#------------------------------------------------------------------------------
#$Date: 2016-02-20 00:18:51 +0200 (Sat, 20 Feb 2016) $
#$Revision: 176760 $
#$URL: svn://www.crystallography.net/cod/cif/2/01/39/2013950.cif $
#------------------------------------------------------------------------------
#
# This file is available in the Crystallography Open Database (COD),
# http://www.crystallography.net/. The original data for this entry
# were provided by IUCr Journals, http://journals.iucr.org/.
#
# The file may be used within the scientific community so long as
# proper attribution is given to the journal article from which the
# data were obtained.
#
data_2013950
loop_
_publ_author_name
'Ma, Cheng-Bing'
'Hu, Ming-Qiang'
'Zhang, Chun-Xia'
'Chen, Feng'
Chen,Chang-Neng
'Liu, Qiu-Tian'
_publ_section_title
catena-Poly[[aqua(2,2'-bipyridine-κ²N,N')manganese(II)]-μ-terephthalato-κ³O,O':O'']
_journal_issue                   6
_journal_name_full               'Acta Crystallographica Section C'
_journal_page_first              m288
_journal_page_last               m290
_journal_paper_doi               10.1107/S0108270104007565
_journal_volume                  60
_journal_year                    2004
_chemical_formula_iupac          '[Mn (C8 H4 O4) (C10 H8 N2) (H2O)]'
_chemical_formula_moiety         'C18 H14 Mn N2 O5'
_chemical_formula_sum            'C18 H14 Mn N2 O5'
_chemical_formula_weight         393.25
_chemical_name_systematic
;
catena-Poly[[aqua(2,2'-bipyridine-κ²N,N')manganese(II)]-μ-terephthalato-
κ³O,O':O'']
;
_space_group_IT_number           14
_symmetry_cell_setting           monoclinic
_symmetry_space_group_name_Hall  '-P 2yn'
_symmetry_space_group_name_H-M   'P 1 21/n 1'
_atom_sites_solution_hydrogens   geom
_atom_sites_solution_primary     direct
_atom_sites_solution_secondary   difmap
_audit_creation_method           SHELXL
_cell_angle_alpha                90.00
_cell_angle_beta                 111.726(2)
_cell_angle_gamma                90.00
_cell_formula_units_Z            4
_cell_length_a                   9.8637(2)
_cell_length_b                   16.3316(5)
_cell_length_c                   11.31100(10)
_cell_measurement_reflns_used    2431
_cell_measurement_temperature    293(2)
_cell_measurement_theta_max      25.04
_cell_measurement_theta_min      2.30
_cell_volume                     1692.66(7)
_computing_cell_refinement       'SAINT (Siemens,1994)'
_computing_data_collection       'SMART (Siemens,1996)'
_computing_data_reduction        'SHELXTL (Siemens,1994) and SAINT'
_computing_molecular_graphics    SHELXTL
_computing_publication_material  SHELXTL
_computing_structure_refinement  SHELXTL
_computing_structure_solution    SHELXTL
_diffrn_ambient_temperature      293(2)
_diffrn_measured_fraction_theta_full 0.990
_diffrn_measured_fraction_theta_max 0.990
_diffrn_measurement_device_type  'Siemens SMART CCD area-detector'
_diffrn_measurement_method       'φ and ω scans'
_diffrn_radiation_monochromator  graphite
_diffrn_radiation_source         'fine-focus sealed tube'
_diffrn_radiation_type           MoK\a
_diffrn_radiation_wavelength     0.71073
_diffrn_reflns_av_R_equivalents  0.0256
_diffrn_reflns_av_sigmaI/netI    0.0436
_diffrn_reflns_limit_h_max       11
_diffrn_reflns_limit_h_min       -9
_diffrn_reflns_limit_k_max       19
_diffrn_reflns_limit_k_min       -12
_diffrn_reflns_limit_l_max       9
_diffrn_reflns_limit_l_min       -13
_diffrn_reflns_number            5399
_diffrn_reflns_theta_full        25.04
_diffrn_reflns_theta_max         25.04
_diffrn_reflns_theta_min         2.30
_diffrn_standards_decay_%        0
_diffrn_standards_interval_time  0
_diffrn_standards_number         0
_exptl_absorpt_coefficient_mu    0.812
_exptl_absorpt_correction_T_max  .784
_exptl_absorpt_correction_T_min  .626
_exptl_absorpt_correction_type   multi-scan
_exptl_absorpt_process_details   'SADABS (Sheldrick, 1996)'
_exptl_crystal_colour            'pale yellow'
_exptl_crystal_density_diffrn    1.543
_exptl_crystal_density_method    'not measured'
_exptl_crystal_description       block
_exptl_crystal_F_000             804
_exptl_crystal_size_max          .54
_exptl_crystal_size_mid          .53
_exptl_crystal_size_min          .30
_refine_diff_density_max         0.400
_refine_diff_density_min         -0.304
_refine_ls_extinction_method     none
_refine_ls_goodness_of_fit_ref   1.025
_refine_ls_hydrogen_treatment    mixed
_refine_ls_matrix_type           full
_refine_ls_number_parameters     243
_refine_ls_number_reflns         2973
_refine_ls_number_restraints     2
_refine_ls_restrained_S_all      1.025
_refine_ls_R_factor_all          0.0720
_refine_ls_R_factor_gt           0.0455
_refine_ls_shift/su_max          0.000
_refine_ls_shift/su_mean         0.000
_refine_ls_structure_factor_coef Fsqd
_refine_ls_weighting_details
'calc w=1/[σ²(Fo²)+(0.1P)²] where P=(Fo²+2Fc²)/3'
_refine_ls_weighting_scheme      calc
_refine_ls_wR_factor_gt          0.1234
_refine_ls_wR_factor_ref         0.1498
_reflns_number_gt                2230
_reflns_number_total             2973
_reflns_threshold_expression     I>2σ(I)
_cod_data_source_file            fa1056.cif
_cod_data_source_block           I
_cod_depositor_comments
;
The following automatic conversions were performed:
'_symmetry_cell_setting' value 'Monoclinic' changed to 'monoclinic'
according to '/home/saulius/struct/CIF-dictionaries/cif_core.dic'
dictionary named 'cif_core.dic' version 2.4.1 from
2010-06-29.

'_geom_bond_publ_flag' value 'YES' changed to 'yes' according
to '/home/saulius/struct/CIF-dictionaries/cif_core.dic' dictionary named
'cif_core.dic' version 2.4.1 from 2010-06-29 (6 times).

Automatic conversion script
Id: cif_fix_enum 1527 2010-12-29 10:47:43Z saulius 

The following automatic conversions were performed:

'_symmetry_cell_setting' value 'Monoclinic' changed to 'monoclinic'
according to /home/saulius/struct/CIF-dictionaries/cif_core.dic
dictionary named 'cif_core.dic' version 2.4.1 from
2010-06-29.

'_geom_bond_publ_flag' value 'YES' changed to 'yes'
according to /home/saulius/struct/CIF-dictionaries/cif_core.dic
dictionary named 'cif_core.dic' version 2.4.1 from 2010-06-29 (6
times).

'_geom_angle_publ_flag' value 'YES' changed to 'yes'
according to /home/saulius/struct/CIF-dictionaries/cif_core.dic
dictionary named 'cif_core.dic' version 2.4.1 from 2010-06-29 (15
times).

Automatic conversion script
Id: cif_fix_values 1715 2011-07-08 13:25:40Z adriana 
;
_cod_original_cell_volume        1692.66(6)
_cod_original_sg_symbol_H-M      'P 21/n'
_cod_database_code               2013950
_cod_database_fobs_code          2013950
loop_
_symmetry_equiv_pos_as_xyz
'x, y, z'
'-x+1/2, y+1/2, -z+1/2'
'-x, -y, -z'
'x-1/2, -y-1/2, z-1/2'
loop_
_atom_site_label
_atom_site_fract_x
_atom_site_fract_y
_atom_site_fract_z
_atom_site_U_iso_or_equiv
_atom_site_adp_type
_atom_site_calc_flag
_atom_site_refinement_flags
_atom_site_occupancy
_atom_site_disorder_assembly
_atom_site_disorder_group
_atom_site_type_symbol
Mn 0.29665(5) 0.04021(3) 0.12849(5) 0.0325(2) Uani d . 1 . . Mn
O1 0.0809(2) 0.09837(15) 0.1140(2) 0.0420(6) Uani d . 1 . . O
O2 0.2808(2) 0.13618(15) 0.2681(2) 0.0390(6) Uani d . 1 . . O
O3 -0.1197(3) 0.38453(16) 0.5214(2) 0.0452(6) Uani d . 1 . . O
O4 -0.3006(3) 0.38864(19) 0.3321(3) 0.0605(8) Uani d . 1 . . O
O5 0.1858(3) -0.02654(17) -0.0456(3) 0.0434(6) Uani d D 1 . . O
H5B 0.105(3) -0.054(3) -0.067(5) 0.085(18) Uiso d D 1 . . H
H5C 0.172(5) 0.011(2) -0.101(4) 0.088(19) Uiso d D 1 . . H
N1 0.2832(3) -0.06673(18) 0.2505(3) 0.0395(7) Uani d . 1 . . N
N2 0.5235(3) 0.01268(19) 0.2626(3) 0.0391(7) Uani d . 1 . . N
C1 0.0596(3) 0.1985(2) 0.2614(3) 0.0304(7) Uani d . 1 . . C
C2 0.1288(4) 0.2408(2) 0.3730(3) 0.0453(10) Uani d . 1 . . C
H2A 0.2284 0.2338 0.4172 0.054 Uiso calc R 1 . . H
C3 0.0514(4) 0.2933(2) 0.4196(3) 0.0471(10) Uani d . 1 . . C
H3A 0.0993 0.3209 0.4956 0.057 Uiso calc R 1 . . H
C4 -0.0965(3) 0.3057(2) 0.3552(3) 0.0330(8) Uani d . 1 . . C
C5 -0.1640(4) 0.2656(2) 0.2410(3) 0.0395(9) Uani d . 1 . . C
H5A -0.2623 0.2752 0.1943 0.047 Uiso calc R 1 . . H
C6 -0.0877(4) 0.2115(2) 0.1951(3) 0.0386(8) Uani d . 1 . . C
H6A -0.1356 0.1836 0.1194 0.046 Uiso calc R 1 . . H
C7 0.1469(4) 0.1414(2) 0.2124(3) 0.0324(8) Uani d . 1 . . C
C8 -0.1799(4) 0.3642(2) 0.4064(3) 0.0359(8) Uani d . 1 . . C
C9 0.1606(4) -0.1075(3) 0.2371(4) 0.0530(10) Uani d . 1 . . C
H9A 0.0757 -0.0945 0.1688 0.064 Uiso calc R 1 . . H
C10 0.1548(5) -0.1676(3) 0.3197(5) 0.0604(12) Uani d . 1 . . C
H10A 0.0679 -0.1951 0.3069 0.072 Uiso calc R 1 . . H
C11 0.2787(5) -0.1866(3) 0.4209(4) 0.0628(12) Uani d . 1 . . C
H11A 0.2769 -0.2269 0.4783 0.075 Uiso calc R 1 . . H
C12 0.4063(5) -0.1456(2) 0.4373(4) 0.0507(10) Uani d . 1 . . C
H12A 0.4914 -0.1576 0.5060 0.061 Uiso calc R 1 . . H
C13 0.4058(4) -0.0861(2) 0.3494(3) 0.0378(8) Uani d . 1 . . C
C14 0.5393(4) -0.0403(2) 0.3574(3) 0.0377(8) Uani d . 1 . . C
C15 0.6717(4) -0.0510(2) 0.4556(4) 0.0473(10) Uani d . 1 . . C
H15A 0.6807 -0.0880 0.5206 0.057 Uiso calc R 1 . . H
C16 0.7904(5) -0.0066(3) 0.4568(4) 0.0601(12) Uani d . 1 . . C
H16A 0.8802 -0.0129 0.5230 0.072 Uiso calc R 1 . . H
C17 0.7753(5) 0.0475(3) 0.3589(4) 0.0597(12) Uani d . 1 . . C
H17A 0.8544 0.0779 0.3572 0.072 Uiso calc R 1 . . H
C18 0.6407(4) 0.0552(3) 0.2645(4) 0.0507(11) Uani d . 1 . . C
H18A 0.6298 0.0917 0.1985 0.061 Uiso calc R 1 . . H
loop_
_atom_type_symbol
_atom_type_description
_atom_type_scat_dispersion_real
_atom_type_scat_dispersion_imag
_atom_type_scat_source
C C 0.0033 0.0016 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
H H 0.0000 0.0000 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
N N 0.0061 0.0033 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
O O 0.0106 0.0060 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
Mn Mn 0.3368 0.7283 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
loop_
_geom_angle_atom_site_label_1
_geom_angle_atom_site_label_2
_geom_angle_atom_site_label_3
_geom_angle_site_symmetry_1
_geom_angle_site_symmetry_3
_geom_angle
_geom_angle_publ_flag
O3 Mn O5 4_665 . 86.79(10) yes
O3 Mn N2 4_665 . 90.04(10) yes
O5 Mn N2 . . 123.97(11) yes
O3 Mn N1 4_665 . 158.43(11) yes
O5 Mn N1 . . 92.42(11) yes
N2 Mn N1 . . 72.56(11) yes
O3 Mn O2 4_665 . 98.05(10) yes
O5 Mn O2 . . 147.16(10) yes
N2 Mn O2 . . 88.63(10) yes
N1 Mn O2 . . 94.26(10) yes
O3 Mn O1 4_665 . 105.72(9) yes
O5 Mn O1 . . 90.04(10) yes
N2 Mn O1 . . 143.66(10) yes
N1 Mn O1 . . 95.83(10) yes
O2 Mn O1 . . 57.31(8) yes
O3 Mn C7 4_665 . 103.58(10) ?
O5 Mn C7 . . 119.07(11) ?
N2 Mn C7 . . 116.00(11) ?
N1 Mn C7 . . 95.64(10) ?
O2 Mn C7 . . 28.22(9) ?
O1 Mn C7 . . 29.09(9) ?
C7 O1 Mn . . 90.30(19) ?
C7 O2 Mn . . 91.6(2) ?
C8 O3 Mn . 4_566 128.0(2) ?
Mn O5 H5B . . 128(3) ?
Mn O5 H5C . . 102(4) ?
H5B O5 H5C . . 106(5) ?
C9 N1 C13 . . 118.2(3) ?
C9 N1 Mn . . 124.7(3) ?
C13 N1 Mn . . 116.8(2) ?
C18 N2 C14 . . 118.5(3) ?
C18 N2 Mn . . 123.1(2) ?
C14 N2 Mn . . 117.6(2) ?
C2 C1 C6 . . 119.0(3) ?
C2 C1 C7 . . 119.4(3) ?
C6 C1 C7 . . 121.6(3) ?
C3 C2 C1 . . 120.4(3) ?
C3 C2 H2A . . 119.8 ?
C1 C2 H2A . . 119.8 ?
C2 C3 C4 . . 121.0(3) ?
C2 C3 H3A . . 119.5 ?
C4 C3 H3A . . 119.5 ?
C5 C4 C3 . . 118.3(3) ?
C5 C4 C8 . . 121.1(3) ?
C3 C4 C8 . . 120.6(3) ?
C4 C5 C6 . . 121.0(3) ?
C4 C5 H5A . . 119.5 ?
C6 C5 H5A . . 119.5 ?
C5 C6 C1 . . 120.3(3) ?
C5 C6 H6A . . 119.9 ?
C1 C6 H6A . . 119.9 ?
O2 C7 O1 . . 120.8(3) ?
O2 C7 C1 . . 120.2(3) ?
O1 C7 C1 . . 119.1(3) ?
O2 C7 Mn . . 60.14(17) ?
O1 C7 Mn . . 60.62(17) ?
C1 C7 Mn . . 179.0(2) ?
O4 C8 O3 . . 125.6(3) ?
O4 C8 C4 . . 117.8(3) ?
O3 C8 C4 . . 116.6(3) ?
N1 C9 C10 . . 122.9(4) ?
N1 C9 H9A . . 118.6 ?
C10 C9 H9A . . 118.6 ?
C11 C10 C9 . . 118.9(4) ?
C11 C10 H10A . . 120.5 ?
C9 C10 H10A . . 120.5 ?
C10 C11 C12 . . 119.5(4) ?
C10 C11 H11A . . 120.2 ?
C12 C11 H11A . . 120.2 ?
C11 C12 C13 . . 118.9(4) ?
C11 C12 H12A . . 120.5 ?
C13 C12 H12A . . 120.5 ?
N1 C13 C12 . . 121.5(3) ?
N1 C13 C14 . . 115.8(3) ?
C12 C13 C14 . . 122.7(3) ?
N2 C14 C15 . . 121.4(4) ?
N2 C14 C13 . . 115.9(3) ?
C15 C14 C13 . . 122.6(3) ?
C16 C15 C14 . . 119.4(4) ?
C16 C15 H15A . . 120.3 ?
C14 C15 H15A . . 120.3 ?
C15 C16 C17 . . 119.5(4) ?
C15 C16 H16A . . 120.3 ?
C17 C16 H16A . . 120.3 ?
C18 C17 C16 . . 118.0(4) ?
C18 C17 H17A . . 121.0 ?
C16 C17 H17A . . 121.0 ?
N2 C18 C17 . . 123.2(4) ?
N2 C18 H18A . . 118.4 ?
C17 C18 H18A . . 118.4 ?
loop_
_geom_bond_atom_site_label_1
_geom_bond_atom_site_label_2
_geom_bond_site_symmetry_2
_geom_bond_distance
_geom_bond_publ_flag
Mn O3 4_665 2.098(2) yes
Mn O5 . 2.160(3) yes
Mn N2 . 2.235(3) yes
Mn N1 . 2.260(3) yes
Mn O2 . 2.271(2) yes
Mn O1 . 2.281(2) yes
Mn C7 . 2.617(3) ?
O1 C7 . 1.272(4) ?
O2 C7 . 1.238(4) ?
O3 C8 . 1.259(4) ?
O3 Mn 4_566 2.098(2) ?
O4 C8 . 1.241(4) ?
O5 H5B . 0.861(19) ?
O5 H5C . 0.847(19) ?
N1 C9 . 1.340(5) ?
N1 C13 . 1.346(5) ?
N2 C18 . 1.341(5) ?
N2 C14 . 1.341(4) ?
C1 C2 . 1.378(5) ?
C1 C6 . 1.382(4) ?
C1 C7 . 1.508(4) ?
C2 C3 . 1.376(5) ?
C2 H2A . 0.9300 ?
C3 C4 . 1.383(5) ?
C3 H3A . 0.9300 ?
C4 C5 . 1.379(5) ?
C4 C8 . 1.509(4) ?
C5 C6 . 1.380(5) ?
C5 H5A . 0.9300 ?
C6 H6A . 0.9300 ?
C9 C10 . 1.371(6) ?
C9 H9A . 0.9300 ?
C10 C11 . 1.365(6) ?
C10 H10A . 0.9300 ?
C11 C12 . 1.375(6) ?
C11 H11A . 0.9300 ?
C12 C13 . 1.389(5) ?
C12 H12A . 0.9300 ?
C13 C14 . 1.487(5) ?
C14 C15 . 1.377(5) ?
C15 C16 . 1.373(6) ?
C15 H15A . 0.9300 ?
C16 C17 . 1.381(6) ?
C16 H16A . 0.9300 ?
C17 C18 . 1.367(6) ?
C17 H17A . 0.9300 ?
C18 H18A . 0.9300 ?
loop_
_geom_hbond_atom_site_label_D
_geom_hbond_atom_site_label_H
_geom_hbond_atom_site_label_A
_geom_hbond_site_symmetry_A
_geom_hbond_distance_DH
_geom_hbond_distance_HA
_geom_hbond_distance_DA
_geom_hbond_angle_DHA
_geom_hbond_publ_flag
O5 H5B O1 3 0.86(2) 1.86(2) 2.718(4) 172(5) yes
O5 H5C O4 4_665 0.85(2) 1.87(3) 2.672(4) 157(5) yes
loop_
_geom_torsion_atom_site_label_1
_geom_torsion_atom_site_label_2
_geom_torsion_atom_site_label_3
_geom_torsion_atom_site_label_4
_geom_torsion_site_symmetry_1
_geom_torsion
O3 Mn O1 C7 4_665 -89.8(2)
O5 Mn O1 C7 . -176.4(2)
N2 Mn O1 C7 . 22.8(3)
N1 Mn O1 C7 . 91.1(2)
O2 Mn O1 C7 . -0.21(18)
O3 Mn O2 C7 4_665 103.8(2)
O5 Mn O2 C7 . 7.2(3)
N2 Mn O2 C7 . -166.4(2)
N1 Mn O2 C7 . -94.0(2)
O1 Mn O2 C7 . 0.21(18)
O3 Mn N1 C9 4_665 -139.0(3)
O5 Mn N1 C9 . -51.7(3)
N2 Mn N1 C9 . -176.6(3)
O2 Mn N1 C9 . 96.2(3)
O1 Mn N1 C9 . 38.6(3)
C7 Mn N1 C9 . 67.9(3)
O3 Mn N1 C13 4_665 46.3(4)
O5 Mn N1 C13 . 133.7(3)
N2 Mn N1 C13 . 8.8(2)
O2 Mn N1 C13 . -78.5(2)
O1 Mn N1 C13 . -136.0(2)
C7 Mn N1 C13 . -106.8(2)
O3 Mn N2 C18 4_665 13.2(3)
O5 Mn N2 C18 . 99.4(3)
N1 Mn N2 C18 . -179.7(3)
O2 Mn N2 C18 . -84.8(3)
O1 Mn N2 C18 . -104.1(3)
C7 Mn N2 C18 . -92.0(3)
O3 Mn N2 C14 4_665 -177.3(3)
O5 Mn N2 C14 . -91.1(3)
N1 Mn N2 C14 . -10.2(3)
O2 Mn N2 C14 . 84.7(3)
O1 Mn N2 C14 . 65.5(3)
C7 Mn N2 C14 . 77.6(3)
C6 C1 C2 C3 . 1.8(6)
C7 C1 C2 C3 . 179.9(3)
C1 C2 C3 C4 . -0.8(6)
C2 C3 C4 C5 . -1.7(6)
C2 C3 C4 C8 . -179.3(3)
C3 C4 C5 C6 . 3.1(6)
C8 C4 C5 C6 . -179.3(3)
C4 C5 C6 C1 . -2.1(6)
C2 C1 C6 C5 . -0.4(5)
C7 C1 C6 C5 . -178.5(3)
Mn O2 C7 O1 . -0.4(3)
Mn O2 C7 C1 . 179.0(3)
Mn O1 C7 O2 . 0.4(3)
Mn O1 C7 C1 . -179.0(3)
C2 C1 C7 O2 . -4.1(5)
C6 C1 C7 O2 . 173.9(3)
C2 C1 C7 O1 . 175.3(3)
C6 C1 C7 O1 . -6.7(5)
O3 Mn C7 O2 4_665 -81.6(2)
O5 Mn C7 O2 . -175.55(18)
N2 Mn C7 O2 . 15.2(2)
N1 Mn C7 O2 . 88.5(2)
O1 Mn C7 O2 . -179.6(3)
O3 Mn C7 O1 4_665 97.99(19)
O5 Mn C7 O1 . 4.1(2)
N2 Mn C7 O1 . -165.20(19)
N1 Mn C7 O1 . -91.9(2)
O2 Mn C7 O1 . 179.6(3)
Mn O3 C8 O4 4_566 3.5(5)
Mn O3 C8 C4 4_566 -177.2(2)
C5 C4 C8 O4 . -15.1(5)
C3 C4 C8 O4 . 162.5(4)
C5 C4 C8 O3 . 165.5(3)
C3 C4 C8 O3 . -16.9(5)
C13 N1 C9 C10 . 0.2(6)
Mn N1 C9 C10 . -174.4(3)
N1 C9 C10 C11 . 0.6(7)
C9 C10 C11 C12 . -0.5(7)
C10 C11 C12 C13 . -0.4(6)
C9 N1 C13 C12 . -1.1(5)
Mn N1 C13 C12 . 173.9(3)
C9 N1 C13 C14 . 178.4(3)
Mn N1 C13 C14 . -6.6(4)
C11 C12 C13 N1 . 1.2(6)
C11 C12 C13 C14 . -178.3(3)
C18 N2 C14 C15 . 0.5(5)
Mn N2 C14 C15 . -169.5(3)
C18 N2 C14 C13 . -179.6(3)
Mn N2 C14 C13 . 10.4(4)
N1 C13 C14 N2 . -2.4(5)
C12 C13 C14 N2 . 177.1(3)
N1 C13 C14 C15 . 177.5(3)
C12 C13 C14 C15 . -3.0(6)
N2 C14 C15 C16 . 0.0(6)
C13 C14 C15 C16 . -180.0(4)
C14 C15 C16 C17 . -0.6(7)
C15 C16 C17 C18 . 0.7(7)
C14 N2 C18 C17 . -0.4(6)
Mn N2 C18 C17 . 169.0(3)
C16 C17 C18 N2 . -0.2(7)
