#------------------------------------------------------------------------------
#$Date: 2016-02-20 00:18:51 +0200 (Sat, 20 Feb 2016) $
#$Revision: 176760 $
#$URL: svn://www.crystallography.net/cod/cif/2/01/46/2014687.cif $
#------------------------------------------------------------------------------
#
# This file is available in the Crystallography Open Database (COD),
# http://www.crystallography.net/. The original data for this entry
# were provided by IUCr Journals, http://journals.iucr.org/.
#
# The file may be used within the scientific community so long as
# proper attribution is given to the journal article from which the
# data were obtained.
#
data_2014687
loop_
_publ_author_name
'Li, Xia'
'Zhang, Zhuo-Yong'
'Wang, Dao-Yong'
'Song, Hai-Bin'
'Zou, Ying-Quan'
_publ_section_title
;
 Dimeric
 hexakis(4-methylbenzoato)bis(1,10-phenanthroline)didysprosium(III)
;
_journal_issue                   2
_journal_name_full               'Acta Crystallographica Section C'
_journal_page_first              m81
_journal_page_last               m83
_journal_paper_doi               10.1107/S0108270104032585
_journal_volume                  61
_journal_year                    2005
_chemical_formula_iupac          '[Dy2 (C8 H7 O2)6 (C12 H8 N2)2]'
_chemical_formula_moiety         'C72 H58 Dy2 N4 O12'
_chemical_formula_sum            'C72 H58 Dy2 N4 O12'
_chemical_formula_weight         1496.22
_chemical_name_systematic
;
di-μ-4-methylbenzoato-κ⁴O:O'-bis[bis(4-methylbenzoato-
κ²O,O')(1,10-phenanthroline-κ²N,N')dysprosium(III)]
tetra-μ-4-methylbenzoato-κ⁸O:O'-bis[(4-methylbenzoato-
κ²O,O')(1,10-phenanthroline-κ²N,N')dysprosium(III)]
;
_space_group_IT_number           2
_symmetry_cell_setting           triclinic
_symmetry_space_group_name_Hall  '-P 1'
_symmetry_space_group_name_H-M   'P -1'
_atom_sites_solution_hydrogens   geom
_atom_sites_solution_primary     direct
_atom_sites_solution_secondary   difmap
_audit_creation_method           SHELXL97
_cell_angle_alpha                91.619(12)
_cell_angle_beta                 97.925(11)
_cell_angle_gamma                106.440(10)
_cell_formula_units_Z            2
_cell_length_a                   12.760(8)
_cell_length_b                   13.346(9)
_cell_length_c                   19.758(13)
_cell_measurement_reflns_used    987
_cell_measurement_temperature    293(2)
_cell_measurement_theta_max      23.73
_cell_measurement_theta_min      3.12
_cell_volume                     3188(4)
_computing_cell_refinement       SMART
_computing_data_collection       'SMART (Bruker, 1997)'
_computing_data_reduction        'SAINT (Bruker, 1997)'
_computing_molecular_graphics    'SHELXTL (Bruker, 1998)'
_computing_publication_material  SHELXTL
_computing_structure_refinement  'SHELXL97 (Sheldrick, 1997)'
_computing_structure_solution    'SHELXS97 (Sheldrick, 1990)'
_diffrn_ambient_temperature      293(2)
_diffrn_measured_fraction_theta_full 0.995
_diffrn_measured_fraction_theta_max 0.995
_diffrn_measurement_device_type  'Bruker SMART CCD area-detector'
_diffrn_measurement_method       'φ and ω'
_diffrn_radiation_monochromator  graphite
_diffrn_radiation_source         'fine-focus sealed tube'
_diffrn_radiation_type           MoK\a
_diffrn_radiation_wavelength     0.71073
_diffrn_reflns_av_R_equivalents  0.0328
_diffrn_reflns_av_sigmaI/netI    0.0742
_diffrn_reflns_limit_h_max       14
_diffrn_reflns_limit_h_min       -15
_diffrn_reflns_limit_k_max       15
_diffrn_reflns_limit_k_min       -13
_diffrn_reflns_limit_l_max       23
_diffrn_reflns_limit_l_min       -20
_diffrn_reflns_number            16586
_diffrn_reflns_theta_full        25.01
_diffrn_reflns_theta_max         25.01
_diffrn_reflns_theta_min         1.04
_diffrn_standards_decay_%        0
_diffrn_standards_interval_count 0
_diffrn_standards_interval_time  0
_diffrn_standards_number         0
_exptl_absorpt_coefficient_mu    2.392
_exptl_absorpt_correction_T_max  0.750
_exptl_absorpt_correction_T_min  0.541
_exptl_absorpt_correction_type   multi-scan
_exptl_absorpt_process_details   '(SADABS; Sheldrick, 1996)'
_exptl_crystal_colour            yellow
_exptl_crystal_density_diffrn    1.559
_exptl_crystal_density_meas      ?
_exptl_crystal_density_method    'not measured'
_exptl_crystal_description       prism
_exptl_crystal_F_000             1492
_exptl_crystal_size_max          0.22
_exptl_crystal_size_mid          0.18
_exptl_crystal_size_min          0.12
_refine_diff_density_max         0.856
_refine_diff_density_min         -0.958
_refine_ls_extinction_method     none
_refine_ls_goodness_of_fit_ref   1.106
_refine_ls_hydrogen_treatment    constr
_refine_ls_matrix_type           full
_refine_ls_number_parameters     811
_refine_ls_number_reflns         11165
_refine_ls_number_restraints     18
_refine_ls_restrained_S_all      1.112
_refine_ls_R_factor_all          0.0811
_refine_ls_R_factor_gt           0.0434
_refine_ls_shift/su_max          0.003
_refine_ls_shift/su_mean         0.000
_refine_ls_structure_factor_coef Fsqd
_refine_ls_weighting_details
'calc w = 1/[σ²(Fo²)+(0.0549P)²+0.0276P] where P=(Fo²+2Fc²)/3'
_refine_ls_weighting_scheme      calc
_refine_ls_wR_factor_gt          0.0906
_refine_ls_wR_factor_ref         0.1214
_reflns_number_gt                7695
_reflns_number_total             11165
_reflns_threshold_expression     I>2σ(I)
_cod_data_source_file            gd1354.cif
_cod_data_source_block           I
_cod_depositor_comments
;
The following automatic conversions were performed:
'_symmetry_cell_setting' value 'Triclinic' changed to 'triclinic'
according to '/home/saulius/struct/CIF-dictionaries/cif_core.dic'
dictionary named 'cif_core.dic' version 2.4.1 from 2010-06-29.

Automatic conversion script
Id: cif_fix_enum 1527 2010-12-29 10:47:43Z saulius 

The following automatic conversions were performed:

'_symmetry_cell_setting' value 'Triclinic' changed to 'triclinic'
according to /home/saulius/struct/CIF-dictionaries/cif_core.dic
dictionary named 'cif_core.dic' version 2.4.1 from 2010-06-29.

Automatic conversion script
Id: cif_fix_values 1715 2011-07-08 13:25:40Z adriana 

The following automatic conversions were performed:

'_exptl_crystal_density_meas' value 'not measured' was changed to '?'
- the value is perceived as not measured.

Automatic conversion script
Id: cif_fix_values 3008 2015-01-20 13:52:24Z robertas 
;
_cod_original_sg_symbol_H-M      P-1
_cod_database_code               2014687
_cod_database_fobs_code          2014687
loop_
_symmetry_equiv_pos_as_xyz
'x, y, z'
'-x, -y, -z'
loop_
_atom_site_label
_atom_site_fract_x
_atom_site_fract_y
_atom_site_fract_z
_atom_site_U_iso_or_equiv
_atom_site_adp_type
_atom_site_calc_flag
_atom_site_refinement_flags
_atom_site_occupancy
_atom_site_disorder_assembly
_atom_site_disorder_group
_atom_site_type_symbol
Dy1 0.71642(3) 0.54410(3) 0.501141(17) 0.03106(12) Uani d . 1 . . Dy
Dy2 0.38941(3) 0.54073(3) 0.057315(16) 0.02815(11) Uani d . 1 . . Dy
O1 0.8536(5) 0.6978(4) 0.4823(3) 0.0578(18) Uani d . 1 . . O
O2 0.8443(4) 0.6669(4) 0.5892(3) 0.0496(15) Uani d . 1 . . O
O3 0.8172(5) 0.4305(5) 0.5402(3) 0.0532(16) Uani d . 1 . . O
O4 0.6976(4) 0.4510(4) 0.6049(3) 0.0411(13) Uani d . 1 . . O
O5 0.5737(4) 0.4021(4) 0.4615(3) 0.0471(15) Uani d . 1 . . O
O6 0.3962(5) 0.3712(4) 0.4604(3) 0.0486(15) Uani d . 1 . . O
O7 0.3537(4) 0.3629(4) 0.0258(2) 0.0312(12) Uani d . 1 . . O
O8 0.4491(4) 0.3264(4) -0.0537(3) 0.0437(14) Uani d . 1 . . O
O9 0.3156(4) 0.6863(4) 0.0381(3) 0.0401(13) Uani d . 1 . . O
O10 0.3911(4) 0.6790(4) 0.1436(2) 0.0383(13) Uani d . 1 . . O
O11 0.5110(4) 0.4881(4) 0.1375(2) 0.0359(13) Uani d . 1 . . O
O12 0.6053(4) 0.4573(4) 0.0573(2) 0.0369(13) Uani d . 1 . . O
N1 0.6412(5) 0.5955(5) 0.3863(3) 0.0323(15) Uani d . 1 . . N
N2 0.8044(5) 0.4993(5) 0.4006(3) 0.0351(15) Uani d . 1 . . N
N3 0.1812(5) 0.4600(5) 0.0148(3) 0.0320(14) Uani d . 1 . . N
N4 0.2708(5) 0.4507(5) 0.1463(3) 0.0359(15) Uani d . 1 . . N
C1 0.5529(7) 0.6309(6) 0.3770(4) 0.044(2) Uani d . 1 . . C
H1A 0.5112 0.6279 0.4124 0.053 Uiso calc R 1 . . H
C2 0.5209(7) 0.6721(7) 0.3164(4) 0.049(2) Uani d . 1 . . C
H2A 0.4578 0.6946 0.3111 0.058 Uiso calc R 1 . . H
C3 0.5824(7) 0.6790(6) 0.2653(4) 0.048(2) Uani d . 1 . . C
H3A 0.5628 0.7083 0.2251 0.058 Uiso calc R 1 . . H
C4 0.6766(6) 0.6420(6) 0.2727(4) 0.040(2) Uani d . 1 . . C
C5 0.7461(8) 0.6430(7) 0.2212(4) 0.057(3) Uani d . 1 . . C
H5A 0.7338 0.6759 0.1813 0.069 Uiso calc R 1 . . H
C6 0.8274(7) 0.5984(8) 0.2289(4) 0.060(3) Uani d . 1 . . C
H6A 0.8709 0.6014 0.1945 0.072 Uiso calc R 1 . . H
C7 0.8498(6) 0.5457(7) 0.2890(4) 0.046(2) Uani d . 1 . . C
C8 0.9287(7) 0.4914(8) 0.2959(5) 0.061(3) Uani d . 1 . . C
H8A 0.9705 0.4886 0.2612 0.074 Uiso calc R 1 . . H
C9 0.9431(7) 0.4432(8) 0.3536(5) 0.060(3) Uani d . 1 . . C
H9A 0.9952 0.4062 0.3592 0.071 Uiso calc R 1 . . H
C10 0.8803(7) 0.4485(7) 0.4048(4) 0.048(2) Uani d . 1 . . C
H10A 0.8921 0.4144 0.4443 0.058 Uiso calc R 1 . . H
C11 0.7873(6) 0.5477(6) 0.3426(3) 0.0324(18) Uani d . 1 . . C
C12 0.7013(6) 0.5969(6) 0.3348(4) 0.0320(18) Uani d . 1 . . C
C13 0.8858(6) 0.7240(6) 0.5460(4) 0.041(2) Uani d . 1 . . C
C14 0.9718(7) 0.8250(6) 0.5659(4) 0.045(2) Uani d . 1 . . C
C15 1.0428(8) 0.8727(8) 0.5205(5) 0.070(3) Uani d . 1 . . C
H15A 1.0343 0.8413 0.4767 0.084 Uiso calc R 1 . . H
C16 1.1247(9) 0.9651(9) 0.5394(7) 0.092(4) Uani d . 1 . . C
H16A 1.1721 0.9955 0.5090 0.110 Uiso calc R 1 . . H
C17 1.1356(10) 1.0120(8) 0.6045(8) 0.095(5) Uani d . 1 . . C
C18 1.0641(10) 0.9649(8) 0.6495(6) 0.085(4) Uani d . 1 . . C
H18A 1.0712 0.9968 0.6930 0.102 Uiso calc R 1 . . H
C19 0.9842(8) 0.8726(7) 0.6304(5) 0.062(3) Uani d . 1 . . C
H19A 0.9377 0.8417 0.6611 0.074 Uiso calc R 1 . . H
C20 1.2277(11) 1.1152(10) 0.6212(7) 0.130(5) Uani d U 1 . . C
H20A 1.2290 1.1412 0.6672 0.194 Uiso calc R 1 . . H
H20B 1.2144 1.1656 0.5899 0.194 Uiso calc R 1 . . H
H20C 1.2975 1.1037 0.6170 0.194 Uiso calc R 1 . . H
C21 0.7734(7) 0.4141(7) 0.5937(4) 0.041(2) Uani d . 1 . . C
C22 0.8140(7) 0.3464(7) 0.6433(4) 0.044(2) Uani d . 1 . . C
C23 0.7888(7) 0.3412(7) 0.7093(4) 0.046(2) Uani d . 1 . . C
H23A 0.7441 0.3798 0.7229 0.055 Uiso calc R 1 . . H
C24 0.8285(8) 0.2802(8) 0.7551(4) 0.057(3) Uani d . 1 . . C
H24A 0.8107 0.2793 0.7992 0.069 Uiso calc R 1 . . H
C25 0.8927(9) 0.2214(8) 0.7379(5) 0.066(3) Uani d . 1 . . C
C26 0.9180(9) 0.2251(8) 0.6724(5) 0.075(3) Uani d . 1 . . C
H26A 0.9611 0.1845 0.6591 0.090 Uiso calc R 1 . . H
C27 0.8806(8) 0.2883(8) 0.6255(5) 0.066(3) Uani d . 1 . . C
H27A 0.9008 0.2910 0.5820 0.080 Uiso calc R 1 . . H
C28 0.9302(11) 0.1478(10) 0.7872(6) 0.106(4) Uani d . 1 . . C
H28A 0.9049 0.1547 0.8302 0.159 Uiso calc R 1 . . H
H28B 1.0094 0.1656 0.7944 0.159 Uiso calc R 1 . . H
H28C 0.8997 0.0769 0.7681 0.159 Uiso calc R 1 . . H
C29 0.4787(6) 0.3427(6) 0.4532(3) 0.0300(17) Uani d . 1 . . C
C30 0.4641(6) 0.2290(5) 0.4342(3) 0.0297(17) Uani d . 1 . . C
C31 0.5535(7) 0.1916(6) 0.4397(4) 0.048(2) Uani d . 1 . . C
H31A 0.6243 0.2361 0.4542 0.057 Uiso calc R 1 . . H
C32 0.5373(10) 0.0855(8) 0.4234(5) 0.070(3) Uani d . 1 . . C
H32A 0.5983 0.0598 0.4280 0.084 Uiso calc R 1 . . H
C33 0.4353(12) 0.0181(7) 0.4008(5) 0.074(3) Uani d . 1 . . C
C34 0.3485(10) 0.0575(8) 0.3947(6) 0.084(4) Uani d . 1 . . C
H34A 0.2781 0.0132 0.3791 0.100 Uiso calc R 1 . . H
C35 0.3613(7) 0.1623(7) 0.4111(5) 0.062(3) Uani d . 1 . . C
H35A 0.2999 0.1874 0.4063 0.074 Uiso calc R 1 . . H
C36 0.4197(12) -0.0962(9) 0.3833(6) 0.103(4) Uani d U 1 . . C
H36A 0.4900 -0.1101 0.3912 0.155 Uiso calc R 1 . . H
H36B 0.3879 -0.1136 0.3361 0.155 Uiso calc R 1 . . H
H36C 0.3713 -0.1377 0.4117 0.155 Uiso calc R 1 . . H
C37 0.1376(6) 0.4589(6) -0.0504(4) 0.040(2) Uani d . 1 . . C
H37A 0.1830 0.4933 -0.0807 0.048 Uiso calc R 1 . . H
C38 0.0274(7) 0.4088(7) -0.0754(4) 0.051(2) Uani d . 1 . . C
H38A 0.0007 0.4085 -0.1216 0.062 Uiso calc R 1 . . H
C39 -0.0401(6) 0.3609(7) -0.0322(4) 0.047(2) Uani d . 1 . . C
H39A -0.1144 0.3282 -0.0485 0.057 Uiso calc R 1 . . H
C40 0.0010(6) 0.3598(6) 0.0374(4) 0.040(2) Uani d . 1 . . C
C41 -0.0654(7) 0.3165(7) 0.0870(5) 0.057(3) Uani d . 1 . . C
H41A -0.1410 0.2865 0.0737 0.068 Uiso calc R 1 . . H
C42 -0.0220(7) 0.3178(7) 0.1523(5) 0.053(2) Uani d . 1 . . C
H42A -0.0687 0.2909 0.1838 0.064 Uiso calc R 1 . . H
C43 0.0937(7) 0.3589(6) 0.1757(4) 0.044(2) Uani d . 1 . . C
C44 0.1441(8) 0.3569(7) 0.2425(4) 0.055(2) Uani d . 1 . . C
H44A 0.1009 0.3272 0.2751 0.066 Uiso calc R 1 . . H
C45 0.2534(8) 0.3966(7) 0.2609(4) 0.052(2) Uani d . 1 . . C
H45A 0.2877 0.3931 0.3051 0.062 Uiso calc R 1 . . H
C46 0.3124(7) 0.4431(7) 0.2110(4) 0.047(2) Uani d . 1 . . C
H46A 0.3883 0.4718 0.2236 0.056 Uiso calc R 1 . . H
C47 0.1600(6) 0.4074(6) 0.1290(4) 0.0336(18) Uani d . 1 . . C
C48 0.1148(6) 0.4097(6) 0.0584(4) 0.0313(17) Uani d . 1 . . C
C49 0.3662(6) 0.3070(6) -0.0229(4) 0.0294(17) Uani d . 1 . . C
C50 0.2742(6) 0.2086(6) -0.0483(4) 0.0324(17) Uani d . 1 . . C
C51 0.2854(7) 0.1372(7) -0.0961(4) 0.050(2) Uani d . 1 . . C
H51A 0.3523 0.1469 -0.1125 0.060 Uiso calc R 1 . . H
C52 0.1949(9) 0.0488(7) -0.1202(5) 0.067(3) Uani d . 1 . . C
H52A 0.2035 -0.0001 -0.1519 0.081 Uiso calc R 1 . . H
C53 0.0965(8) 0.0337(7) -0.0983(5) 0.052(2) Uani d . 1 . . C
C54 0.0861(7) 0.1048(6) -0.0507(5) 0.052(2) Uani d . 1 . . C
H54A 0.0185 0.0955 -0.0354 0.063 Uiso calc R 1 . . H
C55 0.1739(6) 0.1904(6) -0.0248(4) 0.0375(19) Uani d . 1 . . C
H55A 0.1653 0.2364 0.0088 0.045 Uiso calc R 1 . . H
C56 0.0010(8) -0.0601(7) -0.1268(6) 0.082(4) Uani d . 1 . . C
H56A 0.0242 -0.1006 -0.1596 0.124 Uiso calc R 1 . . H
H56B -0.0591 -0.0370 -0.1487 0.124 Uiso calc R 1 . . H
H56C -0.0227 -0.1026 -0.0902 0.124 Uiso calc R 1 . . H
C57 0.3539(6) 0.7291(6) 0.0987(4) 0.0341(18) Uani d . 1 . . C
C58 0.3514(6) 0.8395(6) 0.1140(4) 0.0350(18) Uani d . 1 . . C
C59 0.3059(8) 0.8935(7) 0.0658(4) 0.056(2) Uani d . 1 . . C
H59A 0.2780 0.8622 0.0219 0.067 Uiso calc R 1 . . H
C60 0.3010(8) 0.9938(7) 0.0813(5) 0.064(3) Uani d . 1 . . C
H60A 0.2690 1.0284 0.0479 0.076 Uiso calc R 1 . . H
C61 0.3429(7) 1.0426(7) 0.1455(5) 0.057(3) Uani d . 1 . . C
C62 0.3866(8) 0.9884(7) 0.1935(5) 0.059(3) Uani d . 1 . . C
H62A 0.4134 1.0194 0.2376 0.071 Uiso calc R 1 . . H
C63 0.3921(7) 0.8892(7) 0.1784(4) 0.052(2) Uani d . 1 . . C
H63A 0.4238 0.8550 0.2121 0.062 Uiso calc R 1 . . H
C64 0.3328(10) 1.1510(7) 0.1634(6) 0.084(4) Uani d . 1 . . C
H64A 0.3651 1.1726 0.2102 0.127 Uiso calc R 1 . . H
H64B 0.2562 1.1486 0.1573 0.127 Uiso calc R 1 . . H
H64C 0.3708 1.2000 0.1340 0.127 Uiso calc R 1 . . H
C65 0.5720(6) 0.4423(6) 0.1155(4) 0.0323(18) Uani d . 1 . . C
C66 0.6086(5) 0.3625(6) 0.1573(4) 0.0323(18) Uani d . 1 . . C
C67 0.6465(7) 0.2871(7) 0.1281(5) 0.054(2) Uani d . 1 . . C
H67A 0.6516 0.2854 0.0816 0.065 Uiso calc R 1 . . H
C68 0.6769(8) 0.2140(8) 0.1684(6) 0.073(3) Uani d . 1 . . C
H68A 0.7023 0.1632 0.1485 0.088 Uiso calc R 1 . . H
C69 0.6705(8) 0.2147(9) 0.2370(6) 0.073(3) Uani d . 1 . . C
C70 0.6307(7) 0.2876(8) 0.2649(5) 0.059(3) Uani d . 1 . . C
H70A 0.6246 0.2877 0.3113 0.071 Uiso calc R 1 . . H
C71 0.5991(6) 0.3611(7) 0.2268(4) 0.043(2) Uani d . 1 . . C
H71A 0.5714 0.4099 0.2472 0.051 Uiso calc R 1 . . H
C72 0.7088(11) 0.1354(10) 0.2794(6) 0.108(4) Uani d U 1 . . C
H72A 0.7001 0.1466 0.3263 0.162 Uiso calc R 1 . . H
H72B 0.7853 0.1433 0.2768 0.162 Uiso calc R 1 . . H
H72C 0.6653 0.0660 0.2622 0.162 Uiso calc R 1 . . H
loop_
_atom_type_symbol
_atom_type_description
_atom_type_scat_dispersion_real
_atom_type_scat_dispersion_imag
_atom_type_scat_source
C C 0.0033 0.0016 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
H H 0.0000 0.0000 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
N N 0.0061 0.0033 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
O O 0.0106 0.0060 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
Dy Dy -0.1892 4.4098 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
loop_
_geom_angle_atom_site_label_1
_geom_angle_atom_site_label_2
_geom_angle_atom_site_label_3
_geom_angle_site_symmetry_1
_geom_angle_site_symmetry_3
_geom_angle
O5 Dy1 O6 . 2_666 92.3(2)
O5 Dy1 O3 . . 88.1(2)
O6 Dy1 O3 2_666 . 139.1(2)
O5 Dy1 O1 . . 150.90(19)
O6 Dy1 O1 2_666 . 95.3(2)
O3 Dy1 O1 . . 103.9(2)
O5 Dy1 O4 . . 79.63(19)
O6 Dy1 O4 2_666 . 85.2(2)
O3 Dy1 O4 . . 54.66(18)
O1 Dy1 O4 . . 128.94(18)
O5 Dy1 O2 . . 155.07(19)
O6 Dy1 O2 2_666 . 78.9(2)
O3 Dy1 O2 . . 83.7(2)
O1 Dy1 O2 . . 53.94(18)
O4 Dy1 O2 . . 76.43(18)
O5 Dy1 N1 . . 76.99(19)
O6 Dy1 N1 2_666 . 82.7(2)
O3 Dy1 N1 . . 136.7(2)
O1 Dy1 N1 . . 76.20(19)
O4 Dy1 N1 . . 153.11(18)
O2 Dy1 N1 . . 124.11(19)
O5 Dy1 N2 . . 85.6(2)
O6 Dy1 N2 2_666 . 147.3(2)
O3 Dy1 N2 . . 73.6(2)
O1 Dy1 N2 . . 72.9(2)
O4 Dy1 N2 . . 126.2(2)
O2 Dy1 N2 . . 114.3(2)
N1 Dy1 N2 . . 65.0(2)
O5 Dy1 C21 . . 84.2(2)
O6 Dy1 C21 2_666 . 111.9(2)
O3 Dy1 C21 . . 27.5(2)
O1 Dy1 C21 . . 118.4(2)
O4 Dy1 C21 . . 27.2(2)
O2 Dy1 C21 . . 77.7(2)
N1 Dy1 C21 . . 156.7(2)
N2 Dy1 C21 . . 100.4(2)
O5 Dy1 C13 . . 177.2(2)
O6 Dy1 C13 2_666 . 86.0(2)
O3 Dy1 C13 . . 94.7(2)
O1 Dy1 C13 . . 27.4(2)
O4 Dy1 C13 . . 102.5(2)
O2 Dy1 C13 . . 26.5(2)
N1 Dy1 C13 . . 100.5(2)
N2 Dy1 C13 . . 94.6(2)
C21 Dy1 C13 . . 98.6(2)
O12 Dy2 O8 2_665 2_665 78.43(18)
O12 Dy2 O11 2_665 . 125.54(18)
O8 Dy2 O11 2_665 . 79.83(19)
O12 Dy2 O7 2_665 . 78.31(17)
O8 Dy2 O7 2_665 . 127.43(18)
O11 Dy2 O7 . . 76.68(17)
O12 Dy2 O9 2_665 . 83.15(18)
O8 Dy2 O9 2_665 . 79.76(19)
O11 Dy2 O9 . . 139.83(18)
O7 Dy2 O9 . . 141.94(16)
O12 Dy2 O10 2_665 . 131.68(18)
O8 Dy2 O10 2_665 . 74.40(18)
O11 Dy2 O10 . . 87.87(18)
O7 Dy2 O10 . . 148.95(17)
O9 Dy2 O10 . . 53.35(17)
O12 Dy2 N3 2_665 . 81.72(18)
O8 Dy2 N3 2_665 . 148.82(19)
O11 Dy2 N3 . . 131.34(19)
O7 Dy2 N3 . . 70.48(18)
O9 Dy2 N3 . . 74.18(18)
O10 Dy2 N3 . . 102.34(18)
O12 Dy2 N4 2_665 . 142.40(18)
O8 Dy2 N4 2_665 . 139.13(19)
O11 Dy2 N4 . . 75.01(19)
O7 Dy2 N4 . . 77.03(18)
O9 Dy2 N4 . . 99.51(19)
O10 Dy2 N4 . . 72.99(19)
N3 Dy2 N4 . . 63.47(19)
O12 Dy2 C57 2_665 . 106.9(2)
O8 Dy2 C57 2_665 . 72.5(2)
O11 Dy2 C57 . . 113.0(2)
O7 Dy2 C57 . . 159.96(18)
O9 Dy2 C57 . . 27.20(18)
O10 Dy2 C57 . . 26.47(18)
N3 Dy2 C57 . . 90.8(2)
N4 Dy2 C57 . . 88.3(2)
C13 O1 Dy1 . . 93.8(5)
C13 O2 Dy1 . . 91.8(5)
C21 O3 Dy1 . . 93.7(5)
C21 O4 Dy1 . . 89.5(5)
C29 O5 Dy1 . . 158.2(5)
C29 O6 Dy1 . 2_666 162.4(5)
C49 O7 Dy2 . . 138.1(5)
C49 O8 Dy2 . 2_665 139.3(5)
C57 O9 Dy2 . . 93.7(4)
C57 O10 Dy2 . . 91.5(4)
C65 O11 Dy2 . . 117.2(5)
C65 O12 Dy2 . 2_665 162.9(4)
C1 N1 C12 . . 119.5(7)
C1 N1 Dy1 . . 122.8(5)
C12 N1 Dy1 . . 117.3(5)
C10 N2 C11 . . 117.5(7)
C10 N2 Dy1 . . 124.8(5)
C11 N2 Dy1 . . 116.5(5)
C37 N3 C48 . . 118.1(6)
C37 N3 Dy2 . . 122.1(5)
C48 N3 Dy2 . . 119.6(4)
C46 N4 C47 . . 115.9(7)
C46 N4 Dy2 . . 123.3(5)
C47 N4 Dy2 . . 120.8(5)
N1 C1 C2 . . 122.4(8)
N1 C1 H1A . . 118.8
C2 C1 H1A . . 118.8
C3 C2 C1 . . 119.3(8)
C3 C2 H2A . . 120.3
C1 C2 H2A . . 120.3
C2 C3 C4 . . 120.3(8)
C2 C3 H3A . . 119.8
C4 C3 H3A . . 119.8
C3 C4 C12 . . 117.1(8)
C3 C4 C5 . . 125.0(8)
C12 C4 C5 . . 117.9(8)
C6 C5 C4 . . 122.0(8)
C6 C5 H5A . . 119.0
C4 C5 H5A . . 119.0
C5 C6 C7 . . 121.6(8)
C5 C6 H6A . . 119.2
C7 C6 H6A . . 119.2
C8 C7 C11 . . 119.1(8)
C8 C7 C6 . . 122.6(8)
C11 C7 C6 . . 118.3(8)
C9 C8 C7 . . 118.6(9)
C9 C8 H8A . . 120.7
C7 C8 H8A . . 120.7
C8 C9 C10 . . 119.9(9)
C8 C9 H9A . . 120.1
C10 C9 H9A . . 120.1
N2 C10 C9 . . 123.8(8)
N2 C10 H10A . . 118.1
C9 C10 H10A . . 118.1
N2 C11 C7 . . 121.1(7)
N2 C11 C12 . . 118.8(7)
C7 C11 C12 . . 120.1(7)
N1 C12 C4 . . 121.2(7)
N1 C12 C11 . . 118.7(6)
C4 C12 C11 . . 120.0(7)
O2 C13 O1 . . 120.3(7)
O2 C13 C14 . . 121.6(7)
O1 C13 C14 . . 118.0(7)
O2 C13 Dy1 . . 61.7(4)
O1 C13 Dy1 . . 58.7(4)
C14 C13 Dy1 . . 175.2(6)
C19 C14 C15 . . 119.0(8)
C19 C14 C13 . . 120.0(8)
C15 C14 C13 . . 121.0(8)
C16 C15 C14 . . 121.3(10)
C16 C15 H15A . . 119.4
C14 C15 H15A . . 119.4
C15 C16 C17 . . 118.9(11)
C15 C16 H16A . . 120.6
C17 C16 H16A . . 120.6
C16 C17 C18 . . 119.8(10)
C16 C17 C20 . . 115.7(14)
C18 C17 C20 . . 124.5(13)
C19 C18 C17 . . 120.7(11)
C19 C18 H18A . . 119.6
C17 C18 H18A . . 119.6
C18 C19 C14 . . 120.4(10)
C18 C19 H19A . . 119.8
C14 C19 H19A . . 119.8
C17 C20 H20A . . 109.5
C17 C20 H20B . . 109.5
H20A C20 H20B . . 109.5
C17 C20 H20C . . 109.5
H20A C20 H20C . . 109.5
H20B C20 H20C . . 109.5
O4 C21 O3 . . 121.9(8)
O4 C21 C22 . . 120.5(7)
O3 C21 C22 . . 117.5(8)
O4 C21 Dy1 . . 63.3(4)
O3 C21 Dy1 . . 58.8(4)
C22 C21 Dy1 . . 175.3(6)
C27 C22 C23 . . 117.3(8)
C27 C22 C21 . . 120.8(8)
C23 C22 C21 . . 121.8(8)
C24 C23 C22 . . 121.4(9)
C24 C23 H23A . . 119.3
C22 C23 H23A . . 119.3
C25 C24 C23 . . 121.9(9)
C25 C24 H24A . . 119.1
C23 C24 H24A . . 119.1
C24 C25 C26 . . 117.6(9)
C24 C25 C28 . . 121.9(10)
C26 C25 C28 . . 120.5(10)
C25 C26 C27 . . 121.5(9)
C25 C26 H26A . . 119.2
C27 C26 H26A . . 119.2
C22 C27 C26 . . 120.3(9)
C22 C27 H27A . . 119.8
C26 C27 H27A . . 119.8
C25 C28 H28A . . 109.5
C25 C28 H28B . . 109.5
H28A C28 H28B . . 109.5
C25 C28 H28C . . 109.5
H28A C28 H28C . . 109.5
H28B C28 H28C . . 109.5
O5 C29 O6 . . 123.9(7)
O5 C29 C30 . . 117.1(7)
O6 C29 C30 . . 119.1(7)
C31 C30 C35 . . 119.3(8)
C31 C30 C29 . . 120.1(7)
C35 C30 C29 . . 120.5(7)
C30 C31 C32 . . 118.9(9)
C30 C31 H31A . . 120.6
C32 C31 H31A . . 120.6
C33 C32 C31 . . 122.4(10)
C33 C32 H32A . . 118.8
C31 C32 H32A . . 118.8
C34 C33 C32 . . 117.5(10)
C34 C33 C36 . . 121.1(12)
C32 C33 C36 . . 121.4(12)
C33 C34 C35 . . 121.8(10)
C33 C34 H34A . . 119.1
C35 C34 H34A . . 119.1
C30 C35 C34 . . 120.1(10)
C30 C35 H35A . . 120.0
C34 C35 H35A . . 120.0
C33 C36 H36A . . 109.5
C33 C36 H36B . . 109.5
H36A C36 H36B . . 109.5
C33 C36 H36C . . 109.5
H36A C36 H36C . . 109.5
H36B C36 H36C . . 109.5
N3 C37 C38 . . 123.0(8)
N3 C37 H37A . . 118.5
C38 C37 H37A . . 118.5
C39 C38 C37 . . 119.5(8)
C39 C38 H38A . . 120.3
C37 C38 H38A . . 120.3
C38 C39 C40 . . 120.2(7)
C38 C39 H39A . . 119.9
C40 C39 H39A . . 119.9
C39 C40 C48 . . 117.0(7)
C39 C40 C41 . . 123.9(7)
C48 C40 C41 . . 119.1(8)
C42 C41 C40 . . 121.3(8)
C42 C41 H41A . . 119.3
C40 C41 H41A . . 119.3
C41 C42 C43 . . 122.2(8)
C41 C42 H42A . . 118.9
C43 C42 H42A . . 118.9
C47 C43 C44 . . 117.8(8)
C47 C43 C42 . . 117.6(8)
C44 C43 C42 . . 124.6(8)
C45 C44 C43 . . 121.5(8)
C45 C44 H44A . . 119.3
C43 C44 H44A . . 119.3
C44 C45 C46 . . 116.5(8)
C44 C45 H45A . . 121.7
C46 C45 H45A . . 121.7
N4 C46 C45 . . 126.0(8)
N4 C46 H46A . . 117.0
C45 C46 H46A . . 117.0
N4 C47 C43 . . 122.3(7)
N4 C47 C48 . . 116.5(6)
C43 C47 C48 . . 121.1(7)
N3 C48 C40 . . 122.2(7)
N3 C48 C47 . . 119.5(6)
C40 C48 C47 . . 118.3(7)
O7 C49 O8 . . 125.6(7)
O7 C49 C50 . . 118.2(6)
O8 C49 C50 . . 116.3(7)
C51 C50 C55 . . 118.2(7)
C51 C50 C49 . . 122.1(7)
C55 C50 C49 . . 119.6(7)
C50 C51 C52 . . 119.7(8)
C50 C51 H51A . . 120.2
C52 C51 H51A . . 120.2
C53 C52 C51 . . 121.4(9)
C53 C52 H52A . . 119.3
C51 C52 H52A . . 119.3
C52 C53 C54 . . 118.5(8)
C52 C53 C56 . . 119.8(9)
C54 C53 C56 . . 121.7(9)
C53 C54 C55 . . 121.4(8)
C53 C54 H54A . . 119.3
C55 C54 H54A . . 119.3
C54 C55 C50 . . 120.8(8)
C54 C55 H55A . . 119.6
C50 C55 H55A . . 119.6
C53 C56 H56A . . 109.5
C53 C56 H56B . . 109.5
H56A C56 H56B . . 109.5
C53 C56 H56C . . 109.5
H56A C56 H56C . . 109.5
H56B C56 H56C . . 109.5
O10 C57 O9 . . 120.0(7)
O10 C57 C58 . . 121.6(7)
O9 C57 C58 . . 118.5(7)
O10 C57 Dy2 . . 62.0(4)
O9 C57 Dy2 . . 59.1(4)
C58 C57 Dy2 . . 169.7(5)
C59 C58 C63 . . 117.3(8)
C59 C58 C57 . . 122.0(7)
C63 C58 C57 . . 120.7(7)
C58 C59 C60 . . 121.3(8)
C58 C59 H59A . . 119.3
C60 C59 H59A . . 119.3
C61 C60 C59 . . 120.6(9)
C61 C60 H60A . . 119.7
C59 C60 H60A . . 119.7
C62 C61 C60 . . 118.0(9)
C62 C61 C64 . . 121.4(9)
C60 C61 C64 . . 120.5(9)
C61 C62 C63 . . 121.7(8)
C61 C62 H62A . . 119.2
C63 C62 H62A . . 119.2
C62 C63 C58 . . 121.1(8)
C62 C63 H63A . . 119.4
C58 C63 H63A . . 119.4
C61 C64 H64A . . 109.5
C61 C64 H64B . . 109.5
H64A C64 H64B . . 109.5
C61 C64 H64C . . 109.5
H64A C64 H64C . . 109.5
H64B C64 H64C . . 109.5
O11 C65 O12 . . 123.5(7)
O11 C65 C66 . . 119.5(7)
O12 C65 C66 . . 117.0(7)
C67 C66 C71 . . 118.7(8)
C67 C66 C65 . . 121.8(7)
C71 C66 C65 . . 119.4(7)
C66 C67 C68 . . 119.6(9)
C66 C67 H67A . . 120.2
C68 C67 H67A . . 120.2
C69 C68 C67 . . 121.5(10)
C69 C68 H68A . . 119.2
C67 C68 H68A . . 119.2
C70 C69 C68 . . 118.5(9)
C70 C69 C72 . . 122.0(10)
C68 C69 C72 . . 119.4(11)
C69 C70 C71 . . 121.9(9)
C69 C70 H70A . . 119.1
C71 C70 H70A . . 119.1
C70 C71 C66 . . 119.7(9)
C70 C71 H71A . . 120.1
C66 C71 H71A . . 120.1
C69 C72 H72A . . 109.5
C69 C72 H72B . . 109.5
H72A C72 H72B . . 109.5
C69 C72 H72C . . 109.5
H72A C72 H72C . . 109.5
H72B C72 H72C . . 109.5
loop_
_geom_bond_atom_site_label_1
_geom_bond_atom_site_label_2
_geom_bond_site_symmetry_2
_geom_bond_distance
_geom_bond_publ_flag
Dy1 O5 . 2.256(5) ?
Dy1 O6 2_666 2.257(6) ?
Dy1 O3 . 2.332(6) ?
Dy1 O1 . 2.367(5) ?
Dy1 O4 . 2.431(5) ?
Dy1 O2 . 2.433(5) ?
Dy1 N1 . 2.529(6) ?
Dy1 N2 . 2.547(6) ?
Dy1 C21 . 2.722(8) ?
Dy1 C13 . 2.763(8) ?
Dy2 O12 2_665 2.276(5) ?
Dy2 O8 2_665 2.318(5) ?
Dy2 O11 . 2.328(5) ?
Dy2 O7 . 2.335(5) ?
Dy2 O9 . 2.405(5) ?
Dy2 O10 . 2.471(5) ?
Dy2 N3 . 2.576(6) ?
Dy2 N4 . 2.579(6) ?
Dy2 C57 . 2.798(8) ?
O1 C13 . 1.276(9) ?
O2 C13 . 1.234(9) ?
O3 C21 . 1.259(9) ?
O4 C21 . 1.245(9) ?
O5 C29 . 1.232(8) ?
O6 C29 . 1.240(9) ?
O6 Dy1 2_666 2.257(6) ?
O7 C49 . 1.257(8) ?
O8 C49 . 1.259(8) ?
O8 Dy2 2_665 2.318(5) ?
O9 C57 . 1.281(8) ?
O10 C57 . 1.248(8) ?
O11 C65 . 1.231(9) ?
O12 C65 . 1.281(8) ?
O12 Dy2 2_665 2.276(5) ?
N1 C1 . 1.333(10) ?
N1 C12 . 1.354(9) ?
N2 C10 . 1.326(10) ?
N2 C11 . 1.354(9) ?
N3 C37 . 1.329(9) ?
N3 C48 . 1.350(9) ?
N4 C46 . 1.332(9) ?
N4 C47 . 1.357(9) ?
C1 C2 . 1.390(11) ?
C1 H1A . 0.9300 ?
C2 C3 . 1.352(11) ?
C2 H2A . 0.9300 ?
C3 C4 . 1.414(11) ?
C3 H3A . 0.9300 ?
C4 C12 . 1.417(10) ?
C4 C5 . 1.436(12) ?
C5 C6 . 1.330(13) ?
C5 H5A . 0.9300 ?
C6 C7 . 1.431(12) ?
C6 H6A . 0.9300 ?
C7 C8 . 1.392(12) ?
C7 C11 . 1.414(10) ?
C8 C9 . 1.340(12) ?
C8 H8A . 0.9300 ?
C9 C10 . 1.387(12) ?
C9 H9A . 0.9300 ?
C10 H10A . 0.9300 ?
C11 C12 . 1.424(11) ?
C13 C14 . 1.480(11) ?
C14 C19 . 1.376(12) ?
C14 C15 . 1.401(12) ?
C15 C16 . 1.374(13) ?
C15 H15A . 0.9300 ?
C16 C17 . 1.386(17) ?
C16 H16A . 0.9300 ?
C17 C18 . 1.397(17) ?
C17 C20 . 1.529(15) ?
C18 C19 . 1.362(13) ?
C18 H18A . 0.9300 ?
C19 H19A . 0.9300 ?
C20 H20A . 0.9600 ?
C20 H20B . 0.9600 ?
C20 H20C . 0.9600 ?
C21 C22 . 1.491(11) ?
C22 C27 . 1.374(12) ?
C22 C23 . 1.383(10) ?
C23 C24 . 1.374(12) ?
C23 H23A . 0.9300 ?
C24 C25 . 1.351(14) ?
C24 H24A . 0.9300 ?
C25 C26 . 1.375(13) ?
C25 C28 . 1.528(13) ?
C26 C27 . 1.396(12) ?
C26 H26A . 0.9300 ?
C27 H27A . 0.9300 ?
C28 H28A . 0.9600 ?
C28 H28B . 0.9600 ?
C28 H28C . 0.9600 ?
C29 C30 . 1.506(10) ?
C30 C31 . 1.361(11) ?
C30 C35 . 1.369(10) ?
C31 C32 . 1.393(12) ?
C31 H31A . 0.9300 ?
C32 C33 . 1.363(15) ?
C32 H32A . 0.9300 ?
C33 C34 . 1.347(15) ?
C33 C36 . 1.505(14) ?
C34 C35 . 1.384(13) ?
C34 H34A . 0.9300 ?
C35 H35A . 0.9300 ?
C36 H36A . 0.9600 ?
C36 H36B . 0.9600 ?
C36 H36C . 0.9600 ?
C37 C38 . 1.387(10) ?
C37 H37A . 0.9300 ?
C38 C39 . 1.341(11) ?
C38 H38A . 0.9300 ?
C39 C40 . 1.405(11) ?
C39 H39A . 0.9300 ?
C40 C48 . 1.412(10) ?
C40 C41 . 1.414(11) ?
C41 C42 . 1.330(12) ?
C41 H41A . 0.9300 ?
C42 C43 . 1.427(11) ?
C42 H42A . 0.9300 ?
C43 C47 . 1.387(10) ?
C43 C44 . 1.391(12) ?
C44 C45 . 1.337(12) ?
C44 H44A . 0.9300 ?
C45 C46 . 1.379(11) ?
C45 H45A . 0.9300 ?
C46 H46A . 0.9300 ?
C47 C48 . 1.439(10) ?
C49 C50 . 1.511(9) ?
C50 C51 . 1.372(11) ?
C50 C55 . 1.381(10) ?
C51 C52 . 1.414(12) ?
C51 H51A . 0.9300 ?
C52 C53 . 1.348(13) ?
C52 H52A . 0.9300 ?
C53 C54 . 1.362(12) ?
C53 C56 . 1.509(11) ?
C54 C55 . 1.381(10) ?
C54 H54A . 0.9300 ?
C55 H55A . 0.9300 ?
C56 H56A . 0.9600 ?
C56 H56B . 0.9600 ?
C56 H56C . 0.9600 ?
C57 C58 . 1.505(10) ?
C58 C59 . 1.374(11) ?
C58 C63 . 1.381(10) ?
C59 C60 . 1.385(12) ?
C59 H59A . 0.9300 ?
C60 C61 . 1.376(12) ?
C60 H60A . 0.9300 ?
C61 C62 . 1.362(12) ?
C61 C64 . 1.525(12) ?
C62 C63 . 1.371(12) ?
C62 H62A . 0.9300 ?
C63 H63A . 0.9300 ?
C64 H64A . 0.9600 ?
C64 H64B . 0.9600 ?
C64 H64C . 0.9600 ?
C65 C66 . 1.502(10) ?
C66 C67 . 1.378(11) ?
C66 C71 . 1.396(10) ?
C67 C68 . 1.382(12) ?
C67 H67A . 0.9300 ?
C68 C69 . 1.368(14) ?
C68 H68A . 0.9300 ?
C69 C70 . 1.355(14) ?
C69 C72 . 1.514(13) ?
C70 C71 . 1.369(11) ?
C70 H70A . 0.9300 ?
C71 H71A . 0.9300 ?
C72 H72A . 0.9600 ?
C72 H72B . 0.9600 ?
C72 H72C . 0.9600 ?
loop_
_geom_torsion_atom_site_label_1
_geom_torsion_atom_site_label_2
_geom_torsion_atom_site_label_3
_geom_torsion_atom_site_label_4
_geom_torsion_site_symmetry_1
_geom_torsion
O5 Dy1 O1 C13 . 175.2(5)
O6 Dy1 O1 C13 2_666 70.6(5)
O3 Dy1 O1 C13 . -72.9(5)
O4 Dy1 O1 C13 . -17.4(6)
O2 Dy1 O1 C13 . -1.5(5)
N1 Dy1 O1 C13 . 151.8(5)
N2 Dy1 O1 C13 . -140.6(5)
C21 Dy1 O1 C13 . -47.8(6)
O5 Dy1 O2 C13 . -174.6(5)
O6 Dy1 O2 C13 2_666 -103.5(5)
O3 Dy1 O2 C13 . 113.7(5)
O1 Dy1 O2 C13 . 1.5(5)
O4 Dy1 O2 C13 . 168.8(5)
N1 Dy1 O2 C13 . -30.3(6)
N2 Dy1 O2 C13 . 44.9(5)
C21 Dy1 O2 C13 . 140.9(5)
O5 Dy1 O3 C21 . -81.0(5)
O6 Dy1 O3 C21 2_666 10.4(6)
O1 Dy1 O3 C21 . 125.8(5)
O4 Dy1 O3 C21 . -2.4(4)
O2 Dy1 O3 C21 . 75.4(5)
N1 Dy1 O3 C21 . -149.7(5)
N2 Dy1 O3 C21 . -167.0(5)
C13 Dy1 O3 C21 . 99.6(5)
O5 Dy1 O4 C21 . 97.5(5)
O6 Dy1 O4 C21 2_666 -169.3(5)
O3 Dy1 O4 C21 . 2.4(4)
O1 Dy1 O4 C21 . -76.3(5)
O2 Dy1 O4 C21 . -89.5(5)
N1 Dy1 O4 C21 . 127.4(5)
N2 Dy1 O4 C21 . 20.8(5)
C13 Dy1 O4 C21 . -84.5(5)
O6 Dy1 O5 C29 2_666 -12.5(14)
O3 Dy1 O5 C29 . 126.5(14)
O1 Dy1 O5 C29 . -117.8(14)
O4 Dy1 O5 C29 . 72.1(14)
O2 Dy1 O5 C29 . 55.8(16)
N1 Dy1 O5 C29 . -94.5(14)
N2 Dy1 O5 C29 . -159.8(14)
C21 Dy1 O5 C29 . 99.2(14)
C13 Dy1 O5 C29 . -66(5)
O12 Dy2 O7 C49 2_665 19.3(6)
O8 Dy2 O7 C49 2_665 -46.1(7)
O11 Dy2 O7 C49 . -112.0(7)
O9 Dy2 O7 C49 . 81.8(7)
O10 Dy2 O7 C49 . -174.1(6)
N3 Dy2 O7 C49 . 104.5(7)
N4 Dy2 O7 C49 . 170.6(7)
C57 Dy2 O7 C49 . 126.6(8)
O12 Dy2 O9 C57 2_665 -150.9(4)
O8 Dy2 O9 C57 2_665 -71.5(4)
O11 Dy2 O9 C57 . -11.0(5)
O7 Dy2 O9 C57 . 148.1(4)
O10 Dy2 O9 C57 . 6.6(4)
N3 Dy2 O9 C57 . 125.8(4)
N4 Dy2 O9 C57 . 67.0(4)
O12 Dy2 O10 C57 2_665 23.7(5)
O8 Dy2 O10 C57 2_665 81.9(4)
O11 Dy2 O10 C57 . 162.0(4)
O7 Dy2 O10 C57 . -138.6(4)
O9 Dy2 O10 C57 . -6.8(4)
N3 Dy2 O10 C57 . -66.1(4)
N4 Dy2 O10 C57 . -123.1(4)
O12 Dy2 O11 C65 2_665 -12.1(6)
O8 Dy2 O11 C65 2_665 -79.9(5)
O7 Dy2 O11 C65 . 52.7(5)
O9 Dy2 O11 C65 . -140.4(5)
O10 Dy2 O11 C65 . -154.4(5)
N3 Dy2 O11 C65 . 101.0(5)
N4 Dy2 O11 C65 . 132.6(6)
C57 Dy2 O11 C65 . -145.8(5)
O5 Dy1 N1 C1 . 80.5(6)
O6 Dy1 N1 C1 2_666 -13.6(6)
O3 Dy1 N1 C1 . 153.4(5)
O1 Dy1 N1 C1 . -110.9(6)
O4 Dy1 N1 C1 . 50.3(8)
O2 Dy1 N1 C1 . -84.9(6)
N2 Dy1 N1 C1 . 171.7(6)
C21 Dy1 N1 C1 . 117.2(7)
C13 Dy1 N1 C1 . -98.1(6)
O5 Dy1 N1 C12 . -106.6(5)
O6 Dy1 N1 C12 2_666 159.3(5)
O3 Dy1 N1 C12 . -33.7(6)
O1 Dy1 N1 C12 . 61.9(5)
O4 Dy1 N1 C12 . -136.9(5)
O2 Dy1 N1 C12 . 88.0(5)
N2 Dy1 N1 C12 . -15.4(5)
C21 Dy1 N1 C12 . -69.9(8)
C13 Dy1 N1 C12 . 74.8(5)
O5 Dy1 N2 C10 . -99.1(7)
O6 Dy1 N2 C10 2_666 173.4(6)
O3 Dy1 N2 C10 . -9.8(6)
O1 Dy1 N2 C10 . 100.8(7)
O4 Dy1 N2 C10 . -25.4(7)
O2 Dy1 N2 C10 . 65.3(7)
N1 Dy1 N2 C10 . -176.8(7)
C21 Dy1 N2 C10 . -15.9(7)
C13 Dy1 N2 C10 . 83.7(7)
O5 Dy1 N2 C11 . 93.7(5)
O6 Dy1 N2 C11 2_666 6.2(7)
O3 Dy1 N2 C11 . -177.0(5)
O1 Dy1 N2 C11 . -66.4(5)
O4 Dy1 N2 C11 . 167.4(4)
O2 Dy1 N2 C11 . -101.9(5)
N1 Dy1 N2 C11 . 16.0(5)
C21 Dy1 N2 C11 . 176.9(5)
C13 Dy1 N2 C11 . -83.5(5)
O12 Dy2 N3 C37 2_665 -10.7(6)
O8 Dy2 N3 C37 2_665 40.1(8)
O11 Dy2 N3 C37 . -141.6(6)
O7 Dy2 N3 C37 . -91.2(6)
O9 Dy2 N3 C37 . 74.5(6)
O10 Dy2 N3 C37 . 120.3(6)
N4 Dy2 N3 C37 . -176.1(7)
C57 Dy2 N3 C37 . 96.2(6)
O12 Dy2 N3 C48 2_665 163.9(6)
O8 Dy2 N3 C48 2_665 -145.3(5)
O11 Dy2 N3 C48 . 33.0(6)
O7 Dy2 N3 C48 . 83.4(5)
O9 Dy2 N3 C48 . -110.9(5)
O10 Dy2 N3 C48 . -65.1(5)
N4 Dy2 N3 C48 . -1.5(5)
C57 Dy2 N3 C48 . -89.2(5)
O12 Dy2 N4 C46 2_665 154.5(6)
O8 Dy2 N4 C46 2_665 -29.1(8)
O11 Dy2 N4 C46 . 24.9(6)
O7 Dy2 N4 C46 . 104.3(6)
O9 Dy2 N4 C46 . -114.4(6)
O10 Dy2 N4 C46 . -67.5(6)
N3 Dy2 N4 C46 . 178.8(7)
C57 Dy2 N4 C46 . -89.5(6)
O12 Dy2 N4 C47 2_665 -25.3(7)
O8 Dy2 N4 C47 2_665 151.1(5)
O11 Dy2 N4 C47 . -154.9(6)
O7 Dy2 N4 C47 . -75.5(6)
O9 Dy2 N4 C47 . 65.8(6)
O10 Dy2 N4 C47 . 112.7(6)
N3 Dy2 N4 C47 . -1.0(5)
C57 Dy2 N4 C47 . 90.7(6)
C12 N1 C1 C2 . -1.6(11)
Dy1 N1 C1 C2 . 171.2(6)
N1 C1 C2 C3 . -1.5(12)
C1 C2 C3 C4 . 1.8(12)
C2 C3 C4 C12 . 0.8(11)
C2 C3 C4 C5 . 178.4(8)
C3 C4 C5 C6 . -173.7(9)
C12 C4 C5 C6 . 3.8(13)
C4 C5 C6 C7 . 0.6(15)
C5 C6 C7 C8 . 174.8(9)
C5 C6 C7 C11 . -3.9(13)
C11 C7 C8 C9 . -0.4(13)
C6 C7 C8 C9 . -179.1(9)
C7 C8 C9 C10 . -0.2(14)
C11 N2 C10 C9 . 0.6(12)
Dy1 N2 C10 C9 . -166.4(7)
C8 C9 C10 N2 . 0.1(14)
C10 N2 C11 C7 . -1.2(10)
Dy1 N2 C11 C7 . 166.9(5)
C10 N2 C11 C12 . 175.8(7)
Dy1 N2 C11 C12 . -16.0(8)
C8 C7 C11 N2 . 1.1(11)
C6 C7 C11 N2 . 179.9(7)
C8 C7 C11 C12 . -175.9(7)
C6 C7 C11 C12 . 2.9(11)
C1 N1 C12 C4 . 4.4(10)
Dy1 N1 C12 C4 . -168.8(5)
C1 N1 C12 C11 . -172.7(7)
Dy1 N1 C12 C11 . 14.2(8)
C3 C4 C12 N1 . -4.0(10)
C5 C4 C12 N1 . 178.3(7)
C3 C4 C12 C11 . 173.0(6)
C5 C4 C12 C11 . -4.7(10)
N2 C11 C12 N1 . 1.4(10)
C7 C11 C12 N1 . 178.5(7)
N2 C11 C12 C4 . -175.7(6)
C7 C11 C12 C4 . 1.4(10)
Dy1 O2 C13 O1 . -2.7(8)
Dy1 O2 C13 C14 . 176.0(7)
Dy1 O1 C13 O2 . 2.8(9)
Dy1 O1 C13 C14 . -176.0(6)
O5 Dy1 C13 O2 . 127(4)
O6 Dy1 C13 O2 2_666 73.0(5)
O3 Dy1 C13 O2 . -65.9(5)
O1 Dy1 C13 O2 . -177.3(9)
O4 Dy1 C13 O2 . -11.1(5)
N1 Dy1 C13 O2 . 154.8(5)
N2 Dy1 C13 O2 . -139.8(5)
C21 Dy1 C13 O2 . -38.5(5)
O5 Dy1 C13 O1 . -56(5)
O6 Dy1 C13 O1 2_666 -109.7(5)
O3 Dy1 C13 O1 . 111.4(5)
O4 Dy1 C13 O1 . 166.2(5)
O2 Dy1 C13 O1 . 177.3(9)
N1 Dy1 C13 O1 . -27.9(5)
N2 Dy1 C13 O1 . 37.5(5)
C21 Dy1 C13 O1 . 138.8(5)
O5 Dy1 C13 C14 . -8(11)
O6 Dy1 C13 C14 2_666 -61(8)
O3 Dy1 C13 C14 . 160(8)
O1 Dy1 C13 C14 . 48(7)
O4 Dy1 C13 C14 . -146(8)
O2 Dy1 C13 C14 . -134(8)
N1 Dy1 C13 C14 . 20(8)
N2 Dy1 C13 C14 . 86(8)
C21 Dy1 C13 C14 . -173(8)
O2 C13 C14 C19 . -19.6(13)
O1 C13 C14 C19 . 159.1(8)
Dy1 C13 C14 C19 . 113(7)
O2 C13 C14 C15 . 159.3(9)
O1 C13 C14 C15 . -22.0(12)
Dy1 C13 C14 C15 . -68(8)
C19 C14 C15 C16 . 0.7(15)
C13 C14 C15 C16 . -178.2(10)
C14 C15 C16 C17 . -0.9(18)
C15 C16 C17 C18 . 0.4(18)
C15 C16 C17 C20 . -179.2(11)
C16 C17 C18 C19 . 0.5(18)
C20 C17 C18 C19 . -180.0(11)
C17 C18 C19 C14 . -0.7(16)
C15 C14 C19 C18 . 0.1(14)
C13 C14 C19 C18 . 179.1(9)
Dy1 O4 C21 O3 . -4.3(8)
Dy1 O4 C21 C22 . 176.9(7)
Dy1 O3 C21 O4 . 4.5(8)
Dy1 O3 C21 C22 . -176.7(6)
O5 Dy1 C21 O4 . -78.6(5)
O6 Dy1 C21 O4 2_666 11.5(5)
O3 Dy1 C21 O4 . -175.8(8)
O1 Dy1 C21 O4 . 120.8(4)
O2 Dy1 C21 O4 . 84.1(5)
N1 Dy1 C21 O4 . -114.5(6)
N2 Dy1 C21 O4 . -163.1(4)
C13 Dy1 C21 O4 . 100.6(5)
O5 Dy1 C21 O3 . 97.1(5)
O6 Dy1 C21 O3 2_666 -172.7(4)
O1 Dy1 C21 O3 . -63.4(5)
O4 Dy1 C21 O3 . 175.8(8)
O2 Dy1 C21 O3 . -100.1(5)
N1 Dy1 C21 O3 . 61.3(8)
N2 Dy1 C21 O3 . 12.7(5)
C13 Dy1 C21 O3 . -83.6(5)
O5 Dy1 C21 C22 . 136(7)
O6 Dy1 C21 C22 2_666 -134(7)
O3 Dy1 C21 C22 . 39(7)
O1 Dy1 C21 C22 . -25(8)
O4 Dy1 C21 C22 . -146(8)
O2 Dy1 C21 C22 . -62(7)
N1 Dy1 C21 C22 . 100(7)
N2 Dy1 C21 C22 . 51(7)
C13 Dy1 C21 C22 . -45(7)
O4 C21 C22 C27 . 166.6(9)
O3 C21 C22 C27 . -12.3(12)
Dy1 C21 C22 C27 . -49(8)
O4 C21 C22 C23 . -14.9(12)
O3 C21 C22 C23 . 166.2(8)
Dy1 C21 C22 C23 . 129(7)
C27 C22 C23 C24 . -0.1(13)
C21 C22 C23 C24 . -178.7(8)
C22 C23 C24 C25 . -0.9(14)
C23 C24 C25 C26 . 0.4(15)
C23 C24 C25 C28 . -175.7(10)
C24 C25 C26 C27 . 1.0(17)
C28 C25 C26 C27 . 177.2(11)
C23 C22 C27 C26 . 1.5(15)
C21 C22 C27 C26 . -179.9(9)
C25 C26 C27 C22 . -2.0(17)
Dy1 O5 C29 O6 . 23.8(19)
Dy1 O5 C29 C30 . -155.3(11)
Dy1 O6 C29 O5 2_666 -35(2)
Dy1 O6 C29 C30 2_666 144.3(15)
O5 C29 C30 C31 . 12.7(10)
O6 C29 C30 C31 . -166.4(7)
O5 C29 C30 C35 . -167.1(8)
O6 C29 C30 C35 . 13.7(11)
C35 C30 C31 C32 . -1.7(12)
C29 C30 C31 C32 . 178.5(7)
C30 C31 C32 C33 . 1.2(14)
C31 C32 C33 C34 . -0.1(16)
C31 C32 C33 C36 . 179.9(9)
C32 C33 C34 C35 . -0.4(17)
C36 C33 C34 C35 . 179.5(10)
C31 C30 C35 C34 . 1.2(14)
C29 C30 C35 C34 . -179.0(8)
C33 C34 C35 C30 . -0.1(17)
C48 N3 C37 C38 . 0.2(12)
Dy2 N3 C37 C38 . 174.9(6)
N3 C37 C38 C39 . 1.6(14)
C37 C38 C39 C40 . -1.2(13)
C38 C39 C40 C48 . -0.8(12)
C38 C39 C40 C41 . 176.2(8)
C39 C40 C41 C42 . -179.9(9)
C48 C40 C41 C42 . -3.0(14)
C40 C41 C42 C43 . -2.5(15)
C41 C42 C43 C47 . 6.0(14)
C41 C42 C43 C44 . -176.2(9)
C47 C43 C44 C45 . -2.5(14)
C42 C43 C44 C45 . 179.8(9)
C43 C44 C45 C46 . 2.4(14)
C47 N4 C46 C45 . -0.6(13)
Dy2 N4 C46 C45 . 179.6(7)
C44 C45 C46 N4 . -0.9(14)
C46 N4 C47 C43 . 0.5(11)
Dy2 N4 C47 C43 . -179.6(6)
C46 N4 C47 C48 . -176.5(7)
Dy2 N4 C47 C48 . 3.3(9)
C44 C43 C47 N4 . 0.9(12)
C42 C43 C47 N4 . 178.8(7)
C44 C43 C47 C48 . 177.9(8)
C42 C43 C47 C48 . -4.2(12)
C37 N3 C48 C40 . -2.3(11)
Dy2 N3 C48 C40 . -177.1(6)
C37 N3 C48 C47 . 178.6(7)
Dy2 N3 C48 C47 . 3.8(9)
C39 C40 C48 N3 . 2.6(12)
C41 C40 C48 N3 . -174.6(7)
C39 C40 C48 C47 . -178.3(7)
C41 C40 C48 C47 . 4.5(11)
N4 C47 C48 N3 . -4.6(11)
C43 C47 C48 N3 . 178.2(7)
N4 C47 C48 C40 . 176.2(7)
C43 C47 C48 C40 . -0.9(11)
Dy2 O7 C49 O8 . 39.6(11)
Dy2 O7 C49 C50 . -139.5(5)
Dy2 O8 C49 O7 2_665 -6.9(12)
Dy2 O8 C49 C50 2_665 172.2(5)
O7 C49 C50 C51 . -172.8(7)
O8 C49 C50 C51 . 8.0(11)
O7 C49 C50 C55 . 9.4(10)
O8 C49 C50 C55 . -169.8(7)
C55 C50 C51 C52 . 0.7(12)
C49 C50 C51 C52 . -177.2(7)
C50 C51 C52 C53 . 1.3(14)
C51 C52 C53 C54 . -1.4(14)
C51 C52 C53 C56 . 178.3(8)
C52 C53 C54 C55 . -0.3(14)
C56 C53 C54 C55 . 179.9(8)
C53 C54 C55 C50 . 2.3(13)
C51 C50 C55 C54 . -2.4(12)
C49 C50 C55 C54 . 175.5(7)
Dy2 O10 C57 O9 . 11.9(7)
Dy2 O10 C57 C58 . -168.8(6)
Dy2 O9 C57 O10 . -12.2(7)
Dy2 O9 C57 C58 . 168.5(6)
O12 Dy2 C57 O10 2_665 -161.7(4)
O8 Dy2 C57 O10 2_665 -90.1(4)
O11 Dy2 C57 O10 . -19.6(5)
O7 Dy2 C57 O10 . 95.9(7)
O9 Dy2 C57 O10 . 168.0(7)
N3 Dy2 C57 O10 . 116.7(4)
N4 Dy2 C57 O10 . 53.3(4)
O12 Dy2 C57 O9 2_665 30.3(4)
O8 Dy2 C57 O9 2_665 101.9(4)
O11 Dy2 C57 O9 . 172.3(4)
O7 Dy2 C57 O9 . -72.1(7)
O10 Dy2 C57 O9 . -168.0(7)
N3 Dy2 C57 O9 . -51.3(4)
N4 Dy2 C57 O9 . -114.7(4)
O12 Dy2 C57 C58 2_665 -49(3)
O8 Dy2 C57 C58 2_665 23(3)
O11 Dy2 C57 C58 . 93(3)
O7 Dy2 C57 C58 . -151(3)
O9 Dy2 C57 C58 . -79(3)
O10 Dy2 C57 C58 . 113(3)
N3 Dy2 C57 C58 . -131(3)
N4 Dy2 C57 C58 . 166(3)
O10 C57 C58 C59 . -176.9(7)
O9 C57 C58 C59 . 2.4(11)
Dy2 C57 C58 C59 . 76(3)
O10 C57 C58 C63 . 1.0(11)
O9 C57 C58 C63 . -179.7(7)
Dy2 C57 C58 C63 . -106(3)
C63 C58 C59 C60 . -0.2(14)
C57 C58 C59 C60 . 177.8(8)
C58 C59 C60 C61 . 0.8(15)
C59 C60 C61 C62 . -1.6(15)
C59 C60 C61 C64 . -177.3(10)
C60 C61 C62 C63 . 1.8(15)
C64 C61 C62 C63 . 177.5(9)
C61 C62 C63 C58 . -1.3(15)
C59 C58 C63 C62 . 0.4(13)
C57 C58 C63 C62 . -177.7(8)
Dy2 O11 C65 O12 . 28.8(9)
Dy2 O11 C65 C66 . -149.8(5)
Dy2 O12 C65 O11 2_665 -69(2)
Dy2 O12 C65 C66 2_665 109.2(17)
O11 C65 C66 C67 . 159.6(7)
O12 C65 C66 C67 . -19.1(10)
O11 C65 C66 C71 . -17.3(10)
O12 C65 C66 C71 . 164.0(6)
C71 C66 C67 C68 . -1.7(13)
C65 C66 C67 C68 . -178.6(8)
C66 C67 C68 C69 . -0.1(15)
C67 C68 C69 C70 . 1.7(16)
C67 C68 C69 C72 . -177.8(10)
C68 C69 C70 C71 . -1.4(16)
C72 C69 C70 C71 . 178.1(9)
C69 C70 C71 C66 . -0.5(14)
C67 C66 C71 C70 . 2.0(12)
C65 C66 C71 C70 . 179.0(7)
