#------------------------------------------------------------------------------
#$Date: 2016-02-20 00:18:51 +0200 (Sat, 20 Feb 2016) $
#$Revision: 176760 $
#$URL: svn://www.crystallography.net/cod/cif/2/01/48/2014805.cif $
#------------------------------------------------------------------------------
#
# This file is available in the Crystallography Open Database (COD),
# http://www.crystallography.net/. The original data for this entry
# were provided by IUCr Journals, http://journals.iucr.org/.
#
# The file may be used within the scientific community so long as
# proper attribution is given to the journal article from which the
# data were obtained.
#
data_2014805
loop_
_publ_author_name
'Wang, Yue'
'Okabe, Nobuo'
_publ_section_title
;Tetrakis(μ₂-1,8-naphthyridine)-1:2κ⁴N:N';3:4κ⁴N:N'-bis(μ₂-salicylato)-1:4κ²O:O';2:3κ²O:O'-tetrakis(salicylic
 acid)-1κO,2κO,3κO,4κO-tetrasilver(I)(4Ag{---Ag})
;
_journal_issue                   6
_journal_name_full               'Acta Crystallographica Section C'
_journal_page_first              m263
_journal_page_last               m265
_journal_paper_doi               10.1107/S0108270105010498
_journal_volume                  61
_journal_year                    2005
_chemical_formula_iupac          '[Ag4 (C7 H5 O3)4 (C7 H6 O3)2 (C8 H6 N2)4]'
_chemical_formula_moiety         'C74 H56 Ag4 N8 O18'
_chemical_formula_sum            'C74 H56 Ag4 N8 O18'
_chemical_formula_weight         1776.75
_chemical_name_systematic
;
Tetrakis(μ₂-1,8-naphthyridine-1:2κ²N:N';3:4κ²N:N')-
bis(μ₂-salicylato-1:4κ²O:O';2:3κ²O:O')-
tetrakis(salicylato-1\kO;2\kO;3\kO;4\kO)tetrasilver(I)(4 Ag---Ag)
;
_space_group_IT_number           14
_symmetry_cell_setting           monoclinic
_symmetry_space_group_name_Hall  '-P 2ybc'
_symmetry_space_group_name_H-M   'P 1 21/c 1'
_atom_sites_solution_hydrogens   geom
_atom_sites_solution_primary     direct
_atom_sites_solution_secondary   difmap
_audit_creation_method           SHELXL97
_cell_angle_alpha                90.00
_cell_angle_beta                 99.26(4)
_cell_angle_gamma                90.00
_cell_formula_units_Z            2
_cell_length_a                   10.205(12)
_cell_length_b                   13.129(10)
_cell_length_c                   25.82(2)
_cell_measurement_reflns_used    21592
_cell_measurement_temperature    296.1
_cell_measurement_theta_max      27.5
_cell_measurement_theta_min      3.1
_cell_volume                     3414(5)
_computing_cell_refinement       RAPID-AUTO
_computing_data_collection       'RAPID-AUTO (Rigaku, 2003)'
_computing_data_reduction
;
CrystalStructure (Rigaku/MSC, 2004) and CRYSTALS (Watkin et al.,
1996)
;
_computing_molecular_graphics
'ORTEPIII (Farrugia, 1997) and PLATON (Spek, 2003)'
_computing_publication_material  CrystalStructure
_computing_structure_refinement  'SHELXL97 (Sheldrick, 1997)'
_computing_structure_solution
;
SIR97 (Altomare et al., 1999) and DIRDIF99 (Beurskens et
al.,  1999)
;
_diffrn_ambient_temperature      296.1
_diffrn_detector_area_resol_mean 10.00
_diffrn_measured_fraction_theta_full 0.996
_diffrn_measured_fraction_theta_max 0.996
_diffrn_measurement_device_type  'Rigaku R-AXIS RAPID'
_diffrn_measurement_method       ω
_diffrn_radiation_monochromator  graphite
_diffrn_radiation_source         'fine-focus sealed tube'
_diffrn_radiation_type           MoK\a
_diffrn_radiation_wavelength     0.71073
_diffrn_reflns_av_R_equivalents  0.0333
_diffrn_reflns_av_sigmaI/netI    0.0523
_diffrn_reflns_limit_h_max       13
_diffrn_reflns_limit_h_min       -13
_diffrn_reflns_limit_k_max       17
_diffrn_reflns_limit_k_min       -14
_diffrn_reflns_limit_l_max       33
_diffrn_reflns_limit_l_min       -33
_diffrn_reflns_number            32278
_diffrn_reflns_theta_full        27.48
_diffrn_reflns_theta_max         27.48
_diffrn_reflns_theta_min         3.10
_exptl_absorpt_coefficient_mu    1.211
_exptl_absorpt_correction_T_max  0.956
_exptl_absorpt_correction_T_min  0.646
_exptl_absorpt_correction_type   multi-scan
_exptl_absorpt_process_details   '(ABSCOR; Higashi, 1995)'
_exptl_crystal_colour            brown
_exptl_crystal_density_diffrn    1.728
_exptl_crystal_density_meas      ?
_exptl_crystal_density_method    'not measured'
_exptl_crystal_description       platelet
_exptl_crystal_F_000             1776.0
_exptl_crystal_size_max          0.3
_exptl_crystal_size_mid          0.3
_exptl_crystal_size_min          0.03
_refine_diff_density_max         0.605
_refine_diff_density_min         -0.464
_refine_ls_extinction_method     none
_refine_ls_goodness_of_fit_ref   0.803
_refine_ls_hydrogen_treatment    constr
_refine_ls_matrix_type           full
_refine_ls_number_parameters     474
_refine_ls_number_reflns         7793
_refine_ls_number_restraints     0
_refine_ls_restrained_S_all      0.803
_refine_ls_R_factor_all          0.0500
_refine_ls_R_factor_gt           0.0267
_refine_ls_shift/su_max          0.000
_refine_ls_shift/su_mean         0.000
_refine_ls_structure_factor_coef Fsqd
_refine_ls_weighting_details
'calc w = 1/[σ²(Fo²)+(0.0275P)²] where P=(Fo²+2Fc²)/3'
_refine_ls_weighting_scheme      calc
_refine_ls_wR_factor_gt          0.0518
_refine_ls_wR_factor_ref         0.0538
_reflns_number_gt                4718
_reflns_number_total             7793
_reflns_threshold_expression     I>2σ(I)
_cod_data_source_file            fg1829.cif
_cod_data_source_block           I
_cod_depositor_comments
;
The following automatic conversions were performed:

'_exptl_crystal_density_meas' value 'not measured' was changed to '?'
- the value is perceived as not measured.

Automatic conversion script
Id: cif_fix_values 3008 2015-01-20 13:52:24Z robertas 
;
_cod_original_sg_symbol_H-M      'P 21/c'
_cod_database_code               2014805
_cod_database_fobs_code          2014805
loop_
_symmetry_equiv_pos_as_xyz
'x, y, z'
'-x, y+1/2, -z+1/2'
'-x, -y, -z'
'x, -y-1/2, z-1/2'
loop_
_atom_site_label
_atom_site_fract_x
_atom_site_fract_y
_atom_site_fract_z
_atom_site_U_iso_or_equiv
_atom_site_adp_type
_atom_site_calc_flag
_atom_site_refinement_flags
_atom_site_occupancy
_atom_site_disorder_assembly
_atom_site_disorder_group
_atom_site_type_symbol
Ag1 0.62246(2) 0.470444(14) 0.053221(7) 0.05080(7) Uani d . 1 . . Ag
Ag2 0.43514(2) 0.659495(14) 0.032040(8) 0.04803(6) Uani d . 1 . . Ag
O1 0.7000(2) 0.56194(16) 0.13328(7) 0.0796(6) Uani d . 1 . . O
O2 0.5667(2) 0.69507(19) 0.11643(8) 0.0926(7) Uani d . 1 . . O
O3 0.8993(2) 0.56971(15) 0.20552(9) 0.0809(6) Uani d . 1 . . O
H31 0.8466 0.5441 0.1818 0.097 Uiso calc R 1 . . H
O4 0.34899(19) 0.83108(12) 0.05138(7) 0.0554(5) Uani d . 1 . . O
O5 0.15975(19) 0.83881(14) -0.00380(7) 0.0642(5) Uani d . 1 . . O
O6 0.3592(2) 0.88082(16) 0.14703(7) 0.0693(6) Uani d . 1 . . O
H61 0.3872 0.8600 0.1209 0.083 Uiso calc R 1 . . H
O7 0.7892(2) 0.30060(16) 0.11288(8) 0.0735(6) Uani d . 1 . . O
O8 0.7143(2) 0.15175(15) 0.07836(7) 0.0716(6) Uani d . 1 . . O
H81 0.7541 0.1698 0.0548 0.086 Uiso calc R 1 . . H
O9 0.7313(3) 0.34942(17) 0.20370(9) 0.0917(7) Uani d . 1 . . O
H91 0.7555 0.3587 0.1753 0.110 Uiso calc R 1 . . H
N1 0.26915(19) 0.57922(14) 0.06134(8) 0.0422(5) Uani d . 1 . . N
N2 0.23070(18) 0.46334(13) -0.00694(7) 0.0401(5) Uani d . 1 . . N
N3 0.47323(19) 0.37828(14) 0.08676(8) 0.0422(5) Uani d . 1 . . N
N4 0.43871(19) 0.26271(14) 0.01825(8) 0.0445(5) Uani d . 1 . . N
C1 0.7541(3) 0.71093(19) 0.18246(9) 0.0454(6) Uani d . 1 . . C
C2 0.8666(3) 0.6677(2) 0.21153(10) 0.0513(7) Uani d . 1 . . C
C3 0.9501(3) 0.7268(2) 0.24770(11) 0.0672(8) Uani d . 1 . . C
H3 1.0258 0.6980 0.2671 0.081 Uiso calc R 1 . . H
C4 0.9212(3) 0.8262(2) 0.25468(12) 0.0716(9) Uani d . 1 . . C
H4 0.9781 0.8654 0.2785 0.086 Uiso calc R 1 . . H
C5 0.8101(3) 0.8692(2) 0.22723(12) 0.0670(8) Uani d . 1 . . C
H5 0.7908 0.9371 0.2328 0.080 Uiso calc R 1 . . H
C6 0.7263(3) 0.8130(2) 0.19127(10) 0.0579(7) Uani d . 1 . . C
H6 0.6505 0.8430 0.1727 0.069 Uiso calc R 1 . . H
C7 0.6651(3) 0.6526(3) 0.14125(11) 0.0600(8) Uani d . 1 . . C
C8 0.3107(3) 0.2684(2) 0.14376(11) 0.0656(8) Uani d . 1 . . C
H8 0.2559 0.2324 0.1627 0.079 Uiso calc R 1 . . H
C9 0.3706(3) 0.3538(3) 0.16351(11) 0.0668(8) Uani d . 1 . . C
H9 0.3587 0.3773 0.1964 0.080 Uiso calc R 1 . . H
C10 0.4513(3) 0.4073(2) 0.13394(10) 0.0545(7) Uani d . 1 . . C
H10 0.4920 0.4667 0.1481 0.065 Uiso calc R 1 . . H
C11 0.2748(3) 0.1438(2) 0.07048(13) 0.0673(9) Uani d . 1 . . C
H11 0.2180 0.1046 0.0871 0.081 Uiso calc R 1 . . H
C12 0.3032(3) 0.11495(19) 0.02341(14) 0.0680(9) Uani d . 1 . . C
H12 0.2683 0.0548 0.0079 0.082 Uiso calc R 1 . . H
C13 0.3857(3) 0.17623(18) -0.00187(12) 0.0577(7) Uani d . 1 . . C
H13 0.4042 0.1554 -0.0343 0.069 Uiso calc R 1 . . H
C14 0.3309(3) 0.23303(18) 0.09425(11) 0.0515(7) Uani d . 1 . . C
C15 0.4141(2) 0.29125(17) 0.06626(10) 0.0415(6) Uani d . 1 . . C
C16 0.0724(3) 0.4918(2) 0.11084(11) 0.0615(8) Uani d . 1 . . C
H16 0.0069 0.4630 0.1274 0.074 Uiso calc R 1 . . H
C17 0.1416(3) 0.5741(2) 0.13188(11) 0.0639(8) Uani d . 1 . . C
H17 0.1240 0.6027 0.1630 0.077 Uiso calc R 1 . . H
C18 0.2395(3) 0.61519(19) 0.10616(10) 0.0545(7) Uani d . 1 . . C
H18 0.2868 0.6711 0.1213 0.065 Uiso calc R 1 . . H
C19 0.0344(3) 0.36505(19) 0.03896(11) 0.0558(7) Uani d . 1 . . C
H19 -0.0314 0.3324 0.0538 0.067 Uiso calc R 1 . . H
C20 0.0679(3) 0.33116(18) -0.00674(12) 0.0569(7) Uani d . 1 . . C
H20 0.0261 0.2742 -0.0233 0.068 Uiso calc R 1 . . H
C21 0.1653(3) 0.38206(18) -0.02886(10) 0.0486(6) Uani d . 1 . . C
H21 0.1857 0.3582 -0.0605 0.058 Uiso calc R 1 . . H
C22 0.1006(2) 0.45027(18) 0.06360(10) 0.0465(6) Uani d . 1 . . C
C23 0.1996(2) 0.49776(17) 0.03935(9) 0.0391(6) Uani d . 1 . . C
C24 0.1614(3) 0.89646(17) 0.08262(10) 0.0432(6) Uani d . 1 . . C
C25 0.2317(3) 0.90972(18) 0.13364(10) 0.0516(7) Uani d . 1 . . C
C26 0.1699(4) 0.9551(2) 0.17221(11) 0.0707(9) Uani d . 1 . . C
H26 0.2161 0.9638 0.2060 0.085 Uiso calc R 1 . . H
C27 0.0422(4) 0.9863(2) 0.16009(14) 0.0829(11) Uani d . 1 . . C
H27 0.0012 1.0158 0.1860 0.099 Uiso calc R 1 . . H
C28 -0.0291(3) 0.9753(2) 0.10992(14) 0.0813(10) Uani d . 1 . . C
H28 -0.1165 0.9977 0.1022 0.098 Uiso calc R 1 . . H
C29 0.0318(3) 0.93065(19) 0.07150(11) 0.0582(7) Uani d . 1 . . C
H29 -0.0151 0.9235 0.0377 0.070 Uiso calc R 1 . . H
C30 0.2289(3) 0.85233(17) 0.04077(10) 0.0441(6) Uani d . 1 . . C
C31 0.6695(3) 0.19006(19) 0.16174(9) 0.0482(6) Uani d . 1 . . C
C32 0.6767(3) 0.2571(2) 0.20436(11) 0.0565(7) Uani d . 1 . . C
C33 0.6194(3) 0.2307(2) 0.24801(11) 0.0688(8) Uani d . 1 . . C
H33 0.6252 0.2749 0.2764 0.083 Uiso calc R 1 . . H
C34 0.5558(3) 0.1410(3) 0.24893(12) 0.0725(9) Uani d . 1 . . C
H34 0.5174 0.1241 0.2781 0.087 Uiso calc R 1 . . H
C35 0.5464(3) 0.0738(2) 0.20731(12) 0.0691(8) Uani d . 1 . . C
H35 0.5018 0.0123 0.2085 0.083 Uiso calc R 1 . . H
C36 0.6035(3) 0.0982(2) 0.16400(11) 0.0584(7) Uani d . 1 . . C
H36 0.5977 0.0527 0.1361 0.070 Uiso calc R 1 . . H
C37 0.7311(3) 0.2187(2) 0.11563(11) 0.0563(7) Uani d . 1 . . C
loop_
_atom_type_symbol
_atom_type_description
_atom_type_scat_dispersion_real
_atom_type_scat_dispersion_imag
_atom_type_scat_source
C C 0.0033 0.0016 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
H H 0.0000 0.0000 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
O O 0.0106 0.0060 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
N N 0.0061 0.0033 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
Ag Ag -0.8971 1.1015 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
loop_
_geom_angle_atom_site_label_1
_geom_angle_atom_site_label_2
_geom_angle_atom_site_label_3
_geom_angle_site_symmetry_1
_geom_angle_site_symmetry_3
_geom_angle
_geom_angle_publ_flag
N3 Ag1 N2 . 3_665 167.87(7) yes
N3 Ag1 O1 . . 95.04(9) yes
N2 Ag1 O1 3_665 . 96.25(9) yes
N3 Ag1 Ag2 . 3_665 84.47(7) yes
N2 Ag1 Ag2 3_665 3_665 83.66(7) yes
O1 Ag1 Ag2 . 3_665 170.27(6) yes
N3 Ag1 Ag2 . . 93.57(8) yes
N2 Ag1 Ag2 3_665 . 92.36(8) yes
O1 Ag1 Ag2 . . 82.04(7) yes
Ag2 Ag1 Ag2 3_665 . 107.69(5) yes
N4 Ag2 N1 3_665 . 163.87(8) yes
N4 Ag2 O2 3_665 . 98.53(10) yes
N1 Ag2 O2 . . 97.34(10) yes
N4 Ag2 O4 3_665 . 87.58(8) yes
N1 Ag2 O4 . . 92.72(8) yes
O2 Ag2 O4 . . 78.90(8) yes
N4 Ag2 Ag1 3_665 3_665 83.53(7) yes
N1 Ag2 Ag1 . 3_665 84.43(7) yes
O2 Ag2 Ag1 . 3_665 148.42(7) yes
O4 Ag2 Ag1 . 3_665 132.63(5) yes
N4 Ag2 Ag1 3_665 . 94.12(8) yes
N1 Ag2 Ag1 . . 92.40(8) yes
O2 Ag2 Ag1 . . 76.12(7) yes
O4 Ag2 Ag1 . . 154.95(5) yes
Ag1 Ag2 Ag1 3_665 . 72.30(5) yes
C7 O1 Ag1 . . 123.0(2) no
C7 O2 Ag2 . . 132.0(2) no
C2 O3 H31 . . 109.5 no
C30 O4 Ag2 . . 121.62(16) no
C25 O6 H61 . . 109.5 no
C37 O8 H81 . . 109.5 no
C32 O9 H91 . . 109.5 no
C18 N1 C23 . . 117.9(2) no
C18 N1 Ag2 . . 114.82(17) no
C23 N1 Ag2 . . 127.29(15) no
C21 N2 C23 . . 117.8(2) no
C21 N2 Ag1 . 3_665 114.60(16) no
C23 N2 Ag1 . 3_665 127.61(15) no
C10 N3 C15 . . 117.9(2) no
C10 N3 Ag1 . . 115.26(17) no
C15 N3 Ag1 . . 126.45(15) no
C13 N4 C15 . . 118.0(2) no
C13 N4 Ag2 . 3_665 113.78(17) no
C15 N4 Ag2 . 3_665 128.16(16) no
C2 C1 C6 . . 118.4(2) no
C2 C1 C7 . . 122.1(3) no
C6 C1 C7 . . 119.4(3) no
O3 C2 C1 . . 121.8(2) no
O3 C2 C3 . . 118.3(3) no
C1 C2 C3 . . 119.9(3) no
C4 C3 C2 . . 120.1(3) no
C4 C3 H3 . . 119.9 no
C2 C3 H3 . . 119.9 no
C3 C4 C5 . . 120.7(3) no
C3 C4 H4 . . 119.6 no
C5 C4 H4 . . 119.6 no
C4 C5 C6 . . 120.4(3) no
C4 C5 H5 . . 119.8 no
C6 C5 H5 . . 119.8 no
C5 C6 C1 . . 120.4(3) no
C5 C6 H6 . . 119.8 no
C1 C6 H6 . . 119.8 no
O2 C7 O1 . . 124.4(3) no
O2 C7 C1 . . 119.3(3) no
O1 C7 C1 . . 116.3(3) no
C9 C8 C14 . . 119.9(3) no
C9 C8 H8 . . 120.1 no
C14 C8 H8 . . 120.1 no
C8 C9 C10 . . 119.1(3) no
C8 C9 H9 . . 120.5 no
C10 C9 H9 . . 120.5 no
N3 C10 C9 . . 123.8(3) no
N3 C10 H10 . . 118.1 no
C9 C10 H10 . . 118.1 no
C12 C11 C14 . . 119.8(3) no
C12 C11 H11 . . 120.1 no
C14 C11 H11 . . 120.1 no
C11 C12 C13 . . 119.5(3) no
C11 C12 H12 . . 120.3 no
C13 C12 H12 . . 120.3 no
N4 C13 C12 . . 123.2(3) no
N4 C13 H13 . . 118.4 no
C12 C13 H13 . . 118.4 no
C11 C14 C8 . . 124.4(3) no
C11 C14 C15 . . 117.5(3) no
C8 C14 C15 . . 118.1(3) no
N4 C15 N3 . . 116.9(2) no
N4 C15 C14 . . 122.0(2) no
N3 C15 C14 . . 121.2(2) no
C17 C16 C22 . . 119.3(2) no
C17 C16 H16 . . 120.3 no
C22 C16 H16 . . 120.3 no
C16 C17 C18 . . 119.0(3) no
C16 C17 H17 . . 120.5 no
C18 C17 H17 . . 120.5 no
N1 C18 C17 . . 123.9(3) no
N1 C18 H18 . . 118.0 no
C17 C18 H18 . . 118.0 no
C20 C19 C22 . . 119.0(2) no
C20 C19 H19 . . 120.5 no
C22 C19 H19 . . 120.5 no
C19 C20 C21 . . 119.7(3) no
C19 C20 H20 . . 120.1 no
C21 C20 H20 . . 120.1 no
N2 C21 C20 . . 123.4(2) no
N2 C21 H21 . . 118.3 no
C20 C21 H21 . . 118.3 no
C19 C22 C16 . . 123.4(2) no
C19 C22 C23 . . 118.4(2) no
C16 C22 C23 . . 118.2(2) no
N1 C23 N2 . . 116.7(2) no
N1 C23 C22 . . 121.6(2) no
N2 C23 C22 . . 121.7(2) no
C29 C24 C25 . . 118.8(2) no
C29 C24 C30 . . 121.0(3) no
C25 C24 C30 . . 120.1(2) no
O6 C25 C26 . . 117.8(3) no
O6 C25 C24 . . 122.2(2) no
C26 C25 C24 . . 120.0(3) no
C27 C26 C25 . . 119.6(3) no
C27 C26 H26 . . 120.2 no
C25 C26 H26 . . 120.2 no
C26 C27 C28 . . 121.7(3) no
C26 C27 H27 . . 119.2 no
C28 C27 H27 . . 119.2 no
C29 C28 C27 . . 119.0(3) no
C29 C28 H28 . . 120.5 no
C27 C28 H28 . . 120.5 no
C24 C29 C28 . . 120.9(3) no
C24 C29 H29 . . 119.5 no
C28 C29 H29 . . 119.5 no
O4 C30 O5 . . 123.8(2) no
O4 C30 C24 . . 118.8(2) no
O5 C30 C24 . . 117.4(3) no
C36 C31 C32 . . 118.5(2) no
C36 C31 C37 . . 121.8(2) no
C32 C31 C37 . . 119.7(3) no
O9 C32 C33 . . 117.8(3) no
O9 C32 C31 . . 121.9(3) no
C33 C32 C31 . . 120.2(3) no
C34 C33 C32 . . 119.9(3) no
C34 C33 H33 . . 120.1 no
C32 C33 H33 . . 120.1 no
C33 C34 C35 . . 121.2(3) no
C33 C34 H34 . . 119.4 no
C35 C34 H34 . . 119.4 no
C36 C35 C34 . . 119.8(3) no
C36 C35 H35 . . 120.1 no
C34 C35 H35 . . 120.1 no
C35 C36 C31 . . 120.5(3) no
C35 C36 H36 . . 119.8 no
C31 C36 H36 . . 119.8 no
O7 C37 O8 . . 123.8(3) no
O7 C37 C31 . . 122.5(3) no
O8 C37 C31 . . 113.7(3) no
loop_
_geom_bond_atom_site_label_1
_geom_bond_atom_site_label_2
_geom_bond_site_symmetry_2
_geom_bond_distance
_geom_bond_publ_flag
Ag1 N3 . 2.227(2) yes
Ag1 N2 3_665 2.237(2) yes
Ag1 O1 . 2.412(2) yes
Ag1 Ag2 3_665 2.772(2) yes
Ag1 Ag2 . 3.127(2) yes
Ag2 N4 3_665 2.219(2) yes
Ag2 N1 . 2.228(3) yes
Ag2 O2 . 2.414(3) yes
Ag2 O4 . 2.498(2) yes
Ag2 Ag1 3_665 2.7725(16) yes
O1 C7 . 1.269(4) no
O2 C7 . 1.234(4) no
O3 C2 . 1.345(3) no
O3 H31 . 0.82 no
O4 C30 . 1.244(3) no
O5 C30 . 1.262(3) no
O6 C25 . 1.346(3) no
O6 H61 . 0.82 no
O7 C37 . 1.235(3) no
O8 C37 . 1.295(3) no
O8 H81 . 0.82 no
O9 C32 . 1.335(3) no
O9 H91 . 0.82 no
N1 C18 . 1.329(3) no
N1 C23 . 1.357(3) no
N2 C21 . 1.335(3) no
N2 C23 . 1.362(3) no
N2 Ag1 3_665 2.237(2) no
N3 C10 . 1.329(3) no
N3 C15 . 1.359(3) no
N4 C13 . 1.327(3) no
N4 C15 . 1.357(3) no
N4 Ag2 3_665 2.219(2) no
C1 C2 . 1.388(4) no
C1 C6 . 1.396(3) no
C1 C7 . 1.494(4) no
C2 C3 . 1.394(4) no
C3 C4 . 1.356(4) no
C3 H3 . 0.93 no
C4 C5 . 1.359(4) no
C4 H4 . 0.93 no
C5 C6 . 1.373(4) no
C5 H5 . 0.93 no
C6 H6 . 0.93 no
C8 C9 . 1.339(4) no
C8 C14 . 1.406(4) no
C8 H8 . 0.93 no
C9 C10 . 1.399(4) no
C9 H9 . 0.93 no
C10 H10 . 0.93 no
C11 C12 . 1.349(4) no
C11 C14 . 1.402(4) no
C11 H11 . 0.93 no
C12 C13 . 1.399(4) no
C12 H12 . 0.93 no
C13 H13 . 0.93 no
C14 C15 . 1.422(3) no
C16 C17 . 1.356(4) no
C16 C22 . 1.407(4) no
C16 H16 . 0.93 no
C17 C18 . 1.394(4) no
C17 H17 . 0.93 no
C18 H18 . 0.93 no
C19 C20 . 1.355(4) no
C19 C22 . 1.405(4) no
C19 H19 . 0.93 no
C20 C21 . 1.394(3) no
C20 H20 . 0.93 no
C21 H21 . 0.93 no
C22 C23 . 1.416(3) no
C24 C29 . 1.382(4) no
C24 C25 . 1.406(4) no
C24 C30 . 1.489(3) no
C25 C26 . 1.395(4) no
C26 C27 . 1.354(4) no
C26 H26 . 0.93 no
C27 C28 . 1.388(5) no
C27 H27 . 0.93 no
C28 C29 . 1.383(4) no
C28 H28 . 0.93 no
C29 H29 . 0.93 no
C31 C36 . 1.387(4) no
C31 C32 . 1.402(3) no
C31 C37 . 1.482(4) no
C32 C33 . 1.394(4) no
C33 C34 . 1.346(4) no
C33 H33 . 0.93 no
C34 C35 . 1.382(4) no
C34 H34 . 0.93 no
C35 C36 . 1.379(4) no
C35 H35 . 0.93 no
C36 H36 . 0.93 no
loop_
_geom_hbond_atom_site_label_D
_geom_hbond_atom_site_label_H
_geom_hbond_atom_site_label_A
_geom_hbond_site_symmetry_A
_geom_hbond_distance_DH
_geom_hbond_distance_HA
_geom_hbond_distance_DA
_geom_hbond_angle_DHA
O3 H31 O1 . 0.82 1.81 2.531(4) 147
O6 H61 O4 . 0.82 1.81 2.540(4) 147
O8 H81 O5 3_665 0.82 1.70 2.484(4) 159
O9 H91 O7 . 0.82 1.86 2.589(4) 147
C16 H16 O3 1_455 0.93 2.82 3.396(5) 121
C27 H27 O3 2_655 0.93 2.91 3.596(6) 132
