#------------------------------------------------------------------------------
#$Date: 2016-02-14 16:26:36 +0200 (Sun, 14 Feb 2016) $
#$Revision: 176435 $
#$URL: svn://www.crystallography.net/cod/cif/2/00/09/2000918.cif $
#------------------------------------------------------------------------------
#
# This file is available in the Crystallography Open Database (COD),
# http://www.crystallography.net/. The original data for this entry
# were provided by IUCr Journals, http://journals.iucr.org/.
#
# The file may be used within the scientific community so long as
# proper attribution is given to the journal article from which the
# data were obtained.
#
data_2000918
loop_
_publ_author_name
'Bruins Slot, H. J.'
'Leusen, F. J. J.'
'van der Haest, A. D.'
'van Bolhuis, F.'
_publ_section_title
;
 Structures of a pair of diastereomeric salts of ephedrine and
 dichloro-substituted cyclic phosphoric acid
;
_journal_issue                   5
_journal_name_full               'Acta Crystallographica Section C'
_journal_page_first              925
_journal_page_last               929
_journal_paper_doi               10.1107/S0108270191011721
_journal_volume                  48
_journal_year                    1992
_chemical_formula_moiety         'C10 H16 N1 O1,C11 H12 Cl2 O4 P1'
_chemical_formula_sum            'C21 H28 Cl2 N O5 P'
_chemical_formula_weight         476.335
_symmetry_cell_setting           monoclinic
_symmetry_space_group_name_H-M   'P 1 21 1'
_cell_angle_alpha                90
_cell_angle_beta                 104.840(10)
_cell_angle_gamma                90
_cell_formula_units_Z            2
_cell_length_a                   10.0630(10)
_cell_length_b                   8.2060(10)
_cell_length_c                   14.8560(10)
_cell_volume                     1185.8(2)
_diffrn_radiation_type           Mo
_diffrn_radiation_wavelength     0.71073
_exptl_absorpt_coefficient_mu    3.689
_exptl_crystal_density_diffrn    1.334
_exptl_crystal_F_000             500
_cod_data_source_file            ab0249.cif
_cod_data_source_block           ab0249a
_cod_original_sg_symbol_H-M      'P 21'
_cod_original_formula_sum        'C21 H28 Cl2 N1 O5 P1'
_cod_database_code               2000918
loop_
_atom_site_label
_atom_site_fract_x
_atom_site_fract_y
_atom_site_fract_z
_atom_site_U_iso_or_equiv
Cl(1) .55235(13) .7375 .15903(8) .0809(4)
Cl(2) .96401(9) .3055(2) .31621(6) .0478(2)
P(2) .72991(7) .7740(2) .45196(5) .0325(2)
O(1) .8417(2) .9074(3) .44502(17) .0414(7)
O(3) .69722(19) .6924(3) .35093(14) .0356(5)
O(21) .6029(2) .8625(4) .46071(17) .0418(6)
O(22) .7901(3) .6481(4) .52278(16) .0475(7)
C(4) .8147(3) .6249(4) .32449(18) .0307(7)
C(5) .9204(3) .7612(4) .3219(2) .0377(8)
C(6) .9614(3) .8407(5) .4187(2) .0442(9)
C(41) .7650(2) .5247(3) .23359(12) .0342(7)
C(42) .6555(2) .5726(3) .16002(12) .0496(10)
C(43) .6205(2) .4800(3) .07858(12) .0665(15)
C(44) .6949(2) .3397(3) .07071(12) .0662(15)
C(45) .80444(2) .2918(3) .14428(12) .0551(10)
C(46) .8395(2) .3844(3) .22572(12) .0391(8)
C(51) 1.0535(4) .6911(6) .3054(3) .0564(13)
C(52) .8648(5) .8892(5) .2484(3) .0567(13)
O(10) .2841(3) .0737(4) .3244(2) .0525(8)
N(2) .5326(3) .2032(4) .42275(19) .0400(7)
C(1) .3200(3) .2316(5) .3014(2) .0426(9)
C(2) .4750(3) .2469(5) .3226(2) .425(9)
C(3) .5389(5) .1383(8) .2623(3) .0660(14)
C(11) .2537(3) .2745(5) .20107(17) .0609(15)
C(12) .2488(3) .4371(5) .17295(17) .082(2)
C(13) .1906(3) .4780(5) .08005(17) .127(4)
C(14) .1373(3) .3563(5) .01528(17) .155(6)
C(15) .1423(3) .1937(5) .04341(17) .143(6)
C(16) .2005(3) .1529(5) .13630(17) .087(2)
C(20) .6756(3) .2614(6) .4641(3) .0614(13)
H(4) .8698(3) .5393(4) .37590(18) ?
H(43) .5357(2) .5171(3) .02162(12) ?
H(44) .6677(2) .2680(3) .00766(12) ?
H(45) .8620(2) .1832(3) .13819(12) ?
H(61) 1.0333(3) .9381(5) .4180(2) ?
H(62) 1.0096(3) .7502(5) .4693(2) ?
H(511) 1.0314(4) .6331(6) .2380(3) ?
H(512) 1.0961(4) .6025(6) .3588(3) ?
H(513) 1.1267(4) .7883(6) .3079(3) ?
H(521) .7710(5) .9396(5) .2593(3) ?
H(522) .8439(5) .8339(5) .1802(3) ?
H(523) .9398(5) .9851(5) .2533(3) ?
H(1) .2818(3) .3174(5) .3439(2) ?
H(2) .4994(3) .3706(5) .3078(2) ?
H(10) .285(6) .076(10) .3903(17) ?
H(12) .2900(3) .5313(5) .22309(17) ?
H(13) .1868(3) .6038(5) .05828(17) ?
H(14) .0923(3) .3879(5) -.05664(17) ?
H(15) .1011(3) .0995(5) -.00674(17) ?
H(16) .2043(3) .0270(5) .15808(17) ?
H(21) .5320(3) .0720(4) .42871(19) ?
H(22) .4667(3) .2554(4) .46223(19) ?
H(31) .4974(5) .1698(8) .1899(3) ?
H(32) .5157(5) .0125(8) .2731(3) ?
H(33) .6489(5) .1555(8) .2809(3) ?
H(201) .7080(3) .2243(6) .5361(3) ?
H(202) .6785(3) .3926(6) .4598(3) ?
H(203) .7437(3) .2093(6) .4262(3) ?
loop_
_geom_bond_atom_site_label_1
_geom_bond_atom_site_label_2
_geom_bond_distance
Cl(1) C(42) 1.703(2)
Cl(2) C(46) 1.713(2)
P(2) O(1) 1.592(3)
P(2) O(3) 1.599(2)
P(2) O(21) 1.504(3)
P(2) O(22) 1.488(3)
O(1) C(6) 1.464(4)
C(4) C(5) 1.551(5)
C(4) C(41) 1.550(3)
C(5) C(6) 1.536(4)
C(5) C(51) 1.534(5)
C(5) C(52) 1.515(5)
O(10) C(1) 1.410(5)
N(2) C(2) 1.495(4)
N(2) C(20) 1.491(5)
C(1) C(2) 1.515(4)
C(1) C(11) 1.510(4)
C(2) C(3) 1.518(6)
C(43) C(44) 1.394(3)
C(12) C(13) 1.395(4)
C(41) C(42) 1.395(3)
C(44) C(45) 1.395(3)
C(13) C(14) 1.395(5)
C(41) C(46) 1.395(3)
C(45) C(46) 1.395(3)
C(11) C(12) 1.395(6)
C(14) C(15) 1.395(6)
C(42) C(43) 1.395(3)
C(11) C(16) 1.394(5)
C(15) C(16) 1.395(4)
C(4) H(4) 1.080(4)
C(44) H(44) 1.080(3)
C(51) H(513) 1.080(7)
O(10) H(10) 0.98(3)
C(2) H(2) 1.080(6)
C(12) H(12) 1.080(5)
C(16) H(16) 1.080(6)
C(6) H(62) 1.079(5)
C(51) H(511) 1.079(6)
C(52) H(522) 1.081(6)
N(2) H(22) 1.080(4)
C(3) H(32) 1.079(9)
C(14) H(14) 1.080(4)
C(20) H(202) 1.079(7)
C(43) H(43) 1.080(3)
C(51) H(512) 1.081(7)
C(52) H(523) 1.080(7)
C(1) H(1) 1.080(5)
C(3) H(33) 1.079(7)
C(15) H(15) 1.080(5)
C(20) H(203) 1.080(5)
