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#$Date: 2021-07-08 12:27:21 +0300 (Thu, 08 Jul 2021) $
#$Revision: 267392 $
#$URL: file:///home/coder/svn-repositories/cod/cif/1/56/40/1564057.cif $
#------------------------------------------------------------------------------
#
# This file is available in the Crystallography Open Database (COD),
# http://www.crystallography.net/
#
# All data on this site have been placed in the public domain by the
# contributors.
#
data_1564057
loop_
_publ_author_name
'Hu, Peng'
'Wu, Yan-Ni'
'Zhao, Yan-Hua'
'Cao, Jiang-Fei'
'Lai, Jia-Long'
'Ma, Dan-Yu'
'Zhu, Li-Li'
'Xiao, Feng-Ping'
_publ_section_title
;
 Structure changes from radical-3d ring dimer to radical-3d-4f 1D chain
 with different magnetic properties
;
_journal_name_full               'Inorganica Chimica Acta'
_journal_page_first              119867
_journal_paper_doi               10.1016/j.ica.2020.119867
_journal_volume                  512
_journal_year                    2020
_chemical_formula_sum            'C51 H41 Cu Dy F30 N6 O16'
_chemical_formula_weight         1789.94
_space_group_crystal_system      monoclinic
_space_group_IT_number           15
_space_group_name_Hall           '-C 2yc'
_space_group_name_H-M_alt        'C 1 2/c 1'
_atom_sites_solution_hydrogens   geom
_audit_creation_method           SHELXL-2014
_cell_angle_alpha                90
_cell_angle_beta                 109.007(2)
_cell_angle_gamma                90
_cell_formula_units_Z            4
_cell_length_a                   30.582(2)
_cell_length_b                   10.4250(7)
_cell_length_c                   22.2316(16)
_cell_measurement_reflns_used    15598
_cell_measurement_temperature    293(2)
_cell_measurement_theta_max      27.9
_cell_measurement_theta_min      1.7
_cell_volume                     6701.4(8)
_computing_structure_refinement  'SHELXL-2014 (Sheldrick, 2014)'
_diffrn_ambient_temperature      293(2)
_diffrn_measured_fraction_theta_full 0.948
_diffrn_measured_fraction_theta_max 0.975
_diffrn_measurement_device_type  CCD
_diffrn_radiation_type           MoK\a
_diffrn_radiation_wavelength     0.71073
_diffrn_reflns_av_R_equivalents  0.0275
_diffrn_reflns_av_unetI/netI     0.0256
_diffrn_reflns_Laue_measured_fraction_full 0.948
_diffrn_reflns_Laue_measured_fraction_max 0.975
_diffrn_reflns_limit_h_max       36
_diffrn_reflns_limit_h_min       -36
_diffrn_reflns_limit_k_max       12
_diffrn_reflns_limit_k_min       -12
_diffrn_reflns_limit_l_max       26
_diffrn_reflns_limit_l_min       -26
_diffrn_reflns_number            22753
_diffrn_reflns_point_group_measured_fraction_full 0.948
_diffrn_reflns_point_group_measured_fraction_max 0.975
_diffrn_reflns_theta_full        25.242
_diffrn_reflns_theta_max         25.015
_diffrn_reflns_theta_min         1.938
_exptl_absorpt_coefficient_mu    1.574
_exptl_crystal_colour            purple
_exptl_crystal_density_diffrn    1.774
_exptl_crystal_description       block
_exptl_crystal_F_000             3528
_refine_diff_density_max         1.170
_refine_diff_density_min         -0.515
_refine_diff_density_rms         0.126
_refine_ls_extinction_coef       .
_refine_ls_extinction_method     none
_refine_ls_goodness_of_fit_ref   0.999
_refine_ls_hydrogen_treatment    constr
_refine_ls_matrix_type           full
_refine_ls_number_parameters     481
_refine_ls_number_reflns         5772
_refine_ls_number_restraints     2
_refine_ls_restrained_S_all      1.008
_refine_ls_R_factor_all          0.0446
_refine_ls_R_factor_gt           0.0399
_refine_ls_shift/su_max          0.001
_refine_ls_shift/su_mean         0.000
_refine_ls_structure_factor_coef Fsqd
_refine_ls_weighting_details
'w=1/[σ²(Fo²)+(0.1000P)²+22.0000P] where P=(Fo²+2Fc²)/3'
_refine_ls_weighting_scheme      calc
_refine_ls_wR_factor_gt          0.1219
_refine_ls_wR_factor_ref         0.1308
_reflns_Friedel_coverage         0.000
_reflns_Friedel_fraction_full    .
_reflns_Friedel_fraction_max     .
_reflns_number_gt                5287
_reflns_number_total             5772
_reflns_threshold_expression     'I > 2σ(I)'
_cod_data_source_file            dycu.cif
_cod_data_source_block           dycu
_cod_original_sg_symbol_H-M      'C 2/c'
_cod_database_code               1564057
_shelx_space_group_comment
;
The symmetry employed for this shelxl refinement is uniquely defined
by the following loop, which should always be used as a source of
symmetry information in preference to the above space-group names.
They are only intended as comments.
;
_shelxl_version_number           2014-3
loop_
_space_group_symop_operation_xyz
'x, y, z'
'-x, y, -z+1/2'
'x+1/2, y+1/2, z'
'-x+1/2, y+1/2, -z+1/2'
'-x, -y, -z'
'x, -y, z-1/2'
'-x+1/2, -y+1/2, -z'
'x+1/2, -y+1/2, z-1/2'
loop_
_atom_site_label
_atom_site_type_symbol
_atom_site_fract_x
_atom_site_fract_y
_atom_site_fract_z
_atom_site_U_iso_or_equiv
_atom_site_adp_type
_atom_site_occupancy
_atom_site_site_symmetry_order
_atom_site_calc_flag
_atom_site_refinement_flags_posn
_atom_site_refinement_flags_adp
_atom_site_refinement_flags_occupancy
_atom_site_disorder_assembly
_atom_site_disorder_group
Dy1 Dy 0.0000 1.01122(2) 0.2500 0.02573(13) Uani 1 2 d S T P . .
Cu1 Cu 0.2500 0.7500 0.5000 0.02641(18) Uani 1 2 d S U P . .
F14 F 0.0038(2) 1.5067(3) 0.1456(3) 0.0921(17) Uani 1 1 d . . . . .
F15 F -0.06219(12) 1.4138(3) 0.10541(18) 0.0709(10) Uani 1 1 d . . . . .
F13 F -0.00202(14) 1.3354(4) 0.08943(18) 0.0704(10) Uani 1 1 d . . . . .
F8 F 0.14045(12) 0.7182(4) 0.2836(2) 0.0825(13) Uani 1 1 d . . . . .
F11 F -0.02166(16) 0.9013(3) 0.02763(17) 0.0757(11) Uani 1 1 d . . . . .
F5 F 0.1807(2) 0.3141(4) 0.3767(3) 0.117(2) Uani 1 1 d . . . . .
F12 F -0.0622(3) 0.7351(7) 0.0181(3) 0.160(3) Uani 1 1 d . . . . .
F6 F 0.20885(16) 0.4489(5) 0.3306(2) 0.0841(12) Uani 1 1 d . . . . .
F2 F 0.17552(19) 0.5361(5) 0.6300(3) 0.0934(14) Uani 1 1 d . . . . .
F9 F 0.08470(16) 0.6200(6) 0.2254(3) 0.142(3) Uani 1 1 d . . . . .
F7 F 0.1129(2) 0.5633(5) 0.3186(4) 0.152(3) Uani 1 1 d . . . . .
F3 F 0.1683(2) 0.3632(4) 0.5815(3) 0.1128(19) Uani 1 1 d . . . . .
F1 F 0.1200(2) 0.5082(8) 0.5487(4) 0.155(4) Uani 1 1 d . . . . .
F10 F 0.0090(2) 0.7310(5) 0.0691(3) 0.125(2) Uani 1 1 d . . . . .
F4 F 0.2540(2) 0.3456(6) 0.4061(3) 0.125(2) Uani 1 1 d . . . . .
O7 O -0.01775(11) 0.9289(3) 0.14718(15) 0.0356(7) Uani 1 1 d . . . . .
O5 O 0.07395(9) 1.0931(3) 0.26678(14) 0.0314(6) Uani 1 1 d . . . . .
O8 O -0.01118(9) 1.1919(3) 0.18220(14) 0.0311(6) Uani 1 1 d . . . . .
O2 O 0.22846(11) 0.6083(3) 0.42871(16) 0.0421(7) Uani 1 1 d . U . . .
O1 O 0.20512(11) 0.6551(3) 0.54479(17) 0.0427(7) Uani 1 1 d . U . . .
O3 O 0.11541(13) 1.0494(4) 0.50133(16) 0.0477(9) Uani 1 1 d . . . . .
O6 O 0.05089(11) 0.8365(3) 0.25780(16) 0.0409(8) Uani 1 1 d . . . . .
O4 O 0.22884(16) 1.0128(5) 0.3048(2) 0.0758(17) Uani 1 1 d . . . . .
N2 N 0.11326(11) 1.0745(3) 0.25735(16) 0.0260(7) Uani 1 1 d . . . . .
N1 N 0.19725(12) 0.8678(3) 0.45461(16) 0.0293(7) Uani 1 1 d . . . . .
N3 N 0.18656(13) 1.0392(5) 0.27569(19) 0.0394(9) Uani 1 1 d . . . . .
C23 C -0.0169(2) 1.3937(5) 0.1333(3) 0.0536(14) Uani 1 1 d . . . . .
C21 C 0.0000 1.3732(6) 0.2500 0.0488(18) Uani 1 2 d S T P . .
H21 H 0.0000 1.4624 0.2500 0.059 Uiso 1 2 calc R U P . .
C8 C 0.17159(15) 0.9178(4) 0.4872(2) 0.0331(9) Uani 1 1 d . . . . .
H8 H 0.1765 0.8900 0.5287 0.040 Uiso 1 1 calc R U . . .
C9 C 0.19050(13) 0.9065(4) 0.39522(19) 0.0274(8) Uani 1 1 d . . . . .
H9 H 0.2084 0.8716 0.3726 0.033 Uiso 1 1 calc R U . . .
C10 C 0.15731(15) 0.9979(3) 0.3664(2) 0.0268(9) Uani 1 1 d . . . . .
C7 C 0.13812(17) 1.0092(4) 0.4617(2) 0.0306(9) Uani 1 1 d . . . . .
C11 C 0.13054(14) 1.0510(4) 0.40009(19) 0.0279(8) Uani 1 1 d . . . . .
H11 H 0.1082 1.1127 0.3817 0.033 Uiso 1 1 calc R U . . .
C25 C -0.03714(16) 0.8295(4) 0.1201(2) 0.0384(10) Uani 1 1 d . . . . .
C12 C 0.15223(14) 1.0367(4) 0.3015(2) 0.0273(8) Uani 1 1 d . . . . .
C19 C 0.10203(17) 0.6631(4) 0.2815(3) 0.0449(12) Uani 1 1 d . . . . .
C2 C 0.2118(2) 0.5034(4) 0.4358(3) 0.0455(13) Uani 1 1 d . . . . .
C17 C 0.12083(15) 1.1205(5) 0.1975(2) 0.0364(10) Uani 1 1 d . . . . .
C14 C 0.16917(16) 1.0641(5) 0.2055(2) 0.0406(11) Uani 1 1 d . . . . .
C3 C 0.1934(2) 0.4647(5) 0.4826(3) 0.0512(13) Uani 1 1 d . . . . .
H3 H 0.1824 0.3811 0.4809 0.061 Uiso 1 1 calc R U . . .
C20 C 0.07001(16) 0.7575(4) 0.3002(2) 0.0371(10) Uani 1 1 d . . . . .
C1 C 0.2133(3) 0.4001(6) 0.3869(4) 0.0686(18) Uani 1 1 d . . . . .
C6 C 0.08359(18) 1.1514(5) 0.4802(2) 0.0478(12) Uani 1 1 d . . . . .
H6A H 0.0595 1.1261 0.4422 0.072 Uiso 1 1 calc R U . . .
H6B H 0.0993 1.2252 0.4715 0.072 Uiso 1 1 calc R U . . .
H6C H 0.0704 1.1722 0.5127 0.072 Uiso 1 1 calc R U . . .
C4 C 0.19034(17) 0.5443(5) 0.5321(3) 0.0434(11) Uani 1 1 d . . . . .
C16 C 0.08219(19) 1.0711(7) 0.1400(2) 0.0550(14) Uani 1 1 d . . . . .
H16A H 0.0782 0.9807 0.1445 0.082 Uiso 1 1 calc R U . . .
H16B H 0.0900 1.0866 0.1021 0.082 Uiso 1 1 calc R U . . .
H16C H 0.0539 1.1149 0.1370 0.082 Uiso 1 1 calc R U . . .
C22 C -0.00846(14) 1.3106(4) 0.1922(2) 0.0367(10) Uani 1 1 d . . . . .
C18 C 0.1193(2) 1.2663(5) 0.1997(3) 0.0510(13) Uani 1 1 d . . . . .
H18A H 0.0897 1.2932 0.2015 0.076 Uiso 1 1 calc R U . . .
H18B H 0.1240 1.3011 0.1623 0.076 Uiso 1 1 calc R U . . .
H18C H 0.1432 1.2966 0.2368 0.076 Uiso 1 1 calc R U . . .
C13 C 0.1684(2) 0.9345(7) 0.1742(3) 0.0604(15) Uani 1 1 d . . . . .
H13A H 0.1993 0.9009 0.1859 0.091 Uiso 1 1 calc R U . . .
H13B H 0.1563 0.9440 0.1288 0.091 Uiso 1 1 calc R U . . .
H13C H 0.1492 0.8765 0.1880 0.091 Uiso 1 1 calc R U . . .
C5 C 0.1639(3) 0.4882(6) 0.5742(4) 0.0592(17) Uani 1 1 d . . . . .
C24 C -0.06486(19) 0.7454(5) 0.1404(3) 0.0471(12) Uani 1 1 d . . . . .
H24 H -0.0802 0.6797 0.1135 0.057 Uiso 1 1 calc R U . . .
C26 C -0.0288(2) 0.7986(5) 0.0569(3) 0.0572(15) Uani 1 1 d . . . . .
C15 C 0.20217(19) 1.1561(7) 0.1883(3) 0.0609(16) Uani 1 1 d . . . . .
H15A H 0.2058 1.2324 0.2136 0.091 Uiso 1 1 calc R U . . .
H15B H 0.1897 1.1783 0.1441 0.091 Uiso 1 1 calc R U . . .
H15C H 0.2317 1.1155 0.1964 0.091 Uiso 1 1 calc R U . . .
loop_
_atom_type_symbol
_atom_type_description
_atom_type_scat_dispersion_real
_atom_type_scat_dispersion_imag
_atom_type_scat_source
C C 0.0033 0.0016 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
H H 0.0000 0.0000 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
Cu Cu 0.3201 1.2651 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
Dy Dy -0.1892 4.4098 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
F F 0.0171 0.0103 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
N N 0.0061 0.0033 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
O O 0.0106 0.0060 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
loop_
_geom_angle_atom_site_label_1
_geom_angle_atom_site_label_2
_geom_angle_atom_site_label_3
_geom_angle
_geom_angle_site_symmetry_1
_geom_angle_site_symmetry_3
O5 Dy1 O5 137.02(15) 2 .
O5 Dy1 O7 94.24(11) 2 .
O5 Dy1 O7 101.28(10) . .
O5 Dy1 O7 101.27(10) 2 2
O5 Dy1 O7 94.24(11) . 2
O7 Dy1 O7 136.86(15) . 2
O5 Dy1 O6 71.91(10) 2 2
O5 Dy1 O6 151.03(12) . 2
O7 Dy1 O6 72.99(11) . 2
O7 Dy1 O6 74.11(12) 2 2
O5 Dy1 O6 151.03(12) 2 .
O5 Dy1 O6 71.91(10) . .
O7 Dy1 O6 74.12(11) . .
O7 Dy1 O6 72.99(11) 2 .
O6 Dy1 O6 79.28(16) 2 .
O5 Dy1 O8 71.04(10) 2 .
O5 Dy1 O8 75.04(10) . .
O7 Dy1 O8 74.31(10) . .
O7 Dy1 O8 148.84(11) 2 .
O6 Dy1 O8 127.66(11) 2 .
O6 Dy1 O8 127.93(11) . .
O5 Dy1 O8 75.03(10) 2 2
O5 Dy1 O8 71.04(10) . 2
O7 Dy1 O8 148.84(11) . 2
O7 Dy1 O8 74.30(10) 2 2
O6 Dy1 O8 127.93(11) 2 2
O6 Dy1 O8 127.66(11) . 2
O8 Dy1 O8 74.54(15) . 2
N1 Cu1 N1 180.0 7_566 .
N1 Cu1 O2 87.29(13) 7_566 .
N1 Cu1 O2 92.71(13) . .
N1 Cu1 O2 92.71(13) 7_566 7_566
N1 Cu1 O2 87.29(13) . 7_566
O2 Cu1 O2 180.0 . 7_566
N1 Cu1 O1 89.13(13) 7_566 7_566
N1 Cu1 O1 90.87(13) . 7_566
O2 Cu1 O1 93.64(13) . 7_566
O2 Cu1 O1 86.36(13) 7_566 7_566
N1 Cu1 O1 90.87(13) 7_566 .
N1 Cu1 O1 89.13(13) . .
O2 Cu1 O1 86.36(13) . .
O2 Cu1 O1 93.64(13) 7_566 .
O1 Cu1 O1 180.0 7_566 .
C25 O7 Dy1 134.4(3) . .
N2 O5 Dy1 145.0(2) . .
C22 O8 Dy1 133.2(3) . .
C2 O2 Cu1 124.3(4) . .
C4 O1 Cu1 123.9(3) . .
C7 O3 C6 117.4(4) . .
C20 O6 Dy1 134.5(3) . .
O5 N2 C12 125.2(3) . .
O5 N2 C17 120.8(3) . .
C12 N2 C17 112.8(3) . .
C9 N1 C8 119.4(4) . .
C9 N1 Cu1 121.4(3) . .
C8 N1 Cu1 118.8(3) . .
O4 N3 C12 125.5(4) . .
O4 N3 C14 121.6(4) . .
C12 N3 C14 112.6(4) . .
F14 C23 F15 108.0(5) . .
F14 C23 F13 107.5(6) . .
F15 C23 F13 106.1(5) . .
F14 C23 C22 113.2(5) . .
F15 C23 C22 110.3(5) . .
F13 C23 C22 111.4(4) . .
C22 C21 C22 123.9(6) . 2
C22 C21 H21 118.0 . .
C22 C21 H21 118.0 2 .
N1 C8 C7 122.3(4) . .
N1 C8 H8 118.8 . .
C7 C8 H8 118.8 . .
N1 C9 C10 121.4(4) . .
N1 C9 H9 119.3 . .
C10 C9 H9 119.3 . .
C9 C10 C11 119.6(4) . .
C9 C10 C12 118.3(4) . .
C11 C10 C12 122.1(4) . .
O3 C7 C8 114.5(4) . .
O3 C7 C11 126.2(4) . .
C8 C7 C11 119.3(4) . .
C7 C11 C10 118.0(4) . .
C7 C11 H11 121.0 . .
C10 C11 H11 121.0 . .
O7 C25 C24 127.7(5) . .
O7 C25 C26 114.8(4) . .
C24 C25 C26 117.5(4) . .
N2 C12 N3 108.3(4) . .
N2 C12 C10 126.3(4) . .
N3 C12 C10 125.4(4) . .
F9 C19 F8 106.0(6) . .
F9 C19 F7 106.2(6) . .
F8 C19 F7 106.9(5) . .
F9 C19 C20 113.2(4) . .
F8 C19 C20 110.9(4) . .
F7 C19 C20 113.2(5) . .
O2 C2 C3 129.4(5) . .
O2 C2 C1 114.7(5) . .
C3 C2 C1 115.9(5) . .
N2 C17 C16 109.6(4) . .
N2 C17 C18 105.9(4) . .
C16 C17 C18 110.0(4) . .
N2 C17 C14 101.2(3) . .
C16 C17 C14 114.9(4) . .
C18 C17 C14 114.5(4) . .
N3 C14 C13 105.7(4) . .
N3 C14 C15 109.3(4) . .
C13 C14 C15 110.9(5) . .
N3 C14 C17 100.8(3) . .
C13 C14 C17 114.5(4) . .
C15 C14 C17 114.7(4) . .
C2 C3 C4 124.0(5) . .
C2 C3 H3 118.0 . .
C4 C3 H3 118.0 . .
O6 C20 C24 127.7(4) . 2
O6 C20 C19 113.7(4) . .
C24 C20 C19 118.6(4) 2 .
F5 C1 F4 110.5(7) . .
F5 C1 F6 105.4(7) . .
F4 C1 F6 105.8(6) . .
F5 C1 C2 113.9(5) . .
F4 C1 C2 108.5(6) . .
F6 C1 C2 112.5(5) . .
O3 C6 H6A 109.5 . .
O3 C6 H6B 109.5 . .
H6A C6 H6B 109.5 . .
O3 C6 H6C 109.5 . .
H6A C6 H6C 109.5 . .
H6B C6 H6C 109.5 . .
O1 C4 C3 128.0(5) . .
O1 C4 C5 116.3(5) . .
C3 C4 C5 115.7(5) . .
C17 C16 H16A 109.5 . .
C17 C16 H16B 109.5 . .
H16A C16 H16B 109.5 . .
C17 C16 H16C 109.5 . .
H16A C16 H16C 109.5 . .
H16B C16 H16C 109.5 . .
O8 C22 C21 127.5(5) . .
O8 C22 C23 115.2(4) . .
C21 C22 C23 117.3(4) . .
C17 C18 H18A 109.5 . .
C17 C18 H18B 109.5 . .
H18A C18 H18B 109.5 . .
C17 C18 H18C 109.5 . .
H18A C18 H18C 109.5 . .
H18B C18 H18C 109.5 . .
C14 C13 H13A 109.5 . .
C14 C13 H13B 109.5 . .
H13A C13 H13B 109.5 . .
C14 C13 H13C 109.5 . .
H13A C13 H13C 109.5 . .
H13B C13 H13C 109.5 . .
F2 C5 F1 106.4(6) . .
F2 C5 F3 106.4(7) . .
F1 C5 F3 105.3(6) . .
F2 C5 C4 114.1(5) . .
F1 C5 C4 110.4(6) . .
F3 C5 C4 113.6(5) . .
C20 C24 C25 121.4(4) 2 .
C20 C24 H24 119.3 2 .
C25 C24 H24 119.3 . .
F12 C26 F10 108.6(6) . .
F12 C26 F11 108.2(6) . .
F10 C26 F11 105.4(5) . .
F12 C26 C25 112.8(5) . .
F10 C26 C25 108.8(5) . .
F11 C26 C25 112.7(4) . .
C14 C15 H15A 109.5 . .
C14 C15 H15B 109.5 . .
H15A C15 H15B 109.5 . .
C14 C15 H15C 109.5 . .
H15A C15 H15C 109.5 . .
H15B C15 H15C 109.5 . .
loop_
_geom_bond_atom_site_label_1
_geom_bond_atom_site_label_2
_geom_bond_distance
_geom_bond_site_symmetry_2
Dy1 O5 2.331(3) 2
Dy1 O5 2.331(3) .
Dy1 O7 2.334(3) .
Dy1 O7 2.334(3) 2
Dy1 O6 2.365(3) 2
Dy1 O6 2.365(3) .
Dy1 O8 2.366(3) .
Dy1 O8 2.366(3) 2
Cu1 N1 2.017(3) 7_566
Cu1 N1 2.017(3) .
Cu1 O2 2.109(3) .
Cu1 O2 2.109(3) 7_566
Cu1 O1 2.178(3) 7_566
Cu1 O1 2.178(3) .
F14 C23 1.324(6) .
F15 C23 1.338(7) .
F13 C23 1.347(7) .
F8 C19 1.295(6) .
F11 C26 1.308(7) .
F5 C1 1.304(8) .
F12 C26 1.286(8) .
F6 C1 1.315(8) .
F2 C5 1.277(9) .
F9 C19 1.268(7) .
F7 C19 1.301(7) .
F3 C5 1.315(7) .
F1 C5 1.294(9) .
F10 C26 1.304(8) .
F4 C1 1.308(9) .
O7 C25 1.247(6) .
O5 N2 1.300(4) .
O8 C22 1.256(5) .
O2 C2 1.239(6) .
O1 C4 1.239(6) .
O3 C7 1.354(6) .
O3 C6 1.414(6) .
O6 C20 1.245(6) .
O4 N3 1.274(6) .
N2 C12 1.333(5) .
N2 C17 1.502(5) .
N1 C9 1.331(5) .
N1 C8 1.336(5) .
N3 C12 1.351(5) .
N3 C14 1.498(6) .
C23 C22 1.520(7) .
C21 C22 1.388(6) .
C21 C22 1.388(6) 2
C21 H21 0.9300 .
C8 C7 1.378(6) .
C8 H8 0.9300 .
C9 C10 1.387(6) .
C9 H9 0.9300 .
C10 C11 1.392(6) .
C10 C12 1.456(6) .
C7 C11 1.382(6) .
C11 H11 0.9300 .
C25 C24 1.393(7) .
C25 C26 1.542(7) .
C19 C20 1.538(6) .
C2 C3 1.393(9) .
C2 C1 1.543(8) .
C17 C16 1.520(7) .
C17 C18 1.523(7) .
C17 C14 1.546(6) .
C14 C13 1.517(9) .
C14 C15 1.529(7) .
C3 C4 1.407(8) .
C3 H3 0.9300 .
C20 C24 1.386(7) 2
C6 H6A 0.9600 .
C6 H6B 0.9600 .
C6 H6C 0.9600 .
C4 C5 1.537(8) .
C16 H16A 0.9600 .
C16 H16B 0.9600 .
C16 H16C 0.9600 .
C18 H18A 0.9600 .
C18 H18B 0.9600 .
C18 H18C 0.9600 .
C13 H13A 0.9600 .
C13 H13B 0.9600 .
C13 H13C 0.9600 .
C24 C20 1.386(7) 2
C24 H24 0.9300 .
C15 H15A 0.9600 .
C15 H15B 0.9600 .
C15 H15C 0.9600 .
loop_
_geom_torsion_atom_site_label_1
_geom_torsion_atom_site_label_2
_geom_torsion_atom_site_label_3
_geom_torsion_atom_site_label_4
_geom_torsion
_geom_torsion_site_symmetry_1
_geom_torsion_site_symmetry_2
_geom_torsion_site_symmetry_3
_geom_torsion_site_symmetry_4
Dy1 O5 N2 C12 -105.5(5) . . . .
Dy1 O5 N2 C17 87.3(5) . . . .
C9 N1 C8 C7 -0.2(7) . . . .
Cu1 N1 C8 C7 173.1(3) . . . .
C8 N1 C9 C10 0.0(6) . . . .
Cu1 N1 C9 C10 -173.1(3) . . . .
N1 C9 C10 C11 0.3(6) . . . .
N1 C9 C10 C12 179.3(4) . . . .
C6 O3 C7 C8 174.4(4) . . . .
C6 O3 C7 C11 -5.7(7) . . . .
N1 C8 C7 O3 -180.0(4) . . . .
N1 C8 C7 C11 0.1(7) . . . .
O3 C7 C11 C10 -179.7(4) . . . .
C8 C7 C11 C10 0.2(6) . . . .
C9 C10 C11 C7 -0.4(6) . . . .
C12 C10 C11 C7 -179.3(4) . . . .
Dy1 O7 C25 C24 16.6(8) . . . .
Dy1 O7 C25 C26 -163.4(4) . . . .
O5 N2 C12 N3 -174.4(4) . . . .
C17 N2 C12 N3 -6.4(5) . . . .
O5 N2 C12 C10 6.2(7) . . . .
C17 N2 C12 C10 174.2(4) . . . .
O4 N3 C12 N2 177.7(5) . . . .
C14 N3 C12 N2 -8.2(6) . . . .
O4 N3 C12 C10 -2.9(8) . . . .
C14 N3 C12 C10 171.3(4) . . . .
C9 C10 C12 N2 148.7(4) . . . .
C11 C10 C12 N2 -32.3(7) . . . .
C9 C10 C12 N3 -30.6(7) . . . .
C11 C10 C12 N3 148.4(5) . . . .
Cu1 O2 C2 C3 16.6(9) . . . .
Cu1 O2 C2 C1 -161.0(4) . . . .
O5 N2 C17 C16 -52.6(5) . . . .
C12 N2 C17 C16 138.8(4) . . . .
O5 N2 C17 C18 66.0(5) . . . .
C12 N2 C17 C18 -102.7(4) . . . .
O5 N2 C17 C14 -174.3(4) . . . .
C12 N2 C17 C14 17.1(5) . . . .
O4 N3 C14 C13 72.9(6) . . . .
C12 N3 C14 C13 -101.4(5) . . . .
O4 N3 C14 C15 -46.4(7) . . . .
C12 N3 C14 C15 139.2(5) . . . .
O4 N3 C14 C17 -167.6(5) . . . .
C12 N3 C14 C17 18.1(6) . . . .
N2 C17 C14 N3 -19.2(5) . . . .
C16 C17 C14 N3 -137.1(4) . . . .
C18 C17 C14 N3 94.2(5) . . . .
N2 C17 C14 C13 93.7(5) . . . .
C16 C17 C14 C13 -24.2(6) . . . .
C18 C17 C14 C13 -152.8(5) . . . .
N2 C17 C14 C15 -136.4(4) . . . .
C16 C17 C14 C15 105.6(6) . . . .
C18 C17 C14 C15 -23.0(6) . . . .
O2 C2 C3 C4 0.6(11) . . . .
C1 C2 C3 C4 178.1(6) . . . .
Dy1 O6 C20 C24 3.2(8) . . . 2
Dy1 O6 C20 C19 -178.1(3) . . . .
F9 C19 C20 O6 -43.4(7) . . . .
F8 C19 C20 O6 75.6(6) . . . .
F7 C19 C20 O6 -164.3(6) . . . .
F9 C19 C20 C24 135.5(6) . . . 2
F8 C19 C20 C24 -105.5(6) . . . 2
F7 C19 C20 C24 14.6(8) . . . 2
O2 C2 C1 F5 -152.9(6) . . . .
C3 C2 C1 F5 29.2(9) . . . .
O2 C2 C1 F4 83.6(7) . . . .
C3 C2 C1 F4 -94.3(7) . . . .
O2 C2 C1 F6 -33.0(8) . . . .
C3 C2 C1 F6 149.0(6) . . . .
Cu1 O1 C4 C3 -9.4(8) . . . .
Cu1 O1 C4 C5 173.0(4) . . . .
C2 C3 C4 O1 -4.4(10) . . . .
C2 C3 C4 C5 173.3(6) . . . .
Dy1 O8 C22 C21 -4.2(6) . . . .
Dy1 O8 C22 C23 177.6(3) . . . .
C22 C21 C22 O8 2.2(3) 2 . . .
C22 C21 C22 C23 -179.7(4) 2 . . .
F14 C23 C22 O8 -153.9(5) . . . .
F15 C23 C22 O8 85.0(6) . . . .
F13 C23 C22 O8 -32.6(6) . . . .
F14 C23 C22 C21 27.8(7) . . . .
F15 C23 C22 C21 -93.3(5) . . . .
F13 C23 C22 C21 149.1(4) . . . .
O1 C4 C5 F2 -26.7(8) . . . .
C3 C4 C5 F2 155.3(6) . . . .
O1 C4 C5 F1 93.0(7) . . . .
C3 C4 C5 F1 -84.9(7) . . . .
O1 C4 C5 F3 -148.9(6) . . . .
C3 C4 C5 F3 33.2(9) . . . .
O7 C25 C24 C20 -7.3(8) . . . 2
C26 C25 C24 C20 172.7(5) . . . 2
O7 C25 C26 F12 -151.9(6) . . . .
C24 C25 C26 F12 28.2(8) . . . .
O7 C25 C26 F10 87.6(6) . . . .
C24 C25 C26 F10 -92.4(6) . . . .
O7 C25 C26 F11 -29.0(7) . . . .
C24 C25 C26 F11 151.0(5) . . . .
