#------------------------------------------------------------------------------
#$Date: 2017-10-13 03:08:28 +0300 (Fri, 13 Oct 2017) $
#$Revision: 201955 $
#$URL: file:///home/coder/svn-repositories/cod/cif/2/00/60/2006031.cif $
#------------------------------------------------------------------------------
#
# This file is available in the Crystallography Open Database (COD),
# http://www.crystallography.net/. The original data for this entry
# were provided by IUCr Journals, http://journals.iucr.org/.
#
# The file may be used within the scientific community so long as
# proper attribution is given to the journal article from which the
# data were obtained.
#
data_2006031
loop_
_publ_author_name
'Wang, S.-Y. S.'
'Boncella, J. M.'
'Abboud, K. A.'
_publ_section_title
;
 A Chelate-Stabilized Tungsten--Imido--Monoalkyl Complex,
 [WCl(PhN)(CH₂CMe₃){o-C₆H₄(NSiMe₃)₂}]
;
_journal_issue                   4
_journal_name_full               'Acta Crystallographica Section C'
_journal_page_first              436
_journal_page_last               438
_journal_paper_doi               10.1107/S0108270196014370
_journal_volume                  53
_journal_year                    1997
_chemical_formula_sum            'C23 H38 Cl N3 Si2 W'
_chemical_formula_weight         632.04
_chemical_name_systematic
;
 ?
;
_space_group_IT_number           2
_symmetry_cell_setting           triclinic
_symmetry_space_group_name_Hall  '-P 1'
_symmetry_space_group_name_H-M   'P -1'
_audit_creation_method           SHELXTL
_cell_angle_alpha                96.705(1)
_cell_angle_beta                 93.814(1)
_cell_angle_gamma                111.296(1)
_cell_formula_units_Z            2
_cell_length_a                   9.3531(1)
_cell_length_b                   11.2640(2)
_cell_length_c                   14.1166(2)
_cell_measurement_reflns_used    8192
_cell_measurement_temperature    173(2)
_cell_measurement_theta_max      27.5
_cell_measurement_theta_min      1.5
_cell_volume                     1366.63(4)
_computing_cell_refinement       'SMART and SAINT (Siemens, 1995)'
_computing_data_collection       'SMART (Siemens, 1995)'
_computing_data_reduction        'SHELXTL95 (Sheldrick, 1995)'
_computing_molecular_graphics    SHELXTL95
_computing_publication_material  SHELXTL95
_computing_structure_refinement  SHELXTL95
_computing_structure_solution    SHELXTL95
_diffrn_ambient_temperature      173(2)
_diffrn_measurement_device       'SMART PLATFORM'
_diffrn_measurement_method       'ω scans'
_diffrn_radiation_monochromator  graphite
_diffrn_radiation_source         'normal-focus sealed tube'
_diffrn_radiation_type           MoK\a
_diffrn_radiation_wavelength     0.71073
_diffrn_reflns_av_R_equivalents  0.049
_diffrn_reflns_av_sigmaI/netI    0.0424
_diffrn_reflns_limit_h_max       11
_diffrn_reflns_limit_h_min       -12
_diffrn_reflns_limit_k_max       15
_diffrn_reflns_limit_k_min       -14
_diffrn_reflns_limit_l_max       19
_diffrn_reflns_limit_l_min       -11
_diffrn_reflns_number            8884
_diffrn_reflns_theta_max         27.49
_diffrn_reflns_theta_min         1.46
_diffrn_standards_decay_%        <1
_diffrn_standards_number         'see text'
_exptl_absorpt_coefficient_mu    4.43
_exptl_absorpt_correction_T_max  0.716
_exptl_absorpt_correction_T_min  0.465
_exptl_absorpt_correction_type   'integration (SHELXTL95; Sheldrick, 1995)'
_exptl_crystal_colour            'Red  '
_exptl_crystal_density_diffrn    1.536
_exptl_crystal_density_meas      ?
_exptl_crystal_description       Needle
_exptl_crystal_F_000             632
_exptl_crystal_size_max          0.23
_exptl_crystal_size_mid          0.10
_exptl_crystal_size_min          0.09
_refine_diff_density_max         1.00
_refine_diff_density_min         -1.46
_refine_ls_extinction_coef       0.0021(4)
_refine_ls_extinction_method     SHELXTL95
_refine_ls_goodness_of_fit_all   1.08
_refine_ls_goodness_of_fit_obs   1.068
_refine_ls_hydrogen_treatment    'H atoms: see text'
_refine_ls_matrix_type           full
_refine_ls_number_parameters     272
_refine_ls_number_reflns         6069
_refine_ls_number_restraints     0
_refine_ls_restrained_S_all      1.111
_refine_ls_restrained_S_obs      1.068
_refine_ls_R_factor_all          0.0376
_refine_ls_R_factor_obs          0.034
_refine_ls_shift/esd_max         -0.001
_refine_ls_shift/esd_mean        0.000
_refine_ls_structure_factor_coef Fsqd
_refine_ls_weighting_details
'w = 1/[σ²(Fo²)+(0.0448P)²+3.7698P] where P=(Fo²+2Fc²)/3'
_refine_ls_weighting_scheme      calc
_refine_ls_wR_factor_all         0.091
_refine_ls_wR_factor_obs         0.0850
_reflns_number_observed          5743
_reflns_number_total             6107
_reflns_observed_criterion       >2sigma(I)
_cod_data_source_file            bk1269.cif
_cod_data_source_block           I
_cod_depositor_comments
;
The following automatic conversions were performed:
'_symmetry_cell_setting' value 'Triclinic' changed to 'triclinic'
according to '/home/saulius/struct/CIF-dictionaries/cif_core.dic'
dictionary named 'cif_core.dic' version 2.4.1 from 2010-06-29.

Automatic conversion script
Id: cif_fix_enum 1527 2010-12-29 10:47:43Z saulius 

The following automatic conversions were performed:

'_symmetry_cell_setting' value 'Triclinic' changed to 'triclinic'
according to /home/saulius/struct/CIF-dictionaries/cif_core.dic
dictionary named 'cif_core.dic' version 2.4.1 from 2010-06-29.

Automatic conversion script
Id: cif_fix_values 1715 2011-07-08 13:25:40Z adriana 

The following automatic conversions were performed:

'_exptl_crystal_density_meas' value 'not measured' was changed to '?'
- the value is perceived as not measured.

Automatic conversion script
Id: cif_fix_values 3008 2015-01-20 13:52:24Z robertas 

The following automatic conversions were performed:

'_refine_ls_weighting_scheme' value 'calc w =
1/[\s^2^(Fo^2^)+(0.0448P)^2^+3.7698P] where P=(Fo^2^+2Fc^2^)/3' was
changed to 'calc'. New tag '_refine_ls_weighting_details' was
created. The value of the new tag was set to 'w =
1/[\s^2^(Fo^2^)+(0.0448P)^2^+3.7698P] where P=(Fo^2^+2Fc^2^)/3'.

Automatic conversion script
Id: cif_fix_values 3143 2015-03-26 13:38:13Z robertas 
;
_cod_original_cell_volume        1366.63(3)
_cod_original_sg_symbol_H-M      P-1
_cod_database_code               2006031
loop_
_symmetry_equiv_pos_as_xyz
'x, y, z'
'-x, -y, -z'
loop_
_atom_site_label
_atom_site_occupancy
_atom_site_fract_x
_atom_site_fract_y
_atom_site_fract_z
_atom_site_U_iso_or_equiv
_atom_site_thermal_displace_type
_atom_site_calc_flag
_atom_site_refinement_flags
_atom_site_type_symbol
W 1 0.43072(2) 0.31367(2) 0.23552(1) 0.0206(1) Uani d . W
Cl 1 0.6426(2) 0.3169(1) 0.1448(1) 0.0398(3) Uani d . Cl
Si1 1 0.0901(1) 0.2537(1) 0.3413(1) 0.0247(2) Uani d . Si
Si2 1 0.6712(2) 0.6319(1) 0.2355(1) 0.0294(3) Uani d . Si
N1 1 0.2379(4) 0.3321(3) 0.2695(3) 0.0223(7) Uani d . N
N2 1 0.4915(4) 0.5012(3) 0.2222(3) 0.0233(7) Uani d . N
N3 1 0.4890(4) 0.2516(4) 0.3317(3) 0.0260(8) Uani d . N
C1 1 0.5683(5) 0.2318(5) 0.4112(3) 0.0266(9) Uani d . C
C2 1 0.6043(6) 0.1228(5) 0.4084(4) 0.0350(11) Uani d . C
H2A 1 0.5738(6) 0.0619(5) 0.3530(4) 0.042 Uiso calc R H
C3 1 0.6857(7) 0.1030(6) 0.4873(5) 0.0467(14) Uani d . C
H3A 1 0.7122(7) 0.0308(6) 0.4839(5) 0.056 Uiso calc R H
C4 1 0.7265(7) 0.1904(7) 0.5703(4) 0.050(2) Uani d . C
H4A 1 0.7789(7) 0.1762(7) 0.6234(4) 0.060 Uiso calc R H
C5 1 0.6910(7) 0.2983(7) 0.5754(4) 0.049(2) Uani d . C
H5A 1 0.7199(7) 0.3571(7) 0.6319(4) 0.058 Uiso calc R H
C6 1 0.6110(6) 0.3210(5) 0.4960(4) 0.0354(11) Uani d . C
H6A 1 0.5867(6) 0.3943(5) 0.4997(4) 0.043 Uiso calc R H
C7 1 0.2155(5) 0.4179(4) 0.2104(3) 0.0226(8) Uani d . C
C8 1 0.0716(5) 0.4213(5) 0.1770(3) 0.0288(9) Uani d . C
H8A 1 -0.0192(5) 0.3625(5) 0.1933(3) 0.035 Uiso calc R H
C9 1 0.0652(6) 0.5113(5) 0.1205(4) 0.0342(10) Uani d . C
H9A 1 -0.0295(6) 0.5153(5) 0.1005(4) 0.041 Uiso calc R H
C10 1 0.2004(7) 0.5963(5) 0.0931(4) 0.0378(11) Uani d . C
H10A 1 0.1947(7) 0.6559(5) 0.0541(4) 0.045 Uiso calc R H
C11 1 0.3405(6) 0.5939(4) 0.1221(3) 0.0286(9) Uani d . C
H11A 1 0.4290(6) 0.6499(4) 0.1014(3) 0.034 Uiso calc R H
C12 1 0.3530(5) 0.5071(4) 0.1836(3) 0.0231(8) Uani d . C
C13 1 0.1697(7) 0.1749(6) 0.4279(4) 0.0385(11) Uani d . C
H13A 1 0.2013(7) 0.1118(6) 0.3933(4) 0.058 Uiso calc R H
H13B 1 0.0918(7) 0.1335(6) 0.4671(4) 0.058 Uiso calc R H
H13C 1 0.2571(7) 0.2386(6) 0.4679(4) 0.058 Uiso calc R H
C14 1 -0.0799(6) 0.1303(5) 0.2618(4) 0.0375(11) Uani d . C
H14A 1 -0.1203(6) 0.1719(5) 0.2173(4) 0.056 Uiso calc R H
H14B 1 -0.1585(6) 0.0884(5) 0.3004(4) 0.056 Uiso calc R H
H14C 1 -0.0481(6) 0.0676(5) 0.2270(4) 0.056 Uiso calc R H
C15 1 0.0293(6) 0.3755(5) 0.4088(4) 0.0321(10) Uani d . C
H15A 1 -0.0119(6) 0.4166(5) 0.3644(4) 0.048 Uiso calc R H
H15B 1 0.1169(6) 0.4391(5) 0.4489(4) 0.048 Uiso calc R H
H15C 1 -0.0484(6) 0.3339(5) 0.4481(4) 0.048 Uiso calc R H
C16 1 0.8075(7) 0.5956(6) 0.3185(5) 0.0448(13) Uani d . C
H16A 1 0.8217(7) 0.5193(6) 0.2904(5) 0.067 Uiso calc R H
H16B 1 0.7661(7) 0.5819(6) 0.3784(5) 0.067 Uiso calc R H
H16C 1 0.9052(7) 0.6668(6) 0.3294(5) 0.067 Uiso calc R H
C17 1 0.7459(7) 0.6588(6) 0.1170(4) 0.0426(13) Uani d . C
H17A 1 0.6734(7) 0.6773(6) 0.0757(4) 0.064 Uiso calc R H
H17B 1 0.7593(7) 0.5827(6) 0.0879(4) 0.064 Uiso calc R H
H17C 1 0.8433(7) 0.7302(6) 0.1265(4) 0.064 Uiso calc R H
C18 1 0.6471(8) 0.7806(5) 0.2928(5) 0.0470(14) Uani d . C
H18A 1 0.5770(8) 0.8012(5) 0.2511(5) 0.071 Uiso calc R H
H18B 1 0.7456(8) 0.8509(5) 0.3038(5) 0.071 Uiso calc R H
H18C 1 0.6065(8) 0.7660(5) 0.3529(5) 0.071 Uiso calc R H
C19 1 0.2907(6) 0.1539(5) 0.1246(3) 0.0284(9) Uani d . C
H19A 1 0.1859(6) 0.1513(5) 0.1246(3) 0.034 Uiso calc R H
H19B 1 0.3238(6) 0.1801(5) 0.0641(3) 0.034 Uiso calc R H
C20 1 0.2778(6) 0.0127(5) 0.1190(4) 0.0337(10) Uani d . C
C21 1 0.1843(9) -0.0608(6) 0.0228(5) 0.054(2) Uani d . C
H21A 1 0.2359(9) -0.0222(6) -0.0288(5) 0.081 Uiso calc R H
H21B 1 0.0832(9) -0.0572(6) 0.0200(5) 0.081 Uiso calc R H
H21C 1 0.1753(9) -0.1491(6) 0.0170(5) 0.081 Uiso calc R H
C22 1 0.1956(9) -0.0489(6) 0.2007(5) 0.052(2) Uani d . C
H22A 1 0.0958(9) -0.0426(6) 0.1992(5) 0.078 Uiso calc R H
H22B 1 0.2557(9) -0.0048(6) 0.2610(5) 0.078 Uiso calc R H
H22C 1 0.1834(9) -0.1379(6) 0.1935(5) 0.078 Uiso calc R H
C23 1 0.4358(7) 0.0009(6) 0.1238(4) 0.0415(12) Uani d . C
H23A 1 0.4900(7) 0.0391(6) 0.0729(4) 0.062 Uiso calc R H
H23B 1 0.4222(7) -0.0884(6) 0.1171(4) 0.062 Uiso calc R H
H23C 1 0.4945(7) 0.0447(6) 0.1845(4) 0.062 Uiso calc R H
loop_
_atom_type_symbol
_atom_type_description
_atom_type_scat_dispersion_real
_atom_type_scat_dispersion_imag
_atom_type_scat_source
C C 0.0033 0.0016 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
H H 0.0000 0.0000 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
N N 0.0061 0.0033 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
Si Si 0.0817 0.0704 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
Cl Cl 0.1484 0.1585 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
W W -0.8490 6.8722 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
loop_
_geom_angle_atom_site_label_1
_geom_angle_atom_site_label_2
_geom_angle_atom_site_label_3
_geom_angle
_geom_angle_publ_flag
N1 W N2 82.62(15) yes
N3 W C19 108.8(2) yes
N1 W C19 88.0(2) yes
N2 W C19 124.5(2) yes
N3 W Cl 95.90(10) yes
N3 W N1 103.9(2) yes
N3 W N2 126.6(2) yes
N1 W Cl 160.20(10) yes
N2 W Cl 86.40(10) yes
C19 W Cl 84.70(10) yes
N1 Si1 C13 108.9(2) ?
N1 Si1 C15 109.4(2) ?
C13 Si1 C15 109.1(2) ?
N1 Si1 C14 109.7(2) ?
C13 Si1 C14 110.0(3) ?
C15 Si1 C14 109.7(2) ?
N2 Si2 C16 107.5(2) ?
N2 Si2 C18 108.9(2) ?
C16 Si2 C18 108.0(3) ?
N2 Si2 C17 111.5(2) ?
C16 Si2 C17 111.3(3) ?
C18 Si2 C17 109.5(3) ?
C7 N1 Si1 119.7(3) no
C7 N1 W 104.6(3) no
Si1 N1 W 135.1(2) no
C12 N2 Si2 123.4(3) no
C12 N2 W 102.9(3) no
Si2 N2 W 133.2(2) no
C1 N3 W 165.1(4) yes
C2 C1 N3 120.4(4) ?
C2 C1 C6 119.0(5) ?
N3 C1 C6 120.6(4) ?
C1 C2 C3 120.8(6) ?
C1 C2 H2A 119.6(3) ?
C3 C2 H2A 119.6(4) ?
C4 C3 C2 119.8(6) ?
C4 C3 H3A 120.1(4) ?
C2 C3 H3A 120.1(4) ?
C5 C4 C3 120.6(5) ?
C5 C4 H4A 119.7(4) ?
C3 C4 H4A 119.7(4) ?
C4 C5 C6 120.5(6) ?
C4 C5 H5A 119.8(4) ?
C6 C5 H5A 119.8(4) ?
C1 C6 C5 119.3(5) ?
C1 C6 H6A 120.4(3) ?
C5 C6 H6A 120.4(4) ?
N1 C7 C8 125.7(4) ?
N1 C7 C12 115.0(4) ?
C8 C7 C12 119.2(4) ?
C9 C8 C7 120.2(4) ?
C9 C8 H8A 119.9(3) ?
C7 C8 H8A 119.9(3) ?
C8 C9 C10 120.1(5) ?
C8 C9 H9A 120.0(3) ?
C10 C9 H9A 120.0(3) ?
C11 C10 C9 121.3(5) ?
C11 C10 H10A 119.4(3) ?
C9 C10 H10A 119.4(3) ?
C10 C11 C12 120.5(5) ?
C10 C11 H11A 119.7(3) ?
C12 C11 H11A 119.7(3) ?
N2 C12 C11 125.4(4) ?
N2 C12 C7 116.0(4) ?
C11 C12 C7 118.7(4) ?
Si1 C13 H13A 109.5(2) ?
Si1 C13 H13B 109.5(2) ?
H13A C13 H13B 109.5 ?
Si1 C13 H13C 109.5(2) ?
H13A C13 H13C 109.5 ?
H13B C13 H13C 109.5 ?
Si1 C14 H14A 109.5(2) ?
Si1 C14 H14B 109.5(2) ?
H14A C14 H14B 109.5 ?
Si1 C14 H14C 109.5(2) ?
H14A C14 H14C 109.5 ?
H14B C14 H14C 109.5 ?
Si1 C15 H15A 109.5(2) ?
Si1 C15 H15B 109.5(2) ?
H15A C15 H15B 109.5 ?
Si1 C15 H15C 109.5(2) ?
H15A C15 H15C 109.5 ?
H15B C15 H15C 109.5 ?
Si2 C16 H16A 109.5(2) ?
Si2 C16 H16B 109.5(2) ?
H16A C16 H16B 109.5 ?
Si2 C16 H16C 109.5(2) ?
H16A C16 H16C 109.5 ?
H16B C16 H16C 109.5 ?
Si2 C17 H17A 109.5(2) ?
Si2 C17 H17B 109.5(2) ?
H17A C17 H17B 109.5 ?
Si2 C17 H17C 109.5(2) ?
H17A C17 H17C 109.5 ?
H17B C17 H17C 109.5 ?
Si2 C18 H18A 109.5(2) ?
Si2 C18 H18B 109.5(2) ?
H18A C18 H18B 109.5 ?
Si2 C18 H18C 109.5(2) ?
H18A C18 H18C 109.5 ?
H18B C18 H18C 109.5 ?
C20 C19 W 126.1(3) ?
C20 C19 H19A 105.8(3) ?
W C19 H19A 105.80(13) ?
C20 C19 H19B 105.8(3) ?
W C19 H19B 105.80(13) ?
H19A C19 H19B 106.2 ?
C22 C20 C23 107.9(5) ?
C22 C20 C21 109.3(5) ?
C23 C20 C21 108.7(5) ?
C22 C20 C19 111.0(4) ?
C23 C20 C19 112.3(4) ?
C21 C20 C19 107.6(4) ?
C20 C21 H21A 109.5(4) ?
C20 C21 H21B 109.5(3) ?
H21A C21 H21B 109.5 ?
C20 C21 H21C 109.5(3) ?
H21A C21 H21C 109.5 ?
H21B C21 H21C 109.5 ?
C20 C22 H22A 109.5(4) ?
C20 C22 H22B 109.5(3) ?
H22A C22 H22B 109.5 ?
C20 C22 H22C 109.5(3) ?
H22A C22 H22C 109.5 ?
H22B C22 H22C 109.5 ?
C20 C23 H23A 109.5(3) ?
C20 C23 H23B 109.5(3) ?
H23A C23 H23B 109.5 ?
C20 C23 H23C 109.5(3) ?
H23A C23 H23C 109.5 ?
H23B C23 H23C 109.5 ?
loop_
_geom_bond_atom_site_label_1
_geom_bond_atom_site_label_2
_geom_bond_site_symmetry_2
_geom_bond_distance
_geom_bond_publ_flag
W N1 . 1.973(4) yes
W N2 . 2.013(4) yes
W N3 . 1.741(4) yes
W C19 . 2.182(5) yes
W Cl . 2.422(1) yes
Si1 N1 . 1.796(4) no
Si1 C13 . 1.856(5) ?
Si1 C15 . 1.857(5) ?
Si1 C14 . 1.874(5) ?
Si2 N2 . 1.768(4) no
Si2 C16 . 1.860(6) ?
Si2 C18 . 1.869(6) ?
Si2 C17 . 1.870(6) ?
N1 C7 . 1.410(5) no
N2 C12 . 1.399(6) no
N3 C1 . 1.388(6) yes
C1 C2 . 1.383(7) ?
C1 C6 . 1.402(7) ?
C2 C3 . 1.393(7) ?
C2 H2A . 0.93 ?
C3 C4 . 1.373(10) ?
C3 H3A . 0.93 ?
C4 C5 . 1.366(10) ?
C4 H4A . 0.93 ?
C5 C6 . 1.405(8) ?
C5 H5A . 0.93 ?
C6 H6A . 0.93 ?
C7 C8 . 1.411(6) ?
C7 C12 . 1.422(6) ?
C8 C9 . 1.377(7) ?
C8 H8A . 0.93 ?
C9 C10 . 1.392(8) ?
C9 H9A . 0.93 ?
C10 C11 . 1.358(7) ?
C10 H10A . 0.93 ?
C11 C12 . 1.410(6) ?
C11 H11A . 0.93 ?
C13 H13A . 0.96 ?
C13 H13B . 0.96 ?
C13 H13C . 0.96 ?
C14 H14A . 0.96 ?
C14 H14B . 0.96 ?
C14 H14C . 0.96 ?
C15 H15A . 0.96 ?
C15 H15B . 0.96 ?
C15 H15C . 0.96 ?
C16 H16A . 0.96 ?
C16 H16B . 0.96 ?
C16 H16C . 0.96 ?
C17 H17A . 0.96 ?
C17 H17B . 0.96 ?
C17 H17C . 0.96 ?
C18 H18A . 0.96 ?
C18 H18B . 0.96 ?
C18 H18C . 0.96 ?
C19 C20 . 1.543(6) ?
C19 H19A . 0.97 ?
C19 H19B . 0.97 ?
C20 C22 . 1.524(8) ?
C20 C23 . 1.528(8) ?
C20 C21 . 1.532(7) ?
C21 H21A . 0.96 ?
C21 H21B . 0.96 ?
C21 H21C . 0.96 ?
C22 H22A . 0.96 ?
C22 H22B . 0.96 ?
C22 H22C . 0.96 ?
C23 H23A . 0.96 ?
C23 H23B . 0.96 ?
C23 H23C . 0.96 ?
loop_
_geom_torsion_atom_site_label_1
_geom_torsion_atom_site_label_2
_geom_torsion_atom_site_label_3
_geom_torsion_atom_site_label_4
_geom_torsion
C13 Si1 N1 C7 -168.6(3)
C15 Si1 N1 C7 -49.5(4)
C14 Si1 N1 C7 70.9(4)
C13 Si1 N1 W 21.3(4)
C15 Si1 N1 W 140.5(3)
C14 Si1 N1 W -99.2(3)
N3 W N1 C7 162.0(3)
N2 W N1 C7 36.0(3)
C19 W N1 C7 -89.1(3)
Cl W N1 C7 -20.9(5)
N3 W N1 Si1 -27.0(3)
N2 W N1 Si1 -152.9(3)
C19 W N1 Si1 81.9(3)
Cl W N1 Si1 150.2(2)
C16 Si2 N2 C12 164.8(4)
C18 Si2 N2 C12 48.0(4)
C17 Si2 N2 C12 -73.0(4)
C16 Si2 N2 W -25.5(4)
C18 Si2 N2 W -142.3(3)
C17 Si2 N2 W 96.7(3)
N3 W N2 C12 -138.7(3)
N1 W N2 C12 -36.8(3)
C19 W N2 C12 45.6(3)
Cl W N2 C12 126.7(3)
N3 W N2 Si2 50.1(4)
N1 W N2 Si2 152.0(3)
C19 W N2 Si2 -125.6(3)
Cl W N2 Si2 -44.6(3)
N1 W N3 C1 -117.7(13)
N2 W N3 C1 -26.6(14)
C19 W N3 C1 149.7(13)
Cl W N3 C1 63.3(13)
W N3 C1 C2 -124.2(12)
W N3 C1 C6 56.8(15)
N3 C1 C2 C3 179.1(5)
C6 C1 C2 C3 -1.9(7)
C1 C2 C3 C4 2.2(8)
C2 C3 C4 C5 -1.4(9)
C3 C4 C5 C6 0.4(9)
C2 C1 C6 C5 0.9(7)
N3 C1 C6 C5 179.8(5)
C4 C5 C6 C1 -0.1(8)
Si1 N1 C7 C8 -21.2(6)
W N1 C7 C8 151.6(4)
Si1 N1 C7 C12 158.9(3)
W N1 C7 C12 -28.3(4)
N1 C7 C8 C9 179.1(4)
C12 C7 C8 C9 -1.0(7)
C7 C8 C9 C10 2.4(8)
C8 C9 C10 C11 -0.9(8)
C9 C10 C11 C12 -1.9(8)
Si2 N2 C12 C11 22.6(6)
W N2 C12 C11 -149.8(4)
Si2 N2 C12 C7 -156.7(3)
W N2 C12 C7 30.9(4)
C10 C11 C12 N2 -176.1(5)
C10 C11 C12 C7 3.2(7)
N1 C7 C12 N2 -2.5(6)
C8 C7 C12 N2 177.7(4)
N1 C7 C12 C11 178.2(4)
C8 C7 C12 C11 -1.7(6)
N3 W C19 C20 -14.2(5)
N1 W C19 C20 -118.2(4)
N2 W C19 C20 162.2(4)
Cl W C19 C20 80.2(4)
W C19 C20 C22 67.8(6)
W C19 C20 C23 -53.1(6)
W C19 C20 C21 -172.7(4)
loop_
_cod_related_entry_id
_cod_related_entry_database
_cod_related_entry_code
1 ChemSpider 30652163
