#------------------------------------------------------------------------------
#$Date: 2022-03-16 01:17:35 +0200 (Wed, 16 Mar 2022) $
#$Revision: 273706 $
#$URL: file:///home/coder/svn-repositories/cod/cif/1/56/66/1566617.cif $
#------------------------------------------------------------------------------
#
# This file is available in the Crystallography Open Database (COD),
# http://www.crystallography.net/
#
# All data on this site have been placed in the public domain by the
# contributors.
#
data_1566617
loop_
_publ_author_name
'Shimamoto, Kento'
'Sunada, Yusuke'
_publ_section_title
;
 Metalation-Induced Denitrogenative Reductive Coupling of Isocyanides on a
 Silylene-Bridged Nickel Cluster
;
_journal_name_full               'Chemical Science'
_journal_paper_doi               10.1039/D1SC06935G
_journal_year                    2022
_chemical_formula_moiety         'C73 H85 N5 Ni2 Si4'
_chemical_formula_sum            'C73 H85 N5 Ni2 Si4'
_chemical_formula_weight         1262.25
_space_group_crystal_system      triclinic
_space_group_IT_number           2
_space_group_name_Hall           '-P 1'
_space_group_name_H-M_alt        'P -1'
_atom_sites_solution_hydrogens   geom
_atom_sites_solution_primary     direct
_atom_sites_solution_secondary   difmap
_audit_update_record
;
2021-11-08 deposited with the CCDC.	2022-03-14 downloaded from the CCDC.
;
_cell_angle_alpha                97.750(7)
_cell_angle_beta                 95.438(7)
_cell_angle_gamma                102.855(7)
_cell_formula_units_Z            4
_cell_length_a                   14.392(12)
_cell_length_b                   22.272(19)
_cell_length_c                   22.510(19)
_cell_measurement_reflns_used    2309
_cell_measurement_temperature    100
_cell_measurement_theta_max      17.82
_cell_measurement_theta_min      4.31
_cell_volume                     6912(10)
_computing_cell_refinement       'RAPID AUTO'
_computing_data_collection       'RAPID AUTO (Rigaku, ????)'
_computing_data_reduction        'RAPID AUTO'
_computing_molecular_graphics    'CrystalStructure 4.3'
_computing_publication_material  'CrystalStructure 4.3 (Rigaku, 2018)'
_computing_structure_refinement  'SHELXL Version 2017/1 (Sheldrick, 2008)'
_computing_structure_solution    'SHELXT Version 2014/5 (Sheldrick, 2014)'
_diffrn_ambient_temperature      100
_diffrn_detector_area_resol_mean 5.814
_diffrn_measured_fraction_theta_full 0.997
_diffrn_measured_fraction_theta_max 0.773
_diffrn_measurement_device_type  'Rigaku R-AXIS IV'
_diffrn_measurement_method       ω
_diffrn_radiation_type           synchrotron
_diffrn_radiation_wavelength     0.41500
_diffrn_reflns_av_R_equivalents  0.1469
_diffrn_reflns_av_unetI/netI     0.1226
_diffrn_reflns_Laue_measured_fraction_full 0.997
_diffrn_reflns_Laue_measured_fraction_max 0.773
_diffrn_reflns_limit_h_max       26
_diffrn_reflns_limit_h_min       -25
_diffrn_reflns_limit_k_max       37
_diffrn_reflns_limit_k_min       -38
_diffrn_reflns_limit_l_max       38
_diffrn_reflns_limit_l_min       -38
_diffrn_reflns_number            282646
_diffrn_reflns_point_group_measured_fraction_full 0.997
_diffrn_reflns_point_group_measured_fraction_max 0.773
_diffrn_reflns_theta_full        14.418
_diffrn_reflns_theta_max         22.231
_diffrn_reflns_theta_min         0.949
_diffrn_standards_number         0
_exptl_absorpt_coefficient_mu    0.000
_exptl_absorpt_correction_T_max  1.000
_exptl_absorpt_correction_T_min  0.374
_exptl_absorpt_correction_type   multi-scan
_exptl_absorpt_process_details   'ABSCOR (Rigaku, 1995)'
_exptl_crystal_colour            lightbrown
_exptl_crystal_density_diffrn    1.213
_exptl_crystal_density_method    'not measured'
_exptl_crystal_description       block
_exptl_crystal_F_000             2680.00
_exptl_crystal_size_max          0.080
_exptl_crystal_size_mid          0.080
_exptl_crystal_size_min          0.060
_refine_diff_density_max         1.36
_refine_diff_density_min         -1.12
_refine_ls_extinction_method     none
_refine_ls_goodness_of_fit_ref   0.969
_refine_ls_hydrogen_treatment    constr
_refine_ls_number_parameters     1542
_refine_ls_number_reflns         67846
_refine_ls_number_restraints     0
_refine_ls_R_factor_all          0.1753
_refine_ls_R_factor_gt           0.0786
_refine_ls_shift/su_max          0.002
_refine_ls_structure_factor_coef Fsqd
_refine_ls_weighting_details
'w = 1/[σ²(Fo²)+(0.1152P)²] where P=(Fo²+2Fc²)/3'
_refine_ls_weighting_scheme      calc
_refine_ls_wR_factor_gt          0.2009
_refine_ls_wR_factor_ref         0.2544
_reflns_Friedel_coverage         0.000
_reflns_number_gt                29903
_reflns_number_total             67846
_reflns_threshold_expression     F²>2.0σ(F²)
_cod_data_source_file            d1sc06935g2.cif
_cod_data_source_block           Ni2(SiPh2)4C(CNtBu)4(NtBu)
_cod_database_code               1566617
loop_
_space_group_symop_id
_space_group_symop_operation_xyz
1 +X,+Y,+Z
2 -X,-Y,-Z
loop_
_atom_site_label
_atom_site_type_symbol
_atom_site_fract_x
_atom_site_fract_y
_atom_site_fract_z
_atom_site_U_iso_or_equiv
_atom_site_adp_type
_atom_site_occupancy
_atom_site_site_symmetry_order
_atom_site_calc_flag
_atom_site_refinement_flags_posn
_atom_site_refinement_flags_adp
_atom_site_refinement_flags_occupancy
_atom_site_disorder_assembly
_atom_site_disorder_group
Ni1 Ni 0.50021(2) 0.68428(2) 0.78836(2) 0.03224(7) Uani 1 1 d . . . . .
Ni2 Ni 0.42053(3) 0.69257(2) 0.69109(2) 0.03625(8) Uani 1 1 d . . . . .
Ni3 Ni 0.93734(3) 0.18490(2) 0.78227(2) 0.03626(8) Uani 1 1 d . . . . .
Ni4 Ni 0.88210(2) 0.28040(2) 0.77444(2) 0.03661(8) Uani 1 1 d . . . . .
Si1 Si 0.68656(6) 0.61580(4) 0.80872(4) 0.03708(16) Uani 1 1 d . . . . .
Si2 Si 0.72334(6) 0.72889(4) 0.80040(4) 0.04100(18) Uani 1 1 d . . . . .
Si3 Si 0.54408(6) 0.63582(4) 0.69742(3) 0.03434(15) Uani 1 1 d . . . . .
Si4 Si 0.29756(6) 0.73408(4) 0.70823(3) 0.04082(17) Uani 1 1 d . . . . .
Si5 Si 1.10420(6) 0.13831(4) 0.69968(3) 0.03611(15) Uani 1 1 d . . . . .
Si6 Si 0.92997(6) 0.11498(4) 0.65997(4) 0.04230(18) Uani 1 1 d . . . . .
Si7 Si 1.01554(6) 0.26217(4) 0.72682(3) 0.03425(15) Uani 1 1 d . . . . .
Si8 Si 0.79822(6) 0.29646(4) 0.84963(4) 0.04203(18) Uani 1 1 d . . . . .
N1 N 0.77458(17) 0.68192(12) 0.84099(13) 0.0437(5) Uani 1 1 d . . . . .
N2 N 0.51795(16) 0.69717(11) 0.92063(10) 0.0364(5) Uani 1 1 d . . . . .
N3 N 0.30976(19) 0.71873(14) 0.78213(11) 0.0460(6) Uani 1 1 d . . . . .
N4 N 0.3070(2) 0.59503(14) 0.59202(12) 0.0530(7) Uani 1 1 d . . . . .
N5 N 0.5267(3) 0.79137(13) 0.63137(12) 0.0571(8) Uani 1 1 d . . . . .
N6 N 1.02066(19) 0.07621(12) 0.65761(11) 0.0425(5) Uani 1 1 d . . . . .
N7 N 0.9662(2) 0.08057(14) 0.84277(15) 0.0606(8) Uani 1 1 d . . . . .
N8 N 0.81098(18) 0.22548(13) 0.87042(11) 0.0431(5) Uani 1 1 d . . . . .
N9 N 0.99023(18) 0.41134(12) 0.78728(11) 0.0414(5) Uani 1 1 d . . . . .
N10 N 0.7296(2) 0.26199(17) 0.66993(13) 0.0617(8) Uani 1 1 d . . . . .
C1 C 0.7309(2) 0.55724(14) 0.75887(14) 0.0416(6) Uani 1 1 d . . . . .
C2 C 0.7260(2) 0.49742(15) 0.76935(15) 0.0466(7) Uani 1 1 d . . . . .
H2 H 0.701632 0.485414 0.803868 0.056 Uiso 1 1 calc R U . . .
C3 C 0.7561(3) 0.45471(16) 0.73055(16) 0.0545(8) Uani 1 1 d . . . . .
H3 H 0.753027 0.414796 0.739468 0.065 Uiso 1 1 calc R U . . .
C4 C 0.7900(2) 0.47055(17) 0.67940(17) 0.0545(8) Uani 1 1 d . . . . .
H4 H 0.810134 0.441593 0.653014 0.065 Uiso 1 1 calc R U . . .
C5 C 0.7945(2) 0.52877(17) 0.66684(17) 0.0531(8) Uani 1 1 d . . . . .
H5 H 0.816829 0.539698 0.631397 0.064 Uiso 1 1 calc R U . . .
C6 C 0.7661(2) 0.57197(15) 0.70658(16) 0.0478(7) Uani 1 1 d . . . . .
H6 H 0.770865 0.612079 0.697779 0.057 Uiso 1 1 calc R U . . .
C7 C 0.6226(2) 0.56833(13) 0.86094(13) 0.0393(6) Uani 1 1 d . . . . .
C8 C 0.5236(2) 0.55117(13) 0.85227(13) 0.0407(6) Uani 1 1 d . . . . .
H8 H 0.490482 0.567686 0.823533 0.049 Uiso 1 1 calc R U . . .
C9 C 0.4728(3) 0.51075(15) 0.88449(14) 0.0471(7) Uani 1 1 d . . . . .
H9 H 0.406004 0.499500 0.877264 0.056 Uiso 1 1 calc R U . . .
C10 C 0.5205(3) 0.48684(16) 0.92748(15) 0.0560(9) Uani 1 1 d . . . . .
H10 H 0.486097 0.459379 0.949742 0.067 Uiso 1 1 calc R U . . .
C11 C 0.6170(3) 0.50299(15) 0.93762(15) 0.0549(8) Uani 1 1 d . . . . .
H11 H 0.649087 0.486675 0.967021 0.066 Uiso 1 1 calc R U . . .
C12 C 0.6689(3) 0.54350(15) 0.90486(14) 0.0476(7) Uani 1 1 d . . . . .
H12 H 0.735653 0.554243 0.912338 0.057 Uiso 1 1 calc R U . . .
C13 C 0.8068(3) 0.76550(15) 0.7501(2) 0.0601(10) Uani 1 1 d . . . . .
C14 C 0.8762(3) 0.73716(18) 0.7295(2) 0.0742(14) Uani 1 1 d . . . . .
H14 H 0.884099 0.701027 0.743651 0.089 Uiso 1 1 calc R U . . .
C15 C 0.9336(4) 0.7604(2) 0.6891(3) 0.111(2) Uani 1 1 d . . . . .
H15 H 0.981255 0.741060 0.677163 0.133 Uiso 1 1 calc R U . . .
C16 C 0.9212(5) 0.8117(2) 0.6662(4) 0.147(4) Uani 1 1 d . . . . .
H16 H 0.959415 0.826913 0.637892 0.176 Uiso 1 1 calc R U . . .
C17 C 0.8517(5) 0.8417(2) 0.6849(3) 0.119(3) Uani 1 1 d . . . . .
H17 H 0.842390 0.876680 0.668986 0.143 Uiso 1 1 calc R U . . .
C18 C 0.7972(4) 0.81910(17) 0.7270(2) 0.0804(15) Uani 1 1 d . . . . .
H18 H 0.752162 0.840047 0.740606 0.096 Uiso 1 1 calc R U . . .
C19 C 0.6899(2) 0.79609(13) 0.84460(15) 0.0423(6) Uani 1 1 d . . . . .
C20 C 0.7284(2) 0.82055(16) 0.90410(16) 0.0492(7) Uani 1 1 d . . . . .
H20 H 0.772115 0.802186 0.923543 0.059 Uiso 1 1 calc R U . . .
C21 C 0.7041(3) 0.87080(17) 0.93499(18) 0.0565(8) Uani 1 1 d . . . . .
H21 H 0.732092 0.886507 0.974612 0.068 Uiso 1 1 calc R U . . .
C22 C 0.6400(3) 0.89758(16) 0.90832(18) 0.0566(8) Uani 1 1 d . . . . .
H22 H 0.622521 0.931269 0.929544 0.068 Uiso 1 1 calc R U . . .
C23 C 0.6006(3) 0.87482(17) 0.84956(18) 0.0560(8) Uani 1 1 d . . . . .
H23 H 0.557206 0.893754 0.830616 0.067 Uiso 1 1 calc R U . . .
C24 C 0.6246(2) 0.82448(15) 0.81855(16) 0.0469(7) Uani 1 1 d . . . . .
H24 H 0.596061 0.809136 0.778978 0.056 Uiso 1 1 calc R U . . .
C25 C 0.4842(2) 0.55100(13) 0.68951(11) 0.0353(5) Uani 1 1 d . . . . .
C26 C 0.5247(2) 0.50481(14) 0.66384(13) 0.0400(6) Uani 1 1 d . . . . .
H26 H 0.584000 0.516080 0.649946 0.048 Uiso 1 1 calc R U . . .
C27 C 0.4804(2) 0.44315(14) 0.65822(15) 0.0465(7) Uani 1 1 d . . . . .
H27 H 0.510021 0.413092 0.641202 0.056 Uiso 1 1 calc R U . . .
C28 C 0.3927(3) 0.42530(15) 0.67747(15) 0.0495(7) Uani 1 1 d . . . . .
H28 H 0.361886 0.383240 0.672766 0.059 Uiso 1 1 calc R U . . .
C29 C 0.3509(2) 0.46925(15) 0.70348(15) 0.0456(7) Uani 1 1 d . . . . .
H29 H 0.291946 0.457304 0.717585 0.055 Uiso 1 1 calc R U . . .
C30 C 0.3954(2) 0.53126(14) 0.70901(12) 0.0390(6) Uani 1 1 d . . . . .
H30 H 0.365234 0.560910 0.726258 0.047 Uiso 1 1 calc R U . . .
C31 C 0.5924(2) 0.64124(14) 0.62335(14) 0.0450(7) Uani 1 1 d . . . . .
C32 C 0.5426(3) 0.60372(18) 0.57199(15) 0.0563(9) Uani 1 1 d . . . . .
H32 H 0.484820 0.576350 0.575103 0.068 Uiso 1 1 calc R U . . .
C33 C 0.5728(4) 0.6041(2) 0.51644(17) 0.0707(12) Uani 1 1 d . . . . .
H33 H 0.536612 0.577525 0.482712 0.085 Uiso 1 1 calc R U . . .
C34 C 0.6579(4) 0.6447(2) 0.5113(2) 0.0827(16) Uani 1 1 d . . . . .
H34 H 0.679360 0.646138 0.473683 0.099 Uiso 1 1 calc R U . . .
C35 C 0.7104(4) 0.6826(2) 0.5610(2) 0.0849(16) Uani 1 1 d . . . . .
H35 H 0.768499 0.709440 0.557527 0.102 Uiso 1 1 calc R U . . .
C36 C 0.6778(3) 0.68156(17) 0.61749(19) 0.0627(10) Uani 1 1 d . . . . .
H36 H 0.713784 0.708164 0.651281 0.075 Uiso 1 1 calc R U . . .
C37 C 0.1779(2) 0.69356(16) 0.66892(13) 0.0451(7) Uani 1 1 d . . . . .
C38 C 0.1172(3) 0.6479(2) 0.69138(18) 0.0644(10) Uani 1 1 d . . . . .
H38 H 0.137186 0.636816 0.727993 0.077 Uiso 1 1 calc R U . . .
C39 C 0.0289(3) 0.6185(2) 0.6619(2) 0.0710(11) Uani 1 1 d . . . . .
H39 H -0.010904 0.588157 0.678683 0.085 Uiso 1 1 calc R U . . .
C40 C -0.0017(3) 0.63312(19) 0.60789(16) 0.0566(8) Uani 1 1 d . . . . .
H40 H -0.062546 0.613384 0.587802 0.068 Uiso 1 1 calc R U . . .
C41 C 0.0570(3) 0.67634(18) 0.58397(15) 0.0556(8) Uani 1 1 d . . . . .
H41 H 0.037344 0.686002 0.546601 0.067 Uiso 1 1 calc R U . . .
C42 C 0.1451(3) 0.70614(17) 0.61393(14) 0.0503(7) Uani 1 1 d . . . . .
H42 H 0.184421 0.736115 0.596509 0.060 Uiso 1 1 calc R U . . .
C43 C 0.3117(3) 0.81948(17) 0.71182(13) 0.0496(7) Uani 1 1 d . . . . .
C44 C 0.2358(4) 0.8452(2) 0.6996(2) 0.0973(19) Uani 1 1 d . . . . .
H44 H 0.173588 0.820244 0.690963 0.117 Uiso 1 1 calc R U . . .
C45 C 0.2526(6) 0.9096(3) 0.7003(3) 0.134(3) Uani 1 1 d . . . . .
H45 H 0.201089 0.927216 0.691560 0.161 Uiso 1 1 calc R U . . .
C46 C 0.3430(6) 0.9470(2) 0.7136(2) 0.102(2) Uani 1 1 d . . . . .
H46 H 0.354540 0.989292 0.711018 0.122 Uiso 1 1 calc R U . . .
C47 C 0.4146(5) 0.9214(2) 0.7303(3) 0.0981(18) Uani 1 1 d . . . . .
H47 H 0.475562 0.946672 0.744048 0.118 Uiso 1 1 calc R U . . .
C48 C 0.3992(3) 0.85898(19) 0.7275(2) 0.0714(11) Uani 1 1 d . . . . .
H48 H 0.451569 0.842336 0.736839 0.086 Uiso 1 1 calc R U . . .
C49 C 0.62419(19) 0.66285(13) 0.76716(12) 0.0353(5) Uani 1 1 d . . . . .
C50 C 0.8638(2) 0.69145(17) 0.88211(19) 0.0561(9) Uani 1 1 d . . . . .
C51 C 0.8435(3) 0.69127(18) 0.94641(18) 0.0588(9) Uani 1 1 d . . . . .
H51A H 0.902764 0.697564 0.972479 0.071 Uiso 1 1 calc R U . . .
H51B H 0.812554 0.724219 0.958126 0.071 Uiso 1 1 calc R U . . .
H51C H 0.802147 0.651901 0.949685 0.071 Uiso 1 1 calc R U . . .
C52 C 0.9127(3) 0.63909(19) 0.8642(2) 0.0657(11) Uani 1 1 d . . . . .
H52A H 0.971171 0.645034 0.890911 0.079 Uiso 1 1 calc R U . . .
H52B H 0.870663 0.599772 0.866825 0.079 Uiso 1 1 calc R U . . .
H52C H 0.927079 0.639405 0.823409 0.079 Uiso 1 1 calc R U . . .
C53 C 0.9323(3) 0.75239(18) 0.8789(2) 0.0680(11) Uani 1 1 d . . . . .
H53A H 0.989811 0.757260 0.906251 0.082 Uiso 1 1 calc R U . . .
H53B H 0.948099 0.752654 0.838439 0.082 Uiso 1 1 calc R U . . .
H53C H 0.902647 0.786150 0.889972 0.082 Uiso 1 1 calc R U . . .
C54 C 0.51286(19) 0.69233(13) 0.86933(12) 0.0361(5) Uani 1 1 d . . . . .
C55 C 0.5235(2) 0.70212(15) 0.98515(12) 0.0433(6) Uani 1 1 d . . . . .
C56 C 0.4430(3) 0.6523(2) 0.99828(16) 0.0760(13) Uani 1 1 d . . . . .
H56A H 0.444490 0.654169 1.041231 0.091 Uiso 1 1 calc R U . . .
H56B H 0.382765 0.658524 0.981428 0.091 Uiso 1 1 calc R U . . .
H56C H 0.450296 0.612133 0.980607 0.091 Uiso 1 1 calc R U . . .
C57 C 0.6189(3) 0.6937(2) 1.00779(16) 0.0666(11) Uani 1 1 d . . . . .
H57A H 0.624949 0.696795 1.050992 0.080 Uiso 1 1 calc R U . . .
H57B H 0.625551 0.653426 0.990157 0.080 Uiso 1 1 calc R U . . .
H57C H 0.668237 0.725539 0.996891 0.080 Uiso 1 1 calc R U . . .
C58 C 0.5135(3) 0.76519(19) 1.01045(15) 0.0601(9) Uani 1 1 d . . . . .
H58A H 0.517034 0.769110 1.053655 0.072 Uiso 1 1 calc R U . . .
H58B H 0.564307 0.796279 0.999996 0.072 Uiso 1 1 calc R U . . .
H58C H 0.452570 0.770913 0.994052 0.072 Uiso 1 1 calc R U . . .
C59 C 0.3874(2) 0.70154(14) 0.76821(11) 0.0378(6) Uani 1 1 d . . . . .
C60 C 0.2803(2) 0.7337(2) 0.84252(14) 0.0568(9) Uani 1 1 d . . . . .
C61 C 0.3541(3) 0.7871(2) 0.87788(14) 0.0600(10) Uani 1 1 d . . . . .
H61A H 0.335803 0.797251 0.917217 0.072 Uiso 1 1 calc R U . . .
H61B H 0.414953 0.776049 0.882025 0.072 Uiso 1 1 calc R U . . .
H61C H 0.359458 0.822520 0.857309 0.072 Uiso 1 1 calc R U . . .
C62 C 0.2677(3) 0.6764(2) 0.87118(17) 0.0661(11) Uani 1 1 d . . . . .
H62A H 0.248583 0.684933 0.910548 0.079 Uiso 1 1 calc R U . . .
H62B H 0.219173 0.643533 0.846543 0.079 Uiso 1 1 calc R U . . .
H62C H 0.327373 0.663832 0.874921 0.079 Uiso 1 1 calc R U . . .
C63 C 0.1855(3) 0.7519(3) 0.83226(19) 0.0892(17) Uani 1 1 d . . . . .
H63A H 0.163652 0.762060 0.870488 0.107 Uiso 1 1 calc R U . . .
H63B H 0.194008 0.787505 0.811812 0.107 Uiso 1 1 calc R U . . .
H63C H 0.138850 0.717679 0.807969 0.107 Uiso 1 1 calc R U . . .
C64 C 0.3531(2) 0.63151(15) 0.63039(13) 0.0440(6) Uani 1 1 d . . . . .
C65 C 0.2493(4) 0.5488(2) 0.5442(2) 0.0747(12) Uani 1 1 d . . . . .
C66 C 0.2922(10) 0.5811(6) 0.4841(6) 0.107(4) Uiso 0.5 1 d . . P . .
C67 C 0.1501(9) 0.5497(6) 0.5347(6) 0.096(3) Uiso 0.5 1 d . . P . .
C68 C 0.2710(8) 0.4861(5) 0.5497(5) 0.074(3) Uiso 0.5 1 d . . P . .
C69 C 0.1484(7) 0.5250(5) 0.5771(5) 0.076(2) Uiso 0.5 1 d . . P . .
C70 C 0.2919(5) 0.4963(3) 0.5345(3) 0.0461(14) Uiso 0.5 1 d . . P . .
C71 C 0.2184(7) 0.5779(5) 0.4972(4) 0.073(2) Uiso 0.5 1 d . . P . .
C72 C 0.4906(2) 0.75250(14) 0.65518(13) 0.0444(7) Uani 1 1 d . . . . .
C73 C 0.5502(4) 0.8361(2) 0.59201(18) 0.0836(16) Uani 1 1 d . . . . .
C74 C 0.5821(4) 0.8056(3) 0.5392(2) 0.101(2) Uani 1 1 d . . . . .
H74A H 0.598400 0.834732 0.511937 0.121 Uiso 1 1 calc R U . . .
H74B H 0.637537 0.790790 0.551594 0.121 Uiso 1 1 calc R U . . .
H74C H 0.531463 0.770955 0.519277 0.121 Uiso 1 1 calc R U . . .
C75 C 0.6058(5) 0.8939(3) 0.6297(3) 0.119(2) Uani 1 1 d . . . . .
H75A H 0.623095 0.925376 0.604786 0.143 Uiso 1 1 calc R U . . .
H75B H 0.567903 0.907823 0.659170 0.143 Uiso 1 1 calc R U . . .
H75C H 0.663064 0.886599 0.649955 0.143 Uiso 1 1 calc R U . . .
C76 C 0.4525(5) 0.8539(3) 0.5706(2) 0.0944(17) Uani 1 1 d . . . . .
H76A H 0.464656 0.884130 0.543842 0.113 Uiso 1 1 calc R U . . .
H76B H 0.406706 0.817194 0.549782 0.113 Uiso 1 1 calc R U . . .
H76C H 0.427297 0.871218 0.605187 0.113 Uiso 1 1 calc R U . . .
C77 C 1.1975(2) 0.17532(15) 0.65584(13) 0.0426(6) Uani 1 1 d . . . . .
C78 C 1.2831(2) 0.21311(16) 0.68510(14) 0.0462(7) Uani 1 1 d . . . . .
H78 H 1.296550 0.215981 0.726754 0.055 Uiso 1 1 calc R U . . .
C79 C 1.3489(3) 0.24668(18) 0.65443(17) 0.0566(8) Uani 1 1 d . . . . .
H79 H 1.406631 0.271306 0.675310 0.068 Uiso 1 1 calc R U . . .
C80 C 1.3303(3) 0.2441(2) 0.59373(18) 0.0633(10) Uani 1 1 d . . . . .
H80 H 1.374655 0.267473 0.573182 0.076 Uiso 1 1 calc R U . . .
C81 C 1.2462(3) 0.2070(2) 0.56292(16) 0.0624(10) Uani 1 1 d . . . . .
H81 H 1.233143 0.205162 0.521358 0.075 Uiso 1 1 calc R U . . .
C82 C 1.1809(3) 0.17252(17) 0.59349(14) 0.0512(7) Uani 1 1 d . . . . .
H82 H 1.124503 0.146769 0.572059 0.061 Uiso 1 1 calc R U . . .
C83 C 1.1787(2) 0.12561(14) 0.76661(13) 0.0432(6) Uani 1 1 d . . . . .
C84 C 1.2423(3) 0.08748(17) 0.76287(16) 0.0567(8) Uani 1 1 d . . . . .
H84 H 1.243680 0.063716 0.725822 0.068 Uiso 1 1 calc R U . . .
C85 C 1.3028(3) 0.0835(2) 0.81145(19) 0.0735(12) Uani 1 1 d . . . . .
H85 H 1.344780 0.057402 0.807254 0.088 Uiso 1 1 calc R U . . .
C86 C 1.3023(4) 0.1176(2) 0.86623(18) 0.0736(12) Uani 1 1 d . . . . .
H86 H 1.342459 0.113936 0.899754 0.088 Uiso 1 1 calc R U . . .
C87 C 1.2434(3) 0.15671(18) 0.87162(16) 0.0630(10) Uani 1 1 d . . . . .
H87 H 1.244807 0.181371 0.908650 0.076 Uiso 1 1 calc R U . . .
C88 C 1.1811(3) 0.16045(15) 0.82285(13) 0.0459(7) Uani 1 1 d . . . . .
H88 H 1.139732 0.186919 0.827669 0.055 Uiso 1 1 calc R U . . .
C89 C 0.8814(3) 0.12739(17) 0.58446(15) 0.0519(8) Uani 1 1 d . . . . .
C90 C 0.9333(3) 0.17062(18) 0.55546(16) 0.0612(9) Uani 1 1 d . . . . .
H90 H 0.991019 0.196102 0.575388 0.073 Uiso 1 1 calc R U . . .
C91 C 0.9029(4) 0.1778(2) 0.49747(19) 0.0788(14) Uani 1 1 d . . . . .
H91 H 0.940293 0.207234 0.478442 0.095 Uiso 1 1 calc R U . . .
C92 C 0.8171(5) 0.1414(3) 0.4681(2) 0.0934(19) Uani 1 1 d . . . . .
H92 H 0.795670 0.145948 0.429106 0.112 Uiso 1 1 calc R U . . .
C93 C 0.7646(4) 0.0992(3) 0.4960(2) 0.0852(16) Uani 1 1 d . . . . .
H93 H 0.706058 0.074770 0.476247 0.102 Uiso 1 1 calc R U . . .
C94 C 0.7951(3) 0.0914(2) 0.55260(18) 0.0677(11) Uani 1 1 d . . . . .
H94 H 0.757331 0.061141 0.570601 0.081 Uiso 1 1 calc R U . . .
C95 C 0.8212(3) 0.07665(18) 0.69218(17) 0.0584(9) Uani 1 1 d . . . . .
C96 C 0.8117(3) 0.0233(2) 0.7180(2) 0.0748(13) Uani 1 1 d . . . . .
H96 H 0.860454 0.002069 0.716908 0.090 Uiso 1 1 calc R U . . .
C97 C 0.7334(5) 0.0004(3) 0.7452(3) 0.110(2) Uani 1 1 d . . . . .
H97 H 0.729232 -0.035582 0.762434 0.132 Uiso 1 1 calc R U . . .
C98 C 0.6602(5) 0.0317(4) 0.7467(3) 0.139(4) Uani 1 1 d . . . . .
H98 H 0.606400 0.016723 0.765084 0.167 Uiso 1 1 calc R U . . .
C99 C 0.6672(3) 0.0836(4) 0.7217(3) 0.119(3) Uani 1 1 d . . . . .
H99 H 0.617751 0.104242 0.722954 0.143 Uiso 1 1 calc R U . . .
C100 C 0.7464(3) 0.1073(3) 0.6939(2) 0.0787(14) Uani 1 1 d . . . . .
H100 H 0.749731 0.143235 0.676573 0.094 Uiso 1 1 calc R U . . .
C101 C 1.12561(19) 0.30401(12) 0.78090(12) 0.0339(5) Uani 1 1 d . . . . .
C102 C 1.2091(2) 0.33843(13) 0.76563(13) 0.0372(5) Uani 1 1 d . . . . .
H102 H 1.213412 0.341623 0.725158 0.045 Uiso 1 1 calc R U . . .
C103 C 1.2865(2) 0.36827(14) 0.80792(14) 0.0419(6) Uani 1 1 d . . . . .
H103 H 1.341904 0.390942 0.795807 0.050 Uiso 1 1 calc R U . . .
C104 C 1.2821(2) 0.36473(14) 0.86766(14) 0.0414(6) Uani 1 1 d . . . . .
H104 H 1.334160 0.385195 0.896449 0.050 Uiso 1 1 calc R U . . .
C105 C 1.2004(2) 0.33076(13) 0.88481(13) 0.0383(5) Uani 1 1 d . . . . .
H105 H 1.196905 0.327717 0.925379 0.046 Uiso 1 1 calc R U . . .
C106 C 1.12379(19) 0.30121(13) 0.84208(11) 0.0341(5) Uani 1 1 d . . . . .
H106 H 1.068654 0.278498 0.854490 0.041 Uiso 1 1 calc R U . . .
C107 C 1.0231(2) 0.30547(14) 0.66074(12) 0.0444(6) Uani 1 1 d . . . . .
C108 C 0.9616(3) 0.33985(18) 0.64257(15) 0.0577(9) Uani 1 1 d . . . . .
H108 H 0.908624 0.341409 0.662893 0.069 Uiso 1 1 calc R U . . .
C109 C 0.9755(4) 0.3724(2) 0.59499(18) 0.0804(14) Uani 1 1 d . . . . .
H109 H 0.932347 0.395582 0.583748 0.097 Uiso 1 1 calc R U . . .
C110 C 1.0520(4) 0.3705(2) 0.56450(17) 0.0824(15) Uani 1 1 d . . . . .
H110 H 1.061848 0.392721 0.532565 0.099 Uiso 1 1 calc R U . . .
C111 C 1.1133(4) 0.3364(2) 0.58079(16) 0.0698(12) Uani 1 1 d . . . . .
H111 H 1.165499 0.334655 0.559768 0.084 Uiso 1 1 calc R U . . .
C112 C 1.0994(3) 0.30435(16) 0.62817(14) 0.0523(8) Uani 1 1 d . . . . .
H112 H 1.142748 0.281027 0.638756 0.063 Uiso 1 1 calc R U . . .
C113 C 0.8550(2) 0.35659(16) 0.91550(14) 0.0467(7) Uani 1 1 d . . . . .
C114 C 0.9523(2) 0.36939(16) 0.93122(14) 0.0482(7) Uani 1 1 d . . . . .
H114 H 0.989330 0.351524 0.905648 0.058 Uiso 1 1 calc R U . . .
C115 C 0.9968(3) 0.40805(18) 0.98392(16) 0.0557(8) Uani 1 1 d . . . . .
H115 H 1.062931 0.415605 0.994384 0.067 Uiso 1 1 calc R U . . .
C116 C 0.9420(3) 0.4351(2) 1.02056(17) 0.0653(10) Uani 1 1 d . . . . .
H116 H 0.971142 0.461570 1.056190 0.078 Uiso 1 1 calc R U . . .
C117 C 0.8464(3) 0.4239(2) 1.00566(17) 0.0693(11) Uani 1 1 d . . . . .
H117 H 0.810005 0.443047 1.030719 0.083 Uiso 1 1 calc R U . . .
C118 C 0.8024(3) 0.38452(19) 0.95369(16) 0.0598(9) Uani 1 1 d . . . . .
H118 H 0.736087 0.376549 0.944134 0.072 Uiso 1 1 calc R U . . .
C119 C 0.6691(2) 0.29403(16) 0.83270(14) 0.0459(7) Uani 1 1 d . . . . .
C120 C 0.6390(2) 0.34844(18) 0.83109(16) 0.0534(8) Uani 1 1 d . . . . .
H120 H 0.684054 0.386554 0.838911 0.064 Uiso 1 1 calc R U . . .
C121 C 0.5442(3) 0.3471(2) 0.81820(18) 0.0597(9) Uani 1 1 d . . . . .
H121 H 0.524767 0.384109 0.817425 0.072 Uiso 1 1 calc R U . . .
C122 C 0.4779(3) 0.2916(2) 0.80647(18) 0.0644(10) Uani 1 1 d . . . . .
H122 H 0.413057 0.290926 0.798463 0.077 Uiso 1 1 calc R U . . .
C123 C 0.5054(3) 0.2375(2) 0.8063(2) 0.0679(11) Uani 1 1 d . . . . .
H123 H 0.459949 0.199553 0.797785 0.081 Uiso 1 1 calc R U . . .
C124 C 0.6013(2) 0.23887(18) 0.81895(17) 0.0539(8) Uani 1 1 d . . . . .
H124 H 0.620280 0.201532 0.818105 0.065 Uiso 1 1 calc R U . . .
C125 C 1.0110(2) 0.18087(13) 0.71038(11) 0.0367(5) Uani 1 1 d . . . . .
C126 C 1.0259(3) 0.01487(16) 0.62760(16) 0.0543(8) Uani 1 1 d . . . . .
C127 C 1.1105(3) 0.02009(19) 0.59217(18) 0.0662(10) Uani 1 1 d . . . . .
H12A H 1.112482 -0.020671 0.572881 0.079 Uiso 1 1 calc R U . . .
H12B H 1.103869 0.046054 0.562035 0.079 Uiso 1 1 calc R U . . .
H12C H 1.168808 0.038217 0.619066 0.079 Uiso 1 1 calc R U . . .
C128 C 1.0382(3) -0.02609(17) 0.67426(19) 0.0674(10) Uani 1 1 d . . . . .
H12D H 1.041634 -0.066387 0.654531 0.081 Uiso 1 1 calc R U . . .
H12E H 1.096353 -0.007446 0.701179 0.081 Uiso 1 1 calc R U . . .
H12F H 0.984419 -0.030595 0.696867 0.081 Uiso 1 1 calc R U . . .
C129 C 0.9353(3) -0.01522(19) 0.58544(18) 0.0675(11) Uani 1 1 d . . . . .
H12G H 0.939696 -0.055437 0.566033 0.081 Uiso 1 1 calc R U . . .
H12H H 0.881445 -0.020034 0.607935 0.081 Uiso 1 1 calc R U . . .
H12I H 0.926974 0.010557 0.555398 0.081 Uiso 1 1 calc R U . . .
C130 C 0.9537(2) 0.12043(15) 0.81827(15) 0.0478(7) Uani 1 1 d . . . . .
C131 C 0.9833(4) 0.0319(2) 0.8757(2) 0.0772(13) Uani 1 1 d . . . . .
C132 C 0.8888(5) -0.0103(3) 0.8788(5) 0.158(4) Uani 1 1 d . . . . .
H13A H 0.898239 -0.043173 0.900522 0.189 Uiso 1 1 calc R U . . .
H13B H 0.849230 0.012930 0.899255 0.189 Uiso 1 1 calc R U . . .
H13C H 0.857923 -0.027946 0.838579 0.189 Uiso 1 1 calc R U . . .
C133 C 1.0330(6) 0.0634(3) 0.9377(2) 0.117(2) Uani 1 1 d . . . . .
H13D H 1.045688 0.032440 0.961119 0.140 Uiso 1 1 calc R U . . .
H13E H 1.092507 0.091472 0.933946 0.140 Uiso 1 1 calc R U . . .
H13F H 0.992436 0.086322 0.957551 0.140 Uiso 1 1 calc R U . . .
C134 C 1.0452(4) -0.0018(2) 0.8421(2) 0.0866(15) Uani 1 1 d . . . . .
H13G H 1.057919 -0.034521 0.862946 0.104 Uiso 1 1 calc R U . . .
H13H H 1.013086 -0.019374 0.802140 0.104 Uiso 1 1 calc R U . . .
H13I H 1.104795 0.026847 0.839386 0.104 Uiso 1 1 calc R U . . .
C135 C 0.86380(19) 0.22253(14) 0.82646(12) 0.0385(6) Uani 1 1 d . . . . .
C136 C 0.7991(3) 0.18703(17) 0.91824(14) 0.0520(8) Uani 1 1 d . . . . .
C137 C 0.7328(3) 0.2128(2) 0.95799(18) 0.0731(12) Uani 1 1 d . . . . .
H13J H 0.722419 0.189126 0.990396 0.088 Uiso 1 1 calc R U . . .
H13K H 0.761719 0.255701 0.974399 0.088 Uiso 1 1 calc R U . . .
H13L H 0.672405 0.209834 0.934303 0.088 Uiso 1 1 calc R U . . .
C138 C 0.8958(3) 0.1937(2) 0.95385(16) 0.0598(9) Uani 1 1 d . . . . .
H13M H 0.888846 0.168665 0.985390 0.072 Uiso 1 1 calc R U . . .
H13N H 0.938397 0.180152 0.927489 0.072 Uiso 1 1 calc R U . . .
H13O H 0.921969 0.236676 0.971365 0.072 Uiso 1 1 calc R U . . .
C139 C 0.7532(3) 0.12143(19) 0.89001(17) 0.0593(9) Uani 1 1 d . . . . .
H13P H 0.744959 0.095649 0.920935 0.071 Uiso 1 1 calc R U . . .
H13Q H 0.691653 0.119632 0.868315 0.071 Uiso 1 1 calc R U . . .
H13R H 0.793398 0.106693 0.862560 0.071 Uiso 1 1 calc R U . . .
C140 C 0.9498(2) 0.36049(15) 0.78298(12) 0.0398(6) Uani 1 1 d . . . . .
C141 C 1.0539(2) 0.47178(14) 0.79273(14) 0.0430(6) Uani 1 1 d . . . . .
C142 C 1.1328(2) 0.47641(16) 0.84272(17) 0.0518(7) Uani 1 1 d . . . . .
H14A H 1.176933 0.516538 0.847580 0.062 Uiso 1 1 calc R U . . .
H14B H 1.105951 0.471343 0.879684 0.062 Uiso 1 1 calc R U . . .
H14C H 1.166266 0.444309 0.832948 0.062 Uiso 1 1 calc R U . . .
C143 C 0.9971(2) 0.51934(16) 0.80747(17) 0.0515(7) Uani 1 1 d . . . . .
H14D H 1.038112 0.560434 0.811400 0.062 Uiso 1 1 calc R U . . .
H14E H 0.945230 0.514104 0.775650 0.062 Uiso 1 1 calc R U . . .
H14F H 0.971612 0.513986 0.844814 0.062 Uiso 1 1 calc R U . . .
C144 C 1.0917(3) 0.47738(18) 0.73352(17) 0.0577(8) Uani 1 1 d . . . . .
H14G H 1.134634 0.517641 0.736138 0.069 Uiso 1 1 calc R U . . .
H14H H 1.125633 0.445463 0.724159 0.069 Uiso 1 1 calc R U . . .
H14I H 1.039128 0.472621 0.702281 0.069 Uiso 1 1 calc R U . . .
C145 C 0.7890(2) 0.26711(17) 0.70875(14) 0.0499(7) Uani 1 1 d . . . . .
C146 C 0.6583(3) 0.2564(2) 0.61932(18) 0.0714(12) Uani 1 1 d . . . . .
C147 C 0.7122(4) 0.2621(3) 0.5645(2) 0.109(2) Uani 1 1 d . . . . .
H14J H 0.667384 0.258690 0.529107 0.131 Uiso 1 1 calc R U . . .
H14K H 0.757608 0.301871 0.570666 0.131 Uiso 1 1 calc R U . . .
H14L H 0.745739 0.229401 0.559194 0.131 Uiso 1 1 calc R U . . .
C148 C 0.5878(4) 0.1967(3) 0.6135(3) 0.110(2) Uani 1 1 d . . . . .
H14M H 0.539898 0.192834 0.579632 0.132 Uiso 1 1 calc R U . . .
H14N H 0.619617 0.163163 0.607437 0.132 Uiso 1 1 calc R U . . .
H14O H 0.557710 0.194836 0.649742 0.132 Uiso 1 1 calc R U . . .
C149 C 0.6126(3) 0.3096(2) 0.6301(2) 0.0769(13) Uani 1 1 d . . . . .
H14P H 0.564322 0.307074 0.596739 0.092 Uiso 1 1 calc R U . . .
H14Q H 0.583467 0.308192 0.666656 0.092 Uiso 1 1 calc R U . . .
H14R H 0.660456 0.348066 0.633807 0.092 Uiso 1 1 calc R U . . .
C150 C 1.2075(7) -0.0353(5) 0.9622(5) 0.078(2) Uiso 0.5 1 d . . P . .
C151 C 1.2785(7) -0.0525(5) 0.9247(4) 0.076(2) Uiso 0.5 1 d . . P . .
C152 C 1.3632(4) -0.0038(3) 0.9353(3) 0.0441(12) Uiso 0.5 1 d . . P . .
C153 C 1.4300(7) -0.0199(4) 0.9000(4) 0.072(2) Uiso 0.5 1 d . . P . .
C154 C 1.5089(8) 0.0322(5) 0.9060(5) 0.083(3) Uiso 0.5 1 d . . P . .
C155 C 0.4694(9) 0.0314(6) 0.5671(6) 0.096(3) Uiso 0.5 1 d . . P . .
C156 C 0.4645(7) 0.0178(5) 0.5114(4) 0.074(2) Uiso 0.5 1 d . . P . .
C157 C 0.3926(13) 0.0665(9) 0.5924(9) 0.073(4) Uiso 0.25 1 d . . P . .
loop_
_atom_type_symbol
_atom_type_description
_atom_type_scat_dispersion_real
_atom_type_scat_dispersion_imag
_atom_type_scat_source
C C 0.0000 0.0000
;
International Tables for Crystallography
(Vol. C, Tables 4.2.6.8 and 6.1.1.4)
;
H H 0.0000 0.0000
;
International Tables for Crystallography
(Vol. C, Table 6.1.1.4)
;
N N 0.0000 0.0000
;
International Tables for Crystallography
(Vol. C, Tables 4.2.6.8 and 6.1.1.4)
;
Ni Ni 0.0000 0.0000
;
International Tables for Crystallography
(Vol. C, Tables 4.2.6.8 and 6.1.1.4)
;
Si Si 0.0000 0.0000
;
International Tables for Crystallography
(Vol. C, Tables 4.2.6.8 and 6.1.1.4)
;
loop_
_geom_angle_atom_site_label_1
_geom_angle_atom_site_label_2
_geom_angle_atom_site_label_3
_geom_angle
_geom_angle_site_symmetry_1
_geom_angle_site_symmetry_3
_geom_angle_publ_flag
C59 Ni1 C54 104.47(12) . . ?
C59 Ni1 C49 151.92(12) . . ?
C54 Ni1 C49 103.55(12) . . ?
C59 Ni1 Si3 106.42(9) . . ?
C54 Ni1 Si3 145.89(9) . . ?
C49 Ni1 Si3 47.30(9) . . ?
C59 Ni1 Ni2 49.05(8) . . ?
C54 Ni1 Ni2 153.28(9) . . ?
C49 Ni1 Ni2 102.87(9) . . ?
Si3 Ni1 Ni2 59.95(6) . . ?
C72 Ni2 C64 106.54(15) . . ?
C72 Ni2 C59 127.05(14) . . ?
C64 Ni2 C59 123.07(14) . . ?
C72 Ni2 Si4 99.83(11) . . ?
C64 Ni2 Si4 95.07(11) . . ?
C59 Ni2 Si4 61.29(9) . . ?
C72 Ni2 Si3 93.86(12) . . ?
C64 Ni2 Si3 88.68(11) . . ?
C59 Ni2 Si3 103.86(9) . . ?
Si4 Ni2 Si3 164.11(3) . . ?
C72 Ni2 Ni1 112.65(12) . . ?
C64 Ni2 Ni1 129.86(10) . . ?
C59 Ni2 Ni1 46.99(10) . . ?
Si4 Ni2 Ni1 107.39(4) . . ?
Si3 Ni2 Ni1 59.32(3) . . ?
C135 Ni3 C130 105.78(14) . . ?
C135 Ni3 C125 149.16(13) . . ?
C130 Ni3 C125 105.06(13) . . ?
C135 Ni3 Si7 105.10(11) . . ?
C130 Ni3 Si7 143.09(11) . . ?
C125 Ni3 Si7 46.60(9) . . ?
C135 Ni3 Ni4 48.65(10) . . ?
C130 Ni3 Ni4 154.20(10) . . ?
C125 Ni3 Ni4 100.56(9) . . ?
Si7 Ni3 Ni4 58.46(5) . . ?
C140 Ni4 C145 107.41(15) . . ?
C140 Ni4 C135 133.48(13) . . ?
C145 Ni4 C135 116.06(15) . . ?
C140 Ni4 Si8 95.20(10) . . ?
C145 Ni4 Si8 101.03(12) . . ?
C135 Ni4 Si8 61.79(10) . . ?
C140 Ni4 Si7 81.98(10) . . ?
C145 Ni4 Si7 101.27(12) . . ?
C135 Ni4 Si7 104.17(9) . . ?
Si8 Ni4 Si7 157.33(3) . . ?
C140 Ni4 Ni3 130.16(10) . . ?
C145 Ni4 Ni3 110.21(12) . . ?
C135 Ni4 Ni3 46.42(9) . . ?
Si8 Ni4 Ni3 108.17(4) . . ?
Si7 Ni4 Ni3 59.71(3) . . ?
N1 Si1 C49 90.32(14) . . ?
N1 Si1 C7 117.28(15) . . ?
C49 Si1 C7 119.40(14) . . ?
N1 Si1 C1 114.24(14) . . ?
C49 Si1 C1 113.36(14) . . ?
C7 Si1 C1 102.78(15) . . ?
N1 Si1 Si2 43.47(10) . . ?
C49 Si1 Si2 46.91(10) . . ?
C7 Si1 Si2 134.22(10) . . ?
C1 Si1 Si2 122.91(11) . . ?
N1 Si2 C49 90.67(14) . . ?
N1 Si2 C13 110.92(17) . . ?
C49 Si2 C13 118.61(16) . . ?
N1 Si2 C19 116.79(16) . . ?
C49 Si2 C19 116.05(14) . . ?
C13 Si2 C19 104.08(15) . . ?
N1 Si2 Si1 44.05(10) . . ?
C49 Si2 Si1 46.69(9) . . ?
C13 Si2 Si1 124.34(11) . . ?
C19 Si2 Si1 131.28(11) . . ?
C49 Si3 C25 111.72(12) . . ?
C49 Si3 C31 119.78(15) . . ?
C25 Si3 C31 102.54(13) . . ?
C49 Si3 Ni1 55.82(9) . . ?
C25 Si3 Ni1 105.77(9) . . ?
C31 Si3 Ni1 150.48(11) . . ?
C49 Si3 Ni2 111.31(9) . . ?
C25 Si3 Ni2 107.92(11) . . ?
C31 Si3 Ni2 102.55(10) . . ?
Ni1 Si3 Ni2 60.73(4) . . ?
N3 Si4 C37 110.36(14) . . ?
N3 Si4 C43 107.90(14) . . ?
C37 Si4 C43 108.88(16) . . ?
N3 Si4 C59 38.67(10) . . ?
C37 Si4 C59 128.33(15) . . ?
C43 Si4 C59 119.20(14) . . ?
N3 Si4 Ni2 88.92(9) . . ?
C37 Si4 Ni2 118.59(12) . . ?
C43 Si4 Ni2 119.64(12) . . ?
C59 Si4 Ni2 50.53(8) . . ?
N6 Si5 C125 90.23(14) . . ?
N6 Si5 C77 113.28(14) . . ?
C125 Si5 C77 113.59(14) . . ?
N6 Si5 C83 119.26(14) . . ?
C125 Si5 C83 119.58(13) . . ?
C77 Si5 C83 101.58(15) . . ?
N6 Si5 Si6 43.45(9) . . ?
C125 Si5 Si6 46.95(10) . . ?
C77 Si5 Si6 121.10(12) . . ?
C83 Si5 Si6 137.26(10) . . ?
N6 Si6 C125 90.00(14) . . ?
N6 Si6 C89 113.35(14) . . ?
C125 Si6 C89 118.63(16) . . ?
N6 Si6 C95 116.17(18) . . ?
C125 Si6 C95 115.08(14) . . ?
C89 Si6 C95 103.99(18) . . ?
N6 Si6 Si5 43.38(10) . . ?
C125 Si6 Si5 46.79(9) . . ?
C89 Si6 Si5 124.95(12) . . ?
C95 Si6 Si5 130.87(15) . . ?
C125 Si7 C107 115.94(13) . . ?
C125 Si7 C101 110.67(13) . . ?
C107 Si7 C101 104.15(14) . . ?
C125 Si7 Ni4 111.54(9) . . ?
C107 Si7 Ni4 107.66(11) . . ?
C101 Si7 Ni4 106.22(10) . . ?
C125 Si7 Ni3 55.34(9) . . ?
C107 Si7 Ni3 153.46(11) . . ?
C101 Si7 Ni3 102.27(10) . . ?
Ni4 Si7 Ni3 61.83(4) . . ?
N8 Si8 C113 105.64(15) . . ?
N8 Si8 C119 109.39(15) . . ?
C113 Si8 C119 111.01(14) . . ?
N8 Si8 C135 38.27(11) . . ?
C113 Si8 C135 118.57(14) . . ?
C119 Si8 C135 125.91(14) . . ?
N8 Si8 Ni4 88.92(9) . . ?
C113 Si8 Ni4 118.73(12) . . ?
C119 Si8 Ni4 119.32(11) . . ?
C135 Si8 Ni4 50.72(8) . . ?
C50 N1 Si2 134.5(2) . . ?
C50 N1 Si1 132.8(2) . . ?
Si2 N1 Si1 92.48(14) . . ?
C54 N2 C55 179.0(3) . . ?
C59 N3 C60 128.9(2) . . ?
C59 N3 Si4 85.14(16) . . ?
C60 N3 Si4 143.0(2) . . ?
C64 N4 C65 179.5(4) . . ?
C72 N5 C73 165.9(4) . . ?
C126 N6 Si5 133.5(2) . . ?
C126 N6 Si6 133.3(2) . . ?
Si5 N6 Si6 93.17(14) . . ?
C130 N7 C131 177.9(4) . . ?
C135 N8 C136 128.7(3) . . ?
C135 N8 Si8 85.7(2) . . ?
C136 N8 Si8 144.1(2) . . ?
C140 N9 C141 171.4(3) . . ?
C145 N10 C146 177.4(4) . . ?
C2 C1 C6 116.3(3) . . ?
C2 C1 Si1 123.6(2) . . ?
C6 C1 Si1 120.0(2) . . ?
C1 C2 C3 122.2(3) . . ?
C1 C2 H2 118.9 . . ?
C3 C2 H2 118.9 . . ?
C4 C3 C2 120.1(3) . . ?
C4 C3 H3 119.9 . . ?
C2 C3 H3 119.9 . . ?
C3 C4 C5 119.6(3) . . ?
C3 C4 H4 120.2 . . ?
C5 C4 H4 120.2 . . ?
C4 C5 C6 120.1(3) . . ?
C4 C5 H5 120.0 . . ?
C6 C5 H5 120.0 . . ?
C1 C6 C5 121.7(3) . . ?
C1 C6 H6 119.1 . . ?
C5 C6 H6 119.1 . . ?
C8 C7 C12 117.1(3) . . ?
C8 C7 Si1 119.2(2) . . ?
C12 C7 Si1 123.4(3) . . ?
C9 C8 C7 122.0(3) . . ?
C9 C8 H8 119.0 . . ?
C7 C8 H8 119.0 . . ?
C8 C9 C10 119.6(3) . . ?
C8 C9 H9 120.2 . . ?
C10 C9 H9 120.2 . . ?
C11 C10 C9 120.0(3) . . ?
C11 C10 H10 120.0 . . ?
C9 C10 H10 120.0 . . ?
C10 C11 C12 120.6(3) . . ?
C10 C11 H11 119.7 . . ?
C12 C11 H11 119.7 . . ?
C11 C12 C7 120.6(3) . . ?
C11 C12 H12 119.7 . . ?
C7 C12 H12 119.7 . . ?
C14 C13 C18 116.7(3) . . ?
C14 C13 Si2 120.8(3) . . ?
C18 C13 Si2 122.3(3) . . ?
C15 C14 C13 122.0(4) . . ?
C15 C14 H14 119.0 . . ?
C13 C14 H14 119.0 . . ?
C16 C15 C14 120.1(4) . . ?
C16 C15 H15 119.9 . . ?
C14 C15 H15 119.9 . . ?
C15 C16 C17 120.2(4) . . ?
C15 C16 H16 119.9 . . ?
C17 C16 H16 119.9 . . ?
C18 C17 C16 118.9(5) . . ?
C18 C17 H17 120.5 . . ?
C16 C17 H17 120.5 . . ?
C17 C18 C13 122.0(4) . . ?
C17 C18 H18 119.0 . . ?
C13 C18 H18 119.0 . . ?
C24 C19 C20 116.4(3) . . ?
C24 C19 Si2 120.3(3) . . ?
C20 C19 Si2 123.3(2) . . ?
C21 C20 C19 122.0(3) . . ?
C21 C20 H20 119.0 . . ?
C19 C20 H20 119.0 . . ?
C22 C21 C20 120.2(4) . . ?
C22 C21 H21 119.9 . . ?
C20 C21 H21 119.9 . . ?
C21 C22 C23 119.4(3) . . ?
C21 C22 H22 120.3 . . ?
C23 C22 H22 120.3 . . ?
C24 C23 C22 120.5(3) . . ?
C24 C23 H23 119.7 . . ?
C22 C23 H23 119.7 . . ?
C23 C24 C19 121.4(3) . . ?
C23 C24 H24 119.3 . . ?
C19 C24 H24 119.3 . . ?
C26 C25 C30 116.3(3) . . ?
C26 C25 Si3 122.4(2) . . ?
C30 C25 Si3 121.2(2) . . ?
C27 C26 C25 121.9(3) . . ?
C27 C26 H26 119.0 . . ?
C25 C26 H26 119.0 . . ?
C26 C27 C28 120.3(3) . . ?
C26 C27 H27 119.9 . . ?
C28 C27 H27 119.9 . . ?
C29 C28 C27 119.6(3) . . ?
C29 C28 H28 120.2 . . ?
C27 C28 H28 120.2 . . ?
C28 C29 C30 120.1(3) . . ?
C28 C29 H29 120.0 . . ?
C30 C29 H29 120.0 . . ?
C29 C30 C25 121.7(3) . . ?
C29 C30 H30 119.1 . . ?
C25 C30 H30 119.1 . . ?
C32 C31 C36 117.0(3) . . ?
C32 C31 Si3 119.8(3) . . ?
C36 C31 Si3 123.2(3) . . ?
C33 C32 C31 123.7(4) . . ?
C33 C32 H32 118.2 . . ?
C31 C32 H32 118.2 . . ?
C32 C33 C34 118.6(4) . . ?
C32 C33 H33 120.7 . . ?
C34 C33 H33 120.7 . . ?
C35 C34 C33 120.0(3) . . ?
C35 C34 H34 120.0 . . ?
C33 C34 H34 120.0 . . ?
C34 C35 C36 120.4(4) . . ?
C34 C35 H35 119.8 . . ?
C36 C35 H35 119.8 . . ?
C31 C36 C35 120.3(4) . . ?
C31 C36 H36 119.8 . . ?
C35 C36 H36 119.8 . . ?
C42 C37 C38 115.9(3) . . ?
C42 C37 Si4 121.4(3) . . ?
C38 C37 Si4 122.7(3) . . ?
C39 C38 C37 122.0(3) . . ?
C39 C38 H38 119.0 . . ?
C37 C38 H38 119.0 . . ?
C38 C39 C40 120.3(4) . . ?
C38 C39 H39 119.9 . . ?
C40 C39 H39 119.9 . . ?
C41 C40 C39 119.1(4) . . ?
C41 C40 H40 120.4 . . ?
C39 C40 H40 120.4 . . ?
C40 C41 C42 120.4(3) . . ?
C40 C41 H41 119.8 . . ?
C42 C41 H41 119.8 . . ?
C41 C42 C37 122.2(3) . . ?
C41 C42 H42 118.9 . . ?
C37 C42 H42 118.9 . . ?
C48 C43 C44 117.1(4) . . ?
C48 C43 Si4 120.4(3) . . ?
C44 C43 Si4 122.4(4) . . ?
C43 C44 C45 119.2(6) . . ?
C43 C44 H44 120.4 . . ?
C45 C44 H44 120.4 . . ?
C46 C45 C44 121.2(5) . . ?
C46 C45 H45 119.4 . . ?
C44 C45 H45 119.4 . . ?
C47 C46 C45 118.2(5) . . ?
C47 C46 H46 120.9 . . ?
C45 C46 H46 120.9 . . ?
C46 C47 C48 120.5(6) . . ?
C46 C47 H47 119.8 . . ?
C48 C47 H47 119.8 . . ?
C43 C48 C47 123.4(5) . . ?
C43 C48 H48 118.3 . . ?
C47 C48 H48 118.3 . . ?
Si3 C49 Si1 126.13(16) . . ?
Si3 C49 Si2 138.72(16) . . ?
Si1 C49 Si2 86.39(14) . . ?
Si3 C49 Ni1 76.88(11) . . ?
Si1 C49 Ni1 123.62(14) . . ?
Si2 C49 Ni1 107.86(14) . . ?
N1 C50 C51 110.9(3) . . ?
N1 C50 C53 111.5(3) . . ?
C51 C50 C53 108.3(3) . . ?
N1 C50 C52 109.0(3) . . ?
C51 C50 C52 108.9(3) . . ?
C53 C50 C52 108.1(3) . . ?
C50 C51 H51A 109.5 . . ?
C50 C51 H51B 109.5 . . ?
H51A C51 H51B 109.5 . . ?
C50 C51 H51C 109.5 . . ?
H51A C51 H51C 109.5 . . ?
H51B C51 H51C 109.5 . . ?
C50 C52 H52A 109.5 . . ?
C50 C52 H52B 109.5 . . ?
H52A C52 H52B 109.5 . . ?
C50 C52 H52C 109.5 . . ?
H52A C52 H52C 109.5 . . ?
H52B C52 H52C 109.5 . . ?
C50 C53 H53A 109.5 . . ?
C50 C53 H53B 109.5 . . ?
H53A C53 H53B 109.5 . . ?
C50 C53 H53C 109.5 . . ?
H53A C53 H53C 109.5 . . ?
H53B C53 H53C 109.5 . . ?
N2 C54 Ni1 177.9(2) . . ?
N2 C55 C57 107.4(3) . . ?
N2 C55 C58 108.6(3) . . ?
C57 C55 C58 110.1(3) . . ?
N2 C55 C56 107.1(3) . . ?
C57 C55 C56 112.3(3) . . ?
C58 C55 C56 111.1(3) . . ?
C55 C56 H56A 109.5 . . ?
C55 C56 H56B 109.5 . . ?
H56A C56 H56B 109.5 . . ?
C55 C56 H56C 109.5 . . ?
H56A C56 H56C 109.5 . . ?
H56B C56 H56C 109.5 . . ?
C55 C57 H57A 109.5 . . ?
C55 C57 H57B 109.5 . . ?
H57A C57 H57B 109.5 . . ?
C55 C57 H57C 109.5 . . ?
H57A C57 H57C 109.5 . . ?
H57B C57 H57C 109.5 . . ?
C55 C58 H58A 109.5 . . ?
C55 C58 H58B 109.5 . . ?
H58A C58 H58B 109.5 . . ?
C55 C58 H58C 109.5 . . ?
H58A C58 H58C 109.5 . . ?
H58B C58 H58C 109.5 . . ?
N3 C59 Ni1 151.9(2) . . ?
N3 C59 Ni2 123.8(2) . . ?
Ni1 C59 Ni2 83.96(11) . . ?
N3 C59 Si4 56.20(15) . . ?
Ni1 C59 Si4 149.64(14) . . ?
Ni2 C59 Si4 68.18(10) . . ?
N3 C60 C61 108.7(3) . . ?
N3 C60 C62 107.8(3) . . ?
C61 C60 C62 113.0(3) . . ?
N3 C60 C63 106.6(3) . . ?
C61 C60 C63 110.0(4) . . ?
C62 C60 C63 110.4(3) . . ?
C60 C61 H61A 109.5 . . ?
C60 C61 H61B 109.5 . . ?
H61A C61 H61B 109.5 . . ?
C60 C61 H61C 109.5 . . ?
H61A C61 H61C 109.5 . . ?
H61B C61 H61C 109.5 . . ?
C60 C62 H62A 109.5 . . ?
C60 C62 H62B 109.5 . . ?
H62A C62 H62B 109.5 . . ?
C60 C62 H62C 109.5 . . ?
H62A C62 H62C 109.5 . . ?
H62B C62 H62C 109.5 . . ?
C60 C63 H63A 109.5 . . ?
C60 C63 H63B 109.5 . . ?
H63A C63 H63B 109.5 . . ?
C60 C63 H63C 109.5 . . ?
H63A C63 H63C 109.5 . . ?
H63B C63 H63C 109.5 . . ?
N4 C64 Ni2 176.2(3) . . ?
C71 C65 C67 61.6(6) . . ?
C71 C65 N4 109.7(5) . . ?
C67 C65 N4 115.4(6) . . ?
C71 C65 C70 123.1(6) . . ?
C67 C65 C70 128.4(7) . . ?
N4 C65 C70 109.8(4) . . ?
C71 C65 C68 136.2(7) . . ?
C67 C65 C68 116.4(7) . . ?
N4 C65 C68 109.2(5) . . ?
C70 C65 C68 20.0(4) . . ?
C71 C65 C69 104.0(6) . . ?
C67 C65 C69 42.4(6) . . ?
N4 C65 C69 100.8(5) . . ?
C70 C65 C69 106.8(6) . . ?
C68 C65 C69 87.6(6) . . ?
C71 C65 C66 40.5(6) . . ?
C67 C65 C66 101.7(7) . . ?
N4 C65 C66 98.2(6) . . ?
C70 C65 C66 94.8(6) . . ?
C68 C65 C66 114.3(7) . . ?
C69 C65 C66 144.1(6) . . ?
C71 C66 C65 54.2(8) . . ?
C69 C67 C65 81.6(9) . . ?
C69 C67 C71 139.7(12) . . ?
C65 C67 C71 58.2(6) . . ?
C70 C68 C65 71.4(16) . . ?
C67 C69 C65 56.0(7) . . ?
C68 C70 C65 88.6(17) . . ?
C66 C71 C65 85.4(10) . . ?
C66 C71 C67 144.7(12) . . ?
C65 C71 C67 60.2(7) . . ?
N5 C72 Ni2 173.7(3) . . ?
N5 C73 C74 107.8(4) . . ?
N5 C73 C75 106.9(4) . . ?
C74 C73 C75 124.1(5) . . ?
N5 C73 C76 106.3(4) . . ?
C74 C73 C76 108.0(4) . . ?
C75 C73 C76 102.5(5) . . ?
C73 C74 H74A 109.5 . . ?
C73 C74 H74B 109.5 . . ?
H74A C74 H74B 109.5 . . ?
C73 C74 H74C 109.5 . . ?
H74A C74 H74C 109.5 . . ?
H74B C74 H74C 109.5 . . ?
C73 C75 H75A 109.5 . . ?
C73 C75 H75B 109.5 . . ?
H75A C75 H75B 109.5 . . ?
C73 C75 H75C 109.5 . . ?
H75A C75 H75C 109.5 . . ?
H75B C75 H75C 109.5 . . ?
C73 C76 H76A 109.5 . . ?
C73 C76 H76B 109.5 . . ?
H76A C76 H76B 109.5 . . ?
C73 C76 H76C 109.5 . . ?
H76A C76 H76C 109.5 . . ?
H76B C76 H76C 109.5 . . ?
C78 C77 C82 116.9(3) . . ?
C78 C77 Si5 120.4(2) . . ?
C82 C77 Si5 122.3(3) . . ?
C79 C78 C77 121.7(3) . . ?
C79 C78 H78 119.1 . . ?
C77 C78 H78 119.1 . . ?
C80 C79 C78 120.3(4) . . ?
C80 C79 H79 119.8 . . ?
C78 C79 H79 119.8 . . ?
C79 C80 C81 119.8(3) . . ?
C79 C80 H80 120.1 . . ?
C81 C80 H80 120.1 . . ?
C80 C81 C82 119.9(3) . . ?
C80 C81 H81 120.1 . . ?
C82 C81 H81 120.1 . . ?
C81 C82 C77 121.4(3) . . ?
C81 C82 H82 119.3 . . ?
C77 C82 H82 119.3 . . ?
C84 C83 C88 116.0(3) . . ?
C84 C83 Si5 123.2(2) . . ?
C88 C83 Si5 120.4(3) . . ?
C85 C84 C83 122.2(3) . . ?
C85 C84 H84 118.9 . . ?
C83 C84 H84 118.9 . . ?
C84 C85 C86 120.3(4) . . ?
C84 C85 H85 119.9 . . ?
C86 C85 H85 119.9 . . ?
C87 C86 C85 119.6(4) . . ?
C87 C86 H86 120.2 . . ?
C85 C86 H86 120.2 . . ?
C86 C87 C88 120.5(3) . . ?
C86 C87 H87 119.8 . . ?
C88 C87 H87 119.8 . . ?
C87 C88 C83 121.4(3) . . ?
C87 C88 H88 119.3 . . ?
C83 C88 H88 119.3 . . ?
C90 C89 C94 116.2(4) . . ?
C90 C89 Si6 120.5(3) . . ?
C94 C89 Si6 123.2(3) . . ?
C89 C90 C91 122.1(4) . . ?
C89 C90 H90 119.0 . . ?
C91 C90 H90 119.0 . . ?
C92 C91 C90 119.4(5) . . ?
C92 C91 H91 120.3 . . ?
C90 C91 H91 120.3 . . ?
C93 C92 C91 119.4(5) . . ?
C93 C92 H92 120.3 . . ?
C91 C92 H92 120.3 . . ?
C92 C93 C94 121.2(5) . . ?
C92 C93 H93 119.4 . . ?
C94 C93 H93 119.4 . . ?
C93 C94 C89 121.6(5) . . ?
C93 C94 H94 119.2 . . ?
C89 C94 H94 119.2 . . ?
C96 C95 C100 117.6(4) . . ?
C96 C95 Si6 125.3(3) . . ?
C100 C95 Si6 116.9(4) . . ?
C97 C96 C95 122.5(6) . . ?
C97 C96 H96 118.8 . . ?
C95 C96 H96 118.8 . . ?
C96 C97 C98 119.0(7) . . ?
C96 C97 H97 120.5 . . ?
C98 C97 H97 120.5 . . ?
C99 C98 C97 119.8(5) . . ?
C99 C98 H98 120.1 . . ?
C97 C98 H98 120.1 . . ?
C98 C99 C100 121.7(7) . . ?
C98 C99 H99 119.2 . . ?
C100 C99 H99 119.2 . . ?
C99 C100 C95 119.3(6) . . ?
C99 C100 H100 120.3 . . ?
C95 C100 H100 120.3 . . ?
C102 C101 C106 115.9(3) . . ?
C102 C101 Si7 125.8(2) . . ?
C106 C101 Si7 118.3(2) . . ?
C103 C102 C101 122.4(3) . . ?
C103 C102 H102 118.8 . . ?
C101 C102 H102 118.8 . . ?
C104 C103 C102 120.1(3) . . ?
C104 C103 H103 119.9 . . ?
C102 C103 H103 119.9 . . ?
C103 C104 C105 119.3(3) . . ?
C103 C104 H104 120.3 . . ?
C105 C104 H104 120.3 . . ?
C104 C105 C106 119.9(3) . . ?
C104 C105 H105 120.1 . . ?
C106 C105 H105 120.1 . . ?
C105 C106 C101 122.3(2) . . ?
C105 C106 H106 118.8 . . ?
C101 C106 H106 118.8 . . ?
C108 C107 C112 116.2(3) . . ?
C108 C107 Si7 126.1(3) . . ?
C112 C107 Si7 117.7(3) . . ?
C107 C108 C109 121.9(4) . . ?
C107 C108 H108 119.0 . . ?
C109 C108 H108 119.0 . . ?
C110 C109 C108 120.1(5) . . ?
C110 C109 H109 120.0 . . ?
C108 C109 H109 120.0 . . ?
C111 C110 C109 119.5(4) . . ?
C111 C110 H110 120.3 . . ?
C109 C110 H110 120.3 . . ?
C110 C111 C112 120.3(4) . . ?
C110 C111 H111 119.9 . . ?
C112 C111 H111 119.9 . . ?
C111 C112 C107 122.1(4) . . ?
C111 C112 H112 119.0 . . ?
C107 C112 H112 119.0 . . ?
C114 C113 C118 117.8(3) . . ?
C114 C113 Si8 119.4(2) . . ?
C118 C113 Si8 122.5(3) . . ?
C113 C114 C115 121.7(3) . . ?
C113 C114 H114 119.2 . . ?
C115 C114 H114 119.2 . . ?
C116 C115 C114 118.7(3) . . ?
C116 C115 H115 120.6 . . ?
C114 C115 H115 120.6 . . ?
C117 C116 C115 120.7(3) . . ?
C117 C116 H116 119.7 . . ?
C115 C116 H116 119.7 . . ?
C116 C117 C118 120.3(3) . . ?
C116 C117 H117 119.9 . . ?
C118 C117 H117 119.9 . . ?
C117 C118 C113 120.9(4) . . ?
C117 C118 H118 119.6 . . ?
C113 C118 H118 119.6 . . ?
C124 C119 C120 117.9(3) . . ?
C124 C119 Si8 121.7(3) . . ?
C120 C119 Si8 120.4(3) . . ?
C121 C120 C119 120.8(4) . . ?
C121 C120 H120 119.6 . . ?
C119 C120 H120 119.6 . . ?
C122 C121 C120 120.0(4) . . ?
C122 C121 H121 120.0 . . ?
C120 C121 H121 120.0 . . ?
C123 C122 C121 120.5(4) . . ?
C123 C122 H122 119.7 . . ?
C121 C122 H122 119.7 . . ?
C122 C123 C124 119.4(4) . . ?
C122 C123 H123 120.3 . . ?
C124 C123 H123 120.3 . . ?
C119 C124 C123 121.3(4) . . ?
C119 C124 H124 119.4 . . ?
C123 C124 H124 119.4 . . ?
Si7 C125 Si5 132.20(16) . . ?
Si7 C125 Si6 134.00(18) . . ?
Si5 C125 Si6 86.26(13) . . ?
Si7 C125 Ni3 78.06(10) . . ?
Si5 C125 Ni3 126.07(15) . . ?
Si6 C125 Ni3 100.24(13) . . ?
N6 C126 C129 110.3(3) . . ?
N6 C126 C128 109.5(3) . . ?
C129 C126 C128 108.9(3) . . ?
N6 C126 C127 110.9(3) . . ?
C129 C126 C127 109.0(3) . . ?
C128 C126 C127 108.2(4) . . ?
C126 C127 H12A 109.5 . . ?
C126 C127 H12B 109.5 . . ?
H12A C127 H12B 109.5 . . ?
C126 C127 H12C 109.5 . . ?
H12A C127 H12C 109.5 . . ?
H12B C127 H12C 109.5 . . ?
C126 C128 H12D 109.5 . . ?
C126 C128 H12E 109.5 . . ?
H12D C128 H12E 109.5 . . ?
C126 C128 H12F 109.5 . . ?
H12D C128 H12F 109.5 . . ?
H12E C128 H12F 109.5 . . ?
C126 C129 H12G 109.5 . . ?
C126 C129 H12H 109.5 . . ?
H12G C129 H12H 109.5 . . ?
C126 C129 H12I 109.5 . . ?
H12G C129 H12I 109.5 . . ?
H12H C129 H12I 109.5 . . ?
N7 C130 Ni3 177.7(4) . . ?
N7 C131 C134 107.5(3) . . ?
N7 C131 C132 107.8(5) . . ?
C134 C131 C132 111.1(5) . . ?
N7 C131 C133 106.9(4) . . ?
C134 C131 C133 111.5(5) . . ?
C132 C131 C133 111.7(5) . . ?
C131 C132 H13A 109.5 . . ?
C131 C132 H13B 109.5 . . ?
H13A C132 H13B 109.5 . . ?
C131 C132 H13C 109.5 . . ?
H13A C132 H13C 109.5 . . ?
H13B C132 H13C 109.5 . . ?
C131 C133 H13D 109.5 . . ?
C131 C133 H13E 109.5 . . ?
H13D C133 H13E 109.5 . . ?
C131 C133 H13F 109.5 . . ?
H13D C133 H13F 109.5 . . ?
H13E C133 H13F 109.5 . . ?
C131 C134 H13G 109.5 . . ?
C131 C134 H13H 109.5 . . ?
H13G C134 H13H 109.5 . . ?
C131 C134 H13I 109.5 . . ?
H13G C134 H13I 109.5 . . ?
H13H C134 H13I 109.5 . . ?
N8 C135 Ni3 151.6(3) . . ?
N8 C135 Ni4 123.4(2) . . ?
Ni3 C135 Ni4 84.92(12) . . ?
N8 C135 Si8 56.06(16) . . ?
Ni3 C135 Si8 152.30(17) . . ?
Ni4 C135 Si8 67.49(11) . . ?
N8 C136 C139 108.6(3) . . ?
N8 C136 C138 108.8(3) . . ?
C139 C136 C138 112.8(3) . . ?
N8 C136 C137 105.9(3) . . ?
C139 C136 C137 110.2(3) . . ?
C138 C136 C137 110.4(3) . . ?
C136 C137 H13J 109.5 . . ?
C136 C137 H13K 109.5 . . ?
H13J C137 H13K 109.5 . . ?
C136 C137 H13L 109.5 . . ?
H13J C137 H13L 109.5 . . ?
H13K C137 H13L 109.5 . . ?
C136 C138 H13M 109.5 . . ?
C136 C138 H13N 109.5 . . ?
H13M C138 H13N 109.5 . . ?
C136 C138 H13O 109.5 . . ?
H13M C138 H13O 109.5 . . ?
H13N C138 H13O 109.5 . . ?
C136 C139 H13P 109.5 . . ?
C136 C139 H13Q 109.5 . . ?
H13P C139 H13Q 109.5 . . ?
C136 C139 H13R 109.5 . . ?
H13P C139 H13R 109.5 . . ?
H13Q C139 H13R 109.5 . . ?
N9 C140 Ni4 177.9(3) . . ?
N9 C141 C143 107.7(3) . . ?
N9 C141 C144 108.0(3) . . ?
C143 C141 C144 110.8(3) . . ?
N9 C141 C142 107.3(3) . . ?
C143 C141 C142 111.2(3) . . ?
C144 C141 C142 111.6(3) . . ?
C141 C142 H14A 109.5 . . ?
C141 C142 H14B 109.5 . . ?
H14A C142 H14B 109.5 . . ?
C141 C142 H14C 109.5 . . ?
H14A C142 H14C 109.5 . . ?
H14B C142 H14C 109.5 . . ?
C141 C143 H14D 109.5 . . ?
C141 C143 H14E 109.5 . . ?
H14D C143 H14E 109.5 . . ?
C141 C143 H14F 109.5 . . ?
H14D C143 H14F 109.5 . . ?
H14E C143 H14F 109.5 . . ?
C141 C144 H14G 109.5 . . ?
C141 C144 H14H 109.5 . . ?
H14G C144 H14H 109.5 . . ?
C141 C144 H14I 109.5 . . ?
H14G C144 H14I 109.5 . . ?
H14H C144 H14I 109.5 . . ?
N10 C145 Ni4 175.7(3) . . ?
N10 C146 C148 109.3(4) . . ?
N10 C146 C149 107.7(3) . . ?
C148 C146 C149 111.3(4) . . ?
N10 C146 C147 106.1(3) . . ?
C148 C146 C147 112.8(4) . . ?
C149 C146 C147 109.3(5) . . ?
C146 C147 H14J 109.5 . . ?
C146 C147 H14K 109.5 . . ?
H14J C147 H14K 109.5 . . ?
C146 C147 H14L 109.5 . . ?
H14J C147 H14L 109.5 . . ?
H14K C147 H14L 109.5 . . ?
C146 C148 H14M 109.5 . . ?
C146 C148 H14N 109.5 . . ?
H14M C148 H14N 109.5 . . ?
C146 C148 H14O 109.5 . . ?
H14M C148 H14O 109.5 . . ?
H14N C148 H14O 109.5 . . ?
C146 C149 H14P 109.5 . . ?
C146 C149 H14Q 109.5 . . ?
H14P C149 H14Q 109.5 . . ?
C146 C149 H14R 109.5 . . ?
H14P C149 H14R 109.5 . . ?
H14Q C149 H14R 109.5 . . ?
C152 C151 C150 109.6(8) . . ?
C153 C152 C151 109.7(7) . . ?
C152 C153 C154 108.3(8) . . ?
C156 C155 C157 117.4(12) . . ?
C155 C156 C156 116.3(12) . 2_656 ?
loop_
_geom_bond_atom_site_label_1
_geom_bond_atom_site_label_2
_geom_bond_distance
_geom_bond_site_symmetry_2
_geom_bond_publ_flag
Ni1 C59 1.782(3) . ?
Ni1 C54 1.795(3) . ?
Ni1 C49 2.029(3) . ?
Ni1 Si3 2.3887(17) . ?
Ni1 Ni2 2.4229(17) . ?
Ni2 C72 1.816(3) . ?
Ni2 C64 1.822(4) . ?
Ni2 C59 1.840(3) . ?
Ni2 Si4 2.2129(16) . ?
Ni2 Si3 2.4042(17) . ?
Ni3 C135 1.784(3) . ?
Ni3 C130 1.789(4) . ?
Ni3 C125 2.019(3) . ?
Ni3 Si7 2.4020(15) . ?
Ni3 Ni4 2.4524(18) . ?
Ni4 C140 1.807(3) . ?
Ni4 C145 1.844(3) . ?
Ni4 C135 1.848(3) . ?
Ni4 Si8 2.2059(15) . ?
Ni4 Si7 2.3710(17) . ?
Si1 N1 1.734(3) . ?
Si1 C49 1.817(3) . ?
Si1 C7 1.859(3) . ?
Si1 C1 1.865(3) . ?
Si1 Si2 2.492(2) . ?
Si2 N1 1.717(3) . ?
Si2 C49 1.824(3) . ?
Si2 C13 1.861(3) . ?
Si2 C19 1.863(3) . ?
Si3 C49 1.803(3) . ?
Si3 C25 1.870(3) . ?
Si3 C31 1.875(3) . ?
Si4 N3 1.743(3) . ?
Si4 C37 1.835(4) . ?
Si4 C43 1.857(4) . ?
Si4 C59 2.091(3) . ?
Si5 N6 1.717(3) . ?
Si5 C125 1.823(3) . ?
Si5 C77 1.853(3) . ?
Si5 C83 1.855(3) . ?
Si5 Si6 2.495(2) . ?
Si6 N6 1.719(3) . ?
Si6 C125 1.827(3) . ?
Si6 C89 1.855(4) . ?
Si6 C95 1.869(4) . ?
Si7 C125 1.784(3) . ?
Si7 C107 1.878(3) . ?
Si7 C101 1.879(3) . ?
Si8 N8 1.751(3) . ?
Si8 C113 1.846(3) . ?
Si8 C119 1.848(3) . ?
Si8 C135 2.104(3) . ?
N1 C50 1.467(4) . ?
N2 C54 1.139(3) . ?
N2 C55 1.435(4) . ?
N3 C59 1.311(3) . ?
N3 C60 1.479(4) . ?
N4 C64 1.144(4) . ?
N4 C65 1.436(5) . ?
N5 C72 1.133(4) . ?
N5 C73 1.428(4) . ?
N6 C126 1.461(4) . ?
N7 C130 1.144(4) . ?
N7 C131 1.445(5) . ?
N8 C135 1.307(3) . ?
N8 C136 1.463(4) . ?
N9 C140 1.139(4) . ?
N9 C141 1.432(4) . ?
N10 C145 1.137(4) . ?
N10 C146 1.432(5) . ?
C1 C2 1.372(4) . ?
C1 C6 1.376(4) . ?
C2 C3 1.373(4) . ?
C2 H2 0.9300 . ?
C3 C4 1.352(5) . ?
C3 H3 0.9300 . ?
C4 C5 1.353(5) . ?
C4 H4 0.9300 . ?
C5 C6 1.381(4) . ?
C5 H5 0.9300 . ?
C6 H6 0.9300 . ?
C7 C8 1.377(4) . ?
C7 C12 1.384(4) . ?
C8 C9 1.362(4) . ?
C8 H8 0.9300 . ?
C9 C10 1.366(5) . ?
C9 H9 0.9300 . ?
C10 C11 1.345(6) . ?
C10 H10 0.9300 . ?
C11 C12 1.378(5) . ?
C11 H11 0.9300 . ?
C12 H12 0.9300 . ?
C13 C14 1.378(5) . ?
C13 C18 1.394(6) . ?
C14 C15 1.363(6) . ?
C14 H14 0.9300 . ?
C15 C16 1.354(9) . ?
C15 H15 0.9300 . ?
C16 C17 1.388(8) . ?
C16 H16 0.9300 . ?
C17 C18 1.363(6) . ?
C17 H17 0.9300 . ?
C18 H18 0.9300 . ?
C19 C24 1.373(5) . ?
C19 C20 1.388(5) . ?
C20 C21 1.367(5) . ?
C20 H20 0.9300 . ?
C21 C22 1.343(5) . ?
C21 H21 0.9300 . ?
C22 C23 1.370(6) . ?
C22 H22 0.9300 . ?
C23 C24 1.368(5) . ?
C23 H23 0.9300 . ?
C24 H24 0.9300 . ?
C25 C26 1.379(4) . ?
C25 C30 1.390(4) . ?
C26 C27 1.363(4) . ?
C26 H26 0.9300 . ?
C27 C28 1.366(5) . ?
C27 H27 0.9300 . ?
C28 C29 1.356(5) . ?
C28 H28 0.9300 . ?
C29 C30 1.370(4) . ?
C29 H29 0.9300 . ?
C30 H30 0.9300 . ?
C31 C32 1.366(5) . ?
C31 C36 1.380(5) . ?
C32 C33 1.363(4) . ?
C32 H32 0.9300 . ?
C33 C34 1.376(7) . ?
C33 H33 0.9300 . ?
C34 C35 1.356(8) . ?
C34 H34 0.9300 . ?
C35 C36 1.398(5) . ?
C35 H35 0.9300 . ?
C36 H36 0.9300 . ?
C37 C42 1.369(4) . ?
C37 C38 1.371(5) . ?
C38 C39 1.355(6) . ?
C38 H38 0.9300 . ?
C39 C40 1.359(5) . ?
C39 H39 0.9300 . ?
C40 C41 1.339(5) . ?
C40 H40 0.9300 . ?
C41 C42 1.358(5) . ?
C41 H41 0.9300 . ?
C42 H42 0.9300 . ?
C43 C48 1.350(6) . ?
C43 C44 1.366(5) . ?
C44 C45 1.397(8) . ?
C44 H44 0.9300 . ?
C45 C46 1.362(10) . ?
C45 H45 0.9300 . ?
C46 C47 1.332(9) . ?
C46 H46 0.9300 . ?
C47 C48 1.350(6) . ?
C47 H47 0.9300 . ?
C48 H48 0.9300 . ?
C50 C51 1.504(6) . ?
C50 C53 1.505(5) . ?
C50 C52 1.520(5) . ?
C51 H51A 0.9600 . ?
C51 H51B 0.9600 . ?
C51 H51C 0.9600 . ?
C52 H52A 0.9600 . ?
C52 H52B 0.9600 . ?
C52 H52C 0.9600 . ?
C53 H53A 0.9600 . ?
C53 H53B 0.9600 . ?
C53 H53C 0.9600 . ?
C55 C57 1.480(5) . ?
C55 C58 1.486(5) . ?
C55 C56 1.497(5) . ?
C56 H56A 0.9600 . ?
C56 H56B 0.9600 . ?
C56 H56C 0.9600 . ?
C57 H57A 0.9600 . ?
C57 H57B 0.9600 . ?
C57 H57C 0.9600 . ?
C58 H58A 0.9600 . ?
C58 H58B 0.9600 . ?
C58 H58C 0.9600 . ?
C60 C61 1.483(6) . ?
C60 C62 1.490(6) . ?
C60 C63 1.513(5) . ?
C61 H61A 0.9600 . ?
C61 H61B 0.9600 . ?
C61 H61C 0.9600 . ?
C62 H62A 0.9600 . ?
C62 H62B 0.9600 . ?
C62 H62C 0.9600 . ?
C63 H63A 0.9600 . ?
C63 H63B 0.9600 . ?
C63 H63C 0.9600 . ?
C65 C71 1.398(10) . ?
C65 C67 1.428(13) . ?
C65 C70 1.436(8) . ?
C65 C68 1.515(12) . ?
C65 C69 1.705(11) . ?
C65 C66 1.718(14) . ?
C66 C71 1.119(14) . ?
C67 C69 1.163(14) . ?
C67 C71 1.448(15) . ?
C68 C70 0.518(11) . ?
C73 C74 1.453(7) . ?
C73 C75 1.462(8) . ?
C73 C76 1.593(8) . ?
C74 H74A 0.9600 . ?
C74 H74B 0.9600 . ?
C74 H74C 0.9600 . ?
C75 H75A 0.9600 . ?
C75 H75B 0.9600 . ?
C75 H75C 0.9600 . ?
C76 H76A 0.9600 . ?
C76 H76B 0.9600 . ?
C76 H76C 0.9600 . ?
C77 C78 1.376(5) . ?
C77 C82 1.392(4) . ?
C78 C79 1.372(4) . ?
C78 H78 0.9300 . ?
C79 C80 1.358(6) . ?
C79 H79 0.9300 . ?
C80 C81 1.368(6) . ?
C80 H80 0.9300 . ?
C81 C82 1.375(5) . ?
C81 H81 0.9300 . ?
C82 H82 0.9300 . ?
C83 C84 1.381(5) . ?
C83 C88 1.386(4) . ?
C84 C85 1.357(5) . ?
C84 H84 0.9300 . ?
C85 C86 1.359(6) . ?
C85 H85 0.9300 . ?
C86 C87 1.347(6) . ?
C86 H86 0.9300 . ?
C87 C88 1.374(5) . ?
C87 H87 0.9300 . ?
C88 H88 0.9300 . ?
C89 C90 1.361(6) . ?
C89 C94 1.391(5) . ?
C90 C91 1.379(6) . ?
C90 H90 0.9300 . ?
C91 C92 1.368(8) . ?
C91 H91 0.9300 . ?
C92 C93 1.334(8) . ?
C92 H92 0.9300 . ?
C93 C94 1.354(6) . ?
C93 H93 0.9300 . ?
C94 H94 0.9300 . ?
C95 C96 1.378(6) . ?
C95 C100 1.398(6) . ?
C96 C97 1.364(6) . ?
C96 H96 0.9300 . ?
C97 C98 1.387(11) . ?
C97 H97 0.9300 . ?
C98 C99 1.342(12) . ?
C98 H98 0.9300 . ?
C99 C100 1.388(7) . ?
C99 H99 0.9300 . ?
C100 H100 0.9300 . ?
C101 C102 1.375(4) . ?
C101 C106 1.389(4) . ?
C102 C103 1.373(4) . ?
C102 H102 0.9300 . ?
C103 C104 1.364(4) . ?
C103 H103 0.9300 . ?
C104 C105 1.368(4) . ?
C104 H104 0.9300 . ?
C105 C106 1.371(4) . ?
C105 H105 0.9300 . ?
C106 H106 0.9300 . ?
C107 C108 1.362(5) . ?
C107 C112 1.380(5) . ?
C108 C109 1.377(5) . ?
C108 H108 0.9300 . ?
C109 C110 1.357(7) . ?
C109 H109 0.9300 . ?
C110 C111 1.342(7) . ?
C110 H110 0.9300 . ?
C111 C112 1.368(5) . ?
C111 H111 0.9300 . ?
C112 H112 0.9300 . ?
C113 C114 1.366(5) . ?
C113 C118 1.374(4) . ?
C114 C115 1.376(5) . ?
C114 H114 0.9300 . ?
C115 C116 1.367(5) . ?
C115 H115 0.9300 . ?
C116 C117 1.343(6) . ?
C116 H116 0.9300 . ?
C117 C118 1.369(5) . ?
C117 H117 0.9300 . ?
C118 H118 0.9300 . ?
C119 C124 1.366(5) . ?
C119 C120 1.379(5) . ?
C120 C121 1.360(5) . ?
C120 H120 0.9300 . ?
C121 C122 1.359(6) . ?
C121 H121 0.9300 . ?
C122 C123 1.350(6) . ?
C122 H122 0.9300 . ?
C123 C124 1.374(5) . ?
C123 H123 0.9300 . ?
C124 H124 0.9300 . ?
C126 C129 1.501(5) . ?
C126 C128 1.504(6) . ?
C126 C127 1.509(5) . ?
C127 H12A 0.9600 . ?
C127 H12B 0.9600 . ?
C127 H12C 0.9600 . ?
C128 H12D 0.9600 . ?
C128 H12E 0.9600 . ?
C128 H12F 0.9600 . ?
C129 H12G 0.9600 . ?
C129 H12H 0.9600 . ?
C129 H12I 0.9600 . ?
C131 C134 1.483(6) . ?
C131 C132 1.484(8) . ?
C131 C133 1.508(8) . ?
C132 H13A 0.9600 . ?
C132 H13B 0.9600 . ?
C132 H13C 0.9600 . ?
C133 H13D 0.9600 . ?
C133 H13E 0.9600 . ?
C133 H13F 0.9600 . ?
C134 H13G 0.9600 . ?
C134 H13H 0.9600 . ?
C134 H13I 0.9600 . ?
C136 C139 1.488(5) . ?
C136 C138 1.506(5) . ?
C136 C137 1.519(5) . ?
C137 H13J 0.9600 . ?
C137 H13K 0.9600 . ?
C137 H13L 0.9600 . ?
C138 H13M 0.9600 . ?
C138 H13N 0.9600 . ?
C138 H13O 0.9600 . ?
C139 H13P 0.9600 . ?
C139 H13Q 0.9600 . ?
C139 H13R 0.9600 . ?
C141 C143 1.497(4) . ?
C141 C144 1.497(5) . ?
C141 C142 1.498(5) . ?
C142 H14A 0.9600 . ?
C142 H14B 0.9600 . ?
C142 H14C 0.9600 . ?
C143 H14D 0.9600 . ?
C143 H14E 0.9600 . ?
C143 H14F 0.9600 . ?
C144 H14G 0.9600 . ?
C144 H14H 0.9600 . ?
C144 H14I 0.9600 . ?
C146 C148 1.465(7) . ?
C146 C149 1.481(6) . ?
C146 C147 1.524(7) . ?
C147 H14J 0.9600 . ?
C147 H14K 0.9600 . ?
C147 H14L 0.9600 . ?
C148 H14M 0.9600 . ?
C148 H14N 0.9600 . ?
C148 H14O 0.9600 . ?
C149 H14P 0.9600 . ?
C149 H14Q 0.9600 . ?
C149 H14R 0.9600 . ?
C150 C151 1.467(13) . ?
C151 C152 1.416(11) . ?
C152 C153 1.379(11) . ?
C153 C154 1.414(14) . ?
C155 C156 1.241(14) . ?
C155 C157 1.59(2) . ?
C156 C156 1.509(19) 2_656 ?
loop_
_geom_torsion_atom_site_label_1
_geom_torsion_atom_site_label_2
_geom_torsion_atom_site_label_3
_geom_torsion_atom_site_label_4
_geom_torsion
_geom_torsion_site_symmetry_1
_geom_torsion_site_symmetry_2
_geom_torsion_site_symmetry_3
_geom_torsion_site_symmetry_4
_geom_torsion_publ_flag
C49 Si2 N1 C50 176.9(3) . . . . ?
C13 Si2 N1 C50 55.8(4) . . . . ?
C19 Si2 N1 C50 -63.2(3) . . . . ?
Si1 Si2 N1 C50 174.0(4) . . . . ?
C49 Si2 N1 Si1 2.89(12) . . . . ?
C13 Si2 N1 Si1 -118.25(16) . . . . ?
C19 Si2 N1 Si1 122.75(14) . . . . ?
C49 Si1 N1 C50 -177.1(3) . . . . ?
C7 Si1 N1 C50 59.2(3) . . . . ?
C1 Si1 N1 C50 -61.2(3) . . . . ?
Si2 Si1 N1 C50 -174.2(4) . . . . ?
C49 Si1 N1 Si2 -2.90(12) . . . . ?
C7 Si1 N1 Si2 -126.63(14) . . . . ?
C1 Si1 N1 Si2 113.03(15) . . . . ?
C37 Si4 N3 C59 126.5(2) . . . . ?
C43 Si4 N3 C59 -114.6(2) . . . . ?
Ni2 Si4 N3 C59 6.27(19) . . . . ?
C37 Si4 N3 C60 -74.3(5) . . . . ?
C43 Si4 N3 C60 44.6(5) . . . . ?
C59 Si4 N3 C60 159.2(6) . . . . ?
Ni2 Si4 N3 C60 165.5(4) . . . . ?
C125 Si5 N6 C126 -178.9(3) . . . . ?
C77 Si5 N6 C126 65.1(3) . . . . ?
C83 Si5 N6 C126 -54.3(3) . . . . ?
Si6 Si5 N6 C126 176.5(4) . . . . ?
C125 Si5 N6 Si6 4.62(12) . . . . ?
C77 Si5 N6 Si6 -111.32(14) . . . . ?
C83 Si5 N6 Si6 129.24(14) . . . . ?
C125 Si6 N6 C126 178.9(3) . . . . ?
C89 Si6 N6 C126 -59.6(3) . . . . ?
C95 Si6 N6 C126 60.7(3) . . . . ?
Si5 Si6 N6 C126 -176.5(4) . . . . ?
C125 Si6 N6 Si5 -4.61(12) . . . . ?
C89 Si6 N6 Si5 116.85(16) . . . . ?
C95 Si6 N6 Si5 -122.79(16) . . . . ?
C113 Si8 N8 C135 -116.5(2) . . . . ?
C119 Si8 N8 C135 123.90(19) . . . . ?
Ni4 Si8 N8 C135 3.06(16) . . . . ?
C113 Si8 N8 C136 47.9(4) . . . . ?
C119 Si8 N8 C136 -71.6(4) . . . . ?
C135 Si8 N8 C136 164.5(5) . . . . ?
Ni4 Si8 N8 C136 167.5(4) . . . . ?
N1 Si1 C1 C2 119.1(3) . . . . ?
C49 Si1 C1 C2 -139.3(3) . . . . ?
C7 Si1 C1 C2 -9.0(3) . . . . ?
Si2 Si1 C1 C2 168.1(2) . . . . ?
N1 Si1 C1 C6 -64.5(3) . . . . ?
C49 Si1 C1 C6 37.1(3) . . . . ?
C7 Si1 C1 C6 167.3(3) . . . . ?
Si2 Si1 C1 C6 -15.6(3) . . . . ?
C6 C1 C2 C3 1.1(5) . . . . ?
Si1 C1 C2 C3 177.5(3) . . . . ?
C1 C2 C3 C4 -1.4(5) . . . . ?
C2 C3 C4 C5 0.2(6) . . . . ?
C3 C4 C5 C6 1.1(6) . . . . ?
C2 C1 C6 C5 0.3(5) . . . . ?
Si1 C1 C6 C5 -176.3(3) . . . . ?
C4 C5 C6 C1 -1.3(5) . . . . ?
N1 Si1 C7 C8 130.5(2) . . . . ?
C49 Si1 C7 C8 23.1(3) . . . . ?
C1 Si1 C7 C8 -103.3(3) . . . . ?
Si2 Si1 C7 C8 80.1(3) . . . . ?
N1 Si1 C7 C12 -56.4(3) . . . . ?
C49 Si1 C7 C12 -163.7(2) . . . . ?
C1 Si1 C7 C12 69.8(3) . . . . ?
Si2 Si1 C7 C12 -106.8(3) . . . . ?
C12 C7 C8 C9 -1.1(4) . . . . ?
Si1 C7 C8 C9 172.5(2) . . . . ?
C7 C8 C9 C10 1.0(5) . . . . ?
C8 C9 C10 C11 -0.3(5) . . . . ?
C9 C10 C11 C12 -0.2(5) . . . . ?
C10 C11 C12 C7 0.0(5) . . . . ?
C8 C7 C12 C11 0.6(4) . . . . ?
Si1 C7 C12 C11 -172.7(3) . . . . ?
N1 Si2 C13 C14 26.5(4) . . . . ?
C49 Si2 C13 C14 -76.4(4) . . . . ?
C19 Si2 C13 C14 152.9(4) . . . . ?
Si1 Si2 C13 C14 -21.4(5) . . . . ?
N1 Si2 C13 C18 -159.6(4) . . . . ?
C49 Si2 C13 C18 97.5(4) . . . . ?
C19 Si2 C13 C18 -33.2(4) . . . . ?
Si1 Si2 C13 C18 152.5(3) . . . . ?
C18 C13 C14 C15 0.7(8) . . . . ?
Si2 C13 C14 C15 175.0(5) . . . . ?
C13 C14 C15 C16 -2.3(10) . . . . ?
C14 C15 C16 C17 1.5(12) . . . . ?
C15 C16 C17 C18 0.7(12) . . . . ?
C16 C17 C18 C13 -2.3(10) . . . . ?
C14 C13 C18 C17 1.6(8) . . . . ?
Si2 C13 C18 C17 -172.5(5) . . . . ?
N1 Si2 C19 C24 -160.7(2) . . . . ?
C49 Si2 C19 C24 -55.5(3) . . . . ?
C13 Si2 C19 C24 76.7(3) . . . . ?
Si1 Si2 C19 C24 -109.6(2) . . . . ?
N1 Si2 C19 C20 19.8(3) . . . . ?
C49 Si2 C19 C20 125.0(3) . . . . ?
C13 Si2 C19 C20 -102.8(3) . . . . ?
Si1 Si2 C19 C20 70.9(3) . . . . ?
C24 C19 C20 C21 -1.0(5) . . . . ?
Si2 C19 C20 C21 178.5(3) . . . . ?
C19 C20 C21 C22 1.1(5) . . . . ?
C20 C21 C22 C23 -1.2(6) . . . . ?
C21 C22 C23 C24 1.4(6) . . . . ?
C22 C23 C24 C19 -1.4(5) . . . . ?
C20 C19 C24 C23 1.2(5) . . . . ?
Si2 C19 C24 C23 -178.4(3) . . . . ?
C49 Si3 C25 C26 -88.1(3) . . . . ?
C31 Si3 C25 C26 41.4(3) . . . . ?
Ni1 Si3 C25 C26 -147.0(2) . . . . ?
Ni2 Si3 C25 C26 149.2(2) . . . . ?
C49 Si3 C25 C30 92.5(2) . . . . ?
C31 Si3 C25 C30 -138.0(2) . . . . ?
Ni1 Si3 C25 C30 33.5(2) . . . . ?
Ni2 Si3 C25 C30 -30.2(2) . . . . ?
C30 C25 C26 C27 -0.4(4) . . . . ?
Si3 C25 C26 C27 -179.9(2) . . . . ?
C25 C26 C27 C28 0.9(5) . . . . ?
C26 C27 C28 C29 -1.5(5) . . . . ?
C27 C28 C29 C30 1.6(5) . . . . ?
C28 C29 C30 C25 -1.2(5) . . . . ?
C26 C25 C30 C29 0.6(4) . . . . ?
Si3 C25 C30 C29 -180.0(2) . . . . ?
C49 Si3 C31 C32 158.3(3) . . . . ?
C25 Si3 C31 C32 34.0(3) . . . . ?
Ni1 Si3 C31 C32 -129.3(3) . . . . ?
Ni2 Si3 C31 C32 -77.9(3) . . . . ?
C49 Si3 C31 C36 -21.2(3) . . . . ?
C25 Si3 C31 C36 -145.5(3) . . . . ?
Ni1 Si3 C31 C36 51.2(4) . . . . ?
Ni2 Si3 C31 C36 102.6(3) . . . . ?
C36 C31 C32 C33 0.2(5) . . . . ?
Si3 C31 C32 C33 -179.4(3) . . . . ?
C31 C32 C33 C34 -0.4(6) . . . . ?
C32 C33 C34 C35 0.9(7) . . . . ?
C33 C34 C35 C36 -1.2(7) . . . . ?
C32 C31 C36 C35 -0.5(5) . . . . ?
Si3 C31 C36 C35 179.1(3) . . . . ?
C34 C35 C36 C31 1.0(7) . . . . ?
N3 Si4 C37 C42 169.2(3) . . . . ?
C43 Si4 C37 C42 50.9(3) . . . . ?
C59 Si4 C37 C42 -151.0(2) . . . . ?
Ni2 Si4 C37 C42 -90.5(3) . . . . ?
N3 Si4 C37 C38 -12.8(4) . . . . ?
C43 Si4 C37 C38 -131.1(3) . . . . ?
C59 Si4 C37 C38 27.0(4) . . . . ?
Ni2 Si4 C37 C38 87.5(3) . . . . ?
C42 C37 C38 C39 -2.0(6) . . . . ?
Si4 C37 C38 C39 179.9(4) . . . . ?
C37 C38 C39 C40 1.0(7) . . . . ?
C38 C39 C40 C41 0.8(7) . . . . ?
C39 C40 C41 C42 -1.5(6) . . . . ?
C40 C41 C42 C37 0.3(6) . . . . ?
C38 C37 C42 C41 1.4(5) . . . . ?
Si4 C37 C42 C41 179.5(3) . . . . ?
N3 Si4 C43 C48 73.5(3) . . . . ?
C37 Si4 C43 C48 -166.7(3) . . . . ?
C59 Si4 C43 C48 32.9(4) . . . . ?
Ni2 Si4 C43 C48 -25.8(3) . . . . ?
N3 Si4 C43 C44 -105.8(4) . . . . ?
C37 Si4 C43 C44 13.9(4) . . . . ?
C59 Si4 C43 C44 -146.4(3) . . . . ?
Ni2 Si4 C43 C44 154.9(3) . . . . ?
C48 C43 C44 C45 3.8(8) . . . . ?
Si4 C43 C44 C45 -176.8(5) . . . . ?
C43 C44 C45 C46 -0.8(10) . . . . ?
C44 C45 C46 C47 -4.9(10) . . . . ?
C45 C46 C47 C48 7.4(9) . . . . ?
C44 C43 C48 C47 -1.4(7) . . . . ?
Si4 C43 C48 C47 179.2(4) . . . . ?
C46 C47 C48 C43 -4.4(9) . . . . ?
C25 Si3 C49 Si1 27.5(2) . . . . ?
C31 Si3 C49 Si1 -92.32(19) . . . . ?
Ni1 Si3 C49 Si1 122.25(18) . . . . ?
Ni2 Si3 C49 Si1 148.21(13) . . . . ?
C25 Si3 C49 Si2 163.0(2) . . . . ?
C31 Si3 C49 Si2 43.2(3) . . . . ?
Ni1 Si3 C49 Si2 -102.2(2) . . . . ?
Ni2 Si3 C49 Si2 -76.3(2) . . . . ?
C25 Si3 C49 Ni1 -94.77(12) . . . . ?
C31 Si3 C49 Ni1 145.42(12) . . . . ?
Ni2 Si3 C49 Ni1 25.96(9) . . . . ?
N1 Si1 C49 Si3 155.14(17) . . . . ?
C7 Si1 C49 Si3 -82.9(2) . . . . ?
C1 Si1 C49 Si3 38.4(2) . . . . ?
Si2 Si1 C49 Si3 152.4(2) . . . . ?
N1 Si1 C49 Si2 2.73(11) . . . . ?
C7 Si1 C49 Si2 124.69(13) . . . . ?
C1 Si1 C49 Si2 -113.98(14) . . . . ?
N1 Si1 C49 Ni1 -106.37(19) . . . . ?
C7 Si1 C49 Ni1 15.6(2) . . . . ?
C1 Si1 C49 Ni1 136.92(17) . . . . ?
Si2 Si1 C49 Ni1 -109.1(2) . . . . ?
N1 Si2 C49 Si3 -148.2(2) . . . . ?
C13 Si2 C49 Si3 -33.8(3) . . . . ?
C19 Si2 C49 Si3 91.3(2) . . . . ?
Si1 Si2 C49 Si3 -145.4(3) . . . . ?
N1 Si2 C49 Si1 -2.76(12) . . . . ?
C13 Si2 C49 Si1 111.64(17) . . . . ?
C19 Si2 C49 Si1 -123.25(14) . . . . ?
N1 Si2 C49 Ni1 121.47(15) . . . . ?
C13 Si2 C49 Ni1 -124.13(17) . . . . ?
C19 Si2 C49 Ni1 0.98(19) . . . . ?
Si1 Si2 C49 Ni1 124.23(17) . . . . ?
Si2 N1 C50 C51 107.8(4) . . . . ?
Si1 N1 C50 C51 -80.3(4) . . . . ?
Si2 N1 C50 C53 -12.9(5) . . . . ?
Si1 N1 C50 C53 158.9(3) . . . . ?
Si2 N1 C50 C52 -132.2(3) . . . . ?
Si1 N1 C50 C52 39.6(5) . . . . ?
C60 N3 C59 Ni1 -2.0(8) . . . . ?
Si4 N3 C59 Ni1 162.0(5) . . . . ?
C60 N3 C59 Ni2 -173.2(3) . . . . ?
Si4 N3 C59 Ni2 -9.1(3) . . . . ?
C60 N3 C59 Si4 -164.1(4) . . . . ?
C54 Ni1 C59 N3 3.3(6) . . . . ?
C49 Ni1 C59 N3 -173.1(4) . . . . ?
Si3 Ni1 C59 N3 168.6(5) . . . . ?
Ni2 Ni1 C59 N3 -172.6(6) . . . . ?
C54 Ni1 C59 Ni2 175.88(11) . . . . ?
C49 Ni1 C59 Ni2 -0.5(3) . . . . ?
Si3 Ni1 C59 Ni2 -18.75(12) . . . . ?
C54 Ni1 C59 Si4 152.8(3) . . . . ?
C49 Ni1 C59 Si4 -23.6(6) . . . . ?
Si3 Ni1 C59 Si4 -41.8(4) . . . . ?
Ni2 Ni1 C59 Si4 -23.1(3) . . . . ?
C72 Ni2 C59 N3 88.4(3) . . . . ?
C64 Ni2 C59 N3 -68.2(3) . . . . ?
Si4 Ni2 C59 N3 8.1(2) . . . . ?
Si3 Ni2 C59 N3 -165.8(3) . . . . ?
Ni1 Ni2 C59 N3 175.8(4) . . . . ?
C72 Ni2 C59 Ni1 -87.46(18) . . . . ?
C64 Ni2 C59 Ni1 116.00(15) . . . . ?
Si4 Ni2 C59 Ni1 -167.69(15) . . . . ?
Si3 Ni2 C59 Ni1 18.40(12) . . . . ?
C72 Ni2 C59 Si4 80.23(17) . . . . ?
C64 Ni2 C59 Si4 -76.31(16) . . . . ?
Si3 Ni2 C59 Si4 -173.92(5) . . . . ?
Ni1 Ni2 C59 Si4 167.69(15) . . . . ?
C59 N3 C60 C61 60.4(5) . . . . ?
Si4 N3 C60 C61 -92.6(4) . . . . ?
C59 N3 C60 C62 -62.5(5) . . . . ?
Si4 N3 C60 C62 144.5(4) . . . . ?
C59 N3 C60 C63 178.9(4) . . . . ?
Si4 N3 C60 C63 26.0(6) . . . . ?
C67 C65 C66 C71 7.3(11) . . . . ?
N4 C65 C66 C71 -110.9(9) . . . . ?
C70 C65 C66 C71 138.3(9) . . . . ?
C68 C65 C66 C71 133.7(10) . . . . ?
C69 C65 C66 C71 10.6(15) . . . . ?
C71 C65 C67 C69 -177.4(11) . . . . ?
N4 C65 C67 C69 -77.7(9) . . . . ?
C70 C65 C67 C69 71.2(11) . . . . ?
C68 C65 C67 C69 52.2(11) . . . . ?
C66 C65 C67 C69 177.2(9) . . . . ?
N4 C65 C67 C71 99.7(7) . . . . ?
C70 C65 C67 C71 -111.4(8) . . . . ?
C68 C65 C67 C71 -130.4(8) . . . . ?
C69 C65 C67 C71 177.4(11) . . . . ?
C66 C65 C67 C71 -5.4(8) . . . . ?
C71 C65 C68 C70 56(2) . . . . ?
C67 C65 C68 C70 131.8(17) . . . . ?
N4 C65 C68 C70 -95.4(17) . . . . ?
C69 C65 C68 C70 164.0(18) . . . . ?
C66 C65 C68 C70 13.5(19) . . . . ?
C71 C67 C69 C65 -3.4(14) . . . . ?
C71 C65 C69 C67 2.4(10) . . . . ?
N4 C65 C69 C67 116.1(9) . . . . ?
C70 C65 C69 C67 -129.2(9) . . . . ?
C68 C65 C69 C67 -134.9(10) . . . . ?
C66 C65 C69 C67 -4.7(15) . . . . ?
C71 C65 C70 C68 -136.6(17) . . . . ?
C67 C65 C70 C68 -59(2) . . . . ?
N4 C65 C70 C68 91.8(18) . . . . ?
C69 C65 C70 C68 -16.7(18) . . . . ?
C66 C65 C70 C68 -167.7(18) . . . . ?
C65 C66 C71 C67 -12.3(18) . . . . ?
C67 C65 C71 C66 -171.8(12) . . . . ?
N4 C65 C71 C66 79.2(10) . . . . ?
C70 C65 C71 C66 -52.4(11) . . . . ?
C68 C65 C71 C66 -72.2(13) . . . . ?
C69 C65 C71 C66 -173.6(9) . . . . ?
N4 C65 C71 C67 -109.0(7) . . . . ?
C70 C65 C71 C67 119.4(9) . . . . ?
C68 C65 C71 C67 99.6(11) . . . . ?
C69 C65 C71 C67 -1.8(8) . . . . ?
C66 C65 C71 C67 171.8(12) . . . . ?
C69 C67 C71 C66 18(3) . . . . ?
C65 C67 C71 C66 14(2) . . . . ?
C69 C67 C71 C65 4.0(17) . . . . ?
C72 N5 C73 C74 -83.9(16) . . . . ?
C72 N5 C73 C75 140.6(14) . . . . ?
C72 N5 C73 C76 31.6(17) . . . . ?
N6 Si5 C77 C78 -161.6(3) . . . . ?
C125 Si5 C77 C78 97.3(3) . . . . ?
C83 Si5 C77 C78 -32.5(3) . . . . ?
Si6 Si5 C77 C78 150.0(2) . . . . ?
N6 Si5 C77 C82 26.0(3) . . . . ?
C125 Si5 C77 C82 -75.1(3) . . . . ?
C83 Si5 C77 C82 155.2(3) . . . . ?
Si6 Si5 C77 C82 -22.4(3) . . . . ?
C82 C77 C78 C79 0.2(5) . . . . ?
Si5 C77 C78 C79 -172.6(3) . . . . ?
C77 C78 C79 C80 1.1(6) . . . . ?
C78 C79 C80 C81 -1.1(6) . . . . ?
C79 C80 C81 C82 -0.1(6) . . . . ?
C80 C81 C82 C77 1.3(6) . . . . ?
C78 C77 C82 C81 -1.4(5) . . . . ?
Si5 C77 C82 C81 171.2(3) . . . . ?
N6 Si5 C83 C84 62.8(3) . . . . ?
C125 Si5 C83 C84 171.7(3) . . . . ?
C77 Si5 C83 C84 -62.4(3) . . . . ?
Si6 Si5 C83 C84 114.5(3) . . . . ?
N6 Si5 C83 C88 -124.9(3) . . . . ?
C125 Si5 C83 C88 -16.1(3) . . . . ?
C77 Si5 C83 C88 109.8(3) . . . . ?
Si6 Si5 C83 C88 -73.2(3) . . . . ?
C88 C83 C84 C85 0.9(6) . . . . ?
Si5 C83 C84 C85 173.4(4) . . . . ?
C83 C84 C85 C86 0.1(7) . . . . ?
C84 C85 C86 C87 -1.9(8) . . . . ?
C85 C86 C87 C88 2.7(7) . . . . ?
C86 C87 C88 C83 -1.7(6) . . . . ?
C84 C83 C88 C87 -0.1(5) . . . . ?
Si5 C83 C88 C87 -172.9(3) . . . . ?
N6 Si6 C89 C90 -73.5(3) . . . . ?
C125 Si6 C89 C90 30.1(3) . . . . ?
C95 Si6 C89 C90 159.5(3) . . . . ?
Si5 Si6 C89 C90 -25.1(3) . . . . ?
N6 Si6 C89 C94 102.1(3) . . . . ?
C125 Si6 C89 C94 -154.3(3) . . . . ?
C95 Si6 C89 C94 -25.0(3) . . . . ?
Si5 Si6 C89 C94 150.5(3) . . . . ?
C94 C89 C90 C91 -0.9(5) . . . . ?
Si6 C89 C90 C91 175.0(3) . . . . ?
C89 C90 C91 C92 1.2(6) . . . . ?
C90 C91 C92 C93 -0.4(7) . . . . ?
C91 C92 C93 C94 -0.7(7) . . . . ?
C92 C93 C94 C89 1.0(7) . . . . ?
C90 C89 C94 C93 -0.2(6) . . . . ?
Si6 C89 C94 C93 -175.9(3) . . . . ?
N6 Si6 C95 C96 5.4(4) . . . . ?
C125 Si6 C95 C96 -97.9(3) . . . . ?
C89 Si6 C95 C96 130.7(3) . . . . ?
Si5 Si6 C95 C96 -44.4(4) . . . . ?
N6 Si6 C95 C100 -179.4(3) . . . . ?
C125 Si6 C95 C100 77.3(3) . . . . ?
C89 Si6 C95 C100 -54.1(3) . . . . ?
Si5 Si6 C95 C100 130.8(3) . . . . ?
C100 C95 C96 C97 -0.7(6) . . . . ?
Si6 C95 C96 C97 174.5(4) . . . . ?
C95 C96 C97 C98 0.3(8) . . . . ?
C96 C97 C98 C99 0.0(9) . . . . ?
C97 C98 C99 C100 0.0(9) . . . . ?
C98 C99 C100 C95 -0.4(7) . . . . ?
C96 C95 C100 C99 0.7(6) . . . . ?
Si6 C95 C100 C99 -174.9(3) . . . . ?
C125 Si7 C101 C102 100.6(2) . . . . ?
C107 Si7 C101 C102 -24.6(3) . . . . ?
Ni4 Si7 C101 C102 -138.1(2) . . . . ?
Ni3 Si7 C101 C102 158.0(2) . . . . ?
C125 Si7 C101 C106 -80.2(2) . . . . ?
C107 Si7 C101 C106 154.6(2) . . . . ?
Ni4 Si7 C101 C106 41.1(2) . . . . ?
Ni3 Si7 C101 C106 -22.8(2) . . . . ?
C106 C101 C102 C103 0.1(4) . . . . ?
Si7 C101 C102 C103 179.3(2) . . . . ?
C101 C102 C103 C104 -0.4(4) . . . . ?
C102 C103 C104 C105 0.6(4) . . . . ?
C103 C104 C105 C106 -0.6(4) . . . . ?
C104 C105 C106 C101 0.4(4) . . . . ?
C102 C101 C106 C105 -0.1(4) . . . . ?
Si7 C101 C106 C105 -179.4(2) . . . . ?
C125 Si7 C107 C108 124.2(3) . . . . ?
C101 Si7 C107 C108 -114.0(3) . . . . ?
Ni4 Si7 C107 C108 -1.5(3) . . . . ?
Ni3 Si7 C107 C108 60.4(4) . . . . ?
C125 Si7 C107 C112 -57.9(3) . . . . ?
C101 Si7 C107 C112 63.9(3) . . . . ?
Ni4 Si7 C107 C112 176.4(2) . . . . ?
Ni3 Si7 C107 C112 -121.7(3) . . . . ?
C112 C107 C108 C109 -0.9(5) . . . . ?
Si7 C107 C108 C109 177.0(3) . . . . ?
C107 C108 C109 C110 0.3(7) . . . . ?
C108 C109 C110 C111 0.5(7) . . . . ?
C109 C110 C111 C112 -0.7(7) . . . . ?
C110 C111 C112 C107 0.0(6) . . . . ?
C108 C107 C112 C111 0.8(5) . . . . ?
Si7 C107 C112 C111 -177.4(3) . . . . ?
N8 Si8 C113 C114 67.8(3) . . . . ?
C119 Si8 C113 C114 -173.7(3) . . . . ?
C135 Si8 C113 C114 28.7(3) . . . . ?
Ni4 Si8 C113 C114 -29.7(3) . . . . ?
N8 Si8 C113 C118 -104.9(3) . . . . ?
C119 Si8 C113 C118 13.6(4) . . . . ?
C135 Si8 C113 C118 -144.0(3) . . . . ?
Ni4 Si8 C113 C118 157.6(3) . . . . ?
C118 C113 C114 C115 1.1(6) . . . . ?
Si8 C113 C114 C115 -171.9(3) . . . . ?
C113 C114 C115 C116 -1.4(6) . . . . ?
C114 C115 C116 C117 0.4(7) . . . . ?
C115 C116 C117 C118 0.8(7) . . . . ?
C116 C117 C118 C113 -1.1(7) . . . . ?
C114 C113 C118 C117 0.1(6) . . . . ?
Si8 C113 C118 C117 172.9(4) . . . . ?
N8 Si8 C119 C124 -20.2(3) . . . . ?
C113 Si8 C119 C124 -136.4(3) . . . . ?
C135 Si8 C119 C124 19.2(4) . . . . ?
Ni4 Si8 C119 C124 79.8(3) . . . . ?
N8 Si8 C119 C120 162.6(2) . . . . ?
C113 Si8 C119 C120 46.4(3) . . . . ?
C135 Si8 C119 C120 -158.0(2) . . . . ?
Ni4 Si8 C119 C120 -97.4(3) . . . . ?
C124 C119 C120 C121 2.2(5) . . . . ?
Si8 C119 C120 C121 179.5(3) . . . . ?
C119 C120 C121 C122 -0.3(6) . . . . ?
C120 C121 C122 C123 -1.3(6) . . . . ?
C121 C122 C123 C124 0.8(7) . . . . ?
C120 C119 C124 C123 -2.7(5) . . . . ?
Si8 C119 C124 C123 -179.9(3) . . . . ?
C122 C123 C124 C119 1.2(6) . . . . ?
C107 Si7 C125 Si5 80.8(2) . . . . ?
C101 Si7 C125 Si5 -37.5(2) . . . . ?
Ni4 Si7 C125 Si5 -155.51(16) . . . . ?
Ni3 Si7 C125 Si5 -128.4(2) . . . . ?
C107 Si7 C125 Si6 -58.1(2) . . . . ?
C101 Si7 C125 Si6 -176.35(17) . . . . ?
Ni4 Si7 C125 Si6 65.6(2) . . . . ?
Ni3 Si7 C125 Si6 92.8(2) . . . . ?
C107 Si7 C125 Ni3 -150.83(13) . . . . ?
C101 Si7 C125 Ni3 90.88(13) . . . . ?
Ni4 Si7 C125 Ni3 -27.14(10) . . . . ?
N6 Si5 C125 Si7 -156.0(2) . . . . ?
C77 Si5 C125 Si7 -40.4(2) . . . . ?
C83 Si5 C125 Si7 79.6(2) . . . . ?
Si6 Si5 C125 Si7 -151.7(3) . . . . ?
N6 Si5 C125 Si6 -4.35(12) . . . . ?
C77 Si5 C125 Si6 111.31(15) . . . . ?
C83 Si5 C125 Si6 -128.71(13) . . . . ?
N6 Si5 C125 Ni3 95.60(19) . . . . ?
C77 Si5 C125 Ni3 -148.75(17) . . . . ?
C83 Si5 C125 Ni3 -28.8(2) . . . . ?
Si6 Si5 C125 Ni3 99.9(2) . . . . ?
N6 Si6 C125 Si7 155.1(2) . . . . ?
C89 Si6 C125 Si7 38.3(3) . . . . ?
C95 Si6 C125 Si7 -85.8(3) . . . . ?
Si5 Si6 C125 Si7 150.8(3) . . . . ?
N6 Si6 C125 Si5 4.34(12) . . . . ?
C89 Si6 C125 Si5 -112.50(15) . . . . ?
C95 Si6 C125 Si5 123.48(18) . . . . ?
N6 Si6 C125 Ni3 -121.66(14) . . . . ?
C89 Si6 C125 Ni3 121.50(16) . . . . ?
C95 Si6 C125 Ni3 -2.5(2) . . . . ?
Si5 Si6 C125 Ni3 -126.00(17) . . . . ?
Si5 N6 C126 C129 -167.1(3) . . . . ?
Si6 N6 C126 C129 8.0(5) . . . . ?
Si5 N6 C126 C128 73.1(4) . . . . ?
Si6 N6 C126 C128 -111.7(3) . . . . ?
Si5 N6 C126 C127 -46.2(4) . . . . ?
Si6 N6 C126 C127 128.9(3) . . . . ?
C136 N8 C135 Ni3 10.1(7) . . . . ?
Si8 N8 C135 Ni3 178.5(4) . . . . ?
C136 N8 C135 Ni4 -172.8(3) . . . . ?
Si8 N8 C135 Ni4 -4.4(2) . . . . ?
C136 N8 C135 Si8 -168.4(4) . . . . ?
C130 Ni3 C135 N8 -6.4(5) . . . . ?
C125 Ni3 C135 N8 173.5(4) . . . . ?
Si7 Ni3 C135 N8 -165.9(5) . . . . ?
Ni4 Ni3 C135 N8 177.6(6) . . . . ?
C130 Ni3 C135 Ni4 175.98(13) . . . . ?
C125 Ni3 C135 Ni4 -4.1(3) . . . . ?
Si7 Ni3 C135 Ni4 16.45(10) . . . . ?
C130 Ni3 C135 Si8 170.9(3) . . . . ?
C125 Ni3 C135 Si8 -9.2(5) . . . . ?
Si7 Ni3 C135 Si8 11.3(4) . . . . ?
Ni4 Ni3 C135 Si8 -5.1(3) . . . . ?
C140 Ni4 C135 N8 72.4(3) . . . . ?
C145 Ni4 C135 N8 -84.9(3) . . . . ?
Si8 Ni4 C135 N8 3.9(2) . . . . ?
Si7 Ni4 C135 N8 164.8(2) . . . . ?
Ni3 Ni4 C135 N8 -178.6(3) . . . . ?
C140 Ni4 C135 Ni3 -108.95(16) . . . . ?
C145 Ni4 C135 Ni3 93.75(15) . . . . ?
Si8 Ni4 C135 Ni3 -177.42(13) . . . . ?
Si7 Ni4 C135 Ni3 -16.60(10) . . . . ?
C140 Ni4 C135 Si8 68.47(17) . . . . ?
C145 Ni4 C135 Si8 -88.82(14) . . . . ?
Si7 Ni4 C135 Si8 160.82(4) . . . . ?
Ni3 Ni4 C135 Si8 177.42(13) . . . . ?
C135 N8 C136 C139 -64.0(4) . . . . ?
Si8 N8 C136 C139 136.0(3) . . . . ?
C135 N8 C136 C138 59.1(4) . . . . ?
Si8 N8 C136 C138 -100.9(4) . . . . ?
C135 N8 C136 C137 177.7(3) . . . . ?
Si8 N8 C136 C137 17.8(5) . . . . ?
C150 C151 C152 C153 180.0(8) . . . . ?
C151 C152 C153 C154 173.1(8) . . . . ?
C157 C155 C156 C156 -177.6(12) . . . 2_656 ?
