#------------------------------------------------------------------------------
#$Date: 2016-02-19 16:29:56 +0200 (Fri, 19 Feb 2016) $
#$Revision: 176759 $
#$URL: svn://www.crystallography.net/cod/cif/2/00/45/2004549.cif $
#------------------------------------------------------------------------------
#
# This file is available in the Crystallography Open Database (COD),
# http://www.crystallography.net/. The original data for this entry
# were provided by IUCr Journals, http://journals.iucr.org/.
#
# The file may be used within the scientific community so long as
# proper attribution is given to the journal article from which the
# data were obtained.
#
data_2004549
loop_
_publ_author_name
'Banwell, M. G.'
'Hockless, D. C. R.'
'Peters, S. C.'
_publ_contact_author
;
Dr. David C. R. Hockless
Research School of Chemistry
Institute of Advanced Studies
Australian National University
Canberra
ACT 0200
Australia
;
_publ_section_title
;
 An ABC-ring Analogue of Paclitaxel (TaxolTM)
;
_journal_issue                   2
_journal_name_full               'Acta Crystallographica Section C'
_journal_page_first              370
_journal_page_last               372
_journal_paper_doi               10.1107/S0108270195010869
_journal_volume                  52
_journal_year                    1996
_chemical_formula_moiety         'C20 H22 Br N O5'
_chemical_formula_sum            'C20 H22 Br N O5'
_chemical_formula_weight         436.30
_space_group_IT_number           14
_symmetry_cell_setting           monoclinic
_symmetry_space_group_name_Hall  '-P 2yn'
_symmetry_space_group_name_H-M   'P 1 21/n 1'
_audit_creation_method           'from TEXRAY.INF file'
_cell_angle_alpha                90
_cell_angle_beta                 92.05(2)
_cell_angle_gamma                90
_cell_formula_units_Z            8
_cell_length_a                   7.906(4)
_cell_length_b                   14.687(3)
_cell_length_c                   32.908(2)
_cell_measurement_reflns_used    24
_cell_measurement_temperature    213(1)
_cell_measurement_theta_max      47.7
_cell_measurement_theta_min      40.2
_cell_volume                     3819(2)
_computing_cell_refinement       'MSC/AFC Diffractometer Control Software'
_computing_data_collection
;MSC/AFC Diffractometer Control Software (Molecular Structure Corporation,
 1992)
;
_computing_data_reduction
'TEXSAN (Molecular Structure Corporation, 1992)'
_computing_publication_material  TEXSAN
_computing_structure_refinement  TEXSAN
_computing_structure_solution    'PATTY DIRDIF92 (Beurskens et al., 1992)'
_diffrn_ambient_temperature      213.0(10)
_diffrn_measurement_device       'Rigaku AFC6R'
_diffrn_measurement_method       'ω/2θ scans'
_diffrn_radiation_monochromator  'equatorial graphite'
_diffrn_radiation_source         'Rigaku RU200B rotating Cu anode'
_diffrn_radiation_type           CuK\a
_diffrn_radiation_wavelength     1.5418
_diffrn_reflns_av_R_equivalents  2.16
_diffrn_reflns_limit_h_max       8
_diffrn_reflns_limit_h_min       0
_diffrn_reflns_limit_k_max       16
_diffrn_reflns_limit_k_min       0
_diffrn_reflns_limit_l_max       36
_diffrn_reflns_limit_l_min       -36
_diffrn_reflns_number            6412
_diffrn_reflns_theta_max         60.27
_diffrn_reflns_theta_min         1.50
_diffrn_standards_decay_%        5.44
_diffrn_standards_interval_count 150
_diffrn_standards_number         3
_exptl_absorpt_coefficient_mu    3.210
_exptl_absorpt_correction_T_max  1.000
_exptl_absorpt_correction_T_min  0.838
_exptl_absorpt_correction_type
;
empirical based on azimuthal (\y) scans (North, Phillips & Mathews, 1968)
;
_exptl_crystal_colour            colourless
_exptl_crystal_density_diffrn    1.518
_exptl_crystal_description       prism
_exptl_crystal_F_000             1792.00
_exptl_crystal_size_max          0.180
_exptl_crystal_size_mid          0.160
_exptl_crystal_size_min          0.080
_refine_diff_density_max         0.70
_refine_diff_density_min         -0.56
_refine_ls_extinction_coef       4E-7(5)
_refine_ls_extinction_method
'Zachariasen (1968) type 2 Gaussian isotropic'
_refine_ls_goodness_of_fit_obs   2.230
_refine_ls_hydrogen_treatment    noref
_refine_ls_matrix_type           full
_refine_ls_number_parameters     488
_refine_ls_number_reflns         4412
_refine_ls_number_restraints     0
_refine_ls_R_factor_all          0.0571
_refine_ls_R_factor_obs          0.0410
_refine_ls_shift/esd_max         0.0010
_refine_ls_structure_factor_coef F
_refine_ls_weighting_details     w=4Fₒ²/[σ²(Fₒ²)+(0.010Fₒ²)²]
_refine_ls_weighting_scheme      calc
_refine_ls_wR_factor_all         0.0433
_refine_ls_wR_factor_obs         0.0410
_reflns_number_observed          4412
_reflns_number_total             5926
_reflns_observed_criterion       I>3\s(I)
_cod_data_source_file            ta1039.cif
_cod_data_source_block           mgb2
_cod_depositor_comments
;
The following automatic conversions were performed:

'_refine_ls_weighting_scheme' value '
w=4F~o~^2^/[\s^2^(F~o~^2^)+(0.010F~o~^2^)^2^]' was changed to 'calc'.
New tag '_refine_ls_weighting_details' was created. The value of the
new tag was set to 'w=4F~o~^2^/[\s^2^(F~o~^2^)+(0.010F~o~^2^)^2^]'.

Automatic conversion script
Id: cif_fix_values 3143 2015-03-26 13:38:13Z robertas 
;
_cod_original_cell_volume        3818.0(10)
_cod_original_sg_symbol_H-M      'P 21/n'
_cod_database_code               2004549
loop_
_symmetry_equiv_pos_as_xyz
'   +x,   +y,   +z'
1/2-x,1/2+y,1/2-z
'   -x,   -y,   -z'
1/2+x,1/2-y,1/2+z
loop_
_atom_site_label
_atom_site_fract_x
_atom_site_fract_y
_atom_site_fract_z
_atom_site_U_iso_or_equiv
_atom_site_thermal_displace_type
Br(1A) 0.85693(7) 0.84349(3) 0.50241(1) 0.0424(1) Uani
O(1A) 0.7682(4) 1.0116(2) 0.45052(9) 0.0354(9) Uani
O(1'A) 0.6305(5) 1.0794(2) 0.3970(1) 0.058(1) Uani
O(4'A) 0.7242(4) 0.9022(2) 0.30455(9) 0.048(1) Uani
O(5'A) 0.2501(4) 0.7463(2) 0.33927(10) 0.050(1) Uani
O(9A) 0.9622(4) 0.6236(2) 0.46211(10) 0.049(1) Uani
N(1A) 0.4655(5) 0.8421(2) 0.3208(1) 0.037(1) Uani
C(1A) 0.8631(6) 0.9460(3) 0.4259(1) 0.031(1) Uani
C(1'A) 0.6651(6) 1.0745(3) 0.4327(2) 0.047(1) Uani
C(1''A) 0.6011(8) 1.1376(4) 0.4647(2) 0.071(3) Uani
C(2A) 0.7330(6) 0.8820(3) 0.4050(1) 0.033(1) Uani
C(3A) 0.8067(6) 0.7953(3) 0.3849(1) 0.034(1) Uani
C(4A) 0.7069(6) 0.7636(3) 0.3457(1) 0.035(1) Uani
C(4'A) 0.6404(6) 0.8440(3) 0.3210(1) 0.039(1) Uani
C(5A) 0.5478(6) 0.7047(3) 0.3516(1) 0.039(1) Uani
C(5'A) 0.3996(7) 0.7634(3) 0.3377(1) 0.040(1) Uani
C(6A) 0.5358(6) 0.6619(3) 0.3927(1) 0.041(1) Uani
C(7A) 0.6623(6) 0.6648(3) 0.4200(1) 0.042(1) Uani
C(8A) 0.8180(6) 0.7172(3) 0.4153(1) 0.036(1) Uani
C(9A) 0.9593(6) 0.7007(3) 0.4378(1) 0.040(1) Uani
C(9'A) 1.0914(9) 0.6176(4) 0.4924(2) 0.082(2) Uani
C(10A) 1.1129(6) 0.7549(3) 0.4343(1) 0.038(1) Uani
C(11A) 1.1159(6) 0.8452(3) 0.4399(1) 0.036(1) Uani
C(12A) 1.2412(6) 0.9074(3) 0.4210(1) 0.047(1) Uani
C(13A) 1.1439(6) 0.9551(3) 0.3850(1) 0.048(1) Uani
C(14A) 0.9789(6) 1.0008(3) 0.3979(1) 0.041(1) Uani
C(15A) 0.9787(6) 0.9016(3) 0.4586(1) 0.031(1) Uani
Br(1B) 0.73020(7) 1.26315(4) 0.90099(1) 0.0436(1) Uani
O(1B) 0.6625(4) 1.3218(2) 0.81220(8) 0.037(3) Uani
O(1'B) 0.5508(5) 1.2901(2) 0.74958(10) 0.058(1) Uani
O(4'B) 0.6975(4) 1.0244(2) 0.73291(10) 0.047(1) Uani
O(5'B) 0.2209(5) 0.9801(2) 0.8048(1) 0.055(1) Uani
O(9B) 0.9179(4) 1.0445(2) 0.93391(9) 0.052(1) Uani
N(1B) 0.4386(5) 1.0038(3) 0.7610(1) 0.042(1) Uani
C(1B) 0.7804(6) 1.2433(3) 0.8143(1) 0.033(1) Uani
C(1'B) 0.5593(6) 1.3368(3) 0.7796(1) 0.039(1) Uani
C(1''B) 0.4548(6) 1.4208(3) 0.7860(1) 0.044(1) Uani
C(2B) 0.6716(6) 1.1564(3) 0.8140(1) 0.034(1) Uani
C(3B) 0.7638(6) 1.0658(3) 0.8251(1) 0.035(1) Uani
C(4B) 0.6768(6) 0.9810(3) 0.8043(1) 0.038(1) Uani
C(4'B) 0.6139(7) 1.0042(3) 0.7619(1) 0.041(1) Uani
C(5B) 0.5157(6) 0.9471(3) 0.8250(1) 0.043(1) Uani
C(5'B) 0.3705(7) 0.9784(3) 0.7977(1) 0.044(1) Uani
C(6B) 0.5007(6) 0.9720(3) 0.8686(1) 0.045(1) Uani
C(7B) 0.6234(6) 1.0139(3) 0.8894(1) 0.045(1) Uani
C(8B) 0.7751(6) 1.0503(3) 0.8708(1) 0.037(1) Uani
C(9B) 0.9112(6) 1.0737(3) 0.8941(1) 0.041(1) Uani
C(9'B) 1.005(1) 1.0995(5) 0.9626(2) 0.108(3) Uani
C(10B) 1.0540(6) 1.1239(3) 0.8779(1) 0.046(1) Uani
C(11B) 1.0354(6) 1.2018(3) 0.8581(1) 0.041(1) Uani
C(12B) 1.1624(6) 1.2361(4) 0.8286(2) 0.056(1) Uani
C(13B) 1.0833(8) 1.2181(5) 0.7861(2) 0.084(1) Uani
C(14B) 0.9062(7) 1.2530(3) 0.7797(1) 0.048(1) Uani
C(15B) 0.8777(6) 1.2609(3) 0.8543(1) 0.036(1) Uani
H(1A) 0.3967 0.8901 0.3102 0.0445 Uiso
H(1''Aa) 0.6943 1.1669 0.4783 0.0851 Uiso
H(1''Ab) 0.5292 1.1822 0.4523 0.0851 Uiso
H(1''Ac) 0.5396 1.1037 0.4838 0.0851 Uiso
H(2Aa) 0.6565 0.8627 0.4249 0.0401 Uiso
H(2Ab) 0.6733 0.9156 0.3844 0.0401 Uiso
H(3A) 0.9187 0.8093 0.3774 0.0404 Uiso
H(4A) 0.7822 0.7303 0.3295 0.0422 Uiso
H(5A) 0.5532 0.6560 0.3327 0.0464 Uiso
H(6A) 0.4341 0.6317 0.3993 0.0489 Uiso
H(7A) 0.6516 0.6305 0.4442 0.0505 Uiso
H(9'Aa) 1.0842 0.6680 0.5104 0.0980 Uiso
H(9'Ab) 1.1983 0.6179 0.4802 0.0980 Uiso
H(9'Ac) 1.0788 0.5627 0.5073 0.0980 Uiso
H(10A) 1.2149 0.7248 0.4278 0.0454 Uiso
H(12Aa) 1.3338 0.8735 0.4114 0.0559 Uiso
H(12Ab) 1.2816 0.9513 0.4402 0.0559 Uiso
H(13Aa) 1.2152 1.0002 0.3741 0.0570 Uiso
H(13Ab) 1.1168 0.9108 0.3648 0.0570 Uiso
H(14Aa) 1.0091 1.0556 0.4117 0.0497 Uiso
H(14Ab) 0.9145 1.0149 0.3738 0.0497 Uiso
H(15A) 1.0372 0.9510 0.4713 0.0375 Uiso
H(1B) 0.3713 1.0194 0.7375 0.0503 Uiso
H(1''Ba) 0.5275 1.4717 0.7900 0.0525 Uiso
H(1''Bb) 0.3825 1.4308 0.7627 0.0525 Uiso
H(1''Bc) 0.3884 1.4128 0.8092 0.0525 Uiso
H(2Ba) 0.6223 1.1497 0.7874 0.0406 Uiso
H(2Bb) 0.5847 1.1650 0.8328 0.0406 Uiso
H(3B) 0.8759 1.0697 0.8158 0.0420 Uiso
H(4B) 0.7562 0.9325 0.8033 0.0460 Uiso
H(5B) 0.5172 0.8825 0.8237 0.0514 Uiso
H(6B) 0.3996 0.9572 0.8819 0.0544 Uiso
H(7B) 0.6130 1.0209 0.9179 0.0535 Uiso
H(9'Ba) 1.1205 1.1044 0.9556 0.1297 Uiso
H(9'Bb) 0.9556 1.1584 0.9628 0.1297 Uiso
H(9'Bc) 0.9991 1.0729 0.9888 0.1297 Uiso
H(10B) 1.1646 1.0995 0.8818 0.0549 Uiso
H(12Ba) 1.1817 1.2994 0.8325 0.0674 Uiso
H(12Bb) 1.2663 1.2041 0.8321 0.0674 Uiso
H(13Ba) 1.1523 1.2465 0.7667 0.1013 Uiso
H(13Bb) 1.0821 1.1542 0.7816 0.1013 Uiso
H(14Ba) 0.9144 1.3162 0.7738 0.0574 Uiso
H(14Bb) 0.8582 1.2220 0.7568 0.0574 Uiso
H(15B) 0.9189 1.3214 0.8521 0.0437 Uiso
loop_
_atom_type_symbol
_atom_type_scat_dispersion_real
_atom_type_scat_dispersion_imag
_atom_type_scat_source
C 0.018 0.009
;
International Tables for Crystallography (1992, Vol C. Tables 4.2.6.8 and
6.1.1.4)
;
H 0.000 0.000
;
International Tables for Crystallography (1992, Vol C. Tables 4.2.6.8 and
6.1.1.4)
;
Br -0.676 1.280
;
International Tables for Crystallography (1992, Vol C. Tables 4.2.6.8 and
6.1.1.4)
;
N 0.031 0.018
;
International Tables for Crystallography (1992, Vol C. Tables 4.2.6.8 and
6.1.1.4)
;
O 0.049 0.032
;
International Tables for Crystallography (1992, Vol C. Tables 4.2.6.8 and
6.1.1.4)
;
loop_
_geom_angle_atom_site_label_1
_geom_angle_atom_site_label_2
_geom_angle_atom_site_label_3
_geom_angle
_geom_angle_publ_flag
C(1A) O(1A) C(1'A) 121.1(3) ?
C(9A) O(9A) C(9'A) 117.3(4) ?
C(4'A) N(1A) C(5'A) 113.8(4) ?
O(1A) C(1A) C(2A) 107.4(3) ?
O(1A) C(1A) C(14A) 108.0(3) ?
O(1A) C(1A) C(15A) 101.1(3) yes
C(2A) C(1A) C(14A) 117.0(3) yes
C(2A) C(1A) C(15A) 115.2(3) yes
C(14A) C(1A) C(15A) 106.8(4) ?
O(1A) C(1'A) O(1'A) 125.3(5) ?
O(1A) C(1'A) C(1''A) 109.3(4) ?
O(1'A) C(1'A) C(1''A) 125.4(5) ?
C(1A) C(2A) C(3A) 115.8(4) yes
C(2A) C(3A) C(4A) 114.2(4) ?
C(2A) C(3A) C(8A) 110.5(3) ?
C(4A) C(3A) C(8A) 109.5(4) ?
C(3A) C(4A) C(4'A) 111.5(4) ?
C(3A) C(4A) C(5A) 117.0(4) yes
C(4'A) C(4A) C(5A) 103.6(4) yes
O(4'A) C(4'A) N(1A) 124.8(5) ?
O(4'A) C(4'A) C(4A) 126.9(4) ?
N(1A) C(4'A) C(4A) 108.3(4) ?
C(4A) C(5A) C(5'A) 105.5(4) ?
C(4A) C(5A) C(6A) 115.2(4) yes
C(5'A) C(5A) C(6A) 116.1(4) ?
O(5'A) C(5'A) N(1A) 124.7(5) ?
O(5'A) C(5'A) C(5A) 127.9(5) ?
N(1A) C(5'A) C(5A) 107.3(4) ?
C(5A) C(6A) C(7A) 122.0(4) ?
C(6A) C(7A) C(8A) 124.5(4) ?
C(3A) C(8A) C(7A) 115.8(4) ?
C(3A) C(8A) C(9A) 121.8(4) ?
C(7A) C(8A) C(9A) 122.4(4) ?
O(9A) C(9A) C(8A) 117.5(4) ?
O(9A) C(9A) C(10A) 119.6(4) ?
C(8A) C(9A) C(10A) 122.6(4) ?
C(9A) C(10A) C(11A) 122.6(4) ?
C(10A) C(11A) C(12A) 123.7(4) ?
C(10A) C(11A) C(15A) 126.1(4) yes
C(12A) C(11A) C(15A) 109.2(4) yes
C(11A) C(12A) C(13A) 105.9(4) ?
C(12A) C(13A) C(14A) 112.9(4) ?
C(1A) C(14A) C(13A) 117.4(4) yes
Br(1A) C(15A) C(1A) 114.0(3) ?
Br(1A) C(15A) C(11A) 116.1(3) yes
C(1A) C(15A) C(11A) 111.5(3) ?
C(4'B) N(1B) C(5'B) 113.6(4) ?
C(1B) O(1B) C(1'B) 121.9(3) ?
O(1B) C(1B) C(2B) 107.1(3) ?
O(1B) C(1B) C(14B) 108.3(3) ?
O(1B) C(1B) C(15B) 101.9(3) yes
C(2B) C(1B) C(14B) 116.5(4) yes
C(2B) C(1B) C(15B) 114.4(3) yes
C(14B) C(1B) C(15B) 107.6(4) ?
O(1'B) C(1'B) O(1B) 125.3(4) ?
O(1'B) C(1'B) C(1''B) 124.6(4) ?
O(1B) C(1'B) C(1''B) 110.2(4) ?
C(1B) C(2B) C(3B) 116.8(4) yes
C(2B) C(3B) C(4B) 112.5(3) ?
C(2B) C(3B) C(8B) 111.9(4) ?
C(4B) C(3B) C(8B) 108.7(4) ?
C(3B) C(4B) C(4'B) 110.5(4) ?
C(3B) C(4B) C(5B) 114.8(4) yes
C(4'B) C(4B) C(5B) 103.3(4) yes
N(1B) C(4'B) O(4'B) 123.8(4) ?
N(1B) C(4'B) C(4B) 108.4(4) ?
O(4'B) C(4'B) C(4B) 127.7(5) ?
C(4B) C(5B) C(5'B) 105.2(4) ?
C(4B) C(5B) C(6B) 116.0(4) yes
C(5'B) C(5B) C(6B) 114.5(4) ?
N(1B) C(5'B) C(5B) 106.8(4) ?
N(1B) C(5'B) O(5'B) 125.0(5) ?
C(5B) C(5'B) O(5'B) 128.2(5) ?
C(5B) C(6B) C(7B) 122.1(5) ?
C(6B) C(7B) C(8B) 123.5(4) ?
C(3B) C(8B) C(7B) 116.6(4) ?
C(3B) C(8B) C(9B) 122.9(4) ?
C(7B) C(8B) C(9B) 120.3(4) ?
C(9B) O(9B) C(9'B) 117.5(4) ?
C(8B) C(9B) O(9B) 117.8(4) ?
C(8B) C(9B) C(10B) 122.2(4) ?
O(9B) C(9B) C(10B) 119.9(4) ?
C(9B) C(10B) C(11B) 122.8(4) ?
C(10B) C(11B) C(12B) 122.8(5) ?
C(10B) C(11B) C(15B) 127.7(5) yes
C(12B) C(11B) C(15B) 108.6(4) yes
C(11B) C(12B) C(13B) 105.7(4) ?
C(12B) C(13B) C(14B) 114.6(5) ?
C(1B) C(14B) C(13B) 119.2(4) yes
Br(1B) C(15B) C(1B) 112.5(3) ?
Br(1B) C(15B) C(11B) 116.9(3) yes
C(1B) C(15B) C(11B) 111.2(4) ?
loop_
_geom_bond_atom_site_label_1
_geom_bond_atom_site_label_2
_geom_bond_distance
_geom_bond_publ_flag
Br(1B) C(15B) 1.963(4) ?
Br(1A) C(15A) 1.958(4) ?
O(1A) C(1A) 1.481(5) yes
O(1A) C(1'A) 1.351(5) ?
O(1'A) C(1'A) 1.201(5) ?
O(4'A) C(4'A) 1.221(5) ?
O(5'A) C(5'A) 1.212(6) ?
O(9A) C(9A) 1.386(5) ?
O(9A) C(9'A) 1.405(6) ?
N(1A) C(4'A) 1.383(6) ?
N(1A) C(5'A) 1.391(6) ?
C(1A) C(2A) 1.537(6) yes
C(1A) C(14A) 1.547(6) yes
C(1A) C(15A) 1.533(6) yes
C(1'A) C(1''A) 1.504(7) ?
C(2A) C(3A) 1.557(6) yes
C(3A) C(4A) 1.558(6) yes
C(3A) C(8A) 1.524(6) ?
C(4A) C(4'A) 1.516(6) yes
C(4A) C(5A) 1.545(6) yes
C(5A) C(5'A) 1.513(6) ?
C(5A) C(6A) 1.497(6) yes
C(6A) C(7A) 1.320(6) yes
C(7A) C(8A) 1.464(6) yes
C(8A) C(9A) 1.339(6) yes
C(9A) C(10A) 1.460(6) yes
C(10A) C(11A) 1.340(6) yes
C(11A) C(12A) 1.500(6) yes
C(11A) C(15A) 1.512(6) yes
C(12A) C(13A) 1.554(7) ?
C(13A) C(14A) 1.540(7) ?
N(1B) C(4'B) 1.385(6) ?
N(1B) C(5'B) 1.391(6) ?
O(1'B) C(1'B) 1.203(5) ?
O(1B) C(1B) 1.483(5) yes
O(1B) C(1'B) 1.342(5) ?
C(1B) C(2B) 1.539(6) yes
C(1B) C(14B) 1.545(6) yes
C(1B) C(15B) 1.522(6) yes
C(1'B) C(1''B) 1.503(6) ?
C(2B) C(3B) 1.555(6) yes
C(3B) C(4B) 1.568(6) yes
C(3B) C(8B) 1.518(6) ?
O(4'B) C(4'B) 1.216(5) ?
C(4B) C(4'B) 1.506(6) yes
C(4B) C(5B) 1.547(6) yes
C(5B) C(5'B) 1.504(6) ?
C(5B) C(6B) 1.491(6) yes
O(5'B) C(5'B) 1.214(6) ?
C(6B) C(7B) 1.319(6) yes
C(7B) C(8B) 1.466(6) yes
C(8B) C(9B) 1.344(6) yes
O(9B) C(9B) 1.378(5) ?
O(9B) C(9'B) 1.405(6) ?
C(9B) C(10B) 1.465(7) yes
C(10B) C(11B) 1.321(6) yes
C(11B) C(12B) 1.508(7) yes
C(11B) C(15B) 1.521(6) yes
C(12B) C(13B) 1.534(8) ?
C(13B) C(14B) 1.499(8) ?
