#------------------------------------------------------------------------------
#$Date: 2025-07-05 13:10:14 +0300 (Sat, 05 Jul 2025) $
#$Revision: 300370 $
#$URL: file:///home/coder/svn-repositories/cod/cif/1/56/58/1565893.cif $
#------------------------------------------------------------------------------
#
# This file is available in the Crystallography Open Database (COD),
# http://www.crystallography.net/. The original data for this entry
# were provided by IUCr Journals, http://journals.iucr.org/.
#
# The file may be used within the scientific community so long as
# proper attribution is given to the journal article from which the
# data were obtained.
#
data_1565893
loop_
_publ_author_name
'Davis, Wade L.'
'Muller, Alfred'
_publ_section_title
;
 Dichlorido(η6-p-cymene)[tris(4-methoxyphenyl)phosphane]ruthenium(II)
;
_journal_coeditor_code           TK4072
_journal_issue                   12
_journal_name_full               IUCrData
_journal_page_first              x211259
_journal_paper_doi               10.1107/S2414314621012591
_journal_volume                  6
_journal_year                    2021
_chemical_formula_iupac          '[Ru Cl2 (C10 H14) (C21 H21 O3 P)]'
_chemical_formula_moiety         'C31 H35 Cl2 O3 P Ru'
_chemical_formula_sum            'C31 H35 Cl2 O3 P Ru'
_chemical_formula_weight         658.53
_chemical_name_systematic
;
Dichlorido(η⁶-p-cymene)[tris(4-methoxyphenyl)phosphane]ruthenium(II)
;
_space_group_IT_number           2
_space_group_name_Hall           '-P 1'
_space_group_name_H-M_alt        'P -1'
_symmetry_cell_setting           triclinic
_symmetry_space_group_name_Hall  '-P 1'
_symmetry_space_group_name_H-M   'P -1'
_atom_sites_solution_hydrogens   geom
_atom_sites_solution_primary     direct
_atom_sites_solution_secondary   difmap
_audit_creation_method           'WinGX routine CIF_UPDATE'
_cell_angle_alpha                91.459(3)
_cell_angle_beta                 91.205(3)
_cell_angle_gamma                90.613(3)
_cell_formula_units_Z            4
_cell_length_a                   12.4069(17)
_cell_length_b                   14.0221(19)
_cell_length_c                   16.934(2)
_cell_measurement_reflns_used    9270
_cell_measurement_temperature    100(2)
_cell_measurement_theta_max      28.50
_cell_measurement_theta_min      2.55
_cell_volume                     2944.2(7)
_computing_cell_refinement
;
SAINT (Bruker, 2008)
;
_computing_data_collection
;
APEX2 (Bruker, 2011)
;
_computing_data_reduction
;
SAINT and XPREP (Bruker, 2008)
;
_computing_molecular_graphics
;
DIAMOND (Brandenburg & Putz, 2005)
;
_computing_publication_material
;
publCIF (Westrip, 2010) and WinGX (Farrugia, 2012)
;
_computing_structure_refinement
;
SHELXL97 (Sheldrick, 2008)
;
_computing_structure_solution
;
SIR97 (Altomare et al., 1999)
;
_diffrn_ambient_temperature      100(2)
_diffrn_detector_area_resol_mean 8.4
_diffrn_measured_fraction_theta_full 0.984
_diffrn_measured_fraction_theta_max 0.984
_diffrn_measurement_device_type  'Bruker APEX DUO 4K-CCD'
_diffrn_measurement_method       'φ and ω scans'
_diffrn_radiation_monochromator  graphite
_diffrn_radiation_type           MoK\a
_diffrn_radiation_wavelength     0.71073
_diffrn_reflns_av_R_equivalents  0.0525
_diffrn_reflns_av_unetI/netI     0.0348
_diffrn_reflns_limit_h_max       16
_diffrn_reflns_limit_h_min       -16
_diffrn_reflns_limit_k_max       18
_diffrn_reflns_limit_k_min       -18
_diffrn_reflns_limit_l_max       22
_diffrn_reflns_limit_l_min       -22
_diffrn_reflns_number            88599
_diffrn_reflns_theta_full        28.62
_diffrn_reflns_theta_max         28.62
_diffrn_reflns_theta_min         1.2
_diffrn_standards_decay_%        0
_diffrn_standards_interval_count 0
_diffrn_standards_interval_time  0
_diffrn_standards_number         0
_exptl_absorpt_coefficient_mu    0.799
_exptl_absorpt_correction_T_max  0.850
_exptl_absorpt_correction_T_min  0.654
_exptl_absorpt_correction_type   multi-scan
_exptl_absorpt_process_details
;
SADABS (Bruker, 2008)
;
_exptl_crystal_colour            orange
_exptl_crystal_density_diffrn    1.486
_exptl_crystal_density_method    'not measured'
_exptl_crystal_description       block
_exptl_crystal_F_000             1352
_exptl_crystal_size_max          0.58
_exptl_crystal_size_mid          0.28
_exptl_crystal_size_min          0.21
_refine_diff_density_max         3.949
_refine_diff_density_min         -1.945
_refine_ls_extinction_method     none
_refine_ls_goodness_of_fit_ref   1.092
_refine_ls_hydrogen_treatment    constr
_refine_ls_matrix_type           full
_refine_ls_number_parameters     698
_refine_ls_number_reflns         14838
_refine_ls_number_restraints     0
_refine_ls_restrained_S_all      1.092
_refine_ls_R_factor_all          0.0795
_refine_ls_R_factor_gt           0.0697
_refine_ls_shift/su_max          0.047
_refine_ls_shift/su_mean         0.002
_refine_ls_structure_factor_coef Fsqd
_refine_ls_weighting_details
'calc w=1/[σ²(Fo²)+(0.0475P)²+35.9275P] where P=(Fo²+2Fc²)/3'
_refine_ls_weighting_scheme      calc
_refine_ls_wR_factor_ref         0.1809
_reflns_number_gt                13368
_reflns_number_total             14838
_reflns_threshold_expression     >2σ(I)
_cod_data_source_file            tk4072sup1.cif
_cod_data_source_block           I
_cod_database_code               1565893
_cod_database_fobs_code          1565893
loop_
_symmetry_equiv_pos_as_xyz
'x, y, z'
'-x, -y, -z'
loop_
_atom_site_type_symbol
_atom_site_label
_atom_site_fract_x
_atom_site_fract_y
_atom_site_fract_z
_atom_site_U_iso_or_equiv
_atom_site_adp_type
_atom_site_calc_flag
_atom_site_refinement_flags
_atom_site_occupancy
_atom_site_disorder_assembly
_atom_site_disorder_group
C C1 0.9475(5) 0.2043(4) 0.3616(4) 0.0200(12) Uani d . 1 . .
C C2 0.8727(5) 0.2354(4) 0.3038(4) 0.0182(11) Uani d . 1 . .
H H2 0.8617 0.1993 0.256 0.022 Uiso calc R 1 . .
C C3 0.8146(5) 0.3197(4) 0.3169(4) 0.0223(13) Uani d . 1 . .
H H3 0.7666 0.3407 0.2766 0.027 Uiso calc R 1 . .
C C4 0.8250(5) 0.3741(4) 0.3878(4) 0.0228(13) Uani d . 1 . .
C C5 0.8988(5) 0.3408(4) 0.4470(4) 0.0211(12) Uani d . 1 . .
H H5 0.908 0.376 0.4954 0.025 Uiso calc R 1 . .
C C6 0.9574(5) 0.2576(4) 0.4346(4) 0.0205(12) Uani d . 1 . .
H H6 1.0045 0.2361 0.4752 0.025 Uiso calc R 1 . .
C C7 1.0125(5) 0.3287(4) 0.1271(3) 0.0172(11) Uani d . 1 . .
C C8 1.1043(5) 0.3261(4) 0.0816(4) 0.0222(12) Uani d . 1 . .
H H8 1.1598 0.3723 0.0913 0.027 Uiso calc R 1 . .
C C9 1.1166(6) 0.2571(5) 0.0220(4) 0.0274(14) Uani d . 1 . .
H H9 1.1793 0.2574 -0.0092 0.033 Uiso calc R 1 . .
C C10 1.0370(6) 0.1878(5) 0.0083(4) 0.0271(14) Uani d . 1 . .
C C11 0.9439(6) 0.1888(5) 0.0538(4) 0.0260(14) Uani d . 1 . .
H H11 0.8895 0.1413 0.0451 0.031 Uiso calc R 1 . .
C C12 0.9318(5) 0.2589(5) 0.1109(4) 0.0219(12) Uani d . 1 . .
H H12 0.8674 0.2604 0.1402 0.026 Uiso calc R 1 . .
C C13 0.8761(5) 0.4836(4) 0.1781(4) 0.0186(11) Uani d . 1 . .
C C14 0.8191(5) 0.4697(4) 0.1067(4) 0.0210(12) Uani d . 1 . .
H H14 0.8367 0.418 0.0722 0.025 Uiso calc R 1 . .
C C15 0.7368(6) 0.5309(5) 0.0856(4) 0.0258(13) Uani d . 1 . .
H H15 0.6986 0.5211 0.0368 0.031 Uiso calc R 1 . .
C C16 0.7102(5) 0.6067(4) 0.1358(4) 0.0240(13) Uani d . 1 . .
C C17 0.7668(5) 0.6216(4) 0.2071(4) 0.0238(13) Uani d . 1 . .
H H17 0.7493 0.6736 0.2413 0.029 Uiso calc R 1 . .
C C18 0.8488(5) 0.5601(5) 0.2276(4) 0.0226(12) Uani d . 1 . .
H H18 0.8871 0.5703 0.2763 0.027 Uiso calc R 1 . .
C C19 1.0993(5) 0.5078(4) 0.1843(4) 0.0203(12) Uani d . 1 . .
C C20 1.0782(5) 0.5693(5) 0.1217(4) 0.0232(13) Uani d . 1 . .
H H20 1.0116 0.5632 0.0933 0.028 Uiso calc R 1 . .
C C21 1.1521(5) 0.6388(4) 0.1003(4) 0.0222(12) Uani d . 1 . .
H H21 1.1359 0.6796 0.0579 0.027 Uiso calc R 1 . .
C C22 1.2496(5) 0.6478(4) 0.1415(4) 0.0215(12) Uani d . 1 . .
C C23 1.2724(5) 0.5878(5) 0.2036(4) 0.0230(13) Uani d . 1 . .
H H23 1.3393 0.5941 0.2317 0.028 Uiso calc R 1 . .
C C24 1.1978(5) 0.5184(5) 0.2251(4) 0.0231(12) Uani d . 1 . .
H H24 1.2141 0.478 0.2679 0.028 Uiso calc R 1 . .
C C25 0.7616(6) 0.4622(5) 0.4029(5) 0.0322(16) Uani d . 1 . .
H H25A 0.7462 0.4932 0.3527 0.048 Uiso calc R 1 . .
H H25B 0.8032 0.506 0.438 0.048 Uiso calc R 1 . .
H H25C 0.6936 0.4453 0.4278 0.048 Uiso calc R 1 . .
C C26 1.0125(5) 0.1142(4) 0.3513(4) 0.0207(12) Uani d . 1 . .
H H26 1.0865 0.1269 0.3739 0.025 Uiso calc R 1 . .
C C27 0.9588(6) 0.0383(5) 0.4007(4) 0.0280(14) Uani d . 1 . .
H H27A 0.9638 0.0577 0.4567 0.042 Uiso calc R 1 . .
H H27B 0.9954 -0.0227 0.3927 0.042 Uiso calc R 1 . .
H H27C 0.8828 0.0312 0.3844 0.042 Uiso calc R 1 . .
C C28 1.0233(6) 0.0813(5) 0.2656(4) 0.0278(14) Uani d . 1 . .
H H28A 0.9523 0.0624 0.2437 0.042 Uiso calc R 1 . .
H H28B 1.0719 0.0268 0.2628 0.042 Uiso calc R 1 . .
H H28C 1.0528 0.1336 0.235 0.042 Uiso calc R 1 . .
C C29 1.1271(9) 0.1161(7) -0.0998(5) 0.049(2) Uani d . 1 . .
H H29A 1.1253 0.1741 -0.1309 0.073 Uiso calc R 1 . .
H H29B 1.1218 0.06 -0.1354 0.073 Uiso calc R 1 . .
H H29C 1.1949 0.1144 -0.0692 0.073 Uiso calc R 1 . .
C C30 0.5940(7) 0.7367(5) 0.1615(6) 0.0390(19) Uani d . 1 . .
H H30A 0.5683 0.7091 0.2103 0.058 Uiso calc R 1 . .
H H30B 0.5354 0.7718 0.1362 0.058 Uiso calc R 1 . .
H H30C 0.6545 0.7804 0.1739 0.058 Uiso calc R 1 . .
C C31 1.3045(6) 0.7780(5) 0.0639(5) 0.0304(15) Uani d . 1 . .
H H31A 1.2944 0.7418 0.014 0.046 Uiso calc R 1 . .
H H31B 1.3646 0.8233 0.0594 0.046 Uiso calc R 1 . .
H H31C 1.2385 0.813 0.0757 0.046 Uiso calc R 1 . .
C C32 0.4449(5) 0.2814(4) 0.1359(4) 0.0190(12) Uani d . 1 . .
C C33 0.3718(5) 0.2540(4) 0.1934(4) 0.0183(11) Uani d . 1 . .
H H33 0.3641 0.292 0.2402 0.022 Uiso calc R 1 . .
C C34 0.3089(5) 0.1683(4) 0.1812(4) 0.0210(12) Uani d . 1 . .
H H34 0.2632 0.148 0.2221 0.025 Uiso calc R 1 . .
C C35 0.3126(5) 0.1135(4) 0.1110(4) 0.0212(12) Uani d . 1 . .
C C36 0.3841(5) 0.1456(5) 0.0516(4) 0.0226(12) Uani d . 1 . .
H H36 0.3881 0.1106 0.003 0.027 Uiso calc R 1 . .
C C37 0.4476(5) 0.2269(5) 0.0639(4) 0.0214(12) Uani d . 1 . .
H H37 0.494 0.2467 0.0233 0.026 Uiso calc R 1 . .
C C38 0.5152(5) 0.1593(4) 0.3719(3) 0.0185(11) Uani d . 1 . .
C C39 0.6095(6) 0.1654(5) 0.4173(4) 0.0250(13) Uani d . 1 . .
H H39 0.6641 0.1195 0.4087 0.03 Uiso calc R 1 . .
C C40 0.6268(6) 0.2363(5) 0.4749(4) 0.0281(14) Uani d . 1 . .
H H40 0.6913 0.2376 0.5062 0.034 Uiso calc R 1 . .
C C41 0.5486(7) 0.3059(5) 0.4864(4) 0.0299(15) Uani d . 1 . .
C C42 0.4540(6) 0.3013(5) 0.4414(4) 0.0280(14) Uani d . 1 . .
H H42 0.4006 0.3485 0.4492 0.034 Uiso calc R 1 . .
C C43 0.4362(5) 0.2290(4) 0.3853(3) 0.0214(12) Uani d . 1 . .
H H43 0.3703 0.2263 0.3557 0.026 Uiso calc R 1 . .
C C44 0.5937(5) -0.0197(4) 0.3173(4) 0.0189(11) Uani d . 1 . .
C C45 0.5752(5) -0.0781(5) 0.3822(4) 0.0228(13) Uani d . 1 . .
H H45 0.5114 -0.0699 0.4116 0.027 Uiso calc R 1 . .
C C46 0.6487(5) -0.1481(5) 0.4044(4) 0.0235(13) Uani d . 1 . .
H H46 0.6348 -0.1869 0.4483 0.028 Uiso calc R 1 . .
C C47 0.7417(5) -0.1600(4) 0.3618(4) 0.0220(12) Uani d . 1 . .
C C48 0.7613(5) -0.1022(5) 0.2979(4) 0.0238(13) Uani d . 1 . .
H H48 0.8256 -0.1102 0.2692 0.029 Uiso calc R 1 . .
C C49 0.6883(5) -0.0329(4) 0.2755(4) 0.0209(12) Uani d . 1 . .
H H49 0.7029 0.0057 0.2316 0.025 Uiso calc R 1 . .
C C50 0.3715(5) 0.0036(4) 0.3202(4) 0.0200(12) Uani d . 1 . .
C C51 0.3168(5) 0.0175(5) 0.3909(4) 0.0221(12) Uani d . 1 . .
H H51 0.3372 0.0691 0.4257 0.027 Uiso calc R 1 . .
C C52 0.2334(5) -0.0431(5) 0.4106(4) 0.0255(13) Uani d . 1 . .
H H52 0.1972 -0.0331 0.4589 0.031 Uiso calc R 1 . .
C C53 0.2024(5) -0.1183(5) 0.3603(4) 0.0252(14) Uani d . 1 . .
C C54 0.2562(5) -0.1337(4) 0.2897(4) 0.0236(13) Uani d . 1 . .
H H54 0.2357 -0.1855 0.2551 0.028 Uiso calc R 1 . .
C C55 0.3400(5) -0.0729(5) 0.2706(4) 0.0226(12) Uani d . 1 . .
H H55 0.3767 -0.0836 0.2225 0.027 Uiso calc R 1 . .
C C56 0.2434(6) 0.0267(5) 0.0959(5) 0.0296(15) Uani d . 1 . .
H H56A 0.2352 -0.0074 0.1452 0.044 Uiso calc R 1 . .
H H56B 0.2772 -0.0151 0.0566 0.044 Uiso calc R 1 . .
H H56C 0.1723 0.0459 0.0759 0.044 Uiso calc R 1 . .
C C57 0.5140(6) 0.3707(4) 0.1460(4) 0.0242(13) Uani d . 1 . .
H H57 0.5865 0.3565 0.1241 0.029 Uiso calc R 1 . .
C C58 0.4621(6) 0.4480(5) 0.0951(4) 0.0269(14) Uani d . 1 . .
H H58A 0.4603 0.4265 0.0396 0.04 Uiso calc R 1 . .
H H58B 0.5046 0.5072 0.1009 0.04 Uiso calc R 1 . .
H H58C 0.3884 0.4595 0.1126 0.04 Uiso calc R 1 . .
C C59 0.5305(6) 0.4050(5) 0.2319(4) 0.0297(15) Uani d . 1 . .
H H59A 0.4615 0.4258 0.2531 0.045 Uiso calc R 1 . .
H H59B 0.5821 0.4584 0.2344 0.045 Uiso calc R 1 . .
H H59C 0.5585 0.3526 0.2633 0.045 Uiso calc R 1 . .
C C60 0.6452(9) 0.3841(7) 0.5933(6) 0.053(2) Uani d . 1 . .
H H60A 0.6483 0.3251 0.6231 0.079 Uiso calc R 1 . .
H H60B 0.6376 0.4386 0.63 0.079 Uiso calc R 1 . .
H H60C 0.7117 0.3915 0.5637 0.079 Uiso calc R 1 . .
C C61 0.7966(6) -0.2890(5) 0.4415(5) 0.0300(15) Uani d . 1 . .
H H61A 0.7958 -0.2524 0.4916 0.045 Uiso calc R 1 . .
H H61B 0.8528 -0.3374 0.4442 0.045 Uiso calc R 1 . .
H H61C 0.7263 -0.3202 0.432 0.045 Uiso calc R 1 . .
C C62 0.0789(7) -0.2475(5) 0.3309(6) 0.041(2) Uani d . 1 . .
H H62A 0.0605 -0.2194 0.28 0.062 Uiso calc R 1 . .
H H62B 0.0144 -0.277 0.3526 0.062 Uiso calc R 1 . .
H H62C 0.1342 -0.2961 0.3233 0.062 Uiso calc R 1 . .
P P1 0.99715(12) 0.41789(10) 0.20650(9) 0.0166(3) Uani d . 1 . .
P P2 0.49275(13) 0.06929(10) 0.29344(9) 0.0169(3) Uani d . 1 . .
Cl Cl1 1.17183(12) 0.30968(11) 0.32444(10) 0.0246(3) Uani d . 1 . .
Cl Cl2 1.04584(14) 0.50981(11) 0.38312(9) 0.0242(3) Uani d . 1 . .
Cl Cl3 0.66582(12) 0.17348(11) 0.17376(10) 0.0254(3) Uani d . 1 . .
Cl Cl4 0.52593(13) -0.02586(10) 0.11852(8) 0.0211(3) Uani d . 1 . .
Ru Ru1 0.98521(4) 0.35528(3) 0.33430(3) 0.01596(11) Uani d . 1 . .
Ru Ru2 0.47608(4) 0.13050(3) 0.16486(3) 0.01558(11) Uani d . 1 . .
O O1 1.0393(5) 0.1160(4) -0.0478(3) 0.0378(13) Uani d . 1 . .
O O2 0.6284(4) 0.6629(3) 0.1096(3) 0.0314(11) Uani d . 1 . .
O O3 1.3276(4) 0.7138(3) 0.1262(3) 0.0269(10) Uani d . 1 . .
O O4 0.5567(6) 0.3797(4) 0.5406(3) 0.0430(14) Uani d . 1 . .
O O5 0.8184(4) -0.2262(3) 0.3785(3) 0.0266(10) Uani d . 1 . .
O O6 0.1193(4) -0.1746(3) 0.3846(3) 0.0321(12) Uani d . 1 . .
loop_
_atom_type_symbol
_atom_type_description
_atom_type_scat_dispersion_real
_atom_type_scat_dispersion_imag
_atom_type_scat_source
C C 0.0033 0.0016 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
H H 0 0 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
P P 0.1023 0.0942 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
Cl Cl 0.1484 0.1585 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
Ru Ru -1.2594 0.8363 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
O O 0.0106 0.006 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
loop_
_geom_angle_atom_site_label_1
_geom_angle_atom_site_label_2
_geom_angle_atom_site_label_3
_geom_angle_site_symmetry_1
_geom_angle_site_symmetry_3
_geom_angle
_geom_angle_publ_flag
C2 C1 C6 . . 118.3(5) ?
C2 C1 C26 . . 122.8(6) ?
C6 C1 C26 . . 118.8(5) ?
C2 C1 Ru1 . . 71.1(3) ?
C6 C1 Ru1 . . 71.8(3) ?
C26 C1 Ru1 . . 131.3(4) ?
C3 C2 C1 . . 120.1(6) ?
C3 C2 Ru1 . . 70.0(4) ?
C1 C2 Ru1 . . 71.7(3) ?
C3 C2 H2 . . 119.9 ?
C1 C2 H2 . . 119.9 ?
Ru1 C2 H2 . . 131 ?
C2 C3 C4 . . 122.2(6) ?
C2 C3 Ru1 . . 72.7(4) ?
C4 C3 Ru1 . . 72.7(4) ?
C2 C3 H3 . . 118.9 ?
C4 C3 H3 . . 118.9 ?
Ru1 C3 H3 . . 128 ?
C3 C4 C5 . . 117.4(6) ?
C3 C4 C25 . . 122.5(6) ?
C5 C4 C25 . . 120.1(6) ?
C3 C4 Ru1 . . 70.0(4) ?
C5 C4 Ru1 . . 71.3(3) ?
C25 C4 Ru1 . . 130.4(5) ?
C6 C5 C4 . . 121.0(6) ?
C6 C5 Ru1 . . 72.5(3) ?
C4 C5 Ru1 . . 71.0(3) ?
C6 C5 H5 . . 119.5 ?
C4 C5 H5 . . 119.5 ?
Ru1 C5 H5 . . 129.5 ?
C5 C6 C1 . . 120.9(6) ?
C5 C6 Ru1 . . 71.1(3) ?
C1 C6 Ru1 . . 70.8(3) ?
C5 C6 H6 . . 119.5 ?
C1 C6 H6 . . 119.5 ?
Ru1 C6 H6 . . 131.4 ?
C8 C7 C12 . . 117.6(6) ?
C8 C7 P1 . . 121.5(5) ?
C12 C7 P1 . . 120.9(5) ?
C7 C8 C9 . . 121.4(6) ?
C7 C8 H8 . . 119.3 ?
C9 C8 H8 . . 119.3 ?
C10 C9 C8 . . 119.9(7) ?
C10 C9 H9 . . 120 ?
C8 C9 H9 . . 120 ?
O1 C10 C9 . . 125.8(7) ?
O1 C10 C11 . . 114.5(6) ?
C9 C10 C11 . . 119.7(6) ?
C12 C11 C10 . . 119.6(6) ?
C12 C11 H11 . . 120.2 ?
C10 C11 H11 . . 120.2 ?
C11 C12 C7 . . 121.7(6) ?
C11 C12 H12 . . 119.1 ?
C7 C12 H12 . . 119.1 ?
C18 C13 C14 . . 118.7(6) ?
C18 C13 P1 . . 116.4(5) ?
C14 C13 P1 . . 124.5(5) ?
C15 C14 C13 . . 120.5(6) ?
C15 C14 H14 . . 119.7 ?
C13 C14 H14 . . 119.7 ?
C14 C15 C16 . . 120.1(6) ?
C14 C15 H15 . . 119.9 ?
C16 C15 H15 . . 119.9 ?
O2 C16 C15 . . 115.6(6) ?
O2 C16 C17 . . 124.5(6) ?
C15 C16 C17 . . 119.9(6) ?
C18 C17 C16 . . 119.5(6) ?
C18 C17 H17 . . 120.2 ?
C16 C17 H17 . . 120.2 ?
C17 C18 C13 . . 121.2(6) ?
C17 C18 H18 . . 119.4 ?
C13 C18 H18 . . 119.4 ?
C24 C19 C20 . . 117.8(6) ?
C24 C19 P1 . . 124.0(5) ?
C20 C19 P1 . . 118.2(5) ?
C21 C20 C19 . . 121.9(6) ?
C21 C20 H20 . . 119.1 ?
C19 C20 H20 . . 119.1 ?
C22 C21 C20 . . 119.3(6) ?
C22 C21 H21 . . 120.3 ?
C20 C21 H21 . . 120.3 ?
O3 C22 C21 . . 124.5(6) ?
O3 C22 C23 . . 115.7(6) ?
C21 C22 C23 . . 119.8(6) ?
C22 C23 C24 . . 120.6(6) ?
C22 C23 H23 . . 119.7 ?
C24 C23 H23 . . 119.7 ?
C19 C24 C23 . . 120.5(6) ?
C19 C24 H24 . . 119.8 ?
C23 C24 H24 . . 119.8 ?
C4 C25 H25A . . 109.5 ?
C4 C25 H25B . . 109.5 ?
H25A C25 H25B . . 109.5 ?
C4 C25 H25C . . 109.5 ?
H25A C25 H25C . . 109.5 ?
H25B C25 H25C . . 109.5 ?
C1 C26 C28 . . 113.8(5) ?
C1 C26 C27 . . 106.8(5) ?
C28 C26 C27 . . 112.0(5) ?
C1 C26 H26 . . 108.1 ?
C28 C26 H26 . . 108.1 ?
C27 C26 H26 . . 108.1 ?
C26 C27 H27A . . 109.5 ?
C26 C27 H27B . . 109.5 ?
H27A C27 H27B . . 109.5 ?
C26 C27 H27C . . 109.5 ?
H27A C27 H27C . . 109.5 ?
H27B C27 H27C . . 109.5 ?
C26 C28 H28A . . 109.5 ?
C26 C28 H28B . . 109.5 ?
H28A C28 H28B . . 109.5 ?
C26 C28 H28C . . 109.5 ?
H28A C28 H28C . . 109.5 ?
H28B C28 H28C . . 109.5 ?
O1 C29 H29A . . 109.5 ?
O1 C29 H29B . . 109.5 ?
H29A C29 H29B . . 109.5 ?
O1 C29 H29C . . 109.5 ?
H29A C29 H29C . . 109.5 ?
H29B C29 H29C . . 109.5 ?
O2 C30 H30A . . 109.5 ?
O2 C30 H30B . . 109.5 ?
H30A C30 H30B . . 109.5 ?
O2 C30 H30C . . 109.5 ?
H30A C30 H30C . . 109.5 ?
H30B C30 H30C . . 109.5 ?
O3 C31 H31A . . 109.5 ?
O3 C31 H31B . . 109.5 ?
H31A C31 H31B . . 109.5 ?
O3 C31 H31C . . 109.5 ?
H31A C31 H31C . . 109.5 ?
H31B C31 H31C . . 109.5 ?
C33 C32 C37 . . 118.3(6) ?
C33 C32 C57 . . 121.8(6) ?
C37 C32 C57 . . 119.7(5) ?
C33 C32 Ru2 . . 71.6(3) ?
C37 C32 Ru2 . . 71.8(3) ?
C57 C32 Ru2 . . 131.7(4) ?
C32 C33 C34 . . 119.6(6) ?
C32 C33 Ru2 . . 71.5(3) ?
C34 C33 Ru2 . . 68.9(3) ?
C32 C33 H33 . . 120.2 ?
C34 C33 H33 . . 120.2 ?
Ru2 C33 H33 . . 132.3 ?
C35 C34 C33 . . 122.1(6) ?
C35 C34 Ru2 . . 73.2(4) ?
C33 C34 Ru2 . . 73.0(3) ?
C35 C34 H34 . . 119 ?
C33 C34 H34 . . 119 ?
Ru2 C34 H34 . . 127 ?
C34 C35 C36 . . 117.1(6) ?
C34 C35 C56 . . 122.6(6) ?
C36 C35 C56 . . 120.3(6) ?
C34 C35 Ru2 . . 69.5(4) ?
C36 C35 Ru2 . . 71.6(4) ?
C56 C35 Ru2 . . 131.2(4) ?
C37 C36 C35 . . 121.2(6) ?
C37 C36 Ru2 . . 72.0(4) ?
C35 C36 Ru2 . . 70.8(4) ?
C37 C36 H36 . . 119.4 ?
C35 C36 H36 . . 119.4 ?
Ru2 C36 H36 . . 130.5 ?
C36 C37 C32 . . 121.5(6) ?
C36 C37 Ru2 . . 71.7(4) ?
C32 C37 Ru2 . . 71.0(3) ?
C36 C37 H37 . . 119.2 ?
C32 C37 H37 . . 119.2 ?
Ru2 C37 H37 . . 131 ?
C39 C38 C43 . . 117.7(6) ?
C39 C38 P2 . . 122.9(5) ?
C43 C38 P2 . . 119.3(5) ?
C40 C39 C38 . . 122.2(6) ?
C40 C39 H39 . . 118.9 ?
C38 C39 H39 . . 118.9 ?
C39 C40 C41 . . 119.4(7) ?
C39 C40 H40 . . 120.3 ?
C41 C40 H40 . . 120.3 ?
O4 C41 C42 . . 115.8(7) ?
O4 C41 C40 . . 124.8(7) ?
C42 C41 C40 . . 119.4(7) ?
C43 C42 C41 . . 120.9(7) ?
C43 C42 H42 . . 119.5 ?
C41 C42 H42 . . 119.5 ?
C42 C43 C38 . . 120.4(6) ?
C42 C43 H43 . . 119.8 ?
C38 C43 H43 . . 119.8 ?
C49 C44 C45 . . 118.1(6) ?
C49 C44 P2 . . 123.9(4) ?
C45 C44 P2 . . 118.0(5) ?
C46 C45 C44 . . 121.6(6) ?
C46 C45 H45 . . 119.2 ?
C44 C45 H45 . . 119.2 ?
C47 C46 C45 . . 119.3(6) ?
C47 C46 H46 . . 120.4 ?
C45 C46 H46 . . 120.4 ?
O5 C47 C46 . . 123.9(6) ?
O5 C47 C48 . . 116.3(6) ?
C46 C47 C48 . . 119.8(6) ?
C49 C48 C47 . . 121.1(6) ?
C49 C48 H48 . . 119.4 ?
C47 C48 H48 . . 119.4 ?
C48 C49 C44 . . 120.2(6) ?
C48 C49 H49 . . 119.9 ?
C44 C49 H49 . . 119.9 ?
C55 C50 C51 . . 118.3(6) ?
C55 C50 P2 . . 116.8(5) ?
C51 C50 P2 . . 124.5(5) ?
C52 C51 C50 . . 120.6(6) ?
C52 C51 H51 . . 119.7 ?
C50 C51 H51 . . 119.7 ?
C53 C52 C51 . . 120.4(6) ?
C53 C52 H52 . . 119.8 ?
C51 C52 H52 . . 119.8 ?
O6 C53 C52 . . 116.4(6) ?
O6 C53 C54 . . 123.7(7) ?
C52 C53 C54 . . 119.9(6) ?
C55 C54 C53 . . 119.4(6) ?
C55 C54 H54 . . 120.3 ?
C53 C54 H54 . . 120.3 ?
C54 C55 C50 . . 121.5(6) ?
C54 C55 H55 . . 119.3 ?
C50 C55 H55 . . 119.3 ?
C35 C56 H56A . . 109.5 ?
C35 C56 H56B . . 109.5 ?
H56A C56 H56B . . 109.5 ?
C35 C56 H56C . . 109.5 ?
H56A C56 H56C . . 109.5 ?
H56B C56 H56C . . 109.5 ?
C32 C57 C59 . . 114.0(5) ?
C32 C57 C58 . . 107.4(5) ?
C59 C57 C58 . . 111.7(6) ?
C32 C57 H57 . . 107.8 ?
C59 C57 H57 . . 107.8 ?
C58 C57 H57 . . 107.8 ?
C57 C58 H58A . . 109.5 ?
C57 C58 H58B . . 109.5 ?
H58A C58 H58B . . 109.5 ?
C57 C58 H58C . . 109.5 ?
H58A C58 H58C . . 109.5 ?
H58B C58 H58C . . 109.5 ?
C57 C59 H59A . . 109.5 ?
C57 C59 H59B . . 109.5 ?
H59A C59 H59B . . 109.5 ?
C57 C59 H59C . . 109.5 ?
H59A C59 H59C . . 109.5 ?
H59B C59 H59C . . 109.5 ?
O4 C60 H60A . . 109.5 ?
O4 C60 H60B . . 109.5 ?
H60A C60 H60B . . 109.5 ?
O4 C60 H60C . . 109.5 ?
H60A C60 H60C . . 109.5 ?
H60B C60 H60C . . 109.5 ?
O5 C61 H61A . . 109.5 ?
O5 C61 H61B . . 109.5 ?
H61A C61 H61B . . 109.5 ?
O5 C61 H61C . . 109.5 ?
H61A C61 H61C . . 109.5 ?
H61B C61 H61C . . 109.5 ?
O6 C62 H62A . . 109.5 ?
O6 C62 H62B . . 109.5 ?
H62A C62 H62B . . 109.5 ?
O6 C62 H62C . . 109.5 ?
H62A C62 H62C . . 109.5 ?
H62B C62 H62C . . 109.5 ?
C7 P1 C19 . . 102.9(3) ?
C7 P1 C13 . . 104.5(3) ?
C19 P1 C13 . . 99.0(3) ?
C7 P1 Ru1 . . 114.85(18) ?
C19 P1 Ru1 . . 121.1(2) ?
C13 P1 Ru1 . . 112.2(2) ?
C38 P2 C44 . . 102.3(3) ?
C38 P2 C50 . . 105.7(3) ?
C44 P2 C50 . . 99.2(3) ?
C38 P2 Ru2 . . 114.78(19) ?
C44 P2 Ru2 . . 121.3(2) ?
C50 P2 Ru2 . . 111.5(2) ?
C3 Ru1 C2 . . 37.3(2) ?
C3 Ru1 C4 . . 37.3(3) ?
C2 Ru1 C4 . . 67.5(2) ?
C3 Ru1 C5 . . 66.9(2) ?
C2 Ru1 C5 . . 78.9(2) ?
C4 Ru1 C5 . . 37.7(2) ?
C3 Ru1 C1 . . 67.4(2) ?
C2 Ru1 C1 . . 37.2(2) ?
C4 Ru1 C1 . . 80.4(2) ?
C5 Ru1 C1 . . 67.1(2) ?
C3 Ru1 C6 . . 78.6(2) ?
C2 Ru1 C6 . . 66.5(2) ?
C4 Ru1 C6 . . 67.1(2) ?
C5 Ru1 C6 . . 36.5(2) ?
C1 Ru1 C6 . . 37.4(2) ?
C3 Ru1 P1 . . 92.34(17) ?
C2 Ru1 P1 . . 97.58(16) ?
C4 Ru1 P1 . . 113.67(18) ?
C5 Ru1 P1 . . 150.43(18) ?
C1 Ru1 P1 . . 125.74(17) ?
C6 Ru1 P1 . . 162.96(17) ?
C3 Ru1 Cl2 . . 122.15(17) ?
C2 Ru1 Cl2 . . 158.84(17) ?
C4 Ru1 Cl2 . . 91.80(17) ?
C5 Ru1 Cl2 . . 87.36(17) ?
C1 Ru1 Cl2 . . 147.33(17) ?
C6 Ru1 Cl2 . . 110.54(17) ?
P1 Ru1 Cl2 . . 86.50(5) ?
C3 Ru1 Cl1 . . 149.35(17) ?
C2 Ru1 Cl1 . . 112.33(16) ?
C4 Ru1 Cl1 . . 158.28(18) ?
C5 Ru1 Cl1 . . 120.70(18) ?
C1 Ru1 Cl1 . . 87.69(17) ?
C6 Ru1 Cl1 . . 92.52(16) ?
P1 Ru1 Cl1 . . 88.03(5) ?
Cl2 Ru1 Cl1 . . 88.47(6) ?
C34 Ru2 C35 . . 37.3(2) ?
C34 Ru2 C33 . . 38.1(2) ?
C35 Ru2 C33 . . 68.0(2) ?
C34 Ru2 C32 . . 67.9(2) ?
C35 Ru2 C32 . . 80.8(2) ?
C33 Ru2 C32 . . 36.8(2) ?
C34 Ru2 C36 . . 66.7(2) ?
C35 Ru2 C36 . . 37.6(2) ?
C33 Ru2 C36 . . 78.6(2) ?
C32 Ru2 C36 . . 67.0(2) ?
C34 Ru2 C37 . . 78.7(2) ?
C35 Ru2 C37 . . 67.1(2) ?
C33 Ru2 C37 . . 66.0(2) ?
C32 Ru2 C37 . . 37.3(2) ?
C36 Ru2 C37 . . 36.3(2) ?
C34 Ru2 P2 . . 92.57(17) ?
C35 Ru2 P2 . . 113.98(17) ?
C33 Ru2 P2 . . 98.15(16) ?
C32 Ru2 P2 . . 125.91(17) ?
C36 Ru2 P2 . . 150.73(18) ?
C37 Ru2 P2 . . 163.06(18) ?
C34 Ru2 Cl4 . . 121.57(17) ?
C35 Ru2 Cl4 . . 91.48(17) ?
C33 Ru2 Cl4 . . 159.07(17) ?
C32 Ru2 Cl4 . . 147.58(17) ?
C36 Ru2 Cl4 . . 87.74(17) ?
C37 Ru2 Cl4 . . 110.89(17) ?
P2 Ru2 Cl4 . . 86.05(5) ?
C34 Ru2 Cl3 . . 149.64(17) ?
C35 Ru2 Cl3 . . 157.78(17) ?
C33 Ru2 Cl3 . . 111.78(17) ?
C32 Ru2 Cl3 . . 87.18(16) ?
C36 Ru2 Cl3 . . 120.25(18) ?
C37 Ru2 Cl3 . . 92.11(17) ?
P2 Ru2 Cl3 . . 88.21(6) ?
Cl4 Ru2 Cl3 . . 88.77(6) ?
C10 O1 C29 . . 117.0(6) ?
C16 O2 C30 . . 117.1(6) ?
C22 O3 C31 . . 116.5(5) ?
C41 O4 C60 . . 119.1(7) ?
C47 O5 C61 . . 116.8(5) ?
C53 O6 C62 . . 117.7(6) ?
loop_
_geom_bond_atom_site_label_1
_geom_bond_atom_site_label_2
_geom_bond_site_symmetry_2
_geom_bond_distance
_geom_bond_publ_flag
C1 C2 . 1.416(8) ?
C1 C6 . 1.430(9) ?
C1 C26 . 1.514(8) ?
C1 Ru1 . 2.226(6) ?
C2 C3 . 1.406(8) ?
C2 Ru1 . 2.217(6) ?
C2 H2 . 0.95 ?
C3 C4 . 1.408(10) ?
C3 Ru1 . 2.182(7) ?
C3 H3 . 0.95 ?
C4 C5 . 1.434(9) ?
C4 C25 . 1.491(9) ?
C4 Ru1 . 2.217(6) ?
C5 C6 . 1.395(9) ?
C5 Ru1 . 2.221(6) ?
C5 H5 . 0.95 ?
C6 Ru1 . 2.239(6) ?
C6 H6 . 0.95 ?
C7 C8 . 1.389(9) ?
C7 C12 . 1.411(9) ?
C7 P1 . 1.827(6) ?
C8 C9 . 1.391(10) ?
C8 H8 . 0.95 ?
C9 C10 . 1.389(10) ?
C9 H9 . 0.95 ?
C10 O1 . 1.368(8) ?
C10 C11 . 1.401(10) ?
C11 C12 . 1.372(10) ?
C11 H11 . 0.95 ?
C12 H12 . 0.95 ?
C13 C18 . 1.393(9) ?
C13 C14 . 1.398(9) ?
C13 P1 . 1.832(6) ?
C14 C15 . 1.387(9) ?
C14 H14 . 0.95 ?
C15 C16 . 1.391(10) ?
C15 H15 . 0.95 ?
C16 O2 . 1.366(8) ?
C16 C17 . 1.393(10) ?
C17 C18 . 1.386(9) ?
C17 H17 . 0.95 ?
C18 H18 . 0.95 ?
C19 C24 . 1.396(9) ?
C19 C20 . 1.405(8) ?
C19 P1 . 1.830(6) ?
C20 C21 . 1.390(8) ?
C20 H20 . 0.95 ?
C21 C22 . 1.387(9) ?
C21 H21 . 0.95 ?
C22 O3 . 1.364(8) ?
C22 C23 . 1.390(9) ?
C23 C24 . 1.397(9) ?
C23 H23 . 0.95 ?
C24 H24 . 0.95 ?
C25 H25A . 0.98 ?
C25 H25B . 0.98 ?
C25 H25C . 0.98 ?
C26 C28 . 1.521(9) ?
C26 C27 . 1.526(8) ?
C26 H26 . 1 ?
C27 H27A . 0.98 ?
C27 H27B . 0.98 ?
C27 H27C . 0.98 ?
C28 H28A . 0.98 ?
C28 H28B . 0.98 ?
C28 H28C . 0.98 ?
C29 O1 . 1.414(11) ?
C29 H29A . 0.98 ?
C29 H29B . 0.98 ?
C29 H29C . 0.98 ?
C30 O2 . 1.417(10) ?
C30 H30A . 0.98 ?
C30 H30B . 0.98 ?
C30 H30C . 0.98 ?
C31 O3 . 1.431(8) ?
C31 H31A . 0.98 ?
C31 H31B . 0.98 ?
C31 H31C . 0.98 ?
C32 C33 . 1.403(8) ?
C32 C37 . 1.423(9) ?
C32 C57 . 1.514(9) ?
C32 Ru2 . 2.221(6) ?
C33 C34 . 1.434(8) ?
C33 Ru2 . 2.222(6) ?
C33 H33 . 0.95 ?
C34 C35 . 1.402(9) ?
C34 Ru2 . 2.168(6) ?
C34 H34 . 0.95 ?
C35 C36 . 1.432(9) ?
C35 C56 . 1.494(9) ?
C35 Ru2 . 2.215(6) ?
C36 C37 . 1.388(9) ?
C36 Ru2 . 2.227(6) ?
C36 H36 . 0.95 ?
C37 Ru2 . 2.231(6) ?
C37 H37 . 0.95 ?
C38 C39 . 1.387(9) ?
C38 C43 . 1.410(9) ?
C38 P2 . 1.825(6) ?
C39 C40 . 1.387(10) ?
C39 H39 . 0.95 ?
C40 C41 . 1.396(11) ?
C40 H40 . 0.95 ?
C41 O4 . 1.368(9) ?
C41 C42 . 1.386(11) ?
C42 C43 . 1.384(9) ?
C42 H42 . 0.95 ?
C43 H43 . 0.95 ?
C44 C49 . 1.396(9) ?
C44 C45 . 1.408(8) ?
C44 P2 . 1.824(6) ?
C45 C46 . 1.399(8) ?
C45 H45 . 0.95 ?
C46 C47 . 1.383(9) ?
C46 H46 . 0.95 ?
C47 O5 . 1.367(7) ?
C47 C48 . 1.392(9) ?
C48 C49 . 1.389(9) ?
C48 H48 . 0.95 ?
C49 H49 . 0.95 ?
C50 C55 . 1.392(9) ?
C50 C51 . 1.400(9) ?
C50 P2 . 1.827(6) ?
C51 C52 . 1.384(9) ?
C51 H51 . 0.95 ?
C52 C53 . 1.384(10) ?
C52 H52 . 0.95 ?
C53 O6 . 1.369(8) ?
C53 C54 . 1.393(9) ?
C54 C55 . 1.387(9) ?
C54 H54 . 0.95 ?
C55 H55 . 0.95 ?
C56 H56A . 0.98 ?
C56 H56B . 0.98 ?
C56 H56C . 0.98 ?
C57 C59 . 1.530(10) ?
C57 C58 . 1.539(8) ?
C57 H57 . 1 ?
C58 H58A . 0.98 ?
C58 H58B . 0.98 ?
C58 H58C . 0.98 ?
C59 H59A . 0.98 ?
C59 H59B . 0.98 ?
C59 H59C . 0.98 ?
C60 O4 . 1.400(12) ?
C60 H60A . 0.98 ?
C60 H60B . 0.98 ?
C60 H60C . 0.98 ?
C61 O5 . 1.429(8) ?
C61 H61A . 0.98 ?
C61 H61B . 0.98 ?
C61 H61C . 0.98 ?
C62 O6 . 1.431(10) ?
C62 H62A . 0.98 ?
C62 H62B . 0.98 ?
C62 H62C . 0.98 ?
P1 Ru1 . 2.3629(15) ?
P2 Ru2 . 2.3665(15) ?
Cl1 Ru1 . 2.4167(16) ?
Cl2 Ru1 . 2.4068(16) ?
Cl3 Ru2 . 2.4244(16) ?
Cl4 Ru2 . 2.4016(15) ?
loop_
_geom_hbond_atom_site_label_D
_geom_hbond_atom_site_label_H
_geom_hbond_atom_site_label_A
_geom_hbond_site_symmetry_A
_geom_hbond_distance_DH
_geom_hbond_distance_HA
_geom_hbond_distance_DA
_geom_hbond_angle_DHA
C5 H5 Cl2 2_766 0.95 2.62 3.566(7) 171
C36 H36 Cl4 2_655 0.95 2.6 3.506(7) 159
C43 H43 Cl1 1_455 0.95 2.78 3.619(7) 147
C62 H62B O5 1_455 0.98 2.58 3.362(9) 136
C18 H18 Cl2 . 0.95 2.8 3.643(7) 149
C24 H24 Cl1 . 0.95 2.62 3.427(6) 143
C49 H49 Cl3 . 0.95 2.61 3.416(6) 143
C55 H55 Cl4 . 0.95 2.71 3.562(6) 149
C20 H20 Cg1 . 0.95 2.95 3.614(7) 128
loop_
_geom_torsion_atom_site_label_1
_geom_torsion_atom_site_label_2
_geom_torsion_atom_site_label_3
_geom_torsion_atom_site_label_4
_geom_torsion_site_symmetry_1
_geom_torsion_site_symmetry_2
_geom_torsion_site_symmetry_3
_geom_torsion_site_symmetry_4
_geom_torsion
_geom_torsion_publ_flag
C6 C1 C2 C3 . . . . 3.4(9) ?
C26 C1 C2 C3 . . . . 179.9(6) ?
Ru1 C1 C2 C3 . . . . -52.6(5) ?
C6 C1 C2 Ru1 . . . . 56.0(5) ?
C26 C1 C2 Ru1 . . . . -127.5(6) ?
C1 C2 C3 C4 . . . . -2.3(9) ?
Ru1 C2 C3 C4 . . . . -55.6(5) ?
C1 C2 C3 Ru1 . . . . 53.4(5) ?
C2 C3 C4 C5 . . . . 0.6(9) ?
Ru1 C3 C4 C5 . . . . -55.0(5) ?
C2 C3 C4 C25 . . . . -178.5(6) ?
Ru1 C3 C4 C25 . . . . 125.9(6) ?
C2 C3 C4 Ru1 . . . . 55.7(5) ?
C3 C4 C5 C6 . . . . -0.3(9) ?
C25 C4 C5 C6 . . . . 178.8(6) ?
Ru1 C4 C5 C6 . . . . -54.7(5) ?
C3 C4 C5 Ru1 . . . . 54.4(5) ?
C25 C4 C5 Ru1 . . . . -126.5(6) ?
C4 C5 C6 C1 . . . . 1.6(9) ?
Ru1 C5 C6 C1 . . . . -52.4(5) ?
C4 C5 C6 Ru1 . . . . 54.0(5) ?
C2 C1 C6 C5 . . . . -3.1(9) ?
C26 C1 C6 C5 . . . . -179.7(6) ?
Ru1 C1 C6 C5 . . . . 52.5(5) ?
C2 C1 C6 Ru1 . . . . -55.7(5) ?
C26 C1 C6 Ru1 . . . . 127.7(5) ?
C12 C7 C8 C9 . . . . 0.0(9) ?
P1 C7 C8 C9 . . . . 178.9(5) ?
C7 C8 C9 C10 . . . . -1.4(10) ?
C8 C9 C10 O1 . . . . -179.6(6) ?
C8 C9 C10 C11 . . . . 1.1(10) ?
O1 C10 C11 C12 . . . . -178.7(6) ?
C9 C10 C11 C12 . . . . 0.6(10) ?
C10 C11 C12 C7 . . . . -2.1(9) ?
C8 C7 C12 C11 . . . . 1.8(9) ?
P1 C7 C12 C11 . . . . -177.2(5) ?
C18 C13 C14 C15 . . . . -0.1(9) ?
P1 C13 C14 C15 . . . . -171.6(5) ?
C13 C14 C15 C16 . . . . -0.2(10) ?
C14 C15 C16 O2 . . . . 179.8(6) ?
C14 C15 C16 C17 . . . . 0.6(10) ?
O2 C16 C17 C18 . . . . -179.7(6) ?
C15 C16 C17 C18 . . . . -0.6(10) ?
C16 C17 C18 C13 . . . . 0.3(10) ?
C14 C13 C18 C17 . . . . 0.1(9) ?
P1 C13 C18 C17 . . . . 172.2(5) ?
C24 C19 C20 C21 . . . . 0.0(10) ?
P1 C19 C20 C21 . . . . -179.1(5) ?
C19 C20 C21 C22 . . . . 0.2(10) ?
C20 C21 C22 O3 . . . . -179.4(6) ?
C20 C21 C22 C23 . . . . -0.2(10) ?
O3 C22 C23 C24 . . . . 179.2(6) ?
C21 C22 C23 C24 . . . . -0.1(10) ?
C20 C19 C24 C23 . . . . -0.3(10) ?
P1 C19 C24 C23 . . . . 178.9(5) ?
C22 C23 C24 C19 . . . . 0.3(10) ?
C2 C1 C26 C28 . . . . 21.7(8) ?
C6 C1 C26 C28 . . . . -161.8(6) ?
Ru1 C1 C26 C28 . . . . -71.3(8) ?
C2 C1 C26 C27 . . . . -102.3(7) ?
C6 C1 C26 C27 . . . . 74.2(7) ?
Ru1 C1 C26 C27 . . . . 164.7(5) ?
C37 C32 C33 C34 . . . . 5.1(8) ?
C57 C32 C33 C34 . . . . -179.5(5) ?
Ru2 C32 C33 C34 . . . . -51.3(5) ?
C37 C32 C33 Ru2 . . . . 56.4(5) ?
C57 C32 C33 Ru2 . . . . -128.2(5) ?
C32 C33 C34 C35 . . . . -4.2(9) ?
Ru2 C33 C34 C35 . . . . -56.7(5) ?
C32 C33 C34 Ru2 . . . . 52.4(5) ?
C33 C34 C35 C36 . . . . 1.2(9) ?
Ru2 C34 C35 C36 . . . . -55.3(5) ?
C33 C34 C35 C56 . . . . -176.9(6) ?
Ru2 C34 C35 C56 . . . . 126.6(6) ?
C33 C34 C35 Ru2 . . . . 56.6(5) ?
C34 C35 C36 C37 . . . . 0.7(9) ?
C56 C35 C36 C37 . . . . 178.8(6) ?
Ru2 C35 C36 C37 . . . . -53.6(5) ?
C34 C35 C36 Ru2 . . . . 54.3(5) ?
C56 C35 C36 Ru2 . . . . -127.6(6) ?
C35 C36 C37 C32 . . . . 0.4(9) ?
Ru2 C36 C37 C32 . . . . -52.7(5) ?
C35 C36 C37 Ru2 . . . . 53.0(5) ?
C33 C32 C37 C36 . . . . -3.3(9) ?
C57 C32 C37 C36 . . . . -178.8(6) ?
Ru2 C32 C37 C36 . . . . 53.0(5) ?
C33 C32 C37 Ru2 . . . . -56.3(5) ?
C57 C32 C37 Ru2 . . . . 128.2(5) ?
C43 C38 C39 C40 . . . . 0.8(9) ?
P2 C38 C39 C40 . . . . 177.7(5) ?
C38 C39 C40 C41 . . . . -2.0(10) ?
C39 C40 C41 O4 . . . . -179.4(6) ?
C39 C40 C41 C42 . . . . 1.7(10) ?
O4 C41 C42 C43 . . . . -179.1(6) ?
C40 C41 C42 C43 . . . . -0.1(9) ?
C41 C42 C43 C38 . . . . -1.1(9) ?
C39 C38 C43 C42 . . . . 0.8(9) ?
P2 C38 C43 C42 . . . . -176.2(5) ?
C49 C44 C45 C46 . . . . -0.4(10) ?
P2 C44 C45 C46 . . . . -180.0(5) ?
C44 C45 C46 C47 . . . . 0.1(11) ?
C45 C46 C47 O5 . . . . -180.0(6) ?
C45 C46 C47 C48 . . . . 0.4(10) ?
O5 C47 C48 C49 . . . . 179.7(6) ?
C46 C47 C48 C49 . . . . -0.7(10) ?
C47 C48 C49 C44 . . . . 0.4(10) ?
C45 C44 C49 C48 . . . . 0.2(10) ?
P2 C44 C49 C48 . . . . 179.7(5) ?
C55 C50 C51 C52 . . . . -0.2(9) ?
P2 C50 C51 C52 . . . . -172.1(5) ?
C50 C51 C52 C53 . . . . -0.4(10) ?
C51 C52 C53 O6 . . . . 179.9(6) ?
C51 C52 C53 C54 . . . . 0.7(10) ?
O6 C53 C54 C55 . . . . -179.6(6) ?
C52 C53 C54 C55 . . . . -0.5(10) ?
C53 C54 C55 C50 . . . . -0.1(10) ?
C51 C50 C55 C54 . . . . 0.5(9) ?
P2 C50 C55 C54 . . . . 173.0(5) ?
C33 C32 C57 C59 . . . . 22.4(8) ?
C37 C32 C57 C59 . . . . -162.3(6) ?
Ru2 C32 C57 C59 . . . . -70.9(8) ?
C33 C32 C57 C58 . . . . -101.9(7) ?
C37 C32 C57 C58 . . . . 73.4(7) ?
Ru2 C32 C57 C58 . . . . 164.8(5) ?
C8 C7 P1 C19 . . . . 16.9(5) ?
C12 C7 P1 C19 . . . . -164.2(5) ?
C8 C7 P1 C13 . . . . 119.9(5) ?
C12 C7 P1 C13 . . . . -61.2(5) ?
C8 C7 P1 Ru1 . . . . -116.7(4) ?
C12 C7 P1 Ru1 . . . . 62.1(5) ?
C24 C19 P1 C7 . . . . -103.7(6) ?
C20 C19 P1 C7 . . . . 75.4(6) ?
C24 C19 P1 C13 . . . . 149.0(6) ?
C20 C19 P1 C13 . . . . -31.9(6) ?
C24 C19 P1 Ru1 . . . . 26.2(7) ?
C20 C19 P1 Ru1 . . . . -154.7(4) ?
C18 C13 P1 C7 . . . . -177.0(5) ?
C14 C13 P1 C7 . . . . -5.3(6) ?
C18 C13 P1 C19 . . . . -71.0(5) ?
C14 C13 P1 C19 . . . . 100.7(6) ?
C18 C13 P1 Ru1 . . . . 58.0(5) ?
C14 C13 P1 Ru1 . . . . -130.4(5) ?
C39 C38 P2 C44 . . . . 18.3(6) ?
C43 C38 P2 C44 . . . . -164.8(5) ?
C39 C38 P2 C50 . . . . 121.7(5) ?
C43 C38 P2 C50 . . . . -61.4(5) ?
C39 C38 P2 Ru2 . . . . -115.0(5) ?
C43 C38 P2 Ru2 . . . . 61.8(5) ?
C49 C44 P2 C38 . . . . -105.7(6) ?
C45 C44 P2 C38 . . . . 73.8(6) ?
C49 C44 P2 C50 . . . . 145.9(6) ?
C45 C44 P2 C50 . . . . -34.6(6) ?
C49 C44 P2 Ru2 . . . . 23.7(7) ?
C45 C44 P2 Ru2 . . . . -156.8(4) ?
C55 C50 P2 C38 . . . . -177.2(5) ?
C51 C50 P2 C38 . . . . -5.1(6) ?
C55 C50 P2 C44 . . . . -71.5(5) ?
C51 C50 P2 C44 . . . . 100.5(6) ?
C55 C50 P2 Ru2 . . . . 57.5(5) ?
C51 C50 P2 Ru2 . . . . -130.5(5) ?
C4 C3 Ru1 C2 . . . . 133.0(5) ?
C2 C3 Ru1 C4 . . . . -133.0(5) ?
C2 C3 Ru1 C5 . . . . -102.3(4) ?
C4 C3 Ru1 C5 . . . . 30.7(4) ?
C2 C3 Ru1 C1 . . . . -28.6(3) ?
C4 C3 Ru1 C1 . . . . 104.4(4) ?
C2 C3 Ru1 C6 . . . . -66.0(4) ?
C4 C3 Ru1 C6 . . . . 67.0(4) ?
C2 C3 Ru1 P1 . . . . 99.5(3) ?
C4 C3 Ru1 P1 . . . . -127.6(3) ?
C2 C3 Ru1 Cl2 . . . . -173.2(3) ?
C4 C3 Ru1 Cl2 . . . . -40.2(4) ?
C2 C3 Ru1 Cl1 . . . . 9.4(6) ?
C4 C3 Ru1 Cl1 . . . . 142.4(3) ?
C1 C2 Ru1 C3 . . . . -133.0(5) ?
C3 C2 Ru1 C4 . . . . 28.7(4) ?
C1 C2 Ru1 C4 . . . . -104.3(4) ?
C3 C2 Ru1 C5 . . . . 66.4(4) ?
C1 C2 Ru1 C5 . . . . -66.7(4) ?
C3 C2 Ru1 C1 . . . . 133.0(5) ?
C3 C2 Ru1 C6 . . . . 102.4(4) ?
C1 C2 Ru1 C6 . . . . -30.6(4) ?
C3 C2 Ru1 P1 . . . . -83.9(3) ?
C1 C2 Ru1 P1 . . . . 143.1(3) ?
C3 C2 Ru1 Cl2 . . . . 16.1(7) ?
C1 C2 Ru1 Cl2 . . . . -116.9(5) ?
C3 C2 Ru1 Cl1 . . . . -174.8(3) ?
C1 C2 Ru1 Cl1 . . . . 52.1(4) ?
C5 C4 Ru1 C3 . . . . 129.8(5) ?
C25 C4 Ru1 C3 . . . . -116.1(8) ?
C3 C4 Ru1 C2 . . . . -28.6(3) ?
C5 C4 Ru1 C2 . . . . 101.2(4) ?
C25 C4 Ru1 C2 . . . . -144.8(8) ?
C3 C4 Ru1 C5 . . . . -129.8(5) ?
C25 C4 Ru1 C5 . . . . 114.0(8) ?
C3 C4 Ru1 C1 . . . . -65.1(4) ?
C5 C4 Ru1 C1 . . . . 64.8(4) ?
C25 C4 Ru1 C1 . . . . 178.8(7) ?
C3 C4 Ru1 C6 . . . . -101.6(4) ?
C5 C4 Ru1 C6 . . . . 28.2(4) ?
C25 C4 Ru1 C6 . . . . 142.3(8) ?
C3 C4 Ru1 P1 . . . . 59.9(4) ?
C5 C4 Ru1 P1 . . . . -170.3(3) ?
C25 C4 Ru1 P1 . . . . -56.3(7) ?
C3 C4 Ru1 Cl2 . . . . 146.8(3) ?
C5 C4 Ru1 Cl2 . . . . -83.3(3) ?
C25 C4 Ru1 Cl2 . . . . 30.7(7) ?
C3 C4 Ru1 Cl1 . . . . -122.8(5) ?
C5 C4 Ru1 Cl1 . . . . 7.1(7) ?
C25 C4 Ru1 Cl1 . . . . 121.1(6) ?
C6 C5 Ru1 C3 . . . . 102.4(4) ?
C4 C5 Ru1 C3 . . . . -30.4(4) ?
C6 C5 Ru1 C2 . . . . 65.3(4) ?
C4 C5 Ru1 C2 . . . . -67.5(4) ?
C6 C5 Ru1 C4 . . . . 132.8(6) ?
C6 C5 Ru1 C1 . . . . 28.3(4) ?
C4 C5 Ru1 C1 . . . . -104.5(4) ?
C4 C5 Ru1 C6 . . . . -132.8(6) ?
C6 C5 Ru1 P1 . . . . 151.0(3) ?
C4 C5 Ru1 P1 . . . . 18.2(6) ?
C6 C5 Ru1 Cl2 . . . . -130.8(4) ?
C4 C5 Ru1 Cl2 . . . . 96.4(3) ?
C6 C5 Ru1 Cl1 . . . . -44.1(4) ?
C4 C5 Ru1 Cl1 . . . . -177.0(3) ?
C2 C1 Ru1 C3 . . . . 28.7(4) ?
C6 C1 Ru1 C3 . . . . -101.1(4) ?
C26 C1 Ru1 C3 . . . . 146.1(7) ?
C6 C1 Ru1 C2 . . . . -129.8(5) ?
C26 C1 Ru1 C2 . . . . 117.5(7) ?
C2 C1 Ru1 C4 . . . . 65.2(4) ?
C6 C1 Ru1 C4 . . . . -64.6(4) ?
C26 C1 Ru1 C4 . . . . -177.3(6) ?
C2 C1 Ru1 C5 . . . . 102.1(4) ?
C6 C1 Ru1 C5 . . . . -27.7(4) ?
C26 C1 Ru1 C5 . . . . -140.5(7) ?
C2 C1 Ru1 C6 . . . . 129.8(5) ?
C26 C1 Ru1 C6 . . . . -112.8(7) ?
C2 C1 Ru1 P1 . . . . -47.1(4) ?
C6 C1 Ru1 P1 . . . . -176.9(3) ?
C26 C1 Ru1 P1 . . . . 70.3(6) ?
C2 C1 Ru1 Cl2 . . . . 143.4(3) ?
C6 C1 Ru1 Cl2 . . . . 13.6(5) ?
C26 C1 Ru1 Cl2 . . . . -99.1(6) ?
C2 C1 Ru1 Cl1 . . . . -133.0(4) ?
C6 C1 Ru1 Cl1 . . . . 97.2(3) ?
C26 C1 Ru1 Cl1 . . . . -15.6(6) ?
C5 C6 Ru1 C3 . . . . -66.4(4) ?
C1 C6 Ru1 C3 . . . . 67.5(4) ?
C5 C6 Ru1 C2 . . . . -103.5(4) ?
C1 C6 Ru1 C2 . . . . 30.4(4) ?
C5 C6 Ru1 C4 . . . . -29.1(4) ?
C1 C6 Ru1 C4 . . . . 104.8(4) ?
C1 C6 Ru1 C5 . . . . 134.0(6) ?
C5 C6 Ru1 C1 . . . . -134.0(6) ?
C5 C6 Ru1 P1 . . . . -125.4(5) ?
C1 C6 Ru1 P1 . . . . 8.6(8) ?
C5 C6 Ru1 Cl2 . . . . 53.9(4) ?
C1 C6 Ru1 Cl2 . . . . -172.2(3) ?
C5 C6 Ru1 Cl1 . . . . 143.2(4) ?
C1 C6 Ru1 Cl1 . . . . -82.9(3) ?
C7 P1 Ru1 C3 . . . . -80.9(3) ?
C19 P1 Ru1 C3 . . . . 154.6(3) ?
C13 P1 Ru1 C3 . . . . 38.2(3) ?
C7 P1 Ru1 C2 . . . . -43.8(3) ?
C19 P1 Ru1 C2 . . . . -168.4(3) ?
C13 P1 Ru1 C2 . . . . 75.3(3) ?
C7 P1 Ru1 C4 . . . . -112.6(3) ?
C19 P1 Ru1 C4 . . . . 122.9(3) ?
C13 P1 Ru1 C4 . . . . 6.6(3) ?
C7 P1 Ru1 C5 . . . . -124.6(4) ?
C19 P1 Ru1 C5 . . . . 110.9(4) ?
C13 P1 Ru1 C5 . . . . -5.4(4) ?
C7 P1 Ru1 C1 . . . . -17.3(3) ?
C19 P1 Ru1 C1 . . . . -141.8(3) ?
C13 P1 Ru1 C1 . . . . 101.8(3) ?
C7 P1 Ru1 C6 . . . . -23.7(6) ?
C19 P1 Ru1 C6 . . . . -148.2(6) ?
C13 P1 Ru1 C6 . . . . 95.4(6) ?
C7 P1 Ru1 Cl2 . . . . 157.0(2) ?
C19 P1 Ru1 Cl2 . . . . 32.5(2) ?
C13 P1 Ru1 Cl2 . . . . -83.8(2) ?
C7 P1 Ru1 Cl1 . . . . 68.4(2) ?
C19 P1 Ru1 Cl1 . . . . -56.1(2) ?
C13 P1 Ru1 Cl1 . . . . -172.4(2) ?
C33 C34 Ru2 C35 . . . . -132.3(5) ?
C35 C34 Ru2 C33 . . . . 132.3(5) ?
C35 C34 Ru2 C32 . . . . 104.3(4) ?
C33 C34 Ru2 C32 . . . . -28.0(3) ?
C35 C34 Ru2 C36 . . . . 30.9(3) ?
C33 C34 Ru2 C36 . . . . -101.4(4) ?
C35 C34 Ru2 C37 . . . . 66.9(4) ?
C33 C34 Ru2 C37 . . . . -65.4(4) ?
C35 C34 Ru2 P2 . . . . -127.8(3) ?
C33 C34 Ru2 P2 . . . . 99.9(3) ?
C35 C34 Ru2 Cl4 . . . . -40.8(4) ?
C33 C34 Ru2 Cl4 . . . . -173.1(3) ?
C35 C34 Ru2 Cl3 . . . . 141.4(3) ?
C33 C34 Ru2 Cl3 . . . . 9.1(6) ?
C36 C35 Ru2 C34 . . . . 129.5(5) ?
C56 C35 Ru2 C34 . . . . -116.0(8) ?
C34 C35 Ru2 C33 . . . . -29.5(3) ?
C36 C35 Ru2 C33 . . . . 100.0(4) ?
C56 C35 Ru2 C33 . . . . -145.5(7) ?
C34 C35 Ru2 C32 . . . . -65.5(4) ?
C36 C35 Ru2 C32 . . . . 64.0(4) ?
C56 C35 Ru2 C32 . . . . 178.5(7) ?
C34 C35 Ru2 C36 . . . . -129.5(5) ?
C56 C35 Ru2 C36 . . . . 114.5(8) ?
C34 C35 Ru2 C37 . . . . -101.8(4) ?
C36 C35 Ru2 C37 . . . . 27.7(4) ?
C56 C35 Ru2 C37 . . . . 142.3(7) ?
C34 C35 Ru2 P2 . . . . 59.8(3) ?
C36 C35 Ru2 P2 . . . . -170.7(3) ?
C56 C35 Ru2 P2 . . . . -56.2(7) ?
C34 C35 Ru2 Cl4 . . . . 146.1(3) ?
C36 C35 Ru2 Cl4 . . . . -84.4(3) ?
C56 C35 Ru2 Cl4 . . . . 30.2(6) ?
C34 C35 Ru2 Cl3 . . . . -123.5(4) ?
C36 C35 Ru2 Cl3 . . . . 6.0(7) ?
C56 C35 Ru2 Cl3 . . . . 120.5(6) ?
C32 C33 Ru2 C34 . . . . -133.4(6) ?
C32 C33 Ru2 C35 . . . . -104.5(4) ?
C34 C33 Ru2 C35 . . . . 28.9(4) ?
C34 C33 Ru2 C32 . . . . 133.4(6) ?
C32 C33 Ru2 C36 . . . . -66.7(4) ?
C34 C33 Ru2 C36 . . . . 66.7(4) ?
C32 C33 Ru2 C37 . . . . -30.8(4) ?
C34 C33 Ru2 C37 . . . . 102.6(4) ?
C32 C33 Ru2 P2 . . . . 142.9(3) ?
C34 C33 Ru2 P2 . . . . -83.7(3) ?
C32 C33 Ru2 Cl4 . . . . -116.8(5) ?
C34 C33 Ru2 Cl4 . . . . 16.6(7) ?
C32 C33 Ru2 Cl3 . . . . 51.5(4) ?
C34 C33 Ru2 Cl3 . . . . -175.1(3) ?
C33 C32 Ru2 C34 . . . . 28.9(4) ?
C37 C32 Ru2 C34 . . . . -100.6(4) ?
C57 C32 Ru2 C34 . . . . 145.6(7) ?
C33 C32 Ru2 C35 . . . . 65.5(4) ?
C37 C32 Ru2 C35 . . . . -64.1(4) ?
C57 C32 Ru2 C35 . . . . -177.9(6) ?
C37 C32 Ru2 C33 . . . . -129.5(6) ?
C57 C32 Ru2 C33 . . . . 116.6(8) ?
C33 C32 Ru2 C36 . . . . 102.0(4) ?
C37 C32 Ru2 C36 . . . . -27.5(4) ?
C57 C32 Ru2 C36 . . . . -141.3(7) ?
C33 C32 Ru2 C37 . . . . 129.5(6) ?
C57 C32 Ru2 C37 . . . . -113.9(7) ?
C33 C32 Ru2 P2 . . . . -47.5(4) ?
C37 C32 Ru2 P2 . . . . -177.0(3) ?
C57 C32 Ru2 P2 . . . . 69.1(6) ?
C33 C32 Ru2 Cl4 . . . . 143.5(3) ?
C37 C32 Ru2 Cl4 . . . . 14.0(5) ?
C57 C32 Ru2 Cl4 . . . . -99.9(6) ?
C33 C32 Ru2 Cl3 . . . . -133.3(4) ?
C37 C32 Ru2 Cl3 . . . . 97.2(3) ?
C57 C32 Ru2 Cl3 . . . . -16.6(6) ?
C37 C36 Ru2 C34 . . . . 103.0(4) ?
C35 C36 Ru2 C34 . . . . -30.6(3) ?
C37 C36 Ru2 C35 . . . . 133.6(6) ?
C37 C36 Ru2 C33 . . . . 64.9(4) ?
C35 C36 Ru2 C33 . . . . -68.7(4) ?
C37 C36 Ru2 C32 . . . . 28.2(4) ?
C35 C36 Ru2 C32 . . . . -105.4(4) ?
C35 C36 Ru2 C37 . . . . -133.6(6) ?
C37 C36 Ru2 P2 . . . . 151.2(3) ?
C35 C36 Ru2 P2 . . . . 17.6(6) ?
C37 C36 Ru2 Cl4 . . . . -131.0(4) ?
C35 C36 Ru2 Cl4 . . . . 95.4(3) ?
C37 C36 Ru2 Cl3 . . . . -43.8(4) ?
C35 C36 Ru2 Cl3 . . . . -177.4(3) ?
C36 C37 Ru2 C34 . . . . -65.9(4) ?
C32 C37 Ru2 C34 . . . . 68.3(4) ?
C36 C37 Ru2 C35 . . . . -28.7(4) ?
C32 C37 Ru2 C35 . . . . 105.5(4) ?
C36 C37 Ru2 C33 . . . . -103.8(4) ?
C32 C37 Ru2 C33 . . . . 30.4(4) ?
C36 C37 Ru2 C32 . . . . -134.2(6) ?
C32 C37 Ru2 C36 . . . . 134.2(6) ?
C36 C37 Ru2 P2 . . . . -125.9(6) ?
C32 C37 Ru2 P2 . . . . 8.3(8) ?
C36 C37 Ru2 Cl4 . . . . 53.8(4) ?
C32 C37 Ru2 Cl4 . . . . -172.0(3) ?
C36 C37 Ru2 Cl3 . . . . 143.3(4) ?
C32 C37 Ru2 Cl3 . . . . -82.5(3) ?
C38 P2 Ru2 C34 . . . . -80.6(3) ?
C44 P2 Ru2 C34 . . . . 155.7(3) ?
C50 P2 Ru2 C34 . . . . 39.5(3) ?
C38 P2 Ru2 C35 . . . . -112.2(3) ?
C44 P2 Ru2 C35 . . . . 124.1(3) ?
C50 P2 Ru2 C35 . . . . 7.9(3) ?
C38 P2 Ru2 C33 . . . . -42.7(3) ?
C44 P2 Ru2 C33 . . . . -166.4(3) ?
C50 P2 Ru2 C33 . . . . 77.4(3) ?
C38 P2 Ru2 C32 . . . . -16.1(3) ?
C44 P2 Ru2 C32 . . . . -139.9(3) ?
C50 P2 Ru2 C32 . . . . 104.0(3) ?
C38 P2 Ru2 C36 . . . . -123.8(4) ?
C44 P2 Ru2 C36 . . . . 112.4(4) ?
C50 P2 Ru2 C36 . . . . -3.7(4) ?
C38 P2 Ru2 C37 . . . . -22.3(6) ?
C44 P2 Ru2 C37 . . . . -146.1(6) ?
C50 P2 Ru2 C37 . . . . 97.8(6) ?
C38 P2 Ru2 Cl4 . . . . 158.0(2) ?
C44 P2 Ru2 Cl4 . . . . 34.2(2) ?
C50 P2 Ru2 Cl4 . . . . -81.9(2) ?
C38 P2 Ru2 Cl3 . . . . 69.1(2) ?
C44 P2 Ru2 Cl3 . . . . -54.7(2) ?
C50 P2 Ru2 Cl3 . . . . -170.8(2) ?
C9 C10 O1 C29 . . . . -4.5(11) ?
C11 C10 O1 C29 . . . . 174.9(7) ?
C15 C16 O2 C30 . . . . 175.7(6) ?
C17 C16 O2 C30 . . . . -5.1(10) ?
C21 C22 O3 C31 . . . . 1.0(10) ?
C23 C22 O3 C31 . . . . -178.3(6) ?
C42 C41 O4 C60 . . . . 174.0(7) ?
C40 C41 O4 C60 . . . . -4.9(11) ?
C46 C47 O5 C61 . . . . 3.3(10) ?
C48 C47 O5 C61 . . . . -177.1(6) ?
C52 C53 O6 C62 . . . . 174.5(6) ?
C54 C53 O6 C62 . . . . -6.3(10) ?
