(5) 0.068(2) Uani 1 1 d . . . . .
Cl3 Cl 0.3076(4) 0.0719(4) 0.6209(7) 0.119(4) Uiso 1 1 d . . . . .
Cl4 Cl 0.2750(2) 0.1423(3) 0.1612(4) 0.0572(17) Uiso 1 1 d . . . . .
Cl5 Cl 0.2857(5) 0.3819(6) 0.8735(9) 0.164(6) Uiso 1 1 d . . . . .
N1 N 0.1990(7) 0.3354(8) 0.2416(10) 0.049(4) Uani 1 1 d . U . . .
N2 N 0.2483(6) 0.2958(7) 0.1963(9) 0.038(3) Uani 1 1 d . U . . .
N3 N 0.3361(6) 0.4082(6) 0.1875(9) 0.035(3) Uani 1 1 d . U . . .
N4 N 0.3726(5) 0.4571(6) 0.2474(8) 0.028(3) Uani 1 1 d . U . . .
N5 N 0.2266(5) 0.1741(7) 0.4100(10) 0.040(3) Uani 1 1 d . U . . .
N6 N 0.2833(6) 0.1462(7) 0.4432(10) 0.039(3) Uani 1 1 d . U . . .
N7 N 0.3671(6) 0.2045(7) 0.2767(10) 0.041(4) Uani 1 1 d . U . . .
N8 N 0.3990(6) 0.2675(7) 0.2444(9) 0.038(4) Uani 1 1 d . U . . .
N9 N 0.2315(6) 0.2493(8) 0.6886(10) 0.048(4) Uani 1 1 d . U . . .
N10 N 0.2884(6) 0.2680(7) 0.7359(9) 0.036(3) Uani 1 1 d . U . . .
N11 N 0.3841(5) 0.1923(6) 0.6108(9) 0.034(3) Uani 1 1 d . U . . .
N12 N 0.4227(5) 0.2013(6) 0.5212(9) 0.032(3) Uani 1 1 d . U . . .
N13 N 0.2068(6) 0.4200(8) 0.6712(9) 0.044(4) Uani 1 1 d . U . . .
N14 N 0.2485(6) 0.4782(7) 0.6637(10) 0.042(4) Uani 1 1 d . U . . .
N15 N 0.3630(5) 0.4099(6) 0.7289(9) 0.028(3) Uani 1 1 d . U . . .
N16 N 0.4091(5) 0.3600(7) 0.7045(9) 0.035(3) Uani 1 1 d . U . . .
N17 N 0.1886(5) 0.4799(7) 0.4160(10) 0.038(3) Uani 1 1 d . U . . .
N18 N 0.2327(6) 0.5009(7) 0.3401(9) 0.038(3) Uani 1 1 d . U . . .
N19 N 0.3306(5) 0.5412(6) 0.4803(9) 0.034(3) Uani 1 1 d . U . . .
N20 N 0.3835(6) 0.5185(6) 0.5334(9) 0.036(3) Uani 1 1 d . U . . .
C1 C 0.1528(6) 0.3995(6) 0.2786(11) 0.069(6) Uani 1 1 d G U . . .
C2 C 0.1153(6) 0.4077(7) 0.3053(11) 0.076(6) Uani 1 1 d G U . . .
H2 H 0.102297 0.384010 0.331510 0.092 Uiso 1 1 calc R U . . .
C3 C 0.0968(5) 0.4505(8) 0.2937(12) 0.087(7) Uani 1 1 d G U . . .
H3 H 0.071105 0.456076 0.311990 0.104 Uiso 1 1 calc R U . . .
C4 C 0.1158(7) 0.4851(6) 0.2554(12) 0.096(8) Uani 1 1 d G U . . .
H4 H 0.103126 0.514381 0.247489 0.116 Uiso 1 1 calc R U . . .
C5 C 0.1533(7) 0.4769(7) 0.2287(10) 0.080(7) Uani 1 1 d G U . . .
H5 H 0.166339 0.500621 0.202509 0.096 Uiso 1 1 calc R U . . .
C6 C 0.1719(5) 0.4341(8) 0.2403(10) 0.067(6) Uani 1 1 d G U . . .
H6 H 0.197532 0.428555 0.222028 0.081 Uiso 1 1 calc R U . . .
C7 C 0.1725(9) 0.3555(10) 0.2969(15) 0.060(5) Uani 1 1 d . U . . .
H7A H 0.151988 0.332011 0.308420 0.072 Uiso 1 1 calc R U . . .
H7B H 0.188427 0.360819 0.339394 0.072 Uiso 1 1 calc R U . . .
C8 C 0.2335(7) 0.3164(8) 0.2560(11) 0.039(4) Uani 1 1 d . U . . .
C9 C 0.1886(5) 0.3271(6) 0.1738(6) 0.045(4) Uani 1 1 d G U . . .
C10 C 0.1553(4) 0.3375(6) 0.1343(9) 0.061(5) Uani 1 1 d G U . . .
H10 H 0.134333 0.355208 0.153947 0.073 Uiso 1 1 calc R U . . .
C11 C 0.1528(5) 0.3221(7) 0.0659(8) 0.067(6) Uani 1 1 d G U . . .
H11 H 0.130131 0.329175 0.038806 0.081 Uiso 1 1 calc R U . . .
C12 C 0.1836(5) 0.2962(6) 0.0371(6) 0.064(6) Uani 1 1 d G U . . .
H12 H 0.181886 0.285645 -0.009688 0.076 Uiso 1 1 calc R U . . .
C13 C 0.2168(5) 0.2858(5) 0.0766(7) 0.051(5) Uani 1 1 d G U . . .
H13 H 0.237842 0.268147 0.056959 0.061 Uiso 1 1 calc R U . . .
C14 C 0.2193(4) 0.3013(5) 0.1450(7) 0.038(4) Uani 1 1 d G U . . .
C15 C 0.2847(8) 0.2695(8) 0.1914(11) 0.041(4) Uani 1 1 d . U . . .
H15A H 0.278370 0.235801 0.185678 0.049 Uiso 1 1 calc R U . . .
H15B H 0.299682 0.273055 0.235314 0.049 Uiso 1 1 calc R U . . .
C16 C 0.3106(4) 0.2851(5) 0.1312(7) 0.039(4) Uani 1 1 d G U . . .
C17 C 0.3214(5) 0.2503(4) 0.0845(8) 0.042(5) Uani 1 1 d G U . . .
H17 H 0.310362 0.219758 0.088350 0.051 Uiso 1 1 calc R U . . .
C18 C 0.3485(5) 0.2600(4) 0.0321(7) 0.045(5) Uani 1 1 d G U . . .
H18 H 0.355979 0.236191 0.000202 0.054 Uiso 1 1 calc R U . . .
C19 C 0.3648(4) 0.3047(5) 0.0265(7) 0.043(5) Uani 1 1 d G U . . .
H19 H 0.383280 0.311335 -0.009268 0.052 Uiso 1 1 calc R U . . .
C20 C 0.3539(5) 0.3395(4) 0.0733(7) 0.042(5) Uani 1 1 d G U . . .
H20 H 0.364965 0.370046 0.069410 0.050 Uiso 1 1 calc R U . . .
C21 C 0.3268(5) 0.3298(4) 0.1256(7) 0.038(4) Uani 1 1 d G U . . .
C22 C 0.3096(7) 0.3690(8) 0.1706(11) 0.036(4) Uani 1 1 d . U . . .
H22A H 0.286161 0.381881 0.146580 0.044 Uiso 1 1 calc R U . . .
H22B H 0.300394 0.354984 0.214827 0.044 Uiso 1 1 calc R U . . .
C23 C 0.3503(7) 0.4191(8) 0.2541(11) 0.032(4) Uani 1 1 d . U . . .
C24 C 0.3486(4) 0.4441(4) 0.1413(6) 0.033(4) Uani 1 1 d G U . . .
C25 C 0.3408(4) 0.4534(5) 0.0717(6) 0.041(5) Uani 1 1 d G U . . .
H25 H 0.323710 0.433471 0.046079 0.050 Uiso 1 1 calc R U . . .
C26 C 0.3581(5) 0.4921(5) 0.0397(5) 0.041(5) Uani 1 1 d G U . . .
H26 H 0.352730 0.498476 -0.007887 0.050 Uiso 1 1 calc R U . . .
C27 C 0.3831(4) 0.5213(4) 0.0772(7) 0.043(5) Uani 1 1 d G U . . .
H27 H 0.394867 0.547677 0.055279 0.051 Uiso 1 1 calc R U . . .
C28 C 0.3909(4) 0.5119(5) 0.1468(6) 0.035(4) Uani 1 1 d G U . . .
H28 H 0.407985 0.531873 0.172411 0.042 Uiso 1 1 calc R U . . .
C29 C 0.3736(4) 0.4733(5) 0.1788(5) 0.031(4) Uani 1 1 d G U . . .
C30 C 0.3905(7) 0.4820(8) 0.3075(11) 0.037(4) Uani 1 1 d . U . . .
H30A H 0.378442 0.513502 0.310956 0.045 Uiso 1 1 calc R U . . .
H30B H 0.383716 0.464649 0.350511 0.045 Uiso 1 1 calc R U . . .
C31 C 0.4336(4) 0.4873(6) 0.3043(9) 0.041(4) Uani 1 1 d G U . . .
C32 C 0.4509(5) 0.5315(5) 0.3006(9) 0.056(5) Uani 1 1 d G U . . .
H32 H 0.434773 0.558564 0.295393 0.067 Uiso 1 1 calc R U . . .
C33 C 0.4917(5) 0.5361(6) 0.3044(10) 0.067(6) Uani 1 1 d G U . . .
H33 H 0.503543 0.566234 0.301784 0.081 Uiso 1 1 calc R U . . .
C34 C 0.5153(4) 0.4964(8) 0.3119(11) 0.081(7) Uani 1 1 d G U . . .
H34 H 0.543227 0.499560 0.314525 0.097 Uiso 1 1 calc R U . . .
C35 C 0.4980(5) 0.4523(7) 0.3157(11) 0.080(7) Uani 1 1 d G U . . .
H35 H 0.514141 0.425213 0.320876 0.096 Uiso 1 1 calc R U . . .
C36 C 0.4572(5) 0.4477(5) 0.3119(10) 0.061(6) Uani 1 1 d G U . . .
H36 H 0.445371 0.417542 0.314485 0.073 Uiso 1 1 calc R U . . .
C37 C 0.1777(5) 0.2120(6) 0.3317(6) 0.044(4) Uani 1 1 d G U . . .
C38 C 0.1406(5) 0.2324(6) 0.3249(7) 0.054(5) Uani 1 1 d G U . . .
H38 H 0.126041 0.241110 0.365128 0.065 Uiso 1 1 calc R U . . .
C39 C 0.1247(4) 0.2402(6) 0.2592(9) 0.060(6) Uani 1 1 d G U . . .
H39 H 0.099376 0.254108 0.254538 0.072 Uiso 1 1 calc R U . . .
C40 C 0.1460(5) 0.2275(6) 0.2003(7) 0.054(5) Uani 1 1 d G U . . .
H40 H 0.135190 0.232747 0.155389 0.064 Uiso 1 1 calc R U . . .
C41 C 0.1831(5) 0.2071(6) 0.2071(6) 0.045(5) Uani 1 1 d G U . . .
H41 H 0.197670 0.198389 0.166830 0.054 Uiso 1 1 calc R U . . .
C42 C 0.1990(4) 0.1993(6) 0.2728(8) 0.045(5) Uani 1 1 d G U . . .
H42 H 0.224335 0.185390 0.277419 0.054 Uiso 1 1 calc R U . . .
C43 C 0.1931(7) 0.2072(9) 0.4035(12) 0.044(4) Uani 1 1 d . U . . .
H43A H 0.201730 0.238464 0.420163 0.053 Uiso 1 1 calc R U . . .
H43B H 0.171395 0.196532 0.434155 0.053 Uiso 1 1 calc R U . . .
C44 C 0.2628(7) 0.1857(8) 0.4346(11) 0.033(3) Uani 1 1 d . U . . .
C45 C 0.2252(5) 0.1259(4) 0.4015(8) 0.042(4) Uani 1 1 d G U . . .
C46 C 0.1953(4) 0.0956(6) 0.3808(8) 0.051(5) Uani 1 1 d G U . . .
H46 H 0.170863 0.107886 0.364409 0.061 Uiso 1 1 calc R U . . .
C47 C 0.2010(5) 0.0474(5) 0.3840(9) 0.058(5) Uani 1 1 d G U . . .
H47 H 0.180507 0.026691 0.369827 0.069 Uiso 1 1 calc R U . . .
C48 C 0.2367(5) 0.0294(4) 0.4080(9) 0.062(5) Uani 1 1 d G U . . .
H48 H 0.240594 -0.003522 0.410152 0.074 Uiso 1 1 calc R U . . .
C49 C 0.2666(4) 0.0597(5) 0.4287(8) 0.049(5) Uani 1 1 d G U . . .
H49 H 0.291038 0.047460 0.445061 0.059 Uiso 1 1 calc R U . . .
C50 C 0.2609(4) 0.1080(5) 0.4255(8) 0.038(4) Uani 1 1 d G U . . .
C51 C 0.3236(7) 0.1450(8) 0.4717(11) 0.041(4) Uani 1 1 d . U . . .
H51A H 0.322689 0.129375 0.517660 0.049 Uiso 1 1 calc R U . . .
H51B H 0.332365 0.177751 0.479568 0.049 Uiso 1 1 calc R U . . .
C52 C 0.3550(4) 0.1201(5) 0.4269(8) 0.039(4) Uani 1 1 d G U . . .
C53 C 0.3741(5) 0.0824(5) 0.4579(7) 0.055(5) Uani 1 1 d G U . . .
H53 H 0.365446 0.071138 0.501860 0.066 Uiso 1 1 calc R U . . .
C54 C 0.4059(5) 0.0611(4) 0.4247(9) 0.054(5) Uani 1 1 d G U . . .
H54 H 0.418925 0.035328 0.445862 0.064 Uiso 1 1 calc R U . . .
C55 C 0.4185(4) 0.0776(5) 0.3604(9) 0.055(5) Uani 1 1 d G U . . .
H55 H 0.440214 0.063053 0.337649 0.066 Uiso 1 1 calc R U . . .
C56 C 0.3994(5) 0.1153(5) 0.3294(7) 0.046(5) Uani 1 1 d G U . . .
H56 H 0.408023 0.126589 0.285432 0.055 Uiso 1 1 calc R U . . .
C57 C 0.3676(4) 0.1366(4) 0.3626(8) 0.044(4) Uani 1 1 d G U . . .
C58 C 0.3419(7) 0.1732(8) 0.3194(12) 0.041(4) Uani 1 1 d . U . . .
H58A H 0.323464 0.156001 0.288656 0.049 Uiso 1 1 calc R U . . .
H58B H 0.325978 0.192442 0.351856 0.049 Uiso 1 1 calc R U . . .
C59 C 0.3754(7) 0.2495(8) 0.2943(11) 0.032(4) Uani 1 1 d . U . . .
C60 C 0.3833(5) 0.1949(6) 0.2130(7) 0.046(5) Uani 1 1 d G U . . .
C61 C 0.3820(5) 0.1554(5) 0.1707(8) 0.055(6) Uani 1 1 d G U . . .
H61 H 0.366651 0.129019 0.184104 0.066 Uiso 1 1 calc R U . . .
C62 C 0.4030(6) 0.1546(5) 0.1086(8) 0.062(6) Uani 1 1 d G U . . .
H62 H 0.402109 0.127602 0.079667 0.074 Uiso 1 1 calc R U . . .
C63 C 0.4255(5) 0.1932(6) 0.0889(7) 0.061(6) Uani 1 1 d G U . . .
H63 H 0.439869 0.192636 0.046528 0.073 Uiso 1 1 calc R U . . .
C64 C 0.4268(5) 0.2327(5) 0.1313(8) 0.051(5) Uani 1 1 d G U . . .
H64 H 0.442171 0.259087 0.117826 0.061 Uiso 1 1 calc R U . . .
C65 C 0.4058(5) 0.2335(5) 0.1933(7) 0.041(4) Uani 1 1 d G U . . .
C66 C 0.4133(8) 0.3135(9) 0.2388(13) 0.047(4) Uani 1 1 d . U . . .
H66A H 0.401462 0.332418 0.276564 0.056 Uiso 1 1 calc R U . . .
H66B H 0.403939 0.326761 0.194147 0.056 Uiso 1 1 calc R U . . .
C67 C 0.4564(4) 0.3190(7) 0.2419(10) 0.053(5) Uani 1 1 d G U . . .
C68 C 0.4773(6) 0.3009(7) 0.2981(9) 0.071(6) Uani 1 1 d G U . . .
H68 H 0.463812 0.283454 0.332990 0.085 Uiso 1 1 calc R U . . .
C69 C 0.5178(6) 0.3083(8) 0.3034(11) 0.083(6) Uani 1 1 d G U . . .
H69 H 0.531999 0.295892 0.341786 0.100 Uiso 1 1 calc R U . . .
C70 C 0.5374(4) 0.3338(8) 0.2524(13) 0.088(7) Uani 1 1 d G U . . .
H70 H 0.565101 0.338810 0.255970 0.106 Uiso 1 1 calc R U . . .
C71 C 0.5166(6) 0.3519(8) 0.1962(11) 0.082(6) Uani 1 1 d G U . . .
H71 H 0.530016 0.369291 0.161357 0.099 Uiso 1 1 calc R U . . .
C72 C 0.4761(6) 0.3445(7) 0.1910(9) 0.072(6) Uani 1 1 d G U . . .
H72 H 0.461828 0.356853 0.152559 0.086 Uiso 1 1 calc R U . . .
C73 C 0.1927(6) 0.1988(5) 0.6101(10) 0.057(5) Uani 1 1 d G U . . .
C74 C 0.1561(5) 0.1873(6) 0.5822(11) 0.068(5) Uani 1 1 d G U . . .
H74 H 0.135045 0.209380 0.583939 0.082 Uiso 1 1 calc R U . . .
C75 C 0.1502(5) 0.1437(7) 0.5518(10) 0.077(6) Uani 1 1 d G U . . .
H75 H 0.125139 0.135853 0.532750 0.092 Uiso 1 1 calc R U . . .
C76 C 0.1810(7) 0.1114(6) 0.5493(10) 0.074(6) Uani 1 1 d G U . . .
H76 H 0.176957 0.081560 0.528486 0.088 Uiso 1 1 calc R U . . .
C77 C 0.2176(6) 0.1228(6) 0.5771(11) 0.076(6) Uani 1 1 d G U . . .
H77 H 0.238681 0.100793 0.575411 0.091 Uiso 1 1 calc R U . . .
C78 C 0.2235(5) 0.1665(7) 0.6075(10) 0.062(5) Uani 1 1 d G U . . .
H78 H 0.248588 0.174319 0.626600 0.075 Uiso 1 1 calc R U . . .
C79 C 0.1993(8) 0.2472(10) 0.6409(14) 0.052(4) Uani 1 1 d . U . . .
H79A H 0.204257 0.269661 0.602589 0.063 Uiso 1 1 calc R U . . .
H79B H 0.174885 0.257202 0.665028 0.063 Uiso 1 1 calc R U . . .
C80 C 0.2666(7) 0.2701(8) 0.6770(11) 0.033(4) Uani 1 1 d . U . . .
C81 C 0.2317(5) 0.2324(7) 0.7560(7) 0.054(5) Uani 1 1 d G U . . .
C82 C 0.2033(4) 0.2087(7) 0.7946(9) 0.066(6) Uani 1 1 d G U . . .
H82 H 0.178796 0.200422 0.773956 0.080 Uiso 1 1 calc R U . . .
C83 C 0.2109(5) 0.1970(7) 0.8635(9) 0.072(7) Uani 1 1 d G U . . .
H83 H 0.191463 0.180762 0.889954 0.086 Uiso 1 1 calc R U . . .
C84 C 0.2468(6) 0.2091(7) 0.8938(7) 0.070(7) Uani 1 1 d G U . . .
H84 H 0.251896 0.201077 0.940902 0.084 Uiso 1 1 calc R U . . .
C85 C 0.2751(4) 0.2328(7) 0.8552(8) 0.057(6) Uani 1 1 d G U . . .
H85 H 0.299664 0.241053 0.875853 0.068 Uiso 1 1 calc R U . . .
C86 C 0.2676(4) 0.2445(6) 0.7863(8) 0.043(4) Uani 1 1 d G U . . .
C87 C 0.3266(7) 0.2891(9) 0.7461(12) 0.042(4) Uani 1 1 d . U . . .
H87A H 0.323524 0.315448 0.779149 0.050 Uiso 1 1 calc R U . . .
H87B H 0.335332 0.302529 0.701183 0.050 Uiso 1 1 calc R U . . .
C88 C 0.3587(4) 0.2576(5) 0.7726(7) 0.037(4) Uani 1 1 d G U . . .
C89 C 0.3757(4) 0.2706(5) 0.8355(7) 0.038(4) Uani 1 1 d G U . . .
H89 H 0.364832 0.295895 0.861432 0.045 Uiso 1 1 calc R U . . .
C90 C 0.4085(4) 0.2466(6) 0.8606(6) 0.045(5) Uani 1 1 d G U . . .
H90 H 0.420039 0.255455 0.903614 0.054 Uiso 1 1 calc R U . . .
C91 C 0.4243(4) 0.2095(5) 0.8227(8) 0.046(5) Uani 1 1 d G U . . .
H91 H 0.446703 0.193132 0.839831 0.055 Uiso 1 1 calc R U . . .
C92 C 0.4073(5) 0.1966(5) 0.7598(7) 0.049(5) Uani 1 1 d G U . . .
H92 H 0.418160 0.171249 0.733866 0.059 Uiso 1 1 calc R U . . .
C93 C 0.3745(4) 0.2206(5) 0.7347(6) 0.040(4) Uani 1 1 d G U . . .
C94 C 0.3557(7) 0.2030(9) 0.6640(11) 0.039(4) Uani 1 1 d . U . . .
H94A H 0.339729 0.174572 0.673446 0.047 Uiso 1 1 calc R U . . .
H94B H 0.337495 0.227509 0.646392 0.047 Uiso 1 1 calc R U . . .
C95 C 0.3923(6) 0.2228(7) 0.5563(10) 0.029(3) Uani 1 1 d . U . . .
C96 C 0.4067(4) 0.1517(5) 0.6059(8) 0.040(4) Uani 1 1 d G U . . .
C97 C 0.4077(5) 0.1104(5) 0.6441(7) 0.050(5) Uani 1 1 d G U . . .
H97 H 0.389903 0.105878 0.681682 0.060 Uiso 1 1 calc R U . . .
C98 C 0.4349(5) 0.0756(4) 0.6274(9) 0.056(5) Uani 1 1 d G U . . .
H98 H 0.435679 0.047347 0.653541 0.068 Uiso 1 1 calc R U . . .
C99 C 0.4610(5) 0.0822(5) 0.5725(9) 0.058(6) Uani 1 1 d G U . . .
H99 H 0.479633 0.058442 0.561054 0.069 Uiso 1 1 calc R U . . .
C100 C 0.4600(4) 0.1236(5) 0.5343(7) 0.042(4) Uani 1 1 d G U . . .
H100 H 0.477812 0.128067 0.496709 0.050 Uiso 1 1 calc R U . . .
C101 C 0.4328(5) 0.1583(4) 0.5510(7) 0.038(4) Uani 1 1 d G U . . .
C102 C 0.4407(7) 0.2181(8) 0.4573(12) 0.041(4) Uani 1 1 d . U . . .
H10A H 0.428177 0.248219 0.444098 0.050 Uiso 1 1 calc R U . . .
H10B H 0.435179 0.195255 0.419705 0.050 Uiso 1 1 calc R U . . .
C103 C 0.4833(4) 0.2249(7) 0.4625(10) 0.048(5) Uani 1 1 d G U . . .
C104 C 0.4972(5) 0.2553(6) 0.5134(10) 0.068(6) Uani 1 1 d G U . . .
H104 H 0.479023 0.271979 0.541939 0.081 Uiso 1 1 calc R U . . .
C105 C 0.5376(6) 0.2614(7) 0.5227(11) 0.084(7) Uani 1 1 d G U . . .
H105 H 0.547086 0.282156 0.557502 0.100 Uiso 1 1 calc R U . . .
C106 C 0.5641(4) 0.2370(8) 0.4810(12) 0.089(8) Uani 1 1 d G U . . .
H106 H 0.591775 0.241156 0.487293 0.107 Uiso 1 1 calc R U . . .
C107 C 0.5503(5) 0.2066(8) 0.4300(11) 0.082(7) Uani 1 1 d G U . . .
H107 H 0.568403 0.189978 0.401521 0.099 Uiso 1 1 calc R U . . .
C108 C 0.5098(5) 0.2006(7) 0.4208(9) 0.074(7) Uani 1 1 d G U . . .
H108 H 0.500341 0.179801 0.385957 0.089 Uiso 1 1 calc R U . . .
C109 C 0.1728(6) 0.3503(8) 0.7173(9) 0.072(6) Uani 1 1 d G U . . .
C110 C 0.1355(6) 0.3300(9) 0.7207(10) 0.090(8) Uani 1 1 d G U . . .
H110 H 0.117968 0.332316 0.682245 0.107 Uiso 1 1 calc R U . . .
C111 C 0.1238(6) 0.3062(9) 0.7804(13) 0.103(9) Uani 1 1 d G U . . .
H111 H 0.098303 0.292293 0.782671 0.124 Uiso 1 1 calc R U . . .
C112 C 0.1494(7) 0.3027(9) 0.8366(11) 0.107(9) Uani 1 1 d G U . . .
H112 H 0.141434 0.286468 0.877389 0.129 Uiso 1 1 calc R U . . .
C113 C 0.1867(7) 0.3230(9) 0.8332(10) 0.091(8) Uani 1 1 d G U . . .
H113 H 0.204230 0.320666 0.871682 0.109 Uiso 1 1 calc R U . . .
C114 C 0.1984(5) 0.3468(8) 0.7736(11) 0.071(6) Uani 1 1 d G U . . .
H114 H 0.223895 0.360690 0.771256 0.085 Uiso 1 1 calc R U . . .
C115 C 0.1859(9) 0.3781(11) 0.6547(15) 0.061(5) Uani 1 1 d . U . . .
H11A H 0.202974 0.357950 0.625501 0.073 Uiso 1 1 calc R U . . .
H11B H 0.162249 0.386336 0.626880 0.073 Uiso 1 1 calc R U . . .
C116 C 0.2396(7) 0.4373(9) 0.6376(11) 0.036(4) Uani 1 1 d . U . . .
C117 C 0.1940(5) 0.4538(5) 0.7165(8) 0.052(5) Uani 1 1 d G U . . .
C118 C 0.1611(5) 0.4568(6) 0.7595(9) 0.059(6) Uani 1 1 d G U . . .
H118 H 0.143189 0.431245 0.762552 0.071 Uiso 1 1 calc R U . . .
C119 C 0.1544(5) 0.4973(7) 0.7981(9) 0.070(6) Uani 1 1 d G U . . .
H119 H 0.131906 0.499355 0.827479 0.084 Uiso 1 1 calc R U . . .
C120 C 0.1806(5) 0.5347(6) 0.7936(9) 0.062(6) Uani 1 1 d G U . . .
H120 H 0.176032 0.562360 0.819977 0.074 Uiso 1 1 calc R U . . .
C121 C 0.2135(5) 0.5317(5) 0.7506(9) 0.060(5) Uani 1 1 d G U . . .
H121 H 0.231441 0.557256 0.747548 0.072 Uiso 1 1 calc R U . . .
C122 C 0.2202(4) 0.4912(6) 0.7120(8) 0.042(4) Uani 1 1 d G U . . .
C123 C 0.2788(7) 0.5095(8) 0.6355(12) 0.037(4) Uani 1 1 d . U . . .
H12A H 0.265594 0.538177 0.618337 0.044 Uiso 1 1 calc R U . . .
H12B H 0.291042 0.493827 0.594919 0.044 Uiso 1 1 calc R U . . .
C124 C 0.3120(4) 0.5244(5) 0.6852(8) 0.037(4) Uani 1 1 d G U . . .
C125 C 0.3191(4) 0.5723(4) 0.6882(8) 0.043(4) Uani 1 1 d G U . . .
H125 H 0.300784 0.593634 0.668023 0.051 Uiso 1 1 calc R U . . .
C126 C 0.3530(5) 0.5892(3) 0.7206(9) 0.047(5) Uani 1 1 d G U . . .
H126 H 0.357803 0.621970 0.722601 0.057 Uiso 1 1 calc R U . . .
C127 C 0.3798(4) 0.5580(5) 0.7500(8) 0.047(5) Uani 1 1 d G U . . .
H127 H 0.402919 0.569522 0.772208 0.057 Uiso 1 1 calc R U . . .
C128 C 0.3727(4) 0.5100(4) 0.7471(8) 0.040(4) Uani 1 1 d G U . . .
H128 H 0.391014 0.488737 0.767236 0.048 Uiso 1 1 calc R U . . .
C129 C 0.3388(4) 0.4932(3) 0.7147(8) 0.035(4) Uani 1 1 d G U . . .
C130 C 0.3282(7) 0.4396(8) 0.7185(12) 0.037(4) Uani 1 1 d . U . . .
H13A H 0.309442 0.434387 0.757279 0.045 Uiso 1 1 calc R U . . .
H13B H 0.314845 0.430194 0.674866 0.045 Uiso 1 1 calc R U . . .
C131 C 0.3785(6) 0.3818(7) 0.6797(10) 0.024(3) Uani 1 1 d . U . . .
C132 C 0.3836(4) 0.4035(5) 0.7898(6) 0.032(4) Uani 1 1 d G U . . .
C133 C 0.3785(4) 0.4198(5) 0.8573(7) 0.042(4) Uani 1 1 d G U . . .
H133 H 0.357646 0.440943 0.867699 0.050 Uiso 1 1 calc R U . . .
C134 C 0.4041(5) 0.4053(5) 0.9096(5) 0.048(5) Uani 1 1 d G U . . .
H134 H 0.400677 0.416425 0.955744 0.058 Uiso 1 1 calc R U . . .
C135 C 0.4347(4) 0.3743(5) 0.8944(6) 0.044(4) Uani 1 1 d G U . . .
H135 H 0.452148 0.364387 0.930137 0.052 Uiso 1 1 calc R U . . .
C136 C 0.4397(4) 0.3580(5) 0.8269(7) 0.046(5) Uani 1 1 d G U . . .
H136 H 0.460589 0.336866 0.816486 0.055 Uiso 1 1 calc R U . . .
C137 C 0.4141(4) 0.3726(5) 0.7746(5) 0.034(4) Uani 1 1 d G U . . .
C138 C 0.4342(7) 0.3250(8) 0.6692(11) 0.036(4) Uani 1 1 d . U . . .
H13C H 0.424969 0.320861 0.620735 0.044 Uiso 1 1 calc R U . . .
H13D H 0.431702 0.294414 0.693242 0.044 Uiso 1 1 calc R U . . .
C139 C 0.4769(3) 0.3397(6) 0.6687(9) 0.043(4) Uani 1 1 d G U . . .
C140 C 0.4870(4) 0.3817(5) 0.6365(9) 0.051(5) Uani 1 1 d G U . . .
H140 H 0.466901 0.401339 0.617952 0.061 Uiso 1 1 calc R U . . .
C141 C 0.5264(5) 0.3949(5) 0.6313(9) 0.061(5) Uani 1 1 d G U . . .
H141 H 0.533310 0.423534 0.609270 0.073 Uiso 1 1 calc R U . . .
C142 C 0.5558(4) 0.3661(7) 0.6584(10) 0.065(6) Uani 1 1 d G U . . .
H142 H 0.582757 0.375096 0.654903 0.078 Uiso 1 1 calc R U . . .
C143 C 0.5457(4) 0.3241(6) 0.6907(9) 0.063(6) Uani 1 1 d G U . . .
H143 H 0.565796 0.304463 0.709219 0.075 Uiso 1 1 calc R U . . .
C144 C 0.5063(5) 0.3109(5) 0.6959(9) 0.054(5) Uani 1 1 d G U . . .
H144 H 0.499387 0.282268 0.717903 0.065 Uiso 1 1 calc R U . . .
C145 C 0.1499(5) 0.4744(6) 0.5270(8) 0.054(5) Uani 1 1 d G U . . .
C146 C 0.1705(4) 0.5120(6) 0.5555(9) 0.050(5) Uani 1 1 d G U . . .
H146 H 0.195485 0.520707 0.537020 0.061 Uiso 1 1 calc R U . . .
C147 C 0.1545(5) 0.5369(6) 0.6109(9) 0.062(6) Uani 1 1 d G U . . .
H147 H 0.168534 0.562555 0.630328 0.074 Uiso 1 1 calc R U . . .
C148 C 0.1179(6) 0.5241(7) 0.6379(9) 0.075(7) Uani 1 1 d G U . . .
H148 H 0.106957 0.541124 0.675735 0.090 Uiso 1 1 calc R U . . .
C149 C 0.0973(5) 0.4865(8) 0.6094(10) 0.081(7) Uani 1 1 d G U . . .
H149 H 0.072331 0.477845 0.627833 0.097 Uiso 1 1 calc R U . . .
C150 C 0.1133(5) 0.4617(6) 0.5540(10) 0.071(7) Uani 1 1 d G U . . .
H150 H 0.099281 0.435997 0.534524 0.085 Uiso 1 1 calc R U . . .
C151 C 0.1660(7) 0.4510(9) 0.4644(14) 0.051(4) Uani 1 1 d . U . . .
H15C H 0.183211 0.424977 0.479955 0.061 Uiso 1 1 calc R U . . .
H15D H 0.143642 0.436979 0.438617 0.061 Uiso 1 1 calc R U . . .
C152 C 0.2227(7) 0.4685(8) 0.3866(12) 0.037(4) Uani 1 1 d . U . . .
C153 C 0.1763(5) 0.5233(5) 0.3905(9) 0.046(4) Uani 1 1 d G U . . .
C154 C 0.1431(4) 0.5509(6) 0.4027(9) 0.059(6) Uani 1 1 d G U . . .
H154 H 0.123550 0.540728 0.434801 0.070 Uiso 1 1 calc R U . . .
C155 C 0.1385(5) 0.5932(6) 0.3679(10) 0.073(7) Uani 1 1 d G U . . .
H155 H 0.115850 0.612070 0.376188 0.088 Uiso 1 1 calc R U . . .
C156 C 0.1671(6) 0.6081(5) 0.3209(10) 0.068(6) Uani 1 1 d G U . . .
H156 H 0.164019 0.637034 0.297107 0.082 Uiso 1 1 calc R U . . .
C157 C 0.2003(5) 0.5805(6) 0.3087(9) 0.059(6) Uani 1 1 d G U . . .
H157 H 0.219888 0.590656 0.276638 0.071 Uiso 1 1 calc R U . . .
C158 C 0.2049(4) 0.5381(6) 0.3436(9) 0.046(4) Uani 1 1 d G U . . .
C159 C 0.2670(7) 0.5005(9) 0.2935(12) 0.044(4) Uani 1 1 d . U . . .
H15E H 0.257130 0.497573 0.245286 0.052 Uiso 1 1 calc R U . . .
H15F H 0.282568 0.471860 0.303663 0.052 Uiso 1 1 calc R U . . .
C160 C 0.2953(4) 0.5426(5) 0.2961(7) 0.043(4) Uani 1 1 d G U . . .
C161 C 0.3070(5) 0.5596(5) 0.2316(6) 0.043(5) Uani 1 1 d G U . . .
H161 H 0.294645 0.548344 0.190501 0.052 Uiso 1 1 calc R U . . .
C162 C 0.3366(5) 0.5933(6) 0.2273(6) 0.049(5) Uani 1 1 d G U . . .
H162 H 0.344570 0.604937 0.183176 0.059 Uiso 1 1 calc R U . . .
C163 C 0.3546(4) 0.6098(5) 0.2874(7) 0.043(5) Uani 1 1 d G U . . .
H163 H 0.374887 0.632764 0.284449 0.052 Uiso 1 1 calc R U . . .
C164 C 0.3430(4) 0.5927(5) 0.3519(6) 0.038(4) Uani 1 1 d G U . . .
H164 H 0.355279 0.603999 0.393048 0.046 Uiso 1 1 calc R U . . .
C165 C 0.3133(4) 0.5591(5) 0.3563(6) 0.038(4) Uani 1 1 d G U . . .
C166 C 0.2984(7) 0.5429(8) 0.4277(10) 0.036(4) Uani 1 1 d . U . . .
H16A H 0.277567 0.564670 0.443993 0.043 Uiso 1 1 calc R U . . .
H16B H 0.286487 0.511343 0.423222 0.043 Uiso 1 1 calc R U . . .
C167 C 0.3522(7) 0.5033(8) 0.4932(11) 0.037(4) Uani 1 1 d . U . . .
C168 C 0.3464(4) 0.5798(4) 0.5117(8) 0.038(4) Uani 1 1 d G U . . .
C169 C 0.3349(4) 0.6266(5) 0.5143(8) 0.047(5) Uani 1 1 d G U . . .
H169 H 0.311024 0.636214 0.492641 0.056 Uiso 1 1 calc R U . . .
C170 C 0.3584(5) 0.6592(4) 0.5485(8) 0.047(5) Uani 1 1 d G U . . .
H170 H 0.350557 0.691209 0.550274 0.057 Uiso 1 1 calc R U . . .
C171 C 0.3934(5) 0.6451(4) 0.5802(8) 0.048(5) Uani 1 1 d G U . . .
H171 H 0.409430 0.667454 0.603551 0.058 Uiso 1 1 calc R U . . .
C172 C 0.4049(4) 0.5983(5) 0.5776(8) 0.045(5) Uani 1 1 d G U . . .
H172 H 0.428771 0.588704 0.599195 0.054 Uiso 1 1 calc R U . . .
C173 C 0.3814(4) 0.5657(4) 0.5433(8) 0.037(4) Uani 1 1 d G U . . .
C174 C 0.4123(7) 0.4853(8) 0.5628(13) 0.040(4) Uani 1 1 d . U . . .
H17A H 0.410714 0.455335 0.537001 0.048 Uiso 1 1 calc R U . . .
H17B H 0.405322 0.478955 0.611867 0.048 Uiso 1 1 calc R U . . .
C175 C 0.4549(3) 0.5038(5) 0.5594(8) 0.036(4) Uani 1 1 d G U . . .
C176 C 0.4725(5) 0.5149(6) 0.4962(6) 0.049(5) Uani 1 1 d G U . . .
H176 H 0.458690 0.509333 0.453980 0.059 Uiso 1 1 calc R U . . .
C177 C 0.5103(5) 0.5340(6) 0.4948(7) 0.056(5) Uani 1 1 d G U . . .
H177 H 0.522299 0.541538 0.451621 0.068 Uiso 1 1 calc R U . . .
C178 C 0.5304(4) 0.5421(5) 0.5566(9) 0.046(5) Uani 1 1 d G U . . .
H178 H 0.556249 0.555180 0.555671 0.055 Uiso 1 1 calc R U . . .
C179 C 0.5128(4) 0.5311(6) 0.6198(7) 0.046(5) Uani 1 1 d G U . . .
H179 H 0.526592 0.536617 0.662080 0.055 Uiso 1 1 calc R U . . .
C180 C 0.4750(4) 0.5119(5) 0.6212(6) 0.040(4) Uani 1 1 d G U . . .
H180 H 0.462984 0.504412 0.664440 0.048 Uiso 1 1 calc R U . . .
loop_
_atom_type_symbol
_atom_type_description
_atom_type_scat_dispersion_real
_atom_type_scat_dispersion_imag
_atom_type_scat_source
C C 0.0033 0.0016 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
H H 0.0000 0.0000 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
N N 0.0061 0.0033 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
Cl Cl 0.1484 0.1585 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
Au Au -2.0133 8.8022 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
loop_
_geom_angle_atom_site_label_1
_geom_angle_atom_site_label_2
_geom_angle_atom_site_label_3
_geom_angle
_geom_angle_site_symmetry_1
_geom_angle_site_symmetry_3
_geom_angle_publ_flag
Cl1 Au1 Au7 178.18(18) . . ?
Cl1 Au1 Au2 119.76(16) . . ?
Au7 Au1 Au2 59.32(3) . . ?
Cl1 Au1 Au6 119.14(17) . . ?
Au7 Au1 Au6 59.08(3) . . ?
Au2 Au1 Au6 60.44(3) . . ?
Cl1 Au1 Au3 122.66(17) . . ?
Au7 Au1 Au3 58.56(3) . . ?
Au2 Au1 Au3 60.79(3) . . ?
Au6 Au1 Au3 108.97(4) . . ?
Cl1 Au1 Au4 123.09(17) . . ?
Au7 Au1 Au4 58.55(3) . . ?
Au2 Au1 Au4 109.63(4) . . ?
Au6 Au1 Au4 108.48(4) . . ?
Au3 Au1 Au4 60.81(3) . . ?
Cl1 Au1 Au5 120.88(16) . . ?
Au7 Au1 Au5 58.88(3) . . ?
Au2 Au1 Au5 109.06(4) . . ?
Au6 Au1 Au5 60.13(3) . . ?
Au3 Au1 Au5 108.89(4) . . ?
Au4 Au1 Au5 59.94(3) . . ?
C8 Au2 Au7 173.0(7) . . ?
C8 Au2 Au1 121.6(7) . . ?
Au7 Au2 Au1 58.29(3) . . ?
C8 Au2 Au6 114.7(7) . . ?
Au7 Au2 Au6 58.66(3) . . ?
Au1 Au2 Au6 60.16(3) . . ?
C8 Au2 Au3 128.7(7) . . ?
Au7 Au2 Au3 57.98(3) . . ?
Au1 Au2 Au3 60.01(3) . . ?
Au6 Au2 Au3 108.13(4) . . ?
C8 Au2 Au10 117.6(7) . . ?
Au7 Au2 Au10 58.23(3) . . ?
Au1 Au2 Au10 108.84(4) . . ?
Au6 Au2 Au10 61.70(3) . . ?
Au3 Au2 Au10 106.71(4) . . ?
C8 Au2 Au11 127.0(7) . . ?
Au7 Au2 Au11 56.88(3) . . ?
Au1 Au2 Au11 106.45(3) . . ?
Au6 Au2 Au11 107.48(3) . . ?
Au3 Au2 Au11 58.63(3) . . ?
Au10 Au2 Au11 58.55(3) . . ?
C44 Au3 Au7 175.9(6) . . ?
C44 Au3 Au1 122.1(6) . . ?
Au7 Au3 Au1 58.23(3) . . ?
C44 Au3 Au11 118.9(6) . . ?
Au7 Au3 Au11 58.42(3) . . ?
Au1 Au3 Au11 108.81(4) . . ?
C44 Au3 Au2 117.7(6) . . ?
Au7 Au3 Au2 58.65(3) . . ?
Au1 Au3 Au2 59.21(3) . . ?
Au11 Au3 Au2 62.41(3) . . ?
C44 Au3 Au4 125.9(6) . . ?
Au7 Au3 Au4 58.03(3) . . ?
Au1 Au3 Au4 59.66(3) . . ?
Au11 Au3 Au4 107.29(3) . . ?
Au2 Au3 Au4 107.45(4) . . ?
C44 Au3 Au12 124.0(6) . . ?
Au7 Au3 Au12 58.08(3) . . ?
Au1 Au3 Au12 107.03(4) . . ?
Au11 Au3 Au12 59.96(3) . . ?
Au2 Au3 Au12 109.35(3) . . ?
Au4 Au3 Au12 58.76(3) . . ?
C80 Au4 Au7 178.9(7) . . ?
C80 Au4 Au1 122.7(6) . . ?
Au7 Au4 Au1 58.17(3) . . ?
C80 Au4 Au5 120.8(6) . . ?
Au7 Au4 Au5 58.84(3) . . ?
Au1 Au4 Au5 60.14(3) . . ?
C80 Au4 Au12 120.6(6) . . ?
Au7 Au4 Au12 59.08(3) . . ?
Au1 Au4 Au12 109.16(4) . . ?
Au5 Au4 Au12 108.55(3) . . ?
C80 Au4 Au3 122.9(7) . . ?
Au7 Au4 Au3 57.99(3) . . ?
Au1 Au4 Au3 59.54(3) . . ?
Au5 Au4 Au3 108.03(4) . . ?
Au12 Au4 Au3 61.55(3) . . ?
C80 Au4 Au8 120.7(7) . . ?
Au7 Au4 Au8 58.25(3) . . ?
Au1 Au4 Au8 107.72(4) . . ?
Au5 Au4 Au8 59.94(3) . . ?
Au12 Au4 Au8 59.50(3) . . ?
Au3 Au4 Au8 108.05(3) . . ?
C116 Au5 Au7 176.0(7) . . ?
C116 Au5 Au4 117.8(7) . . ?
Au7 Au5 Au4 58.23(3) . . ?
C116 Au5 Au6 124.1(6) . . ?
Au7 Au5 Au6 58.62(3) . . ?
Au4 Au5 Au6 108.14(4) . . ?
C116 Au5 Au1 120.2(7) . . ?
Au7 Au5 Au1 57.90(3) . . ?
Au4 Au5 Au1 59.91(3) . . ?
Au6 Au5 Au1 59.74(3) . . ?
C116 Au5 Au8 120.9(6) . . ?
Au7 Au5 Au8 58.49(3) . . ?
Au4 Au5 Au8 61.13(3) . . ?
Au6 Au5 Au8 107.96(3) . . ?
Au1 Au5 Au8 108.48(4) . . ?
C116 Au5 Au9 126.0(7) . . ?
Au7 Au5 Au9 57.54(3) . . ?
Au4 Au5 Au9 107.49(3) . . ?
Au6 Au5 Au9 59.75(3) . . ?
Au1 Au5 Au9 106.83(3) . . ?
Au8 Au5 Au9 59.05(3) . . ?
C152 Au6 Au7 173.3(7) . . ?
C152 Au6 Au1 121.9(6) . . ?
Au7 Au6 Au1 58.02(3) . . ?
C152 Au6 Au2 127.8(7) . . ?
Au7 Au6 Au2 58.62(3) . . ?
Au1 Au6 Au2 59.40(3) . . ?
C152 Au6 Au5 115.1(6) . . ?
Au7 Au6 Au5 58.56(3) . . ?
Au1 Au6 Au5 60.13(3) . . ?
Au2 Au6 Au5 108.23(4) . . ?
C152 Au6 Au9 117.9(6) . . ?
Au7 Au6 Au9 58.01(3) . . ?
Au1 Au6 Au9 108.24(4) . . ?
Au2 Au6 Au9 107.68(4) . . ?
Au5 Au6 Au9 61.14(3) . . ?
C152 Au6 Au10 126.4(6) . . ?
Au7 Au6 Au10 57.42(3) . . ?
Au1 Au6 Au10 106.47(4) . . ?
Au2 Au6 Au10 59.44(3) . . ?
Au5 Au6 Au10 107.99(3) . . ?
Au9 Au6 Au10 59.34(3) . . ?
Au13 Au7 Au1 179.52(5) . . ?
Au13 Au7 Au3 116.67(4) . . ?
Au1 Au7 Au3 63.21(3) . . ?
Au13 Au7 Au4 116.24(4) . . ?
Au1 Au7 Au4 63.28(3) . . ?
Au3 Au7 Au4 63.97(3) . . ?
Au13 Au7 Au11 63.01(3) . . ?
Au1 Au7 Au11 117.15(4) . . ?
Au3 Au7 Au11 63.32(3) . . ?
Au4 Au7 Au11 116.18(4) . . ?
Au13 Au7 Au9 63.16(3) . . ?
Au1 Au7 Au9 116.98(4) . . ?
Au3 Au7 Au9 178.81(4) . . ?
Au4 Au7 Au9 117.20(4) . . ?
Au11 Au7 Au9 115.85(4) . . ?
Au13 Au7 Au10 63.89(3) . . ?
Au1 Au7 Au10 116.59(4) . . ?
Au3 Au7 Au10 115.22(4) . . ?
Au4 Au7 Au10 179.18(4) . . ?
Au11 Au7 Au10 63.10(3) . . ?
Au9 Au7 Au10 63.60(3) . . ?
Au13 Au7 Au5 116.61(4) . . ?
Au1 Au7 Au5 63.22(3) . . ?
Au3 Au7 Au5 116.37(4) . . ?
Au4 Au7 Au5 62.93(3) . . ?
Au11 Au7 Au5 178.88(4) . . ?
Au9 Au7 Au5 64.47(3) . . ?
Au10 Au7 Au5 117.79(4) . . ?
Au13 Au7 Au2 118.02(4) . . ?
Au1 Au7 Au2 62.38(3) . . ?
Au3 Au7 Au2 63.37(3) . . ?
Au4 Au7 Au2 116.18(4) . . ?
Au11 Au7 Au2 65.76(3) . . ?
Au9 Au7 Au2 115.58(4) . . ?
Au10 Au7 Au2 63.26(3) . . ?
Au5 Au7 Au2 115.16(4) . . ?
Au13 Au7 Au6 117.46(4) . . ?
Au1 Au7 Au6 62.91(3) . . ?
Au3 Au7 Au6 116.03(4) . . ?
Au4 Au7 Au6 115.54(4) . . ?
Au11 Au7 Au6 118.30(4) . . ?
Au9 Au7 Au6 63.45(3) . . ?
Au10 Au7 Au6 64.84(3) . . ?
Au5 Au7 Au6 62.82(3) . . ?
Au2 Au7 Au6 62.73(3) . . ?
Au13 Au7 Au8 62.57(3) . . ?
Au1 Au7 Au8 117.04(4) . . ?
Au3 Au7 Au8 118.16(4) . . ?
Au4 Au7 Au8 64.39(3) . . ?
Au11 Au7 Au8 115.77(4) . . ?
Au9 Au7 Au8 62.90(3) . . ?
Au10 Au7 Au8 116.19(4) . . ?
Au5 Au7 Au8 63.32(3) . . ?
Au2 Au7 Au8 178.12(4) . . ?
Au6 Au7 Au8 115.39(4) . . ?
Au13 Au7 Au12 62.96(3) . . ?
Au1 Au7 Au12 116.66(4) . . ?
Au3 Au7 Au12 64.89(3) . . ?
Au4 Au7 Au12 62.88(3) . . ?
Au11 Au7 Au12 63.85(3) . . ?
Au9 Au7 Au12 115.67(4) . . ?
Au10 Au7 Au12 116.76(4) . . ?
Au5 Au7 Au12 115.03(4) . . ?
Au2 Au7 Au12 119.14(4) . . ?
Au6 Au7 Au12 177.84(4) . . ?
Au8 Au7 Au12 62.74(3) . . ?
C131 Au8 Au7 174.3(5) . . ?
C131 Au8 Au13 126.8(5) . . ?
Au7 Au8 Au13 57.80(3) . . ?
C131 Au8 Au9 126.3(5) . . ?
Au7 Au8 Au9 58.17(3) . . ?
Au13 Au8 Au9 59.94(3) . . ?
C131 Au8 Au12 119.4(6) . . ?
Au7 Au8 Au12 58.69(3) . . ?
Au13 Au8 Au12 59.99(3) . . ?
Au9 Au8 Au12 108.34(3) . . ?
C131 Au8 Au5 119.7(5) . . ?
Au7 Au8 Au5 58.19(3) . . ?
Au13 Au8 Au5 108.23(3) . . ?
Au9 Au8 Au5 61.08(3) . . ?
Au12 Au8 Au5 107.51(3) . . ?
C131 Au8 Au4 116.9(5) . . ?
Au7 Au8 Au4 57.37(3) . . ?
Au13 Au8 Au4 106.47(3) . . ?
Au9 Au8 Au4 107.37(3) . . ?
Au12 Au8 Au4 59.22(3) . . ?
Au5 Au8 Au4 58.93(3) . . ?
C167 Au9 Au7 173.7(6) . . ?
C167 Au9 Au13 125.5(7) . . ?
Au7 Au9 Au13 57.90(3) . . ?
C167 Au9 Au8 117.1(6) . . ?
Au7 Au9 Au8 58.93(3) . . ?
Au13 Au9 Au8 59.52(3) . . ?
C167 Au9 Au6 121.2(6) . . ?
Au7 Au9 Au6 58.54(3) . . ?
Au13 Au9 Au6 108.83(4) . . ?
Au8 Au9 Au6 108.11(4) . . ?
C167 Au9 Au10 127.7(6) . . ?
Au7 Au9 Au10 58.30(3) . . ?
Au13 Au9 Au10 60.32(3) . . ?
Au8 Au9 Au10 108.50(3) . . ?
Au6 Au9 Au10 61.36(3) . . ?
C167 Au9 Au5 116.0(6) . . ?
Au7 Au9 Au5 57.99(3) . . ?
Au13 Au9 Au5 106.95(3) . . ?
Au8 Au9 Au5 59.87(3) . . ?
Au6 Au9 Au5 59.11(3) . . ?
Au10 Au9 Au5 107.98(3) . . ?
C23 Au10 Au7 177.4(6) . . ?
C23 Au10 Au11 124.1(6) . . ?
Au7 Au10 Au11 58.34(3) . . ?
C23 Au10 Au2 121.3(6) . . ?
Au7 Au10 Au2 58.51(3) . . ?
Au11 Au10 Au2 62.43(3) . . ?
C23 Au10 Au13 124.1(6) . . ?
Au7 Au10 Au13 57.44(3) . . ?
Au11 Au10 Au13 59.29(3) . . ?
Au2 Au10 Au13 108.50(3) . . ?
C23 Au10 Au9 120.4(6) . . ?
Au7 Au10 Au9 58.09(3) . . ?
Au11 Au10 Au9 107.39(3) . . ?
Au2 Au10 Au9 107.19(3) . . ?
Au13 Au10 Au9 59.20(3) . . ?
C23 Au10 Au6 119.8(6) . . ?
Au7 Au10 Au6 57.73(3) . . ?
Au11 Au10 Au6 108.30(3) . . ?
Au2 Au10 Au6 58.87(3) . . ?
Au13 Au10 Au6 106.32(3) . . ?
Au9 Au10 Au6 59.30(3) . . ?
C59 Au11 Au7 174.5(6) . . ?
C59 Au11 Au13 123.9(6) . . ?
Au7 Au11 Au13 57.97(3) . . ?
C59 Au11 Au10 117.2(6) . . ?
Au7 Au11 Au10 58.56(3) . . ?
Au13 Au11 Au10 60.64(3) . . ?
C59 Au11 Au3 122.8(6) . . ?
Au7 Au11 Au3 58.25(3) . . ?
Au13 Au11 Au3 108.17(3) . . ?
Au10 Au11 Au3 107.36(4) . . ?
C59 Au11 Au12 126.9(6) . . ?
Au7 Au11 Au12 58.52(3) . . ?
Au13 Au11 Au12 59.54(3) . . ?
Au10 Au11 Au12 108.55(3) . . ?
Au3 Au11 Au12 61.34(3) . . ?
C59 Au11 Au2 118.0(6) . . ?
Au7 Au11 Au2 57.36(3) . . ?
Au13 Au11 Au2 106.89(3) . . ?
Au10 Au11 Au2 59.02(3) . . ?
Au3 Au11 Au2 58.96(3) . . ?
Au12 Au11 Au2 107.72(3) . . ?
C95 Au12 Au7 174.6(6) . . ?
C95 Au12 Au13 124.7(6) . . ?
Au7 Au12 Au13 57.55(3) . . ?
C95 Au12 Au4 122.6(6) . . ?
Au7 Au12 Au4 58.04(3) . . ?
Au13 Au12 Au4 107.61(3) . . ?
C95 Au12 Au8 126.8(6) . . ?
Au7 Au12 Au8 58.57(3) . . ?
Au13 Au12 Au8 59.37(3) . . ?
Au4 Au12 Au8 61.28(3) . . ?
C95 Au12 Au11 118.5(6) . . ?
Au7 Au12 Au11 57.63(3) . . ?
Au13 Au12 Au11 59.12(3) . . ?
Au4 Au12 Au11 107.02(3) . . ?
Au8 Au12 Au11 107.20(3) . . ?
C95 Au12 Au3 118.1(6) . . ?
Au7 Au12 Au3 57.04(3) . . ?
Au13 Au12 Au3 105.75(3) . . ?
Au4 Au12 Au3 59.69(3) . . ?
Au8 Au12 Au3 107.99(3) . . ?
Au11 Au12 Au3 58.70(3) . . ?
Cl2 Au13 Au7 172.0(2) . . ?
Cl2 Au13 Au8 112.5(2) . . ?
Au7 Au13 Au8 59.63(3) . . ?
Cl2 Au13 Au11 126.4(2) . . ?
Au7 Au13 Au11 59.02(3) . . ?
Au8 Au13 Au11 109.99(3) . . ?
Cl2 Au13 Au9 119.7(2) . . ?
Au7 Au13 Au9 58.95(3) . . ?
Au8 Au13 Au9 60.54(3) . . ?
Au11 Au13 Au9 109.06(4) . . ?
Cl2 Au13 Au12 116.4(2) . . ?
Au7 Au13 Au12 59.49(3) . . ?
Au8 Au13 Au12 60.63(3) . . ?
Au11 Au13 Au12 61.34(3) . . ?
Au9 Au13 Au12 109.34(4) . . ?
Cl2 Au13 Au10 128.5(2) . . ?
Au7 Au13 Au10 58.68(3) . . ?
Au8 Au13 Au10 109.44(4) . . ?
Au11 Au13 Au10 60.08(3) . . ?
Au9 Au13 Au10 60.48(3) . . ?
Au12 Au13 Au10 109.55(3) . . ?
C8 N1 C9 111(2) . . ?
C8 N1 C7 122(2) . . ?
C9 N1 C7 126(2) . . ?
C8 N2 C14 106.5(18) . . ?
C8 N2 C15 125.7(19) . . ?
C14 N2 C15 127.5(17) . . ?
C23 N3 C24 108.2(16) . . ?
C23 N3 C22 125.3(17) . . ?
C24 N3 C22 126.2(16) . . ?
C23 N4 C29 112.1(16) . . ?
C23 N4 C30 123.1(17) . . ?
C29 N4 C30 124.5(16) . . ?
C44 N5 C45 108.4(19) . . ?
C44 N5 C43 124(2) . . ?
C45 N5 C43 126.6(18) . . ?
C44 N6 C50 110.8(18) . . ?
C44 N6 C51 123.1(19) . . ?
C50 N6 C51 126.0(18) . . ?
C59 N7 C60 109.3(18) . . ?
C59 N7 C58 123.3(19) . . ?
C60 N7 C58 127.3(17) . . ?
C59 N8 C65 109.5(17) . . ?
C59 N8 C66 127.9(19) . . ?
C65 N8 C66 122.5(18) . . ?
C80 N9 C81 107.7(18) . . ?
C80 N9 C79 126(2) . . ?
C81 N9 C79 126.4(19) . . ?
C80 N10 C86 109.6(18) . . ?
C80 N10 C87 125.8(19) . . ?
C86 N10 C87 124.6(18) . . ?
C96 N11 C95 111.2(17) . . ?
C96 N11 C94 126.3(17) . . ?
C95 N11 C94 122.5(19) . . ?
C95 N12 C101 111.9(17) . . ?
C95 N12 C102 125.6(18) . . ?
C101 N12 C102 122.2(16) . . ?
C117 N13 C116 107.5(19) . . ?
C117 N13 C115 125.1(19) . . ?
C116 N13 C115 127(2) . . ?
C116 N14 C122 109.9(19) . . ?
C116 N14 C123 124.3(19) . . ?
C122 N14 C123 124.7(18) . . ?
C131 N15 C132 108.9(16) . . ?
C131 N15 C130 124.1(17) . . ?
C132 N15 C130 126.8(16) . . ?
C131 N16 C137 109.1(16) . . ?
C131 N16 C138 127.8(18) . . ?
C137 N16 C138 122.9(16) . . ?
C152 N17 C153 109.1(19) . . ?
C152 N17 C151 126(2) . . ?
C153 N17 C151 124.7(18) . . ?
C152 N18 C158 108.6(18) . . ?
C152 N18 C159 127(2) . . ?
C158 N18 C159 123.9(18) . . ?
C167 N19 C168 111.0(18) . . ?
C167 N19 C166 123.9(19) . . ?
C168 N19 C166 124.1(16) . . ?
C173 N20 C167 110.4(17) . . ?
C173 N20 C174 128.0(18) . . ?
C167 N20 C174 121.5(18) . . ?
C2 C1 C6 120.0 . . ?
C2 C1 C7 118.0(19) . . ?
C6 C1 C7 121.8(19) . . ?
C3 C2 C1 120.0 . . ?
C3 C2 H2 120.0 . . ?
C1 C2 H2 120.0 . . ?
C4 C3 C2 120.0 . . ?
C4 C3 H3 120.0 . . ?
C2 C3 H3 120.0 . . ?
C3 C4 C5 120.0 . . ?
C3 C4 H4 120.0 . . ?
C5 C4 H4 120.0 . . ?
C4 C5 C6 120.0 . . ?
C4 C5 H5 120.0 . . ?
C6 C5 H5 120.0 . . ?
C5 C6 C1 120.0 . . ?
C5 C6 H6 120.0 . . ?
C1 C6 H6 120.0 . . ?
C1 C7 N1 115(2) . . ?
C1 C7 H7A 108.4 . . ?
N1 C7 H7A 108.4 . . ?
C1 C7 H7B 108.4 . . ?
N1 C7 H7B 108.4 . . ?
H7A C7 H7B 107.5 . . ?
N1 C8 N2 108.6(19) . . ?
N1 C8 Au2 127.9(18) . . ?
N2 C8 Au2 122.9(18) . . ?
N1 C9 C10 133.9(14) . . ?
N1 C9 C14 106.1(14) . . ?
C10 C9 C14 120.0 . . ?
C11 C10 C9 120.0 . . ?
C11 C10 H10 120.0 . . ?
C9 C10 H10 120.0 . . ?
C10 C11 C12 120.0 . . ?
C10 C11 H11 120.0 . . ?
C12 C11 H11 120.0 . . ?
C13 C12 C11 120.0 . . ?
C13 C12 H12 120.0 . . ?
C11 C12 H12 120.0 . . ?
C12 C13 C14 120.0 . . ?
C12 C13 H13 120.0 . . ?
C14 C13 H13 120.0 . . ?
C13 C14 C9 120.0 . . ?
C13 C14 N2 132.4(13) . . ?
C9 C14 N2 107.6(13) . . ?
N2 C15 C16 112.9(18) . . ?
N2 C15 H15A 109.0 . . ?
C16 C15 H15A 109.0 . . ?
N2 C15 H15B 109.0 . . ?
C16 C15 H15B 109.0 . . ?
H15A C15 H15B 107.8 . . ?
C17 C16 C21 120.0 . . ?
C17 C16 C15 115.8(12) . . ?
C21 C16 C15 123.8(12) . . ?
C16 C17 C18 120.0 . . ?
C16 C17 H17 120.0 . . ?
C18 C17 H17 120.0 . . ?
C19 C18 C17 120.0 . . ?
C19 C18 H18 120.0 . . ?
C17 C18 H18 120.0 . . ?
C20 C19 C18 120.0 . . ?
C20 C19 H19 120.0 . . ?
C18 C19 H19 120.0 . . ?
C21 C20 C19 120.0 . . ?
C21 C20 H20 120.0 . . ?
C19 C20 H20 120.0 . . ?
C20 C21 C16 120.0 . . ?
C20 C21 C22 120.9(11) . . ?
C16 C21 C22 118.4(12) . . ?
N3 C22 C21 116.8(17) . . ?
N3 C22 H22A 108.1 . . ?
C21 C22 H22A 108.1 . . ?
N3 C22 H22B 108.1 . . ?
C21 C22 H22B 108.1 . . ?
H22A C22 H22B 107.3 . . ?
N4 C23 N3 106.6(17) . . ?
N4 C23 Au10 128.1(16) . . ?
N3 C23 Au10 125.0(15) . . ?
C25 C24 C29 120.0 . . ?
C25 C24 N3 133.3(11) . . ?
C29 C24 N3 106.7(11) . . ?
C24 C25 C26 120.0 . . ?
C24 C25 H25 120.0 . . ?
C26 C25 H25 120.0 . . ?
C27 C26 C25 120.0 . . ?
C27 C26 H26 120.0 . . ?
C25 C26 H26 120.0 . . ?
C26 C27 C28 120.0 . . ?
C26 C27 H27 120.0 . . ?
C28 C27 H27 120.0 . . ?
C29 C28 C27 120.0 . . ?
C29 C28 H28 120.0 . . ?
C27 C28 H28 120.0 . . ?
C28 C29 C24 120.0 . . ?
C28 C29 N4 133.7(11) . . ?
C24 C29 N4 106.0(11) . . ?
C31 C30 N4 115.0(17) . . ?
C31 C30 H30A 108.5 . . ?
N4 C30 H30A 108.5 . . ?
C31 C30 H30B 108.5 . . ?
N4 C30 H30B 108.5 . . ?
H30A C30 H30B 107.5 . . ?
C32 C31 C36 120.0 . . ?
C32 C31 C30 121.0(14) . . ?
C36 C31 C30 118.7(14) . . ?
C31 C32 C33 120.0 . . ?
C31 C32 H32 120.0 . . ?
C33 C32 H32 120.0 . . ?
C34 C33 C32 120.0 . . ?
C34 C33 H33 120.0 . . ?
C32 C33 H33 120.0 . . ?
C35 C34 C33 120.0 . . ?
C35 C34 H34 120.0 . . ?
C33 C34 H34 120.0 . . ?
C34 C35 C36 120.0 . . ?
C34 C35 H35 120.0 . . ?
C36 C35 H35 120.0 . . ?
C35 C36 C31 120.0 . . ?
C35 C36 H36 120.0 . . ?
C31 C36 H36 120.0 . . ?
C38 C37 C42 120.0 . . ?
C38 C37 C43 116.4(14) . . ?
C42 C37 C43 123.6(14) . . ?
C39 C38 C37 120.0 . . ?
C39 C38 H38 120.0 . . ?
C37 C38 H38 120.0 . . ?
C38 C39 C40 120.0 . . ?
C38 C39 H39 120.0 . . ?
C40 C39 H39 120.0 . . ?
C39 C40 C41 120.0 . . ?
C39 C40 H40 120.0 . . ?
C41 C40 H40 120.0 . . ?
C42 C41 C40 120.0 . . ?
C42 C41 H41 120.0 . . ?
C40 C41 H41 120.0 . . ?
C41 C42 C37 120.0 . . ?
C41 C42 H42 120.0 . . ?
C37 C42 H42 120.0 . . ?
N5 C43 C37 113.9(18) . . ?
N5 C43 H43A 108.8 . . ?
C37 C43 H43A 108.8 . . ?
N5 C43 H43B 108.8 . . ?
C37 C43 H43B 108.8 . . ?
H43A C43 H43B 107.7 . . ?
N6 C44 N5 108(2) . . ?
N6 C44 Au3 126.8(17) . . ?
N5 C44 Au3 125.3(17) . . ?
N5 C45 C46 132.5(13) . . ?
N5 C45 C50 107.2(13) . . ?
C46 C45 C50 120.0 . . ?
C47 C46 C45 120.0 . . ?
C47 C46 H46 120.0 . . ?
C45 C46 H46 120.0 . . ?
C46 C47 C48 120.0 . . ?
C46 C47 H47 120.0 . . ?
C48 C47 H47 120.0 . . ?
C49 C48 C47 120.0 . . ?
C49 C48 H48 120.0 . . ?
C47 C48 H48 120.0 . . ?
C48 C49 C50 120.0 . . ?
C48 C49 H49 120.0 . . ?
C50 C49 H49 120.0 . . ?
N6 C50 C49 134.3(13) . . ?
N6 C50 C45 105.7(13) . . ?
C49 C50 C45 120.0 . . ?
N6 C51 C52 116.1(16) . . ?
N6 C51 H51A 108.3 . . ?
C52 C51 H51A 108.3 . . ?
N6 C51 H51B 108.3 . . ?
C52 C51 H51B 108.3 . . ?
H51A C51 H51B 107.4 . . ?
C53 C52 C57 120.0 . . ?
C53 C52 C51 115.9(13) . . ?
C57 C52 C51 123.7(13) . . ?
C54 C53 C52 120.0 . . ?
C54 C53 H53 120.0 . . ?
C52 C53 H53 120.0 . . ?
C53 C54 C55 120.0 . . ?
C53 C54 H54 120.0 . . ?
C55 C54 H54 120.0 . . ?
C56 C55 C54 120.0 . . ?
C56 C55 H55 120.0 . . ?
C54 C55 H55 120.0 . . ?
C55 C56 C57 120.0 . . ?
C55 C56 H56 120.0 . . ?
C57 C56 H56 120.0 . . ?
C56 C57 C52 120.0 . . ?
C56 C57 C58 117.9(13) . . ?
C52 C57 C58 121.2(13) . . ?
N7 C58 C57 111.7(18) . . ?
N7 C58 H58A 109.3 . . ?
C57 C58 H58A 109.3 . . ?
N7 C58 H58B 109.3 . . ?
C57 C58 H58B 109.3 . . ?
H58A C58 H58B 107.9 . . ?
N8 C59 N7 107.7(18) . . ?
N8 C59 Au11 124.7(16) . . ?
N7 C59 Au11 126.6(16) . . ?
N7 C60 C61 132.3(13) . . ?
N7 C60 C65 107.7(13) . . ?
C61 C60 C65 120.0 . . ?
C62 C61 C60 120.0 . . ?
C62 C61 H61 120.0 . . ?
C60 C61 H61 120.0 . . ?
C63 C62 C61 120.0 . . ?
C63 C62 H62 120.0 . . ?
C61 C62 H62 120.0 . . ?
C62 C63 C64 120.0 . . ?
C62 C63 H63 120.0 . . ?
C64 C63 H63 120.0 . . ?
C63 C64 C65 120.0 . . ?
C63 C64 H64 120.0 . . ?
C65 C64 H64 120.0 . . ?
C64 C65 C60 120.0 . . ?
C64 C65 N8 134.4(12) . . ?
C60 C65 N8 105.5(12) . . ?
N8 C66 C67 116(2) . . ?
N8 C66 H66A 108.3 . . ?
C67 C66 H66A 108.3 . . ?
N8 C66 H66B 108.3 . . ?
C67 C66 H66B 108.3 . . ?
H66A C66 H66B 107.4 . . ?
C68 C67 C72 120.0 . . ?
C68 C67 C66 119.8(16) . . ?
C72 C67 C66 120.1(16) . . ?
C69 C68 C67 120.0 . . ?
C69 C68 H68 120.0 . . ?
C67 C68 H68 120.0 . . ?
C68 C69 C70 120.0 . . ?
C68 C69 H69 120.0 . . ?
C70 C69 H69 120.0 . . ?
C71 C70 C69 120.0 . . ?
C71 C70 H70 120.0 . . ?
C69 C70 H70 120.0 . . ?
C70 C71 C72 120.0 . . ?
C70 C71 H71 120.0 . . ?
C72 C71 H71 120.0 . . ?
C71 C72 C67 120.0 . . ?
C71 C72 H72 120.0 . . ?
C67 C72 H72 120.0 . . ?
C74 C73 C78 120.0 . . ?
C74 C73 C79 119.6(16) . . ?
C78 C73 C79 120.4(16) . . ?
C75 C74 C73 120.0 . . ?
C75 C74 H74 120.0 . . ?
C73 C74 H74 120.0 . . ?
C76 C75 C74 120.0 . . ?
C76 C75 H75 120.0 . . ?
C74 C75 H75 120.0 . . ?
C75 C76 C77 120.0 . . ?
C75 C76 H76 120.0 . . ?
C77 C76 H76 120.0 . . ?
C78 C77 C76 120.0 . . ?
C78 C77 H77 120.0 . . ?
C76 C77 H77 120.0 . . ?
C77 C78 C73 120.0 . . ?
C77 C78 H78 120.0 . . ?
C73 C78 H78 120.0 . . ?
N9 C79 C73 114(2) . . ?
N9 C79 H79A 108.8 . . ?
C73 C79 H79A 108.8 . . ?
N9 C79 H79B 108.8 . . ?
C73 C79 H79B 108.8 . . ?
H79A C79 H79B 107.7 . . ?
N9 C80 N10 108.8(19) . . ?
N9 C80 Au4 126.1(17) . . ?
N10 C80 Au4 125.1(17) . . ?
N9 C81 C82 131.9(14) . . ?
N9 C81 C86 108.1(14) . . ?
C82 C81 C86 120.0 . . ?
C81 C82 C83 120.0 . . ?
C81 C82 H82 120.0 . . ?
C83 C82 H82 120.0 . . ?
C84 C83 C82 120.0 . . ?
C84 C83 H83 120.0 . . ?
C82 C83 H83 120.0 . . ?
C85 C84 C83 120.0 . . ?
C85 C84 H84 120.0 . . ?
C83 C84 H84 120.0 . . ?
C86 C85 C84 120.0 . . ?
C86 C85 H85 120.0 . . ?
C84 C85 H85 120.0 . . ?
N10 C86 C85 134.2(13) . . ?
N10 C86 C81 105.8(13) . . ?
C85 C86 C81 120.0 . . ?
N10 C87 C88 116.5(18) . . ?
N10 C87 H87A 108.2 . . ?
C88 C87 H87A 108.2 . . ?
N10 C87 H87B 108.2 . . ?
C88 C87 H87B 108.2 . . ?
H87A C87 H87B 107.3 . . ?
C89 C88 C93 120.0 . . ?
C89 C88 C87 115.8(14) . . ?
C93 C88 C87 123.8(13) . . ?
C90 C89 C88 120.0 . . ?
C90 C89 H89 120.0 . . ?
C88 C89 H89 120.0 . . ?
C91 C90 C89 120.0 . . ?
C91 C90 H90 120.0 . . ?
C89 C90 H90 120.0 . . ?
C90 C91 C92 120.0 . . ?
C90 C91 H91 120.0 . . ?
C92 C91 H91 120.0 . . ?
C93 C92 C91 120.0 . . ?
C93 C92 H92 120.0 . . ?
C91 C92 H92 120.0 . . ?
C92 C93 C88 120.0 . . ?
C92 C93 C94 117.6(13) . . ?
C88 C93 C94 122.3(13) . . ?
N11 C94 C93 114.1(18) . . ?
N11 C94 H94A 108.7 . . ?
C93 C94 H94A 108.7 . . ?
N11 C94 H94B 108.7 . . ?
C93 C94 H94B 108.7 . . ?
H94A C94 H94B 107.6 . . ?
N12 C95 N11 103.9(18) . . ?
N12 C95 Au12 126.8(15) . . ?
N11 C95 Au12 127.6(15) . . ?
N11 C96 C97 133.3(12) . . ?
N11 C96 C101 106.7(12) . . ?
C97 C96 C101 120.0 . . ?
C98 C97 C96 120.0 . . ?
C98 C97 H97 120.0 . . ?
C96 C97 H97 120.0 . . ?
C99 C98 C97 120.0 . . ?
C99 C98 H98 120.0 . . ?
C97 C98 H98 120.0 . . ?
C98 C99 C100 120.0 . . ?
C98 C99 H99 120.0 . . ?
C100 C99 H99 120.0 . . ?
C101 C100 C99 120.0 . . ?
C101 C100 H100 120.0 . . ?
C99 C100 H100 120.0 . . ?
C100 C101 C96 120.0 . . ?
C100 C101 N12 133.9(12) . . ?
C96 C101 N12 106.0(12) . . ?
N12 C102 C103 113.6(19) . . ?
N12 C102 H10A 108.8 . . ?
C103 C102 H10A 108.8 . . ?
N12 C102 H10B 108.8 . . ?
C103 C102 H10B 108.8 . . ?
H10A C102 H10B 107.7 . . ?
C104 C103 C108 120.0 . . ?
C104 C103 C102 117.8(15) . . ?
C108 C103 C102 122.2(15) . . ?
C103 C104 C105 120.0 . . ?
C103 C104 H104 120.0 . . ?
C105 C104 H104 120.0 . . ?
C106 C105 C104 120.0 . . ?
C106 C105 H105 120.0 . . ?
C104 C105 H105 120.0 . . ?
C105 C106 C107 120.0 . . ?
C105 C106 H106 120.0 . . ?
C107 C106 H106 120.0 . . ?
C108 C107 C106 120.0 . . ?
C108 C107 H107 120.0 . . ?
C106 C107 H107 120.0 . . ?
C107 C108 C103 120.0 . . ?
C107 C108 H108 120.0 . . ?
C103 C108 H108 120.0 . . ?
C110 C109 C114 120.0 . . ?
C110 C109 C115 121.5(18) . . ?
C114 C109 C115 118.4(18) . . ?
C111 C110 C109 120.0 . . ?
C111 C110 H110 120.0 . . ?
C109 C110 H110 120.0 . . ?
C110 C111 C112 120.0 . . ?
C110 C111 H111 120.0 . . ?
C112 C111 H111 120.0 . . ?
C111 C112 C113 120.0 . . ?
C111 C112 H112 120.0 . . ?
C113 C112 H112 120.0 . . ?
C114 C113 C112 120.0 . . ?
C114 C113 H113 120.0 . . ?
C112 C113 H113 120.0 . . ?
C113 C114 C109 120.0 . . ?
C113 C114 H114 120.0 . . ?
C109 C114 H114 120.0 . . ?
N13 C115 C109 114(2) . . ?
N13 C115 H11A 108.7 . . ?
C109 C115 H11A 108.7 . . ?
N13 C115 H11B 108.7 . . ?
C109 C115 H11B 108.7 . . ?
H11A C115 H11B 107.6 . . ?
N14 C116 N13 109.0(19) . . ?
N14 C116 Au5 128.0(17) . . ?
N13 C116 Au5 122.9(17) . . ?
N13 C117 C118 132.5(14) . . ?
N13 C117 C122 107.4(14) . . ?
C118 C117 C122 120.0 . . ?
C117 C118 C119 120.0 . . ?
C117 C118 H118 120.0 . . ?
C119 C118 H118 120.0 . . ?
C120 C119 C118 120.0 . . ?
C120 C119 H119 120.0 . . ?
C118 C119 H119 120.0 . . ?
C121 C120 C119 120.0 . . ?
C121 C120 H120 120.0 . . ?
C119 C120 H120 120.0 . . ?
C120 C121 C122 120.0 . . ?
C120 C121 H121 120.0 . . ?
C122 C121 H121 120.0 . . ?
N14 C122 C121 134.0(14) . . ?
N14 C122 C117 106.0(14) . . ?
C121 C122 C117 120.0 . . ?
N14 C123 C124 116.9(18) . . ?
N14 C123 H12A 108.1 . . ?
C124 C123 H12A 108.1 . . ?
N14 C123 H12B 108.1 . . ?
C124 C123 H12B 108.1 . . ?
H12A C123 H12B 107.3 . . ?
C125 C124 C129 120.0 . . ?
C125 C124 C123 115.1(12) . . ?
C129 C124 C123 123.7(12) . . ?
C126 C125 C124 120.0 . . ?
C126 C125 H125 120.0 . . ?
C124 C125 H125 120.0 . . ?
C127 C126 C125 120.0 . . ?
C127 C126 H126 120.0 . . ?
C125 C126 H126 120.0 . . ?
C128 C127 C126 120.0 . . ?
C128 C127 H127 120.0 . . ?
C126 C127 H127 120.0 . . ?
C129 C128 C127 120.0 . . ?
C129 C128 H128 120.0 . . ?
C127 C128 H128 120.0 . . ?
C128 C129 C124 120.0 . . ?
C128 C129 C130 120.2(12) . . ?
C124 C129 C130 119.4(12) . . ?
N15 C130 C129 112.6(17) . . ?
N15 C130 H13A 109.1 . . ?
C129 C130 H13A 109.1 . . ?
N15 C130 H13B 109.1 . . ?
C129 C130 H13B 109.1 . . ?
H13A C130 H13B 107.8 . . ?
N16 C131 N15 109.7(18) . . ?
N16 C131 Au8 126.1(15) . . ?
N15 C131 Au8 123.5(14) . . ?
N15 C132 C133 133.7(11) . . ?
N15 C132 C137 106.3(11) . . ?
C133 C132 C137 120.0 . . ?
C134 C133 C132 120.0 . . ?
C134 C133 H133 120.0 . . ?
C132 C133 H133 120.0 . . ?
C135 C134 C133 120.0 . . ?
C135 C134 H134 120.0 . . ?
C133 C134 H134 120.0 . . ?
C134 C135 C136 120.0 . . ?
C134 C135 H135 120.0 . . ?
C136 C135 H135 120.0 . . ?
C135 C136 C137 120.0 . . ?
C135 C136 H136 120.0 . . ?
C137 C136 H136 120.0 . . ?
C136 C137 C132 120.0 . . ?
C136 C137 N16 133.9(11) . . ?
C132 C137 N16 105.9(11) . . ?
N16 C138 C139 111.4(18) . . ?
N16 C138 H13C 109.3 . . ?
C139 C138 H13C 109.3 . . ?
N16 C138 H13D 109.3 . . ?
C139 C138 H13D 109.3 . . ?
H13C C138 H13D 108.0 . . ?
C140 C139 C144 120.0 . . ?
C140 C139 C138 118.6(13) . . ?
C144 C139 C138 121.3(13) . . ?
C139 C140 C141 120.0 . . ?
C139 C140 H140 120.0 . . ?
C141 C140 H140 120.0 . . ?
C142 C141 C140 120.0 . . ?
C142 C141 H141 120.0 . . ?
C140 C141 H141 120.0 . . ?
C141 C142 C143 120.0 . . ?
C141 C142 H142 120.0 . . ?
C143 C142 H142 120.0 . . ?
C142 C143 C144 120.0 . . ?
C142 C143 H143 120.0 . . ?
C144 C143 H143 120.0 . . ?
C143 C144 C139 120.0 . . ?
C143 C144 H144 120.0 . . ?
C139 C144 H144 120.0 . . ?
C146 C145 C150 120.0 . . ?
C146 C145 C151 118.9(15) . . ?
C150 C145 C151 120.9(15) . . ?
C145 C146 C147 120.0 . . ?
C145 C146 H146 120.0 . . ?
C147 C146 H146 120.0 . . ?
C146 C147 C148 120.0 . . ?
C146 C147 H147 120.0 . . ?
C148 C147 H147 120.0 . . ?
C149 C148 C147 120.0 . . ?
C149 C148 H148 120.0 . . ?
C147 C148 H148 120.0 . . ?
C148 C149 C150 120.0 . . ?
C148 C149 H149 120.0 . . ?
C150 C149 H149 120.0 . . ?
C149 C150 C145 120.0 . . ?
C149 C150 H150 120.0 . . ?
C145 C150 H150 120.0 . . ?
N17 C151 C145 117(2) . . ?
N17 C151 H15C 108.0 . . ?
C145 C151 H15C 108.0 . . ?
N17 C151 H15D 108.0 . . ?
C145 C151 H15D 108.0 . . ?
H15C C151 H15D 107.2 . . ?
N17 C152 N18 110(2) . . ?
N17 C152 Au6 126.9(17) . . ?
N18 C152 Au6 123.0(17) . . ?
C154 C153 C158 120.0 . . ?
C154 C153 N17 133.1(13) . . ?
C158 C153 N17 106.9(13) . . ?
C153 C154 C155 120.0 . . ?
C153 C154 H154 120.0 . . ?
C155 C154 H154 120.0 . . ?
C154 C155 C156 120.0 . . ?
C154 C155 H155 120.0 . . ?
C156 C155 H155 120.0 . . ?
C157 C156 C155 120.0 . . ?
C157 C156 H156 120.0 . . ?
C155 C156 H156 120.0 . . ?
C158 C157 C156 120.0 . . ?
C158 C157 H157 120.0 . . ?
C156 C157 H157 120.0 . . ?
C157 C158 C153 120.0 . . ?
C157 C158 N18 134.5(13) . . ?
C153 C158 N18 105.3(13) . . ?
N18 C159 C160 118(2) . . ?
N18 C159 H15E 107.8 . . ?
C160 C159 H15E 107.8 . . ?
N18 C159 H15F 107.8 . . ?
C160 C159 H15F 107.8 . . ?
H15E C159 H15F 107.2 . . ?
C161 C160 C165 120.0 . . ?
C161 C160 C159 114.9(12) . . ?
C165 C160 C159 124.4(12) . . ?
C160 C161 C162 120.0 . . ?
C160 C161 H161 120.0 . . ?
C162 C161 H161 120.0 . . ?
C161 C162 C163 120.0 . . ?
C161 C162 H162 120.0 . . ?
C163 C162 H162 120.0 . . ?
C164 C163 C162 120.0 . . ?
C164 C163 H163 120.0 . . ?
C162 C163 H163 120.0 . . ?
C165 C164 C163 120.0 . . ?
C165 C164 H164 120.0 . . ?
C163 C164 H164 120.0 . . ?
C164 C165 C160 120.0 . . ?
C164 C165 C166 119.9(12) . . ?
C160 C165 C166 120.0(12) . . ?
N19 C166 C165 112.2(17) . . ?
N19 C166 H16A 109.2 . . ?
C165 C166 H16A 109.2 . . ?
N19 C166 H16B 109.2 . . ?
C165 C166 H16B 109.2 . . ?
H16A C166 H16B 107.9 . . ?
N19 C167 N20 105.8(19) . . ?
N19 C167 Au9 126.0(17) . . ?
N20 C167 Au9 127.0(16) . . ?
N19 C168 C169 132.9(12) . . ?
N19 C168 C173 107.0(12) . . ?
C169 C168 C173 120.0 . . ?
C170 C169 C168 120.0 . . ?
C170 C169 H169 120.0 . . ?
C168 C169 H169 120.0 . . ?
C169 C170 C171 120.0 . . ?
C169 C170 H170 120.0 . . ?
C171 C170 H170 120.0 . . ?
C172 C171 C170 120.0 . . ?
C172 C171 H171 120.0 . . ?
C170 C171 H171 120.0 . . ?
C171 C172 C173 120.0 . . ?
C171 C172 H172 120.0 . . ?
C173 C172 H172 120.0 . . ?
N20 C173 C172 134.4(12) . . ?
N20 C173 C168 105.6(12) . . ?
C172 C173 C168 120.0 . . ?
N20 C174 C175 112.6(18) . . ?
N20 C174 H17A 109.1 . . ?
C175 C174 H17A 109.1 . . ?
N20 C174 H17B 109.1 . . ?
C175 C174 H17B 109.1 . . ?
H17A C174 H17B 107.8 . . ?
C176 C175 C180 120.0 . . ?
C176 C175 C174 121.1(13) . . ?
C180 C175 C174 118.8(13) . . ?
C175 C176 C177 120.0 . . ?
C175 C176 H176 120.0 . . ?
C177 C176 H176 120.0 . . ?
C178 C177 C176 120.0 . . ?
C178 C177 H177 120.0 . . ?
C176 C177 H177 120.0 . . ?
C177 C178 C179 120.0 . . ?
C177 C178 H178 120.0 . . ?
C179 C178 H178 120.0 . . ?
C180 C179 C178 120.0 . . ?
C180 C179 H179 120.0 . . ?
C178 C179 H179 120.0 . . ?
C179 C180 C175 120.0 . . ?
C179 C180 H180 120.0 . . ?
C175 C180 H180 120.0 . . ?
loop_
_geom_bond_atom_site_label_1
_geom_bond_atom_site_label_2
_geom_bond_distance
_geom_bond_site_symmetry_2
_geom_bond_publ_flag
Au1 Cl1 2.363(6) . ?
Au1 Au7 2.7465(12) . ?
Au1 Au2 2.8605(12) . ?
Au1 Au6 2.8827(13) . ?
Au1 Au3 2.8840(13) . ?
Au1 Au4 2.8876(12) . ?
Au1 Au5 2.8943(12) . ?
Au2 C8 2.06(2) . ?
Au2 Au7 2.7765(12) . ?
Au2 Au6 2.8908(12) . ?
Au2 Au3 2.9064(12) . ?
Au2 Au10 2.9080(12) . ?
Au2 Au11 3.0065(13) . ?
Au3 C44 2.07(2) . ?
Au3 Au7 2.7565(12) . ?
Au3 Au11 2.8965(12) . ?
Au3 Au4 2.9210(11) . ?
Au3 Au12 2.9747(12) . ?
Au4 C80 2.05(2) . ?
Au4 Au7 2.7577(12) . ?
Au4 Au5 2.8885(12) . ?
Au4 Au12 2.8928(12) . ?
Au4 Au8 2.9530(12) . ?
Au5 C116 2.08(2) . ?
Au5 Au7 2.7757(12) . ?
Au5 Au6 2.8942(12) . ?
Au5 Au8 2.9185(12) . ?
Au5 Au9 2.9538(12) . ?
Au6 C152 2.06(2) . ?
Au6 Au7 2.7777(12) . ?
Au6 Au9 2.9132(12) . ?
Au6 Au10 2.9734(12) . ?
Au7 Au13 2.7310(12) . ?
Au7 Au11 2.7616(12) . ?
Au7 Au9 2.7619(12) . ?
Au7 Au10 2.7682(12) . ?
Au7 Au8 2.7845(11) . ?
Au7 Au12 2.7883(12) . ?
Au8 C131 2.09(2) . ?
Au8 Au13 2.8645(11) . ?
Au8 Au9 2.8939(11) . ?
Au8 Au12 2.9011(12) . ?
Au9 C167 2.04(2) . ?
Au9 Au13 2.8765(12) . ?
Au9 Au10 2.9142(11) . ?
Au10 C23 2.03(2) . ?
Au10 Au11 2.8935(12) . ?
Au10 Au13 2.9096(12) . ?
Au11 C59 2.05(2) . ?
Au11 Au13 2.8703(12) . ?
Au11 Au12 2.9348(12) . ?
Au12 C95 2.01(2) . ?
Au12 Au13 2.8827(12) . ?
Au13 Cl2 2.300(6) . ?
N1 C8 1.32(3) . ?
N1 C9 1.37(2) . ?
N1 C7 1.51(3) . ?
N2 C8 1.38(3) . ?
N2 C14 1.40(2) . ?
N2 C15 1.45(3) . ?
N3 C23 1.40(3) . ?
N3 C24 1.418(19) . ?
N3 C22 1.47(3) . ?
N4 C23 1.33(3) . ?
N4 C29 1.397(18) . ?
N4 C30 1.49(3) . ?
N5 C44 1.35(3) . ?
N5 C45 1.38(2) . ?
N5 C43 1.48(3) . ?
N6 C44 1.33(3) . ?
N6 C50 1.37(2) . ?
N6 C51 1.47(3) . ?
N7 C59 1.35(3) . ?
N7 C60 1.37(2) . ?
N7 C58 1.48(3) . ?
N8 C59 1.35(3) . ?
N8 C65 1.40(2) . ?
N8 C66 1.40(3) . ?
N9 C80 1.35(3) . ?
N9 C81 1.38(2) . ?
N9 C79 1.43(3) . ?
N10 C80 1.35(3) . ?
N10 C86 1.37(2) . ?
N10 C87 1.44(3) . ?
N11 C96 1.39(2) . ?
N11 C95 1.39(3) . ?
N11 C94 1.44(3) . ?
N12 C95 1.37(3) . ?
N12 C101 1.40(2) . ?
N12 C102 1.45(3) . ?
N13 C117 1.37(2) . ?
N13 C116 1.38(3) . ?
N13 C115 1.43(3) . ?
N14 C116 1.30(3) . ?
N14 C122 1.38(2) . ?
N14 C123 1.46(3) . ?
N15 C131 1.35(3) . ?
N15 C132 1.374(19) . ?
N15 C130 1.47(3) . ?
N16 C131 1.30(3) . ?
N16 C137 1.40(2) . ?
N16 C138 1.48(3) . ?
N17 C152 1.33(3) . ?
N17 C153 1.39(2) . ?
N17 C151 1.46(3) . ?
N18 C152 1.33(3) . ?
N18 C158 1.42(2) . ?
N18 C159 1.47(3) . ?
N19 C167 1.33(3) . ?
N19 C168 1.36(2) . ?
N19 C166 1.49(3) . ?
N20 C173 1.36(2) . ?
N20 C167 1.38(3) . ?
N20 C174 1.47(3) . ?
C1 C2 1.3900 . ?
C1 C6 1.3900 . ?
C1 C7 1.46(3) . ?
C2 C3 1.3900 . ?
C2 H2 0.9500 . ?
C3 C4 1.3900 . ?
C3 H3 0.9500 . ?
C4 C5 1.3900 . ?
C4 H4 0.9500 . ?
C5 C6 1.3900 . ?
C5 H5 0.9500 . ?
C6 H6 0.9500 . ?
C7 H7A 0.9900 . ?
C7 H7B 0.9900 . ?
C9 C10 1.3900 . ?
C9 C14 1.3900 . ?
C10 C11 1.3900 . ?
C10 H10 0.9500 . ?
C11 C12 1.3900 . ?
C11 H11 0.9500 . ?
C12 C13 1.3900 . ?
C12 H12 0.9500 . ?
C13 C14 1.3900 . ?
C13 H13 0.9500 . ?
C15 C16 1.52(2) . ?
C15 H15A 0.9900 . ?
C15 H15B 0.9900 . ?
C16 C17 1.3900 . ?
C16 C21 1.3900 . ?
C17 C18 1.3900 . ?
C17 H17 0.9500 . ?
C18 C19 1.3900 . ?
C18 H18 0.9500 . ?
C19 C20 1.3900 . ?
C19 H19 0.9500 . ?
C20 C21 1.3900 . ?
C20 H20 0.9500 . ?
C21 C22 1.53(2) . ?
C22 H22A 0.9900 . ?
C22 H22B 0.9900 . ?
C24 C25 1.3900 . ?
C24 C29 1.3900 . ?
C25 C26 1.3900 . ?
C25 H25 0.9500 . ?
C26 C27 1.3900 . ?
C26 H26 0.9500 . ?
C27 C28 1.3900 . ?
C27 H27 0.9500 . ?
C28 C29 1.3900 . ?
C28 H28 0.9500 . ?
C30 C31 1.47(3) . ?
C30 H30A 0.9900 . ?
C30 H30B 0.9900 . ?
C31 C32 1.3900 . ?
C31 C36 1.3900 . ?
C32 C33 1.3900 . ?
C32 H32 0.9500 . ?
C33 C34 1.3900 . ?
C33 H33 0.9500 . ?
C34 C35 1.3900 . ?
C34 H34 0.9500 . ?
C35 C36 1.3900 . ?
C35 H35 0.9500 . ?
C36 H36 0.9500 . ?
C37 C38 1.3900 . ?
C37 C42 1.3900 . ?
C37 C43 1.48(3) . ?
C38 C39 1.3900 . ?
C38 H38 0.9500 . ?
C39 C40 1.3900 . ?
C39 H39 0.9500 . ?
C40 C41 1.3900 . ?
C40 H40 0.9500 . ?
C41 C42 1.3900 . ?
C41 H41 0.9500 . ?
C42 H42 0.9500 . ?
C43 H43A 0.9900 . ?
C43 H43B 0.9900 . ?
C45 C46 1.3900 . ?
C45 C50 1.3900 . ?
C46 C47 1.3900 . ?
C46 H46 0.9500 . ?
C47 C48 1.3900 . ?
C47 H47 0.9500 . ?
C48 C49 1.3900 . ?
C48 H48 0.9500 . ?
C49 C50 1.3900 . ?
C49 H49 0.9500 . ?
C51 C52 1.54(3) . ?
C51 H51A 0.9900 . ?
C51 H51B 0.9900 . ?
C52 C53 1.3900 . ?
C52 C57 1.3900 . ?
C53 C54 1.3900 . ?
C53 H53 0.9500 . ?
C54 C55 1.3900 . ?
C54 H54 0.9500 . ?
C55 C56 1.3900 . ?
C55 H55 0.9500 . ?
C56 C57 1.3900 . ?
C56 H56 0.9500 . ?
C57 C58 1.59(3) . ?
C58 H58A 0.9900 . ?
C58 H58B 0.9900 . ?
C60 C61 1.3900 . ?
C60 C65 1.3900 . ?
C61 C62 1.3900 . ?
C61 H61 0.9500 . ?
C62 C63 1.3900 . ?
C62 H62 0.9500 . ?
C63 C64 1.3900 . ?
C63 H63 0.9500 . ?
C64 C65 1.3900 . ?
C64 H64 0.9500 . ?
C66 C67 1.47(3) . ?
C66 H66A 0.9900 . ?
C66 H66B 0.9900 . ?
C67 C68 1.3900 . ?
C67 C72 1.3900 . ?
C68 C69 1.3900 . ?
C68 H68 0.9500 . ?
C69 C70 1.3900 . ?
C69 H69 0.9500 . ?
C70 C71 1.3900 . ?
C70 H70 0.9500 . ?
C71 C72 1.3900 . ?
C71 H71 0.9500 . ?
C72 H72 0.9500 . ?
C73 C74 1.3900 . ?
C73 C78 1.3900 . ?
C73 C79 1.52(3) . ?
C74 C75 1.3900 . ?
C74 H74 0.9500 . ?
C75 C76 1.3900 . ?
C75 H75 0.9500 . ?
C76 C77 1.3900 . ?
C76 H76 0.9500 . ?
C77 C78 1.3900 . ?
C77 H77 0.9500 . ?
C78 H78 0.9500 . ?
C79 H79A 0.9900 . ?
C79 H79B 0.9900 . ?
C81 C82 1.3900 . ?
C81 C86 1.3900 . ?
C82 C83 1.3900 . ?
C82 H82 0.9500 . ?
C83 C84 1.3900 . ?
C83 H83 0.9500 . ?
C84 C85 1.3900 . ?
C84 H84 0.9500 . ?
C85 C86 1.3900 . ?
C85 H85 0.9500 . ?
C87 C88 1.50(3) . ?
C87 H87A 0.9900 . ?
C87 H87B 0.9900 . ?
C88 C89 1.3900 . ?
C88 C93 1.3900 . ?
C89 C90 1.3900 . ?
C89 H89 0.9500 . ?
C90 C91 1.3900 . ?
C90 H90 0.9500 . ?
C91 C92 1.3900 . ?
C91 H91 0.9500 . ?
C92 C93 1.3900 . ?
C92 H92 0.9500 . ?
C93 C94 1.58(2) . ?
C94 H94A 0.9900 . ?
C94 H94B 0.9900 . ?
C96 C97 1.3900 . ?
C96 C101 1.3900 . ?
C97 C98 1.3900 . ?
C97 H97 0.9500 . ?
C98 C99 1.3900 . ?
C98 H98 0.9500 . ?
C99 C100 1.3900 . ?
C99 H99 0.9500 . ?
C100 C101 1.3900 . ?
C100 H100 0.9500 . ?
C102 C103 1.46(3) . ?
C102 H10A 0.9900 . ?
C102 H10B 0.9900 . ?
C103 C104 1.3900 . ?
C103 C108 1.3900 . ?
C104 C105 1.3900 . ?
C104 H104 0.9500 . ?
C105 C106 1.3900 . ?
C105 H105 0.9500 . ?
C106 C107 1.3900 . ?
C106 H106 0.9500 . ?
C107 C108 1.3900 . ?
C107 H107 0.9500 . ?
C108 H108 0.9500 . ?
C109 C110 1.3900 . ?
C109 C114 1.3900 . ?
C109 C115 1.51(3) . ?
C110 C111 1.3900 . ?
C110 H110 0.9500 . ?
C111 C112 1.3900 . ?
C111 H111 0.9500 . ?
C112 C113 1.3900 . ?
C112 H112 0.9500 . ?
C113 C114 1.3900 . ?
C113 H113 0.9500 . ?
C114 H114 0.9500 . ?
C115 H11A 0.9900 . ?
C115 H11B 0.9900 . ?
C117 C118 1.3900 . ?
C117 C122 1.3900 . ?
C118 C119 1.3900 . ?
C118 H118 0.9500 . ?
C119 C120 1.3900 . ?
C119 H119 0.9500 . ?
C120 C121 1.3900 . ?
C120 H120 0.9500 . ?
C121 C122 1.3900 . ?
C121 H121 0.9500 . ?
C123 C124 1.53(3) . ?
C123 H12A 0.9900 . ?
C123 H12B 0.9900 . ?
C124 C125 1.3900 . ?
C124 C129 1.3900 . ?
C125 C126 1.3900 . ?
C125 H125 0.9500 . ?
C126 C127 1.3900 . ?
C126 H126 0.9500 . ?
C127 C128 1.3900 . ?
C127 H127 0.9500 . ?
C128 C129 1.3900 . ?
C128 H128 0.9500 . ?
C129 C130 1.57(2) . ?
C130 H13A 0.9900 . ?
C130 H13B 0.9900 . ?
C132 C133 1.3900 . ?
C132 C137 1.3900 . ?
C133 C134 1.3900 . ?
C133 H133 0.9500 . ?
C134 C135 1.3900 . ?
C134 H134 0.9500 . ?
C135 C136 1.3900 . ?
C135 H135 0.9500 . ?
C136 C137 1.3900 . ?
C136 H136 0.9500 . ?
C138 C139 1.50(3) . ?
C138 H13C 0.9900 . ?
C138 H13D 0.9900 . ?
C139 C140 1.3900 . ?
C139 C144 1.3900 . ?
C140 C141 1.3900 . ?
C140 H140 0.9500 . ?
C141 C142 1.3900 . ?
C141 H141 0.9500 . ?
C142 C143 1.3900 . ?
C142 H142 0.9500 . ?
C143 C144 1.3900 . ?
C143 H143 0.9500 . ?
C144 H144 0.9500 . ?
C145 C146 1.3900 . ?
C145 C150 1.3900 . ?
C145 C151 1.48(3) . ?
C146 C147 1.3900 . ?
C146 H146 0.9500 . ?
C147 C148 1.3900 . ?
C147 H147 0.9500 . ?
C148 C149 1.3900 . ?
C148 H148 0.9500 . ?
C149 C150 1.3900 . ?
C149 H149 0.9500 . ?
C150 H150 0.9500 . ?
C151 H15C 0.9900 . ?
C151 H15D 0.9900 . ?
C153 C154 1.3900 . ?
C153 C158 1.3900 . ?
C154 C155 1.3900 . ?
C154 H154 0.9500 . ?
C155 C156 1.3900 . ?
C155 H155 0.9500 . ?
C156 C157 1.3900 . ?
C156 H156 0.9500 . ?
C157 C158 1.3900 . ?
C157 H157 0.9500 . ?
C159 C160 1.54(3) . ?
C159 H15E 0.9900 . ?
C159 H15F 0.9900 . ?
C160 C161 1.3900 . ?
C160 C165 1.3900 . ?
C161 C162 1.3900 . ?
C161 H161 0.9500 . ?
C162 C163 1.3900 . ?
C162 H162 0.9500 . ?
C163 C164 1.3900 . ?
C163 H163 0.9500 . ?
C164 C165 1.3900 . ?
C164 H164 0.9500 . ?
C165 C166 1.53(2) . ?
C166 H16A 0.9900 . ?
C166 H16B 0.9900 . ?
C168 C169 1.3900 . ?
C168 C173 1.3900 . ?
C169 C170 1.3900 . ?
C169 H169 0.9500 . ?
C170 C171 1.3900 . ?
C170 H170 0.9500 . ?
C171 C172 1.3900 . ?
C171 H171 0.9500 . ?
C172 C173 1.3900 . ?
C172 H172 0.9500 . ?
C174 C175 1.53(3) . ?
C174 H17A 0.9900 . ?
C174 H17B 0.9900 . ?
C175 C176 1.3900 . ?
C175 C180 1.3900 . ?
C176 C177 1.3900 . ?
C176 H176 0.9500 . ?
C177 C178 1.3900 . ?
C177 H177 0.9500 . ?
C178 C179 1.3900 . ?
C178 H178 0.9500 . ?
C179 C180 1.3900 . ?
C179 H179 0.9500 . ?
C180 H180 0.9500 . ?
loop_
_geom_torsion_atom_site_label_1
_geom_torsion_atom_site_label_2
_geom_torsion_atom_site_label_3
_geom_torsion_atom_site_label_4
_geom_torsion
_geom_torsion_site_symmetry_1
_geom_torsion_site_symmetry_2
_geom_torsion_site_symmetry_3
_geom_torsion_site_symmetry_4
_geom_torsion_publ_flag
C6 C1 C2 C3 0.0 . . . . ?
C7 C1 C2 C3 175(2) . . . . ?
C1 C2 C3 C4 0.0 . . . . ?
C2 C3 C4 C5 0.0 . . . . ?
C3 C4 C5 C6 0.0 . . . . ?
C4 C5 C6 C1 0.0 . . . . ?
C2 C1 C6 C5 0.0 . . . . ?
C7 C1 C6 C5 -175(2) . . . . ?
C2 C1 C7 N1 146.9(19) . . . . ?
C6 C1 C7 N1 -38(3) . . . . ?
C8 N1 C7 C1 139(2) . . . . ?
C9 N1 C7 C1 -52(4) . . . . ?
C9 N1 C8 N2 2(3) . . . . ?
C7 N1 C8 N2 172(2) . . . . ?
C9 N1 C8 Au2 173.2(16) . . . . ?
C7 N1 C8 Au2 -17(4) . . . . ?
C14 N2 C8 N1 -3(2) . . . . ?
C15 N2 C8 N1 -177(2) . . . . ?
C14 N2 C8 Au2 -174.8(14) . . . . ?
C15 N2 C8 Au2 11(3) . . . . ?
C8 N1 C9 C10 176.9(16) . . . . ?
C7 N1 C9 C10 7(3) . . . . ?
C8 N1 C9 C14 0(2) . . . . ?
C7 N1 C9 C14 -170(2) . . . . ?
N1 C9 C10 C11 -177(2) . . . . ?
C14 C9 C10 C11 0.0 . . . . ?
C9 C10 C11 C12 0.0 . . . . ?
C10 C11 C12 C13 0.0 . . . . ?
C11 C12 C13 C14 0.0 . . . . ?
C12 C13 C14 C9 0.0 . . . . ?
C12 C13 C14 N2 179.2(18) . . . . ?
N1 C9 C14 C13 177.7(16) . . . . ?
C10 C9 C14 C13 0.0 . . . . ?
N1 C9 C14 N2 -1.7(16) . . . . ?
C10 C9 C14 N2 -179.4(14) . . . . ?
C8 N2 C14 C13 -176.3(15) . . . . ?
C15 N2 C14 C13 -3(3) . . . . ?
C8 N2 C14 C9 3.0(18) . . . . ?
C15 N2 C14 C9 176.7(18) . . . . ?
C8 N2 C15 C16 -131(2) . . . . ?
C14 N2 C15 C16 57(3) . . . . ?
N2 C15 C16 C17 -124.6(16) . . . . ?
N2 C15 C16 C21 63(2) . . . . ?
C21 C16 C17 C18 0.0 . . . . ?
C15 C16 C17 C18 -172.9(17) . . . . ?
C16 C17 C18 C19 0.0 . . . . ?
C17 C18 C19 C20 0.0 . . . . ?
C18 C19 C20 C21 0.0 . . . . ?
C19 C20 C21 C16 0.0 . . . . ?
C19 C20 C21 C22 -170.7(17) . . . . ?
C17 C16 C21 C20 0.0 . . . . ?
C15 C16 C21 C20 172.3(18) . . . . ?
C17 C16 C21 C22 170.9(16) . . . . ?
C15 C16 C21 C22 -17(2) . . . . ?
C23 N3 C22 C21 -113(2) . . . . ?
C24 N3 C22 C21 73(3) . . . . ?
C20 C21 C22 N3 -35(2) . . . . ?
C16 C21 C22 N3 154.0(15) . . . . ?
C29 N4 C23 N3 1(2) . . . . ?
C30 N4 C23 N3 174.9(18) . . . . ?
C29 N4 C23 Au10 -172.5(14) . . . . ?
C30 N4 C23 Au10 1(3) . . . . ?
C24 N3 C23 N4 -5(2) . . . . ?
C22 N3 C23 N4 -179(2) . . . . ?
C24 N3 C23 Au10 169.3(14) . . . . ?
C22 N3 C23 Au10 -5(3) . . . . ?
C23 N3 C24 C25 -174.2(14) . . . . ?
C22 N3 C24 C25 0(3) . . . . ?
C23 N3 C24 C29 6.2(19) . . . . ?
C22 N3 C24 C29 -179.3(18) . . . . ?
C29 C24 C25 C26 0.0 . . . . ?
N3 C24 C25 C26 -179.6(19) . . . . ?
C24 C25 C26 C27 0.0 . . . . ?
C25 C26 C27 C28 0.0 . . . . ?
C26 C27 C28 C29 0.0 . . . . ?
C27 C28 C29 C24 0.0 . . . . ?
C27 C28 C29 N4 -173.3(18) . . . . ?
C25 C24 C29 C28 0.0 . . . . ?
N3 C24 C29 C28 179.7(14) . . . . ?
C25 C24 C29 N4 174.9(14) . . . . ?
N3 C24 C29 N4 -5.4(14) . . . . ?
C23 N4 C29 C28 176.7(15) . . . . ?
C30 N4 C29 C28 3(3) . . . . ?
C23 N4 C29 C24 2.7(18) . . . . ?
C30 N4 C29 C24 -170.9(16) . . . . ?
C23 N4 C30 C31 124(2) . . . . ?
C29 N4 C30 C31 -63(3) . . . . ?
N4 C30 C31 C32 116.4(17) . . . . ?
N4 C30 C31 C36 -70(2) . . . . ?
C36 C31 C32 C33 0.0 . . . . ?
C30 C31 C32 C33 173.8(17) . . . . ?
C31 C32 C33 C34 0.0 . . . . ?
C32 C33 C34 C35 0.0 . . . . ?
C33 C34 C35 C36 0.0 . . . . ?
C34 C35 C36 C31 0.0 . . . . ?
C32 C31 C36 C35 0.0 . . . . ?
C30 C31 C36 C35 -173.9(17) . . . . ?
C42 C37 C38 C39 0.0 . . . . ?
C43 C37 C38 C39 177.1(18) . . . . ?
C37 C38 C39 C40 0.0 . . . . ?
C38 C39 C40 C41 0.0 . . . . ?
C39 C40 C41 C42 0.0 . . . . ?
C40 C41 C42 C37 0.0 . . . . ?
C38 C37 C42 C41 0.0 . . . . ?
C43 C37 C42 C41 -176.9(19) . . . . ?
C44 N5 C43 C37 121(2) . . . . ?
C45 N5 C43 C37 -68(3) . . . . ?
C38 C37 C43 N5 163.7(14) . . . . ?
C42 C37 C43 N5 -19(3) . . . . ?
C50 N6 C44 N5 -1(2) . . . . ?
C51 N6 C44 N5 -177.7(18) . . . . ?
C50 N6 C44 Au3 -178.9(14) . . . . ?
C51 N6 C44 Au3 4(3) . . . . ?
C45 N5 C44 N6 -2(2) . . . . ?
C43 N5 C44 N6 170.4(19) . . . . ?
C45 N5 C44 Au3 176.5(13) . . . . ?
C43 N5 C44 Au3 -11(3) . . . . ?
C44 N5 C45 C46 177.1(14) . . . . ?
C43 N5 C45 C46 5(3) . . . . ?
C44 N5 C45 C50 3.3(18) . . . . ?
C43 N5 C45 C50 -168.4(18) . . . . ?
N5 C45 C46 C47 -173.1(18) . . . . ?
C50 C45 C46 C47 0.0 . . . . ?
C45 C46 C47 C48 0.0 . . . . ?
C46 C47 C48 C49 0.0 . . . . ?
C47 C48 C49 C50 0.0 . . . . ?
C44 N6 C50 C49 -175.2(14) . . . . ?
C51 N6 C50 C49 1(3) . . . . ?
C44 N6 C50 C45 2.9(19) . . . . ?
C51 N6 C50 C45 179.6(17) . . . . ?
C48 C49 C50 N6 177.9(19) . . . . ?
C48 C49 C50 C45 0.0 . . . . ?
N5 C45 C50 N6 -3.8(14) . . . . ?
C46 C45 C50 N6 -178.4(14) . . . . ?
N5 C45 C50 C49 174.7(14) . . . . ?
C46 C45 C50 C49 0.0 . . . . ?
C44 N6 C51 C52 -126(2) . . . . ?
C50 N6 C51 C52 58(3) . . . . ?
N6 C51 C52 C53 -121.0(16) . . . . ?
N6 C51 C52 C57 67(2) . . . . ?
C57 C52 C53 C54 0.0 . . . . ?
C51 C52 C53 C54 -172.7(15) . . . . ?
C52 C53 C54 C55 0.0 . . . . ?
C53 C54 C55 C56 0.0 . . . . ?
C54 C55 C56 C57 0.0 . . . . ?
C55 C56 C57 C52 0.0 . . . . ?
C55 C56 C57 C58 -169.1(15) . . . . ?
C53 C52 C57 C56 0.0 . . . . ?
C51 C52 C57 C56 172.1(16) . . . . ?
C53 C52 C57 C58 168.7(16) . . . . ?
C51 C52 C57 C58 -19.2(19) . . . . ?
C59 N7 C58 C57 -103(2) . . . . ?
C60 N7 C58 C57 82(3) . . . . ?
C56 C57 C58 N7 -42(2) . . . . ?
C52 C57 C58 N7 149.1(14) . . . . ?
C65 N8 C59 N7 1(2) . . . . ?
C66 N8 C59 N7 176(2) . . . . ?
C65 N8 C59 Au11 -168.7(14) . . . . ?
C66 N8 C59 Au11 7(3) . . . . ?
C60 N7 C59 N8 -4(3) . . . . ?
C58 N7 C59 N8 180(2) . . . . ?
C60 N7 C59 Au11 164.9(15) . . . . ?
C58 N7 C59 Au11 -11(3) . . . . ?
C59 N7 C60 C61 -176.5(16) . . . . ?
C58 N7 C60 C61 -1(3) . . . . ?
C59 N7 C60 C65 6(2) . . . . ?
C58 N7 C60 C65 -178(2) . . . . ?
N7 C60 C61 C62 -177(2) . . . . ?
C65 C60 C61 C62 0.0 . . . . ?
C60 C61 C62 C63 0.0 . . . . ?
C61 C62 C63 C64 0.0 . . . . ?
C62 C63 C64 C65 0.0 . . . . ?
C63 C64 C65 C60 0.0 . . . . ?
C63 C64 C65 N8 -176(2) . . . . ?
N7 C60 C65 C64 177.8(17) . . . . ?
C61 C60 C65 C64 0.0 . . . . ?
N7 C60 C65 N8 -5.5(17) . . . . ?
C61 C60 C65 N8 176.7(16) . . . . ?
C59 N8 C65 C64 179.1(16) . . . . ?
C66 N8 C65 C64 3(3) . . . . ?
C59 N8 C65 C60 3(2) . . . . ?
C66 N8 C65 C60 -173.0(19) . . . . ?
C59 N8 C66 C67 118(3) . . . . ?
C65 N8 C66 C67 -67(3) . . . . ?
N8 C66 C67 C68 -55(3) . . . . ?
N8 C66 C67 C72 128.9(19) . . . . ?
C72 C67 C68 C69 0.0 . . . . ?
C66 C67 C68 C69 -176(2) . . . . ?
C67 C68 C69 C70 0.0 . . . . ?
C68 C69 C70 C71 0.0 . . . . ?
C69 C70 C71 C72 0.0 . . . . ?
C70 C71 C72 C67 0.0 . . . . ?
C68 C67 C72 C71 0.0 . . . . ?
C66 C67 C72 C71 176(2) . . . . ?
C78 C73 C74 C75 0.0 . . . . ?
C79 C73 C74 C75 177.8(19) . . . . ?
C73 C74 C75 C76 0.0 . . . . ?
C74 C75 C76 C77 0.0 . . . . ?
C75 C76 C77 C78 0.0 . . . . ?
C76 C77 C78 C73 0.0 . . . . ?
C74 C73 C78 C77 0.0 . . . . ?
C79 C73 C78 C77 -177.8(19) . . . . ?
C80 N9 C79 C73 108(3) . . . . ?
C81 N9 C79 C73 -75(3) . . . . ?
C74 C73 C79 N9 158.6(16) . . . . ?
C78 C73 C79 N9 -24(3) . . . . ?
C81 N9 C80 N10 -2(3) . . . . ?
C79 N9 C80 N10 176(2) . . . . ?
C81 N9 C80 Au4 179.4(16) . . . . ?
C79 N9 C80 Au4 -3(4) . . . . ?
C86 N10 C80 N9 2(3) . . . . ?
C87 N10 C80 N9 -175(2) . . . . ?
C86 N10 C80 Au4 -179.8(15) . . . . ?
C87 N10 C80 Au4 3(3) . . . . ?
C80 N9 C81 C82 179.4(16) . . . . ?
C79 N9 C81 C82 2(4) . . . . ?
C80 N9 C81 C86 2(2) . . . . ?
C79 N9 C81 C86 -176(2) . . . . ?
N9 C81 C82 C83 -178(2) . . . . ?
C86 C81 C82 C83 0.0 . . . . ?
C81 C82 C83 C84 0.0 . . . . ?
C82 C83 C84 C85 0.0 . . . . ?
C83 C84 C85 C86 0.0 . . . . ?
C80 N10 C86 C85 -179.0(17) . . . . ?
C87 N10 C86 C85 -2(3) . . . . ?
C80 N10 C86 C81 0(2) . . . . ?
C87 N10 C86 C81 176.5(19) . . . . ?
C84 C85 C86 N10 178(2) . . . . ?
C84 C85 C86 C81 0.0 . . . . ?
N9 C81 C86 N10 -0.7(18) . . . . ?
C82 C81 C86 N10 -178.8(17) . . . . ?
N9 C81 C86 C85 178.1(19) . . . . ?
C82 C81 C86 C85 0.0 . . . . ?
C80 N10 C87 C88 -128(2) . . . . ?
C86 N10 C87 C88 56(3) . . . . ?
N10 C87 C88 C89 -120.3(18) . . . . ?
N10 C87 C88 C93 67(2) . . . . ?
C93 C88 C89 C90 0.0 . . . . ?
C87 C88 C89 C90 -173.1(15) . . . . ?
C88 C89 C90 C91 0.0 . . . . ?
C89 C90 C91 C92 0.0 . . . . ?
C90 C91 C92 C93 0.0 . . . . ?
C91 C92 C93 C88 0.0 . . . . ?
C91 C92 C93 C94 -177.9(15) . . . . ?
C89 C88 C93 C92 0.0 . . . . ?
C87 C88 C93 C92 172.5(16) . . . . ?
C89 C88 C93 C94 177.8(16) . . . . ?
C87 C88 C93 C94 -9.7(19) . . . . ?
C96 N11 C94 C93 79(3) . . . . ?
C95 N11 C94 C93 -101(2) . . . . ?
C92 C93 C94 N11 -44(2) . . . . ?
C88 C93 C94 N11 138.1(16) . . . . ?
C101 N12 C95 N11 1(2) . . . . ?
C102 N12 C95 N11 176.5(19) . . . . ?
C101 N12 C95 Au12 -164.0(14) . . . . ?
C102 N12 C95 Au12 11(3) . . . . ?
C96 N11 C95 N12 -5(2) . . . . ?
C94 N11 C95 N12 175.5(19) . . . . ?
C96 N11 C95 Au12 160.8(14) . . . . ?
C94 N11 C95 Au12 -19(3) . . . . ?
C95 N11 C96 C97 -175.5(14) . . . . ?
C94 N11 C96 C97 4(3) . . . . ?
C95 N11 C96 C101 6.0(18) . . . . ?
C94 N11 C96 C101 -174.1(18) . . . . ?
N11 C96 C97 C98 -178.4(19) . . . . ?
C101 C96 C97 C98 0.0 . . . . ?
C96 C97 C98 C99 0.0 . . . . ?
C97 C98 C99 C100 0.0 . . . . ?
C98 C99 C100 C101 0.0 . . . . ?
C99 C100 C101 C96 0.0 . . . . ?
C99 C100 C101 N12 -175.3(19) . . . . ?
N11 C96 C101 C100 178.8(15) . . . . ?
C97 C96 C101 C100 0.0 . . . . ?
N11 C96 C101 N12 -4.7(14) . . . . ?
C97 C96 C101 N12 176.5(14) . . . . ?
C95 N12 C101 C100 177.9(14) . . . . ?
C102 N12 C101 C100 3(3) . . . . ?
C95 N12 C101 C96 2.1(18) . . . . ?
C102 N12 C101 C96 -173.2(17) . . . . ?
C95 N12 C102 C103 124(2) . . . . ?
C101 N12 C102 C103 -62(3) . . . . ?
N12 C102 C103 C104 -57(2) . . . . ?
N12 C102 C103 C108 119.5(18) . . . . ?
C108 C103 C104 C105 0.0 . . . . ?
C102 C103 C104 C105 177.0(19) . . . . ?
C103 C104 C105 C106 0.0 . . . . ?
C104 C105 C106 C107 0.0 . . . . ?
C105 C106 C107 C108 0.0 . . . . ?
C106 C107 C108 C103 0.0 . . . . ?
C104 C103 C108 C107 0.0 . . . . ?
C102 C103 C108 C107 -177(2) . . . . ?
C114 C109 C110 C111 0.0 . . . . ?
C115 C109 C110 C111 -177(2) . . . . ?
C109 C110 C111 C112 0.0 . . . . ?
C110 C111 C112 C113 0.0 . . . . ?
C111 C112 C113 C114 0.0 . . . . ?
C112 C113 C114 C109 0.0 . . . . ?
C110 C109 C114 C113 0.0 . . . . ?
C115 C109 C114 C113 177(2) . . . . ?
C117 N13 C115 C109 -51(4) . . . . ?
C116 N13 C115 C109 139(2) . . . . ?
C110 C109 C115 N13 138(2) . . . . ?
C114 C109 C115 N13 -40(3) . . . . ?
C122 N14 C116 N13 -4(3) . . . . ?
C123 N14 C116 N13 -173(2) . . . . ?
C122 N14 C116 Au5 178.7(15) . . . . ?
C123 N14 C116 Au5 10(3) . . . . ?
C117 N13 C116 N14 4(3) . . . . ?
C115 N13 C116 N14 175(2) . . . . ?
C117 N13 C116 Au5 -178.8(15) . . . . ?
C115 N13 C116 Au5 -8(4) . . . . ?
C116 N13 C117 C118 174.8(15) . . . . ?
C115 N13 C117 C118 4(3) . . . . ?
C116 N13 C117 C122 -2(2) . . . . ?
C115 N13 C117 C122 -173(2) . . . . ?
N13 C117 C118 C119 -177(2) . . . . ?
C122 C117 C118 C119 0.0 . . . . ?
C117 C118 C119 C120 0.0 . . . . ?
C118 C119 C120 C121 0.0 . . . . ?
C119 C120 C121 C122 0.0 . . . . ?
C116 N14 C122 C121 -174.3(16) . . . . ?
C123 N14 C122 C121 -6(3) . . . . ?
C116 N14 C122 C117 3(2) . . . . ?
C123 N14 C122 C117 171.2(18) . . . . ?
C120 C121 C122 N14 177(2) . . . . ?
C120 C121 C122 C117 0.0 . . . . ?
N13 C117 C122 N14 -0.4(17) . . . . ?
C118 C117 C122 N14 -177.7(16) . . . . ?
N13 C117 C122 C121 177.3(17) . . . . ?
C118 C117 C122 C121 0.0 . . . . ?
C116 N14 C123 C124 -123(2) . . . . ?
C122 N14 C123 C124 71(3) . . . . ?
N14 C123 C124 C125 -129.5(16) . . . . ?
N14 C123 C124 C129 63(2) . . . . ?
C129 C124 C125 C126 0.0 . . . . ?
C123 C124 C125 C126 -167.7(15) . . . . ?
C124 C125 C126 C127 0.0 . . . . ?
C125 C126 C127 C128 0.0 . . . . ?
C126 C127 C128 C129 0.0 . . . . ?
C127 C128 C129 C124 0.0 . . . . ?
C127 C128 C129 C130 -173.0(17) . . . . ?
C125 C124 C129 C128 0.0 . . . . ?
C123 C124 C129 C128 166.6(17) . . . . ?
C125 C124 C129 C130 173.1(16) . . . . ?
C123 C124 C129 C130 -20.3(19) . . . . ?
C131 N15 C130 C129 -108(2) . . . . ?
C132 N15 C130 C129 76(3) . . . . ?
C128 C129 C130 N15 -26(2) . . . . ?
C124 C129 C130 N15 161.1(14) . . . . ?
C137 N16 C131 N15 2(2) . . . . ?
C138 N16 C131 N15 178(2) . . . . ?
C137 N16 C131 Au8 -168.5(13) . . . . ?
C138 N16 C131 Au8 8(3) . . . . ?
C132 N15 C131 N16 -4(2) . . . . ?
C130 N15 C131 N16 -180.0(19) . . . . ?
C132 N15 C131 Au8 167.0(12) . . . . ?
C130 N15 C131 Au8 -9(3) . . . . ?
C131 N15 C132 C133 -173.7(13) . . . . ?
C130 N15 C132 C133 2(3) . . . . ?
C131 N15 C132 C137 4.0(17) . . . . ?
C130 N15 C132 C137 -179.9(17) . . . . ?
N15 C132 C133 C134 177.4(18) . . . . ?
C137 C132 C133 C134 0.0 . . . . ?
C132 C133 C134 C135 0.0 . . . . ?
C133 C134 C135 C136 0.0 . . . . ?
C134 C135 C136 C137 0.0 . . . . ?
C135 C136 C137 C132 0.0 . . . . ?
C135 C136 C137 N16 -173.8(19) . . . . ?
N15 C132 C137 C136 -178.1(14) . . . . ?
C133 C132 C137 C136 0.0 . . . . ?
N15 C132 C137 N16 -2.7(14) . . . . ?
C133 C132 C137 N16 175.3(14) . . . . ?
C131 N16 C137 C136 175.0(13) . . . . ?
C138 N16 C137 C136 -1(3) . . . . ?
C131 N16 C137 C132 0.6(19) . . . . ?
C138 N16 C137 C132 -175.8(17) . . . . ?
C131 N16 C138 C139 123(2) . . . . ?
C137 N16 C138 C139 -61(3) . . . . ?
N16 C138 C139 C140 -60(2) . . . . ?
N16 C138 C139 C144 124.3(15) . . . . ?
C144 C139 C140 C141 0.0 . . . . ?
C138 C139 C140 C141 -175.9(16) . . . . ?
C139 C140 C141 C142 0.0 . . . . ?
C140 C141 C142 C143 0.0 . . . . ?
C141 C142 C143 C144 0.0 . . . . ?
C142 C143 C144 C139 0.0 . . . . ?
C140 C139 C144 C143 0.0 . . . . ?
C138 C139 C144 C143 175.8(17) . . . . ?
C150 C145 C146 C147 0.0 . . . . ?
C151 C145 C146 C147 175.0(19) . . . . ?
C145 C146 C147 C148 0.0 . . . . ?
C146 C147 C148 C149 0.0 . . . . ?
C147 C148 C149 C150 0.0 . . . . ?
C148 C149 C150 C145 0.0 . . . . ?
C146 C145 C150 C149 0.0 . . . . ?
C151 C145 C150 C149 -175(2) . . . . ?
C152 N17 C151 C145 135(2) . . . . ?
C153 N17 C151 C145 -49(3) . . . . ?
C146 C145 C151 N17 -31(3) . . . . ?
C150 C145 C151 N17 143.9(17) . . . . ?
C153 N17 C152 N18 -3(3) . . . . ?
C151 N17 C152 N18 174(2) . . . . ?
C153 N17 C152 Au6 170.5(15) . . . . ?
C151 N17 C152 Au6 -13(3) . . . . ?
C158 N18 C152 N17 5(3) . . . . ?
C159 N18 C152 N17 -176(2) . . . . ?
C158 N18 C152 Au6 -168.8(15) . . . . ?
C159 N18 C152 Au6 10(3) . . . . ?
C152 N17 C153 C154 178.9(16) . . . . ?
C151 N17 C153 C154 2(3) . . . . ?
C152 N17 C153 C158 0(2) . . . . ?
C151 N17 C153 C158 -177.0(19) . . . . ?
C158 C153 C154 C155 0.0 . . . . ?
N17 C153 C154 C155 -179(2) . . . . ?
C153 C154 C155 C156 0.0 . . . . ?
C154 C155 C156 C157 0.0 . . . . ?
C155 C156 C157 C158 0.0 . . . . ?
C156 C157 C158 C153 0.0 . . . . ?
C156 C157 C158 N18 175(2) . . . . ?
C154 C153 C158 C157 0.0 . . . . ?
N17 C153 C158 C157 179.1(16) . . . . ?
C154 C153 C158 N18 -176.1(16) . . . . ?
N17 C153 C158 N18 3.1(15) . . . . ?
C152 N18 C158 C157 179.7(16) . . . . ?
C159 N18 C158 C157 1(3) . . . . ?
C152 N18 C158 C153 -5(2) . . . . ?
C159 N18 C158 C153 176.5(18) . . . . ?
C152 N18 C159 C160 -124(2) . . . . ?
C158 N18 C159 C160 54(3) . . . . ?
N18 C159 C160 C161 -135.4(16) . . . . ?
N18 C159 C160 C165 54(2) . . . . ?
C165 C160 C161 C162 0.0 . . . . ?
C159 C160 C161 C162 -171.1(16) . . . . ?
C160 C161 C162 C163 0.0 . . . . ?
C161 C162 C163 C164 0.0 . . . . ?
C162 C163 C164 C165 0.0 . . . . ?
C163 C164 C165 C160 0.0 . . . . ?
C163 C164 C165 C166 -175.6(16) . . . . ?
C161 C160 C165 C164 0.0 . . . . ?
C159 C160 C165 C164 170.2(18) . . . . ?
C161 C160 C165 C166 175.6(16) . . . . ?
C159 C160 C165 C166 -14(2) . . . . ?
C167 N19 C166 C165 -92(2) . . . . ?
C168 N19 C166 C165 76(2) . . . . ?
C164 C165 C166 N19 -36(2) . . . . ?
C160 C165 C166 N19 148.9(14) . . . . ?
C168 N19 C167 N20 -1(2) . . . . ?
C166 N19 C167 N20 167.7(18) . . . . ?
C168 N19 C167 Au9 166.8(14) . . . . ?
C166 N19 C167 Au9 -24(3) . . . . ?
C173 N20 C167 N19 -2(2) . . . . ?
C174 N20 C167 N19 175.0(19) . . . . ?
C173 N20 C167 Au9 -169.3(15) . . . . ?
C174 N20 C167 Au9 7(3) . . . . ?
C167 N19 C168 C169 -179.4(15) . . . . ?
C166 N19 C168 C169 12(3) . . . . ?
C167 N19 C168 C173 3.3(19) . . . . ?
C166 N19 C168 C173 -165.5(16) . . . . ?
N19 C168 C169 C170 -177.0(19) . . . . ?
C173 C168 C169 C170 0.0 . . . . ?
C168 C169 C170 C171 0.0 . . . . ?
C169 C170 C171 C172 0.0 . . . . ?
C170 C171 C172 C173 0.0 . . . . ?
C167 N20 C173 C172 -178.6(15) . . . . ?
C174 N20 C173 C172 5(3) . . . . ?
C167 N20 C173 C168 3.5(19) . . . . ?
C174 N20 C173 C168 -172.8(19) . . . . ?
C171 C172 C173 N20 -178(2) . . . . ?
C171 C172 C173 C168 0.0 . . . . ?
N19 C168 C173 N20 -4.1(14) . . . . ?
C169 C168 C173 N20 178.3(14) . . . . ?
N19 C168 C173 C172 177.7(14) . . . . ?
C169 C168 C173 C172 0.0 . . . . ?
C173 N20 C174 C175 -44(3) . . . . ?
C167 N20 C174 C175 140(2) . . . . ?
N20 C174 C175 C176 -60(2) . . . . ?
N20 C174 C175 C180 116.6(17) . . . . ?
C180 C175 C176 C177 0.0 . . . . ?
C174 C175 C176 C177 176.5(16) . . . . ?
C175 C176 C177 C178 0.0 . . . . ?
C176 C177 C178 C179 0.0 . . . . ?
C177 C178 C179 C180 0.0 . . . . ?
C178 C179 C180 C175 0.0 . . . . ?
C176 C175 C180 C179 0.0 . . . . ?
C174 C175 C180 C179 -176.5(15) . . . . ?
