#------------------------------------------------------------------------------
#$Date: 2021-11-23 11:29:42 +0200 (Tue, 23 Nov 2021) $
#$Revision: 270824 $
#$URL: file:///home/coder/svn-repositories/cod/cif/1/56/53/1565351.cif $
#------------------------------------------------------------------------------
#
# This file is available in the Crystallography Open Database (COD),
# http://www.crystallography.net/
#
# All data on this site have been placed in the public domain by the
# contributors.
#
data_1565351
loop_
_publ_author_name
'Berti, Beatrice'
'Bortoluzzi, Marco'
'Cesari, Cristiana'
'Femoni, Cristina'
'Iapalucci, Maria Carmela'
'Zacchini, Stefano'
_publ_section_title
;
 Reactions of [Pt6(CO)6(SnX2)2(SnX3)4]4-- (X = Cl, Br) with
 Acids: Syntheses and molecular structures of
 [Pt12(CO)10(SnCl)2(SnCl2)4{Cl2Sn(μ-OH)SnCl2}2]2-- And
 [Pt7(CO)6(SnBr2)4{Br2Sn(μ-OH)SnBr2}{Br2Sn(μ-Br)SnBr2}]2-- Platinum
 carbonyl clusters decorated by Sn(II)-Fragments
;
_journal_name_full               'Inorganica Chimica Acta'
_journal_page_first              119432
_journal_paper_doi               10.1016/j.ica.2020.119432
_journal_volume                  503
_journal_year                    2020
_chemical_formula_sum            'C50 H40 Br6 O2 P2 Pt2 Sn'
_chemical_formula_weight         1723.09
_space_group_crystal_system      monoclinic
_space_group_IT_number           14
_space_group_name_Hall           '-P 2ybc'
_space_group_name_H-M_alt        'P 1 21/c 1'
_atom_sites_solution_hydrogens   geom
_audit_creation_method           SHELXL-2014/7
_cell_angle_alpha                90
_cell_angle_beta                 110.363(2)
_cell_angle_gamma                90
_cell_formula_units_Z            4
_cell_length_a                   22.1246(16)
_cell_length_b                   13.9666(10)
_cell_length_c                   18.0304(14)
_cell_measurement_reflns_used    9870
_cell_measurement_temperature    100(2)
_cell_measurement_theta_max      28.1045
_cell_measurement_theta_min      2.2635
_cell_volume                     5223.3(7)
_computing_cell_refinement       'APEX2 (Bruker AXS, 2006)'
_computing_data_collection       'APEX2 (Bruker AXS, 2006)'
_computing_data_reduction        'SAINT (Bruker AXS, 2004)'
_computing_molecular_graphics    'SCHAKAL99 (Keller, 1999)'
_computing_publication_material  'XCIF (Bruker AXS, 2001)'
_computing_structure_refinement  'SHELXL-2014/7 (Sheldrick, 2014)'
_computing_structure_solution    'SHELXL-2014/7 (Sheldrick, 2014)'
_diffrn_ambient_temperature      100(2)
_diffrn_measured_fraction_theta_full 1.000
_diffrn_measured_fraction_theta_max 1.000
_diffrn_measurement_device_type  'PHOTON100 area detector'
_diffrn_measurement_method       'phi and omega scans'
_diffrn_radiation_type           MoK\a
_diffrn_radiation_wavelength     0.71073
_diffrn_reflns_av_R_equivalents  0.0909
_diffrn_reflns_av_unetI/netI     0.0572
_diffrn_reflns_Laue_measured_fraction_full 1.000
_diffrn_reflns_Laue_measured_fraction_max 1.000
_diffrn_reflns_limit_h_max       27
_diffrn_reflns_limit_h_min       -27
_diffrn_reflns_limit_k_max       17
_diffrn_reflns_limit_k_min       -17
_diffrn_reflns_limit_l_max       22
_diffrn_reflns_limit_l_min       -22
_diffrn_reflns_number            63258
_diffrn_reflns_point_group_measured_fraction_full 1.000
_diffrn_reflns_point_group_measured_fraction_max 1.000
_diffrn_reflns_theta_full        25.242
_diffrn_reflns_theta_max         26.000
_diffrn_reflns_theta_min         1.758
_diffrn_source                   'fine-focus sealed tube'
_exptl_absorpt_coefficient_mu    10.506
_exptl_absorpt_correction_T_max  0.1519
_exptl_absorpt_correction_T_min  0.0383
_exptl_absorpt_correction_type   empirical
_exptl_absorpt_process_details
;
 Data were corrected for Lorentz polarization and absorption
 effects (empirical absorption corrections SADABS).
 R(int) = 0.1734 (selected reflections only, before parameter refinement)
 R(int) = 0.0965 (selected reflections only, after parameter refinement)
;
_exptl_crystal_colour            yellow
_exptl_crystal_density_diffrn    2.191
_exptl_crystal_description       plate
_exptl_crystal_F_000             3208
_exptl_crystal_size_max          0.160
_exptl_crystal_size_mid          0.150
_exptl_crystal_size_min          0.110
_refine_diff_density_max         2.295
_refine_diff_density_min         -2.302
_refine_diff_density_rms         0.243
_refine_ls_extinction_coef       .
_refine_ls_extinction_method     none
_refine_ls_goodness_of_fit_ref   1.058
_refine_ls_hydrogen_treatment    constr
_refine_ls_matrix_type           full
_refine_ls_number_parameters     568
_refine_ls_number_reflns         10261
_refine_ls_number_restraints     12
_refine_ls_restrained_S_all      1.059
_refine_ls_R_factor_all          0.0546
_refine_ls_R_factor_gt           0.0430
_refine_ls_shift/su_max          0.001
_refine_ls_shift/su_mean         0.000
_refine_ls_structure_factor_coef Fsqd
_refine_ls_weighting_details
'w=1/[σ²(Fo²)+(0.0496P)²+29.7489P] where P=(Fo²+2Fc²)/3'
_refine_ls_weighting_scheme      calc
_refine_ls_wR_factor_gt          0.1009
_refine_ls_wR_factor_ref         0.1070
_reflns_Friedel_coverage         0.000
_reflns_Friedel_fraction_full    .
_reflns_Friedel_fraction_max     .
_reflns_number_gt                8808
_reflns_number_total             10261
_reflns_threshold_expression     'I > 2σ(I)'
_cod_data_source_file            ICA-2020-503-119432.cif
_cod_data_source_block           5
_cod_original_sg_symbol_H-M      'P 21/c'
_cod_database_code               1565351
_shelx_shelxl_version_number     2014/7
_shelx_space_group_comment
;
The symmetry employed for this shelxl refinement is uniquely defined
by the following loop, which should always be used as a source of
symmetry information in preference to the above space-group names.
They are only intended as comments.
;
_shelx_estimated_absorpt_t_min   0.284
_shelx_estimated_absorpt_t_max   0.391
loop_
_space_group_symop_operation_xyz
'x, y, z'
'-x, y+1/2, -z+1/2'
'-x, -y, -z'
'x, -y-1/2, z-1/2'
loop_
_atom_site_label
_atom_site_type_symbol
_atom_site_fract_x
_atom_site_fract_y
_atom_site_fract_z
_atom_site_U_iso_or_equiv
_atom_site_adp_type
_atom_site_occupancy
_atom_site_site_symmetry_order
_atom_site_calc_flag
_atom_site_refinement_flags_posn
_atom_site_refinement_flags_adp
_atom_site_refinement_flags_occupancy
_atom_site_disorder_assembly
_atom_site_disorder_group
Pt1 Pt 0.76535(2) 0.37393(2) 0.57163(2) 0.01079(8) Uani 1 1 d . . . . .
Pt2 Pt 0.72755(2) 0.64345(2) 0.44074(2) 0.01246(8) Uani 1 1 d . . . . .
Sn1 Sn 0.70298(2) 0.46652(3) 0.44683(3) 0.01262(12) Uani 1 1 d . . . . .
Br1 Br 0.83511(4) 0.29953(5) 0.70089(4) 0.01921(17) Uani 1 1 d . . . . .
Br2 Br 0.85749(4) 0.45604(5) 0.55360(4) 0.01675(16) Uani 1 1 d . . . . .
Br3 Br 0.75579(4) 0.81753(5) 0.45083(6) 0.0256(2) Uani 1 1 d . . . . .
Br4 Br 0.70092(4) 0.64943(6) 0.56140(5) 0.02298(18) Uani 1 1 d . . . . .
Br5 Br 0.71890(4) 0.37143(5) 0.33406(5) 0.02184(18) Uani 1 1 d . . . . .
Br6 Br 0.58149(4) 0.44440(6) 0.40263(5) 0.0288(2) Uani 1 1 d . . . . .
C1 C 0.6917(4) 0.3151(6) 0.5714(4) 0.0209(18) Uani 1 1 d . . . . .
C2 C 0.7447(4) 0.6300(5) 0.3477(4) 0.0176(16) Uani 1 1 d . . . . .
O1 O 0.6457(3) 0.2779(4) 0.5721(3) 0.0264(13) Uani 1 1 d . . . . .
O2 O 0.7554(3) 0.6241(4) 0.2933(4) 0.0332(15) Uani 1 1 d . . . . .
P1 P 0.96440(9) 0.99067(12) 0.64828(11) 0.0106(4) Uani 1 1 d . . . . .
C101 C 0.9714(3) 0.8689(5) 0.6221(4) 0.0113(14) Uani 1 1 d . . . . .
C102 C 0.9196(4) 0.8074(5) 0.6118(5) 0.0170(16) Uani 1 1 d . . . . .
H102 H 0.8819 0.8305 0.6196 0.020 Uiso 1 1 calc R U . . .
C103 C 0.9225(4) 0.7137(5) 0.5905(5) 0.0213(17) Uani 1 1 d . . . . .
H103 H 0.8871 0.6719 0.5838 0.026 Uiso 1 1 calc R U . . .
C104 C 0.9777(4) 0.6805(5) 0.5788(5) 0.0223(18) Uani 1 1 d . . . . .
H104 H 0.9799 0.6157 0.5639 0.027 Uiso 1 1 calc R U . . .
C105 C 1.0294(4) 0.7406(5) 0.5887(5) 0.0204(17) Uani 1 1 d . . . . .
H105 H 1.0671 0.7169 0.5813 0.024 Uiso 1 1 calc R U . . .
C106 C 1.0263(4) 0.8353(5) 0.6093(5) 0.0170(16) Uani 1 1 d . . . . .
H106 H 1.0614 0.8772 0.6147 0.020 Uiso 1 1 calc R U . . .
C107 C 1.0391(3) 1.0547(5) 0.6713(4) 0.0108(14) Uani 1 1 d . . . . .
C108 C 1.0852(4) 1.0475(6) 0.7450(5) 0.0208(17) Uani 1 1 d . . . . .
H108 H 1.0781 1.0066 0.7833 0.025 Uiso 1 1 calc R U . . .
C109 C 1.1421(4) 1.0990(6) 0.7645(5) 0.0249(19) Uani 1 1 d . . . . .
H109 H 1.1741 1.0929 0.8155 0.030 Uiso 1 1 calc R U . . .
C110 C 1.1519(4) 1.1596(6) 0.7090(5) 0.0229(18) Uani 1 1 d . . . . .
H110 H 1.1902 1.1967 0.7229 0.027 Uiso 1 1 calc R U . . .
C111 C 1.1066(4) 1.1666(5) 0.6337(5) 0.0184(16) Uani 1 1 d . . . . .
H111 H 1.1140 1.2073 0.5955 0.022 Uiso 1 1 calc R U . . .
C112 C 1.0503(4) 1.1139(5) 0.6144(4) 0.0151(15) Uani 1 1 d . . . . .
H112 H 1.0192 1.1177 0.5626 0.018 Uiso 1 1 calc R U . . .
C113 C 0.9060(3) 1.0511(5) 0.5664(4) 0.0090(14) Uani 1 1 d . . . . .
C114 C 0.8719(3) 0.9985(5) 0.4979(4) 0.0137(15) Uani 1 1 d . . . . .
H114 H 0.8769 0.9311 0.4965 0.016 Uiso 1 1 calc R U . . .
C115 C 0.8307(4) 1.0469(5) 0.4325(5) 0.0183(16) Uani 1 1 d . . . . .
H115 H 0.8072 1.0119 0.3863 0.022 Uiso 1 1 calc R U . . .
C116 C 0.8234(4) 1.1456(5) 0.4338(5) 0.0181(16) Uani 1 1 d . . . . .
H116 H 0.7961 1.1782 0.3882 0.022 Uiso 1 1 calc R U . . .
C117 C 0.8564(4) 1.1960(5) 0.5022(4) 0.0147(15) Uani 1 1 d . . . . .
H117 H 0.8505 1.2633 0.5036 0.018 Uiso 1 1 calc R U . . .
C118 C 0.8978(4) 1.1501(5) 0.5683(5) 0.0164(16) Uani 1 1 d . . . . .
H118 H 0.9204 1.1856 0.6147 0.020 Uiso 1 1 calc R U . . .
C119 C 0.9421(3) 0.9853(5) 0.7347(4) 0.0125(15) Uani 1 1 d . . . . .
C120 C 0.9700(4) 0.9159(5) 0.7913(5) 0.0213(17) Uani 1 1 d . . . . .
H120 H 0.9997 0.8714 0.7835 0.026 Uiso 1 1 calc R U . . .
C121 C 0.9544(4) 0.9115(6) 0.8599(5) 0.0273(19) Uani 1 1 d . . . . .
H121 H 0.9748 0.8659 0.8999 0.033 Uiso 1 1 calc R U . . .
C122 C 0.9093(4) 0.9740(6) 0.8691(5) 0.0252(19) Uani 1 1 d . U . . .
H122 H 0.8969 0.9688 0.9143 0.030 Uiso 1 1 calc R U . . .
C123 C 0.8822(4) 1.0429(7) 0.8141(5) 0.027(2) Uani 1 1 d . . . . .
H123 H 0.8525 1.0870 0.8225 0.033 Uiso 1 1 calc R U . . .
C124 C 0.8974(4) 1.0497(6) 0.7462(5) 0.0190(17) Uani 1 1 d . . . . .
H124 H 0.8778 1.0973 0.7077 0.023 Uiso 1 1 calc R U . . .
P2 P 0.42022(9) 0.99272(13) 0.61248(11) 0.0112(4) Uani 1 1 d . . . . .
C201 C 0.4782(4) 0.8980(5) 0.6322(5) 0.0155(16) Uani 1 1 d . . . . .
C202 C 0.4804(4) 0.8387(6) 0.5714(5) 0.0262(19) Uani 1 1 d . . . . .
H202 H 0.4504 0.8467 0.5192 0.031 Uiso 1 1 calc R U . . .
C203 C 0.5266(5) 0.7682(7) 0.5878(6) 0.038(2) Uani 1 1 d . . . . .
H203 H 0.5279 0.7264 0.5468 0.046 Uiso 1 1 calc R U . . .
C204 C 0.5708(5) 0.7574(7) 0.6626(6) 0.044(3) Uani 1 1 d . U . . .
H204 H 0.6030 0.7093 0.6728 0.052 Uiso 1 1 calc R U . . .
C205 C 0.5686(4) 0.8166(7) 0.7237(6) 0.035(2) Uani 1 1 d . . . . .
H205 H 0.5996 0.8093 0.7753 0.042 Uiso 1 1 calc R U . . .
C206 C 0.5210(4) 0.8864(6) 0.7093(5) 0.0222(18) Uani 1 1 d . . . . .
H206 H 0.5177 0.9252 0.7510 0.027 Uiso 1 1 calc R U . . .
C207 C 0.4597(3) 1.1062(5) 0.6221(4) 0.0116(14) Uani 1 1 d . . . . .
C208 C 0.5251(4) 1.1159(5) 0.6652(4) 0.0160(16) Uani 1 1 d . . . . .
H208 H 0.5496 1.0616 0.6902 0.019 Uiso 1 1 calc R U . . .
C209 C 0.5550(4) 1.2049(6) 0.6717(5) 0.0223(18) Uani 1 1 d . . . . .
H209 H 0.5998 1.2112 0.7005 0.027 Uiso 1 1 calc R U . . .
C210 C 0.5189(4) 1.2842(6) 0.6361(5) 0.0190(16) Uani 1 1 d . . . . .
H210 H 0.5391 1.3450 0.6401 0.023 Uiso 1 1 calc R U . . .
C211 C 0.4543(4) 1.2749(5) 0.5950(5) 0.0178(16) Uani 1 1 d . . . . .
H211 H 0.4296 1.3297 0.5716 0.021 Uiso 1 1 calc R U . . .
C212 C 0.4247(4) 1.1866(5) 0.5872(4) 0.0155(16) Uani 1 1 d . . . . .
H212 H 0.3800 1.1809 0.5576 0.019 Uiso 1 1 calc R U . . .
C213 C 0.3646(3) 0.9822(5) 0.5128(4) 0.0137(15) Uani 1 1 d . . . . .
C214 C 0.3810(4) 1.0162(7) 0.4510(5) 0.0264(19) Uani 1 1 d . . . . .
H214 H 0.4213 1.0472 0.4614 0.032 Uiso 1 1 calc R U . . .
C215 C 0.3392(4) 1.0059(7) 0.3734(5) 0.029(2) Uani 1 1 d . . . . .
H215 H 0.3504 1.0298 0.3306 0.035 Uiso 1 1 calc R U . . .
C216 C 0.2808(4) 0.9601(6) 0.3599(5) 0.0238(18) Uani 1 1 d . . . . .
H216 H 0.2519 0.9519 0.3072 0.029 Uiso 1 1 calc R U . . .
C217 C 0.2641(4) 0.9263(6) 0.4215(5) 0.0223(18) Uani 1 1 d . . . . .
H217 H 0.2237 0.8955 0.4108 0.027 Uiso 1 1 calc R U . . .
C218 C 0.3049(4) 0.9363(5) 0.4981(4) 0.0181(16) Uani 1 1 d . . . . .
H218 H 0.2931 0.9127 0.5406 0.022 Uiso 1 1 calc R U . . .
C219 C 0.3771(3) 0.9825(5) 0.6796(4) 0.0132(15) Uani 1 1 d . . . . .
C220 C 0.3573(4) 1.0643(6) 0.7088(5) 0.0199(17) Uani 1 1 d . . . . .
H220 H 0.3705 1.1256 0.6976 0.024 Uiso 1 1 calc R U . . .
C221 C 0.3186(4) 1.0564(6) 0.7536(5) 0.0260(19) Uani 1 1 d . . . . .
H221 H 0.3052 1.1124 0.7735 0.031 Uiso 1 1 calc R U . . .
C222 C 0.2989(4) 0.9671(6) 0.7701(5) 0.0209(17) Uani 1 1 d . . . . .
H222 H 0.2723 0.9622 0.8015 0.025 Uiso 1 1 calc R U . . .
C223 C 0.3177(4) 0.8860(5) 0.7413(4) 0.0173(16) Uani 1 1 d . . . . .
H223 H 0.3041 0.8249 0.7525 0.021 Uiso 1 1 calc R U . . .
C224 C 0.3568(4) 0.8934(5) 0.6959(4) 0.0146(15) Uani 1 1 d . . . . .
H224 H 0.3698 0.8372 0.6759 0.018 Uiso 1 1 calc R U . . .
loop_
_atom_type_symbol
_atom_type_description
_atom_type_scat_dispersion_real
_atom_type_scat_dispersion_imag
_atom_type_scat_source
C C 0.0033 0.0016 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
H H 0.0000 0.0000 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
O O 0.0106 0.0060 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
P P 0.1023 0.0942 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
Br Br -0.2901 2.4595 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
Sn Sn -0.6537 1.4246 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
Pt Pt -1.7033 8.3905 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
loop_
_geom_angle_atom_site_label_1
_geom_angle_atom_site_label_2
_geom_angle_atom_site_label_3
_geom_angle
_geom_angle_site_symmetry_1
_geom_angle_site_symmetry_3
C1 Pt1 Br2 172.6(2) . .
C1 Pt1 Br1 94.3(2) . .
Br2 Pt1 Br1 92.60(3) . .
C1 Pt1 Sn1 91.0(2) . .
Br2 Pt1 Sn1 82.27(2) . .
Br1 Pt1 Sn1 173.28(2) . .
C2 Pt2 Br4 175.7(2) . .
C2 Pt2 Br3 92.3(2) . .
Br4 Pt2 Br3 91.92(3) . .
C2 Pt2 Sn1 93.1(2) . .
Br4 Pt2 Sn1 82.72(2) . .
Br3 Pt2 Sn1 173.76(3) . .
Pt2 Sn1 Br6 108.87(3) . .
Pt2 Sn1 Pt1 118.30(2) . .
Br6 Sn1 Pt1 113.84(3) . .
Pt2 Sn1 Br5 112.37(3) . .
Br6 Sn1 Br5 96.37(3) . .
Pt1 Sn1 Br5 104.90(3) . .
O1 C1 Pt1 179.3(7) . .
O2 C2 Pt2 178.4(7) . .
C101 P1 C119 105.4(3) . .
C101 P1 C107 112.2(3) . .
C119 P1 C107 109.2(3) . .
C101 P1 C113 109.5(3) . .
C119 P1 C113 113.4(3) . .
C107 P1 C113 107.2(3) . .
C102 C101 C106 119.6(7) . .
C102 C101 P1 118.7(6) . .
C106 C101 P1 121.8(6) . .
C103 C102 C101 120.7(7) . .
C103 C102 H102 119.7 . .
C101 C102 H102 119.7 . .
C102 C103 C104 119.4(7) . .
C102 C103 H103 120.3 . .
C104 C103 H103 120.3 . .
C105 C104 C103 120.7(7) . .
C105 C104 H104 119.7 . .
C103 C104 H104 119.7 . .
C104 C105 C106 120.0(7) . .
C104 C105 H105 120.0 . .
C106 C105 H105 120.0 . .
C105 C106 C101 119.7(7) . .
C105 C106 H106 120.2 . .
C101 C106 H106 120.2 . .
C108 C107 C112 119.4(7) . .
C108 C107 P1 120.2(6) . .
C112 C107 P1 120.4(6) . .
C107 C108 C109 120.8(7) . .
C107 C108 H108 119.6 . .
C109 C108 H108 119.6 . .
C110 C109 C108 119.5(8) . .
C110 C109 H109 120.3 . .
C108 C109 H109 120.3 . .
C111 C110 C109 120.7(7) . .
C111 C110 H110 119.7 . .
C109 C110 H110 119.7 . .
C112 C111 C110 119.4(7) . .
C112 C111 H111 120.3 . .
C110 C111 H111 120.3 . .
C111 C112 C107 120.1(7) . .
C111 C112 H112 119.9 . .
C107 C112 H112 119.9 . .
C118 C113 C114 120.2(6) . .
C118 C113 P1 120.5(6) . .
C114 C113 P1 119.2(5) . .
C115 C114 C113 119.0(6) . .
C115 C114 H114 120.5 . .
C113 C114 H114 120.5 . .
C114 C115 C116 120.9(7) . .
C114 C115 H115 119.5 . .
C116 C115 H115 119.5 . .
C117 C116 C115 119.4(7) . .
C117 C116 H116 120.3 . .
C115 C116 H116 120.3 . .
C118 C117 C116 121.1(7) . .
C118 C117 H117 119.4 . .
C116 C117 H117 119.4 . .
C117 C118 C113 119.4(7) . .
C117 C118 H118 120.3 . .
C113 C118 H118 120.3 . .
C120 C119 C124 119.7(7) . .
C120 C119 P1 118.8(6) . .
C124 C119 P1 121.5(6) . .
C119 C120 C121 119.9(8) . .
C119 C120 H120 120.1 . .
C121 C120 H120 120.1 . .
C122 C121 C120 119.5(8) . .
C122 C121 H121 120.3 . .
C120 C121 H121 120.3 . .
C123 C122 C121 120.8(8) . .
C123 C122 H122 119.6 . .
C121 C122 H122 119.6 . .
C122 C123 C124 120.9(8) . .
C122 C123 H123 119.6 . .
C124 C123 H123 119.6 . .
C123 C124 C119 119.2(8) . .
C123 C124 H124 120.4 . .
C119 C124 H124 120.4 . .
C207 P2 C219 111.3(3) . .
C207 P2 C201 110.1(3) . .
C219 P2 C201 108.7(3) . .
C207 P2 C213 108.1(3) . .
C219 P2 C213 109.2(3) . .
C201 P2 C213 109.4(4) . .
C202 C201 C206 121.3(8) . .
C202 C201 P2 120.2(6) . .
C206 C201 P2 118.4(6) . .
C203 C202 C201 119.0(9) . .
C203 C202 H202 120.5 . .
C201 C202 H202 120.5 . .
C204 C203 C202 120.8(9) . .
C204 C203 H203 119.6 . .
C202 C203 H203 119.6 . .
C203 C204 C205 120.3(8) . .
C203 C204 H204 119.8 . .
C205 C204 H204 119.8 . .
C204 C205 C206 120.1(9) . .
C204 C205 H205 120.0 . .
C206 C205 H205 120.0 . .
C201 C206 C205 118.4(8) . .
C201 C206 H206 120.8 . .
C205 C206 H206 120.8 . .
C212 C207 C208 118.9(7) . .
C212 C207 P2 119.8(6) . .
C208 C207 P2 121.3(6) . .
C207 C208 C209 120.3(7) . .
C207 C208 H208 119.8 . .
C209 C208 H208 119.8 . .
C210 C209 C208 119.6(7) . .
C210 C209 H209 120.2 . .
C208 C209 H209 120.2 . .
C211 C210 C209 120.0(7) . .
C211 C210 H210 120.0 . .
C209 C210 H210 120.0 . .
C210 C211 C212 120.6(7) . .
C210 C211 H211 119.7 . .
C212 C211 H211 119.7 . .
C211 C212 C207 120.5(7) . .
C211 C212 H212 119.7 . .
C207 C212 H212 119.7 . .
C214 C213 C218 120.1(7) . .
C214 C213 P2 120.1(6) . .
C218 C213 P2 119.8(6) . .
C213 C214 C215 120.7(8) . .
C213 C214 H214 119.6 . .
C215 C214 H214 119.6 . .
C216 C215 C214 118.5(8) . .
C216 C215 H215 120.7 . .
C214 C215 H215 120.7 . .
C217 C216 C215 120.9(7) . .
C217 C216 H216 119.5 . .
C215 C216 H216 119.5 . .
C216 C217 C218 121.0(7) . .
C216 C217 H217 119.5 . .
C218 C217 H217 119.5 . .
C217 C218 C213 118.7(7) . .
C217 C218 H218 120.6 . .
C213 C218 H218 120.6 . .
C224 C219 C220 119.2(7) . .
C224 C219 P2 120.2(6) . .
C220 C219 P2 120.2(6) . .
C221 C220 C219 120.1(7) . .
C221 C220 H220 120.0 . .
C219 C220 H220 120.0 . .
C220 C221 C222 120.4(8) . .
C220 C221 H221 119.8 . .
C222 C221 H221 119.8 . .
C223 C222 C221 120.2(7) . .
C223 C222 H222 119.9 . .
C221 C222 H222 119.9 . .
C222 C223 C224 119.8(7) . .
C222 C223 H223 120.1 . .
C224 C223 H223 120.1 . .
C223 C224 C219 120.4(7) . .
C223 C224 H224 119.8 . .
C219 C224 H224 119.8 . .
loop_
_geom_bond_atom_site_label_1
_geom_bond_atom_site_label_2
_geom_bond_distance
_geom_bond_site_symmetry_2
Pt1 C1 1.822(9) .
Pt1 Br2 2.4573(8) .
Pt1 Br1 2.5279(8) .
Pt1 Sn1 2.5454(6) .
Pt2 C2 1.853(8) .
Pt2 Br4 2.4453(9) .
Pt2 Br3 2.5011(8) .
Pt2 Sn1 2.5408(6) .
Sn1 Br6 2.5425(10) .
Sn1 Br5 2.5536(9) .
C1 O1 1.149(10) .
C2 O2 1.089(9) .
P1 C101 1.786(7) .
P1 C119 1.792(7) .
P1 C107 1.796(7) .
P1 C113 1.797(7) .
C101 C102 1.392(10) .
C101 C106 1.394(10) .
C102 C103 1.372(11) .
C102 H102 0.9500 .
C103 C104 1.388(11) .
C103 H103 0.9500 .
C104 C105 1.379(11) .
C104 H104 0.9500 .
C105 C106 1.381(11) .
C105 H105 0.9500 .
C106 H106 0.9500 .
C107 C108 1.369(10) .
C107 C112 1.405(10) .
C108 C109 1.384(11) .
C108 H108 0.9500 .
C109 C110 1.383(12) .
C109 H109 0.9500 .
C110 C111 1.383(11) .
C110 H110 0.9500 .
C111 C112 1.382(11) .
C111 H111 0.9500 .
C112 H112 0.9500 .
C113 C118 1.396(10) .
C113 C114 1.410(10) .
C114 C115 1.388(11) .
C114 H114 0.9500 .
C115 C116 1.389(11) .
C115 H115 0.9500 .
C116 C117 1.386(11) .
C116 H116 0.9500 .
C117 C118 1.383(11) .
C117 H117 0.9500 .
C118 H118 0.9500 .
C119 C120 1.388(11) .
C119 C124 1.405(10) .
C120 C121 1.395(12) .
C120 H120 0.9500 .
C121 C122 1.379(13) .
C121 H121 0.9500 .
C122 C123 1.363(13) .
C122 H122 0.9500 .
C123 C124 1.380(12) .
C123 H123 0.9500 .
C124 H124 0.9500 .
P2 C207 1.788(7) .
P2 C219 1.789(7) .
P2 C201 1.789(8) .
P2 C213 1.797(7) .
C201 C202 1.389(11) .
C201 C206 1.392(11) .
C202 C203 1.376(12) .
C202 H202 0.9500 .
C203 C204 1.371(15) .
C203 H203 0.9500 .
C204 C205 1.391(14) .
C204 H204 0.9500 .
C205 C206 1.392(11) .
C205 H205 0.9500 .
C206 H206 0.9500 .
C207 C212 1.385(10) .
C207 C208 1.391(10) .
C208 C209 1.394(11) .
C208 H208 0.9500 .
C209 C210 1.385(11) .
C209 H209 0.9500 .
C210 C211 1.368(11) .
C210 H210 0.9500 .
C211 C212 1.380(10) .
C211 H211 0.9500 .
C212 H212 0.9500 .
C213 C214 1.370(11) .
C213 C218 1.408(10) .
C214 C215 1.390(12) .
C214 H214 0.9500 .
C215 C216 1.386(12) .
C215 H215 0.9500 .
C216 C217 1.369(12) .
C216 H216 0.9500 .
C217 C218 1.370(11) .
C217 H217 0.9500 .
C218 H218 0.9500 .
C219 C224 1.388(10) .
C219 C220 1.391(11) .
C220 C221 1.370(11) .
C220 H220 0.9500 .
C221 C222 1.387(11) .
C221 H221 0.9500 .
C222 C223 1.370(11) .
C222 H222 0.9500 .
C223 C224 1.386(11) .
C223 H223 0.9500 .
C224 H224 0.9500 .
