#------------------------------------------------------------------------------
#$Date: 2016-02-20 00:18:51 +0200 (Sat, 20 Feb 2016) $
#$Revision: 176760 $
#$URL: svn://www.crystallography.net/cod/cif/2/01/40/2014040.cif $
#------------------------------------------------------------------------------
#
# This file is available in the Crystallography Open Database (COD),
# http://www.crystallography.net/. The original data for this entry
# were provided by IUCr Journals, http://journals.iucr.org/.
#
# The file may be used within the scientific community so long as
# proper attribution is given to the journal article from which the
# data were obtained.
#
data_2014040
loop_
_publ_author_name
'Zheng, Yan'
'Wang, Shu-Li'
_publ_section_title
;catena-Poly[[silver(I)-μ₃-2,2'-[o-phenylenebis(methylenethio)]dianiline-κ⁴N:S,S':N']
 nitrate chloroform solvate]
;
_journal_issue                   6
_journal_name_full               'Acta Crystallographica Section C'
_journal_page_first              m278
_journal_page_last               m279
_journal_paper_doi               10.1107/S0108270104009473
_journal_volume                  60
_journal_year                    2004
_chemical_formula_iupac          '[Ag (C20 H20 N2 S2)] (N O3) , C H Cl3'
_chemical_formula_moiety         'C20 H20 Ag N2 S2 + , N O3 - , C H Cl3'
_chemical_formula_sum            'C21 H21 Ag Cl3 N3 O3 S2'
_chemical_formula_weight         641.75
_chemical_name_systematic
;
catena-Poly[[silver(I)-μ₃-2,2'-[o-phenylenebis(methylenethio)]dianiline-
κ⁴N:S,S':N'] nitrate chloroform solvate]
;
_space_group_IT_number           2
_symmetry_cell_setting           triclinic
_symmetry_space_group_name_Hall  '-P 1'
_symmetry_space_group_name_H-M   'P -1'
_cell_angle_alpha                102.385(11)
_cell_angle_beta                 98.580(12)
_cell_angle_gamma                101.351(11)
_cell_formula_units_Z            2
_cell_length_a                   9.441(6)
_cell_length_b                   9.805(6)
_cell_length_c                   13.936(9)
_cell_measurement_reflns_used    865
_cell_measurement_temperature    293(2)
_cell_measurement_theta_max      24.56
_cell_measurement_theta_min      2.28
_cell_volume                     1210.4(13)
_computing_cell_refinement       SMART
_computing_data_collection       'SMART (Bruker, 1998)'
_computing_data_reduction        'SAINT (Bruker, 1998)'
_computing_molecular_graphics    'SHELXTL (Bruker, 1998)'
_computing_publication_material  SHELXTL
_computing_structure_refinement  'SHELXL97 (Sheldrick, 1997)'
_computing_structure_solution    'SHELXS97 (Sheldrick, 1997)'
_diffrn_ambient_temperature      293(2)
_diffrn_measured_fraction_theta_full 0.995
_diffrn_measured_fraction_theta_max 0.995
_diffrn_measurement_device_type  'Bruker SMART CCD area-detector'
_diffrn_measurement_method       'φ and ω'
_diffrn_radiation_monochromator  graphite
_diffrn_radiation_source         'fine-focus sealed tube'
_diffrn_radiation_type           MoK\a
_diffrn_radiation_wavelength     0.71073
_diffrn_reflns_av_R_equivalents  0.0327
_diffrn_reflns_av_sigmaI/netI    0.0997
_diffrn_reflns_limit_h_max       11
_diffrn_reflns_limit_h_min       -7
_diffrn_reflns_limit_k_max       11
_diffrn_reflns_limit_k_min       -11
_diffrn_reflns_limit_l_max       14
_diffrn_reflns_limit_l_min       -16
_diffrn_reflns_number            5074
_diffrn_reflns_theta_full        25.03
_diffrn_reflns_theta_max         25.03
_diffrn_reflns_theta_min         1.53
_exptl_absorpt_coefficient_mu    1.366
_exptl_absorpt_correction_T_max  0.772
_exptl_absorpt_correction_T_min  0.685
_exptl_absorpt_correction_type   empirical
_exptl_absorpt_process_details
'via multi-scan [SADABS (Sheldrick, 1996; Blessing, 1995)]'
_exptl_crystal_colour            colourless
_exptl_crystal_density_diffrn    1.761
_exptl_crystal_density_meas      ?
_exptl_crystal_density_method    'not measured'
_exptl_crystal_description       block
_exptl_crystal_F_000             644
_exptl_crystal_size_max          0.30
_exptl_crystal_size_mid          0.25
_exptl_crystal_size_min          0.20
_refine_diff_density_max         1.199
_refine_diff_density_min         -0.650
_refine_ls_goodness_of_fit_ref   0.956
_refine_ls_hydrogen_treatment    constr
_refine_ls_matrix_type           full
_refine_ls_number_parameters     298
_refine_ls_number_reflns         4269
_refine_ls_number_restraints     0
_refine_ls_restrained_S_all      0.956
_refine_ls_R_factor_all          0.1042
_refine_ls_R_factor_gt           0.0528
_refine_ls_shift/su_max          0.001
_refine_ls_shift/su_mean         0.000
_refine_ls_structure_factor_coef Fsqd
_refine_ls_weighting_details
'calc w = 1/[σ²(Fo²)+(0.0802P)²] where P=(Fo²+2Fc²)/3'
_refine_ls_weighting_scheme      calc
_refine_ls_wR_factor_ref         0.1522
_reflns_number_gt                2561
_reflns_number_total             4269
_reflns_threshold_expression     I>2σ(I)
_cod_data_source_file            na1660.cif
_cod_data_source_block           I
_cod_depositor_comments
;
The following automatic conversions were performed:
'_symmetry_cell_setting' value 'Triclinic' changed to 'triclinic'
according to '/home/saulius/struct/CIF-dictionaries/cif_core.dic'
dictionary named 'cif_core.dic' version 2.4.1 from 2010-06-29.

Automatic conversion script
Id: cif_fix_enum 1527 2010-12-29 10:47:43Z saulius 

The following automatic conversions were performed:

'_symmetry_cell_setting' value 'Triclinic' changed to 'triclinic'
according to /home/saulius/struct/CIF-dictionaries/cif_core.dic
dictionary named 'cif_core.dic' version 2.4.1 from 2010-06-29.

Automatic conversion script
Id: cif_fix_values 1715 2011-07-08 13:25:40Z adriana 

The following automatic conversions were performed:

'_exptl_crystal_density_meas' value 'not measured' was changed to '?'
- the value is perceived as not measured.

Automatic conversion script
Id: cif_fix_values 3008 2015-01-20 13:52:24Z robertas 
;
_cod_original_sg_symbol_H-M      P-1
_cod_database_code               2014040
_cod_database_fobs_code          2014040
loop_
_symmetry_equiv_pos_as_xyz
'x, y, z'
'-x, -y, -z'
loop_
_atom_site_label
_atom_site_fract_x
_atom_site_fract_y
_atom_site_fract_z
_atom_site_U_iso_or_equiv
_atom_site_adp_type
_atom_site_calc_flag
_atom_site_refinement_flags
_atom_site_occupancy
_atom_site_disorder_assembly
_atom_site_disorder_group
_atom_site_type_symbol
Ag1 0.50351(6) 0.74897(6) 0.98894(4) 0.0400(2) Uani d . 1 . . Ag
S1 0.6038(2) 0.53961(19) 0.90899(14) 0.0325(5) Uani d . 1 . . S
S2 0.66958(18) 0.97716(19) 0.97168(13) 0.0306(4) Uani d . 1 . . S
N1 0.5194(7) 0.2206(6) 0.8363(4) 0.0386(15) Uani d . 1 . . N
H1C 0.6155 0.2501 0.8351 0.046 Uiso calc R 1 . . H
H1D 0.4917 0.1260 0.8063 0.046 Uiso calc R 1 . . H
N2 0.7575(6) 1.2978(6) 1.0613(5) 0.0348(15) Uani d . 1 . . N
H2A 0.7963 1.2829 1.0059 0.042 Uiso calc R 1 . . H
H2B 0.7916 1.3912 1.0937 0.042 Uiso calc R 1 . . H
C1 0.7513(7) 0.5961(8) 0.8443(6) 0.0353(18) Uani d . 1 . . C
H1A 0.8386 0.6504 0.8940 0.042 Uiso calc R 1 . . H
H1B 0.7751 0.5112 0.8066 0.042 Uiso calc R 1 . . H
C2 0.7141(7) 0.6850(7) 0.7750(6) 0.0333(18) Uani d . 1 . . C
C3 0.6581(8) 0.6177(9) 0.6744(6) 0.042(2) Uani d . 1 . . C
H3A 0.6469 0.5190 0.6525 0.051 Uiso calc R 1 . . H
C4 0.6194(10) 0.6917(9) 0.6078(6) 0.059(3) Uani d . 1 . . C
H4A 0.5780 0.6434 0.5414 0.071 Uiso calc R 1 . . H
C5 0.6407(10) 0.8371(9) 0.6375(7) 0.057(2) Uani d . 1 . . C
H5A 0.6147 0.8885 0.5915 0.068 Uiso calc R 1 . . H
C6 0.7005(8) 0.9068(8) 0.7353(6) 0.043(2) Uani d . 1 . . C
H6A 0.7138 1.0060 0.7556 0.051 Uiso calc R 1 . . H
C7 0.7410(7) 0.8342(7) 0.8036(5) 0.0295(17) Uani d . 1 . . C
C8 0.8091(7) 0.9186(7) 0.9087(5) 0.0330(17) Uani d . 1 . . C
H8A 0.8840 1.0015 0.9080 0.040 Uiso calc R 1 . . H
H8B 0.8560 0.8595 0.9446 0.040 Uiso calc R 1 . . H
C9 0.4635(8) 0.4397(8) 0.8059(5) 0.0336(17) Uani d . 1 . . C
C10 0.3802(8) 0.5079(9) 0.7502(6) 0.042(2) Uani d . 1 . . C
H10A 0.3944 0.6073 0.7696 0.050 Uiso calc R 1 . . H
C11 0.2772(9) 0.4300(10) 0.6669(6) 0.051(2) Uani d . 1 . . C
H11A 0.2204 0.4756 0.6299 0.061 Uiso calc R 1 . . H
C12 0.2587(9) 0.2847(11) 0.6388(6) 0.055(2) Uani d . 1 . . C
H12A 0.1911 0.2319 0.5808 0.067 Uiso calc R 1 . . H
C13 0.3370(8) 0.2152(9) 0.6936(6) 0.044(2) Uani d . 1 . . C
H13A 0.3207 0.1156 0.6738 0.053 Uiso calc R 1 . . H
C14 0.4400(7) 0.2914(7) 0.7782(5) 0.0304(17) Uani d . 1 . . C
C15 0.7762(7) 1.0669(7) 1.0934(5) 0.0293(16) Uani d . 1 . . C
C16 0.8256(8) 0.9879(8) 1.1560(6) 0.0388(19) Uani d . 1 . . C
H16A 0.8031 0.8881 1.1347 0.047 Uiso calc R 1 . . H
C17 0.9074(9) 1.0555(10) 1.2492(6) 0.049(2) Uani d . 1 . . C
H17A 0.9417 1.0021 1.2913 0.059 Uiso calc R 1 . . H
C18 0.9390(9) 1.2018(10) 1.2805(6) 0.052(2) Uani d . 1 . . C
H18A 0.9940 1.2479 1.3445 0.063 Uiso calc R 1 . . H
C19 0.8902(8) 1.2811(8) 1.2185(6) 0.0396(19) Uani d . 1 . . C
H19A 0.9121 1.3807 1.2411 0.048 Uiso calc R 1 . . H
C20 0.8092(7) 1.2156(7) 1.1231(5) 0.0312(17) Uani d . 1 . . C
C21 0.8248(9) 0.2444(8) 0.5954(6) 0.045(2) Uani d . 1 . . C
H21A 0.8803 0.2676 0.6644 0.054 Uiso calc R 1 . . H
Cl1 0.6404(3) 0.2104(3) 0.5995(2) 0.0704(7) Uani d . 1 . . Cl
Cl2 0.8785(3) 0.3900(3) 0.5468(2) 0.0810(8) Uani d . 1 . . Cl
Cl3 0.8698(3) 0.0933(3) 0.5284(2) 0.0779(8) Uani d . 1 . . Cl
N3 0.0262(8) 0.6789(8) 0.1288(6) 0.0490(18) Uani d . 1 . . N
O1 -0.0375(10) 0.6207(10) 0.1811(7) 0.124(4) Uani d . 1 . . O
O2 -0.0298(12) 0.6992(13) 0.0539(7) 0.155(5) Uani d . 1 . . O
O3 0.1554(7) 0.7287(7) 0.1542(6) 0.083(2) Uani d . 1 . . O
loop_
_atom_type_symbol
_atom_type_description
_atom_type_scat_dispersion_real
_atom_type_scat_dispersion_imag
_atom_type_scat_source
C C 0.0033 0.0016 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
H H 0.0000 0.0000 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
N N 0.0061 0.0033 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
O O 0.0106 0.0060 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
S S 0.1246 0.1234 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
Ag Ag -0.8971 1.1015 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
Cl Cl 0.1484 0.1585 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
loop_
_geom_angle_atom_site_label_1
_geom_angle_atom_site_label_2
_geom_angle_atom_site_label_3
_geom_angle_site_symmetry_1
_geom_angle_site_symmetry_3
_geom_angle
N2 Ag1 N1 2_677 2_667 90.3(2)
N2 Ag1 S1 2_677 . 111.83(14)
N1 Ag1 S1 2_667 . 118.04(15)
N2 Ag1 S2 2_677 . 120.79(15)
N1 Ag1 S2 2_667 . 108.66(15)
S1 Ag1 S2 . . 107.09(8)
C9 S1 C1 . . 100.3(3)
C9 S1 Ag1 . . 104.5(2)
C1 S1 Ag1 . . 112.0(2)
C15 S2 C8 . . 100.9(3)
C15 S2 Ag1 . . 106.6(2)
C8 S2 Ag1 . . 105.6(2)
C14 N1 Ag1 . 2_667 117.9(4)
C14 N1 H1C . . 107.8
Ag1 N1 H1C 2_667 . 107.8
C14 N1 H1D . . 107.8
Ag1 N1 H1D 2_667 . 107.8
H1C N1 H1D . . 107.2
C20 N2 Ag1 . 2_677 115.8(4)
C20 N2 H2A . . 108.3
Ag1 N2 H2A 2_677 . 108.3
C20 N2 H2B . . 108.3
Ag1 N2 H2B 2_677 . 108.3
H2A N2 H2B . . 107.4
C2 C1 S1 . . 114.0(5)
C2 C1 H1A . . 108.8
S1 C1 H1A . . 108.8
C2 C1 H1B . . 108.8
S1 C1 H1B . . 108.8
H1A C1 H1B . . 107.7
C3 C2 C7 . . 117.6(7)
C3 C2 C1 . . 118.6(7)
C7 C2 C1 . . 123.7(7)
C4 C3 C2 . . 121.7(8)
C4 C3 H3A . . 119.2
C2 C3 H3A . . 119.2
C3 C4 C5 . . 120.1(8)
C3 C4 H4A . . 119.9
C5 C4 H4A . . 119.9
C4 C5 C6 . . 119.5(8)
C4 C5 H5A . . 120.3
C6 C5 H5A . . 120.3
C7 C6 C5 . . 121.4(7)
C7 C6 H6A . . 119.3
C5 C6 H6A . . 119.3
C6 C7 C2 . . 119.6(7)
C6 C7 C8 . . 118.2(6)
C2 C7 C8 . . 122.2(7)
C7 C8 S2 . . 110.0(5)
C7 C8 H8A . . 109.7
S2 C8 H8A . . 109.7
C7 C8 H8B . . 109.7
S2 C8 H8B . . 109.7
H8A C8 H8B . . 108.2
C10 C9 C14 . . 119.8(7)
C10 C9 S1 . . 120.7(6)
C14 C9 S1 . . 119.5(6)
C11 C10 C9 . . 120.3(8)
C11 C10 H10A . . 119.8
C9 C10 H10A . . 119.8
C12 C11 C10 . . 119.2(8)
C12 C11 H11A . . 120.4
C10 C11 H11A . . 120.4
C13 C12 C11 . . 121.4(8)
C13 C12 H12A . . 119.3
C11 C12 H12A . . 119.3
C12 C13 C14 . . 120.3(8)
C12 C13 H13A . . 119.9
C14 C13 H13A . . 119.9
C13 C14 C9 . . 119.0(7)
C13 C14 N1 . . 120.8(7)
C9 C14 N1 . . 120.3(6)
C16 C15 C20 . . 121.1(7)
C16 C15 S2 . . 119.6(5)
C20 C15 S2 . . 119.4(6)
C17 C16 C15 . . 120.1(7)
C17 C16 H16A . . 120.0
C15 C16 H16A . . 120.0
C16 C17 C18 . . 119.8(8)
C16 C17 H17A . . 120.1
C18 C17 H17A . . 120.1
C17 C18 C19 . . 120.5(8)
C17 C18 H18A . . 119.8
C19 C18 H18A . . 119.8
C18 C19 C20 . . 121.0(8)
C18 C19 H19A . . 119.5
C20 C19 H19A . . 119.5
C19 C20 C15 . . 117.6(7)
C19 C20 N2 . . 120.4(7)
C15 C20 N2 . . 121.9(6)
Cl1 C21 Cl2 . . 112.2(5)
Cl1 C21 Cl3 . . 111.1(5)
Cl2 C21 Cl3 . . 110.5(4)
Cl1 C21 H21A . . 107.6
Cl2 C21 H21A . . 107.6
Cl3 C21 H21A . . 107.6
O2 N3 O1 . . 124.7(11)
O2 N3 O3 . . 115.6(10)
O1 N3 O3 . . 119.6(9)
loop_
_geom_bond_atom_site_label_1
_geom_bond_atom_site_label_2
_geom_bond_site_symmetry_2
_geom_bond_distance
_geom_bond_publ_flag
Ag1 N2 2_677 2.383(6) ?
Ag1 N1 2_667 2.436(6) ?
Ag1 S1 . 2.540(2) ?
Ag1 S2 . 2.546(2) ?
S1 C9 . 1.759(7) ?
S1 C1 . 1.829(7) ?
S2 C15 . 1.779(7) ?
S2 C8 . 1.806(7) ?
N1 C14 . 1.402(9) ?
N1 Ag1 2_667 2.436(6) ?
N1 H1C . 0.9000 ?
N1 H1D . 0.9000 ?
N2 C20 . 1.398(9) ?
N2 Ag1 2_677 2.383(6) ?
N2 H2A . 0.9000 ?
N2 H2B . 0.9000 ?
C1 C2 . 1.482(10) ?
C1 H1A . 0.9700 ?
C1 H1B . 0.9700 ?
C2 C3 . 1.387(10) ?
C2 C7 . 1.391(10) ?
C3 C4 . 1.347(11) ?
C3 H3A . 0.9300 ?
C4 C5 . 1.361(12) ?
C4 H4A . 0.9300 ?
C5 C6 . 1.364(11) ?
C5 H5A . 0.9300 ?
C6 C7 . 1.360(10) ?
C6 H6A . 0.9300 ?
C7 C8 . 1.495(9) ?
C8 H8A . 0.9700 ?
C8 H8B . 0.9700 ?
C9 C10 . 1.384(10) ?
C9 C14 . 1.386(10) ?
C10 C11 . 1.367(11) ?
C10 H10A . 0.9300 ?
C11 C12 . 1.363(12) ?
C11 H11A . 0.9300 ?
C12 C13 . 1.359(12) ?
C12 H12A . 0.9300 ?
C13 C14 . 1.374(10) ?
C13 H13A . 0.9300 ?
C15 C16 . 1.375(10) ?
C15 C20 . 1.385(9) ?
C16 C17 . 1.361(11) ?
C16 H16A . 0.9300 ?
C17 C18 . 1.364(12) ?
C17 H17A . 0.9300 ?
C18 C19 . 1.369(11) ?
C18 H18A . 0.9300 ?
C19 C20 . 1.379(10) ?
C19 H19A . 0.9300 ?
C21 Cl1 . 1.718(8) ?
C21 Cl2 . 1.728(9) ?
C21 Cl3 . 1.738(8) ?
C21 H21A . 0.9800 ?
N3 O2 . 1.172(10) ?
N3 O1 . 1.180(9) ?
N3 O3 . 1.189(8) ?
loop_
_geom_hbond_atom_site_label_D
_geom_hbond_atom_site_label_H
_geom_hbond_atom_site_label_A
_geom_hbond_site_symmetry_A
_geom_hbond_distance_DH
_geom_hbond_distance_HA
_geom_hbond_distance_DA
_geom_hbond_angle_DHA
_geom_hbond_publ_flag
N1 H1C S1 . 0.90 2.83 2.977(6) 90 y
N2 H2A S2 . 0.90 2.91 3.018(6) 88 y
N1 H1C O3 2_666 0.90 2.11 2.990(9) 165 y
C21 H21A O1 2_666 0.98 2.33 3.287(13) 165 y
C21 H21A O3 2_666 0.98 2.59 3.416(12) 142 y
N2 H2A O3 2_676 0.90 2.33 3.203(10) 164 y
N2 H2A O2 2_676 0.90 2.46 3.227(12) 144 y
N2 H2B O1 1_666 0.90 2.44 3.303(10) 161 y
C1 H1A O2 1_656 0.97 2.29 3.152(12) 148 y
loop_
_geom_torsion_atom_site_label_1
_geom_torsion_atom_site_label_2
_geom_torsion_atom_site_label_3
_geom_torsion_atom_site_label_4
_geom_torsion_site_symmetry_1
_geom_torsion
N2 Ag1 S1 C9 2_677 19.0(3)
N1 Ag1 S1 C9 2_667 121.7(3)
S2 Ag1 S1 C9 . -115.4(3)
N2 Ag1 S1 C1 2_677 126.7(3)
N1 Ag1 S1 C1 2_667 -130.6(3)
S2 Ag1 S1 C1 . -7.7(3)
N2 Ag1 S2 C15 2_677 123.1(3)
N1 Ag1 S2 C15 2_667 21.2(3)
S1 Ag1 S2 C15 . -107.4(2)
N2 Ag1 S2 C8 2_677 -130.1(3)
N1 Ag1 S2 C8 2_667 127.9(3)
S1 Ag1 S2 C8 . -0.6(2)
C9 S1 C1 C2 . 60.7(6)
Ag1 S1 C1 C2 . -49.7(6)
S1 C1 C2 C3 . -94.6(7)
S1 C1 C2 C7 . 89.6(7)
C7 C2 C3 C4 . -5.3(11)
C1 C2 C3 C4 . 178.7(7)
C2 C3 C4 C5 . 2.8(13)
C3 C4 C5 C6 . -0.5(14)
C4 C5 C6 C7 . 0.8(13)
C5 C6 C7 C2 . -3.4(11)
C5 C6 C7 C8 . 178.5(7)
C3 C2 C7 C6 . 5.5(10)
C1 C2 C7 C6 . -178.7(7)
C3 C2 C7 C8 . -176.5(6)
C1 C2 C7 C8 . -0.7(10)
C6 C7 C8 S2 . 74.4(7)
C2 C7 C8 S2 . -103.6(7)
C15 S2 C8 C7 . 178.0(5)
Ag1 S2 C8 C7 . 67.1(5)
C1 S1 C9 C10 . -79.6(6)
Ag1 S1 C9 C10 . 36.5(6)
C1 S1 C9 C14 . 98.1(6)
Ag1 S1 C9 C14 . -145.8(5)
C14 C9 C10 C11 . -1.4(11)
S1 C9 C10 C11 . 176.3(6)
C9 C10 C11 C12 . -0.7(12)
C10 C11 C12 C13 . 2.2(13)
C11 C12 C13 C14 . -1.6(13)
C12 C13 C14 C9 . -0.6(11)
C12 C13 C14 N1 . 178.8(7)
C10 C9 C14 C13 . 2.0(11)
S1 C9 C14 C13 . -175.7(5)
C10 C9 C14 N1 . -177.4(6)
S1 C9 C14 N1 . 5.0(9)
Ag1 N1 C14 C13 2_667 -120.1(6)
Ag1 N1 C14 C9 2_667 59.3(8)
C8 S2 C15 C16 . -72.7(6)
Ag1 S2 C15 C16 . 37.3(6)
C8 S2 C15 C20 . 106.7(6)
Ag1 S2 C15 C20 . -143.2(5)
C20 C15 C16 C17 . 0.5(11)
S2 C15 C16 C17 . 179.9(6)
C15 C16 C17 C18 . 0.6(12)
C16 C17 C18 C19 . -0.7(12)
C17 C18 C19 C20 . -0.4(12)
C18 C19 C20 C15 . 1.4(11)
C18 C19 C20 N2 . 178.7(7)
C16 C15 C20 C19 . -1.5(10)
S2 C15 C20 C19 . 179.1(5)
C16 C15 C20 N2 . -178.7(6)
S2 C15 C20 N2 . 1.9(9)
Ag1 N2 C20 C19 2_677 -118.3(6)
Ag1 N2 C20 C15 2_677 58.8(8)
