#------------------------------------------------------------------------------
#$Date: 2021-07-31 01:56:42 +0300 (Sat, 31 Jul 2021) $
#$Revision: 267828 $
#$URL: file:///home/coder/svn-repositories/cod/cif/1/56/42/1564265.cif $
#------------------------------------------------------------------------------
#
# This file is available in the Crystallography Open Database (COD),
# http://www.crystallography.net/
#
# All data on this site have been placed in the public domain by the
# contributors.
#
data_1564265
loop_
_publ_author_name
'Zhou, Ting'
'Liu, Shuang'
'Wang, Song'
'Mi, Shengyong'
'Gao, Pan'
'Guo, Xianmin'
'Su, Qijin'
'Guo, Huadong'
_publ_section_title
;
 Dual-Function Lanthanide--Organic Frameworks Based on a Zwitterionic
 Ligand as a Ratiometric Thermometer and a Selective Sensor for
 Nitroaromatic Explosives
;
_journal_name_full
'Industrial & Engineering Chemistry Research'
_journal_paper_doi               10.1021/acs.iecr.1c01963
_journal_year                    2021
_chemical_formula_moiety         'C60 H46 Eu2 N4 O17'
_chemical_formula_sum            'C60 H46 Eu2 N4 O17'
_chemical_formula_weight         1398.93
_space_group_crystal_system      triclinic
_space_group_IT_number           2
_space_group_name_Hall           '-P 1'
_space_group_name_H-M_alt        'P -1'
_atom_sites_solution_hydrogens   geom
_audit_creation_method           SHELXL-2018/3
_cell_angle_alpha                109.118(5)
_cell_angle_beta                 91.669(5)
_cell_angle_gamma                98.481(5)
_cell_formula_units_Z            2
_cell_length_a                   11.715(5)
_cell_length_b                   15.058(5)
_cell_length_c                   18.880(5)
_cell_measurement_reflns_used    19737
_cell_measurement_temperature    293(2)
_cell_measurement_theta_max      26.183
_cell_measurement_theta_min      1.145
_cell_volume                     3101.7(19)
_computing_structure_refinement  'SHELXL-2018/3 (Sheldrick, 2018)'
_diffrn_ambient_temperature      293(2)
_diffrn_measured_fraction_theta_full 1.000
_diffrn_measured_fraction_theta_max 0.997
_diffrn_measurement_device_type  'CCD area detector'
_diffrn_radiation_type           MoK\a
_diffrn_radiation_wavelength     0.71069
_diffrn_reflns_av_R_equivalents  0.0471
_diffrn_reflns_av_unetI/netI     0.1199
_diffrn_reflns_Laue_measured_fraction_full 1.000
_diffrn_reflns_Laue_measured_fraction_max 0.997
_diffrn_reflns_limit_h_max       10
_diffrn_reflns_limit_h_min       -14
_diffrn_reflns_limit_k_max       18
_diffrn_reflns_limit_k_min       -18
_diffrn_reflns_limit_l_max       23
_diffrn_reflns_limit_l_min       -22
_diffrn_reflns_number            19737
_diffrn_reflns_point_group_measured_fraction_full 1.000
_diffrn_reflns_point_group_measured_fraction_max 0.997
_diffrn_reflns_theta_full        25.240
_diffrn_reflns_theta_max         26.183
_diffrn_reflns_theta_min         1.145
_exptl_absorpt_coefficient_mu    2.073
_exptl_absorpt_correction_T_max  0.720
_exptl_absorpt_correction_T_min  0.669
_exptl_absorpt_correction_type   empirical
_exptl_absorpt_process_details   SADABS
_exptl_crystal_colour            colorless
_exptl_crystal_density_diffrn    1.498
_exptl_crystal_description       block
_exptl_crystal_F_000             1392
_exptl_crystal_size_max          0.20
_exptl_crystal_size_mid          0.18
_exptl_crystal_size_min          0.16
_refine_diff_density_max         1.012
_refine_diff_density_min         -1.042
_refine_diff_density_rms         0.159
_refine_ls_extinction_coef       0.00122(15)
_refine_ls_extinction_expression Fc^*^=kFc[1+0.001xFc²λ³/sin(2θ)]^-1/4^
_refine_ls_extinction_method     'SHELXL-2018/3 (Sheldrick 2018)'
_refine_ls_goodness_of_fit_ref   0.949
_refine_ls_hydrogen_treatment    constr
_refine_ls_matrix_type           full
_refine_ls_number_parameters     749
_refine_ls_number_reflns         12408
_refine_ls_number_restraints     0
_refine_ls_restrained_S_all      0.949
_refine_ls_R_factor_all          0.1099
_refine_ls_R_factor_gt           0.0545
_refine_ls_shift/su_max          0.001
_refine_ls_shift/su_mean         0.000
_refine_ls_structure_factor_coef Fsqd
_refine_ls_weighting_details
'w=1/[σ²(Fo²)+(0.0709P)²+0.1752P] where P=(Fo²+2Fc²)/3'
_refine_ls_weighting_scheme      calc
_refine_ls_wR_factor_gt          0.1394
_refine_ls_wR_factor_ref         0.1542
_reflns_Friedel_coverage         0.000
_reflns_number_gt                6865
_reflns_number_total             12408
_reflns_threshold_expression     'I > 2σ(I)'
_cod_data_source_file            ie1c01963_si_001.cif
_cod_data_source_block           shelx
_cod_database_code               1564265
_shelx_shelxl_version_number     2018/3
_shelx_space_group_comment
;
The symmetry employed for this shelxl refinement is uniquely defined
by the following loop, which should always be used as a source of
symmetry information in preference to the above space-group names.
They are only intended as comments.
;
loop_
_space_group_symop_operation_xyz
'x, y, z'
'-x, -y, -z'
loop_
_atom_site_label
_atom_site_type_symbol
_atom_site_fract_x
_atom_site_fract_y
_atom_site_fract_z
_atom_site_U_iso_or_equiv
_atom_site_adp_type
_atom_site_occupancy
_atom_site_site_symmetry_order
_atom_site_calc_flag
_atom_site_refinement_flags_posn
_atom_site_refinement_flags_adp
_atom_site_refinement_flags_occupancy
_atom_site_disorder_assembly
_atom_site_disorder_group
C1 C 0.6249(8) 0.1348(8) 0.9204(5) 0.047(2) Uani 1 1 d . . . . .
C2 C 0.7352(8) 0.1513(7) 0.9688(5) 0.044(2) Uani 1 1 d . . . . .
C3 C 0.8133(8) 0.2367(7) 0.9855(5) 0.055(3) Uani 1 1 d . . . . .
H3 H 0.795862 0.285124 0.968766 0.067 Uiso 1 1 calc R U . . .
C4 C 0.9165(9) 0.2480(8) 1.0270(6) 0.062(3) Uani 1 1 d . . . . .
H4 H 0.970481 0.303051 1.035445 0.074 Uiso 1 1 calc R U . . .
C5 C 0.9420(9) 0.1786(8) 1.0569(5) 0.050(3) Uani 1 1 d . . . . .
C6 C 0.8625(9) 0.0954(7) 1.0425(5) 0.052(3) Uani 1 1 d . . . . .
H6 H 0.877982 0.049087 1.062342 0.062 Uiso 1 1 calc R U . . .
C7 C 0.7611(8) 0.0814(7) 0.9989(5) 0.052(3) Uani 1 1 d . . . . .
H7 H 0.708840 0.025070 0.989013 0.062 Uiso 1 1 calc R U . . .
C8 C 1.0525(9) 0.1901(8) 1.1014(6) 0.069(3) Uani 1 1 d . . . . .
H8A H 1.114700 0.184452 1.068195 0.083 Uiso 1 1 calc R U . . .
H8B H 1.048823 0.138930 1.122238 0.083 Uiso 1 1 calc R U . . .
C9 C 1.0521(11) 0.2926(8) 1.2336(7) 0.070(3) Uani 1 1 d . . . . .
H9 H 1.014466 0.239994 1.243926 0.085 Uiso 1 1 calc R U . . .
C10 C 1.0779(10) 0.3781(8) 1.2890(6) 0.065(3) Uani 1 1 d . . . . .
H10 H 1.055648 0.383057 1.336823 0.078 Uiso 1 1 calc R U . . .
C11 C 1.1357(9) 0.4584(7) 1.2775(6) 0.051(3) Uani 1 1 d . . . . .
C12 C 1.1629(10) 0.4470(8) 1.2056(7) 0.069(3) Uani 1 1 d . . . . .
H12 H 1.198203 0.499385 1.193963 0.083 Uiso 1 1 calc R U . . .
C13 C 1.1392(9) 0.3600(8) 1.1505(6) 0.061(3) Uani 1 1 d . . . . .
H13 H 1.163581 0.352831 1.102797 0.074 Uiso 1 1 calc R U . . .
C14 C 1.1646(9) 0.5517(7) 1.3384(6) 0.051(3) Uani 1 1 d . . . . .
C15 C 1.1017(9) 0.5728(7) 1.4016(6) 0.060(3) Uani 1 1 d . . . . .
H15 H 1.042141 0.527381 1.406233 0.072 Uiso 1 1 calc R U . . .
C16 C 1.1272(9) 0.6604(8) 1.4572(6) 0.061(3) Uani 1 1 d . . . . .
H16 H 1.085179 0.673715 1.499416 0.073 Uiso 1 1 calc R U . . .
C17 C 1.2169(8) 0.7301(7) 1.4504(5) 0.043(2) Uani 1 1 d . . . . .
C18 C 1.2809(10) 0.7063(7) 1.3897(5) 0.059(3) Uani 1 1 d . . . . .
H18 H 1.344230 0.749737 1.386703 0.071 Uiso 1 1 calc R U . . .
C19 C 1.2544(9) 0.6197(8) 1.3327(6) 0.058(3) Uani 1 1 d . . . . .
H19 H 1.296481 0.606851 1.290519 0.070 Uiso 1 1 calc R U . . .
C20 C 1.2494(9) 0.8260(7) 1.5097(5) 0.048(2) Uani 1 1 d . . . . .
C21 C 0.3754(8) 0.2381(7) 0.7380(6) 0.044(2) Uani 1 1 d . . . . .
C22 C 0.4221(9) 0.3346(7) 0.7367(5) 0.044(2) Uani 1 1 d . . . . .
C23 C 0.4656(10) 0.4073(7) 0.8026(6) 0.065(3) Uani 1 1 d . . . . .
H23 H 0.467232 0.395331 0.847885 0.078 Uiso 1 1 calc R U . . .
C24 C 0.5068(10) 0.4977(7) 0.8016(5) 0.061(3) Uani 1 1 d . . . . .
H24 H 0.533668 0.546249 0.846560 0.073 Uiso 1 1 calc R U . . .
C25 C 0.5087(9) 0.5174(7) 0.7349(5) 0.048(2) Uani 1 1 d . . . . .
C26 C 0.4652(9) 0.4444(7) 0.6706(6) 0.056(3) Uani 1 1 d . . . . .
H26 H 0.464497 0.456100 0.625192 0.067 Uiso 1 1 calc R U . . .
C27 C 0.4227(9) 0.3553(7) 0.6704(5) 0.053(3) Uani 1 1 d . . . . .
H27 H 0.393854 0.307662 0.625354 0.064 Uiso 1 1 calc R U . . .
C28 C 0.5545(9) 0.6116(7) 0.7311(5) 0.047(2) Uani 1 1 d . . . . .
C29 C 0.5536(9) 0.6934(8) 0.7899(6) 0.058(3) Uani 1 1 d . . . . .
H29 H 0.526878 0.688915 0.834693 0.070 Uiso 1 1 calc R U . . .
C30 C 0.5910(9) 0.7825(7) 0.7854(6) 0.053(3) Uani 1 1 d . . . . .
H30 H 0.588290 0.837100 0.826149 0.064 Uiso 1 1 calc R U . . .
C31 C 0.6369(9) 0.7107(8) 0.6650(6) 0.058(3) Uani 1 1 d . . . . .
H31 H 0.664472 0.715790 0.620546 0.069 Uiso 1 1 calc R U . . .
C32 C 0.6036(9) 0.6227(7) 0.6701(5) 0.058(3) Uani 1 1 d . . . . .
H32 H 0.614954 0.569099 0.630737 0.070 Uiso 1 1 calc R U . . .
C33 C 0.6688(7) 0.8857(7) 0.7170(6) 0.046(2) Uani 1 1 d . . . . .
H33A H 0.647826 0.885081 0.666722 0.055 Uiso 1 1 calc R U . . .
H33B H 0.628477 0.930842 0.752015 0.055 Uiso 1 1 calc R U . . .
C34 C 0.7953(8) 0.9175(7) 0.7346(5) 0.041(2) Uani 1 1 d . . . . .
C35 C 0.8394(8) 0.9782(7) 0.8042(6) 0.050(3) Uani 1 1 d . . . . .
H35 H 0.788687 0.995971 0.841387 0.060 Uiso 1 1 calc R U . . .
C36 C 0.9560(8) 1.0144(6) 0.8220(5) 0.041(2) Uani 1 1 d . . . . .
H36 H 0.981481 1.057464 0.869644 0.049 Uiso 1 1 calc R U . . .
C37 C 1.0351(7) 0.9868(6) 0.7693(5) 0.039(2) Uani 1 1 d . . . . .
C38 C 0.9926(9) 0.9206(7) 0.6979(5) 0.048(3) Uani 1 1 d . . . . .
H38 H 1.043512 0.899711 0.661543 0.057 Uiso 1 1 calc R U . . .
C39 C 0.8748(8) 0.8868(7) 0.6822(5) 0.046(2) Uani 1 1 d . . . . .
H39 H 0.848112 0.842308 0.635241 0.055 Uiso 1 1 calc R U . . .
C40 C 1.1599(8) 1.0279(7) 0.7876(6) 0.045(2) Uani 1 1 d . . . . .
C41 C 0.5672(8) 0.0682(6) 0.6826(5) 0.037(2) Uani 1 1 d . . . . .
C42 C 0.6913(8) 0.1146(7) 0.7004(5) 0.039(2) Uani 1 1 d . . . . .
C43 C 0.7727(8) 0.0806(7) 0.6517(5) 0.048(2) Uani 1 1 d . . . . .
H43 H 0.747974 0.031692 0.606509 0.057 Uiso 1 1 calc R U . . .
C44 C 0.8889(9) 0.1164(8) 0.6673(6) 0.059(3) Uani 1 1 d . . . . .
H44 H 0.941809 0.093262 0.632970 0.071 Uiso 1 1 calc R U . . .
C45 C 0.9254(8) 0.1874(7) 0.7353(6) 0.051(3) Uani 1 1 d . . . . .
C46 C 0.8440(10) 0.2254(8) 0.7835(6) 0.063(3) Uani 1 1 d . . . . .
H46 H 0.868019 0.276061 0.827768 0.076 Uiso 1 1 calc R U . . .
C47 C 0.7293(9) 0.1888(8) 0.7662(6) 0.056(3) Uani 1 1 d . . . . .
H47 H 0.675756 0.214333 0.799141 0.067 Uiso 1 1 calc R U . . .
C48 C 1.0553(9) 0.2187(7) 0.7557(7) 0.062(3) Uani 1 1 d . . . . .
H48A H 1.073528 0.218473 0.806058 0.075 Uiso 1 1 calc R U . . .
H48B H 1.096123 0.173458 0.721255 0.075 Uiso 1 1 calc R U . . .
C49 C 1.1205(14) 0.3922(10) 0.8154(7) 0.109(6) Uani 1 1 d . . . . .
H49 H 1.109444 0.385244 0.862001 0.130 Uiso 1 1 calc R U . . .
C50 C 1.1608(13) 0.4787(9) 0.8111(7) 0.096(5) Uani 1 1 d . . . . .
H50 H 1.179230 0.529724 0.855816 0.115 Uiso 1 1 calc R U . . .
C51 C 1.1763(9) 0.4963(7) 0.7448(6) 0.049(3) Uani 1 1 d . . . . .
C52 C 1.1492(10) 0.4159(7) 0.6806(7) 0.066(3) Uani 1 1 d . . . . .
H52 H 1.159288 0.420827 0.633315 0.079 Uiso 1 1 calc R U . . .
C53 C 1.1074(10) 0.3290(8) 0.6877(6) 0.066(3) Uani 1 1 d . . . . .
H53 H 1.086007 0.276729 0.644172 0.079 Uiso 1 1 calc R U . . .
C54 C 1.2215(9) 0.5920(7) 0.7406(6) 0.055(3) Uani 1 1 d . . . . .
C55 C 1.2488(10) 0.6702(7) 0.8078(6) 0.064(3) Uani 1 1 d . . . . .
H55 H 1.240241 0.661471 0.854001 0.076 Uiso 1 1 calc R U . . .
C56 C 1.2887(10) 0.7605(7) 0.8047(6) 0.061(3) Uani 1 1 d . . . . .
H56 H 1.306733 0.812202 0.848997 0.073 Uiso 1 1 calc R U . . .
C57 C 1.3014(9) 0.7731(6) 0.7376(5) 0.045(2) Uani 1 1 d . . . . .
C58 C 1.2720(10) 0.6961(7) 0.6724(6) 0.061(3) Uani 1 1 d . . . . .
H58 H 1.279186 0.705369 0.626260 0.073 Uiso 1 1 calc R U . . .
C59 C 1.2335(11) 0.6085(8) 0.6736(6) 0.080(4) Uani 1 1 d . . . . .
H59 H 1.214733 0.558117 0.628516 0.095 Uiso 1 1 calc R U . . .
C60 C 1.3484(8) 0.8716(7) 0.7351(6) 0.045(2) Uani 1 1 d . . . . .
N1 N 1.0806(8) 0.2839(6) 1.1645(5) 0.060(2) Uani 1 1 d . . . . .
N2 N 1.0964(7) 0.3164(6) 0.7525(5) 0.057(2) Uani 1 1 d . . . . .
N3 N 0.6310(6) 0.7889(6) 0.7215(4) 0.0416(19) Uani 1 1 d . . . . .
N4 N 0.3453(10) 0.1852(11) 0.9983(5) 0.085(4) Uani 1 1 d . . . . .
O1 O 0.5826(6) 0.2056(5) 0.9172(3) 0.0485(16) Uani 1 1 d . . . . .
O2 O 0.5787(6) 0.0501(5) 0.8828(4) 0.061(2) Uani 1 1 d . . . . .
O3 O 1.3452(6) 0.8746(5) 1.5126(3) 0.0516(17) Uani 1 1 d . . . . .
O4 O 1.1767(6) 0.8565(5) 1.5554(4) 0.063(2) Uani 1 1 d . . . . .
O5 O 0.3718(6) 0.2271(4) 0.8022(4) 0.0518(18) Uani 1 1 d . . . . .
O6 O 0.3422(7) 0.1738(5) 0.6761(4) 0.0580(19) Uani 1 1 d . . . . .
O7 O 1.1987(5) 1.0654(5) 0.8551(4) 0.0528(18) Uani 1 1 d . . . . .
O8 O 1.2255(5) 1.0269(4) 0.7347(3) 0.0453(16) Uani 1 1 d . . . . .
O9 O 0.5323(5) 0.0176(5) 0.6173(3) 0.0546(18) Uani 1 1 d . . . . .
O10 O 0.4989(5) 0.0820(5) 0.7335(3) 0.0473(17) Uani 1 1 d . . . . .
O11 O 1.3572(6) 0.8823(4) 0.6722(4) 0.0520(18) Uani 1 1 d . . . . .
O12 O 1.3737(6) 0.9367(4) 0.7978(4) 0.0496(17) Uani 1 1 d . . . . .
O13 O 0.3819(8) 0.1092(7) 0.9775(5) 0.078(3) Uani 1 1 d . . . . .
O14 O 0.3426(7) 0.2317(6) 0.9538(5) 0.080(2) Uani 1 1 d . . . . .
O15 O 0.3120(9) 0.2162(9) 1.0606(4) 0.136(5) Uani 1 1 d . . . . .
OW1 O 0.3841(8) 0.0722(6) 0.5252(4) 0.086(3) Uani 1 1 d . . . . .
OW2 O 0.1363(6) 0.0496(6) 0.5659(5) 0.098(3) Uani 1 1 d . . . . .
Eu1 Eu 0.32066(4) 0.00479(3) 0.62312(2) 0.03476(15) Uani 1 1 d . . . . .
Eu2 Eu 0.40521(4) 0.10330(3) 0.84488(2) 0.03556(15) Uani 1 1 d . . . . .
loop_
_atom_type_symbol
_atom_type_description
_atom_type_scat_dispersion_real
_atom_type_scat_dispersion_imag
_atom_type_scat_source
C C 0.0033 0.0016 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
H H 0.0000 0.0000 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
N N 0.0061 0.0033 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
O O 0.0106 0.0060 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
Eu Eu -0.1578 3.6682 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
loop_
_geom_angle_atom_site_label_1
_geom_angle_atom_site_label_2
_geom_angle_atom_site_label_3
_geom_angle
_geom_angle_site_symmetry_1
_geom_angle_site_symmetry_3
_geom_angle_publ_flag
O1 C1 O2 122.0(9) . . ?
O1 C1 C2 119.0(9) . . ?
O2 C1 C2 118.9(9) . . ?
O1 C1 Eu2 61.4(5) . . ?
O2 C1 Eu2 61.3(5) . . ?
C2 C1 Eu2 173.2(6) . . ?
C3 C2 C7 119.0(9) . . ?
C3 C2 C1 120.4(9) . . ?
C7 C2 C1 120.6(9) . . ?
C4 C3 C2 119.2(10) . . ?
C4 C3 H3 120.4 . . ?
C2 C3 H3 120.4 . . ?
C3 C4 C5 121.6(10) . . ?
C3 C4 H4 119.2 . . ?
C5 C4 H4 119.2 . . ?
C6 C5 C4 119.0(9) . . ?
C6 C5 C8 119.0(10) . . ?
C4 C5 C8 122.0(10) . . ?
C7 C6 C5 120.2(10) . . ?
C7 C6 H6 119.9 . . ?
C5 C6 H6 119.9 . . ?
C6 C7 C2 120.9(9) . . ?
C6 C7 H7 119.5 . . ?
C2 C7 H7 119.5 . . ?
C5 C8 N1 113.4(8) . . ?
C5 C8 H8A 108.9 . . ?
N1 C8 H8A 108.9 . . ?
C5 C8 H8B 108.9 . . ?
N1 C8 H8B 108.9 . . ?
H8A C8 H8B 107.7 . . ?
N1 C9 C10 120.0(11) . . ?
N1 C9 H9 120.0 . . ?
C10 C9 H9 120.0 . . ?
C9 C10 C11 122.8(11) . . ?
C9 C10 H10 118.6 . . ?
C11 C10 H10 118.6 . . ?
C12 C11 C10 115.7(10) . . ?
C12 C11 C14 121.7(10) . . ?
C10 C11 C14 122.6(10) . . ?
C13 C12 C11 121.1(11) . . ?
C13 C12 H12 119.4 . . ?
C11 C12 H12 119.4 . . ?
N1 C13 C12 120.7(11) . . ?
N1 C13 H13 119.7 . . ?
C12 C13 H13 119.7 . . ?
C19 C14 C15 119.2(10) . . ?
C19 C14 C11 120.1(10) . . ?
C15 C14 C11 120.6(10) . . ?
C16 C15 C14 120.4(10) . . ?
C16 C15 H15 119.8 . . ?
C14 C15 H15 119.8 . . ?
C15 C16 C17 120.2(10) . . ?
C15 C16 H16 119.9 . . ?
C17 C16 H16 119.9 . . ?
C18 C17 C16 118.3(10) . . ?
C18 C17 C20 119.1(9) . . ?
C16 C17 C20 122.4(9) . . ?
C17 C18 C19 121.9(10) . . ?
C17 C18 H18 119.1 . . ?
C19 C18 H18 119.1 . . ?
C18 C19 C14 119.8(10) . . ?
C18 C19 H19 120.1 . . ?
C14 C19 H19 120.1 . . ?
O3 C20 O4 120.9(10) . . ?
O3 C20 C17 120.3(9) . . ?
O4 C20 C17 118.7(9) . . ?
O3 C20 Eu1 57.9(5) . 1_666 ?
O4 C20 Eu1 63.1(5) . 1_666 ?
C17 C20 Eu1 177.4(7) . 1_666 ?
O6 C21 O5 125.1(9) . . ?
O6 C21 C22 117.6(8) . . ?
O5 C21 C22 117.3(9) . . ?
C23 C22 C27 117.9(9) . . ?
C23 C22 C21 120.5(8) . . ?
C27 C22 C21 121.7(9) . . ?
C24 C23 C22 120.4(9) . . ?
C24 C23 H23 119.8 . . ?
C22 C23 H23 119.8 . . ?
C23 C24 C25 121.3(10) . . ?
C23 C24 H24 119.3 . . ?
C25 C24 H24 119.3 . . ?
C26 C25 C24 117.1(9) . . ?
C26 C25 C28 119.8(9) . . ?
C24 C25 C28 123.0(9) . . ?
C27 C26 C25 122.5(9) . . ?
C27 C26 H26 118.7 . . ?
C25 C26 H26 118.7 . . ?
C26 C27 C22 120.7(9) . . ?
C26 C27 H27 119.6 . . ?
C22 C27 H27 119.6 . . ?
C32 C28 C29 115.7(9) . . ?
C32 C28 C25 122.1(10) . . ?
C29 C28 C25 122.1(9) . . ?
C28 C29 C30 122.4(10) . . ?
C28 C29 H29 118.8 . . ?
C30 C29 H29 118.8 . . ?
N3 C30 C29 118.9(9) . . ?
N3 C30 H30 120.6 . . ?
C29 C30 H30 120.6 . . ?
N3 C31 C32 121.6(10) . . ?
N3 C31 H31 119.2 . . ?
C32 C31 H31 119.2 . . ?
C28 C32 C31 121.3(10) . . ?
C28 C32 H32 119.4 . . ?
C31 C32 H32 119.4 . . ?
C34 C33 N3 112.1(7) . . ?
C34 C33 H33A 109.2 . . ?
N3 C33 H33A 109.2 . . ?
C34 C33 H33B 109.2 . . ?
N3 C33 H33B 109.2 . . ?
H33A C33 H33B 107.9 . . ?
C35 C34 C39 116.8(9) . . ?
C35 C34 C33 120.8(9) . . ?
C39 C34 C33 122.3(9) . . ?
C34 C35 C36 122.9(9) . . ?
C34 C35 H35 118.5 . . ?
C36 C35 H35 118.5 . . ?
C35 C36 C37 120.4(9) . . ?
C35 C36 H36 119.8 . . ?
C37 C36 H36 119.8 . . ?
C36 C37 C38 117.8(8) . . ?
C36 C37 C40 120.4(9) . . ?
C38 C37 C40 121.8(8) . . ?
C39 C38 C37 119.9(9) . . ?
C39 C38 H38 120.0 . . ?
C37 C38 H38 120.0 . . ?
C38 C39 C34 121.9(9) . . ?
C38 C39 H39 119.1 . . ?
C34 C39 H39 119.1 . . ?
O7 C40 O8 120.9(9) . . ?
O7 C40 C37 119.3(8) . . ?
O8 C40 C37 119.7(9) . . ?
O7 C40 Eu2 53.4(5) . 1_665 ?
O8 C40 Eu2 67.9(5) . 1_665 ?
C37 C40 Eu2 171.6(6) . 1_665 ?
O9 C41 O10 120.5(9) . . ?
O9 C41 C42 119.6(8) . . ?
O10 C41 C42 119.9(8) . . ?
O9 C41 Eu1 54.6(5) . . ?
O10 C41 Eu1 67.2(5) . . ?
C42 C41 Eu1 166.0(6) . . ?
C47 C42 C43 117.9(9) . . ?
C47 C42 C41 122.1(9) . . ?
C43 C42 C41 119.9(9) . . ?
C44 C43 C42 122.5(10) . . ?
C44 C43 H43 118.8 . . ?
C42 C43 H43 118.8 . . ?
C43 C44 C45 118.5(10) . . ?
C43 C44 H44 120.8 . . ?
C45 C44 H44 120.8 . . ?
C44 C45 C46 119.7(10) . . ?
C44 C45 C48 117.9(10) . . ?
C46 C45 C48 122.3(11) . . ?
C47 C46 C45 120.3(11) . . ?
C47 C46 H46 119.8 . . ?
C45 C46 H46 119.8 . . ?
C46 C47 C42 120.9(10) . . ?
C46 C47 H47 119.5 . . ?
C42 C47 H47 119.5 . . ?
N2 C48 C45 112.2(8) . . ?
N2 C48 H48A 109.2 . . ?
C45 C48 H48A 109.2 . . ?
N2 C48 H48B 109.2 . . ?
C45 C48 H48B 109.2 . . ?
H48A C48 H48B 107.9 . . ?
N2 C49 C50 119.8(12) . . ?
N2 C49 H49 120.1 . . ?
C50 C49 H49 120.1 . . ?
C49 C50 C51 124.1(13) . . ?
C49 C50 H50 118.0 . . ?
C51 C50 H50 118.0 . . ?
C50 C51 C52 114.4(10) . . ?
C50 C51 C54 123.7(10) . . ?
C52 C51 C54 121.9(9) . . ?
C53 C52 C51 119.5(11) . . ?
C53 C52 H52 120.2 . . ?
C51 C52 H52 120.2 . . ?
N2 C53 C52 123.3(11) . . ?
N2 C53 H53 118.4 . . ?
C52 C53 H53 118.4 . . ?
C59 C54 C55 118.1(10) . . ?
C59 C54 C51 122.8(10) . . ?
C55 C54 C51 119.1(9) . . ?
C56 C55 C54 119.8(10) . . ?
C56 C55 H55 120.1 . . ?
C54 C55 H55 120.1 . . ?
C57 C56 C55 120.2(10) . . ?
C57 C56 H56 119.9 . . ?
C55 C56 H56 119.9 . . ?
C56 C57 C58 119.3(9) . . ?
C56 C57 C60 119.7(9) . . ?
C58 C57 C60 121.0(9) . . ?
C59 C58 C57 121.8(10) . . ?
C59 C58 H58 119.1 . . ?
C57 C58 H58 119.1 . . ?
C58 C59 C54 120.8(11) . . ?
C58 C59 H59 119.6 . . ?
C54 C59 H59 119.6 . . ?
O11 C60 O12 125.5(9) . . ?
O11 C60 C57 118.7(9) . . ?
O12 C60 C57 115.8(8) . . ?
C9 N1 C13 119.7(10) . . ?
C9 N1 C8 121.4(10) . . ?
C13 N1 C8 118.9(10) . . ?
C53 N2 C49 118.8(10) . . ?
C53 N2 C48 120.2(10) . . ?
C49 N2 C48 121.0(10) . . ?
C31 N3 C30 119.7(8) . . ?
C31 N3 C33 122.1(8) . . ?
C30 N3 C33 118.2(8) . . ?
O15 N4 O13 121.4(14) . . ?
O15 N4 O14 119.6(15) . . ?
O13 N4 O14 119.0(10) . . ?
O15 N4 Eu2 175.2(9) . . ?
O13 N4 Eu2 58.9(5) . . ?
O14 N4 Eu2 60.4(5) . . ?
C1 O1 Eu2 92.0(6) . . ?
C1 O2 Eu2 91.9(6) . . ?
C20 O3 Eu1 96.4(6) . 1_666 ?
C20 O4 Eu1 90.5(6) . 1_666 ?
C21 O5 Eu2 133.1(6) . . ?
C21 O6 Eu1 138.5(6) . . ?
C40 O7 Eu2 102.2(5) . 1_665 ?
C40 O8 Eu1 170.1(6) . 1_665 ?
C40 O8 Eu2 86.6(6) . 1_665 ?
Eu1 O8 Eu2 102.6(2) 1_665 1_665 ?
C41 O9 Eu1 101.3(5) . . ?
C41 O10 Eu2 167.3(6) . . ?
C41 O10 Eu1 87.8(5) . . ?
Eu2 O10 Eu1 103.2(2) . . ?
C60 O11 Eu1 133.9(6) . 1_665 ?
C60 O12 Eu2 137.7(6) . 1_665 ?
N4 O13 Eu2 96.3(7) . . ?
N4 O14 Eu2 94.0(7) . . ?
O8 Eu1 O6 77.4(2) 1_445 . ?
O8 Eu1 O11 72.4(2) 1_445 1_445 ?
O6 Eu1 O11 133.5(2) . 1_445 ?
O8 Eu1 O3 137.7(2) 1_445 1_444 ?
O6 Eu1 O3 144.2(2) . 1_444 ?
O11 Eu1 O3 76.4(2) 1_445 1_444 ?
O8 Eu1 O9 124.5(2) 1_445 . ?
O6 Eu1 O9 89.7(2) . . ?
O11 Eu1 O9 79.5(2) 1_445 . ?
O3 Eu1 O9 75.5(2) 1_444 . ?
O8 Eu1 OW1 146.5(2) 1_445 . ?
O6 Eu1 OW1 72.1(2) . . ?
O11 Eu1 OW1 140.2(2) 1_445 . ?
O3 Eu1 OW1 72.1(2) 1_444 . ?
O9 Eu1 OW1 69.4(3) . . ?
O8 Eu1 O4 90.9(2) 1_445 1_444 ?
O6 Eu1 O4 143.3(2) . 1_444 ?
O11 Eu1 O4 72.1(2) 1_445 1_444 ?
O3 Eu1 O4 52.1(2) 1_444 1_444 ?
O9 Eu1 O4 124.5(2) . 1_444 ?
OW1 Eu1 O4 105.4(3) . 1_444 ?
O8 Eu1 OW2 87.0(2) 1_445 . ?
O6 Eu1 OW2 75.1(2) . . ?
O11 Eu1 OW2 135.9(2) 1_445 . ?
O3 Eu1 OW2 96.3(2) 1_444 . ?
O9 Eu1 OW2 141.5(2) . . ?
OW1 Eu1 OW2 72.2(3) . . ?
O4 Eu1 OW2 69.7(2) 1_444 . ?
O8 Eu1 O10 77.09(19) 1_445 . ?
O6 Eu1 O10 67.0(2) . . ?
O11 Eu1 O10 72.3(2) 1_445 . ?
O3 Eu1 O10 119.3(2) 1_444 . ?
O9 Eu1 O10 48.74(18) . . ?
OW1 Eu1 O10 102.7(3) . . ?
O4 Eu1 O10 144.4(2) 1_444 . ?
OW2 Eu1 O10 141.1(2) . . ?
O8 Eu1 C20 114.8(3) 1_445 1_444 ?
O6 Eu1 C20 154.7(3) . 1_444 ?
O11 Eu1 C20 71.6(2) 1_445 1_444 ?
O3 Eu1 C20 25.8(2) 1_444 1_444 ?
O9 Eu1 C20 99.5(3) . 1_444 ?
OW1 Eu1 C20 89.1(3) . 1_444 ?
O4 Eu1 C20 26.4(2) 1_444 1_444 ?
OW2 Eu1 C20 83.2(3) . 1_444 ?
O10 Eu1 C20 135.6(2) . 1_444 ?
O8 Eu1 C41 101.9(2) 1_445 . ?
O6 Eu1 C41 75.1(2) . . ?
O11 Eu1 C41 77.6(2) 1_445 . ?
O3 Eu1 C41 98.4(2) 1_444 . ?
O9 Eu1 C41 24.13(19) . . ?
OW1 Eu1 C41 83.4(3) . . ?
O4 Eu1 C41 141.6(2) 1_444 . ?
OW2 Eu1 C41 146.0(2) . . ?
O10 Eu1 C41 24.95(18) . . ?
C20 Eu1 C41 120.5(3) 1_444 . ?
O8 Eu1 Eu2 42.14(15) 1_445 . ?
O6 Eu1 Eu2 66.78(15) . . ?
O11 Eu1 Eu2 67.04(16) 1_445 . ?
O3 Eu1 Eu2 140.35(16) 1_444 . ?
O9 Eu1 Eu2 83.00(14) . . ?
OW1 Eu1 Eu2 130.0(2) . . ?
O4 Eu1 Eu2 124.53(17) 1_444 . ?
OW2 Eu1 Eu2 120.52(19) . . ?
O10 Eu1 Eu2 34.94(11) . . ?
C20 Eu1 Eu2 137.39(19) 1_444 . ?
C41 Eu1 Eu2 59.79(16) . . ?
O5 Eu2 O12 137.0(2) . 1_445 ?
O5 Eu2 O10 73.6(2) . . ?
O12 Eu2 O10 81.2(2) 1_445 . ?
O5 Eu2 O7 89.6(2) . 1_445 ?
O12 Eu2 O7 78.2(2) 1_445 1_445 ?
O10 Eu2 O7 126.9(2) . 1_445 ?
O5 Eu2 O2 135.0(2) . . ?
O12 Eu2 O2 72.3(2) 1_445 . ?
O10 Eu2 O2 81.7(2) . . ?
O7 Eu2 O2 134.8(2) 1_445 . ?
O5 Eu2 O1 88.9(2) . . ?
O12 Eu2 O1 125.6(2) 1_445 . ?
O10 Eu2 O1 89.5(2) . . ?
O7 Eu2 O1 141.3(2) 1_445 . ?
O2 Eu2 O1 53.3(2) . . ?
O5 Eu2 O13 122.6(3) . . ?
O12 Eu2 O13 93.3(3) 1_445 . ?
O10 Eu2 O13 156.6(3) . . ?
O7 Eu2 O13 73.3(3) 1_445 . ?
O2 Eu2 O13 74.9(3) . . ?
O1 Eu2 O13 75.1(2) . . ?
O5 Eu2 O14 72.2(3) . . ?
O12 Eu2 O14 136.8(3) 1_445 . ?
O10 Eu2 O14 141.6(3) . . ?
O7 Eu2 O14 70.0(3) 1_445 . ?
O2 Eu2 O14 111.2(3) . . ?
O1 Eu2 O14 72.9(3) . . ?
O13 Eu2 O14 50.4(3) . . ?
O5 Eu2 O8 74.1(2) . 1_445 ?
O12 Eu2 O8 66.6(2) 1_445 1_445 ?
O10 Eu2 O8 77.1(2) . 1_445 ?
O7 Eu2 O8 49.80(19) 1_445 1_445 ?
O2 Eu2 O8 136.0(2) . 1_445 ?
O1 Eu2 O8 160.63(19) . 1_445 ?
O13 Eu2 O8 121.7(2) . 1_445 ?
O14 Eu2 O8 109.4(2) . 1_445 ?
O5 Eu2 C1 113.6(3) . . ?
O12 Eu2 C1 99.1(3) 1_445 . ?
O10 Eu2 C1 87.3(2) . . ?
O7 Eu2 C1 144.0(2) 1_445 . ?
O2 Eu2 C1 26.8(3) . . ?
O1 Eu2 C1 26.6(2) . . ?
O13 Eu2 C1 71.0(3) . . ?
O14 Eu2 C1 90.5(3) . . ?
O8 Eu2 C1 160.1(2) 1_445 . ?
O5 Eu2 N4 97.8(4) . . ?
O12 Eu2 N4 114.8(3) 1_445 . ?
O10 Eu2 N4 161.4(3) . . ?
O7 Eu2 N4 68.3(3) 1_445 . ?
O2 Eu2 N4 93.8(3) . . ?
O1 Eu2 N4 73.6(3) . . ?
O13 Eu2 N4 24.8(3) . . ?
O14 Eu2 N4 25.6(3) . . ?
O8 Eu2 N4 117.1(3) 1_445 . ?
C1 Eu2 N4 81.0(3) . . ?
O5 Eu2 C40 82.7(3) . 1_445 ?
O12 Eu2 C40 69.4(2) 1_445 1_445 ?
O10 Eu2 C40 102.5(2) . 1_445 ?
O7 Eu2 C40 24.4(2) 1_445 1_445 ?
O2 Eu2 C40 140.2(3) . 1_445 ?
O1 Eu2 C40 162.7(2) . 1_445 ?
O13 Eu2 C40 96.7(3) . 1_445 ?
O14 Eu2 C40 90.1(3) . 1_445 ?
O8 Eu2 C40 25.5(2) 1_445 1_445 ?
C1 Eu2 C40 163.1(3) . 1_445 ?
N4 Eu2 C40 92.5(3) . 1_445 ?
loop_
_geom_bond_atom_site_label_1
_geom_bond_atom_site_label_2
_geom_bond_distance
_geom_bond_site_symmetry_2
_geom_bond_publ_flag
C1 O1 1.257(11) . ?
C1 O2 1.267(11) . ?
C1 C2 1.501(13) . ?
C1 Eu2 2.805(10) . ?
C2 C3 1.401(13) . ?
C2 C7 1.413(13) . ?
C3 C4 1.379(13) . ?
C3 H3 0.9300 . ?
C4 C5 1.404(14) . ?
C4 H4 0.9300 . ?
C5 C6 1.388(14) . ?
C5 C8 1.479(13) . ?
C6 C7 1.374(13) . ?
C6 H6 0.9300 . ?
C7 H7 0.9300 . ?
C8 N1 1.503(12) . ?
C8 H8A 0.9700 . ?
C8 H8B 0.9700 . ?
C9 N1 1.325(13) . ?
C9 C10 1.352(14) . ?
C9 H9 0.9300 . ?
C10 C11 1.380(14) . ?
C10 H10 0.9300 . ?
C11 C12 1.365(14) . ?
C11 C14 1.480(13) . ?
C12 C13 1.363(14) . ?
C12 H12 0.9300 . ?
C13 N1 1.353(13) . ?
C13 H13 0.9300 . ?
C14 C19 1.389(14) . ?
C14 C15 1.393(14) . ?
C15 C16 1.374(14) . ?
C15 H15 0.9300 . ?
C16 C17 1.413(14) . ?
C16 H16 0.9300 . ?
C17 C18 1.367(13) . ?
C17 C20 1.495(13) . ?
C18 C19 1.376(14) . ?
C18 H18 0.9300 . ?
C19 H19 0.9300 . ?
C20 O3 1.236(11) . ?
C20 O4 1.256(11) . ?
C20 Eu1 2.826(10) 1_666 ?
C21 O6 1.256(11) . ?
C21 O5 1.276(10) . ?
C21 C22 1.483(12) . ?
C22 C23 1.383(13) . ?
C22 C27 1.385(12) . ?
C23 C24 1.381(13) . ?
C23 H23 0.9300 . ?
C24 C25 1.385(12) . ?
C24 H24 0.9300 . ?
C25 C26 1.366(13) . ?
C25 C28 1.466(12) . ?
C26 C27 1.360(13) . ?
C26 H26 0.9300 . ?
C27 H27 0.9300 . ?
C28 C32 1.350(12) . ?
C28 C29 1.363(13) . ?
C29 C30 1.379(13) . ?
C29 H29 0.9300 . ?
C30 N3 1.334(11) . ?
C30 H30 0.9300 . ?
C31 N3 1.317(12) . ?
C31 C32 1.361(13) . ?
C31 H31 0.9300 . ?
C32 H32 0.9300 . ?
C33 C34 1.481(12) . ?
C33 N3 1.490(11) . ?
C33 H33A 0.9700 . ?
C33 H33B 0.9700 . ?
C34 C35 1.365(13) . ?
C34 C39 1.394(12) . ?
C35 C36 1.381(12) . ?
C35 H35 0.9300 . ?
C36 C37 1.385(11) . ?
C36 H36 0.9300 . ?
C37 C38 1.411(12) . ?
C37 C40 1.484(12) . ?
C38 C39 1.386(13) . ?
C38 H38 0.9300 . ?
C39 H39 0.9300 . ?
C40 O7 1.252(11) . ?
C40 O8 1.276(10) . ?
C40 Eu2 2.961(10) 1_665 ?
C41 O9 1.237(10) . ?
C41 O10 1.253(9) . ?
C41 C42 1.494(12) . ?
C41 Eu1 2.968(10) . ?
C42 C47 1.379(13) . ?
C42 C43 1.380(12) . ?
C43 C44 1.374(13) . ?
C43 H43 0.9300 . ?
C44 C45 1.381(14) . ?
C44 H44 0.9300 . ?
C45 C46 1.392(14) . ?
C45 C48 1.523(13) . ?
C46 C47 1.362(14) . ?
C46 H46 0.9300 . ?
C47 H47 0.9300 . ?
C48 N2 1.501(11) . ?
C48 H48A 0.9700 . ?
C48 H48B 0.9700 . ?
C49 N2 1.339(15) . ?
C49 C50 1.348(16) . ?
C49 H49 0.9300 . ?
C50 C51 1.372(14) . ?
C50 H50 0.9300 . ?
C51 C52 1.392(14) . ?
C51 C54 1.489(13) . ?
C52 C53 1.378(14) . ?
C52 H52 0.9300 . ?
C53 N2 1.303(12) . ?
C53 H53 0.9300 . ?
C54 C59 1.375(13) . ?
C54 C55 1.408(13) . ?
C55 C56 1.391(13) . ?
C55 H55 0.9300 . ?
C56 C57 1.351(12) . ?
C56 H56 0.9300 . ?
C57 C58 1.379(13) . ?
C57 C60 1.521(12) . ?
C58 C59 1.338(13) . ?
C58 H58 0.9300 . ?
C59 H59 0.9300 . ?
C60 O11 1.253(10) . ?
C60 O12 1.259(11) . ?
N4 O15 1.214(11) . ?
N4 O13 1.227(14) . ?
N4 O14 1.259(13) . ?
N4 Eu2 2.904(10) . ?
O1 Eu2 2.463(6) . ?
O2 Eu2 2.461(7) . ?
O3 Eu1 2.408(6) 1_666 ?
O4 Eu1 2.522(7) 1_666 ?
O5 Eu2 2.337(6) . ?
O6 Eu1 2.381(7) . ?
O7 Eu2 2.431(6) 1_665 ?
O8 Eu1 2.362(6) 1_665 ?
O8 Eu2 2.748(6) 1_665 ?
O9 Eu1 2.467(6) . ?
O10 Eu2 2.351(5) . ?
O10 Eu1 2.739(6) . ?
O11 Eu1 2.403(6) 1_665 ?
O12 Eu2 2.339(6) 1_665 ?
O13 Eu2 2.501(7) . ?
O14 Eu2 2.531(7) . ?
OW1 Eu1 2.468(7) . ?
OW2 Eu1 2.657(8) . ?
Eu1 Eu2 3.9960(12) . ?
loop_
_geom_torsion_atom_site_label_1
_geom_torsion_atom_site_label_2
_geom_torsion_atom_site_label_3
_geom_torsion_atom_site_label_4
_geom_torsion
_geom_torsion_site_symmetry_1
_geom_torsion_site_symmetry_2
_geom_torsion_site_symmetry_3
_geom_torsion_site_symmetry_4
_geom_torsion_publ_flag
O1 C1 C2 C3 -25.3(13) . . . . ?
O2 C1 C2 C3 153.2(9) . . . . ?
O1 C1 C2 C7 154.0(9) . . . . ?
O2 C1 C2 C7 -27.5(13) . . . . ?
C7 C2 C3 C4 3.8(15) . . . . ?
C1 C2 C3 C4 -176.9(9) . . . . ?
C2 C3 C4 C5 -4.0(16) . . . . ?
C3 C4 C5 C6 1.8(16) . . . . ?
C3 C4 C5 C8 179.9(10) . . . . ?
C4 C5 C6 C7 0.6(15) . . . . ?
C8 C5 C6 C7 -177.5(9) . . . . ?
C5 C6 C7 C2 -0.8(15) . . . . ?
C3 C2 C7 C6 -1.5(14) . . . . ?
C1 C2 C7 C6 179.2(9) . . . . ?
C6 C5 C8 N1 -130.8(10) . . . . ?
C4 C5 C8 N1 51.1(14) . . . . ?
N1 C9 C10 C11 -1.3(18) . . . . ?
C9 C10 C11 C12 1.8(17) . . . . ?
C9 C10 C11 C14 -179.5(10) . . . . ?
C10 C11 C12 C13 -3.4(16) . . . . ?
C14 C11 C12 C13 177.8(10) . . . . ?
C11 C12 C13 N1 4.7(17) . . . . ?
C12 C11 C14 C19 -23.8(15) . . . . ?
C10 C11 C14 C19 157.5(11) . . . . ?
C12 C11 C14 C15 155.5(11) . . . . ?
C10 C11 C14 C15 -23.2(15) . . . . ?
C19 C14 C15 C16 0.9(16) . . . . ?
C11 C14 C15 C16 -178.5(10) . . . . ?
C14 C15 C16 C17 0.5(17) . . . . ?
C15 C16 C17 C18 -3.5(16) . . . . ?
C15 C16 C17 C20 -179.0(9) . . . . ?
C16 C17 C18 C19 5.3(16) . . . . ?
C20 C17 C18 C19 -179.1(9) . . . . ?
C17 C18 C19 C14 -4.0(16) . . . . ?
C15 C14 C19 C18 0.8(16) . . . . ?
C11 C14 C19 C18 -179.9(9) . . . . ?
C18 C17 C20 O3 -15.2(14) . . . . ?
C16 C17 C20 O3 160.2(10) . . . . ?
C18 C17 C20 O4 163.5(9) . . . . ?
C16 C17 C20 O4 -21.1(15) . . . . ?
O6 C21 C22 C23 -176.6(10) . . . . ?
O5 C21 C22 C23 3.6(15) . . . . ?
O6 C21 C22 C27 3.9(15) . . . . ?
O5 C21 C22 C27 -175.8(9) . . . . ?
C27 C22 C23 C24 0.9(17) . . . . ?
C21 C22 C23 C24 -178.6(10) . . . . ?
C22 C23 C24 C25 -1.9(18) . . . . ?
C23 C24 C25 C26 1.9(17) . . . . ?
C23 C24 C25 C28 -178.3(10) . . . . ?
C24 C25 C26 C27 -0.9(16) . . . . ?
C28 C25 C26 C27 179.2(10) . . . . ?
C25 C26 C27 C22 0.0(17) . . . . ?
C23 C22 C27 C26 0.1(16) . . . . ?
C21 C22 C27 C26 179.5(10) . . . . ?
C26 C25 C28 C32 -30.3(15) . . . . ?
C24 C25 C28 C32 149.9(11) . . . . ?
C26 C25 C28 C29 151.9(10) . . . . ?
C24 C25 C28 C29 -27.9(16) . . . . ?
C32 C28 C29 C30 5.6(16) . . . . ?
C25 C28 C29 C30 -176.5(10) . . . . ?
C28 C29 C30 N3 -1.0(16) . . . . ?
C29 C28 C32 C31 -7.6(16) . . . . ?
C25 C28 C32 C31 174.5(10) . . . . ?
N3 C31 C32 C28 5.3(18) . . . . ?
N3 C33 C34 C35 -99.5(11) . . . . ?
N3 C33 C34 C39 79.7(11) . . . . ?
C39 C34 C35 C36 4.8(14) . . . . ?
C33 C34 C35 C36 -176.0(8) . . . . ?
C34 C35 C36 C37 -2.6(15) . . . . ?
C35 C36 C37 C38 -0.6(13) . . . . ?
C35 C36 C37 C40 178.2(9) . . . . ?
C36 C37 C38 C39 1.2(13) . . . . ?
C40 C37 C38 C39 -177.5(8) . . . . ?
C37 C38 C39 C34 1.2(14) . . . . ?
C35 C34 C39 C38 -4.1(14) . . . . ?
C33 C34 C39 C38 176.7(8) . . . . ?
C36 C37 C40 O7 20.1(14) . . . . ?
C38 C37 C40 O7 -161.2(9) . . . . ?
C36 C37 C40 O8 -158.1(8) . . . . ?
C38 C37 C40 O8 20.6(14) . . . . ?
O9 C41 C42 C47 163.9(9) . . . . ?
O10 C41 C42 C47 -15.0(13) . . . . ?
Eu1 C41 C42 C47 102(3) . . . . ?
O9 C41 C42 C43 -18.8(13) . . . . ?
O10 C41 C42 C43 162.3(8) . . . . ?
Eu1 C41 C42 C43 -80(3) . . . . ?
C47 C42 C43 C44 1.7(14) . . . . ?
C41 C42 C43 C44 -175.8(9) . . . . ?
C42 C43 C44 C45 1.6(16) . . . . ?
C43 C44 C45 C46 -4.5(15) . . . . ?
C43 C44 C45 C48 173.4(9) . . . . ?
C44 C45 C46 C47 4.2(16) . . . . ?
C48 C45 C46 C47 -173.6(9) . . . . ?
C45 C46 C47 C42 -0.8(16) . . . . ?
C43 C42 C47 C46 -2.1(15) . . . . ?
C41 C42 C47 C46 175.3(9) . . . . ?
C44 C45 C48 N2 109.0(11) . . . . ?
C46 C45 C48 N2 -73.2(13) . . . . ?
N2 C49 C50 C51 2(3) . . . . ?
C49 C50 C51 C52 -1(2) . . . . ?
C49 C50 C51 C54 -179.6(14) . . . . ?
C50 C51 C52 C53 1.9(17) . . . . ?
C54 C51 C52 C53 -179.9(10) . . . . ?
C51 C52 C53 N2 -3.3(18) . . . . ?
C50 C51 C54 C59 -178.3(12) . . . . ?
C52 C51 C54 C59 3.6(17) . . . . ?
C50 C51 C54 C55 -0.9(17) . . . . ?
C52 C51 C54 C55 -179.0(11) . . . . ?
C59 C54 C55 C56 -1.1(17) . . . . ?
C51 C54 C55 C56 -178.6(10) . . . . ?
C54 C55 C56 C57 -0.1(18) . . . . ?
C55 C56 C57 C58 1.4(17) . . . . ?
C55 C56 C57 C60 -178.3(10) . . . . ?
C56 C57 C58 C59 -1.5(18) . . . . ?
C60 C57 C58 C59 178.2(11) . . . . ?
C57 C58 C59 C54 0(2) . . . . ?
C55 C54 C59 C58 1.1(19) . . . . ?
C51 C54 C59 C58 178.5(11) . . . . ?
C56 C57 C60 O11 -178.5(10) . . . . ?
C58 C57 C60 O11 1.8(15) . . . . ?
C56 C57 C60 O12 0.4(14) . . . . ?
C58 C57 C60 O12 -179.3(10) . . . . ?
C10 C9 N1 C13 2.5(17) . . . . ?
C10 C9 N1 C8 -179.5(10) . . . . ?
C12 C13 N1 C9 -4.1(16) . . . . ?
C12 C13 N1 C8 177.8(9) . . . . ?
C5 C8 N1 C9 94.2(13) . . . . ?
C5 C8 N1 C13 -87.8(12) . . . . ?
C52 C53 N2 C49 3.9(18) . . . . ?
C52 C53 N2 C48 -177.3(10) . . . . ?
C50 C49 N2 C53 -3(2) . . . . ?
C50 C49 N2 C48 177.9(13) . . . . ?
C45 C48 N2 C53 -75.6(13) . . . . ?
C45 C48 N2 C49 103.2(14) . . . . ?
C32 C31 N3 C30 -0.3(16) . . . . ?
C32 C31 N3 C33 179.1(9) . . . . ?
C29 C30 N3 C31 -1.7(15) . . . . ?
C29 C30 N3 C33 178.8(8) . . . . ?
C34 C33 N3 C31 -83.7(11) . . . . ?
C34 C33 N3 C30 95.7(10) . . . . ?
O2 C1 O1 Eu2 9.2(9) . . . . ?
C2 C1 O1 Eu2 -172.3(7) . . . . ?
O1 C1 O2 Eu2 -9.2(9) . . . . ?
C2 C1 O2 Eu2 172.3(7) . . . . ?
O4 C20 O3 Eu1 3.6(10) . . . 1_666 ?
C17 C20 O3 Eu1 -177.7(7) . . . 1_666 ?
O3 C20 O4 Eu1 -3.4(10) . . . 1_666 ?
C17 C20 O4 Eu1 177.9(8) . . . 1_666 ?
O6 C21 O5 Eu2 38.2(15) . . . . ?
C22 C21 O5 Eu2 -142.1(7) . . . . ?
O5 C21 O6 Eu1 -26.8(16) . . . . ?
C22 C21 O6 Eu1 153.4(7) . . . . ?
O8 C40 O7 Eu2 -6.8(10) . . . 1_665 ?
C37 C40 O7 Eu2 175.1(7) . . . 1_665 ?
O7 C40 O8 Eu2 5.9(9) . . . 1_665 ?
C37 C40 O8 Eu2 -176.0(8) . . . 1_665 ?
O10 C41 O9 Eu1 14.0(10) . . . . ?
C42 C41 O9 Eu1 -164.9(7) . . . . ?
O9 C41 O10 Eu2 138(2) . . . . ?
C42 C41 O10 Eu2 -43(3) . . . . ?
Eu1 C41 O10 Eu2 150(3) . . . . ?
O9 C41 O10 Eu1 -12.4(8) . . . . ?
C42 C41 O10 Eu1 166.5(7) . . . . ?
O12 C60 O11 Eu1 -38.9(15) . . . 1_665 ?
C57 C60 O11 Eu1 139.9(7) . . . 1_665 ?
O11 C60 O12 Eu2 17.2(16) . . . 1_665 ?
C57 C60 O12 Eu2 -161.7(6) . . . 1_665 ?
O15 N4 O13 Eu2 174.4(11) . . . . ?
O14 N4 O13 Eu2 -5.6(13) . . . . ?
O15 N4 O14 Eu2 -174.5(11) . . . . ?
O13 N4 O14 Eu2 5.5(12) . . . . ?
