#------------------------------------------------------------------------------
#$Date: 2016-02-20 00:18:51 +0200 (Sat, 20 Feb 2016) $
#$Revision: 176760 $
#$URL: svn://www.crystallography.net/cod/cif/2/01/16/2011647.cif $
#------------------------------------------------------------------------------
#
# This file is available in the Crystallography Open Database (COD),
# http://www.crystallography.net/. The original data for this entry
# were provided by IUCr Journals, http://journals.iucr.org/.
#
# The file may be used within the scientific community so long as
# proper attribution is given to the journal article from which the
# data were obtained.
#
data_2011647
loop_
_publ_author_name
'Ellis, Dianne D.'
'Spek, Anthony L.'
_publ_section_title
;
 Tetrakis(triphenylphosphine)silver(I) tetraphenylborate acetonitrile
 solvate
;
_journal_issue                   12
_journal_name_full               'Acta Crystallographica Section C'
_journal_page_first              e547
_journal_page_last               e548
_journal_paper_doi               10.1107/S0108270100015079
_journal_volume                  56
_journal_year                    2000
_chemical_formula_iupac          '[Ag (C18 H15 P)4] (C24 H20 B), C2 H3 N'
_chemical_formula_moiety         'C72 H60 Ag P4, C24 H20 B, C2 H3 N'
_chemical_formula_sum            'C98 H83 Ag B N P4'
_chemical_formula_weight         1517.21
_chemical_name_systematic
;
 ?
;
_space_group_IT_number           73
_symmetry_cell_setting           orthorhombic
_symmetry_space_group_name_Hall  '-I 2b 2c'
_symmetry_space_group_name_H-M   'I b c a'
_audit_creation_method           SHELXL-97
_cell_angle_alpha                90.00
_cell_angle_beta                 90.00
_cell_angle_gamma                90.00
_cell_formula_units_Z            8
_cell_length_a                   21.763(2)
_cell_length_b                   22.955(2)
_cell_length_c                   30.767(2)
_cell_measurement_reflns_used    22
_cell_measurement_temperature    150(2)
_cell_measurement_theta_max      13.63
_cell_measurement_theta_min      11.56
_cell_volume                     15370(2)
_computing_cell_refinement       'SET4 (de Boer & Duisenberg, 1984)'
_computing_data_collection
'locally modified CAD-4 Software (Enraf-Nonius, 1989)'
_computing_data_reduction        'HELENA (Spek, 1997)'
_computing_publication_material  'PLATON (Spek, 2000)'
_computing_structure_refinement  'SHELXL97 (Sheldrick, 1997)'
_computing_structure_solution    'DIRDIF (Beurksens et al., 1999)'
_diffrn_ambient_temperature      150(2)
_diffrn_measured_fraction_theta_full .963
_diffrn_measured_fraction_theta_max .963
_diffrn_measurement_device_type  'Enraf-Nonius CAD-4T'
_diffrn_measurement_method       ω
_diffrn_radiation_monochromator  graphite
_diffrn_radiation_source         'rotating anode'
_diffrn_radiation_type           MoK\a
_diffrn_radiation_wavelength     .71073
_diffrn_reflns_av_R_equivalents  .103
_diffrn_reflns_av_sigmaI/netI    .1212
_diffrn_reflns_limit_h_max       25
_diffrn_reflns_limit_h_min       -5
_diffrn_reflns_limit_k_max       27
_diffrn_reflns_limit_k_min       -5
_diffrn_reflns_limit_l_max       36
_diffrn_reflns_limit_l_min       -36
_diffrn_reflns_number            11437
_diffrn_reflns_theta_full        25.00
_diffrn_reflns_theta_max         25
_diffrn_reflns_theta_min         1.32
_diffrn_standards_decay_%        .5
_diffrn_standards_interval_time  60
_diffrn_standards_number         3
_exptl_absorpt_coefficient_mu    .396
_exptl_absorpt_correction_type   none
_exptl_crystal_colour            colourless
_exptl_crystal_density_diffrn    1.311
_exptl_crystal_density_method    'not measured'
_exptl_crystal_description       block
_exptl_crystal_F_000             6320
_exptl_crystal_size_max          .30
_exptl_crystal_size_mid          .30
_exptl_crystal_size_min          .30
_refine_diff_density_max         .718
_refine_diff_density_min         -.685
_refine_ls_extinction_method     none
_refine_ls_goodness_of_fit_ref   1.013
_refine_ls_hydrogen_treatment    constr
_refine_ls_matrix_type           full
_refine_ls_number_parameters     476
_refine_ls_number_reflns         6511
_refine_ls_number_restraints     0
_refine_ls_restrained_S_all      1.013
_refine_ls_R_factor_all          .128
_refine_ls_R_factor_gt           .058
_refine_ls_shift/su_max          <0.001
_refine_ls_shift/su_mean         <0.001
_refine_ls_structure_factor_coef Fsqd
_refine_ls_weighting_details
'calc w = 1/[σ²(Fo²)+(0.0514P)²] where P = (Fo²+2Fc²)/3'
_refine_ls_weighting_scheme      calc
_refine_ls_wR_factor_ref         .140
_reflns_number_gt                3689
_reflns_number_total             6511
_reflns_threshold_expression     I>2σ(I)
_cod_data_source_file            qa0442.cif
_cod_data_source_block           I
_cod_database_code               2011647
_cod_database_fobs_code          2011647
loop_
_symmetry_equiv_pos_as_xyz
'x, y, z'
'-x, -y+1/2, z'
'x, -y, -z+1/2'
'-x, y+1/2, -z+1/2'
'x+1/2, y+1/2, z+1/2'
'-x+1/2, -y+1, z+1/2'
'x+1/2, -y+1/2, -z+1'
'-x+1/2, y+1, -z+1'
'-x, -y, -z'
'x, y-1/2, -z'
'-x, y, z-1/2'
'x, -y-1/2, z-1/2'
'-x+1/2, -y+1/2, -z+1/2'
'x+1/2, y, -z+1/2'
'-x+1/2, y+1/2, z'
'x+1/2, -y, z'
loop_
_atom_site_label
_atom_site_fract_x
_atom_site_fract_y
_atom_site_fract_z
_atom_site_U_iso_or_equiv
_atom_site_adp_type
_atom_site_calc_flag
_atom_site_refinement_flags
_atom_site_occupancy
_atom_site_disorder_assembly
_atom_site_disorder_group
_atom_site_type_symbol
Ag1 .0000 .2500 .06285(2) .01927(14) Uani d S 1 . . Ag
P1 -.06671(6) .31841(6) .11337(5) .0226(3) Uani d . 1 . . P
P2 .06968(6) .31386(6) .01336(5) .0194(3) Uani d . 1 . . P
C1 -.1198(2) .3690(2) .08737(18) .0206(12) Uani d . 1 . . C
C2 -.1059(3) .3932(3) .0480(2) .0369(16) Uani d . 1 . . C
H2 -.0690 .3822 .0336 .044 Uiso calc R 1 . . H
C3 -.1447(3) .4339(2) .0283(2) .0400(17) Uani d . 1 . . C
H3 -.1339 .4506 .0010 .048 Uiso calc R 1 . . H
C4 -.1986(3) .4499(3) .0484(2) .0401(17) Uani d . 1 . . C
H4 -.2250 .4780 .0355 .048 Uiso calc R 1 . . H
C5 -.2137(3) .4247(2) .0873(2) .0303(15) Uani d . 1 . . C
H5 -.2517 .4344 .1007 .036 Uiso calc R 1 . . H
C6 -.1752(2) .3858(2) .1072(2) .0307(14) Uani d . 1 . . C
H61 -.1860 .3700 .1348 .037 Uiso calc R 1 . . H
C7 -.0240(2) .3658(2) .1504(2) .0274(13) Uani d . 1 . . C
C8 -.0367(2) .4246(2) .15618(19) .0270(13) Uani d . 1 . . C
H8 -.0685 .4424 .1397 .032 Uiso calc R 1 . . H
C9 -.0036(3) .4575(2) .1856(2) .0349(13) Uani d . 1 . . C
H9 -.0121 .4979 .1886 .042 Uiso calc R 1 . . H
C10 .0416(3) .4321(3) .2104(2) .0364(16) Uani d . 1 . . C
H10 .0636 .4546 .2311 .044 Uiso calc R 1 . . H
C11 .0547(3) .3738(3) .2051(2) .0389(16) Uani d . 1 . . C
H11 .0861 .3563 .2222 .047 Uiso calc R 1 . . H
C12 .0229(3) .3409(2) .17552(19) .0326(15) Uani d . 1 . . C
H12 .0328 .3008 .1720 .039 Uiso calc R 1 . . H
C13 -.1176(2) .2789(2) .15006(19) .0266(13) Uani d . 1 . . C
C14 -.1216(3) .2895(2) .19466(19) .0326(14) Uani d . 1 . . C
H14 -.0970 .3190 .2075 .039 Uiso calc R 1 . . H
C15 -.1615(3) .2572(3) .2202(2) .0420(17) Uani d . 1 . . C
H15 -.1638 .2643 .2505 .050 Uiso calc R 1 . . H
C16 -.1975(3) .2149(3) .2018(2) .0439(19) Uani d . 1 . . C
H16 -.2244 .1926 .2195 .053 Uiso calc R 1 . . H
C17 -.1950(3) .2045(3) .1581(2) .0404(17) Uani d . 1 . . C
H17 -.2207 .1756 .1455 .049 Uiso calc R 1 . . H
C18 -.1549(2) .2363(2) .1321(2) .0310(16) Uani d . 1 . . C
H18 -.1531 .2287 .1018 .037 Uiso calc R 1 . . H
C19 .1205(2) .2777(2) -.02543(19) .0209(12) Uani d . 1 . . C
C20 .1535(3) .2288(2) -.0117(2) .0303(15) Uani d . 1 . . C
H201 .1499 .2154 .0174 .036 Uiso calc R 1 . . H
C21 .1912(3) .2002(3) -.0406(2) .0379(16) Uani d . 1 . . C
H21 .2132 .1667 -.0313 .045 Uiso calc R 1 . . H
C22 .1979(3) .2191(3) -.0830(2) .0382(16) Uani d . 1 . . C
H22 .2243 .1993 -.1026 .046 Uiso calc R 1 . . H
C23 .1655(3) .2674(3) -.0961(2) .0435(18) Uani d . 1 . . C
H23 .1696 .2809 -.1252 .052 Uiso calc R 1 . . H
C24 .1271(2) .2964(2) -.06802(19) .0311(13) Uani d . 1 . . C
H24 .1050 .3296 -.0779 .037 Uiso calc R 1 . . H
C25 .0291(2) .3661(2) -.02123(18) .0237(12) Uani d . 1 . . C
C26 -.0191(2) .3454(2) -.0467(2) .0280(14) Uani d . 1 . . C
H26 -.0300 .3054 -.0453 .034 Uiso calc R 1 . . H
C27 -.0507(3) .3819(3) -.0734(2) .0433(17) Uani d . 1 . . C
H27 -.0837 .3671 -.0904 .052 Uiso calc R 1 . . H
C28 -.0353(3) .4398(3) -.0762(2) .0477(19) Uani d . 1 . . C
H28 -.0576 .4651 -.0948 .057 Uiso calc R 1 . . H
C29 .0132(3) .4609(3) -.0515(2) .047(2) Uani d . 1 . . C
H29 .0246 .5008 -.0536 .056 Uiso calc R 1 . . H
C30 .0448(3) .4242(2) -.0240(2) .0347(15) Uani d . 1 . . C
H30 .0776 .4390 -.0069 .042 Uiso calc R 1 . . H
C31 .1218(2) .3606(2) .04394(18) .0232(12) Uani d . 1 . . C
C32 .1839(2) .3644(2) .0365(2) .0352(15) Uani d . 1 . . C
H32 .2018 .3425 .0136 .042 Uiso calc R 1 . . H
C33 .2207(3) .3994(3) .0618(2) .0503(19) Uani d . 1 . . C
H33 .2637 .4011 .0564 .060 Uiso calc R 1 . . H
C34 .1954(3) .4320(3) .0949(2) .0437(18) Uani d . 1 . . C
H34 .2208 .4565 .1120 .052 Uiso calc R 1 . . H
C35 .1332(3) .4290(2) .1032(2) .0342(15) Uani d . 1 . . C
H35 .1157 .4515 .1259 .041 Uiso calc R 1 . . H
C36 .0967(3) .3931(2) .07824(18) .0241(13) Uani d . 1 . . C
H36 .0540 .3904 .0843 .029 Uiso calc R 1 . . H
B1 .2161(4) .0000 .2500 .0234(19) Uani d S 1 . . B
C37 .1712(2) -.0363(2) .21717(18) .0234(13) Uani d . 1 . . C
C38 .1227(2) -.0703(2) .23330(19) .0279(13) Uani d . 1 . . C
H38 .1165 -.0720 .2638 .033 Uiso calc R 1 . . H
C39 .0830(3) -.1019(3) .2061(2) .0353(15) Uani d . 1 . . C
H39 .0511 -.1247 .2185 .042 Uiso calc R 1 . . H
C40 .0897(3) -.1004(3) .1622(2) .0361(16) Uani d . 1 . . C
H40 .0639 -.1230 .1439 .043 Uiso calc R 1 . . H
C41 .1348(3) -.0652(3) .1447(2) .0429(17) Uani d . 1 . . C
H41 .1386 -.0615 .1141 .051 Uiso calc R 1 . . H
C42 .1748(3) -.0352(3) .17210(18) .0309(14) Uani d . 1 . . C
H42 .2064 -.0126 .1592 .037 Uiso calc R 1 . . H
C43 .2614(2) .0445(2) .22240(17) .0221(12) Uani d . 1 . . C
C44 .3144(3) .0240(2) .20171(16) .0247(13) Uani d . 1 . . C
H44 .3229 -.0165 .2029 .030 Uiso calc R 1 . . H
C45 .3549(2) .0594(3) .17965(19) .0328(14) Uani d . 1 . . C
H45 .3908 .0432 .1669 .039 Uiso calc R 1 . . H
C46 .3434(3) .1188(2) .17599(19) .0336(15) Uani d . 1 . . C
H46 .3710 .1436 .1607 .040 Uiso calc R 1 . . H
C47 .2914(3) .1406(2) .19496(18) .0313(14) Uani d . 1 . . C
H47 .2825 .1810 .1926 .038 Uiso calc R 1 . . H
C48 .2511(3) .1044(2) .21769(18) .0268(12) Uani d . 1 . . C
H48 .2154 .1210 .2304 .032 Uiso calc R 1 . . H
N200 .0000 .2500 .3637(5) .172(8) Uani d S 1 . . N
C100 .0000 .2500 .3285(5) .079(4) Uani d S 1 . . C
C300 .0000 .2500 .2850(6) .264(16) Uani d S 1 . . C
H301 .0076 .2896 .2744 .396 Uiso calc PR .50 . . H
H302 -.0400 .2365 .2744 .396 Uiso calc PR .50 . . H
H303 .0324 .2239 .2744 .396 Uiso calc PR .50 . . H
loop_
_atom_type_symbol
_atom_type_description
_atom_type_scat_dispersion_real
_atom_type_scat_dispersion_imag
_atom_type_scat_source
C C .0033 .0016 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
H H .0000 .0000 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
Ag Ag -.8971 1.1015 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
B B .0013 .0007 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
N N .0061 .0033 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
P P .1023 .0942 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
loop_
_geom_angle_atom_site_label_1
_geom_angle_atom_site_label_2
_geom_angle_atom_site_label_3
_geom_angle_site_symmetry_1
_geom_angle_site_symmetry_3
_geom_angle
_geom_angle_publ_flag
P2 Ag1 P2 2 . 108.34(6) y
P2 Ag1 P1 2 2 109.24(4) ?
P2 Ag1 P1 . 2 111.02(4) ?
P2 Ag1 P1 2 . 111.02(4) y
P2 Ag1 P1 . . 109.24(4) y
P1 Ag1 P1 2 . 107.98(7) y
C1 P1 C13 . . 101.7(2) ?
C1 P1 C7 . . 102.5(2) ?
C13 P1 C7 . . 102.6(3) ?
C1 P1 Ag1 . . 117.93(18) ?
C13 P1 Ag1 . . 113.70(18) ?
C7 P1 Ag1 . . 116.17(18) ?
C31 P2 C19 . . 103.2(2) ?
C31 P2 C25 . . 102.4(2) ?
C19 P2 C25 . . 102.1(3) ?
C31 P2 Ag1 . . 113.09(18) ?
C19 P2 Ag1 . . 118.64(16) ?
C25 P2 Ag1 . . 115.38(18) ?
C2 C1 C6 . . 117.6(5) ?
C2 C1 P1 . . 120.6(4) ?
C6 C1 P1 . . 121.8(4) ?
C1 C2 C3 . . 121.5(6) ?
C1 C2 H2 . . 119.2 ?
C3 C2 H2 . . 119.2 ?
C4 C3 C2 . . 119.8(6) ?
C4 C3 H3 . . 120.1 ?
C2 C3 H3 . . 120.1 ?
C5 C4 C3 . . 119.1(6) ?
C5 C4 H4 . . 120.4 ?
C3 C4 H4 . . 120.4 ?
C4 C5 C6 . . 121.3(6) ?
C4 C5 H5 . . 119.3 ?
C6 C5 H5 . . 119.3 ?
C5 C6 C1 . . 120.6(6) ?
C5 C6 H61 . . 119.7 ?
C1 C6 H61 . . 119.7 ?
C8 C7 C12 . . 118.1(5) ?
C8 C7 P1 . . 123.9(5) ?
C12 C7 P1 . . 118.0(4) ?
C9 C8 C7 . . 120.8(5) ?
C9 C8 H8 . . 119.6 ?
C7 C8 H8 . . 119.6 ?
C10 C9 C8 . . 120.3(5) ?
C10 C9 H9 . . 119.8 ?
C8 C9 H9 . . 119.8 ?
C9 C10 C11 . . 119.7(6) ?
C9 C10 H10 . . 120.2 ?
C11 C10 H10 . . 120.2 ?
C12 C11 C10 . . 120.6(6) ?
C12 C11 H11 . . 119.7 ?
C10 C11 H11 . . 119.7 ?
C11 C12 C7 . . 120.5(5) ?
C11 C12 H12 . . 119.7 ?
C7 C12 H12 . . 119.7 ?
C18 C13 C14 . . 118.5(5) ?
C18 C13 P1 . . 117.5(5) ?
C14 C13 P1 . . 124.0(4) ?
C15 C14 C13 . . 120.1(6) ?
C15 C14 H14 . . 119.9 ?
C13 C14 H14 . . 119.9 ?
C16 C15 C14 . . 120.3(6) ?
C16 C15 H15 . . 119.9 ?
C14 C15 H15 . . 119.9 ?
C17 C16 C15 . . 120.5(6) ?
C17 C16 H16 . . 119.7 ?
C15 C16 H16 . . 119.7 ?
C16 C17 C18 . . 119.8(6) ?
C16 C17 H17 . . 120.1 ?
C18 C17 H17 . . 120.1 ?
C13 C18 C17 . . 120.7(6) ?
C13 C18 H18 . . 119.6 ?
C17 C18 H18 . . 119.6 ?
C24 C19 C20 . . 118.8(5) ?
C24 C19 P2 . . 122.7(4) ?
C20 C19 P2 . . 118.6(4) ?
C21 C20 C19 . . 119.5(6) ?
C21 C20 H201 . . 120.2 ?
C19 C20 H201 . . 120.2 ?
C20 C21 C22 . . 121.5(6) ?
C20 C21 H21 . . 119.2 ?
C22 C21 H21 . . 119.2 ?
C23 C22 C21 . . 118.5(6) ?
C23 C22 H22 . . 120.7 ?
C21 C22 H22 . . 120.7 ?
C22 C23 C24 . . 121.2(6) ?
C22 C23 H23 . . 119.4 ?
C24 C23 H23 . . 119.4 ?
C23 C24 C19 . . 120.5(5) ?
C23 C24 H24 . . 119.7 ?
C19 C24 H24 . . 119.7 ?
C30 C25 C26 . . 118.8(5) ?
C30 C25 P2 . . 123.4(4) ?
C26 C25 P2 . . 117.8(4) ?
C27 C26 C25 . . 120.7(5) ?
C27 C26 H26 . . 119.6 ?
C25 C26 H26 . . 119.6 ?
C26 C27 C28 . . 120.6(6) ?
C26 C27 H27 . . 119.7 ?
C28 C27 H27 . . 119.7 ?
C27 C28 C29 . . 119.4(6) ?
C27 C28 H28 . . 120.3 ?
C29 C28 H28 . . 120.3 ?
C30 C29 C28 . . 120.1(6) ?
C30 C29 H29 . . 120.0 ?
C28 C29 H29 . . 120.0 ?
C25 C30 C29 . . 120.4(6) ?
C25 C30 H30 . . 119.8 ?
C29 C30 H30 . . 119.8 ?
C32 C31 C36 . . 118.2(5) ?
C32 C31 P2 . . 124.4(4) ?
C36 C31 P2 . . 117.3(4) ?
C31 C32 C33 . . 121.1(6) ?
C31 C32 H32 . . 119.4 ?
C33 C32 H32 . . 119.4 ?
C32 C33 C34 . . 120.1(6) ?
C32 C33 H33 . . 119.9 ?
C34 C33 H33 . . 119.9 ?
C33 C34 C35 . . 120.1(6) ?
C33 C34 H34 . . 119.9 ?
C35 C34 H34 . . 119.9 ?
C36 C35 C34 . . 119.6(6) ?
C36 C35 H35 . . 120.2 ?
C34 C35 H35 . . 120.2 ?
C35 C36 C31 . . 120.8(6) ?
C35 C36 H36 . . 119.6 ?
C31 C36 H36 . . 119.6 ?
C37 B1 C37 . 3 106.6(6) ?
C37 B1 C43 . 3 111.0(2) ?
C37 B1 C43 3 3 110.7(3) ?
C37 B1 C43 . . 110.7(3) ?
C37 B1 C43 3 . 111.0(2) ?
C43 B1 C43 3 . 106.8(6) ?
C42 C37 C38 . . 113.9(5) ?
C42 C37 B1 . . 125.1(5) ?
C38 C37 B1 . . 121.0(5) ?
C37 C38 C39 . . 122.6(6) ?
C37 C38 H38 . . 118.7 ?
C39 C38 H38 . . 118.7 ?
C40 C39 C38 . . 120.8(6) ?
C40 C39 H39 . . 119.6 ?
C38 C39 H39 . . 119.6 ?
C39 C40 C41 . . 118.7(6) ?
C39 C40 H40 . . 120.7 ?
C41 C40 H40 . . 120.7 ?
C40 C41 C42 . . 119.9(6) ?
C40 C41 H41 . . 120.1 ?
C42 C41 H41 . . 120.1 ?
C37 C42 C41 . . 124.0(6) ?
C37 C42 H42 . . 118.0 ?
C41 C42 H42 . . 118.0 ?
C44 C43 C48 . . 114.6(5) ?
C44 C43 B1 . . 121.2(5) ?
C48 C43 B1 . . 124.3(4) ?
C45 C44 C43 . . 123.6(5) ?
C45 C44 H44 . . 118.2 ?
C43 C44 H44 . . 118.2 ?
C44 C45 C46 . . 120.2(5) ?
C44 C45 H45 . . 119.9 ?
C46 C45 H45 . . 119.9 ?
C47 C46 C45 . . 118.2(5) ?
C47 C46 H46 . . 120.9 ?
C45 C46 H46 . . 120.9 ?
C46 C47 C48 . . 121.1(5) ?
C46 C47 H47 . . 119.5 ?
C48 C47 H47 . . 119.5 ?
C47 C48 C43 . . 122.4(5) ?
C47 C48 H48 . . 118.8 ?
C43 C48 H48 . . 118.8 ?
N200 C100 C300 . . 180.0 ?
C100 C300 H301 . . 109.5 ?
C100 C300 H302 . . 109.5 ?
H301 C300 H302 . . 109.5 ?
C100 C300 H303 . . 109.5 ?
H301 C300 H303 . . 109.5 ?
H302 C300 H303 . . 109.5 ?
loop_
_geom_bond_atom_site_label_1
_geom_bond_atom_site_label_2
_geom_bond_site_symmetry_2
_geom_bond_distance
_geom_bond_publ_flag
Ag1 P2 2 2.6013(13) ?
Ag1 P2 . 2.6014(13) y
Ag1 P1 2 2.6435(14) ?
Ag1 P1 . 2.6436(14) y
P1 C1 . 1.822(5) ?
P1 C13 . 1.823(6) ?
P1 C7 . 1.829(6) ?
P2 C31 . 1.822(5) ?
P2 C19 . 1.827(5) ?
P2 C25 . 1.830(6) ?
C1 C2 . 1.368(8) ?
C1 C6 . 1.405(7) ?
C2 C3 . 1.398(8) ?
C2 H2 . .9500 ?
C3 C4 . 1.376(9) ?
C3 H3 . .9500 ?
C4 C5 . 1.367(9) ?
C4 H4 . .9500 ?
C5 C6 . 1.372(8) ?
C5 H5 . .9500 ?
C6 H61 . .9500 ?
C7 C8 . 1.388(7) ?
C7 C12 . 1.404(7) ?
C8 C9 . 1.380(8) ?
C8 H8 . .9500 ?
C9 C10 . 1.376(9) ?
C9 H9 . .9500 ?
C10 C11 . 1.377(8) ?
C10 H10 . .9500 ?
C11 C12 . 1.372(8) ?
C11 H11 . .9500 ?
C12 H12 . .9500 ?
C13 C18 . 1.385(7) ?
C13 C14 . 1.397(8) ?
C14 C15 . 1.385(8) ?
C14 H14 . .9500 ?
C15 C16 . 1.370(9) ?
C15 H15 . .9500 ?
C16 C17 . 1.367(9) ?
C16 H16 . .9500 ?
C17 C18 . 1.390(8) ?
C17 H17 . .9500 ?
C18 H18 . .9500 ?
C19 C24 . 1.387(8) ?
C19 C20 . 1.397(7) ?
C20 C21 . 1.379(8) ?
C20 H201 . .9500 ?
C21 C22 . 1.381(9) ?
C21 H21 . .9500 ?
C22 C23 . 1.374(8) ?
C22 H22 . .9500 ?
C23 C24 . 1.374(8) ?
C23 H23 . .9500 ?
C24 H24 . .9500 ?
C25 C30 . 1.378(7) ?
C25 C26 . 1.393(7) ?
C26 C27 . 1.360(8) ?
C26 H26 . .9500 ?
C27 C28 . 1.373(9) ?
C27 H27 . .9500 ?
C28 C29 . 1.387(9) ?
C28 H28 . .9500 ?
C29 C30 . 1.380(8) ?
C29 H29 . .9500 ?
C30 H30 . .9500 ?
C31 C32 . 1.374(7) ?
C31 C36 . 1.403(8) ?
C32 C33 . 1.374(8) ?
C32 H32 . .9500 ?
C33 C34 . 1.378(9) ?
C33 H33 . .9500 ?
C34 C35 . 1.378(9) ?
C34 H34 . .9500 ?
C35 C36 . 1.377(8) ?
C35 H35 . .9500 ?
C36 H36 . .9500 ?
B1 C37 . 1.633(7) ?
B1 C37 3 1.633(7) ?
B1 C43 3 1.656(7) ?
B1 C43 . 1.656(7) ?
C37 C42 . 1.389(8) ?
C37 C38 . 1.404(7) ?
C38 C39 . 1.405(8) ?
C38 H38 . .9500 ?
C39 C40 . 1.359(8) ?
C39 H39 . .9500 ?
C40 C41 . 1.380(8) ?
C40 H40 . .9500 ?
C41 C42 . 1.393(8) ?
C41 H41 . .9500 ?
C42 H42 . .9500 ?
C43 C44 . 1.398(7) ?
C43 C48 . 1.400(7) ?
C44 C45 . 1.378(7) ?
C44 H44 . .9500 ?
C45 C46 . 1.390(8) ?
C45 H45 . .9500 ?
C46 C47 . 1.369(8) ?
C46 H46 . .9500 ?
C47 C48 . 1.396(7) ?
C47 H47 . .9500 ?
C48 H48 . .9500 ?
N200 C100 . 1.083(17) ?
C100 C300 . 1.34(2) ?
C300 H301 . .9800 ?
C300 H302 . .9800 ?
C300 H303 . .9800 ?
loop_
_geom_torsion_atom_site_label_1
_geom_torsion_atom_site_label_2
_geom_torsion_atom_site_label_3
_geom_torsion_atom_site_label_4
_geom_torsion_site_symmetry_1
_geom_torsion
P2 Ag1 P1 C1 2 -58.1(2)
P2 Ag1 P1 C1 . 61.3(2)
P1 Ag1 P1 C1 2 -177.8(2)
P2 Ag1 P1 C13 2 60.8(2)
P2 Ag1 P1 C13 . -179.7(2)
P1 Ag1 P1 C13 2 -58.9(2)
P2 Ag1 P1 C7 2 179.7(2)
P2 Ag1 P1 C7 . -60.9(2)
P1 Ag1 P1 C7 2 59.9(2)
P2 Ag1 P2 C31 2 -179.4(2)
P1 Ag1 P2 C31 2 -59.4(2)
P1 Ag1 P2 C31 . 59.5(2)
P2 Ag1 P2 C19 2 -58.4(2)
P1 Ag1 P2 C19 2 61.6(2)
P1 Ag1 P2 C19 . -179.5(2)
P2 Ag1 P2 C25 2 63.18(19)
P1 Ag1 P2 C25 2 -176.86(19)
P1 Ag1 P2 C25 . -57.9(2)
C13 P1 C1 C2 . -158.1(5)
C7 P1 C1 C2 . 96.0(5)
Ag1 P1 C1 C2 . -33.0(6)
C13 P1 C1 C6 . 23.8(5)
C7 P1 C1 C6 . -82.1(5)
Ag1 P1 C1 C6 . 148.9(4)
C6 C1 C2 C3 . .9(9)
P1 C1 C2 C3 . -177.3(5)
C1 C2 C3 C4 . -.7(10)
C2 C3 C4 C5 . -1.0(9)
C3 C4 C5 C6 . 2.6(9)
C4 C5 C6 C1 . -2.4(9)
C2 C1 C6 C5 . .6(8)
P1 C1 C6 C5 . 178.8(4)
C1 P1 C7 C8 . 3.7(6)
C13 P1 C7 C8 . -101.6(5)
Ag1 P1 C7 C8 . 133.8(4)
C1 P1 C7 C12 . -178.4(5)
C13 P1 C7 C12 . 76.3(5)
Ag1 P1 C7 C12 . -48.4(5)
C12 C7 C8 C9 . .5(9)
P1 C7 C8 C9 . 178.3(5)
C7 C8 C9 C10 . -1.6(10)
C8 C9 C10 C11 . 1.6(10)
C9 C10 C11 C12 . -.4(10)
C10 C11 C12 C7 . -.7(10)
C8 C7 C12 C11 . .7(9)
P1 C7 C12 C11 . -177.3(5)
C1 P1 C13 C18 . 77.3(4)
C7 P1 C13 C18 . -176.8(4)
Ag1 P1 C13 C18 . -50.5(5)
C1 P1 C13 C14 . -101.8(5)
C7 P1 C13 C14 . 4.0(5)
Ag1 P1 C13 C14 . 130.3(4)
C18 C13 C14 C15 . 1.1(8)
P1 C13 C14 C15 . -179.7(4)
C13 C14 C15 C16 . -.5(9)
C14 C15 C16 C17 . -.7(10)
C15 C16 C17 C18 . 1.2(10)
C14 C13 C18 C17 . -.6(8)
P1 C13 C18 C17 . -179.8(4)
C16 C17 C18 C13 . -.5(9)
C31 P2 C19 C24 . -98.3(5)
C25 P2 C19 C24 . 7.7(5)
Ag1 P2 C19 C24 . 135.8(4)
C31 P2 C19 C20 . 82.4(4)
C25 P2 C19 C20 . -171.6(4)
Ag1 P2 C19 C20 . -43.5(4)
C24 C19 C20 C21 . -.5(8)
P2 C19 C20 C21 . 178.8(5)
C19 C20 C21 C22 . .8(9)
C20 C21 C22 C23 . -.5(9)
C21 C22 C23 C24 . -.1(9)
C22 C23 C24 C19 . .3(9)
C20 C19 C24 C23 . .0(8)
P2 C19 C24 C23 . -179.3(5)
C31 P2 C25 C30 . 7.2(6)
C19 P2 C25 C30 . -99.4(5)
Ag1 P2 C25 C30 . 130.5(5)
C31 P2 C25 C26 . -174.3(4)
C19 P2 C25 C26 . 79.0(5)
Ag1 P2 C25 C26 . -51.1(5)
C30 C25 C26 C27 . -.8(9)
P2 C25 C26 C27 . -179.3(5)
C25 C26 C27 C28 . .6(10)
C26 C27 C28 C29 . .3(11)
C27 C28 C29 C30 . -1.0(11)
C26 C25 C30 C29 . .1(9)
P2 C25 C30 C29 . 178.5(5)
C28 C29 C30 C25 . .8(11)
C19 P2 C31 C32 . .4(6)
C25 P2 C31 C32 . -105.4(5)
Ag1 P2 C31 C32 . 129.8(5)
C19 P2 C31 C36 . -177.4(4)
C25 P2 C31 C36 . 76.8(5)
Ag1 P2 C31 C36 . -48.0(5)
C36 C31 C32 C33 . -.3(9)
P2 C31 C32 C33 . -178.0(5)
C31 C32 C33 C34 . -.9(11)
C32 C33 C34 C35 . 1.0(11)
C33 C34 C35 C36 . .2(10)
C34 C35 C36 C31 . -1.4(9)
C32 C31 C36 C35 . 1.5(9)
P2 C31 C36 C35 . 179.3(4)
C37 B1 C37 C42 3 127.5(6)
C43 B1 C37 C42 3 -111.8(5)
C43 B1 C37 C42 . 6.6(8)
C37 B1 C37 C38 3 -49.7(4)
C43 B1 C37 C38 3 71.0(7)
C43 B1 C37 C38 . -170.6(5)
C42 C37 C38 C39 . 2.2(8)
B1 C37 C38 C39 . 179.7(5)
C37 C38 C39 C40 . -.7(9)
C38 C39 C40 C41 . -2.5(10)
C39 C40 C41 C42 . 4.0(10)
C38 C37 C42 C41 . -.7(9)
B1 C37 C42 C41 . -178.0(5)
C40 C41 C42 C37 . -2.5(10)
C37 B1 C43 C44 . -79.6(6)
C37 B1 C43 C44 3 162.1(5)
C43 B1 C43 C44 3 41.3(4)
C37 B1 C43 C48 . 100.5(5)
C37 B1 C43 C48 3 -17.7(7)
C43 B1 C43 C48 3 -138.5(6)
C48 C43 C44 C45 . 2.3(8)
B1 C43 C44 C45 . -177.6(5)
C43 C44 C45 C46 . -1.8(9)
C44 C45 C46 C47 . .3(9)
C45 C46 C47 C48 . .5(9)
C46 C47 C48 C43 . .0(9)
C44 C43 C48 C47 . -1.4(8)
B1 C43 C48 C47 . 178.5(5)
