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#$Date: 2016-02-14 16:26:36 +0200 (Sun, 14 Feb 2016) $
#$Revision: 176435 $
#$URL: svn://www.crystallography.net/cod/cif/2/00/05/2000524.cif $
#------------------------------------------------------------------------------
#
# This file is available in the Crystallography Open Database (COD),
# http://www.crystallography.net/. The original data for this entry
# were provided by IUCr Journals, http://journals.iucr.org/.
#
# The file may be used within the scientific community so long as
# proper attribution is given to the journal article from which the
# data were obtained.
#
data_2000524
loop_
_publ_author_name
'Csöregh, I.'
_publ_section_title
;
 Structures and absolute configurations of enantiomers of two local
 anaesthetics: (2S)-1-methyl- and
 (2R)-1-butyl-2',6'-pipecoloxylidide hydrochlorides
;
_journal_issue                   10
_journal_name_full               'Acta Crystallographica Section C'
_journal_page_first              1794
_journal_page_last               1798
_journal_paper_doi               10.1107/S0108270192001604
_journal_volume                  48
_journal_year                    1992
_chemical_formula_moiety         'C18 H29 N2 O1,H1 Cl1'
_chemical_formula_sum            'C18 H30 Cl N2 O'
_chemical_formula_weight         324.89
_symmetry_cell_setting           monoclinic
_symmetry_space_group_name_H-M   'P 1 21 1'
_cell_angle_alpha                90
_cell_angle_beta                 114.38(6)
_cell_angle_gamma                90
_cell_formula_units_Z            2
_cell_length_a                   9.7018(6)
_cell_length_b                   10.9221(8)
_cell_length_c                   9.9519(7)
_cell_volume                     960.5(5)
_diffrn_radiation_type           Cu
_diffrn_radiation_wavelength     1.54183
_exptl_absorpt_coefficient_mu    1.68
_exptl_crystal_density_diffrn    1.1234(2)
_exptl_crystal_F_000             352
_cod_data_source_file            ka0013.cif
_cod_data_source_block           ka0013b
_cod_original_cell_volume        960.5(2)
_cod_original_sg_symbol_H-M      'P 21'
_cod_original_formula_sum        'C18 H30 Cl1 N2 O1'
_cod_database_code               2000524
loop_
_atom_site_label
_atom_site_fract_x
_atom_site_fract_y
_atom_site_fract_z
_atom_site_U_iso_or_equiv
C(7) -.3654(4) -.8538(3) -.9737(4) .0390(10)
O(7) -.4002(3) -.9615(3) -1.0029(3) .0550(10)
N(8) -.2247(3) -.8146(3) -.8901(3) .0450(10)
C(9) -.1005(4) -.8990(4) -.8330(4) .047(2)
C(10) -.0464(4) -.9523(4) -.9291(5) .052(2)
C(11) .0712(4) -1.0372(5) -.8710(5) .061(2)
C(12) .1332(5) -1.0641(4) -.7233(6) .069(2)
C(13) .0818(4) -1.0087(4) -.6289(5) .062(2)
C(14) -.0376(4) -.9244(4) -.6822(4) .053(2)
C(15) -.0998(5) -.8674(5) -.5813(5) .066(2)
C(16) -.1107(5) -.9206(5) -1.0905(5) .064(2)
Cl -.20410(10) -.5426 -.78710(10) .0604(3)
N(1) -.6342(3) -.8039(3) -1.0683(3) .0410(10)
C(1') -.6475(5) -.8292(4) -.9248(4) .056(2)
C(2') -.6440(11) -.7162(6) -.8364(7) .112(4)
C(3') -.6571(8) -.7484(7) -.6953(6) .096(3)
C(4') -.5338(12) -.8214(13) -.5885(8) .190(7)
C(2) -.4817(4) -.7539(3) -1.0455(4) .0410(10)
C(3) -.4747(5) -.7220(5) -1.1931(4) .056(2)
C(4) -.6090(5) -.6442(4) -1.2933(4) .058(2)
C(5) -.7534(5) -.7087(4) -1.3175(5) .061(2)
C(6) -.7650(4) -.7282(4) -1.1713(5) .053(2)
H(1) -.6488 -.8841 -1.1070 0.07(2)
H(1'a) -.5615 -.8834 -.8631 0.07(2)
H(1'b) -.7454 -.8727 -.9479 0.08(2)
H(2'a) -.7303 -.6618 -.8965 0.24(3)
H(2'b) -.5463 -.6721 -.8122 0.23(3)
H(3'a) -.7530 -.7956 -.7216 0.15(3)
H(3'b) -.6631 -.6701 -.6459 0.10(2)
H(4'a) -.5376 -.8376 -.4912 .150(10)
H(4'b) -.4423 -.7712 -.5730 .150(10)
H(4'c) -.5285 -.9010 -.6359 .150(10)
H(2) -.4621 -.6782 -.9838 .08(2)
H(3a) -.4738 -.7998 -1.2456 .09(2)
H(3b) -.3792 -.6755 -1.1723 .08(2)
H(4a) -.6030 -.6314 -1.3902 .07(2)
H(4b) -.6062 -.5631 -1.2456 .08(2)
H(5a) -.8410 -.6580 -1.3837 .07(2)
H(5b) -.7556 -.7899 -1.3648 .08(2)
H(6a) -.8618 -.7716 -1.1896 .08(2)
H(6b) -.7641 -.6489 -1.1248 .050(10)
H(8) -.2064 -.7203 -.8665 .07(2)
H(11) .1105 -1.0786 -.9378 .09(2)
H(12) .2172 -1.1252 -.6837 .08(2)
H(13) .1300 -1.0286 -.5212 .08(2)
H(15a) -.0547 -.8937 -.4756 .150(10)
H(15b) -.2105 -.8864 -.6262 .150(10)
H(15c) -.0849 -.7772 -.5872 .150(10)
H(16a) -.1752 -.8454 -1.1144 .150(10)
H(16b) -.1751 -.9935 -1.1372 .150(10)
H(16c) -.0312 -.9115 -1.1294 .150(10)
loop_
_geom_bond_atom_site_label_1
_geom_bond_atom_site_label_2
_geom_bond_distance
C(7) O(7) 1.225(4)
C(7) N(8) 1.342(4)
N(8) C(9) 1.435(5)
C(9) C(10) 1.394(6)
C(9) C(14) 1.394(5)
C(10) C(11) 1.396(6)
C(10) C(16) 1.504(6)
C(11) C(12) 1.371(7)
C(12) C(13) 1.373(8)
C(13) C(14) 1.402(6)
C(14) C(15) 1.504(7)
N(1) C(1') 1.512(6)
N(1) C(2) 1.503(5)
N(1) C(6) 1.507(4)
C(1') C(2') 1.508(8)
C(2') C(3') 1.503(11)
C(3') C(4') 1.465(12)
C(2) C(3) 1.538(6)
C(2) C(7) 1.520(5)
C(3) C(4) 1.530(6)
C(4) C(5) 1.496(7)
C(5) C(6) 1.519(7)
