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#$Date: 2022-09-28 18:08:17 +0300 (Wed, 28 Sep 2022) $
#$Revision: 278247 $
#$URL: file:///home/coder/svn-repositories/cod/cif/2/00/08/2000841.cif $
#------------------------------------------------------------------------------
#
# This file is available in the Crystallography Open Database (COD),
# http://www.crystallography.net/. The original data for this entry
# were provided by IUCr Journals, http://journals.iucr.org/.
#
# The file may be used within the scientific community so long as
# proper attribution is given to the journal article from which the
# data were obtained.
#
data_2000841
loop_
_publ_author_name
'Hong, M.'
'Huang, Z.'
'Lei, X.'
'Jiang, F.'
'Liu, H.'
_publ_section_title
;
 Structure of bis(N,N-diethyldithiocarbamato)gold(III)
 hexafluoroantimonate
;
_journal_issue                   6
_journal_name_full               'Acta Crystallographica Section C'
_journal_page_first              1101
_journal_page_last               1102
_journal_paper_doi               10.1107/S010827019101291X
_journal_volume                  48
_journal_year                    1992
_chemical_formula_moiety         'C10 H20 Au1 N2 S4,F6 Sb1'
_chemical_formula_sum            'C10 H20 Au F6 N2 S4 Sb'
_chemical_formula_weight         1458.55
_space_group_IT_number           2
_space_group_name_Hall           '-P 1'
_space_group_name_H-M_alt        'P -1'
_symmetry_cell_setting           triclinic
_symmetry_space_group_name_Hall  '-P 1'
_symmetry_space_group_name_H-M   'P -1'
_cell_angle_alpha                100.370(10)
_cell_angle_beta                 105.92(5)
_cell_angle_gamma                74.69(3)
_cell_formula_units_Z            4
_cell_length_a                   14.533(3)
_cell_length_b                   18.004(5)
_cell_length_c                   8.538(2)
_cell_volume                     2058.1(10)
_diffrn_radiation_type           Mo
_diffrn_radiation_wavelength     0.71073
_exptl_absorpt_coefficient_mu    8.87
_exptl_crystal_density_diffrn    2.353
_exptl_crystal_F_000             1368
_cod_data_source_file            as0529.cif
_cod_data_source_block           as0529a
_cod_original_cell_volume        2058.06
_cod_original_formula_sum        'C10 H20 Au1 F6 N2 S4 Sb1'
_cod_database_code               2000841
loop_
_space_group_symop_id
_space_group_symop_operation_xyz
1 x,y,z
2 -x,-y,-z
loop_
_atom_site_label
_atom_site_fract_x
_atom_site_fract_y
_atom_site_fract_z
_atom_site_attached_hydrogens
Au(1) .94780(5) .60835(4) .65278(9) 0
Au(2) .35591(5) -.10628(4) .53398(8) 0
Sb(1) .56350(10) .34575(8) .8224(2) 0
Sb(2) .15720(10) .13515(9) 1.0282(2) 0
S(1) 1.1055(4) .6304(3) .7275(6) 0
S(2) .7873(4) .5928(3) .5806(6) 0
S(3) .9869(4) .6066(3) .4050(6) 0
S(4) .9109(4) .6105(3) .9015(6) 0
S(5) .1858(4) -.0749(3) .4922(6) 0
S(6) .3276(3) -.1498(3) .7533(6) 0
S(7) .5258(3) -.1327(3) .5857(5) 0
S(8) .3869(4) -.0656(3) .3133(6) 0
F(21) .4980(10) .4080(10) .974(2) 0
F(22) .665(2) .317(2) .977(2) 0
F(23) .5100(10) .2710(10) .827(2) 0
F(24) .6110(10) .4220(10) .803(2) 0
F(25) .6300(10) .2818(9) .674(2) 0
F(26) .463(2) .379(2) .661(3) 0
F(31) .7560(10) -.1878(9) .831(2) 0
F(32) .7420(10) -.0610(10) 1.032(2) 0
F(33) .8320(10) -.0775(9) .803(2) 0
F(34) .0540(10) .2063(9) .095(2) 0
F(35) .8520(10) .8060(10) .133(2) 0
F(36) .0680(10) .0820(10) .890(2) 0
N(10) .1700(10) .6306(9) .460(2) 0
N(20) .7210(10) .6086(9) .850(2) 0
N(30) .1350(10) -.1208(8) .735(2) 0
N(40) .5820(10) -.0966(8) .342(2) 0
C(10) .9010(10) .3780(10) .480(2) 0
C(11) .7370(10) .3510(10) .425(3) 2
C(12) .658(2) .4250(10) .392(3) 3
C(13) .162(2) .6190(10) .282(3) 2
C(14) .120(2) .699(2) .211(3) 3
C(20) .7930(10) .6050(10) .789(2) 0
C(21) .6200(10) .6040(10) .748(2) 2
C(22) .554(2) .684(2) .731(3) 3
C(23) .730(2) .6250(10) 1.037(2) 2
C(24) .762(2) .5460(10) 1.106(3) 3
C(30) .2020(10) -.1160(10) .671(2) 0
C(31) .1570(10) -.1630(10) .883(2) 2
C(32) .159(2) -.1040(10) 1.036(3) 3
C(33) .0300(10) -.0870(10) .658(2) 2
C(34) -.016(2) -.148(2) .536(3) 3
C(40) .5110(10) -.0970(10) .402(2) 0
C(41) .5620(10) -.0660(10) .178(2) 2
C(42) .559(2) -.1350(10) .040(2) 3
C(43) .6860(10) -.1230(10) .430(2) 2
C(44) .724(2) .7890(10) .400(3) 3
loop_
_geom_bond_atom_site_label_1
_geom_bond_atom_site_label_2
_geom_bond_distance
Au(1) S(1) 2.326(6)
Au(1) S(2) 2.323(5)
Au(1) S(3) 2.330(6)
Au(1) S(4) 2.320(6)
Au(2) S(5) 2.326(5)
Au(2) S(6) 2.326(6)
Au(2) S(7) 2.318(5)
Au(2) S(8) 2.330(6)
Sb(1) F(21) 1.852(6)
Sb(1) F(22) 1.720(10)
Sb(1) F(23) 1.738(9)
Sb(1) F(24) 1.750(9)
Sb(1) F(25) 1.856(6)
Sb(1) F(26) 1.770(10)
Sb(2) F(31) 1.825(6)
Sb(2) F(32) 1.826(7)
Sb(2) F(33) 1.870(7)
Sb(2) F(34) 1.841(7)
Sb(2) F(35) 1.843(7)
Sb(2) F(36) 1.850(7)
S(1) C(10) 1.73(2)
S(2) C(20) 1.74(2)
S(3) C(10) 1.72(2)
S(4) C(20) 1.74(2)
S(5) C(30) 1.75(2)
S(6) C(30) 1.750(10)
S(7) C(40) 1.74(2)
S(8) C(40) 1.740(10)
N(10) C(10) 1.32(3)
N(10) C(11) 1.52(2)
N(10) C(13) 1.47(3)
N(20) C(20) 1.27(3)
N(20) C(21) 1.50(2)
N(20) C(23) 1.54(3)
N(30) C(30) 1.27(3)
N(30) C(31) 1.51(3)
N(30) C(33) 1.49(2)
N(40) C(40) 1.28(3)
N(40) C(41) 1.51(3)
N(40) C(43) 1.49(3)
C(11) C(12) 1.52(3)
C(13) C(14) 1.57(4)
C(21) C(22) 1.52(3)
C(23) C(24) 1.55(3)
C(31) C(32) 1.52(3)
C(33) C(34) 1.53(3)
C(41) C(42) 1.55(3)
C(43) C(44) 1.53320
