#------------------------------------------------------------------------------
#$Date: 2021-12-14 12:05:23 +0200 (Tue, 14 Dec 2021) $
#$Revision: 271403 $
#$URL: file:///home/coder/svn-repositories/cod/cif/1/56/57/1565750.cif $
#------------------------------------------------------------------------------
#
# This file is available in the Crystallography Open Database (COD),
# http://www.crystallography.net/
#
# All data on this site have been placed in the public domain by the
# contributors.
#
data_1565750
loop_
_publ_author_name
'Yakubu, Abdallah'
'Suzuki, Takayoshi'
'Kita, Masakazu'
_publ_section_title
;
 Dinuclear lanthanoid(III) dithiocarbamato complexes bridged by
 (E)-N-benzylidenepicolinohydrazonate: Syntheses, crystal structures and
 spectroscopic properties
;
_journal_name_full               'Inorganica Chimica Acta'
_journal_page_first              119124
_journal_paper_doi               10.1016/j.ica.2019.119124
_journal_volume                  498
_journal_year                    2019
_chemical_formula_moiety         'C49 H55 Cl9 Eu2 N10 O2 S8'
_chemical_formula_sum            'C49 H55 Cl9 Eu2 N10 O2 S8'
_chemical_formula_weight         1695.48
_space_group_crystal_system      monoclinic
_space_group_IT_number           9
_space_group_name_Hall           'C -2yc'
_space_group_name_H-M_alt        'C 1 c 1'
_atom_sites_solution_hydrogens   geom
_atom_sites_solution_primary     direct
_atom_sites_solution_secondary   difmap
_audit_creation_method           SHELXL-2014/7
_cell_angle_alpha                90
_cell_angle_beta                 122.602(3)
_cell_angle_gamma                90
_cell_formula_units_Z            4
_cell_length_a                   35.816(3)
_cell_length_b                   9.9959(6)
_cell_length_c                   21.716(2)
_cell_measurement_reflns_used    9317
_cell_measurement_temperature    273(2)
_cell_measurement_theta_max      27.49
_cell_measurement_theta_min      3.17
_cell_volume                     6549.6(9)
_computing_cell_refinement       'CrystalClear-SM Expert 2.0 r16'
_computing_data_collection
'CrystalClear-SM Expert 2.0 r16 (Rigaku, 2014)'
_computing_data_reduction        'CrystalClear-SM Expert 2.0 r16'
_computing_molecular_graphics    'CrystalStructure 4.2.1'
_computing_publication_material  'CrystalStructure 4.2.1 (Rigaku, 2016)'
_computing_structure_refinement  'SHELXL-2014/7 (Sheldrick, 2014)'
_computing_structure_solution    'Il Milione (Burla, et al., 2007)'
_diffrn_ambient_temperature      273(2)
_diffrn_detector_area_resol_mean 29.257
_diffrn_measured_fraction_theta_full 0.995
_diffrn_measured_fraction_theta_max 0.991
_diffrn_measurement_device_type  'Rigaku Saturn70'
_diffrn_measurement_method       ω
_diffrn_radiation_type           MoK\a
_diffrn_radiation_wavelength     0.71075
_diffrn_reflns_av_R_equivalents  0.0454
_diffrn_reflns_av_unetI/netI     0.0637
_diffrn_reflns_Laue_measured_fraction_full 0.995
_diffrn_reflns_Laue_measured_fraction_max 0.991
_diffrn_reflns_limit_h_max       45
_diffrn_reflns_limit_h_min       -46
_diffrn_reflns_limit_k_max       12
_diffrn_reflns_limit_k_min       -12
_diffrn_reflns_limit_l_max       28
_diffrn_reflns_limit_l_min       -27
_diffrn_reflns_number            31899
_diffrn_reflns_point_group_measured_fraction_full 0.941
_diffrn_reflns_point_group_measured_fraction_max 0.925
_diffrn_reflns_theta_full        25.242
_diffrn_reflns_theta_max         27.482
_diffrn_reflns_theta_min         3.166
_exptl_absorpt_coefficient_mu    2.566
_exptl_absorpt_correction_T_max  1.000
_exptl_absorpt_correction_T_min  1.000
_exptl_absorpt_correction_type   numerical
_exptl_absorpt_process_details   'NUMABS (Rigaku, 1999)'
_exptl_crystal_colour            orange
_exptl_crystal_density_diffrn    1.719
_exptl_crystal_density_method    'not measured'
_exptl_crystal_description       prism
_exptl_crystal_F_000             3368
_exptl_crystal_size_max          0.080
_exptl_crystal_size_mid          0.070
_exptl_crystal_size_min          0.050
_refine_diff_density_max         2.728
_refine_diff_density_min         -1.898
_refine_diff_density_rms         0.162
_refine_ls_abs_structure_details
;
 Flack x determined using 4797 quotients [(I+)-(I-)]/[(I+)+(I-)]
 (Parsons, Flack and Wagner, Acta Cryst. B69 (2013) 249-259).
;
_refine_ls_abs_structure_Flack   0.263(7)
_refine_ls_extinction_coef       .
_refine_ls_extinction_method     none
_refine_ls_goodness_of_fit_ref   1.047
_refine_ls_hydrogen_treatment    constr
_refine_ls_matrix_type           full
_refine_ls_number_parameters     721
_refine_ls_number_reflns         13852
_refine_ls_number_restraints     2
_refine_ls_restrained_S_all      1.047
_refine_ls_R_factor_all          0.0607
_refine_ls_R_factor_gt           0.0578
_refine_ls_shift/su_max          0.001
_refine_ls_shift/su_mean         0.000
_refine_ls_structure_factor_coef Fsqd
_refine_ls_weighting_details
'w=1/[σ²(Fo²)+(0.0910P)²+17.1745P] where P=(Fo²+2Fc²)/3'
_refine_ls_weighting_scheme      calc
_refine_ls_wR_factor_gt          0.1480
_refine_ls_wR_factor_ref         0.1512
_reflns_Friedel_coverage         0.866
_reflns_Friedel_fraction_full    0.886
_reflns_Friedel_fraction_max     0.859
_reflns_number_gt                12968
_reflns_number_total             13852
_reflns_threshold_expression     'I > 2σ(I)'
_cod_data_source_file            5b_Eu_pyrdtc_bphz.cif
_cod_data_source_block           '[Eu2(pyrdtc)4(Lbph)]'
_cod_original_cell_volume        6549.6(10)
_cod_original_sg_symbol_H-M      'C c'
_cod_database_code               1565750
_shelx_shelxl_version_number     2014/7
_shelx_space_group_comment
;
The symmetry employed for this shelxl refinement is uniquely defined
by the following loop, which should always be used as a source of
symmetry information in preference to the above space-group names.
They are only intended as comments.
;
_shelx_estimated_absorpt_t_min   0.821
_shelx_estimated_absorpt_t_max   0.882
loop_
_space_group_symop_operation_xyz
'x, y, z'
'x, -y, z+1/2'
'x+1/2, y+1/2, z'
'x+1/2, -y+1/2, z+1/2'
loop_
_atom_site_label
_atom_site_type_symbol
_atom_site_fract_x
_atom_site_fract_y
_atom_site_fract_z
_atom_site_U_iso_or_equiv
_atom_site_adp_type
_atom_site_occupancy
_atom_site_site_symmetry_order
_atom_site_calc_flag
_atom_site_refinement_flags_posn
_atom_site_refinement_flags_adp
_atom_site_refinement_flags_occupancy
_atom_site_disorder_assembly
_atom_site_disorder_group
Eu1 Eu 0.45161(2) 0.95259(6) 0.72167(2) 0.02700(15) Uani 1 1 d . . . . .
Eu2 Eu 0.32939(2) 1.10655(6) 0.61514(2) 0.02689(14) Uani 1 1 d . . . . .
Cl1 Cl 0.5753(2) 1.4649(8) 0.7244(3) 0.097(2) Uani 1 1 d . . . . .
Cl2 Cl 0.6465(2) 1.2882(6) 0.8246(3) 0.0777(14) Uani 1 1 d . . . . .
Cl3 Cl 0.5988(3) 1.2352(9) 0.6699(4) 0.114(2) Uani 1 1 d . . . . .
Cl4 Cl 0.19697(14) 0.4956(4) 0.6001(2) 0.0543(9) Uani 1 1 d . . . . .
Cl5 Cl 0.11956(16) 0.6657(5) 0.5163(3) 0.0770(14) Uani 1 1 d . . . . .
Cl6 Cl 0.2090(3) 0.7776(5) 0.6255(3) 0.144(4) Uani 1 1 d . . . . .
Cl7 Cl 0.3785(6) 1.2843(12) 0.8487(6) 0.207(7) Uani 1 1 d . . . . .
Cl8 Cl 0.3434(3) 1.1884(10) 0.9258(4) 0.122(3) Uani 1 1 d . . . . .
Cl9 Cl 0.4369(3) 1.2411(9) 1.0012(6) 0.134(3) Uani 1 1 d . . . . .
S1 S 0.53124(10) 0.8956(4) 0.72706(17) 0.0366(7) Uani 1 1 d . . . . .
S2 S 0.46311(12) 1.0733(4) 0.6113(2) 0.0441(8) Uani 1 1 d . . . . .
S3 S 0.42894(11) 0.9159(4) 0.82882(17) 0.0346(7) Uani 1 1 d . . . . .
S4 S 0.51146(10) 0.8009(3) 0.85021(16) 0.0305(6) Uani 1 1 d . . . . .
S5 S 0.35042(11) 1.1542(4) 0.50647(18) 0.0405(8) Uani 1 1 d . . . . .
S6 S 0.26514(10) 1.2457(3) 0.48488(16) 0.0317(6) Uani 1 1 d . . . . .
S7 S 0.25402(10) 1.1656(4) 0.62280(19) 0.0376(7) Uani 1 1 d . . . . .
S8 S 0.32098(11) 0.9682(3) 0.72560(19) 0.0340(7) Uani 1 1 d . . . . .
O1 O 0.3749(3) 0.9165(9) 0.6336(5) 0.0281(17) Uani 1 1 d . . . . .
O2 O 0.4066(3) 1.1446(9) 0.7011(4) 0.0290(17) Uani 1 1 d . . . . .
N1 N 0.5274(4) 0.9486(12) 0.6058(6) 0.039(3) Uani 1 1 d . . . . .
N2 N 0.4309(3) 0.7206(11) 0.6605(5) 0.032(2) Uani 1 1 d . . . . .
N3 N 0.3149(3) 0.7865(11) 0.5470(5) 0.031(2) Uani 1 1 d . . . . .
N4 N 0.2903(3) 0.9041(11) 0.5403(5) 0.030(2) Uani 1 1 d . . . . .
N5 N 0.2956(5) 1.3241(13) 0.4040(7) 0.047(3) Uani 1 1 d . . . . .
N6 N 0.2526(4) 1.0490(11) 0.7307(6) 0.034(2) Uani 1 1 d . . . . .
N7 N 0.3504(3) 1.3437(11) 0.6700(5) 0.030(2) Uani 1 1 d . . . . .
N8 N 0.4666(3) 1.2752(10) 0.7855(5) 0.029(2) Uani 1 1 d . . . . .
N9 N 0.4900(3) 1.1611(12) 0.7947(6) 0.033(2) Uani 1 1 d . . . . .
N10 N 0.4753(4) 0.7192(13) 0.9225(6) 0.039(2) Uani 1 1 d . . . . .
C1 C 0.5652(5) 0.8584(16) 0.6296(8) 0.042(3) Uani 1 1 d . . . . .
H1A H 0.5570 0.7664 0.6310 0.050 Uiso 1 1 calc R U . . .
H1B H 0.5900 0.8832 0.6777 0.050 Uiso 1 1 calc R U . . .
C2 C 0.5766(7) 0.876(2) 0.5732(10) 0.068(6) Uani 1 1 d . . . . .
H2A H 0.5889 0.7943 0.5670 0.082 Uiso 1 1 calc R U . . .
H2B H 0.5979 0.9478 0.5866 0.082 Uiso 1 1 calc R U . . .
C3 C 0.5308(8) 0.912(3) 0.5007(11) 0.085(8) Uani 1 1 d . . . . .
H3A H 0.5350 0.9589 0.4658 0.102 Uiso 1 1 calc R U . . .
H3B H 0.5128 0.8328 0.4778 0.102 Uiso 1 1 calc R U . . .
C4 C 0.5109(6) 1.0021(18) 0.5321(8) 0.051(4) Uani 1 1 d . . . . .
H4A H 0.5204 1.0939 0.5349 0.061 Uiso 1 1 calc R U . . .
H4B H 0.4788 0.9990 0.5022 0.061 Uiso 1 1 calc R U . . .
C5 C 0.5087(4) 0.9722(13) 0.6433(7) 0.032(3) Uani 1 1 d . . . . .
C6 C 0.4597(4) 0.6206(13) 0.6763(7) 0.033(3) Uani 1 1 d . . . . .
H6 H 0.4892 0.6364 0.7123 0.040 Uiso 1 1 calc R U . . .
C7 C 0.4491(4) 0.4978(14) 0.6439(7) 0.034(3) Uani 1 1 d . . . . .
H7 H 0.4707 0.4327 0.6570 0.041 Uiso 1 1 calc R U . . .
C8 C 0.4041(5) 0.4730(14) 0.5895(7) 0.035(3) Uani 1 1 d . . . . .
H8 H 0.3951 0.3902 0.5664 0.042 Uiso 1 1 calc R U . . .
C9 C 0.3733(4) 0.5758(14) 0.5712(7) 0.032(3) Uani 1 1 d . . . . .
H9 H 0.3436 0.5637 0.5349 0.038 Uiso 1 1 calc R U . . .
C10 C 0.3878(4) 0.6940(14) 0.6078(6) 0.031(3) Uani 1 1 d . . . . .
C11 C 0.3571(4) 0.8079(12) 0.5958(6) 0.028(2) Uani 1 1 d . . . . .
C12 C 0.2479(4) 0.8934(13) 0.4968(7) 0.033(3) Uani 1 1 d . . . . .
H12 H 0.2332 0.9736 0.4913 0.039 Uiso 1 1 calc R U . . .
C13 C 0.2176(4) 0.7850(13) 0.4542(7) 0.031(3) Uani 1 1 d . . . . .
C14 C 0.2269(4) 0.6463(14) 0.4660(7) 0.034(3) Uani 1 1 d . . . . .
H14 H 0.2553 0.6170 0.5013 0.041 Uiso 1 1 calc R U . . .
C15 C 0.1943(5) 0.5562(15) 0.4252(9) 0.044(3) Uani 1 1 d . . . . .
H15 H 0.2014 0.4658 0.4334 0.053 Uiso 1 1 calc R U . . .
C16 C 0.1514(5) 0.5900(15) 0.3727(10) 0.047(4) Uani 1 1 d . . . . .
H16 H 0.1299 0.5252 0.3467 0.056 Uiso 1 1 calc R U . . .
C17 C 0.1414(4) 0.7300(16) 0.3595(9) 0.047(4) Uani 1 1 d . . . . .
H17 H 0.1130 0.7576 0.3236 0.057 Uiso 1 1 calc R U . . .
C18 C 0.1737(4) 0.8231(16) 0.3999(8) 0.040(3) Uani 1 1 d . . . . .
H18 H 0.1666 0.9136 0.3915 0.048 Uiso 1 1 calc R U . . .
C19 C 0.3273(6) 1.3394(17) 0.3821(9) 0.051(4) Uani 1 1 d . . . . .
H19A H 0.3368 1.2534 0.3747 0.061 Uiso 1 1 calc R U . . .
H19B H 0.3530 1.3906 0.4177 0.061 Uiso 1 1 calc R U . . .
C20 C 0.2969(8) 1.422(2) 0.3039(11) 0.071(6) Uani 1 1 d . . . . .
H20A H 0.3152 1.4819 0.2956 0.085 Uiso 1 1 calc R U . . .
H20B H 0.2813 1.3615 0.2629 0.085 Uiso 1 1 calc R U . . .
C21 C 0.2686(10) 1.491(3) 0.3145(15) 0.102(9) Uani 1 1 d . . . . .
H21A H 0.2424 1.5151 0.2677 0.123 Uiso 1 1 calc R U . . .
H21B H 0.2826 1.5733 0.3409 0.123 Uiso 1 1 calc R U . . .
C22 C 0.2556(7) 1.4057(17) 0.3579(10) 0.063(5) Uani 1 1 d . . . . .
H22A H 0.2488 1.4607 0.3875 0.075 Uiso 1 1 calc R U . . .
H22B H 0.2301 1.3500 0.3258 0.075 Uiso 1 1 calc R U . . .
C23 C 0.3030(4) 1.2458(13) 0.4585(6) 0.031(3) Uani 1 1 d . . . . .
C24 C 0.2112(5) 1.1267(14) 0.7085(9) 0.044(3) Uani 1 1 d . . . . .
H24A H 0.1888 1.1138 0.6571 0.053 Uiso 1 1 calc R U . . .
H24B H 0.2174 1.2215 0.7179 0.053 Uiso 1 1 calc R U . . .
C25 C 0.1963(8) 1.067(3) 0.7567(14) 0.099(10) Uani 1 1 d . . . . .
H25A H 0.1811 1.1341 0.7678 0.119 Uiso 1 1 calc R U . . .
H25B H 0.1765 0.9924 0.7324 0.119 Uiso 1 1 calc R U . . .
C26 C 0.2372(7) 1.023(2) 0.8238(11) 0.072(6) Uani 1 1 d . . . . .
H26A H 0.2310 0.9535 0.8483 0.086 Uiso 1 1 calc R U . . .
H26B H 0.2519 1.0970 0.8572 0.086 Uiso 1 1 calc R U . . .
C27 C 0.2656(6) 0.9683(18) 0.7948(8) 0.051(4) Uani 1 1 d . . . . .
H27A H 0.2970 0.9787 0.8312 0.061 Uiso 1 1 calc R U . . .
H27B H 0.2594 0.8745 0.7819 0.061 Uiso 1 1 calc R U . . .
C28 C 0.2736(4) 1.0601(13) 0.6975(6) 0.031(2) Uani 1 1 d . . . . .
C29 C 0.3196(5) 1.4443(13) 0.6508(8) 0.035(3) Uani 1 1 d . . . . .
H29 H 0.2900 1.4288 0.6145 0.042 Uiso 1 1 calc R U . . .
C30 C 0.3321(5) 1.5690(15) 0.6852(7) 0.038(3) Uani 1 1 d . . . . .
H30 H 0.3109 1.6353 0.6726 0.046 Uiso 1 1 calc R U . . .
C31 C 0.3760(5) 1.5935(13) 0.7380(7) 0.034(3) Uani 1 1 d . . . . .
H31 H 0.3845 1.6767 0.7607 0.041 Uiso 1 1 calc R U . . .
C32 C 0.4077(4) 1.4937(13) 0.7574(7) 0.033(3) Uani 1 1 d . . . . .
H32 H 0.4374 1.5089 0.7926 0.040 Uiso 1 1 calc R U . . .
C33 C 0.3931(4) 1.3690(12) 0.7218(7) 0.030(2) Uani 1 1 d . . . . .
C34 C 0.4246(4) 1.2571(13) 0.7384(6) 0.030(3) Uani 1 1 d . . . . .
C35 C 0.5322(4) 1.1605(14) 0.8408(7) 0.032(3) Uani 1 1 d . . . . .
H35 H 0.5453 1.0771 0.8471 0.038 Uiso 1 1 calc R U . . .
C36 C 0.5634(4) 1.2663(12) 0.8851(6) 0.028(2) Uani 1 1 d . . . . .
C37 C 0.5548(5) 1.4042(14) 0.8743(8) 0.037(3) Uani 1 1 d . . . . .
H37 H 0.5269 1.4338 0.8375 0.045 Uiso 1 1 calc R U . . .
C38 C 0.5881(5) 1.4986(15) 0.9186(8) 0.043(3) Uani 1 1 d . . . . .
H38 H 0.5829 1.5901 0.9109 0.052 Uiso 1 1 calc R U . . .
C39 C 0.6294(5) 1.4491(15) 0.9748(8) 0.044(4) Uani 1 1 d . . . . .
H39 H 0.6515 1.5091 1.0055 0.052 Uiso 1 1 calc R U . . .
C40 C 0.6378(4) 1.3134(14) 0.9855(8) 0.039(3) Uani 1 1 d . . . . .
H40 H 0.6654 1.2832 1.0232 0.047 Uiso 1 1 calc R U . . .
C41 C 0.6057(4) 1.2235(13) 0.9408(7) 0.032(2) Uani 1 1 d . . . . .
H41 H 0.6120 1.1325 0.9475 0.038 Uiso 1 1 calc R U . . .
C42 C 0.4408(5) 0.7049(19) 0.9396(9) 0.053(4) Uani 1 1 d . . . . .
H42A H 0.4130 0.6747 0.8974 0.063 Uiso 1 1 calc R U . . .
H42B H 0.4362 0.7878 0.9577 0.063 Uiso 1 1 calc R U . . .
C43 C 0.4619(12) 0.598(3) 0.9991(19) 0.119(12) Uani 1 1 d . . . . .
H43A H 0.4768 0.6400 1.0468 0.143 Uiso 1 1 calc R U . . .
H43B H 0.4391 0.5393 0.9950 0.143 Uiso 1 1 calc R U . . .
C44 C 0.4930(8) 0.522(3) 0.9922(15) 0.108(10) Uani 1 1 d . . . . .
H44A H 0.4789 0.4450 0.9604 0.129 Uiso 1 1 calc R U . . .
H44B H 0.5171 0.4907 1.0395 0.129 Uiso 1 1 calc R U . . .
C45 C 0.5089(7) 0.6193(17) 0.9592(9) 0.059(5) Uani 1 1 d . . . . .
H45A H 0.5365 0.6600 0.9970 0.071 Uiso 1 1 calc R U . . .
H45B H 0.5140 0.5743 0.9247 0.071 Uiso 1 1 calc R U . . .
C46 C 0.4716(4) 0.8049(13) 0.8709(6) 0.032(3) Uani 1 1 d . . . . .
C47 C 0.5849(12) 1.273(4) 0.7322(14) 0.144(16) Uani 1 1 d . . . . .
H47 H 0.5631 1.2165 0.7336 0.172 Uiso 1 1 calc R U . . .
C48 C 0.1770(5) 0.6590(17) 0.5660(10) 0.056(4) Uani 1 1 d . . . . .
H48 H 0.1835 0.6681 0.5278 0.067 Uiso 1 1 calc R U . . .
C49 C 0.3897(9) 1.169(3) 0.920(2) 0.125(12) Uani 1 1 d . . . . .
H49 H 0.3945 1.0772 0.9106 0.150 Uiso 1 1 calc R U . . .
loop_
_atom_type_symbol
_atom_type_description
_atom_type_scat_dispersion_real
_atom_type_scat_dispersion_imag
_atom_type_scat_source
C C 0.0033 0.0016 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
N N 0.0061 0.0033 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
Cl Cl 0.1484 0.1585 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
O O 0.0106 0.0060 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
Eu Eu -0.1578 3.6682 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
S S 0.1246 0.1234 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
H H 0.0000 0.0000 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
loop_
_geom_angle_atom_site_label_1
_geom_angle_atom_site_label_2
_geom_angle_atom_site_label_3
_geom_angle
_geom_angle_site_symmetry_1
_geom_angle_site_symmetry_3
O1 Eu1 O2 66.5(3) . .
O1 Eu1 N9 129.1(3) . .
O2 Eu1 N9 62.6(3) . .
O1 Eu1 N2 64.0(3) . .
O2 Eu1 N2 130.5(3) . .
N9 Eu1 N2 166.8(3) . .
O1 Eu1 S1 134.3(2) . .
O2 Eu1 S1 136.7(2) . .
N9 Eu1 S1 86.8(2) . .
N2 Eu1 S1 81.1(2) . .
O1 Eu1 S4 129.4(2) . .
O2 Eu1 S4 133.0(2) . .
N9 Eu1 S4 87.5(2) . .
N2 Eu1 S4 83.3(2) . .
S1 Eu1 S4 69.37(9) . .
O1 Eu1 S3 85.6(2) . .
O2 Eu1 S3 78.3(2) . .
N9 Eu1 S3 83.9(3) . .
N2 Eu1 S3 100.0(2) . .
S1 Eu1 S3 130.94(9) . .
S4 Eu1 S3 62.19(9) . .
O1 Eu1 S2 90.9(2) . .
O2 Eu1 S2 83.9(2) . .
N9 Eu1 S2 84.5(3) . .
N2 Eu1 S2 94.5(3) . .
S1 Eu1 S2 62.16(9) . .
S4 Eu1 S2 131.18(9) . .
S3 Eu1 S2 161.74(11) . .
O1 Eu1 C46 105.6(3) . .
O2 Eu1 C46 108.3(3) . .
N9 Eu1 C46 89.8(3) . .
N2 Eu1 C46 87.3(3) . .
S1 Eu1 C46 100.9(2) . .
S4 Eu1 C46 31.5(2) . .
S3 Eu1 C46 31.3(2) . .
S2 Eu1 C46 162.3(2) . .
O1 Eu1 Eu2 33.2(2) . .
O2 Eu1 Eu2 33.27(19) . .
N9 Eu1 Eu2 95.9(2) . .
N2 Eu1 Eu2 97.3(2) . .
S1 Eu1 Eu2 149.44(7) . .
S4 Eu1 Eu2 141.04(6) . .
S3 Eu1 Eu2 79.54(7) . .
S2 Eu1 Eu2 87.73(7) . .
C46 Eu1 Eu2 109.5(2) . .
O2 Eu2 O1 66.3(3) . .
O2 Eu2 N4 130.1(3) . .
O1 Eu2 N4 63.8(3) . .
O2 Eu2 N7 64.3(3) . .
O1 Eu2 N7 130.5(3) . .
N4 Eu2 N7 165.3(3) . .
O2 Eu2 S7 130.9(2) . .
O1 Eu2 S7 137.3(2) . .
N4 Eu2 S7 89.4(3) . .
N7 Eu2 S7 80.4(2) . .
O2 Eu2 S6 132.0(2) . .
O1 Eu2 S6 131.5(2) . .
N4 Eu2 S6 83.2(2) . .
N7 Eu2 S6 83.6(2) . .
S7 Eu2 S6 71.07(9) . .
O2 Eu2 S5 84.8(2) . .
O1 Eu2 S5 79.2(2) . .
N4 Eu2 S5 84.5(3) . .
N7 Eu2 S5 94.9(2) . .
S7 Eu2 S5 133.41(9) . .
S6 Eu2 S5 62.36(9) . .
O2 Eu2 S8 91.3(2) . .
O1 Eu2 S8 81.3(2) . .
N4 Eu2 S8 83.2(3) . .
N7 Eu2 S8 100.9(2) . .
S7 Eu2 S8 62.02(9) . .
S6 Eu2 S8 131.06(9) . .
S5 Eu2 S8 160.08(10) . .
O2 Eu2 C11 86.6(3) . .
O1 Eu2 C11 20.4(3) . .
N4 Eu2 C11 43.4(3) . .
N7 Eu2 C11 150.8(3) . .
S7 Eu2 C11 124.2(2) . .
S6 Eu2 C11 117.3(2) . .
S5 Eu2 C11 79.2(2) . .
S8 Eu2 C11 81.0(2) . .
O2 Eu2 Eu1 33.2(2) . .
O1 Eu2 Eu1 33.1(2) . .
N4 Eu2 Eu1 96.9(2) . .
N7 Eu2 Eu1 97.5(2) . .
S7 Eu2 Eu1 145.22(7) . .
S6 Eu2 Eu1 143.58(6) . .
S5 Eu2 Eu1 81.34(7) . .
S8 Eu2 Eu1 84.71(7) . .
C11 Eu2 Eu1 53.5(2) . .
C5 S1 Eu1 88.8(4) . .
C5 S2 Eu1 87.1(5) . .
C46 S3 Eu1 87.4(4) . .
C46 S4 Eu1 87.2(4) . .
C23 S5 Eu2 88.6(4) . .
C23 S6 Eu2 88.3(4) . .
C28 S7 Eu2 90.6(4) . .
C28 S8 Eu2 88.5(4) . .
C11 O1 Eu1 126.5(7) . .
C11 O1 Eu2 119.8(7) . .
Eu1 O1 Eu2 113.7(3) . .
C34 O2 Eu1 120.6(7) . .
C34 O2 Eu2 125.8(8) . .
Eu1 O2 Eu2 113.5(3) . .
C5 N1 C1 124.6(11) . .
C5 N1 C4 124.1(12) . .
C1 N1 C4 111.1(11) . .
C6 N2 C10 115.8(11) . .
C6 N2 Eu1 124.8(8) . .
C10 N2 Eu1 119.4(8) . .
C11 N3 N4 108.9(10) . .
C12 N4 N3 115.1(10) . .
C12 N4 Eu2 124.7(9) . .
N3 N4 Eu2 120.1(7) . .
C23 N5 C19 122.6(14) . .
C23 N5 C22 126.0(13) . .
C19 N5 C22 111.4(13) . .
C28 N6 C27 126.6(11) . .
C28 N6 C24 122.9(11) . .
C27 N6 C24 110.4(11) . .
C33 N7 C29 118.6(11) . .
C33 N7 Eu2 118.4(8) . .
C29 N7 Eu2 122.9(8) . .
C34 N8 N9 111.1(10) . .
C35 N9 N8 119.2(11) . .
C35 N9 Eu1 119.9(9) . .
N8 N9 Eu1 120.9(7) . .
C46 N10 C45 125.3(12) . .
C46 N10 C42 123.1(13) . .
C45 N10 C42 111.1(12) . .
N1 C1 C2 104.2(11) . .
N1 C1 H1A 110.9 . .
C2 C1 H1A 110.9 . .
N1 C1 H1B 110.9 . .
C2 C1 H1B 110.9 . .
H1A C1 H1B 108.9 . .
C1 C2 C3 104.2(14) . .
C1 C2 H2A 110.9 . .
C3 C2 H2A 110.9 . .
C1 C2 H2B 110.9 . .
C3 C2 H2B 110.9 . .
H2A C2 H2B 108.9 . .
C4 C3 C2 100.0(16) . .
C4 C3 H3A 111.8 . .
C2 C3 H3A 111.8 . .
C4 C3 H3B 111.8 . .
C2 C3 H3B 111.8 . .
H3A C3 H3B 109.5 . .
N1 C4 C3 105.1(13) . .
N1 C4 H4A 110.7 . .
C3 C4 H4A 110.7 . .
N1 C4 H4B 110.7 . .
C3 C4 H4B 110.7 . .
H4A C4 H4B 108.8 . .
N1 C5 S2 122.9(10) . .
N1 C5 S1 117.7(9) . .
S2 C5 S1 119.4(8) . .
N2 C6 C7 125.3(12) . .
N2 C6 H6 117.3 . .
C7 C6 H6 117.3 . .
C6 C7 C8 117.5(12) . .
C6 C7 H7 121.3 . .
C8 C7 H7 121.3 . .
C9 C8 C7 118.5(12) . .
C9 C8 H8 120.8 . .
C7 C8 H8 120.8 . .
C10 C9 C8 118.5(12) . .
C10 C9 H9 120.7 . .
C8 C9 H9 120.7 . .
C9 C10 N2 124.3(12) . .
C9 C10 C11 122.8(11) . .
N2 C10 C11 112.9(11) . .
O1 C11 N3 127.3(11) . .
O1 C11 C10 117.1(10) . .
N3 C11 C10 115.5(11) . .
O1 C11 Eu2 39.8(5) . .
N3 C11 Eu2 87.5(7) . .
C10 C11 Eu2 156.9(8) . .
N4 C12 C13 135.0(12) . .
N4 C12 H12 112.5 . .
C13 C12 H12 112.5 . .
C14 C13 C18 117.5(12) . .
C14 C13 C12 126.1(11) . .
C18 C13 C12 116.2(12) . .
C15 C14 C13 119.5(12) . .
C15 C14 H14 120.2 . .
C13 C14 H14 120.2 . .
C14 C15 C16 124.3(14) . .
C14 C15 H15 117.9 . .
C16 C15 H15 117.9 . .
C15 C16 C17 117.0(13) . .
C15 C16 H16 121.5 . .
C17 C16 H16 121.5 . .
C18 C17 C16 120.0(13) . .
C18 C17 H17 120.0 . .
C16 C17 H17 120.0 . .
C17 C18 C13 121.7(14) . .
C17 C18 H18 119.2 . .
C13 C18 H18 119.2 . .
N5 C19 C20 100.9(14) . .
N5 C19 H19A 111.6 . .
C20 C19 H19A 111.6 . .
N5 C19 H19B 111.6 . .
C20 C19 H19B 111.6 . .
H19A C19 H19B 109.4 . .
C21 C20 C19 102.7(16) . .
C21 C20 H20A 111.2 . .
C19 C20 H20A 111.2 . .
C21 C20 H20B 111.2 . .
C19 C20 H20B 111.2 . .
H20A C20 H20B 109.1 . .
C20 C21 C22 109.2(19) . .
C20 C21 H21A 109.8 . .
C22 C21 H21A 109.8 . .
C20 C21 H21B 109.8 . .
C22 C21 H21B 109.8 . .
H21A C21 H21B 108.3 . .
N5 C22 C21 102.8(17) . .
N5 C22 H22A 111.2 . .
C21 C22 H22A 111.2 . .
N5 C22 H22B 111.2 . .
C21 C22 H22B 111.2 . .
H22A C22 H22B 109.1 . .
N5 C23 S5 121.3(10) . .
N5 C23 S6 118.7(10) . .
S5 C23 S6 119.9(7) . .
N6 C24 C25 103.0(12) . .
N6 C24 H24A 111.2 . .
C25 C24 H24A 111.2 . .
N6 C24 H24B 111.2 . .
C25 C24 H24B 111.2 . .
H24A C24 H24B 109.1 . .
C26 C25 C24 105.6(17) . .
C26 C25 H25A 110.6 . .
C24 C25 H25A 110.6 . .
C26 C25 H25B 110.6 . .
C24 C25 H25B 110.6 . .
H25A C25 H25B 108.8 . .
C25 C26 C27 102.9(15) . .
C25 C26 H26A 111.2 . .
C27 C26 H26A 111.2 . .
C25 C26 H26B 111.2 . .
C27 C26 H26B 111.2 . .
H26A C26 H26B 109.1 . .
N6 C27 C26 104.4(12) . .
N6 C27 H27A 110.9 . .
C26 C27 H27A 110.9 . .
N6 C27 H27B 110.9 . .
C26 C27 H27B 110.9 . .
H27A C27 H27B 108.9 . .
N6 C28 S8 120.8(10) . .
N6 C28 S7 120.5(10) . .
S8 C28 S7 118.7(7) . .
N7 C29 C30 120.9(13) . .
N7 C29 H29 119.5 . .
C30 C29 H29 119.5 . .
C31 C30 C29 119.7(13) . .
C31 C30 H30 120.1 . .
C29 C30 H30 120.1 . .
C30 C31 C32 120.1(13) . .
C30 C31 H31 119.9 . .
C32 C31 H31 119.9 . .
C31 C32 C33 117.8(12) . .
C31 C32 H32 121.1 . .
C33 C32 H32 121.1 . .
N7 C33 C32 122.8(11) . .
N7 C33 C34 115.6(11) . .
C32 C33 C34 121.6(11) . .
N8 C34 O2 124.8(12) . .
N8 C34 C33 119.5(11) . .
O2 C34 C33 115.7(10) . .
N9 C35 C36 132.1(13) . .
N9 C35 H35 114.0 . .
C36 C35 H35 114.0 . .
C41 C36 C37 118.8(12) . .
C41 C36 C35 115.8(11) . .
C37 C36 C35 125.4(11) . .
C36 C37 C38 120.8(13) . .
C36 C37 H37 119.6 . .
C38 C37 H37 119.6 . .
C39 C38 C37 117.5(13) . .
C39 C38 H38 121.2 . .
C37 C38 H38 121.2 . .
C40 C39 C38 121.7(13) . .
C40 C39 H39 119.1 . .
C38 C39 H39 119.1 . .
C41 C40 C39 120.0(13) . .
C41 C40 H40 120.0 . .
C39 C40 H40 120.0 . .
C40 C41 C36 121.1(12) . .
C40 C41 H41 119.4 . .
C36 C41 H41 119.4 . .
N10 C42 C43 100.5(16) . .
N10 C42 H42A 111.7 . .
C43 C42 H42A 111.7 . .
N10 C42 H42B 111.7 . .
C43 C42 H42B 111.7 . .
H42A C42 H42B 109.4 . .
C44 C43 C42 110.1(17) . .
C44 C43 H43A 109.6 . .
C42 C43 H43A 109.6 . .
C44 C43 H43B 109.6 . .
C42 C43 H43B 109.6 . .
H43A C43 H43B 108.1 . .
C43 C44 C45 103(2) . .
C43 C44 H44A 111.2 . .
C45 C44 H44A 111.2 . .
C43 C44 H44B 111.2 . .
C45 C44 H44B 111.2 . .
H44A C44 H44B 109.1 . .
N10 C45 C44 107.4(17) . .
N10 C45 H45A 110.2 . .
C44 C45 H45A 110.2 . .
N10 C45 H45B 110.2 . .
C44 C45 H45B 110.2 . .
H45A C45 H45B 108.5 . .
N10 C46 S3 120.9(10) . .
N10 C46 S4 118.5(10) . .
S3 C46 S4 120.6(7) . .
N10 C46 Eu1 166.9(9) . .
S3 C46 Eu1 61.3(4) . .
S4 C46 Eu1 61.3(4) . .
Cl3 C47 Cl1 105.3(16) . .
Cl3 C47 Cl2 99.8(17) . .
Cl1 C47 Cl2 93.5(19) . .
Cl3 C47 H47 118.1 . .
Cl1 C47 H47 118.1 . .
Cl2 C47 H47 118.1 . .
Cl6 C48 Cl5 122.9(11) . .
Cl6 C48 Cl4 112.1(9) . .
Cl5 C48 Cl4 111.8(9) . .
Cl6 C48 H48 102.2 . .
Cl5 C48 H48 102.2 . .
Cl4 C48 H48 102.2 . .
Cl8 C49 Cl7 102.4(18) . .
Cl8 C49 Cl9 108.4(19) . .
Cl7 C49 Cl9 104.1(19) . .
Cl8 C49 H49 113.7 . .
Cl7 C49 H49 113.7 . .
Cl9 C49 H49 113.7 . .
loop_
_geom_bond_atom_site_label_1
_geom_bond_atom_site_label_2
_geom_bond_distance
_geom_bond_site_symmetry_2
Eu1 O1 2.381(8) .
Eu1 O2 2.388(9) .
Eu1 N9 2.530(11) .
Eu1 N2 2.575(11) .
Eu1 S1 2.848(3) .
Eu1 S4 2.870(3) .
Eu1 S3 2.871(3) .
Eu1 S2 2.903(4) .
Eu1 C46 3.269(12) .
Eu1 Eu2 3.9964(8) .
Eu2 O2 2.391(8) .
Eu2 O1 2.392(8) .
Eu2 N4 2.498(10) .
Eu2 N7 2.577(11) .
Eu2 S7 2.854(3) .
Eu2 S6 2.867(3) .
Eu2 S5 2.877(3) .
Eu2 S8 2.921(3) .
Eu2 C11 3.243(12) .
Cl1 C47 1.94(4) .
Cl2 C47 2.04(4) .
Cl3 C47 1.72(2) .
Cl4 C48 1.776(17) .
Cl5 C48 1.734(15) .
Cl6 C48 1.672(18) .
Cl7 C49 1.79(4) .
Cl8 C49 1.74(4) .
Cl9 C49 1.81(3) .
S1 C5 1.723(13) .
S2 C5 1.716(13) .
S3 C46 1.702(13) .
S4 C46 1.712(13) .
S5 C23 1.703(13) .
S6 C23 1.734(12) .
S7 C28 1.735(13) .
S8 C28 1.725(13) .
O1 C11 1.302(15) .
O2 C34 1.332(15) .
N1 C5 1.326(17) .
N1 C1 1.468(16) .
N1 C4 1.474(17) .
N2 C6 1.341(17) .
N2 C10 1.362(15) .
N3 C11 1.313(15) .
N3 N4 1.430(15) .
N4 C12 1.289(16) .
N5 C23 1.322(17) .
N5 C19 1.456(18) .
N5 C22 1.48(2) .
N6 C28 1.300(16) .
N6 C27 1.450(16) .
N6 C24 1.504(17) .
N7 C33 1.347(16) .
N7 C29 1.382(17) .
N8 C34 1.300(16) .
N8 N9 1.365(15) .
N9 C35 1.286(16) .
N10 C46 1.360(17) .
N10 C45 1.43(2) .
N10 C42 1.474(18) .
C1 C2 1.50(2) .
C1 H1A 0.9700 .
C1 H1B 0.9700 .
C2 C3 1.59(3) .
C2 H2A 0.9700 .
C2 H2B 0.9700 .
C3 C4 1.52(3) .
C3 H3A 0.9700 .
C3 H3B 0.9700 .
C4 H4A 0.9700 .
C4 H4B 0.9700 .
C6 C7 1.364(19) .
C6 H6 0.9300 .
C7 C8 1.418(19) .
C7 H7 0.9300 .
C8 C9 1.399(19) .
C8 H8 0.9300 .
C9 C10 1.360(19) .
C9 H9 0.9300 .
C10 C11 1.507(17) .
C12 C13 1.459(17) .
C12 H12 0.9300 .
C13 C14 1.418(19) .
C13 C18 1.418(17) .
C14 C15 1.359(19) .
C14 H14 0.9300 .
C15 C16 1.37(2) .
C15 H15 0.9300 .
C16 C17 1.43(2) .
C16 H16 0.9300 .
C17 C18 1.37(2) .
C17 H17 0.9300 .
C18 H18 0.9300 .
C19 C20 1.66(3) .
C19 H19A 0.9700 .
C19 H19B 0.9700 .
C20 C21 1.34(3) .
C20 H20A 0.9700 .
C20 H20B 0.9700 .
C21 C22 1.52(2) .
C21 H21A 0.9700 .
C21 H21B 0.9700 .
C22 H22A 0.9700 .
C22 H22B 0.9700 .
C24 C25 1.53(3) .
C24 H24A 0.9700 .
C24 H24B 0.9700 .
C25 C26 1.47(3) .
C25 H25A 0.9700 .
C25 H25B 0.9700 .
C26 C27 1.56(2) .
C26 H26A 0.9700 .
C26 H26B 0.9700 .
C27 H27A 0.9700 .
C27 H27B 0.9700 .
C29 C30 1.40(2) .
C29 H29 0.9300 .
C30 C31 1.38(2) .
C30 H30 0.9300 .
C31 C32 1.394(19) .
C31 H31 0.9300 .
C32 C33 1.410(18) .
C32 H32 0.9300 .
C33 C34 1.487(17) .
C35 C36 1.461(17) .
C35 H35 0.9300 .
C36 C41 1.402(17) .
C36 C37 1.404(18) .
C37 C38 1.42(2) .
C37 H37 0.9300 .
C38 C39 1.40(2) .
C38 H38 0.9300 .
C39 C40 1.38(2) .
C39 H39 0.9300 .
C40 C41 1.368(18) .
C40 H40 0.9300 .
C41 H41 0.9300 .
C42 C43 1.53(3) .
C42 H42A 0.9700 .
C42 H42B 0.9700 .
C43 C44 1.42(4) .
C43 H43A 0.9700 .
C43 H43B 0.9700 .
C44 C45 1.50(2) .
C44 H44A 0.9700 .
C44 H44B 0.9700 .
C45 H45A 0.9700 .
C45 H45B 0.9700 .
C47 H47 0.9800 .
C48 H48 0.9800 .
C49 H49 0.9800 .
loop_
_geom_torsion_atom_site_label_1
_geom_torsion_atom_site_label_2
_geom_torsion_atom_site_label_3
_geom_torsion_atom_site_label_4
_geom_torsion
_geom_torsion_site_symmetry_1
_geom_torsion_site_symmetry_2
_geom_torsion_site_symmetry_3
_geom_torsion_site_symmetry_4
C11 N3 N4 C12 -176.2(11) . . . .
C11 N3 N4 Eu2 0.7(13) . . . .
C34 N8 N9 C35 -178.5(11) . . . .
C34 N8 N9 Eu1 2.0(13) . . . .
C5 N1 C1 C2 -174.7(16) . . . .
C4 N1 C1 C2 9.5(19) . . . .
N1 C1 C2 C3 -30(2) . . . .
C1 C2 C3 C4 39(2) . . . .
C5 N1 C4 C3 -159.8(17) . . . .
C1 N1 C4 C3 16(2) . . . .
C2 C3 C4 N1 -33(2) . . . .
C1 N1 C5 S2 -177.2(12) . . . .
C4 N1 C5 S2 -2(2) . . . .
C1 N1 C5 S1 2(2) . . . .
C4 N1 C5 S1 177.3(12) . . . .
Eu1 S2 C5 N1 163.5(12) . . . .
Eu1 S2 C5 S1 -15.7(8) . . . .
Eu1 S1 C5 N1 -163.2(11) . . . .
Eu1 S1 C5 S2 16.0(8) . . . .
C10 N2 C6 C7 0(2) . . . .
Eu1 N2 C6 C7 -179.4(10) . . . .
N2 C6 C7 C8 -1(2) . . . .
C6 C7 C8 C9 1.2(19) . . . .
C7 C8 C9 C10 -1.6(19) . . . .
C8 C9 C10 N2 2(2) . . . .
C8 C9 C10 C11 -176.0(12) . . . .
C6 N2 C10 C9 -0.9(19) . . . .
Eu1 N2 C10 C9 179.0(10) . . . .
C6 N2 C10 C11 176.9(11) . . . .
Eu1 N2 C10 C11 -3.3(14) . . . .
Eu1 O1 C11 N3 -179.8(9) . . . .
Eu2 O1 C11 N3 -1.2(17) . . . .
Eu1 O1 C11 C10 -1.1(15) . . . .
Eu2 O1 C11 C10 177.5(8) . . . .
Eu1 O1 C11 Eu2 -178.6(12) . . . .
N4 N3 C11 O1 0.3(17) . . . .
N4 N3 C11 C10 -178.4(10) . . . .
N4 N3 C11 Eu2 -0.5(8) . . . .
C9 C10 C11 O1 -179.4(12) . . . .
N2 C10 C11 O1 2.9(16) . . . .
C9 C10 C11 N3 -0.5(18) . . . .
N2 C10 C11 N3 -178.3(11) . . . .
C9 C10 C11 Eu2 -175.3(15) . . . .
N2 C10 C11 Eu2 7(3) . . . .
N3 N4 C12 C13 4(2) . . . .
Eu2 N4 C12 C13 -172.5(11) . . . .
N4 C12 C13 C14 19(2) . . . .
N4 C12 C13 C18 -165.8(15) . . . .
C18 C13 C14 C15 1(2) . . . .
C12 C13 C14 C15 175.1(13) . . . .
C13 C14 C15 C16 -1(2) . . . .
C14 C15 C16 C17 2(3) . . . .
C15 C16 C17 C18 -2(2) . . . .
C16 C17 C18 C13 1(2) . . . .
C14 C13 C18 C17 -1(2) . . . .
C12 C13 C18 C17 -175.8(14) . . . .
C23 N5 C19 C20 169.7(14) . . . .
C22 N5 C19 C20 -10.3(17) . . . .
N5 C19 C20 C21 29(2) . . . .
C19 C20 C21 C22 -37(3) . . . .
C23 N5 C22 C21 170.5(18) . . . .
C19 N5 C22 C21 -10(2) . . . .
C20 C21 C22 N5 31(3) . . . .
C19 N5 C23 S5 -1.2(19) . . . .
C22 N5 C23 S5 178.8(13) . . . .
C19 N5 C23 S6 174.7(11) . . . .
C22 N5 C23 S6 -5(2) . . . .
Eu2 S5 C23 N5 166.6(11) . . . .
Eu2 S5 C23 S6 -9.2(7) . . . .
Eu2 S6 C23 N5 -166.6(10) . . . .
Eu2 S6 C23 S5 9.3(7) . . . .
C28 N6 C24 C25 173.3(18) . . . .
C27 N6 C24 C25 -9(2) . . . .
N6 C24 C25 C26 29(2) . . . .
C24 C25 C26 C27 -37(3) . . . .
C28 N6 C27 C26 164.2(16) . . . .
C24 N6 C27 C26 -13.0(19) . . . .
C25 C26 C27 N6 31(2) . . . .
C27 N6 C28 S8 3(2) . . . .
C24 N6 C28 S8 -180.0(10) . . . .
C27 N6 C28 S7 -178.1(12) . . . .
C24 N6 C28 S7 -1.2(18) . . . .
Eu2 S8 C28 N6 -176.6(11) . . . .
Eu2 S8 C28 S7 4.6(7) . . . .
Eu2 S7 C28 N6 176.5(11) . . . .
Eu2 S7 C28 S8 -4.7(8) . . . .
C33 N7 C29 C30 -1.2(19) . . . .
Eu2 N7 C29 C30 176.0(9) . . . .
N7 C29 C30 C31 1(2) . . . .
C29 C30 C31 C32 -1(2) . . . .
C30 C31 C32 C33 0(2) . . . .
C29 N7 C33 C32 0.1(18) . . . .
Eu2 N7 C33 C32 -177.3(10) . . . .
C29 N7 C33 C34 -178.7(11) . . . .
Eu2 N7 C33 C34 4.0(13) . . . .
C31 C32 C33 N7 0.7(19) . . . .
C31 C32 C33 C34 179.4(11) . . . .
N9 N8 C34 O2 -3.1(16) . . . .
N9 N8 C34 C33 178.6(10) . . . .
Eu1 O2 C34 N8 2.8(16) . . . .
Eu2 O2 C34 N8 179.2(9) . . . .
Eu1 O2 C34 C33 -178.9(7) . . . .
Eu2 O2 C34 C33 -2.5(14) . . . .
N7 C33 C34 N8 177.1(11) . . . .
C32 C33 C34 N8 -1.6(18) . . . .
N7 C33 C34 O2 -1.3(15) . . . .
C32 C33 C34 O2 179.9(11) . . . .
N8 N9 C35 C36 -6(2) . . . .
Eu1 N9 C35 C36 174.0(11) . . . .
N9 C35 C36 C41 167.0(13) . . . .
N9 C35 C36 C37 -16(2) . . . .
C41 C36 C37 C38 0(2) . . . .
C35 C36 C37 C38 -177.3(13) . . . .
C36 C37 C38 C39 -2(2) . . . .
C37 C38 C39 C40 2(2) . . . .
C38 C39 C40 C41 0(2) . . . .
C39 C40 C41 C36 -2(2) . . . .
C37 C36 C41 C40 2.0(19) . . . .
C35 C36 C41 C40 179.5(13) . . . .
C46 N10 C42 C43 179.5(18) . . . .
C45 N10 C42 C43 8(2) . . . .
N10 C42 C43 C44 -24(3) . . . .
C42 C43 C44 C45 29(4) . . . .
C46 N10 C45 C44 -162.2(19) . . . .
C42 N10 C45 C44 9(2) . . . .
C43 C44 C45 N10 -23(3) . . . .
C45 N10 C46 S3 177.7(12) . . . .
C42 N10 C46 S3 7.3(18) . . . .
C45 N10 C46 S4 -3.5(19) . . . .
C42 N10 C46 S4 -173.9(11) . . . .
C45 N10 C46 Eu1 82(4) . . . .
C42 N10 C46 Eu1 -89(4) . . . .
Eu1 S3 C46 N10 -165.1(10) . . . .
Eu1 S3 C46 S4 16.2(7) . . . .
Eu1 S4 C46 N10 165.0(10) . . . .
Eu1 S4 C46 S3 -16.2(7) . . . .
